水体同位素组成及氘过量参数在地热勘探中的示踪作用--以四川绵竹三箭水温泉开发为例

本文研究了四川绵竹三箭水及其邻区水体的同位素组成特征,以氚过量参数(d=δD-8δ^18O)在地热勘探中的示踪作用，再通过对研究区地下水氚过量参数和水笨氰含量(T)的相关性分析，综合运用于查明区内温泉地下水的成因，包括地下热储层内地下水的来源、补给源区、运移途径等等；确定水体均来源于大气降水，山前盆地深部地下水的补给源区在西、西北部高山区,径流方向由西北向东南，径流途径和在地下滞留时间都很长，并由此圈定了几个地热勘查的重点靶区。     

Environmental Isotopic Characterization of Groundwater and Surface Water in Northeast Missan Province,South Iraq

The present work studies the environmental isotopes assess groundwater characteristics of the different parts of the main aquifer in the northeast Missan Province in south of Iraq.Water samples of groundwater and surface water were collected for two dry and wet seasons during the water year of 2011–2012.The study shows that most of the groundwater in the aquifer falls above the global meteoric water line,and all the samples fall below the Mediterranean meteoric water line,indicating that these samples are a mixture of two water types.The tritium content of these samples supports this conclusion.The overall conclusion of this study indicates that there are two sources of groundwater recharge in the studied area:the ephemeral streams(Teeb and Dewerge) and major precipitation sources.According to the tritium levels at or below one tritium unit(TU) obtained from the water,supply wells are highly confined or "not vulnerable".Overall,the 3H results imply that recent recharge has taken place during the last four to five decades.In the recharge area,the high tritium content in the southern part of the Teeb area suggests that the recharge originates from rapid infiltration of surface runoff.Therefore,the groundwater resources in the study area should be protected from contamination,because it will influence the aquifer in a relatively short period of time if any contamination enters the recharge areas of the aquifer.     

基于氚同位素的安阳河中下游流域地下水更新能力研究

利用水中氚值与地下水年龄分布特征和多年平均更新速率,分析安阳河中下游流域地下水更新能力。应用MGMTP重建研究区1953—2016年大气降水氚值,应用集中参数模型(LPMs)计算地下水年龄,采用Le Gal La Shalle等提出的方法估算潜水与泉水多年平均更新速率。研究结果表明:(1)潜水与泉水由近20多年来大气降水补给。潜水样点受局部水文地质条件控制,补给径流条件差异明显。(2)小南海泉平均滞留时间23 a,多年平均更新速率3.6%,水量呈不断衰减趋势。(3)安阳河冲洪积扇扇后缘为补给区,受地表水渗漏与大气降水入渗补给,更新能力较强。扇中部至京港澳高速路地带为现代地下水,年龄40~60 a。扇前缘为现代与次现代地下水的混合水,年龄大于60 a,更新能力较弱。(4)剥蚀岗丘与冲洪积平原深层承压水为较老地下水,更新能力极弱。因此,对小南海泉域的保护需要加强,并在短时期内能取得明显成效。受南水北调中线水源补给及限量地下水开采影响,安阳市区地下水降落漏斗大幅度缩减。     

Hydrogeochemical and Isotopic Study of Groundwater in a Semi-arid Region: Yeniceoba Plain (Cihanbeyli-KONYA), Central Anatolia,Turkey

Groundwater is the most important source of water supply in the Yeniceoba Plain in Central Anatolia,Turkey.An understanding of the geochemical evolution of groundwater is important for the sustainable development of water resources in this region.A hydrogeochemical investigation was conducted in the Plio-Quaternary aquifer system using stable isotopes(δ~(18)O andδD),tritium(~3H),major and minor elements(Ca,Na,K,Mg,Cl,SO_4,NO_3,HCO_3 and Br)in order to identify groundwater chemistry patterns and the processes affecting groundwater mineralization in this system.The chemical data reveal that the chemical composition of groundwater in this aquifer system is mainly controlled by rock/water interactions including dissolution of evaporitic minerals,weathering of silicates,precipitation/dissolution of carbonates,ion exchange,and evaporation.Based on the values of Cl/Br ratio(300 mg/l)in the Plio-Quaternary groundwater,dissolution of evaporitic minerals in aquifer contributes significantly to the high mineralization.The stable isotope analyses indicate that the groundwater in the system was influenced by evaporation of rainfall during infiltration.Low tritium values(generally1 tritium units)of groundwater reflect a minor contribution of recent recharge and groundwater residence times of more than three or four decades.     

全球大气降水中年平均氚浓度的恢复模型

氚作为一种天然的环境同位素可广泛应用于水文地质领域,由于实测资料的稀缺,极大地限制了氚的应用。为了能够解决这一问题,选用国际原子能机构最近发布的1960~2005年南纬50°至北纬70°区域内氚值实测资料,应用因子分析方法建立了全球大气降水中年平均氚浓度的恢复模型。选取了三个任意典型站点对采用“直接求参法”所建模型进行了验证和一个任选站点对采用“间接求参法”所建模型进行了验证,然后以南京站为例对模型进行了具体应用。因子分析应用于全球氚值恢复具有物理意义明确、适用范围广泛、操作方法简单、影响因素少,很好地恢复出氚值变化曲线的峰值和形态等特点。分析结果表明全球模型输出结果与实测值吻合,不但具有全球适用性,而且在一定程度上解决了原全球模型精度欠佳的问题,为资料稀缺和无资料地区1960~2005年大气降水中年平均氚浓度恢复提供了一种新方法。同时对模型应用中出现的问题也提出了解决方案。     

Characterization of the groundwater flow system in the hillside and coastal aquifers of the Mersin-Tarsus region (Turkey)

In the region between Mersin and Tarsus cities, located along the Mediterranean Sea coast in southern Turkey, the demand for groundwater has increased dramatically as the available surface water supplies have already been developed. Fundamental information is required to characterize the existing groundwater system in this area in order to establish a sustainable groundwater-use policy. For this purpose, hydrochemical and environmental isotopic data were collected and integrated with available geological and hydrogeological information to develop a conceptual model of the system. Results, backed up mainly by depleted stable isotope composition and infinitesimal tritium content, suggest that most of the groundwater along the coastal zone is supplied by the neighboring mountain belt while local precipitation has also contributes to aquifer recharge. The validation of the conceptual perspective by a steady-state numerical groundwater flow model reveals that about 90% of the recharge to the aquifer system is supplied by the deep flow of karstic groundwater fed from the Taurus Mountains. Monitoring of changes in the recharge regime of the mountain sector seems to be critical in establishing future groundwater use policies.     

中国西北干旱区多级洼地地下水环境同位素分布特征及指示意义

研究区位于西北干旱区,有两级储水洼地,地下水由山区侧向补给一级洼地,一级洼地通过泉水排泄地下水继而补给二级洼地,同时大气降水直接入渗、洪流间接入渗补给各储水洼地。通过氢氧同位素比例公式计算得到一级洼地大气降水占总补给量60%,其中直接补给量约占21%,山区洪流补给量约占79%,另外,山前侧向补给占40%;二级洼地降水补给量占38%,上游泉水补给量占62%。通过氚值指示,二级洼地不受现代降水影响;活塞流与全混合模型计算得到一级洼地浅层孔隙水平均年龄为32～60 a。     

Tritium across the hydrologic systems of southern Ontario,Canada: implications for groundwater age dating in the Great Lakes Basin

Modern, ambient tritium concentrations in precipitation are lower and more temporally consistent now that they have recovered from the historic thermonuclear bomb peak of the mid-1960s. With the bomb peak no longer the overriding influence on atmospheric tritium concentrations, anthropogenic point sources, such as nuclear-generating stations (NGS), have the largest influence, though the extent and temporal variability of this influence remains uncharacterized. The lack of precipitation monitoring locations means that spatial trends in tritium concentrations in precipitation are unknown. To address this data gap, tritium concentrations in shallow modern groundwater are interpolated throughout southern Ontario (Canada), at the center of the Great Lakes Basin, and the interpolation is tested as a precipitation proxy with a statistical comparison that shows good agreement between the shallow groundwater and precipitation datasets. The shallow groundwater tritium interpolation is used to delineate the extent of NGS influence as representing 66% of the study area. Recharge timings in the subcropping bedrock aquifers of the study area are interpreted qualitatively in areas outside of NGS influence to be primarily a mix of pre-bomb and modern recharge, with no indication of peak recharge levels remaining. The influence of drift thickness on the proportion of tritium-dead versus tritium-live samples is observed spatially and confirmed by comparing data distributions. The oldest waters (pre-1953) tend to occur in subcropping bedrock aquifers underlying the thickest sediment packages.

     

环境同位素方法在平凉市岩溶地下水研究中的应用

应用环境同位素方法对平凉隐伏岩溶水的研究结果表明 ,研究区隐伏岩溶水形成较早 ,且有大量现代水的混入 ,平均混入量为 5 4 %。说明研究区隐伏岩溶水的补给和更新能力较好。环境同位素分析结果还显示 ,大岔河隐伏岩溶水为一相对独立、半开放的水文地质单元。其补给来源部分为流域内大气降水、地表水的补给 ,部分为东南部三道沟岩溶地下水的补给。根据环境同位素 EPM与 EM两种模型计算 ,地下水的滞留时间为 36 a。地下水储存量为 1.314× 10 8m3;储水系数为 7.2 9× 10 - 3。这一结果与传统勘探方法的计算结果基本吻合 ,说明环境同位素方法的实用性 ,可在地下水资源调查中作为传统方法的补充和对比。     

漳州盆地水热系统氚同位素研究

本文依据26个天然水样品的氚同位素测试数据,分析了漳州盆地地下热水及其它天然水的氚值特征及其形成条件;利用“活塞模型”方法计算了漳州盆地地下水和地下热水的年龄;为弄清全盆地地下水的补给、迳流和排泄的总体格局和揭示地下热水的成因提供了依据。     

人工神经网络方法在大气降水氚浓度恢复中的应用

根据人工神经网络能识别输入输出数据间复杂的非线性关系等特性,选用北半球（纬度22~74°）70个站点的IAEA/WMO大气降水氚浓度观测数据,建立了大气降水氚年平均浓度的恢复模型.通过对比认为：人工神经网络恢复的降水氚浓度能客观地反映其真实值,为无资料地区恢复1953年以来大气降水氚浓度提供了一种更好的思路.     

城市扩张下的北京平原区降雨入渗补给量变化

结合WetSpass模型与地理信息系统(geographic information system,GIS)、遥感(remote sense,RS)技术分析了城市扩张引起的土地利用类型变化对北京平原区降水入渗补给量的影响.在估算出1982年和2007年降水入渗补给量的基础上,将2007年土地利用类型还原成1982年的情景重新估算,利用转移矩阵分析两年土地利用类型的相互转化关系,同时,基于GIS空间数据统计功能,计算出不同土地利用类型下的地下水补给量.结果表明,1982年至2007年,研究区内水浇地减少874 km2,其中517 km2转变为城镇建设用地.相对于1982年,2007年城镇建设用地扩张了831 km2,区内降水入渗补给量减少约3 000万m3.研究成果可以为北京平原区的地下水资源保护及土地资源配置提供较为科学的参考.      

Soil-water dynamics and tree water uptake in the Sacramento Mountains of New Mexico (USA): a stable isotope study

In the southwestern United States, precipitation in the high mountains is a primary source of groundwater recharge. Precipitation patterns, soil properties and vegetation largely control the rate and timing of groundwater recharge. The interactions between climate, soil and mountain vegetation thus have important implications for the groundwater supply. This study took place in the Sacramento Mountains, which is the recharge area for multiple regional aquifers in southern New Mexico. The stable isotopes of oxygen and hydrogen were used to determine whether infiltration of precipitation is homogeneously distributed in the soil or whether it is partitioned among soil-water ‘compartments’, from which trees extract water for transpiration as a function of the season. The results indicate that “immobile” or “slow” soil water, which is derived primarily from snowmelt, infiltrates soils in a relatively uniform fashion, filling small pores in the shallow soils. “Mobile” or “fast” soil water, which is mostly associated with summer thunderstorms, infiltrates very quickly through macropores and along preferential flow paths, evading evaporative loss. It was found that throughout the entire year, trees principally use immobile water derived from snowmelt mixed to differing degrees with seasonally available mobile-water sources. The replenishment of these different water pools in soils appears to depend on initial soil-water content, the manner in which the water was introduced to the soil (snowmelt versus intense thunderstorms), and the seasonal variability of the precipitation and evapotranspiration. These results have important implications for the effect of climate change on recharge mechanisms in the Sacramento Mountains.     

高放废物地质处置库北山预选区地下水的形成和分布

本文论述北山地区不同类型地下水的形成和赋存规律。松散岩类孔隙水主要分布于沟谷和洼地，主要为潜水。沟谷潜水的形成以基岩裂隙水的侧向补给及洪流渗漏补给为主，洼地潜水可由沟谷潜水、断裂带或基岩裂隙水、古洪积扇潜水侧向补给，也可由地表洪流渗入补给；碎屑岩类孔隙-裂隙水主要分布在由自垩系或第三系砂砾石构成的山间沉积盆地中，以承压水为主，洪水下渗和盆地周围基岩裂隙水的侧向径流是此类地下水的主要补给来源；基岩裂隙水主要赋存于变质岩、岩浆岩、碎屑岩、碳酸盐岩节理、裂隙中，以潜水为主。降水垂直渗入、侧向补给或洪流渗漏补给为其主要来源。     

应用 D、18O同位素峰值位移法求解大气降水入渗补给量

采用D、¹⁸O同位素峰值位移法求出研究区大气降水入渗补给量。通过野外地中渗透计法和降水入渗系数法对同位素法计算结果检验,发现D、¹⁸O同位素法计算结果具有较高精度,同时验证了在研究区用D、¹⁸O同位素方法求大气降水入渗补给量是可行和可靠的。用该方法求解大气降水入渗补给量具有方便快捷、经济省时的优点,在湿润、半湿润地区大气降水补给研究方面,具有很大的应用潜力和重要的应用价值。     

Assessing hydrochemical evolution of groundwater in limestone terrain via principal component analysis

This paper describes the use of multivariate statistical analysis to trace hydrochemical evolution in a limestone terrain at Zagros region, Iran. The study area includes a deep confined aquifer, overlaid by an unconfined aquifer. The method involves the use of principal component analysis (PCA) to assess and evaluate the hydrochemical evolution based on chemical and isotope variables of 12 piezometers drilled in both the unconfined and confined aquifers. First PCA on all variables shows that water–rock interaction under different conditions with respect to the atmospheric CO₂ is the main process responsible for chemical constituents. As a result, combinations of several ratios such as Ca/TDS, SO₄/TDS and Mg/TDS with physico-chemical and isotope variables reveal different hydrochemical evolution trend in the aquifers. Second PCA on the selective samples and variables reveals that displacement of the unconfined samples from dry to wet season follows a refreshing trend towards river samples that is characterized by reducing electrical conductivity and increasing sulphate and tritium contents. However, the refreshing trend cannot be traced in the confined aquifer samples suggesting no recharge from river to the confined aquifer. Third PCA reveals that, chemical composition of water samples in the unconfined aquifer tends to have considerable difference from each other in the end of recharge period. In contrast, the confined aquifer samples have a tendency to show similar chemical composition during recharge period in comparison to end of dry period. This difference is caused by different mechanism of recharge in the unconfined aquifer (through the whole aquifer surface) and the confined aquifer (through the limited recharge area).     

气候变化条件下咸阳市城区降水入渗补给时空分布特征研究

降水入渗补给受诸如气象、下垫面等多种因素影响和控制,由于这些制约因素的复杂性以及刻画它们的不确定性,因此降水入渗补给呈现出复杂的变化。基于1985-2015年的降水和地下水位监测资料,分析咸阳城区降水的变化趋势,用动态资料分析法计算研究区的入渗补给系数值,做出研究区上世纪90年代和本世纪近15年的降水入渗补给系数分布图,并求得相应的降水入渗量。结果表明,30多年来尽管咸阳城区降水量呈增加的趋势,但是降水入渗补给系数呈减小的趋势,其综合作用的结果是降水入渗量呈减少的趋势。三个年代的降水入渗量分别为3 034.2万m^3,2 821.2万m^3,2 723.6万m^3。     

河北省邯郸、邢台东部四县地下水越流问题的同位素分析

深层地下水的属性、深浅层地下水的水力联系(越流)是水文地质工作者一直研究和争论的问题。在对邯郸、邢台东部四县深、浅层地下水的氢、氧同位素样品的采集与测试中,发现该区地下水中氚同位素含量较高(15～30 TU,最高达51.1 TU)。本文利用区域大气降水中氚同位素衰减规律与特征,结合研究区地下水的水位和水质动态特征、含水层及隔水层的岩性特征,对特定水文地质条件下浅层地下水向深层地下水越流的可能性进行了分析研究,认为:本区存在浅层地下水越流至深层地下水的可能,在深层地下水中出现的高氚含量是其重要的证据。     

The effects of a dry sand layer on groundwater recharge in extremely arid areas: field study in the western Hexi Corridor of northwestern China

Evaporation capacity is an important factor that cannot be ignored when judging whether extreme precipitation events will produce groundwater recharge. The evaporation layer’s role in groundwater recharge was evaluated using a lysimeter simulation experiment in the desert area of Dunhuang, in the western part of the Hexi Corridor in northwestern China’s Gansu Province. The annual precipitation in the study area is extremely low, averaging 38.87 mm during the 60-year study period, and daily pan evaporation amounts to 2,486 mm. Three simulated precipitation regimes (normal, 10 mm; ordinary annual maximum, 21 mm; and extreme, 31 mm) were used in the lysimeter simulation to allow monitoring of water movement and weighing to detect evaporative losses. The differences in soil-water content to a depth of 50 cm in the soil profile significantly affected rainfall infiltration during the initial stages of rainfall events. It was found that the presence of a dry 50-cm-deep sand layer was the key factor for “potential recharge” after the three rainfall events. Daily precipitation events less than 20 mm did not produce groundwater recharge because of the barrier effect created by the dry sand. Infiltration totaled 0.68 mm and penetrated to a depth below 50 cm with 31 mm of rainfall, representing potential recharge equivalent to 1.7 % of the rainfall. This suggests that only extreme precipitation events offer the possibility of recharge of groundwater in this extremely arid area.     

Measurement of recharge rates in soils through detection of tritium produced in Chinese thermonuclear tests

Variations in environmental tritium and moisture content with depth was measured at three sites in sandy-loam and sandy-clay-loam soils, sampled near Hyderabad in May 1974. The tritium input function for precipitation around Hyderabad for the years 1969 to 1973 was determined through measurements on available rain samples and through extrapolation of strontium-90 data for HASL network station at Rawalpindi. Three peaks noticed in the tritium input function and probably caused by Chinese thermonuclear tests in 1970, 1971 and 1972, could be matched with those sequentially identified in the soil profiles. This identification has helped in dating the soil moisture and in calculation of average annual recharge to groundwater. The recharge was found to be 15·4 cm and 14·6 cm for sandy-loam and 11·1 cm for sandy-clay-loam soils.