Riverine organic carbon in the Xijiang River (South China): seasonal variation in content and flux budget

. Riverine water samples were collected from the lower reach hydrometric station Makou of the Xijiang River, in four hydrological seasons during 1997 and 1998. The samples were analyzed for their particulate and dissolved organic carbon. The contents of riverine particulate and dissolved organic carbon changed synchronously during different hydrological processes. The contents of organic carbon and total suspended substances in the riverine water increased with increasing discharge. The mass of organic carbon in the total suspended substances decreased logarithmically with increasing total suspended substances. The transported flux of organic carbon in the Xijiang River drainage is about 10.18᎒⁶ g of C km^–2 year^–1, which is two to three times larger than that of the average value in other river systems. Particulate organic carbon is the main component of riverine organic carbon, with a flux of about 8.30᎒⁶ g of C km^–2 year^–1.     

Hydro-mechanical evaluation of stabilized mine tailings

. In this study, mine tailings waste was stabilized using a combination of lime, fly ash type "C", and aluminum. Treated samples were subjected to mineral identification for evaluating the formation of ettringite and gypsum. Also, unconfined compression, hydraulic conductivity, and cyclic freeze and thaw tests were performed to evaluate the hydro-mechanical properties of the stabilized samples. Experimental results have shown that the application of lime and fly ash type "C" to high sulfate content tailings has improved its plasticity, workability, and volume stability. Moreover, upon addition of aluminum to lime and fly ash in a sulfate-rich environment, ettringite and calcium sulfo-aluminate hydrate are formed in these samples. Application of 5% lime, 10% fly ash type "C", in combination with 110 ppm aluminum, resulted in the formation of a solid monolith capable of producing more than 1,000 kPa of unconfined compressive strength, and reduced tailings permeability to 1.96᎒^–6 cm s^–1, which is less than the recommended permeability of 10^–5 cm s^–1 by most environmental protection agencies for reusability of solidified/stabilized samples. The permeability of the treated tailings samples remained below the recommended permeability, even after exposing the treated samples to 12 freeze and thaw cycles. Therefore, based on the experimental results, it is concluded that treatment of high sulfate-content tailings with lime and fly ash, combined with the availability of aluminum for reactions, is a successful method of solidifying highly reactive mine tailings.     

Occurrence of naphthalenesulfonates and their condensates with formaldehyde in a landfill leachate and their transport behavior in groundwater of the Upper Rhine Valley, Germany

. Naphthalenesulfonates and their condensation products with formaldehyde are manufactured in the chemical industry for broad application as tanning agents, dispersing agents, and as superplasticizers for concrete. With the disposal of waste they have found their way into the aquatic environment. Five monomeric naphthalenesulfonates and a group of dimeric sulfonated naphthalene-formaldehyde condensates (SNFC) were identified in the leachate and in groundwater observation wells downstream in the plume of the Karlsruhe-West landfill, situated in the Upper Rhine Valley in southwest Germany. For the main monomer of technical SNFC products, 2-naphthalenesulfonate (2-NS), the concentration in the leachate was 170 µg l^–1, which decreased to 9.5 µg l^–1 at a distance of about 300 m from the boundary of the landfill. In the Merdingen tracer test field, the transport of these compounds was studied under more controlled conditions in two tracer experiments with (1) two model compounds, and (2) a technical SNFC product and uranine as a reference tracer. In these experiments, the monomeric naphthalenesulfonates and the SNFC with n=2 behave as conservative tracers. Thus, the findings of the landfill study were supported by these results. Higher molecular SNFC were strongly retarded, which is attributed to adsorption to soil particles. The results of the second tracer experiment suggest a degradation of 2-NS and 2,6-naphthalenedisulfonate (2,6-NDS) after adaptation of the microorganisms in the groundwater aquifer as a consequence of the first tracer experiment.     

A comparison of the sludge conditioning capabilities of Canavalia ensiformis and Brachystegen eurycoma

. The finely ground seeds of Canavalia ensiformis (jack bean) and Brachystegen eurycoma (achi seed) were used in the treatment of sewage sludge. They were found to improve sludge filterability and compare favourably with the traditional, ferric chloride conditioner. The optimum dosage for each sample can be determined by drawing a tangent to the corresponding curve of each sample at the point where there is a sharp break between the straight and curvilinear portion. In this work, the optimum values for C. ensiformis and B. eurycoma are 19.50% (0.39 g/cm³) and 21.5% (0.4 g/cm³) respectively. For ferric chloride, the optimum value is 25% (0.5 g/cm³). These results show that ferric chloride is still a better conditioner than both the other conditioners. However, during sludge filtration, cake and filtrate concentration increased with increasing dosages of both C. ensiformis and B. eurycoma samples. This indicates that they would be useful as conditioners if the primary product of filtration is the procurement of low filtrate concentration or high-quality cake.     

Accumulation rates and mass calculations of Zn and Hg in recent sediments, Göta älv estuary, Sweden

Sediment masses and heavy-metal accumulation rates for the recent deposits of the Göta älv estuary were calculated using a GIS. Total masses of 4,000 t Zn and >20 t Hg were recorded, of which 367 t Zn and >0.72 t Hg occur in the inner estuary, the Göteborg harbour, and 3,657 t Zn and 19 t Hg are in the outer estuary, suggesting a high trapping efficiency of the estuary. The accumulation rates are 5 g m^-2 year^-1 Zn and 0.01 g m^-2 year^-1 Hg in the harbour, and 1.5 g m^-2/year^-1 Zn and 0.007 g m^-2 year^-1 Hg in the outer estuary. The Zn and Hg accumulation rates are highest close to the outlet of a sewage treatment plant, and decrease by a factor of 5 for Zn, and a factor of 2 for Hg in the outer estuary. The accumulation rates in the outer estuary decrease after 1980 A.D.     

Sr Isotope and Trace Element Studies of the Great Dyke and Bushveld Mafic Phase and their Relation to Early Proterozoic Magma Genesis in Southern Africa

New Rb-Sr and trace element data are reported for the GreatDyke and Bushveld Mafic Phase layered intrusions. It is arguedthat geochemical characteristics, such as ⁸⁷Sr/⁸⁶Sr ratios andR.E.E. distribution patterns have been little modified by crustalcontamination. Rb-Sr data for whole-rocks of the Great Dyke yield an age of2514±16 m.y. and an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70261±4.Mineral data are consistent with these results. The low errorson the results indicate no significant variation of ⁸⁷Sr/⁸⁶Srratios of successive magmatic influxes emplaced in differentmagma chambers. Earlier Great Dyke magmas were highly Mg-richand represent extensive partial melts of the source material.One such influx is shown to have a high Rb/Sr ratio (0.25) anda fractionated R.E.E. pattern (Ce_N/YB_N 12). These ratios areconsidered to approximate those of the source region. The Bushveld Mafic Phase has been dated accurately for the firsttime and has a Rb-Sr age of 2095±24 m.y. Initial ⁸⁷Sr/⁸⁶Srratios increase in a stepwise manner upwards in the intrusionfrom 0.70563±2 to 0.70769±6. Each increase isabrupt and occurs at a horizon also characterized by a suddenirregularity in cryptic variation. The Mafic Phase was emplacedas a succession of magmatic influxes each of which had higher⁸⁷Sr/⁸⁶Sr ratio than its predecessor. The first magma was both Mg-rich (MgO 21.5 per cent) and SiO₂-rich(50–55 per cent SiO₂) and was derived by extensive partialmelting of a shallow level upper mantle source. This sourcewas characterized by trace element abundance ratios (e.g. Rb/Sr 0.25; K/Rb 90; Ce_N/Yb_N 11), similar to those of kimberlitesand some potassic lavas and comparable with those deduced forthe Great Dyke source region. It is postulated that when the Rhodesian and Kaapvaal cratonsstabilized, underlying refractory mantle became fixed theretoto form a proto-lithosphere. Shortly afterwards, at about 2800m.y. ago, this proto-lithospheric mantle was enriched by passagethrough it of fluids with kimberlitic trace element chemistry.This sub-cratonic mantle thereafter evolved with a relativelyhigh Rb/Sr ratio. Magmas derived from it have anomalous chemicalcharacteristics with respect to those of ocean-floor basalts,reflecting major differences in the evolution of their respectivesource regions.     

Arsenic pollution in groundwater from Hetao Area,China

. Hetao Area, China is a district where arsenic concentrations in drinking water are elevated. The 180,000 people that inhabit the 6,100 km² of the seven counties in the area show symptoms of arsenic poisoning. In this paper, the distribution and origin of arsenic in groundwater were studied. The results demonstrate that the affected district boundaries encompass an area with high contents of As in well water, which the local inhabitants drink and use in daily life. This district is labeled as a population pathological change area. The isotope ratios of ⁸⁷Sr/⁸⁶Sr (0.7100–0.7164), ²⁰⁶Pb/²⁰⁴Pb (18.3817–19.1871), and ²⁰⁷Pb/²⁰⁴Pb (15.7581–15.9578) in groundwater of the population pathological change area are close to the ratios measured in water from mine areas (⁸⁷Sr/⁸⁶Sr=0.7196, ²⁰⁶Pb/²⁰⁴Pb=19.1940, ²⁰⁷Pb/²⁰⁴Pb=15.9574), and are somewhat close to ratios in Yellow River, water which is used to irrigating in Hetao Area (⁸⁷Sr/⁸⁶Sr=0.7168, ²⁰⁶Pb/²⁰⁴Pb=18.3495, ²⁰⁷Pb/²⁰⁴Pb=15.5969). The average content of As in the drinking water is as high as four times more than the environmental standard of As in drinking water. The study suggests that the origin of the As in groundwater of the population pathological change area in Hetao Area is transported from higher elevations where mineral deposits exist. Mining of some of the deposits has occurred for a long time. Mining practices can result in release of toxic elements, which can then be transported from the mining district down gradient.     

The Role of Volatiles in the Thermal History of Metamorphic Terranes

Analytical and numerical solutions to the differential equationsfor the conduction of heat with heat production or with fluidflow have been used to evaluate the role of volatiles in thethermal history of regional metamorphic terranes. The maximumthermal effect from pervasive, single-pass, regional volatileflow may be predicted from a steady-state solution given byBredehoeft & Papadopoulos (1965). For fluid velocity v_F(m/s) and connected porosity , combinations of volatile fluxv_F (m³ of fluid/m²s) and transport distance L(m) such that vLis greater than 3?6?10^–7 should produce regional temperatureincreases due to fluid flow, if the flow persists for l0⁵–10⁶a (depending on the transport distance L). The absolute valueof the temperature increase due to volatile flow will be greaterin regions with higher ambient geothermal gradients. For L=20km, a volatile flux of 1?8 ? 10^–11 (m³ of fluid/m²s) orgreater is required to achieve a temperature effect. Few geologicprocesses release volatiles at this rate for extended periodsof time, so regional thermal effects from the single-pass, pervasiveflow of volatiles are unlikely. A new analytical solution forthe steady state temperature distribution between idealizedparallel channels of fluid flow is presented along with theresults of two-dimensional numerical models of channelized fluidflow. Both approaches show that little temperature increaseis expected near channels of fluid flow relative to the rocksbetween the channels, unless the channels exceed 100 m in widthor unless the fluid fluxes are very large and transient. A possiblethermal effect of volatile flow in metamorphic terranes is theproduction of metamorphic hot spots due to focusing of volatilesinto widely spaced channels or conduits exceeding 1 km in width.Given a sufficient fluid flux (exceeding 10^–10 m³ of fluid/m²s),thermal gradients of over 100K from center to edge may be producedin such channels during relatively short time intervals (10⁵–10⁶a).     

The 1982-83 Eruption at Galunggung Volcano, Java (Indonesia): Oxygen Isotope Geochemistry of a Chemically Zoned Magma Chamber

Mount Galunggung is a historically active volcano in southwesternJava that has erupted four times in the last two centuries.During the most recent event, which occurred during a 9–monthinterval in 1982– 83, some 305 10⁶ m³ of medium–K,calc–alkaline magma was erupted. This eruption was unusualbecause of its duration, the diversity of eruption dynamicsand products, and the range of lava compositions produced. Thecomposition of juvenile material changed gradually during thecourse of the eruption from initial plagioclase (An_60–75)and two–pyrozene bearing andesites with 58% SiO₂ to finalplagioclase (An_85–90), diopside, and olivine (Fo_85–90)bearing primitive magnesium basalts with 47% SiO₂ Mineralogicaland compositional relationships indicate a magmatic evolutioninvolving differentitation of high–Mg parental melt. Theeruptive volumes of 35 10⁶ m³ andesite, 120 10⁶ m³ maficandesite, and 150 10⁶ m³ basalt are consistent with the ideathat the 1982– 83 eruption progressively tapped and draineda magma chamber that had become chemically stratified throughextensive crystal fractionation. Separates of plagioclase and pyroxene have ¹⁸O( SMO W) rangesof + 5. 6 to + 6.0 and + 5.3 to + 5.6, respectively, with ¹⁸O_plag–pxvalues of + 0.4 to + 0.6o, indicating internal O–isotopeequiliburium at temperature of 1100–850 C. The magenesianbasalts have magmatic ¹⁸O/ ¹⁶O ratios similar to those of mid–oceanridge basalt, and the O–isotope ratios of compositionallyevolved derivative melts show no evidence for contaminationof the galunggung magmas by ¹⁸O–rich crust during differentiation.Andesites and transitional mafic and sites have a more variableO–isotope character, with laves and phenocrysts havingboth higher and lower ¹⁸O values than observed in the parentalmagnesium basalts. These features are interpreted to reflectintramagma chamber processes affecting the upper portions ofthe differentiating Galunggung magma body before the 1982–83eruption.     

多年冻土区天然气水合物研究综述

由于多年冻土区天然气水合物的潜在资源价值和对气候、环境的影响,各国纷纷开展了大量的研究,取得了很好的研究进展。本文主要分析了天然气水合物与多年冻土间的关系、多年冻土区天然气水合物的蕴藏情况以及典型多年冻土区天然气水合物研究现状。其结果表明多年冻土控制了天然气水合物形成的温压条件,且在多年冻土层间发现具自保护效应的天然气水合物。同时多年冻土可影响分散性土体中游离气体的聚集和迁移,多年冻土融化可提高孔隙水压力。目前多年冻土区天然气水合物的蕴藏情况的估算并不完整,各国仅对典型多年冻土区天然气水合物储量进行了初步的估算。天然气水合物储量估算结果表明,在美国阿拉斯加地区大约为1.0~1.2×1012 m3,加拿大马更些三角洲Beaufort海地区大约为1.6×1013 m3,俄罗斯西西伯利亚盆地250 m深度范围内可达1.7×1013 m3。我国青藏高原多年冻土区亟待搞清天然气水合物存在与否的直接证据和储量估算等关键问题。     

An environmental risk assessment map of the Slovak Republic: application of data from geochemical atlases

A water budget analysis for the Cedar River watershed in northeastern Iowa was conducted to determine the water balance during the summer months of 2000. The watershed has eight major tributaries that comprise a drainage area of 20,242 km², of which 81% is agricultural land. Water budgets are essential when examining the movement of agricultural chemicals as well as nutrients within the system. The water budget was determined using the hydrologic mass-balance equation, which states that [inflow = outflow - storage]. The inflow components were measured individually and included precipitation, tributary and Cedar River baseflow. The outflow components included evaporation, transpiration, tributary and Cedar River discharge. The results of this study indicate a slightly larger volume of water leaving the watershed (6.24᎒⁹ m³) than entering (6.21᎒⁹ m³). The surplus of the outgoing water (0.5%) is most likely due to an overestimation of transpiration, or the contribution of water from the intermittent streams not measured during the study. Calculations of nutrient flux showed that approximately 2.99᎒⁶ kg of nitrogen and 2.39᎒⁵ kg of phosphorus were lost from the watershed during the study.     

Sorption and anaerobic biodegradation of soluble aromatic compounds during groundwater transport. 1. Laboratory column experiments

. This paper deals with sorption and anaerobic biodegradation of the soluble aromatic fraction of jet fuel and how it is influenced by pore-water velocity during transport in a groundwater aquifer. The study was carried out as controlled laboratory column experiments. A binary mixture of toluene and 1,2,4-trimethylbenzene with a concentration ratio of 2:1 was used through the entire investigations. The column experiments were conducted with contaminated sediments and groundwater, taken from wells at a field research site. The columns were operated anaerobically under continuous-flow conditions at 10 °C in a temperature-controlled refrigerator. Two percent sodium azide was added to the injection solution of two of the columns to prevent biodegradation of the studied organic mixture. Chloride was used as a conservative tracer to characterize the hydrodynamic parameters such as dispersivity and porosity of the columns. The results showed that both compounds in the mixture were attenuated because of sorption and biodegradation processes in the columns. 1,2,4-trimethylbenzene was attenuated more significantly than toluene. Biodegradation of toluene was coupled mainly with the microbial reduction of ferric iron, whereas 1,2,4-trimethylbenzene, in contrast, was mostly sorbed. Their sorption and biodegradation were studied with different pore-water velocities, and a mass balance approach was applied to calculate biodegradation rates. The biodegradation rates of toluene were –0.16, –0.21, and –0.26 (unit: mM day^–1) for pore-water velocities of 96, 82.4, and 54.9 (unit: cm day^–1), respectively. This indicates that a decrease in the pore-water velocity significantly enhanced the biodegradation of toluene, consistent with other reports in the literature. For 1,2,4-trimethylbenzene the biodegradation rates were –0.05, –0.13 (unit: mM day^–1) for pore-water velocities of 96 and 82.4 (unit: cm day^–1), respectively. The biodegradation rate of 1,2,4-trimethylbenzene did not increase at the lowest pore water velocity as expected. This might be a result of substrate competition.     

Rates of Thermal and Chemical Evolution of Magmas in a Cooling Magma Chamber: a Chronological and Theoretical Study on Basaltic and Andesitic Lavas from Rishiri Volcano, Japan

Rates of magmatic processes in a cooling magma chamber wereinvestigated for alkali basalt and trachytic andesite lavaserupted sequentially from Rishiri Volcano, northern Japan, bydating of these lavas using ²³⁸U–²³⁰Th radioactive disequilibriumand ¹⁴C dating methods, in combination with theoretical analyses.We obtained the eruption age of the basaltic lavas to be 29·3± 0·6 ka by ¹⁴C dating of charcoals. The eruptionage of the andesitic lavas was estimated to be 20·2 ±3·1 ka, utilizing a whole-rock isochron formed by U–Thfractionation as a result of degassing after lava emplacement.Because these two lavas represent a series of magmas producedby assimilation and fractional crystallization in the same magmachamber, the difference of the ages (i.e. 9 kyr) is a timescaleof magmatic evolution. The thermal and chemical evolution ofthe Rishiri magma chamber was modeled using mass and energybalance constraints, as well as quantitative information obtainedfrom petrological and geochemical observations on the lavas.Using the timescale of 9 kyr, the thickness of the magma chamberis estimated to have been about 1·7 km. The model calculationsshow that, in the early stage of the evolution, the magma cooledat a relatively high rate (>0·1°C/year), and thecooling rate decreased with time. Convective heat flux fromthe main magma body exceeded 2 W/m² when the magma was basaltic,and the intensity diminished exponentially with magmatic evolution.Volume flux of crustal materials to the magma chamber and rateof convective melt exchange (compositional convection) betweenthe main magma and mush melt also decreased with time, from 0·1 m/year to 10^–3 m/year, and from 1 m/yearto 10^–2 m/year, respectively, as the magmas evolved frombasaltic to andesitic compositions. Although the mechanism ofthe cooling (i.e. thermal convection and/or compositional convection)of the main magma could not be constrained uniquely by the model,it is suggested that compositional convection was not effectivein cooling the main magma, and the magma chamber is consideredto have been cooled by thermal convection, in addition to heatconduction. KEY WORDS: convection; magma chamber; heat and mass transport; timescale; U-series disequilibria     

Influence of acidic atmospheric deposition on soil solution composition in the Daniel Boone National Forest,Kentucky, USA

. Acid atmospheric deposition may enter an environmental ecosystem in a variety of forms and pathways, but the most common components include sulfuric and nitric acids formed when rain water interacts with sulfur (SOx) and nitrogen (NOx) emissions. For many soils and watersheds sensitive to acid deposition, the predominant chronic effect appears to be a low pH, loss of base cations, and a shift in the mineral phase controlling the activity of Al³⁺ and/or SO4^2– in solution. Soil solutions from lysimeters at various depths were taken at two sites in the Daniel Boone National Forest, Kentucky, USA, to evaluate potential impacts caused by acid deposition. The sites chosen were in close proximity to coal-burning power plants near Wolfe and McCreary counties and contained soils from the Rayne and Wernock series, respectively. Physicochemical characteristics of the soils revealed that both sites contained appreciable amounts of exchangeable acidity in the surface horizons, and that their base saturation levels were sufficiently low to be impacted adversely by acidic inputs. Soil solution data indicated that the sites were periodically subjected to relatively high NO3^– and SO4^2– inputs, which may have influenced spatial and temporal variation in Al and pH. As a consequence, the formation of Al-hydroxy-sulfate minerals such as jurbanite, alunite and basaluminite were thermodynamically favored over gibbsite. Given these conditions, long-term changes in soil solution chemistry from acid deposition are acknowledged.     

Comparison of methods for estimation of 50-year peak discharge from a small,rural watershed in North Carolina

Four applied hydrologic methods were used to estimate the 50-year peak storm discharge (Q₅₀) from a 15.8-ha agricultural (67%) and forested (33%) watershed in North Carolina, U.S.A. The methods (and Q₅₀ results) were the NCDOT (North Carolina Department of Transportation) method (0.42 m³/s), the USGS (U.S. Geological Survey) regression method (0.50 m³/s), the rational method (1.2 m³/s), and the NRCS (Natural Resources Conservation Service) TR-55 method (2.6 m³/s). The wide range of results (coefficient of variation=84%, factor of >6 between highest and lowest estimates) indicates significant inaccuracy in one or more of the methods, and presents a practical problem for use of the methods in the design of drainage systems. The NRCS method likely overestimates Q₅₀, and the NCDOT and USGS methods have other potential drawbacks for the study watershed. The least problematic approach in this case is probably the rational method. The best estimate of Q₅₀ from the study watershed is likely ~1 m³/s. The results suggest the importance of developing improved methods for estimation of peak storm discharge from small, rural watersheds.     

Oceanographic controls on shallow‐water temperate carbonate sedimentation: Spencer Gulf,South Australia

Spencer Gulf is a large (ca 22 000 km²), shallow (<60 m water depth) embayment with active heterozoan carbonate sedimentation. Gulf waters are metahaline (salinities 39 to 47‰) and warm‐temperate (ca 12 to ?28°C) with inverse estuarine circulation. The integrated approach of facies analysis paired with high‐resolution, monthly oceanographic data sets is used to pinpoint controls on sedimentation patterns with more confidence than heretofore possible for temperate systems. Biofragments – mainly bivalves, benthic foraminifera, bryozoans, coralline algae and echinoids – accumulate in five benthic environments: luxuriant seagrass meadows, patchy seagrass sand flats, rhodolith pavements, open gravel/sand plains and muddy seafloors. The biotic diversity of Spencer Gulf is remarkably high, considering the elevated seawater salinities. Echinoids and coralline algae (traditionally considered stenohaline organisms) are ubiquitous. Euphotic zone depth is interpreted as the primary control on environmental distribution, whereas seawater salinity, temperature, hydrodynamics and nutrient availability are viewed as secondary controls. Luxuriant seagrass meadows with carbonate muddy sands dominate brightly lit seafloors where waters have relatively low nutrient concentrations (ca 0 to 1 mg Chl‐a m^?3). Low‐diversity bivalve‐dominated deposits occur in meadows with highest seawater salinities and temperatures (43 to 47‰, up to 28°C). Patchy seagrass sand flats cover less‐illuminated seafloors. Open gravel/sand plains contain coarse bivalve–bryozoan sediments, interpreted as subphotic deposits, in waters with near normal marine salinities and moderate trophic resources (0·5 to 1·6 mg Chl‐a m^?3) to support diverse suspension feeders. Rhodolith pavements (coralline algal gravels) form where seagrass growth is arrested, either because of decreased water clarity due to elevated nutrients and associated phytoplankton growth (0·6 to 2 mg Chl‐a m^?3), or bottom waters that are too energetic for seagrasses (currents up to 2 m sec^?1). Muddy seafloors occur in low‐energy areas below the euphotic zone. The relationships between oceanographic influences and depositional patterns outlined in Spencer Gulf are valuable for environmental interpretations of other recent and ancient (particularly Neogene) high‐salinity and temperate carbonate systems worldwide.     

Lead sources in Mesozoic and Cenozoic Andean ore deposits,north-central Chile (30–34°S)

Mesozoic and Cenozoic ore deposits in the Chilean Andes between La Serena (~30°S) and Santiago (~34°S) include polymetallic vein, low- and high-sulfidation epithermal vein, skarn, porphyry copper-molybdenum and porphyry copper-gold. These deposits are associated with volcanic and plutonic complexes emplaced in eastward-migrating longitudinal arcs which formed during subduction along the continental margin of South America since the Middle Jurassic. Stratabound, but epigenetic, volcanic rock- and sedimentary rock-hosted manto deposits contain additional copper resources. Lead isotopic compositions in ore minerals from 29 deposits vary with age and geographic location, and hence with basement and host rocks. Lead in most ore deposits is derived from temporally related igneous rocks, except for the manto deposits whose lead is derived from host volcanic and sedimentary rock sequences. Lead in the ore deposits is dominated by two crustal sources. Low ²⁰⁷Pb/²⁰⁴Pb characterizes one source whereas high ²⁰⁷Pb/²⁰⁴Pb characterizes the second source. Lead isotopic compositions of Jurassic and Miocene ore minerals (²⁰⁶Pb/²⁰⁴Pb>18.50; ²⁰⁷Pb/²⁰⁴Pb>15.61) lie along the average crustal growth curve. By contrast, most Cretaceous deposits have ore minerals with lower ²⁰⁶Pb/²⁰⁴Pb (<18.39) and ²⁰⁷Pb/²⁰⁴Pb (<15.58) than Jurassic ore minerals. The shift in lead isotopic composition to lower lead isotopic values precludes derivation of lead from a source of similar composition to those in the Jurassic or Tertiary deposits. For Cretaceous deposits, polymetallic and low-sulfidation epithermal veins and a skarn have lower ²⁰⁶Pb/²⁰⁴Pb than a porphyry copper-gold system and peripheral gold veins at Andacollo (18.43-18.50). Late Cretaceous veins from the Bellavista deposit have the lowest ²⁰⁶Pb/²⁰⁴Pb (18.33) of all deposits. Ore minerals in Miocene and Pliocene porphyry copper-molybdenum deposits have higher ²⁰⁶Pb/²⁰⁴Pb (18.58-18.67) than Cretaceous deposits, consistent with their age being younger. The Miocene and Pliocene ore minerals also have higher ²⁰⁷Pb/²⁰⁴Pb (15.58-15.66) than Cretaceous ore minerals, thereby requiring an additional input from the high-²⁰⁷Pb/²⁰⁴Pb source into the younger deposits. Miocene auriferous deposits in the north have similar ²⁰⁶Pb/²⁰⁴Pb values as the Miocene and Pliocene porphyry copper-molybdenum deposits in the south, but they are distinguished by higher and variable ²⁰⁷Pb/²⁰⁴Pb (15.61-15.66) and ²⁰⁸Pb/²⁰⁴Pb (38.54-39.01), which are arrayed along steep mixing trends. These ore minerals have the largest input of high-²⁰⁷Pb/²⁰⁴Pb material in the deposits studied. By contrast, lead in the epigenetic manto deposits appears to be derived from the host volcanic or sedimentary rock-dominated sequences, and locally exhibits large-scale isotopic heterogeneity within a deposit. Overall, the lead isotopic compositions of ore minerals mimic the values and variations established in age-equivalent rock sequences. The low-²⁰⁷Pb/²⁰⁴Pb material in the deposits is derived from Cretaceous igneous rocks or their sources as they evolved with time; low ²⁰⁷Pb/²⁰⁴Pb characterizes these rocks. By contrast, high-²⁰⁷Pb/²⁰⁴Pb material is likely derived from Carboniferous to Triassic igneous rocks or their sources, as this lead isotopic characteristic dominates these rocks.     

Rare earth element diffusion in a natural pyrope single crystal at 2.8 GPa

Volume diffusion rates of Ce, Sm, Dy, and Yb have been measured in a natural pyrope-rich garnet single crystal (Py₇₁Alm₁₆Gr₁₃) at a pressure of 2.8 GPa and temperatures of 1,200-1,450 °C. Pieces of a single gem-quality pyrope megacryst were polished, coated with a thin layer of polycrystalline REE oxide, then annealed in a piston cylinder device for times between 2.6 and 90 h. Diffusion profiles in the annealed samples were measured by SIMS depth profiling. The dependence of diffusion rates on temperature can be described by the following Arrhenius equations (diffusion coefficients in m²/s): % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavTnhis1MBaeXatLxBI9gBam % XvP5wqSXMqHnxAJn0BKvguHDwzZbqegm0B1jxALjhiov2DaeHbuLwB % Lnhiov2DGi1BTfMBaebbfv3ySLgzGueE0jxyaibaieYlf9irVeeu0d % Xdh9vqqj-hEeeu0xXdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9 % pgea0dXdar-Jb9hs0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaaca % qabeaadaabauaaaOqaauaabeqaeeaaaaqaaiGbcYgaSjabc+gaVjab % cEgaNnaaBaaaleaacqaIXaqmcqaIWaamaeqaaOGaemiraq0aaSbaaS % qaaiabbMfazjabbkgaIbqabaGccqGH9aqpcqGGOaakcqGHsislcqaI % 3aWncqGGUaGlcqaI3aWncqaIZaWmcqGHXcqScqaIWaamcqGGUaGlcq % aI5aqocqaI3aWncqGGPaqkcqGHsisldaqadaqaaiabiodaZiabisda % 0iabiodaZiabgglaXkabiodaZiabicdaWiaaysW7cqqGRbWAcqqGkb % GscaaMe8UaeeyBa0Maee4Ba8MaeeiBaW2aaWbaaSqabeaacqqGTaql % cqqGXaqmaaGccqGGVaWlcqaIYaGmcqGGUaGlcqaIZaWmcqaIWaamcq % aIZaWmcqWGsbGucqWGubavaiaawIcacaGLPaaaaeaacyGGSbaBcqGG % VbWBcqGGNbWzdaWgaaWcbaGaeGymaeJaeGimaadabeaakiabdseaen % aaBaaaleaacqqGebarcqqG5bqEaeqaaOGaeyypa0JaeiikaGIaeyOe % I0IaeGyoaKJaeiOla4IaeGimaaJaeGinaqJaeyySaeRaeGimaaJaei % Ola4IaeGyoaKJaeG4naCJaeiykaKIaeyOeI0YaaeWaaeaacqaIZaWm % cqaIWaamcqaIYaGmcqGHXcqScqaIZaWmcqaIWaamcaaMe8Uaee4AaS % MaeeOsaOKaaGjbVlabb2gaTjabb+gaVjabbYgaSnaaCaaaleqabaGa % eeyla0IaeeymaedaaOGaei4la8IaeGOmaiJaeiOla4IaeG4mamJaeG % imaaJaeG4mamJaemOuaiLaemivaqfacaGLOaGaayzkaaaabaGagiiB % aWMaei4Ba8Maei4zaC2aaSbaaSqaaiabigdaXiabicdaWaqabaGccq % WGebardaWgaaWcbaGaee4uamLaeeyBa0gabeaakiabg2da9iabcIca % OiabgkHiTiabiMda5iabc6caUiabikdaYiabigdaXiabgglaXkabic % daWiabc6caUiabiMda5iabiEda3iabcMcaPiabgkHiTmaabmaabaGa % eG4mamJaeGimaaJaeGimaaJaeyySaeRaeG4mamJaeGimaaJaaGjbVl % abbUgaRjabbQeakjaaysW7cqqGTbqBcqqGVbWBcqqGSbaBdaahaaWc % beqaaiabb2caTiabbgdaXaaakiabc+caViabikdaYiabc6caUiabio % daZiabicdaWiabiodaZiabdkfasjabdsfaubGaayjkaiaawMcaaaqa % aiGbcYgaSjabc+gaVjabcEgaNnaaBaaaleaacqaIXaqmcqaIWaamae % qaaOGaemiraq0aaSbaaSqaaiabboeadjabbwgaLbqabaGccqGH9aqp % cqGGOaakcqGHsislcqaI5aqocqGGUaGlcqaI3aWncqaI0aancqGHXc % qScqaIYaGmcqGGUaGlcqaI4aaocqaI0aancqGGPaqkcqGHsisldaqa % daqaaiabikdaYiabiIda4iabisda0iabgglaXkabiMda5iabigdaXi % aaysW7cqqGRbWAcqqGkbGscaaMe8UaeeyBa0Maee4Ba8MaeeiBaW2a % aWbaaSqabeaacqqGTaqlcqqGXaqmaaGccqGGVaWlcqaIYaGmcqGGUa % GlcqaIZaWmcqaIWaamcqaIZaWmcqWGsbGucqWGubavaiaawIcacaGL % Paaaaaaaaa!0C76!

Coastal erosion vs riverine sediment discharge in the Arctic Shelf seas

This article presents a comparison of sediment input by rivers and by coastal erosion into both the Laptev Sea and the Canadian Beaufort Sea (CBS). New data on coastal erosion in the Laptev Sea, which are based on field measurements and remote sensing information, and existing data on coastal erosion in the CBS as well as riverine sediment discharge into both the Laptev Sea and the CBS are included. Strong regional differences in the percentages of coastal erosion and riverine sediment supply are observed. The CBS is dominated by the riverine sediment discharge (64.45᎒⁶ t a^-1) mainly of the Mackenzie River, which is the largest single source of sediments in the Arctic. Riverine sediment discharge into the Laptev Sea amounts to 24.10᎒⁶ t a^-1, more than 70% of which are related to the Lena River. In comparison with the CBS, the Laptev Sea coast on average delivers approximately twice as much sediment mass per kilometer, a result of higher erosion rates due to higher cliffs and seasonal ice melting. In the Laptev Sea sediment input by coastal erosion (58.4᎒⁶ t a^-1) is therefore more important than in the CBS and the ratio between riverine and coastal sediment input amounts to 0.4. Coastal erosion supplying 5.6᎒⁶ t a^-1 is less significant for the sediment budget of the CBS where riverine sediment discharge exceeds coastal sediment input by a factor of ca. 10.     

Melt Generation by Plumes: A Study of Hawaiian Volcanism

The mantle plume underlying the Hawaiian Swell has been modellednumerically using a stationary steady axisymmetric plume undera solid conducting lid. A method of calculating the rate ofmelt production from the plume has been developed, and the totalmelt production rate, the residual depth anomaly and the geoidanomaly have been used to constrain the model. The plume hasa central potential temperature of 1558 ?C and the mechanicalboundary layer is 72 km thick. An average of 6?6% melting occursin a melt-producing region which has a vertical extent of 55km and a radial extent of 130 km to produce 0?16 km³/y of melt.A parameterization of melt composition has been developed thatis consistent with laboratory experiments, with models of MORBgeneration, and with primitive Hawaiian tholeiites containing 16% MgO. There is no evidence that the major and minor elementconcentrations in the source region of Hawaiian tholeiites differfrom those in the source region of MORB. The model is consistentwith the REE contents of Kilauean tholeiites if the source regionhas primitive REE contents. The viscosity of the low-viscositylayer is constrained to be 10¹⁶m²/s.