Freeze Shoe Sampler for the Collection of Hyporheic Zone Sediments and Porewater

The Starr and Ingleton (1992) drive point piston sampler (DPPS) design was modified by fitting it with a Murphy and Herkelrath (1996) type sample‐freezing drive shoe (SFDS), which uses liquid carbon dioxide as a cryogen. Liquid carbon dioxide was used to freeze sediments in the lower 0.1 m of the core and the drive‐point piston sealed the core at the top preserving the reductive‐oxidation (redox) sensitive sediments from the atmosphere and maintaining natural stratigraphy. The use of nitrogen gas to provide positive pressure on the gas system blocked the ingress of water which froze on contact with the cryogen thus blocking the gas lines with ice. With this adaptation to the gas system cores could be collected at greater depths beneath the static water level. This tool was used to collect intact saturated sediment cores from the hyporheic zone of the tidally influenced Fraser River in Vancouver, British Columbia, Canada where steep geochemical and microbial gradients develop within the interface between discharging anaerobic groundwater and recharging aerobic river water. In total, 25 cores driven through a 1.5 m sampling interval were collected from the river bed with a mean core recovery of 75%. The ability to deploy this method from a fishing vessel makes the tool more cost effective than traditional marine‐based drilling operations which often use barges, tug boats, and drilling rigs.     

Core Sampler for Soft Bottom Sediments with Lower Closing Mechanism

A novel sediment core sampler is represented. It is suitable for liquid sediments and for undisturbed sediment cores with a large core diameter from shallow and deep waters.     

A Wireline Piston Core Barrel for Sampling Cohesionless Sand and Gravel Below the Water Table

A coring device has been developed to obtain long and minimally disturbed samples of saturated cohesionless sand and gravel. The coring device, which includes a wireline and piston, was developed specifically for use during hollow-stem auger drilling but it also offers possibilities for cable tool and rotary drilling. The core barrel consists of an inner liner made of inexpensive aluminum or plastic tubing, a piston for core recovery, and an exterior steel housing that protects the liner when the core barrel is driven into the aquifer. The core barrel, which is approximately 1.6m (5.6 feet) long, is advanced ahead of the lead auger by hammering at the surface on drill rods that are attached to the core barrel. After the sampler has been driven 1.5m (5 feet), the drill rods are detached and a wireline is used to hoist the core barrel, with the sample contained in the aluminum or plastic liner, to the surface. A vacuum developed by the piston during the coring operation provides good recovery of both the sediment and aquifer fluids contained in the sediment. In the field the sample tubes can be easily split along their length for on-site inspection or they can be capped with the pore water fluids inside and transported to the laboratory. The cores are 5cm (2 inches) in diameter by 1.5m (5 feet) long. Core acquisition to depths of 35m (115 feet), with a recovery greater than 90 percent, has become routine in University of Waterloo aquifer studies. A large diameter (12.7cm [5 inch]) version has also been used successfully. Nearly continuous sample sequences from sand and gravel aquifers have been obtained for studies of sedimentology, hydraulic conductivity, hydrogeochemistry and microbiology.     

A Discrete Point Sampler for Ground Water Monitoring Wells

A discrete point sampler has been developed that overcomes disadvantages inherent in several current small-volume samplers. It is designed to obtain ground water samples after a well has been purged with a pump. It consists of a sample chamber, two ports, and a stopcock for withdrawing sample aliquots. After lowering the sampler into a well, sampling is initiated by pulling on a line that sequentially removes the plugs in the lower and the upper level ports. The sample chamber fills from the bottom port and vents air from the top port. The device is suitable for sampling for volatile organic compounds in ground waters that are not subject to spontaneous bubble degassing. The upper port is sufficiently far above the lower port that none of the water that is sampled is exposed to the vented air. The sample chamber fills in such a way that the water that is taken from the chamber for analysis is not exposed to the headspace in the chamber.     

A Diffusive Sampler for Passive Monitoring of Underground Storage Tanks

Passive measurements of volatile organic compounds (VOCs) provide a method for early detection and long-term monitoring of potential leaks from underground storage tanks (USTs) and associated fuel service lines. A diffusive sampler was constructed of a sorbent tube that fits inside a specially designed sampling chamber. VOCs in the soil enter the chamber by molecular diffusion and are collected by the sorbent. The sorbent is easily retrieved for laboratory analyses by thermally desorbing into a gas chromatograph/mass spectrometer (GC/MS), or qualitative concentrations can be determined directly in the field with specific-indicator detectors.
The diffusive samplers were evaluated in an exposure chamber under controlled conditions. Laboratory measurements of the sorbed mass of organic vapor were found to be in close agreement with theoretical values and indicate the passive sampling approach is viable for detecting relatively low concentrations of organic vapors in the vadose zone over a one-day sampling period, as well as providing relatively long-term monitoring periods up to 58 days. A field test found the sampling approach successful in identifying an area where the vadose zone was contaminated by leaking petroleum USTs.     

A Portable Membrane Contactor Sampler for Analysis of Noble Gases in Groundwater

To enable a wider use of dissolved noble gas concentrations and isotope ratios in groundwater studies, we have developed an efficient and portable sampling device using a commercially available membrane contactor. The device separates dissolved gases from a stream of water and collects them in a small copper tube (6 mm in diameter and 100 mm in length with two pinch‐off clamps) for noble gas analysis by mass spectrometry. We have examined the performance of the sampler using a tank of homogeneous water prepared in the laboratory and by field testing. We find that our sampling device can extract heavier noble gases (Ar, Kr, and Xe) more efficiently than the lighter ones (He and Ne). An extraction time of about 60 min at a flow rate of 3 L/min is sufficient for all noble gases extracted in the sampler to attain equilibrium with the dissolved phase. The extracted gas sample did not indicate fractionation of helium (³He/⁴He) isotopes or other noble gas isotopes. Field performance of the sampling device was tested using a groundwater well in Vienna and results were in excellent agreement with those obtained from the conventional copper tube sampling method.     

LNAPL Distribution in a Cohesionless Soil: A Field Investigation and Cryogenic Sampler

Lighter-than-water Non-Aqueous Phase Liquids (LNAPLs), such as jet fuels or gasolines, are common contaminants of soils and ground water. However, the total volume and distribution of an LNAPL is difficult to accurately determine during a site investigation. LNAPL that is entrapped in the saturated zone due to fluctuating water table conditions is particularly difficult to quantify. Yet, the amount of entrapped product in the saturated zone is theoretically higher, per volume of soil, than the residual product in the unsaturated zone, and small amounts of LNAPL in the saturated zone can contaminate large volumes of ground water.
The only method currently available to quantify the amount of LNAPL is direct soil-core sampling combined with laboratory analysis of the fluid extracted from the soil cores. However, direct sampling of saturated ground water systems with conventional samplers presents a number of problems. In this study, a new sampler was developed that can be used to retrieve undisturbed soil and pore fluid samples from below the water table in cohesionless soils. The sampler uses carbon dioxide to cool the bottom of a saturated soil sample in situ to near freezing. Results of a field study where a prototype sampler was tested demonstrate the usefulness of a cryogenic sampler and show that the amount of LNAPL entrapped below the water table can be a significant part of the total LNAPL in the soil.     

A New Method for Collecting Core Samples Without a Drilling Rig

A new piston sampler allows the collection of high-quality core samples from sand, silt or clay, up to depths of 18 meters. The sampler is operated by a one- or two-person crew without a drilling rig. The sampler and ancillary equipment fit easily into a half-ton truck, making this a highly portable sampling system. Other advantages include minimal mechanical disturbance and precisely known sample depth. Casing is not required to maintain an open corehole below the water table and drilling fluid is not used in the corehole, so the solids and pore water of the sample should not be contaminated by foreign fluids. High-quality samples for physical, geochemical, and microbiological characterization of the subsurface are easily obtained with this new device.     

A Simple and Affordable System for Installing Shallow Drive Point Piezometers

This paper describes a drive point system for installing small‐diameter (15 to 25 mm ID) piezometers to depths of several metres in unconsolidated sediments. The system fills the gap between (1) heavy duty drive point systems powered by drilling rig hydraulics or air hammers that are capable of installing large diameter drive points to depths of many tens of metres and (2) manually driven systems that typically install 10 mm ID or smaller tubing to depths of <2 m. Unlike many existing systems, which install piezometers inside an outer casing that is later removed, our system protects the piezometer screen inside the casing and extends it only once the casing is driven to the desired depth. This avoids clogging of the screen during installation and the risk of creating an annulus around the piezometer, which can provide a preferential pathway for water movement. The piezometer has a larger diameter than most manually driven systems, and thus has a higher yield; it also permits use of most commercially available pressure transducers and electrical conductivity sensors. The piezometers have been successfully installed to depths of up to 6 m using an electric hammer. The system overcomes some issues associated with existing systems and provides the advantages of affordability, rapid installation, mechanical assistance and manual portability.     

Sampling for Purgeable Organic Compounds Using Positive-Displacement Piston and Centrifugal Submersible Pumps: A Comparative Study

Positive-displacement piston pumps that minimize sample agitation have no apparent advantage over centrifugal submersible pumps when used to collect ground water samples for analysis of low concentrations of purge-able organic compounds. Analytical uncertainties inherent in laboratory environments appear to influence analytical results of low-concentration purgeable organic compound samples more than either pump type or sampling team. Centrifugal submersible pumps are at least equally efficient as positive-displacement piston pumps in the recovery of carbon tetrachloride, 1,1,1-trichloroethane, trichloroethylene, and chloroform after sampling and analytical influences are made constant.     

巢湖沉积物柱样中正构烷烃初探

对巢湖湖心沉积物柱样样品的正构烷烃和有机碳进行了分析,利用正构烷烃碳数分布类型、L／H、OEP指标和有机碳数据,对该区近110年来正构烷烃的来源进行初步探讨。研究结果表明：21-25cm和16-20cm处正构烷烃以高等植物和低等生物输入并重;11．15cm即1952-1967年处具有外源性石油污染;从10cm开始,正构烷烃以细菌、藻类为代表的低等生物输人为主;尤其是1-5cm样品正构烷烃和TOC含量明显高值,表明该时期湖泊富营养化加剧。     

Estuarine Habitat Assessment for Construction of a Submarine Transmission Line

The present paper describes a submarine survey using the acoustic discrimination system QTC VIEW (Series V) as an exploratory tool to adjust final route alignment of a new pipeline. By using acoustic sound survey as an exploratory tool described in this paper to adjust final route alignment of a new pipeline to minimize the environmental impact caused and ultimately to avoid any mitigation measures. The transmission pipeline extended from the shore line of Abu-Qir Bay, on the Mediterranean Sea in Egypt, out to 70 nautical miles at sea (60 m water depth). Four main surface sediment types were defined in the study area, namely fine sand, silty sand, silt and clay. Results of the acoustic classification revealed four acoustic classes. The first acoustic class corresponded to fine sand, absence of shell debris and very poor habitats characteristics. The second acoustic class is predominant in the study area and corresponds to the region occupied by silt. It is also characterized by intermediate diversity of macrobenthic invertebrate community which is mainly characterized by polychaeta. The third acoustic class is characterized by silt to silty clay. It is characterized by a high diversity of macrobenthic invertebrate community which is mainly polychaeta with an intermediate diversity of gastropoda and bivalvia. The final acoustic class is characterized by clay and high occurrence of shell debris of gastropoda, bivalvia and polychaeta.     

A New Thermophoretic Precipitator for Off‐Line Particle Analysis

A new thermophoretic particle precipitator has been developed for representative and efficient collection of aerosol particles from the ambient air and technological pipelines. The device consists of hot and cold plates (5 × 5 cm²) capable of operation at temperature gradients ranging from 20 000 to 100 000 K/m. A gas sample is made to pass through a 1‐mm slot between the plates at a flow rate of up to 1.5 L/min, which makes the device suitable for operation in conjunction with common aerosol instruments including DMA and diffusion batteries with similar operational flow rates. It was shown that the efficiency of the device was highest for the lowest gas flow rate used (0.3 L/min) reaching a level of above 99%. The efficiency was decreased reaching its minimal values at the highest flow rate investigated (1.5 L/min). However, even for highest flow rate, the average efficiency for removal of particle smaller than 60 nm was around 50%.     

Simulations of a Line W-based observing system for the Atlantic meridional overturning circulation

In a series of observing system simulations, we test whether the Atlantic meridional overturning circulation (AMOC) can be observed based on the existing Line W deep western boundary array. We simulate a Line W array, which is extended to the surface and to the east to cover the basin to the Bermuda Rise. In the analyzed ocean circulation model ORCA025, such an extended Line W array captures the main characteristics of the western boundary current. Potential trans-basin observing systems for the AMOC are tested by combining the extended Line W array with a mid-ocean transport estimate obtained from thermal wind “measurements” and Ekman transport to the total AMOC (similarly to Hirschi et al., Geophys Res Lett 30(7):1413, 2003). First, we close Line W zonally supplementing the western boundary array with several “moorings” in the basin (Line W-32°N). Second, we supplement the western boundary array with a combination of observations at Bermuda and the eastern part of the RAPID array at 26°N (Line W-B-RAPID). Both, a small number of density profiles across the basin and also only sampling the eastern and western boundary, capture the variability of the AMOC at Line W-32°N and Line W-B-RAPID. In the analyzed model, the AMOC variability at both Line W-32°N and Line W-B-RAPID is dominated by the western boundary current variability. Away from the western boundary, the mid-ocean transport (east of Bermuda) shows no significant relation between the two Line W-based sections and 26°N. Hence, a Line W-based AMOC estimate could yield an estimate of the meridional transport that is independent of the 26°N RAPID estimate. The model-based observing system simulations presented here provide support for the use of Line W as a cornerstone for a trans-basin AMOC observing system.     

Construction and Testing of a Durable Platinum Wire Eh Electrode for In Situ Redox Measurements in the Subsurface

We have developed a rugged, durable platinum wire Eh electrode for application in subsurface environments. The electrode design is described in detail and its performance under aerobic and anaerobic steady-state and transient conditions is assessed. The electrode consists of a 0.5-mm-diameter platinum wire (99.99% purity) cast in a glass fiber-reinforced epoxy jacket. The construction allowed installation through direct insertion into sandy media to depths up to several meters. Data collection was through connection to a datalogger with high impedance input; data points were collected every 10 seconds and averaged and stored once an hour. The electrodes functioned in situ for periods of more than three years and gave reliable readings during oxic, anoxic, and transitional conditions. Performance testing and examination of electrodes recovered after three years in situ indicated that they were not impacted by corrosion, dissolution, or poisoning.     

A Theoretical Explanation for Rock Core Disking in Triaxial Unloading Test by Considering Local Tensile Stress

Rock is a typical inhomogeneous material with a large number of flaws in different scales; the stress field of the rock in its elastic state consists of two parts: the elastic stress, which distributes uniformly in the entire region; and an additional stress, which only exists around the flaws. Theoretical expressions of the additional stress and local stress are derived based on the Maxwell model. Core disking which takes place under the condition that the axial stress is rapidly reduced while the confining pressure is kept unchanged is explained with a new method. Unloading duration’s effect on core disking is analyzed. A new criterion for core disking is presented based on attributing the core disking to the result of the exceedance of local tensile stress over the tensile strength. Based on our theoretical analysis and the conclusions from published resources, core disking is most likely to occur if the maximum principal stress is more than five to six times the tensile strength.