On some aspects of the albedo effect application to the ERS-1 satellite

Some aspects of the perturbative influence of radiation reflected by the Earth's surface on the motion of an artificial satellite are discussed. We concentrate on consequences of the extreme models with anisotropic reflection on the Earth's surface (specular reflection, clouds with anisotropic phase function). The possible effects of Lála's modification of the Earth's albedo nominal value are investigated. The role of the satellite surface optical properties is pointed out in the context of the albedo effect. All mentioned models are purely numerical. The whole message of the paper can be summarized in the following items

-It is very doubtful that the 10^?8 ÷ 10^?9 m s^?2 level is reached when determining the perturbing accelerations caused by the albedo effect in the case of the ERS-1 satellite due to poorly defined optical characteristics of the Earth's atmosphere, the Earth and the satellite's surface.

-In the general case this albedo effect uncertainty level is about 50% with respect to the averaged values, and probably as high as 100% with respect to the instantaneous values of the perturbing accelerations.

     

Theoretische Betrachtungen zum Verhalten des Magnetfeldes in einem sphärischen Erdmodell

The theoreticl treatment of several geophysical problems presupposes the solution of field equations of the magnetic field in the Earth's mantle. The field equations are given in a scalar form for a spherical model of the Earth. It will be shown that analytical solutions are possible in all cases. The boundary conditions are discussed with regard to the dynamo process in the Earth's core and the existence of a field representation, which is investigated on the Earth's surface. The question is discussed, to what extend the mantle's field is given by this field representation, when some special assumptions about the Earth's model are made.     

Mercury's exosphere origins and relations to its magnetosphere and surface

Mariner 10, the only spacecraft that ever passed close to Mercury, revealed several unexpected characteristics: an intrinsic magnetosphere, the highest mean density of any Solar System terrestrial planet and a very thin non-collisional atmosphere. Mercury's atmosphere is very poorly explored since only three atomic elements, H, He and O, were observed during the three flybys of Mariner 10. The measurements done by radio and solar occultations provided upper limits on the neutral and ion densities. These measurements pointed out the close connection between species in Mercury's exosphere and its surface, which is also the case for the Moon. Mariner 10 observations also characterized the vertical distributions and the day to night contrasts of Mercury's exosphere for its lightest components H and He (Broadfoot, A.L., et al., 1976. Mariner 10: Mercury atmosphere. Geophys. Res. Lett. 3, 577–580).More than a decade later, the first observation from a ground-based observatory of Mercury's sodium (Na) exospheric component was reported (Potter, A.E., Morgan, T.H., 1985. Discovery of sodium in the atmosphere of Mercury. Science 229, 651–653). Since then, potassium and more recently calcium have been identified in Mercury's exosphere. The bright Na resonant scattering emission has been often observed since 1985. This large set of observations is now the best source of information on Mercury's exospheric mechanisms of ejection, dynamics, sources and sinks. In particular, several of these observations provided evidence of prompt and delayed effects, both localized and global, for the very inhomogeneous Mercury's Na exosphere. These inhomogenities have been interpreted as the trace of Mercury's magnetosphere–solar wind interaction and have highlighted some of the main sources of exospheric material. Some of these features have been also interpreted as the trace of a global dayside to night side circulation of Mercury's exosphere and therefore have highlighted also the relation between exospheric production and upper surface composition.Hopefully, new sets of in situ measurements will be obtained within the next decade thanks to Messenger and Bepi-Colombo missions. Until then, ground-based observations and modelling will remain the only approaches to resolve questions on Mercury's exosphere. Mercury's exospheric composition and structure as they are presently known are described in this paper. The principal models for the main short and long times terms variations and local and global variations of Mercury's exosphere are described. The mechanisms of production and their characteristics are also given. Mercury's exosphere can also be seen as part of the coupled magnetosphere–upper surface–exosphere system and several of the links between these elements are essential to the interpretation of most of the ground-based observations. The relation between Mercury's planet composition and its exospheric composition is also considered, as is the global recycling, sources and sinks of Mercury's exosphere.     

Radiocarbon on Titan

Abstract— We explore the likely production and fate of ¹⁴C in the thick nitrogen atmosphere of Saturn's moon Titan and investigate the constraints that measurements of ¹⁴C might place on Titan's photochemical, atmospheric transport and surface‐atmosphere interaction processes. Titan's atmosphere is thick enough that cosmic‐ray flux limits the production of ¹⁴C: absence of a strong magnetic field and the increased distance from the Sun suggest production rates of ?9 atom/cm²/s, ?4x higher than Earth. The fate and detectability of ¹⁴C depends on the chemical species into which it is incorporated: as methane it would be hopelessly diluted even in only the atmosphere. However, in the more likely case that the ¹⁴C attaches to the haze that rains out onto the surface (as tholin, HCN or acetylene and their polymers), haze in the atmosphere or recently deposited on the surface would be quite radioactive. Such radioactivity may lead to a significant enhancement in the electrical conductivity of the atmosphere which will be measured by the Huygens probe. Measurements with simple detectors on future missions could place useful constraints on the mass deposition rates of photochemical material on the surface and identify locations where surface deposits of such material are “freshest”.     

Spectral geometric albedos of the Galilean satellites from 0.24 to 0.34 micrometers: Observations with the international ultraviolet explorer

We present the results of an 8-year program of spectrophometry of the Galilean satellites of Jupiter that was undertaken using the International Ultraviolet Explorer (IUE) Spacecraft. The ultraviolet geometric albedos of all four satellites are low. This is consistent with the hypothesis that sulfurous materials escaping from the surface of Io are being distributed by magnetospheric processes to the surfaces of the other three objects. Although iron bearing silicates may also cause UV darkening, these materials also have spectral features in the visible region of the spectrum which are not found in the spectra of the Galilean satellites. For Io, we find that the ultraviolet geometric albedo is very low (P_uv ∼ 0.04). The trailing hemisphere has an albedo that is higher than that of the leading hemisphere. This is opposite of what is observed at visual wavelengths. The decrease of albedo shortward of 0.33 μm is consistent with groundbased observations (Nelson and Hapke, 1978) and the laboratory reflection spectrum of sulfur dioxide frost. The hemispheric albedo asymmetry is consistent with a variable distribution of the frost, it being present in greater abundance on Io's leading hemisphere. The strenght of this feature has not changed with respect to longitude over the8 years of this study. The phase coefficients and opposition surges at ultraviolet wavelenghts indicate that Io's surface regolith is very porous. Europa has the highest ultraviolet albedo of all the Galilean satellites (P_uv ∼ 0.2). This not inconsistent with the hypothesis of recent resurfacing. However, this albedo is not high enough to be consistent with a surface of pure water ice. We confirm a previously reported ultraviolet spectral asymmetry between Europa's leading and trailing hemispheres. The new data are consistent with the previous analyses which interpreted this as the spectral signature of sulfur ions from the Jovian magnetosphere which had been embedded preferentially on the trailing side of Europa's predominately water ice.surface. The opposition surge observed for Europa's trailing side is greater than that for the leading side. This implies that the trailing side is less compact than the leading side, perhaps due to gardening from the ion implantation process. Ganymede's ultraviolet albedo (P_uv ∼ 0.10) is lower than Europa's. Ganymede has an ultraviolet spectral asymmetry that is similar to Europa's for wavelenghts longer than 0.28 μm. However, at wavelengths shorter than 0.28 μm, the two objects have different opposite hemispherical spectral ratios, indicating that the same mechanism cannot be used to explain the ultraviolet spectral albedo of both objects. One possible explanation is that ozone is present in addition to sulfur embedded on Ganymede's surface. The ultraviolet albedo and opposite hemispherical spectral ratio of Calisto is spectrally flat, indicating that the surface is covered by a material that is spectrally absorbing in the ultraviolet but has no change in absorption at the ultraviolet wavelenghts. The orbital phase variation in the ultraviolet indicates that the absorber is assymmetrically distributed in longitude.     

Radar observations of asteroid 25143 Itokawa (1998 SF36)

Abstract— We observed 25143 Itokawa, the target of Japan's Hayabusa (MUSES‐C) sample‐return mission, during its 2001 close approach at Arecibo on twelve dates during March 18‐April 9 and at Goldstone on nine dates during March 20‐April 2. We obtained delay‐Doppler images with range resolutions of 100 ns (15 m) at Arecibo and 125 ns (19 m) at Goldstone. Itokawa's average circular polarization ratio at 13 cm, 0.26 ± 0.04, is comparable to that of Eros, so its cm‐to‐m surface roughness probably is comparable to that on Eros. Itokawa's radar reflectivity and polarization properties indicate a near‐surface bulk density within 20% of 2.5 g cm^?3. We present a preliminary estimate of Itokawa's shape, reconstructed from images with rather limited rotation‐phase coverage, using the method of Hudson (1993) and assuming the lightcurve‐derived spin period (12.132 hr) and pole direction (ecliptic long., lat. = 355°, ?84°) of Kaasalainen et al. (2003). The model can be described as a slightly asymmetrical, slightly flattened ellipsoid with extents along its principal axes of 548 times 312 times 276 m ± 10%. Itokawa's topography is very subdued compared to that of other asteroids for which spacecraft images or radar reconstructions are available. Similarly, gravitational slopes on our Itokawa model average only 9° and everywhere are less than 27°. The radar‐refined orbit allows accurate identification of Itokawa's close planetary approaches through 2170. If radar ranging planned for Itokawa's 2004 apparition succeeds, then tracking of Hayabusa during its 2005 rendezvous should reveal Yarkovsky perturbation of the asteroid's orbit.     

Capillary action in a crack on the surface of asteroids with an application to 433 Eros

Some asteroids contain water ice, and a space mission landing on an asteroid may take liquid to the surface of the asteroid. Gas pressure is very weak on the surface of asteroids. Here we consider the capillary action in a crack on the surface of irregular asteroids. The crack is modeled as a capillary which has a fixed radius. An asteroid's irregular gravitational potential influences the height of the liquid in the capillary. The height of the liquid in the capillary on the surface of such asteroids is derived from the asteroid's irregular gravitational potential. Capillary mechanisms are expected to produce an inhomogeneaous distribution of emergent liquid on the surface. This result is applied to asteroid 433 Eros, which has an irregular, elongated, and concave shape. Two cases are considered: (1) we calculate the height of the liquid in the capillary when the direction of the capillary is perpendicular to the local surface of the asteroid; (2) we calculate the height of the liquid in the capillary when the direction of the capillary is parallel to the vector from the center of mass to the surface position. The projected height in the capillary on the local surface of the asteroid seems to depend on the assumed direction of the capillary.     

Dissociative recombination of nitrile ions with implications for Titan's upper atmosphere

Nitrile ions are abundant in Titan's upper atmosphere and are expected to be lost mainly via dissociative recombination with free electrons. We review in this paper a series of experimental results on the dissociative recombination reactions of nitrile ions known/expected to be present in Titan's upper atmosphere. The experiments were all performed at the heavy ion storage ring CRYRING in Stockholm, Sweden, and the results presented here include information on rate coefficients at electron temperatures relevant for Titan's upper atmosphere as well as information on the product branching fractions of the reactions. We discuss implications of the results for Titan's atmosphere. As an example the presented results support a statement by Krasnopolsky (2009) that nitriles do not degrade to yield N₂ again in Titan's atmosphere, indicating that condensation and polymerization with precipitation to the surface are their ultimate fate.     

Insights into Ceres's evolution from surface composition

Inspired by the recent results of the Dawn mission, thermodynamic models of rock alteration and brine evaporation have been used to help understand the conditions under which water–rock interaction took place within the dwarf planet Ceres. This analysis constrains Ceres's early history and offers a framework within which future observations may be interpreted. A broad range of alteration conditions have been simulated using the Geochemist's Workbench and PHREEQC software, associated with the FREZCHEM model that constrains the consequences of freezing the liquid phase in equilibrium with the observed mineralogical assemblage. Comparison of the modeling results with observed surface mineralogy at Ceres indicates advanced alteration under a relatively high fugacity of hydrogen, a conclusion that is consistent with predictions for, and observations of, large ice‐rich bodies. The simulations suggest production of methane that could help regulate the redox environment and possibly form clathrate hydrates upon freezing of the early ocean. The detection of localized occurrences of natrite (sodium carbonate) at the surface of Ceres provides key constraints on the composition of fluids that are necessarily alkaline. In addition, the combined hydrothermal and freezing simulations suggest that hydrohalite may be abundant in Ceres's subsurface, similar to Earth's polar regions. The global homogeneity of Ceres's surface, made of material formed at depth, suggests a large‐scale formation mechanism, while local heterogeneities associated with impact craters and landslides suggest that some form of sodium carbonate and other salts are accessible in the shallow subsurface.     

Grain size of the surface regolith of asteroid 4 Vesta estimated from its reflectance spectrum in comparison with HED meteorites

Abstract— The grain-size distribution of the regolith of asteroid 4 Vesta has been estimated by comparing its reflectance spectra (0.3–2.6 μm) with those of HED meteorites. The finest grain-size separate (<25 μm) of a particular howardite has a reflectance spectrum most similar to Vesta's. In order to better simulate Vesta's surface mineralogy, reflectance spectra of those finest HED meteorite powders were linearly combined, and Vesta's spectrum was scaled for the best fit between them. Both the albedo and the shape of reflectance spectrum of Vesta were well reproduced by regional mixtures of the finest (<25 μm) powders of HED meteorites. The result suggests the heterogeneity of Vesta's surface and provides an estimate of the visible reflectance of Vesta that is close to its IRAS albedo. Thus, this suggests that fine grains can be generated and retained by relatively small bodies (Vesta is approximately 500 km in diameter).     

Mercurian impact ejecta: Meteorites and mantle

Abstract— We have examined the fate of impact ejecta liberated from the surface of Mercury due to impacts by comets or asteroids, in order to study 1) meteorite transfer to Earth, and 2) reaccumulation of an expelled mantle in giant‐impact scenarios seeking to explain Mercury's large core. In the context of meteorite transfer during the last 30 Myr, we note that Mercury's impact ejecta leave the planet's surface much faster (on average) than other planets in the solar system because it is the only planet where impact speeds routinely range from 5 to 20 times the planet's escape speed; this causes impact ejecta to leave its surface moving many times faster than needed to escape its gravitational pull. Thus, a large fraction of Mercurian ejecta may reach heliocentric orbit with speeds sufficiently high for Earth‐crossing orbits to exist immediately after impact, resulting in larger fractions of the ejecta reaching Earth as meteorites. We calculate the delivery rate to Earth on a time scale of 30 Myr (typical of stony meteorites from the asteroid belt) and show that several percent of the high‐speed ejecta reach Earth (a factor of 2–3 less than typical launches from Mars); this is one to two orders of magnitude more efficient than previous estimates. Similar quantities of material reach Venus. These calculations also yield measurements of the re‐accretion time scale of material ejected from Mercury in a putative giant impact (assuming gravity is dominant). For Mercurian ejecta escaping the gravitational reach of the planet with excess speeds equal to Mercury's escape speed, about one third of ejecta reaccretes in as little as 2 Myr. Thus collisional stripping of a silicate proto‐Mercurian mantle can only work effectively if the liberated mantle material remains in small enough particles that radiation forces can drag them into the Sun on time scale of a few million years, or Mercury would simply re‐accrete the material.     

Eddingtons Zahlen,Einsteins Kriterium und Rydbergs rationelles Dimensionssystem

The discussions about the meaning of the “hierarchy of interactions” and in connection with this about the role of Eddington's “cosmological number” imply the question of the “big numbers” in physics. According to Einstein's and Bridgman's criteria such “big numbers” are hints at unsolved problems in the foundations of physics. Eddington gives a theory of the big number like cosmological quantities. – A new point of view on this question may be to remember Rydberg's suggestion on independigly physical dimensions of lengths L, surfaces S, and volumina V, and to remember Dällenbach's suggestion to introduce a new universal constant α which describes the operational connections between the quardrate of lengths L² and the surface S in microphysics. Coulomb's and Nwton's laws have the same structure. But, the electrical forces are depending on L^-2 and the gravitational forces are depending on S^-1 ∼ (1/α) L^-2 because “gravitation is geometry”. In Planck's elementary units h, c and f Dällenbach's “surface-constant of the vacuum” α is a pure number α ≈ hc/fm², th. i. Eddington's cosmological number ω ∼ 10⁴⁰. However, Rydberg's physical dimensions in geometry and Dällenbach's constant suggest new formulations of the question of “geometrization of physics” and “physicallization of geometry” and the connections between cosmology and microphysics.     

Mercury: Mid‐infrared (3–13.5 μm) observations show heterogeneous composition,presence of intermediate and basic soil types,and pyroxene

Abstract— The Aerospace Corporation's broadband array spectrograph system (BASS) mounted on the NASA infrared telescope facility (IRTF) on Mauna Kea, Hawaii was used to obtain spectral measurements of Mercury's thermal emission on 1998 March 21 (45–85° longitude), and on 1998 May 12 (68–108° longitude). The spectra show heterogeneous composition on Mercury's surface between longitudes 45–85° and about 68–108°. These observations include measurements from 3 to 6 μm, a spectral region not previously covered by mid‐infrared spectroscopy. Excellent quality data were obtained in the atmospheric windows between 3–4.2 and 4.6–5.5 μm. These wavelength regions exhibit high emissivity characteristic of a regolith with strong thermal gradients maintained in a vacuum environment with spectra dominated by grain sizes of ?30 μm. Emission peaks are present at 3.5 and 5 μm in the 45–85° longitude data. The 5 μm peak has been tentatively attributed to clinopyroxene. Data were also obtained in the 7.5–13.5 μm spectral region. Spectra obtained during both observing periods show well‐defined emissivity maxima (EM) in the spectral vicinity (between 7.7 and 9.2 μm) of the Christiansen frequency of silicate soils. The location of the EM for longitudes 45–85° (7.9 μm) is consistent with a surface composition of intermediate SiO₂ content. The overall spectral shape is similar to that obtained previously at the same location with different instrumentation. In the region 68–108° longitude, three EM are observed at 7.8, 8.2, and 9.2 μm, indicating the presence of distinctly different surface composition from the other location. Comparisons of these data to other mid‐infrared spectra of Mercury's surface and asteroids, and of the different instrumentation used in observations are included.     

Organic material from Phoebe to Iapetus

It is suggested that only the outermost layers of Phoebe's crust are carbonized by cosmic protons. Meteorite impact on Phoebe leads to the ejection of materials which coming from deeper layers are different in color than the carbonized ones on the surface. The average material coming at Iapetus from Phoebe has then different spectral properties than that on the surface of Phoebe.     

Titan's damp ground: Constraints on Titan surface thermal properties from the temperature evolution of the Huygens GCMS inlet

Abstract— A simple thermal model is developed to determine the temperature history of the inlet tube of the Huygens probe gas chromatograph mass spectrometer (GCMS) after its fortuitous emplacement on the surface of Saturn's moon Titan. The model parameters are adjusted to match the recorded temperature history of a nearby heater, taking into account heat losses by conduction to the rest of the probe and to Titan's cold atmosphere. The model suggests that after impact when forced convective cooling ceased, the inlet temperature rose from ?110 K to an asymptotic value of only ?145 K. This requires that the inlet was embedded in a surface that acted as an effective heat sink, most plausibly interpreted as wet or damp with liquid methane. The data appear inconsistent with a tar or dry, fine‐grained surface, and the inlet was not warm enough to devolatilize methane hydrate.     

Radar observations of asteroid 1998 ML14

Abstract— Goldstone and Arecibo delay‐Doppler radar imaging of asteroid 1998 ML 14 shortly after its discovery reveals a 1 km diameter spheroid with prominent topography on one side and subdued topography on the other. The object's radar and optical properties are typical for S‐class near‐Earth asteroids. The gravitational slopes of a shape model derived from the images and assumed to have a uniform density are shallow, exceeding 30° over only 4% of the surface. If 1998 ML14's density distribution is uniform, then its orbital environment is similar to a planetary body with a spheroidal gravitational field and is relatively stable. Integration of a radar‐refined orbit reveals that the 1998 apparition was the asteroid's closest approach to Earth since at least 1100 and until 2283, when it approaches to within 2.4 lunar distances. Outside of that time interval, orbit uncertainties based on the present set of observations preclude reliable prediction.     

The rate of small impacts on Earth

Abstract— Asteroids tens to hundreds of meters in diameter constitute the most immediate impact hazard to human populations, yet the rate at which they arrive at Earth's surface is poorly known. Astronomic observations are still incomplete in this size range; impactors are subjected to disruption in Earth's atmosphere, and unlike the Moon, small craters on Earth are rapidly eroded. In this paper, we first model the atmospheric behavior of iron and stony bodies over the mass range 1–10¹² kg (size range 6 cm‐1 km) taking into account deceleration, ablation, and fragmentation. Previous models in meteoritics deal with rather small masses (<10⁵–10⁶ kg) with the aim of interpreting registered fireballs in atmosphere, or with substantially larger objects without taking into account asteroid disruption to model cratering processes. A few earlier attempts to model terrestrial crater strewn fields did not take into account possible cascade fragmentation. We have performed large numbers of simulations in a wide mass range, using both the earlier “pancake” models and also the separated fragments model to develop a statistical picture of atmosphere‐bolide interaction for both iron and stony impactors with initial diameters up to ?1 km. Second, using a compilation of data for the flux at the upper atmosphere, we have derived a cumulative size‐frequency distribution (SFD) for upper atmosphere impactors. This curve is a close fit to virtually all of the upper atmosphere data over 16 orders of magnitude. Third, we have applied our model results to scale the upper atmosphere curve to a flux at the Earth's surface, elucidating the impact rate of objects <1 km diameter on Earth. We find that iron meteorites >5 times 10⁴ kg (2.5 m) arrive at the Earth's surface approximately once every 50 years. Iron bodies a few meters in diameter (10⁵–10⁶ kg), which form craters ?100 m in diameter, will strike the Earth's land area every 500 years. Larger bodies will form craters 0.5 km in diameter every 20,000 years, and craters 1 km in diameter will be formed on the Earth's land area every 50,000 years. Tunguska events (low‐level atmospheric disruption of stony bolides >10⁸ kg) may occur every 500 years. Bodies capable of producing hazardous tsunami (?200 m diameter projectiles) should strike the Earth's surface every ?100,000 years. This data also allows us to assess the completeness of the terrestrial crater record for a given area over a given time interval.     

A photometric and polarimetric study of the moon's surface

The results of the photometric and polarimetric observation of the Moon's surface with high resolution from October 1969 to March 1971 are discussed. It is found that, for a wide part of the Moon's illuminated surface, the brightnessm, expressed by visual magnitude per square second of arc, can be expressed as $$m = 5.0 - 2.5\log H + 2.5\log \{ {{P_v } \mathord{\left/ {\vphantom {{P_v } P}} \right. \kern-\nulldelimiterspace} P}(\alpha )\} ,$$ whereH is the variable part of Hapke's formula,P _v is the observed polarization degree, andP(α) is a function of the phase angleα. The color shows a tendency to reddening at the enhancement of the lunar brightness, and this is expressed by the relation $$B - V = - 0.2\Delta m + 1.7,$$ where Δm =m + 2.5 logH which is a sort of residual from the brightness calculated by Hapke's formula. Remarkable enhancements of the lunar brightness correspond to solar flares which appeared just before the observations. Because of this the above formula for the observed brightness can be interpreted by assuming the luminescence on the lunar surface stimulated by the solar activity.     

Equilibrium condensation from chondritic porous IDP enriched vapor: Implications for Mercury and enstatite chondrite origins

The origin of Mercury's anomalous core and low FeO surface mineralogy are outstanding questions in planetary science. Mercury's composition may result from cosmochemical controls on the precursor solids that accreted to form Mercury. High temperatures and enrichment in solid condensates are likely conditions near the midplane of the inner solar protoplanetary disk. Silicate liquids similar to the liquids quenched in ferromagnesian chondrules are thermodynamically stable in oxygen-rich systems that are highly enriched in dust of CI-chondrite composition. In contrast, the solids surviving into the orbit of Mercury's accretion zone were probably similar to highly unequilibrated, anhydrous, interstellar organic- and presolar grain-bearing chondritic, porous interplanetary dust particles (C-IDPs). Chemical systems enriched in an assumed C-IDP composition dust produce condensates (solid+liquid assemblages in equilibrium with vapor) with super-chondritic atomic Fe/Si ratios at high temperatures, approaching 50% of that estimated for bulk Mercury. Sulfur behaves as a refractory element, but at lower temperatures, in these chemical systems. Stable minerals are FeO-poor, and include CaS and MgS, species found in enstatite chondrites. Disk gradients in volatile compositions of planetary and asteroidal precursors can explain Mercury's anomalous composition, as well as enstatite chondrite and aubrite parent body compositions. This model predicts high sulfur content, and very low FeO content of Mercury's surface rocks.     

The chronology of Mercury's geological and geophysical evolution: The vulcanoid hypothesis

Previous discussions of Mercury's evolution have assumed that its cratering chronology is tied to that of the Moon, i.e., with Caloris forming about 3.9 Gyr ago as part of a late heavy bombardment that affected all of the terrestrial planets. That assumption requires that Mercury's core formed very early, because associated expansion features are not visible, and must have been erased before the cratering flux declined. Moreover, the modest amount of global shrinkage inferred from visible compressional features on Mercury's surface implies that the core is either largely molten at present, or had largely solidified before the end of the bombardment. The former interpretation requires a significant volatile content or implausibly large internal heat sources, while the latter raises questions about how to generate the planet's magnetic field. We have investigated whether constraints on Mercury's chronology could be relaxed by effects of a Mercury-specific bombarding population of planetesimals interior to its orbit, encountering the planet only occasionally due to secular perturbations. Such “vulcanoids” could have been a significant source of early cratering. However, those in orbits that can cross Mercury's are depleted by mutual collisions in ⪅1 Gyr, and can provide at most a modest extension of the period of heavy bombardment. Further inside Mercury's orbit, lower collisional velocities might allow survival of vulcanoids to the present. We report on a search for such bodies and on observational limits to such a population. We also review evidence that Mercury's intercrater plains are of volcanic origin and mainly predate Caloris, and that scarp formation (and global contraction) mainly postdates Caloris and has continued to recent times. If global lineaments are the product of tidal despinning, they constrain core formation to the first half of the planet's lifetime. While some questions and inconsistencies remain, the preponderance of evidence suggests that Mercury differentiated early, and at least half of its core volume is presently molten, probably due to a significant content of some light element such as sulfur.