Concentration–discharge relationships reflect chemostatic characteristics of US catchments

Concentration–discharge relationships have been widely used as clues to the hydrochemical processes that control runoff chemistry. Here we examine concentration–discharge relationships for solutes produced primarily by mineral weathering in 59 geochemically diverse US catchments. We show that these catchments exhibit nearly chemostatic behaviour; their stream concentrations of weathering products such as Ca, Mg, Na, and Si typically vary by factors of only 3 to 20 while discharge varies by several orders of magnitude. Similar patterns are observed at the inter‐annual time scale. This behaviour implies that solute concentrations in stream water are not determined by simple dilution of a fixed solute flux by a variable flux of water, and that rates of solute production and/or mobilization must be nearly proportional to water fluxes, both on storm and inter‐annual timescales. We compared these catchments' concentration–discharge relationships to the predictions of several simple hydrological and geochemical models. Most of these models can be forced to approximately fit the observed concentration–discharge relationships, but often only by assuming unrealistic or internally inconsistent parameter values. We propose a new model that also fits the data and may be more robust. We suggest possible tests of the new model for future studies. The relative stability of concentration under widely varying discharge may help make aquatic environments habitable. It also implies that fluxes of weathering solutes in streams, and thus fluxes of alkalinity to the oceans, are determined primarily by water fluxes. Thus, hydrology may be a major driver of the ocean‐alkalinity feedback regulating climate change. Copyright © 2009 John Wiley & Sons, Ltd.     

A comparative overview of weathering intensity and HCO3 flux in the world's major rivers with emphasis on the Changjiang,Huanghe, Zhujiang (Pearl) and Mississippi Rivers

In this paper, general relationships of riverine bicarbonate concentrations and fluxes as a function of drainage basin mineral content and runoff are examined using a database of the 25 largest rivers in the world. Specific HCO₃⁻ flux normalized to unit basin area, which peaks in the mid latitudes, was found to be strongly correlated with the carbonate mineral content of river basins, while river HCO₃⁻ concentration was related to the balance of precipitation and evaporation. Within this global context, the weathering patterns of CO₂ in a few large rivers (Changjiang, Huanghe, Pearl, and Mississippi rivers) were examined in further detail. The Zhujiang (Pearl River), especially its largest branch (Xijiang), was characterized by the highest specific weathering rate among all the world's large rivers due to an exceptionally high carbonate mineral content (over 80%) in its drainage basin and its warm and wet environment. It has a moderate level of HCO₃⁻ concentration, however, due to dilution by relatively high precipitation in the watershed. In stark contrast, the Huanghe (Yellow River) has one of the lowest specific weathering rates because of low carbonate mineral content and a dry climate. However, it has a high HCO₃⁻ concentration due largely to the concentrating effects of high evaporative water loss, as a result of arid weather and the agricultural use of water through irrigation systems, as well as carbonate-containing surficial deposits (i.e., loess). The strong correlation between specific HCO₃⁻ fluxes and discharge in all four rivers with different discharge seasonality suggests that higher precipitation in drainage basins promotes higher weathering rates.     

Temporal and spatial variability of cation and silica export in an alpine watershed,Emerald Lake,California

A reaction set of possible mineral weathering reactions is proposed to explain observed cation and silica export for the Emerald Lake watershed, a small Sierra Nevada, California catchment. The reaction set was calculated through a stoichiometric mole‐balance method, using a multiyear record of stream flow and snowpack chemical analyses and site‐specific mineral compositions. Reaction‐set calculations were intended to explore how the processes controlling stream cation and silica export depend on differing bedrock mineralogy across the catchment as snowmelt and runoff patterns change over the year. Different regions within the watershed can be differentiated by lake inflow subdrainages, each exhibiting different stream‐flow chemistry and calculated weathering stoichiometry, indicating that different silica and cation generation processes are dominant in wet steep portions of the catchment. Short‐term differences in stream concentrations were assumed to reflect ion exchange equilibria and rapid biological processes, whereas long‐term persistent stream concentration differences in different areas of the catchment were assumed to reflect spatial variability in mineral weathering stoichiometry. Mineralogical analyses of rock samples from the watershed provided site‐specific chemical compositions of major mineral species for reaction calculations. Reaction sets were evaluated by linear regression of calculated versus observed differences between snowmelt and stream‐flow chemistry and by a combined measure. Initially, single weathering reactions were balanced and evaluated to determine the reactions that best explained observed stream chemical export. Next, reactions were combined, using mineral compositions from different rock types to estimate the dependence of ion fluxes on lithology. The seasonal variability of major solute calculated fluxes is low, approximately one order of magnitude, relative to the observed three orders of magnitude variability in basin discharge. Reaction sets using basin‐averaged lithology and Aplite lithologies gave superior explanations of stream chemical composition. Copyright © 2004 John Wiley & Sons, Ltd.     

Linking transit times to catchment sensitivity to atmospheric deposition of acidity and nitrogen in mountains of the western United States

Transit times are hypothesized to influence catchment sensitivity to atmospheric deposition of acidity and nitrogen (N) because they help determine the amount of time available for infiltrating precipitation to interact with catchment soil and biota. Transit time metrics, including fraction of young water (F_yw) and mean transit time (MTT), were calculated for 11 headwater catchments in mountains of the western United States based on differences in the amplitude of the seasonal signal of δ¹⁸O in streamflow and precipitation. Results were statistically compared with catchment characteristics to elucidate controlling mechanisms. Transit times also were compared with stream solute concentrations to test the hypothesis that transit times are a primary influence on weathering rates and biological assimilation of atmospherically deposited N. Results indicate that transit times in the study catchments are strongly related to soil, vegetation, and topographic characteristics, with barren terrain (bare rock and talus) and steep slopes linked to high F_yw and short MTT, whereas forest soil (hydrogroup B) was linked to low F_yw and greater MTT. Concentrations of silicate weathering products (Na⁺ and Si) were negatively related to F_yw and barren terrain, and positively related to MTT and forest soil, supporting the concept that weathering fluxes and buffering capacity tend to be low in alpine areas due to short transit times. Nitrate concentrations were positively related to N deposition, catchment slope, and barren terrain, and negatively related to forest, indicating that hydrologic and/or biogeochemical processes associated with steep slopes limit uptake of atmospherically deposited N by biota. Interannual and seasonal variability in transit times and source water contributions in the study catchments was substantial, reflecting the influence of strong temporal variations in snowmelt inputs in high‐elevation catchments of the western United States. Results from this study confirm that short transit times in these areas are a key reason they are highly sensitive to atmospheric pollution and climate change.     

Conditions for generation of fire‐related debris flows,Capulin Canyon,New Mexico

Comparison of the responses of three drainage basins burned by the Dome fire of 1996 in New Mexico is used to identify the hillslope, channel and fire characteristics that indicate a susceptibility specifically to wildfire‐related debris flow. Summer thunderstorms generated three distinct erosive responses from each of three basins. The Capulin Canyon basin showed widespread erosive sheetwash and rilling from hillslopes, and severe flooding occurred in the channel; the North Tributary basin exhibited extensive erosion of the mineral soil to a depth of 5 cm and downslope movement of up to boulder‐sized material, and at least one debris flow occurred in the channel; negligible surface runoff was observed in the South Tributary basin. The negligible surface runoff observed in the South Tributary basin is attributed to the limited extent and severity of the fire in that basin. The factors that best distinguish between debris‐flow producing and flood‐producing drainages are drainage basin morphology and lithology. A rugged drainage basin morphology, an average 12 per cent channel gradient, and steep, rough hillslopes coupled with colluvium and soil weathered from volcaniclastic and volcanic rocks promoted the generation of debris flows. A less rugged basin morphology, an average gradient of 5 per cent, and long, smooth slopes mantled with pumice promoted flooding. Flood and debris‐flow responses were produced without the presence of water‐repellent soils. The continuity and severity of the burn mosaic, the condition of the riparian vegetation, the condition of the fibrous root mat, accumulations of dry ravel and colluvial material in the channel and on hillslopes, and past debris‐flow activity, appeared to have little bearing on the distinctive responses of the basins. Published in 2000 by John Wiley & Sons, Ltd.     

The significance of channel recharge rates for estimating debris‐flow magnitude and frequency

The quantification of debris‐flow hazard requires estimates of debris‐flow frequency and magnitude. Several methods have been proposed to determine the probable volume of future debris flows from a given basin, but most have neglected to account for debris recharge rates over time, which may lead to underestimation of debris‐flow volumes in basins with rare debris flows. This paper deals with the determination of debris recharge rates in debris‐flow channels based on knowledge of debris storage and the elapsed time since the last debris flow. Data are obtained from coastal British Columbia and a relation is obtained across a sample of basins with similar terrain and climatic conditions. For Rennell Sound on the west coast of the Queen Charlotte Islands, the power‐law relation for area‐normalized recharge rate, R_t, versus elapsed time, t_e was R_t = 0·23t_e^?0·58 with an explained variance of 75 per cent. A difference in recharge rates may exist between creeks in logged and unlogged forested terrain. The power function for undisturbed terrain was R_t = 0·20t_e^?0·49, while the function for logged areas was R_t = 0·30t_e^?0·77. This result suggests that for the same elapsed time since the last debris flow, clearcut gullies tend to recharge at a slower rate than creeks in old growth forest. This finding requires verification, particularly for longer elapsed times since debris flow, but would have important implications for forest resource management in steep coastal terrain. This study demonstrates that commonly used encounter probability equations are inappropriate for recharge‐limited debris flow channels. Copyright © 2005 John Wiley & Sons, Ltd.     

The structure and sedimentology of relict talus,Trotternish, northern Skye,Scotland

Sections up to 3·5 m deep cut through the upper rectilinear segment of relict, vegetated talus slopes at the foot of the Trotternish escarpment reveal stacked debris-flow deposits intercalated with occasional slopewash horizons and buried organic soils. Radiocarbon dating of buried soil horizons indicates that reworking of sediment by debris flows predates 5·9–5·6 Cal ka BP , and has been intermittently active throughout the late Holocene. Particle size analyses of 18 bulk samples from these units indicates that c. 27–30 per cent of the talus deposit is composed of fine (<2 mm) sediment. Sedimentological comparison with tills excludes a glacigenic origin for the talus debris, and the angularity of constituent clasts suggests that in situ weathering has been insignificant in generating fine material. We conclude that the fine sediment within the talus is derived primarily by granular weathering of the rockwall, with syndepositional accumulation of both fine and coarse debris, implying that c. 27–30 per cent of rockwall retreat since deglaciation reflects granular weathering rather than rockfall. The abundance of fines within the talus deposits is inferred to have been of critical importance in facilitating build-up of porewater pressures during rainstorms, leading to episodic failure and flow of debris on the upper parts of the slope. A wider implication of these findings is that the mechanical properties of talus slopes cannot be regarded as those of free-draining accumulations of coarse clasts, and that models that treat talus slopes as such have limited value in explaining their form and evolution. Our findings lend support to models that envisage the upper straight slope on talus accumulations as the product of mass-transport as well as rockfall, and indicate that episodic debris flow has been the primary agent of mass-transport at this site. © 1998 John Wiley & Sons, Ltd.     

A comparison of solute fluxes and sources from glacial and non‐glacial catchments over contrasting melt seasons

Solute and runoff fluxes from two adjacent alpine streams (one glacial and one non‐glacial) were investigated to determine how the inorganic solute chemistry of runoff responded to seasonal and interannual changes in runoff sources and volume, and to differences in physical catchment properties. Intercatchment differences in solute composition were primarily controlled by differences in catchment geology and the presence of soils, whereas differences in total solute fluxes were largely dependent on specific discharge. The glacial stream catchment had higher chemical denudation rates due to the high rates of flushing (higher specific discharge). The non‐glacial Bow River had higher overall concentrations of solutes despite the greater prevalence of more resistant lithologies in this catchment. This is likely the result of both longer average water–rock contact times, and a greater supply of protons from organic soils and/or pyrite oxidation. Increases in snowpack depth/snowmelt runoff reduced the retention of nitrate in the Bow River catchment (i.e. increased nitrate export), probably by reducing net biological uptake, or by reducing the proportion of runoff that had contact with biologically active soil horizons that tend to remove nitrate. The two streams exhibited opposite solute flux responses to climate perturbations over three melt seasons (1998, 1999, and 2000). The 1998 El Niño event resulted in an unusually thin winter snowpack, and increased runoff and solute fluxes from the glacial catchment, but decreased fluxes from the Bow River catchment. Solute fluxes in the Bow River increased proportionally to discharge, indicating that increased snowmelt runoff in this catchment resulted in a proportional increase in weathering rates. In contrast, the proportional variation in solute flux in the glacial stream was only ∼70–80% of the variation in water flux. This suggests that increased ablation of glacier ice and the development of subglacial channels during the 1998 El Niño year apparently reduced the average water–rock contact time in the glacial catchment relative to seasons when the subglacial drainage system was primarily distributed in character. Copyright © 2005 John Wiley & Sons, Ltd.     

Depositional process and alluvial fan-drainage basin morphometric relationships near banff,Alberta, Canada

Two distinct types of alluvial fans occur in the Bow River Valley, Alberta, Canada: fluvially dominated and debris flow dominated. Large, gently sloping fans dominated by fluvial processes are associated with large and less rugged drainage basins, and small rugged basins have produced small, steep fans dominated by debris flow processes. Quantitative analysis demonstrates that strong fan-basin morphometric relationships occur despite a short fan history. Statistical analysis of fan area-basin area relationships indicate that debris flow fan areas do not increase in size as quickly as contributing basins. The relationship of fluvial fan area to basin area is not statistically significant. However, this relationship is probably affected by fan erosion. Examination of fan slope to basin ruggedness relationships indicates that fan slope increases more rapidly than basin ruggedness for both fan types. This is likely related to non-linear discharge and sediment size effects on fluvial fans, and reworking of larger fan surfaces by fluvial processes on debris flow fans.     

Factors controlling seasonal groundwater and solute flux from snow‐dominated basins

Critical zone influences on hydrologic partitioning, subsurface flow paths and reactions along these flow paths dictate the timing and magnitude of groundwater and solute flux to streams. To isolate first‐order controls on seasonal streamflow generation within highly heterogeneous, snow‐dominated basins of the Colorado River, we employ a multivariate statistical approach of end‐member mixing analysis using a suite of daily chemical and isotopic observations. Mixing models are developed across 11 nested basins (0.4 to 85 km²) spanning a gradient of climatological, physical, and geological characteristics. Hydrograph separation using rain, snow, and groundwater as end‐members indicates that seasonal contributions of groundwater to streams is significant. Mean annual groundwater flux ranges from 12% to 33% whereas maximum groundwater contributions of 17% to 50% occur during baseflow. The direct relationship between snow water equivalent and groundwater flux to streams is scale dependent with a trend toward self‐similarity when basins exceed 5.5 km². We find groundwater recharge increases in basins of high relief and within the upper subalpine where maximum snow accumulation is coincident with reduced conifer cover and lower canopy densities. The mixing model developed for the furthest downstream site did not transfer to upstream basins. The resulting error in predicted stream concentrations points toward weathering reactions as a function of source rock and seasonal shifts in flow path. Additionally, the potential for microbial sulfate reduction in floodplain sediments along a low‐gradient, meandering portion of the river is sufficient to modify hillslope contributions and alter mixing ratios in the analysis. Soil flushing in response to snowmelt is not included as an end‐member but is identified as an important mechanism for release of solutes from these mountainous watersheds. End‐member mixing analysis used in combination with high‐frequency observations reveals important aspects of catchment hydrodynamics across scale.     

Chemical weathering in a drainage basin underlain by old red sandstone

A hydrochemical budget is used to quantify the rate of chemical weathering and solutional denudation on Old Red Sandstone in East Twin drainage basin (0.2 km²) on the Mendip Hills for the 1972–73 Water Year. Net nutrient uptake by the biomass and precipitation inputs are subtracted from stream solute outputs to give an estimate of the solutes released to the system by weathering. The mineralogies of the sandstone and the soil are compared to predict possible weathering reactions for the primary and secondary minerals. Tentative estimates of primary mineral alteration and secondary mineral formation are then made by substituting the hydrochemical balances into the formulated weathering reactions. Finally the rate of solutional denudation (0.8 tonnes/a or 1.6 mm/100 a) is compared with other estimates of solutional and mechanical denudation at East Twin and with similarly derived results for other lithologies.     

Influence of basin characteristics on baseflow and stormflow chemistry in the Great Smoky Mountains National Park,USA

Relationships between stream chemistry and elevation, area, Anakeesta geology, soil properties, and dominant vegetation were evaluated to identify the influence of basin characteristics on baseflow and stormflow chemistry in eight streams of the Great Smoky Mountains National Park. Statistical analyses were employed to determine differences between baseflow and stormflow chemistry, and relate basin‐scale factors governing local chemical processes to stream chemistry. Following precipitation events, stream pH was reduced and aluminium concentrations increased, while the response of acid neutralizing capacity (ANC), nitrate, sulfate, and base cations varied. Several basin characteristics were highly correlated with each other, demonstrating the interrelatedness of topographical, geological, soil, and vegetative parameters. These interrelated basin factors uniquely influenced acidification response in these streams. Streams in higher‐elevation basins (>975 m) had significantly lower pH, ANC, sodium, and silicon and higher nitrate concentrations (p < 0.05). Streams in smaller basins (<10 km²) had significantly lower nitrate, sodium, magnesium, silicon, and base cation concentrations. In stormflow, streams in basins with Anakeesta geology (>10%) had significantly lower pH and sodium concentrations, and higher aluminium concentrations. Chemical and physical soil characteristics and dominant overstory vegetation in basins were more strongly correlated with baseflow and stormflow chemical constituents than topographical and geological basin factors. Saturated hydraulic conductivity, of all the soil parameters, was most related to concentrations of stormflow constituents. Basins with higher average hydraulic conductivities were associated with lower stream pH, ANC, and base cation concentrations, and higher nitrate and sulfate concentrations. These results emphasize the importance of soil and geological properties influencing stream chemistry and promote the prioritization of management strategies for aquatic resources. Copyright © 2012 John Wiley & Sons, Ltd.     

Talus slope geomorphology investigated at multiple time scales from high-resolution topographic surveys and historical aerial photographs (Sanetsch Pass,Switzerland)

Talus slopes are common places for debris storage in high-mountain environments and form an important step in the alpine sediment cascade. To understand slope instabilities and sediment transfers, detailed investigations of talus slope geomorphology are needed. Therefore, this study presents a detailed analysis of a talus slope on Col du Sanetsch (Swiss Alps), which is investigated at multiple time scales using high-resolution topographic (HRT) surveys and historical aerial photographs. HRT surveys were collected during three consecutive summers (2017–2019), using uncrewed aerial vehicle (UAV) and terrestrial laser scanning (TLS) measurements. To date, very few studies exist that use HRT methods on talus slopes, especially to the extent of our study area (2 km²). Data acquisition from ground control and in situ field observations is challenging on a talus slope due to the steep terrain (30–37°) and high surface roughness. This results in a poor spatial distribution of ground control points (GCPs), causing unwanted deformation of up to 2 m in the gathered UAV-derived HRT data. The co-alignment of UAV imagery from different survey dates improved this deformation significantly, as validated by the TLS data. Sediment transfer is dominated by small-scale but widespread snow push processes. Pre-existing debris flow channels are prone to erosion and redeposition of material within the channel. A debris flow event of high magnitude occurred in the summer of 2019, as a result of several convective thunderstorms. While low-magnitude (<5,000 m³) debris flow events are frequent throughout the historical record with a return period of 10–20 years, this 2019 event exceeded all historical debris flow events since 1946 in both extent and volume. Future climate predictions show an increase of such intense precipitation events in the region, potentially altering the frequency of debris flows in the study area and changing the dominant geomorphic process which are active on such talus slopes. © 2020 John Wiley & Sons, Ltd.     

Hillslope response to knickpoint migration in the Southern Appalachians: implications for the evolution of post‐orogenic landscapes

The southern Appalachians represent a landscape characterized by locally high topographic relief, steep slopes, and frequent mass movement in the absence of significant tectonic forcing for at least the last 200 Ma. The fundamental processes responsible for landscape evolution in a post‐orogenic landscape remain enigmatic. The non‐glaciated Cullasaja River basin of south‐western North Carolina, with uniform lithology, frequent debris flows, and the availability of high‐resolution airborne lidar DEMs, is an ideal natural setting to study landscape evolution in a post‐orogenic landscape through the lens of hillslope–channel coupling. This investigation is limited to channels with upslope contributing areas >2.7 km², a conservative estimate of the transition from fluvial to debris‐flow dominated channel processes. Values of normalized hypsometry, hypsometric integral, and mean slope vs elevation are used for 14 tributary basins and the Cullasaja basin as a whole to characterize landscape evolution following upstream knickpoint migration. Results highlight the existence of a transient spatial relationship between knickpoints present along the fluvial network of the Cullasaja basin and adjacent hillslopes. Metrics of topography (relief, slope gradient) and hillslope activity (landslide frequency) exhibit significant downstream increases below the current position of major knickpoints. The transient effect of knickpoint‐driven channel incision on basin hillslopes is captured by measuring the relief, mean slope steepness, and mass movement frequency of tributary basins and comparing these results with the distance from major knickpoints along the Cullasaja River. A conceptual model of area–elevation and slope distributions is presented that may be representative of post‐orogenic landscape evolution in analogous geologic settings. Importantly, the model explains how knickpoint migration and channel–hillslope coupling is an important factor in tectonically‐inactive (i.e. post‐orogenic) orogens for the maintenance of significant relief, steep slopes, and weathering‐limited hillslopes. Copyright © 2011 John Wiley & Sons, Ltd.     

Contemporary rates of chemical denudation and atmospheric CO2 sequestration in glacier basins: an Arctic perspective

This paper presents new estimates of solute fluxes from five high Arctic glacier basins in Svalbard. These estimates are combined with data from two other glacier basins to assess the effectiveness of chemical denudation on Svalbard and to estimate rates of temporary (or transient) CO₂ drawdown. We use a solute provenance model to partition solutes into marine, aerosol, atmospheric and crustal components and to estimate their annual fluxes. Crustally derived solute fluxes are equivalent to a mean chemical denudation rate of 350 Σmeq⁺ m⁻² a⁻¹ for Svalbard (range: 160–560 Σmeq⁺ m⁻² a⁻¹), which lies within the global range of 94–4200 Σmeq⁺ m⁻² a⁻¹ for 21 glacier basins in the northern hemisphere, and is close to the continental average of 390 Σmeq⁺ m⁻² a⁻¹. Specific annual discharge is the most significant control upon chemical denudation in the glacierized basins, and basin lithology is an important secondary control, with carbonate‐rich and basaltic lithologies currently showing the greatest chemical denudation rates. Estimates of transient CO₂ drawdown are also directly associated with specific annual discharge and rock type. On Svalbard transient CO₂ drawdown lies in the range 110–3000 kg C km⁻² a⁻¹, whilst the range is 110–13000 kg C km⁻² a⁻¹ for the northern hemisphere glacial data set. Transient CO₂ drawdown is therefore usually low in the Svalbard basins unless carbonate or basalt rocks are abundant. The analysis shows that a large area of uncertainty in the transient CO₂ drawdown estimates exists due to the non‐stoichiometric release of solute during silicate hydrolysis. Silicate hydrolysis is particularly non‐stoichiometric in basins where the extent of glacierization is high, which is most probably an artefact of high flushing rates through ice‐marginal and subglacial environments where K‐feldspars are undergoing mechanical comminution. Copyright © 2000 John Wiley & Sons, Ltd.     

From on high: Geochemistry of alpine springs,Niwot Ridge,Colorado Front Range,USA

Snowmelt‐fed springs and small (0.5 km²) upland catchments in alpine areas of the western United States contribute significantly to the quantity and inorganic chemistry of water delivered to downstream basins but have not been studied extensively. Mineral weathering, transit time, and hydrologic mixing control the solute chemistry of waters that drain the upland zone of Niwot Ridge, Colorado Front Range, and adjacent areas in the granitic core of the Southern Rocky Mountains. Water in 37 springs sampled in this study flows in generally short steep paths (~0.3 km) through shallow regolith with mean transit times (MTT) of weeks to months, producing solutions dominated by Si, Ca²⁺, Na⁺, and HCO₃^?, locally SO₄^2?. Rock type is a significant control on spring, surface, and shallow groundwater chemistry, and plagioclase (oligoclase) is the major source of dissolved Na⁺ and Si. Concentrations of Ca²⁺ exceed stoichiometric predictions of oligoclase weathering by ~3.5×; excess Ca²⁺ likely represents weathering of aeolian material, vein calcite, or trace minerals. Concentrations of base cations and Si increase slowly with estimated MTT of 0.2 years for Niwot Ridge spring waters, and several years for shallow groundwater sampled by wells. Chemical weathering of silicate minerals is slow with estimated rates of ~2.0 and 0.2 pmol·m^?2·s^?1 for oligoclase and microcline, respectively; the most mineralized spring waters are saturated only with respect to kaolinite and montmorillonite. More than 50% of the dissolved base cations + Si measured in Boulder Creek at Orodell (~25 km downstream) accumulate before water emerges from alpine springs on Niwot Ridge. Warming global temperatures are shifting more high‐elevation precipitation to rain, potentially changing run‐off patterns, transit time, and solute loads. Acquisition of solutes by alpine waters thus has implications far beyond small upland catchments.     

Chloride flux out of Yellowstone National Park

Monitoring of the chloride concentration, electrical conductivity, and discharge was carried out for the four major rivers of Yellowstone National Park from September 1982 to January 1984. Chloride flux out of the Park was determined from the measured values of chloride concentration and discharge. The annual chloride flux from the Park was 5.86 × 10¹⁰ g. Of this amount 45% was from the Madison River drainage basin, 32% from the Yellowstone River basin, 12% from the Snake River basin, and 11% from the Falls River basin. Of the annual chloride flux from the Yellowstone River drainage basin 36% was attributed to the Yellowstone Lake drainage basin. The geothermal contribution to the chloride flux was determined by subtracting the chloride contribution from rock weathering and atmospheric precipitation and is 94% of the total chloride flux. Calculations of the geothermal chloride flux for each river are given and the implications of an additional chloride flux out of the western Park boundary discussed. An anomalous increase in chloride flux out of the Park was observed for several weeks prior to the Mt. Borah earthquake in Central Idaho on October 28, 1983, reaching a peak value shortly thereafter. It is suggested that the rise in flux was a precursor of the earthquake. The information in this paper provides baseline data against which future changes in the hydrothermal systems can be measured. It also provides measurements related to the thermal contributions from the different drainage basins of the Park.     

Processes and rates of sediment and wood accumulation in headwater streams of the Oregon Coast Range,USA

Channels that have been scoured to bedrock by debris flows provide unique opportunities to calculate the rate of sediment and wood accumulation in low‐order streams, to understand the temporal succession of channel morphology following disturbance, and to make inferences about processes associated with input and transport of sediment. Dendrochronology was used to estimate the time since the previous debris flow and the time since the last stand‐replacement fire in unlogged basins in the central Coast Range of Oregon. Debris flow activity increased 42 per cent above the background rate in the decades immediately following the last wildfire. Changes in wood and sediment storage were quantified for 13 streams that ranged from 4 to 144 years since the previous debris flow. The volume of wood and sediment in the channel, and the length of channel with exposed bedrock, were strongly correlated with the time since the previous debris flow. Wood increased the storage capacity of the channel and trapped the majority of the sediment in these steep headwater streams. In the absence of wood, channels that have been scoured to bedrock by a debris flow may lack the capacity to store sediment and could persist in a bedrock state for an extended period of time. With an adequate supply of wood, low‐order channels have the potential of storing large volumes of sediment in the interval between debris flows and can function as one of the dominant storage reservoirs for sediment in mountainous terrain. Copyright © 2003 John Wiley & Sons, Ltd.     

Cavernous weathering in the Capitol Reef Desert,Utah

Tafoni and honeycomb weathering are abundant in sandstones at Capitol Reef National Park. Cavities are particularly common in talus blocks resting on alkali-rich soil, in vertical walls of desert washes, and in sandstones containing calcareous cement. Chemical analyses, X-ray diffraction data, and field observations suggest that salt weathering is the most important cause of disintegration, but dissolution of calcite cement also occurs in calcareous sandstones. Cavernous weathering at Capitol Reef produces cavities similar in appearance to features found in arkose outcrops along the coast of northwest Washington, even though the environmental conditions at these two locations are very different.