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1.
Abstract

Carbonyl sulphide (OCS) is an important precursor of sulphate aerosols and consequently a key species in stratospheric ozone depletion. The SPectromètre InfraRouge d'Absorption à Lasers Embarqués (SPIRALE) and shortwave infrared (SWIR) balloon-borne instruments have flown in the tropics and in the polar Arctic, and ground-based measurements have been performed by the Qualité de l'Air (QualAir) Fourier Transform Spectrometer in Paris. Partial and total columns and vertical profiles have been obtained to study OCS variability with altitude, latitude, and season. The annual total column variation in Paris reveals a seasonal variation with a maximum in April–June and a minimum in November–January. Total column measurements above Paris and from SWIR balloon-borne instrument are compared with several MkIV measurements, several Network for the Detection of Atmospheric Composition Change (NDACC) stations, aircraft, ship, and balloon measurements to highlight the OCS total column decrease from tropical to polar latitudes. OCS high-resolution in situ vertical profiles have been measured for the first time in the altitude range between 14 and 30?km at tropical and polar latitudes. OCS profiles are compared with Atmospheric Chemistry Experiment (ACE) satellite measurements and show good agreement. Using the correlation between OCS and N2O from SPIRALE, the OCS stratospheric lifetime has been accurately determined. We find a stratospheric lifetime of 68?±?20 years at polar latitudes and 58?±?14 years at tropical latitudes leading to a global stratospheric sink of 49?±?14?Gg?S?y?1.  相似文献   

2.
Abstract?This paper presents the results of measurements of the concentration of surface ozone and concurrent standard meteorological parameters: total solar radiation, temperature, relative humidity, pressure, wind speed, and vertical and horizontal components of the wind. The data were collected from 2005 to 2010 at stations located in central Poland (Mazowieckie voivodeship): Warszawa (urban), Legionowo (suburban), Granica and Belsk (rural). Furthermore, Granica is situated in the forested area of Kampinoski National Park. Continuously measured surface ozone concentrations demonstrated the well-known diurnal cycle of surface ozone concentration with a maximum in the afternoon and a minimum in the early morning hours. The averaged diurnal variations over six years reveal that the highest concentrations appear at rural stations (Belsk: 55?µg?m?3 and Granica: 50?µg?m?3) and the lowest at the urban station (Warszawa: 41?µg?m?3). The threshold for high levels of surface ozone (120?µg?m?3 per 8?h) was exceeded most often at Granica and Belsk. The occurrence of the ozone “weekend effect,” especially at urban stations, has been identified. The difference between weekend and weekday surface ozone concentrations at urban and rural stations was as high as 6.5?µg?m?3 and approximately 2?µg?m?3, respectively. Using appropriate statistical tools, it has been shown that meteorological conditions have a significant influence on ozone concentration. High correlation coefficients were found between ozone concentration and solar radiation, temperature, relative humidity, and wind speed. The forward stepwise regression model explains up to 75% of the variations in daily surface ozone concentration in terms of meteorological variability in summer and up to 70% in winter. At the same time, a multilayer perceptron neural network model was used to reconstruct the concentration of surface ozone. High correlation coefficients (up to 0.89) indicate that, on the basis of standard meteorological parameters and NO2 concentration, we can determine ozone concentration with high accuracy.  相似文献   

3.
The ozone budget inside the middle stratospheric polar vortex(24-36 km) during the 2002-2003 Arctic winter is studied by analyzing Michelson Interferometer for Passive Atmospheric Sounding(MIPAS) satellite data.A comprehensive global chemical transport model(Model for Ozone and Related Chemical Tracers,MOZART-3) is used to analyze the observed variation in polar vortex ozone during the stratospheric sudden warming(SSW) events.Both MIPAS measurement and MOZART-3 calculation show that a pronounced increase(26-28 DU) in the polar vortex ozone due to the SSW events.Due to the weakening of the polar vortex,the exchange of ozone mass across the edge of the polar vortex increases substantially and amounts to about 3.0× 107 kg according to MOZART-3 calculation.The enhanced downward transport offsets about 80% of polar vortex ozone mass increase by horizontal transport.A "passive ozone" experiment shows that only ~55% of the vertical ozone mass flux in February and March can be attributed to the variation in vertical transport.It is also shown that the enhanced downward ozone above ~32 km should be attributed to the springtime photochemical ozone production.Due to the increase of air temperature,the NOx reaction rate increases by 40%-80% during the SSW events.As a result,NOx catalytic cycle causes another 44% decrease in polar vortex ozone compared to the net ozone changes due to dynamical transport.It is also shown that the largest change in polar vortex ozone is due to horizontal advection by planetary waves in January 2003.  相似文献   

4.
Data of stratospheric ozone measurements with the AK-3 lidar over Obninsk in 2012–2015 are compared with Aura/MLS and Aura/OMI satellite data and parallel surface observations of total ozone (TO) with the Brewer spectrophotometer. The maximum difference in mean ozone concentration between the lidar and Aura/MLS data in the altitude range of 13 to 32 km does not exceed 0.2 x 1012 mol./cm3 (or the maximum of 9% at the altitude of 13 km). At the same time, Aura/OMI data have a positive bias of about 20% relative to lidar data in the range of 13 to 20 km that is associated with OMI measurement errors according to literature data. Total ozone values calculated from lidar measurements jointly with the known climatology data are compared with those measured with the Brewer spectrophotometer. It is demonstrated that the correlation between the results of measurements obtained by two methods is close to linear, and the mean relative difference in the overall measurement range does not exceed 5%.  相似文献   

5.
祁凯  吴林林  张庆奎 《气象科学》2022,42(4):557-563
利用2012-2017年阜阳多普勒雷达与L波段雷达测风数据进行对比分析,统计两者的相关性和测量误差,进一步了解多普勒雷达风廓线产品的准确性和可信度。结果表明:两者测风结果一致性较好,风向和风速相关系数分别为0.97和0.94,标准差分别为19.5°和2.65 m·s^(-1)。多普勒雷达风速总体上在同一高度比L波段雷达风速偏小,两者风速相对偏差平均为24.48%;风速标准差随高度增高呈增大趋势,在降水期间对比差值小于非降水;风向标准差在7 km以下呈递减趋势,8 km以上有小幅增加趋势;风速相关系数随高度增加呈增大趋势,除低空偏低以外,其他高度相关系数均较高。  相似文献   

6.
In the field of climate change impact analysis, bidirectional changes in projections of future wind regimes varying among studies, locations, and models have been described in the literature, which is understandable from a global perspective. However, we should attempt to find evidence in the historical record to support these projections. This paper attempts to address this issue by analyzing historical wind gust observations for up to 57 years (1953–2009) over Canada. Two wind gust analysis techniques were used: the speed of daily wind gust events ≥50?km?h?1 was compared with (1) the climatological daily temperature anomaly and (2) the climatological daily sea level air pressure anomaly. In addition, the frequency of daily wind gust events ≥90?km?h?1 was compared with both daily temperature and pressure anomalies. The results indicate that during the past five decades gust wind speed over Canada increased significantly as the daily temperature anomaly increased and the daily pressure anomaly decreased. About 50–60% of daily wind gust events ≥90?km?h?1 occurred with positive daily temperature anomalies and negative daily pressure anomalies. One major conclusion is that the methods used in and results derived from this study might be applied to climate change impact analysis to support projections of future wind regimes.  相似文献   

7.
测风激光雷达和风廓线雷达作为L波段探空测风的有效补充,均可以提供高时空分辨率的大气风场信息,然而由于工作原理和适用条件存在明显差异,在探测性能上各有优缺点,单一设备的探测数据已不能满足精细化预报的要求。本研究使用2020年1—5月北京南郊观象台的L波段探空资料对同址观测的测风激光雷达和风廓线雷达进行了数据质量评估,结果表明测风激光雷达与探空的一致性较高,U、V分量的相关系数分别为0.97和0.98,均方根误差分别为1.1和0.95 m·s-1,然而在2 km以上数据获取率较低且偏差较大;风廓线雷达与探空相比,U、V分量的相关系数分别为0.94和0.93,均方根误差分别为2.94和2.91 m·s-1,风廓线雷达的探测距离虽然更远,但在0.5 km以下和6 km以上的测量偏差较大。考虑到两种测风雷达在不同探测高度上的性能优缺点,提出分段曲面拟合法对两者的水平风资料进行融合处理,并选取个例对融合效果进行验证,结果表明,融合后的风廓线与融合前相比,风向和风速的一致性均得到明显提升。  相似文献   

8.

A Raman lidar system was operated along with the Microtops sunphotometer measurements to carry out the study of the variation of the optical properties of aerosols over Palampur (32.11° N and 76.53° E), India from 17th April to 11th May 2019. The lidar system is furnished with Raman (N2) channel and depolarization channel allowing independent measurement of Lidar Ratio (LR) and linear depolarization ratio. The study reveals that the majority of the aerosols approximately were restricted within the planetary boundary layer (PBL) and very less loading was present in the free troposphere over the study location. The particle loading over the study period was found to be very less with aerosol backscatter coefficient (at 355 nm) ranging from ~0.13 Mm?1sr?1 to ~7.25 Mm?1sr?1 with mean value of 2.67?±?0.82 Mm?1sr?1 and it is well supplemented by the mean aerosol optical depth (AOD) of 0.37?±?0.13 obtained from Microtops Sunphotometer. The average lidar ratio values for 0-1 km altitude (L1) 72?±?13sr, for 1-2 km (L2) altitude 55?±?8sr, for 2-3 km (L3) 54?±?15sr were observed as suggesting dominance of the biomass burning aerosols and anthropogenic aerosols. The particle depolarization ratio (355 nm) values were found from approximately 4.8?±?2.7% to 11.5?±?1.9% with the mean value of 7?±?1.3% suggesting the presence of non-spherical particles. To trace the sources of the pollution, we derived the HYSPLIT trajectory which shows the majority of the movement was from local sources.

  相似文献   

9.
Abstract

Analysis of current, temperature and salinity records in the nearshore region of the Scotian Shelf during the Canadian Atlantic Storms Program (CASP), reveals that the inertial wave field is highly intermittent, with comparable amplitudes in the surface and deep layers. Clockwise current energy in the surface layer is concentrated at a frequency slightly below inertial, consistent with Doppler shifting by the strong mean current and/or straining by the mean flow shear, whereas the spectral peak in deep water is at the local inertial frequency. Clockwise coherence is high (γ2 ≥ 0.8) horizontally over the scale of the array (60 km × 120 km) and in the vertical, with upward phase propagation rates of 0.15–0.50 × 10?12 ms?1, inversely proportional to the local value of the Brunt Väisälä frequency. Clockwise current energy decreases in the onshore direction and appears to be completely inhibited on the 60‐m isobath.

A case study of the response to the CASP IOP 14 storm indicates that the inertial waves may be generated by a strong wind shift propagating onshore at a speed of 10 ms?1. On the eastern side of the array (Liscomb line), clockwise current oscillations propagate onshore in the surface layer at a rate (8.1 ± 0.9 m s?1) comparable with the speed of the atmospheric front, while waves in the pycnocline move offshore at a lower (internal wave) speed (1.8 m s?1). Furthermore the temperature and salinity fluctuations are in (out) of phase with longshore current in the deep (surface) layer. However, on the western side of the array (Halifax line), the inertial waves are more complex. A sharp steepening of phase lines at the coast indicates that the phase speed of clockwise current oscillations is considerably reduced and the evidence for offshore propagation of internal waves is less clear. The discrepancies between observations on the two lines suggest that the internal wave field is three‐dimensional.

Results of simple mixed‐layer models indicate that the inertial response near the surface is sensitive to the accurate definition of the local wind field, but not to certain model physics, such as the form of the decay term. The observations also show some qualitative similarities with models for two‐dimensional response to a moving front (e.g. Kundu, 1986), but the actual forcing terms are more complicated, based on IOP 14 wind measurements.  相似文献   

10.
Sixteen years (1994 – 2009) of ozone profiling by ozonesondes at Valentia Meteorological and Geophysical Observatory, Ireland (51.94° N, 10.23° W) along with a co-located MkIV Brewer spectrophotometer for the period 1993–2009 are analyzed. Simple and multiple linear regression methods are used to infer the recent trend, if any, in stratospheric column ozone over the station. The decadal trend from 1994 to 2010 is also calculated from the monthly mean data of Brewer and column ozone data derived from satellite observations. Both of these show a 1.5 % increase per decade during this period with an uncertainty of about ±0.25 %. Monthly mean data for March show a much stronger trend of?~?4.8 % increase per decade for both ozonesonde and Brewer data. The ozone profile is divided between three vertical slots of 0–15 km, 15–26 km, and 26 km to the top of the atmosphere and a 11-year running average is calculated. Ozone values for the month of March only are observed to increase at each level with a maximum change of +9.2?±?3.2 % per decade (between years 1994 and 2009) being observed in the vertical region from 15 to 26 km. In the tropospheric region from 0 to 15 km, the trend is positive but with a poor statistical significance. However, for the top level of above 26 km the trend is significantly positive at about 4 % per decade. The March integrated ozonesonde column ozone during this period is found to increase at a rate of ~6.6 % per decade compared with the Brewer and satellite positive trends of ~5 % per decade.  相似文献   

11.
We measured the methane flux of a forest canopy throughout a year using a relaxed eddy accumulation (REA) method. This sampling system was carefully validated against heat and CO2 fluxes measured by the eddy covariance method. Although the sampling system was robust, there were large uncertainties in the measured methane fluxes because of the limited precision of the methane gas analyzer. Based on the spectral characteristics of signals from the methane analyzer and the diurnal variations in the standard deviation of the vertical wind velocity, we found the daytime and nighttime precision of half-hourly methane flux measurements to be approximately 1.2 and 0.7?μg?CH4?m?2?s?1, respectively. Additional uncertainties caused by the dilution effect were estimated to affect the accuracy by as much as 0.21?μg?CH4?m?2?s?1 on a half-hourly basis. Diurnal and seasonal variations were observed in the measured fluxes. The biological emission from plant leaves was not observed in our studies, and thus could be negligible at the canopy-scale exchange. The annual methane sink was 835?±?175?mg?CH4?m?2?year?1 (8.35?kg?CH4?ha?1?year?1), which was comparable to the flux range of 379–2,478?mg?CH4?m?2?year?1 previously measured in other Japanese forest soils. This study indicated that the REA method could be a promising technique to measure canopy scale methane fluxes over forests, but further improvement of precision of the analyzer will be required.  相似文献   

12.
Solar ultraviolet fluxes were measured with a ¼> ‐metre Ebert spectrometer flown as part of an Atmospheric Environment Service balloon payload from Fort Churchill on 8 July 1974. The spectral region from 1820 to 3150Å was scanned each 7.5 s with 1.5Å resolution from 1256 to 0025 UT on 10 July. These measurements covered a range of solar zenith angles from 37° (noon) to 69° with the balloon initially at a float altitude of 28.6 km. Fluxes in the window region 1900 to 2200Å were analyzed to determine ozone content above the balloon. Values from 0.069 to 0.11 cm NTP were obtained at heights over a range from 28.6 to 25.3 km.  相似文献   

13.
Ozone mixing ratios observed by the Bordeaux microwave radiometer between 1995 and 2002 in an altitude range 25–75 km show diurnal variations in the mesosphere and seasonal variations in terms of annual and semi-annual oscillations (SAO) in the stratosphere and in the mesosphere. The observations with 10–15 km altitude resolution are presented and compared to photochemical and transport model results.Diurnal ozone variations are analyzed by averaging the years 1995–1997 for four representative months and six altitude levels. The photochemical models show a good agreement with the observations for altitudes higher than 50 km. Seasonal ozone variations mainly appear as an annual cycle in the middle and upper stratosphere and a semi-annual cycle in the mesosphere with amplitude and phase depending on altitude. Higher resolution (2 km) HALOE (halogen occultation experiment) ozone observations show a phase reversal of the SAO between 44 and 64 km. In HALOE data, a tendancy for an opposite water vapour cycle can be identified in the altitude range 40–60 km.Generally, the relative variations at all altitudes are well explained by the transport model (up to 54 km) and the photochemical models. Only a newly developed photochemical model (1-D) with improved time-dependent treatment of water vapour profiles and solar flux manages to reproduce fairly well the absolute values.  相似文献   

14.
A long-lived and loosely organized squall line moved rapidly across Urumqi, the capital city of Xinjiang Uygur Autonomous Region of China on 26 June 2005, generating hail and strong winds. The squall line was observed by a dual Doppler radar system in a field experiment conducted in 2004 and 2005 by the Chinese Academy of Meteorological Sciences and the local meteorological bureau in northwestern China. The 3D wind fields within the squall line were retrieved through dual Doppler analyses and a variational Doppler radar analysis system (VDRAS). The formation and structure of the squall line as well as the genesis and evolution of embedded convective cells were investigated. During its life period, the squall line consisted of six storm cells extending about 100 km in length, and produced hail of about 25 mm in diameter and strong surface winds up to 11 m s-1. Radar observations revealed a broad region of stratiform rain in a meso-β cyclone, with the squall line located to the west of this. Two meso-γ scale vortices were found within the squall line. Compared to typical squall lines in moist regions, such as Guangdong Province and Shanghai, which tend to be around 300--400 km in length, have echo tops of 17--19 km, and produce maximum surface winds of about 25 m s-1 and temperature variations of about 8oC this squall line system had weaker maximum reflectivity (55 dBZ), a lower echo top (13 km) and smaller extension (about 100 km), relatively little stratiform rainfall preceding the convective line, and a similar moving speed and temperature variation at the surface.  相似文献   

15.
提出一套高光谱分辨率激光雷达(HSRL)系统,用于同时测量大气风和气溶胶的光学性质.该HSRL系统中使用碘分子滤波器分离分子和气溶胶后向散射,同时利用双边缘检测技术测量大气风场引起的多普勒频移.文中选用合理的HSRL参数和大气模型数据,模拟和分析了HSRL的测量性能.系统夜晚运行时,可测量20 km以下的大气风速和气溶胶,风速误差小于2 m s-1,气溶胶的后向散射系数相对误差小于30%.在白天工作时,相同误差下的可探测高度为10 km.模拟分析结果表明,该HSRL雷达有较大的应用前景,对天气和气象研究等有重要意义.  相似文献   

16.
The Pacific Atmospheric Sulfur Experiment (PASE) was a field mission that took place aboard the NCAR C-130 airborne laboratory over the equatorial Pacific Ocean near Christmas Island (Kirimati, Republic of Kiribati) during August?CSeptember, 2007. Eddy covariance measurements of the ozone fluxes at various altitudes above the ocean surface, along with simultaneous mapping of the horizontal gradients provided a unique opportunity to observe all of the dynamical components of the ozone budget in this remote marine environment. The results of six daytime and two sunrise flights indicate that vertical transport into the marine boundary layer from above and horizontal advection by the tradewinds are both important source terms, while photochemical destruction consisting of 82% photolysis (leading to OH production), 11% reaction with HO2, and 7% reaction with OH provides the main sink. The overall photochemical lifetime of ozone in the marine boundary layer was found to be 6.5 days. Ocean uptake of ozone was observed to be fairly slow (mean deposition velocity of 0.024?±?0.014 cm s?1) accounting for a diurnally averaged loss rate that was ??30% as large as the net photochemical destruction. From the measurement of deposition velocity an ozone reactivity of ??50 s?1 in seawater is inferred. Due to the unprecedented measurement accuracy of the dynamical budget terms, unobserved photochemistry was able to be deduced, leading to the conclusion that 3.9?±?3.0 ppt (parts per trillion by volume) of NO is present on average in the daytime tropical marine boundary layer, broadly consistent with several previous studies in similar environments. It is estimated, however, that each ppt of BrO hypothetically present would counter each ppt of NO above the requisite 3.9 ppt needed for budget closure. The long-term budget of ozone is further analyzed in the buffer layer, between the boundary layer and free troposphere, and used to derive an entrainment velocity across the trade wind inversion of 0.51 ± 0.38 cm s?1.  相似文献   

17.
利用三维变分方法对2014年3月30—31日华南一次强飑线过程进行风场反演,经与风廓线雷达探测结果、双多普勒天气雷达反演结果、原始径向速度数据等对比分析,得到如下结论:三维变分方法反演的中低层水平风场与风廓线雷达探测到的结果较为一致,且能很好地表现飑线过境时的风向切变;通过与双多普勒雷达风场反演结果对比发现,两种方法得到的风场空间分布十分相似,均能很好地表现2 km高度上系统内部强带状回波前缘的辐合线以及5 km高度上较弱的辐散;三维变分方法反演的水平风场与径向速度场有较好的一致性,2 km高度强回波带前缘阵风锋处的辐合线位置以及5 km和8 km高度上辐散区的位置均与径向速度场十分吻合;三维变分方法反演的垂直速度能较好地反映该飑线过程中气流的上升和下沉运动,平行于飑线方向的气流变化较小,而系统气流变化主要沿垂直于飑线的方向。三维变分方法反演的飑线系统的三维风场结构合理,反演结果可靠。  相似文献   

18.
Stray light in single-monochromator Brewer instruments increases the uncertainty of solar ultraviolet spectral irradiance measurements and ozone retrievals. To study how spectral irradiance within and outside the measurement ranges of the instruments affects stray light, two Brewer MKII instruments were characterized for the level of in- and out-of-range stray light at multiple laser wavelengths. In addition, several solar-blind filters utilized in single-monochromator Brewers to limit out-of-range stray light were characterized for spectral and spatial transmittances. Finally, the measurement results were used to simulate the effect of stray light and stray light correction on spectral irradiance and ozone measurements at different wavelength regions. The effect of stray light from wavelengths above 340?nm was found to be negligible compared with other sources of uncertainty. On the other hand, contributions from wavelengths between 325 and 340?nm can form a significant portion of the overall stray light of the instrument, with 325?nm being the upper limit of the nominal measurement range of the instrument.  相似文献   

19.
利用义乌CFL 03边界层风廓线雷达资料,对浙中地区15次强对流天气过程进行了分析。结果表明:①水平风不仅能提前于天气图数小时获知冷空气入侵,预判强对流的发生,而且通过对低空西南急流尤其是超低空西南急流或偏南急流的研究发现,其对短时暴雨或降雹能提供非常有利的信息,同时任何风向的超低空急流都可以作为判断雷雨大风的依据;②垂直速度和大气折射率结构常数(CN2)的大小能较好地反映降水开始和结束,而降水发生时,功率谱密度表现为正径向速度,谱宽变宽,且各信号形状较为相似;③当径向速度图出现速度模糊现象,尤其是在低层时,地面对应有大风。风廓线雷达资料对强对流天气的发生发展有较可靠的指示意义。结合多普勒雷达资料,可有效加强本地短临预报能力。  相似文献   

20.
The vertical structure and microphysics of Typhoon Kompasu that caused a lot of damage associated with strong winds and heavy rainfall over the Seoul metropolitan area on 1~2 September 2010 were examined primarily from wind profiler measurements. Four different periods that represent a stratiform, outer rainband, inner rainband, and eyewall region during passage of Typhoon Kompasu from 1200 to 2300 UTC 1 September were selected based on bright band intensities and vertical profiles of radar reflectivities and Doppler velocities. The bright band signatures observed in all of these periods indicated that the structure of Kompasu was basically stratiform in a weakening phase. Maximum rainfall rates up to 50 mm hr?1 at the surface and mean wind speeds greater than 30 m s?1 in the 2–4 km layer were observed in the eyewall region. Unlike the other regions that showed nearly zero vertical air motions or weak downdrafts below a melting layer, a mean updraft of ~1 m s?1 was analyzed only in the eyewall region, which suggests that the updrafts may have enhanced drop growth that led to increasing surface rainfall rates. For each region, the vertical mean characteristics of rainfall parameters retrieved from wind profiler spectra below the melting layer were also examined. The rain properties between the inner and outer rainband were similar although they were apart with a distance of more than 100 km (> 2 hrs in time). The averaged mass-weighted mean diameters within the rainbands were larger than those in the stratiform and eyewall regions. A weaker bright band in the eyewall region suggests the presence of a relatively larger number of rimed particles associated with the updrafts around the melting layer. A stronger bright band was present in the rainbands, which indicates more active aggregation right above the melting layer.  相似文献   

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