Meganodular anhydritization: a new mechanism of gypsum to anhydrite conversion (Palaeogene–Neogene,Ebro Basin,North‐east Spain)

A number of Palaeogene to Early Neogene gypsum units are located along the southern margins of the Ebro Basin (North‐east Spain). These marginal units, of Eocene to Lower Miocene age, formed and accumulated deposits of Ca sulphates (gypsum and anhydrite) in small, shallow saline lakes of low ionic concentration. The lakes were fed mainly by ground water from deep regional aquifers whose recharge areas were located in the mountain chains bounding the basin, and these aquifers recycled and delivered Ca sulphate and Na chloride from Mesozoic evaporites (Triassic and Lower Jurassic). In outcrop, the marginal sulphate units are largely secondary gypsum after anhydrite and exhibit meganodules (from 0·5 to >5 m across) and large irregular masses. In the sub‐surface these meganodules and masses are mostly made of anhydrite, which replaced the original primary gypsum. The isotopic composition (11·1 to 17·4‰ for δ¹⁸O_VSMOW; 10·7 to 15·3‰ for δ³⁴S_VCDT) of secondary gypsum in this meganodular facies indicates that the precursor anhydrite derived from in situ replacement of an initial primary gypsum. As a result of ascending circulation of deep regional fluid flows through the gypsum units near the basin margins, the gypsum was partly altered to anhydrite within burial conditions from shallow to moderate depths (from some metres to a few hundred metres?). At such depths, the temperatures and solute contents of these regional flows exceeded those of the ground water today. These palaeoflows became anhydritizing solutions and partly altered the subsiding gypsum units before they became totally transformed by deep burial anhydritization. The characteristics of the meganodular anhydritization (for example, size and geometry of the meganodules and irregular masses, spatial arrangement, relations with the associated lithologies and the depositional cycles, presence of an enterolithic vein complex and palaeogeographic distribution) are compared with those of the anhydritization generated both in a sabkha setting or under deep burial conditions, and a number of fundamental differences are highlighted.     

Gypsum–anhydrite transformations in Messinian evaporites of central Tuscany (Italy)

The Messinian succession of Tuscany (central Italy) contains three evaporitic units. Among the several exposed evaporitic lithofacies, only selenitic gypsum precipitated directly from evaporating brines. All the other facies, nodular microcrystalline gypsum, gypsarenites and gypsum laminites, despite their macroscopic differences, display the same petrographic textures, indicating that they are the product of dehydration of gypsum to give anhydrite which has been successively rehydrated to secondary gypsum. These secondary facies show an entire array of textures ranging from cloudy ameboid (xenotopic) with anhydrite relics, to idiotopic without anhydrite relics, that are here interpreted as a sequence of progressive stages of rehydration. The presence of completely hydrated petrofacies at the core of nodules which display a less hydrated rim suggests that these rocks have undergone at least two cycles of a dehydration–rehydration process. This interpretation is supported by the presence of satin spar veins that are replaced by microcrystalline gypsum. Satin spar itself is considered to be a by-product of anhydrite hydration. The first dehydration–rehydration event affected the entire gypsum deposit, producing a completely hydrated (idiotopic) facies together with satin spar veins; the second affected only veins, fractures and the rims of nodules, turning the first generation of satin spar and idiotopic gypsum into cloudy ameboid gypsum. Sedimentary structures typical of sabkha environments indicate for the youngest formation that the first dehydration and rehydration process occurred syndepositionally. The preservation of primary gypsum facies only at sites with condensed sections, indicate for the oldest two formations that the first dehydration event occurred upon burial. This event has been estimated to have occurred in the earliest Pliocene. After the Early Pliocene, dehydration was favored even at shallow depths, due to an increased heat flow related with the emplacement of local crustal magmatic bodies. Rehydration possibly occurred when these formations were uplifted and exposed to ground and/or meteoric water. The Volterra Basin has undergone alternating subsidence and uplift events, that can account for two dehydration–rehydration processes at least, also driven by alternating circulation, in the tectonic fractures, of fresh and salty water, the latter derived from dissolution of Messinian halite.     

The development of a burkeite-dominated salt crust – an example of evaporite sedimentation in a saline pan with non-monomineralic deposits

A salt crust from an ephemeral saline lake in northern Namibia includes a basal thenardite layer (Na₂SO₄), followed by intervals consisting of burkeite (Na₆(CO₃)(SO₄)₂) with a palisade-type fabric that are separated by layers of fine-grained burkeite. All palisade burkeite formed as coatings along the sides of the neighbouring intervals and around thin lenses of fine-grained burkeite. During the development of these coatings, the original constituents of the intervals that they now occupy were dissolved. Textural features indicate that the dissolved deposits were composed at least in part of halite crystals. The study of this crust illustrates the complexity of evaporite sedimentation in ephemeral saline lakes where more than one dominant mineral is formed. In the studied basin, selective dissolution of the most soluble salts occurred during flooding stages, partly affecting subsurface occurrences that consisted of continuous beds. The final product is a nearly monomineralic deposit, derived from a layered non-monomineralic formation. The deposit developed to a large extent by subsurface crystal growth in a subaqueous setting, rather than by mineral formation along the brine–sediment interface or under subaerial conditions.     

Reworking of intra-oceanic rocks in a deep sea basin: example from the Bou-Maiza complex (Edough massif,eastern Algeria)

Metagabbros and amphibolites exposed in the Bou-Maïza area of the Edough massif (northeast Algeria) are described in detail. Field and petro-structural observations point to the syn-sedimentary emplacement of gabbros as clasts, blocks and lenses of polymictic gabbroic breccias. Associated amphibolites display fine-scale parallel sedimentary bedding and represent mafic epiclastites, litharenites and mafic greywackes. The mafic beds and lenses are intercalated with aluminous pelitic schists of continental origin, quartzite and marble. It is concluded that all mafic rocks from this locality derive from the erosion of an oceanic plutono-volcanic complex of MORB affinity that was reworked in a block matrix mélange and emplaced as turbidites and debris flows during the Mesozoic. We propose a convergent plate margin setting for these formations connected with the subducted Calabrian branch of the Tethyan slab.     

Diagenetic formation of gypsum and dolomite in a cold‐water coral mound in the Porcupine Seabight,off Ireland

Authigenic gypsum was found in a gravity core, retrieved from the top of Mound Perseverance, a giant cold‐water coral mound in the Porcupine Basin, off Ireland. The occurrence of gypsum in such an environment is intriguing, because gypsum, a classic evaporitic mineral, is undersaturated with respect to sea water. Sedimentological, petrographic and isotopic evidence point to diagenetic formation of the gypsum, tied to oxidation of sedimentary sulphide minerals (i.e. pyrite). This oxidation is attributed to a phase of increased bottom currents which caused erosion and enhanced inflow of oxidizing fluids into the mound sediments. The oxidation of pyrite produced acidity, causing carbonate dissolution and subsequently leading to pore‐water oversaturation with respect to gypsum and dolomite. Calculations based on the isotopic compositions of gypsum and pyrite reveal that between 21·6% and 28·6% of the sulphate incorporated into the gypsum derived from pyrite oxidation. The dissolution of carbonate increased the porosity in the affected sediment layer but promoted lithification of the sediments at the sediment‐water interface. Thus, authigenic gypsum can serve as a signature for diagenetic oxidation events in carbonate‐rich sediments. These observations demonstrate that fluid flow, steered by environmental factors, has an important effect on the diagenesis of coral mounds.     

阿尔及利亚X区块泥盆系Siegenian组储层微观特征及成岩作用对其影响

通过岩石薄片、铸体薄片、扫描电镜、压汞分析及粘土矿物X衍射分析等资料,从储层的岩性、成岩作用、孔隙类型及影响孔隙结构的因素方面,对阿尔及利亚三叠盆地泥盆系Siegenian组储层的微观特征及成岩作用对其影响进行了研究。研究结果表明,该储层以石英细砂岩、粉砂岩为主,成分成熟度高。储集空间主要有原生粒间孔、粒内溶孔、粒间溶孔、铸模孔、胶结物内溶孔及构造裂缝6种,主要以次生溶蚀孔隙为主,且首次在研究区发现了石英溶蚀孔,并研究了碱性流体的来源。孔隙结构以细孔、细喉-微喉型为主,少量中孔细喉型和微孔微喉型。成岩作用类型多样,在区内发现了碱性溶蚀作用。成岩作用对储层发育具有重要的影响,压实、胶结作用是导致孔隙度和渗透率降低的主要因素,溶蚀作用是区内储层改善的最重要的成岩作用类型。X区块勘探程度低,明确其储层微观特征有利于X区块的进一步勘探开发。     

Deep to shallow lacustrine evaporites in the Libros Gypsum (southern Teruel Basin, Miocene, NE Spain): an occurrence of pelletal gypsum rhythmites

ABSTRACT A number of non‐marine evaporite units composed of primary gypsum were deposited in saline lakes that developed in the southern Teruel Basin (NE Spain) during the Miocene. In the basin depocentre, a continuum of lacustrine evaporite lithofacies influenced by the activity of organisms is displayed. The Libros Gypsum was deposited in a deep lake, in which water stratification became unstable with progressive shoaling. Rhythmites, composed of laminae of pelletal gypsum and laminae of very fine lenticular gypsum crystals mixed with siliceous microorganisms, formed in addition to gypsum turbidites, intraformational gypsum breccias and slump structures. The pelletal laminae originated from the faecal activity of animals (crustaceans?) ingesting gypsum crystallites in the lake water during episodes of maximum evaporation, whereas the laminae of very fine lenticular gypsum mixed with microorganisms accumulated during episodes of relative dilution. In the wide marginal zones of the basin, the Libros Gypsum unit consists of massive to thin‐bedded bioturbated gypsum and thin‐bedded clotted gypsum, which formed in intermediate to very shallow (palustrine) water depths. The bioturbated gypsum lithofacies were produced by the action of diverse organisms, presumably worms and coleopterans, and chironomid larvae to a lesser extent; the massive lithofacies precipitated in very shallow water; and the thin‐bedded lithofacies formed in shallow to deeper settings. The thin‐bedded clotted gypsum is a relatively deep facies that may have diverse origins (e.g. bioturbation, compaction, disruption of soft sediments and early diagenesis). There is a well‐developed metre‐scale cyclicity in the marginal lake sequences, which is not observed in the inner lake deposits. This suggests a depth control in the various lacustrine subenvironments to record cyclic evaporitic processes. The isotopic composition of the gypsum indicates early sulphate‐reducing bacterial activity in the bottom of the lake and suggests that the sulphate was derived from the chemical recycling of Triassic evaporites of the country rocks.     

Multiepisodic evaporite sedimentation as an indicator of palaeogeographical evolution in foreland basins (South‐eastern Pyrenean basin,Early–Middle Eocene)

Extensive deposition of marine evaporites occurred during the Early–Middle Eocene in the South‐eastern Pyrenean basin (north‐east Spain). This study integrates stratigraphic and geochemical analyses of subsurface data (oil wells, seismic profiles and gravity data) together with field surveys to characterize this sedimentation in the foredeep and adjacent platform. Four major evaporite units were identified. The oldest was the Serrat Evaporites unit, with a platform‐slope‐basin configuration. Thick salina and sabkha sulphates accumulated on the platform, whereas resedimented and gravity‐derived sulphates were deposited on the slope, and salt and sulphates were deposited in the deep basin. In the subsequent unit (Vallfogona evaporites), thin sulphates formed on the platform, whereas very thick siliciclastic turbidites accumulated in the foredeep. However, some clastic gypsum coming from the platform (gypsarenites and gypsum olistoliths) was intercalated in these turbidites. The following unit, the Beuda Gypsum Formation developed in a sulphate platform‐basin configuration, where the topography of the depositional surface had become smooth. The youngest unit, the Besalú Gypsum, formed in a shallow setting. This small unit provides the last evidence of marine influence in a residual basin. Sulphur and oxygen isotope compositions are consistent with a marine origin for all evaporites. However, δ³⁴S and δ¹⁸O values also suggest that, except for the oldest unit (Serrat Evaporites), there was some sulphate recycling from the older into the younger units. The South‐eastern Pyrenean basin constitutes a fine example of a foreland basin that underwent multiepisodic evaporitic sedimentation. In the basin, depositional factors evolved with time under a structural control. Decreasing complexity is observed in the lithofacies, as well as in the depositional models, together with a diminishing thickness of the evaporite units.     

Contrasting evolution of low-P rare metal granites from two different terranes in the Hoggar area, Algeria

Two mineralogically different rare metal granites located in two distinct terranes from the Tuareg area are compared: the Tin-Amzi granite in the north of the Laouni Terrane and the Ebelekan granite in the Assodé–Issalane Terrane.The Tin-Amzi granite is enclosed within Eburnean granulitic gneisses, and consists of albite, quartz, protolithionite, K-feldspar and topaz granite (PG). The accessory minerals include columbite tantalite, U- and Hf-rich zircon, Th-uraninite, wolframoixiolite and wolframite. This facies is characterised by a mineralogical evolution from the bottom to the top underlined by a strong resorption of K-feldspar and albite and the crystalliK-feldspar of more abundant topaz and protolithionite II which is further altered in muscovite and Mn-siderite. It is underlain by an albite, K-feldspar, F-rich topaz, quartz and muscovite granite (MG), with W–Nb–Ta oxides, wolframite, Nb-rutile, zircon and scarce uranothorite as accessories.The Ebelekan granite intrudes into a coarse-grained biotite granite enclosed within upper amphibolite-facies metasediments. It comprises a zinnwaldite, albite, topaz porphyritic granite (ZG) with “snow ball” quartz and K-feldspar. The accessories are zircon, monazite, uranothorite, Ta bearing cassiterite, columbite tantalite and wodginite. It is capped by a banded aplite-pegmatite (AP).The geochemistry of Tin-Amzi and Ebelekan granites is nearly comparable. Both are peraluminous (A/CNK=1.10–1.29; ASI=1.17–1.31), sodolithic and fluorine rich with high SiO₂, Al₂O₃, Na₂O+K₂O, Rb, Ga, Li, Ta, Nb, Sn and low FeO, MgO, TiO₂, Ba, Sr, Y, Zr and REE contents. These rare metal Ta bearing granites belong to the P-poor subclass, relating to their P₂O₅ content ( 0.03–0.15 wt.%). Nevertheless, they are distinguished by their concentration of W, Sn and Ta. The Tin-Amzi granite is W–Ta bearing with high W/Sn ratio whereas the Ebelekan granite is Ta–Sn bearing with insignificant W content.At Tin-Amzi the W–Nb–Ta minerals define a sequence formed by W-columbite tantalite followed by wolframoixiolite and finally wolframite showing the effect of hydrothermal overprinting with an extreme W enrichment of the fluids. At Ebelekan, the Sn–Nb–Ta oxides follow a Mn sequence: manganocolumbite→manganotantalite→wodginite+titanowodginite→cassiterite that represents a trend of primary crystallisation resulting from progressive substitution Fe→Mn and Nb→Ta during the magmatic fractionation.     

Hydrochemical and isotopic investigation of a sandstone aquifer groundwater in a semi arid region,El Ma El Abiod,Algeria

This work present results of the hydrochemical and isotopic studies on groundwater samples from the study area. Chemical and environmental isotope data are presented and discussed in terms of the origin of dissolved species and of groundwater. All of the investigated groundwater are categorized into two chemical types: low and relatively high mineralized waters type. Interpretation of chemical data, based on both thermodynamic calculations and stability diagrams, suggests that the chemical evolution of groundwater is primarily controlled by water-rock interactions. Interpretation of ¹⁸O and ²H suggests that the recharge of the investigated groundwater may result from differents mechanisms     

Evaporative systems and diagenetic patterns in the Calatayud Basin (Miocene,central Spain)

This paper concerns the evaporite units, depositional systems, cyclicity, diagenetic products and anhydritization patterns of the Calatayud Basin (nonmarine, Miocene, central Spain). In outcrop, the sulphate minerals of these shallow lacustrine evaporites consist of primary and secondary gypsum, the latter originating from the replacement of anhydrite and glauberite. In the evaporative systems of this basin, gypsiferous marshes of low salinity can be distinguished from central, saline lakes of higher salinity. In the gypsiferous marsh facies, the dominant, massive, bioturbated gypsum was partly replaced by synsedimentary chert nodules and siliceous crusts. In the saline lake facies, either cycles of gypsiferous lutite‐laminated gypsarenite or irregular alternations of laminated gypsum, nodular and banded glauberite, thenardite and nodular anhydrite precipitated. Early replacement of part of the glauberite by anhydrite also occurred. Episodes of subaerial exposure are represented by: (1) pedogenic carbonates (with nodular magnesite) and gypsiferous crusts composed of poikilitic crystals; and (2) nodular anhydrite, which formed in a sabkha. Additionally, meganodular anhydrite occurs, which presumably precipitated from ascending, highly saline solutions. The timing of anhydritization was mainly controlled by the salinity of the pore solutions, and occurred from the onset of deposition to moderate burial. Locally, a thick (>200 m) sequence of gypsum cycles developed, which was probably controlled by climatic variation. A trend of upward‐decreasing salinity is deduced from the base to the top of the evaporite succession.     

Behaviour of chromium VI in a multilayer aquifer in the industrial zone of Annaba,Algeria

Industrial wastewater is characterised by the presence of a great quantity of metallic micro-pollutants, among which chromium by its mobility, contaminates the surface and groundwater. The study of different aquifers within the area of Annaba (Algeria) shows extremely variable chromium concentrations in the unconfined aquifer (0–0.22 mg l⁻¹), which becomes practically null in dry period; on the other hand, they remain relatively constant in the deep confined aquifer (about 0.04 mg l⁻¹). To specify the mechanisms of chromium migration in the aquifer system, a study of space–time evolution of chromium concentrations in unconfined aquifer was undertaken, while considering the kinetics of diffusion in the deeper aquifer. Chromium, indirectly reduced microbiologically by sulphate-reducer bacteria in the upper aquifer, is likely to anticipate the auto-depuration capacity of the ground and to reduce the quality of groundwater.     

Dolomitization,gypsum calcitization and silicification in carbonate–evaporite shallow lacustrine deposits

This paper describes and interprets the mineral and facies assemblages that occur in carbonate–evaporite shallow lacustrine deposits, considering the importance of the processes pathway (i.e. dolomitization, gypsum calcitization and silicification). The Palaeogene deposits of the Deza Formation (Almazán Basin, central‐northern Spain) are selected as a case study to determine the variety of physicochemical processes taking place in carbonate–evaporite shallow lakes and their resulting diagenetic features. Dolostones are the predominant lithology and are composed mainly of dolomite with variable amounts of secondary calcite (5 to 50%), which mainly mimic lenticular gypsum (pseudomorphs). Five morphological types of dolomite crystal were identified as follows: dolomite tubes, dolomite cylinders, rhombohedral dolomite, spheroidal and quasi‐rhombohedral dolomite, and cocoon‐shaped dolomite. The dolomite cylinders and tubes are interpreted as the dolomitized cells of a widespread microbial community. The sequence of diagenetic processes started with growth of microlenticular interstitial gypsum in a calcareous mud deposited on the playa margin mudflats, and that sometimes included microbial sediments. Immediately following growth of gypsum, dolomite replaced the original calcite (or possibly aragonite) muds, the microbial community and the gypsum. Partial or total replacement of gypsum by dolomite was related mainly to the biomineralization of endolithic microbial communities on gypsum crystals. Later calcitization took place under vadose, subaerial exposure conditions. The development of calcrete in distal alluvial settings favoured the release of silica and subsequent silicification on the playa margin mudflats. Stable isotope compositions of calcite range from ?9·02 to ?5·83‰ δ¹³C_PDB and ?7·10 to 1·22‰ δ¹⁸O_PDB; for the dolomite, these values vary from ?8·93 to ?3·96‰ δ¹³C_PDB and ?5·53 to 2·4‰ δ¹⁸O_PDB. Quartz from the cherts has δ¹⁸O_SMOW values ranging from 27·1 to 31·1‰. Wide variation and relatively high δ¹⁸O_SMOW values for dolomite indicate evaporitic and closed hydrological conditions; increased influx of meteoric waters reigned during the formation of secondary calcite spar.     

Post-collisional transition from calc-alkaline to alkaline volcanism during the Neogene in Oranie (Algeria): magmatic expression of a slab breakoff

During the Neogene, a magmatic change from calc-alkaline to alkaline types occurred in all the regions surrounding the western Mediterranean. This change has been studied in Oranie (western Algeria). In this area, potassic to shoshonitic calc-alkaline andesites (with La/Nb ratios in the range 4–6) were mainly erupted between 12 and 9 Ma. They were followed (between 10 and 7 Ma) by basalts displaying geochemical features which are transitional between calc-alkaline and alkaline lavas (La/Nb=1–1.7). After a ca. 3-Ma quiescence period, volcanic activity resumed, with the eruption of OIB-type alkaline basalts (La/Nb=0.5–0.6), from 4 to 0.8 Ma. A combined geochemical approach, using incompatible elements and Sr, Nd and O isotopes, allows us to conclude that the transitional basalts derived from the melting of a heterogeneous mantle source, at the boundary between lithosphere and asthenosphere. We propose that melting of a previously subduction-modified lithospheric mantle occurred between 12 and 10 Ma, in response to the upwelling of hot asthenosphere flowing up into an opening gap above a detached sinking slab. As a result, calc-alkaline magmas were formed. From 10 to 7 Ma, the transitional basalts were generated through melting of the boundary mantle zone between the lithosphere and the upwelling asthenosphere. During that stage, the contribution of the lithospheric source was still predominant. Then, as sinking of the oceanic slab progressed, the increasing uprise of the asthenosphere led to the formation and emplacement (from 4 to 0.8 Ma) of typical within-plate alkaline basalts derived from a plume-modified asthenospheric mantle.     

喀喇昆仑林济塘盆地铅锌矿床容矿地层的海相沉积环境：源于侏罗系灰岩微量元素和石膏硫同位素的约束

近年来,喀喇昆仑地区林济塘中生代沉积盆地内发现了火烧云超大型铅锌矿等众多铅锌矿床,以往对该地区的沉积环境以及其成矿相关性缺乏详细探讨。本文开展了林济塘盆地内侏罗系灰岩微量元素和石膏硫同位素分析,以揭示铅锌矿床容矿地层的沉积环境及其与成矿的相关性。研究发现,盆地内侏罗系灰岩中Ba、V、Ni、Cu、Co、Th、Co、Sr元素及比值特征显示其形成于海相,石膏硫同位素δ34S 值为14.89‰~20.63‰,与同期海水相一致。表明该盆地内铅锌矿床的容矿地层形成于干热气候条件下的海相沉积氧化环境。     

Structure of the earth's crust in Jordan from potential field data

Gravity and magnetic data were collected and used to study the crustal structure of Jordan. Three new geophysical maps of Jordan were created: a Moho discontinuity map, a crystalline basement surface map, and a map showing the lowest limit of magnetic blocks. Depths of the Curie Isotherm were also calculated. Results indicate that the depth to the Moho discontinuity in Jordan varies from 32 to 33 km in the northwest to 38 km in the southeast. The basement complex rocks outcrop on the surface in the southwest but lie at about 8 km in the northeast. The Curie Isotherm (585 °C) lies at a depth of about 10 km in the area east of the Dead Sea and dips southeastward towards the Al-Sirhan (Wadi Sirhan), southeast Jordan, where it is located at 35 km depth. Local isostasy of rock masses (blocks) in Jordan does not occur. Nevertheless, this does not rule out the possible existence of isostasy in a regional scale at greater depths within the mantle.     

鄂尔多斯盆地膏质白云岩有利储层的成因及演化

膏质白云岩是鄂尔多斯盆地中东部下古生界马家沟组M51最有利储层,影响膏质白云岩储层性质的最大因素在于溶蚀作用.本文在已有的研究基础上,应用岩心资料及阴极发光、地球化学等方法,测定M51膏质白云岩及其特殊的示底构造的化学成分,并分析其成因模式.岩心、薄片以及物性资料显示:石膏溶蚀形成的大量膏模孔及伴生的次生孔是储层的主要...     

A lost Tethyan evaporitic basin: Evidence from a Cretaceous hemipelagic meta‐selenite – red chert association in the Eastern Mediterranean realm

Ancient evaporite deposits are geological archives of depositional environments characterized by a long‐term negative precipitation balance and bear evidence for global ocean element mass balance calculations. Here, Cretaceous selenite pseudomorphs from western Anatolia (‘Rosetta Marble’) — characterized by their exceptional morphological preservation — and their ‘marine’ geochemical signatures are described and interpreted in a process‐oriented context. These rocks recorded Late Cretaceous high‐pressure/low‐temperature, subduction‐related metamorphism with peak conditions of 1·0 to 1·2 GPa and 300 to 400°C. Metre‐scale, rock‐forming radiating rods, now present as fibrous calcite marble, clearly point to selenitic gypsum as the precursor mineral. Stratigraphic successions are recorded along a reconstructed proximal to distal transect. The cyclical alternation of selenite beds and radiolarian ribbon‐bedded cherts in the distal portions are interpreted as a two type of seawater system. During arid intervals, shallow marine brines cascaded downward into basinal settings and induced precipitation. During more humid times, upwelling‐induced radiolarian blooms caused the deposition of radiolarite facies. Interestingly, there is no comparable depositional setting known from the Cenozoic world. Meta‐selenite geochemical data (δ¹³C, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr) plot within the range of reconstructed middle Cretaceous seawater signatures. Possible sources for the ¹³C‐enriched (mean 2·2‰) values include methanogenesis, gas hydrates and cold seep fluid exhalation. Spatially resolved component‐specific analysis of a rock slab displays isotopic variances between meta‐selenite crystals (mean δ¹³C 2·2‰) and host matrix (mean δ¹³C 1·3‰). The Cretaceous evaporite‐pseudomorphs of Anatolia represent a basin wide event coeval with the Aptian evaporites of the Proto‐Atlantic and the pseudomorphs share many attributes, including lateral distribution of 600 km and stratigraphic thickness of 1·5 to 2·0 km, with the evaporites formed during the younger Messinian salinity crisis. The Rosetta Marble of Anatolia may represent the best‐preserved selenite pseudomorphs worldwide and have a clear potential to act as a template for the study of meta‐selenite in deep time.     

基于InSAR监测数据的石膏矿采空塌陷特征分析——以邳州平台矿和希州矿为例

石膏是一种重要的矿产资源,但石膏矿的大量开采会产生严重的采空塌陷隐患。目前关于石膏矿采空塌陷的研究多集中于采空区矿柱和护顶层的稳定性等方面,有关矿区采空塌陷地表变形及监测预报方面的研究甚少,也缺乏有效的研究方法。针对石膏矿开采后地面变形特征及塌陷特征研究,通过对矿区InSAR监测数据进行地表变形分析,确定了采空塌陷前的地表变形特征。根据邳州平台矿和希州矿2007—2018年InSAR监测数据进行计算分析,可以看出地面塌陷前,地表存在早期缓慢变形,可根据变形量及范围判断塌陷类型及范围。对InSAR监测数据的计算和分析可为矿区地面塌陷地质灾害的监测、预报及防治提供数据资料与科学依据。