Early to middle Holocene silicic tephra horizons from the Katla volcanic system,Iceland: new results from the Faroe Islands

Comparatively few Icelandic tephra horizons dated to the early part of the Holocene have so far been detected outside Iceland. Here, I present several tephra horizons that have been recorded in a Holocene peat sequence on the Faroe Islands. Geochemical analyses show that at least two dacitic and one rhyolitic tephra layers were erupted from the Katla volcanic system on southern Iceland between ca. 8000 and 5900 cal. yr BP. The upper two layers can be correlated with the SILK tephras described from southern Iceland, whereas the third, dated to ca. 8000 cal. yr BP, has a geochemistry virtually identical to the rhyolitic component of the Vedde Ash. The results suggest that the Late Weichselian and early Holocene eruption history of the Katla volcano was probably more complex than inferred from Iceland. A new, early Holocene rhyolitic tephra dated to ca. 10 500 cal. yr BP probably originates in the Snæfellsnes volcanic centre in western Iceland. These new findings may play an important role in developing a Holocene tephra framework for northwest Europe. Copyright © 2002 John Wiley & Sons, Ltd.     

A catalogue of major and trace element data for Icelandic Holocene silicic tephra layers

Tephra layers with Icelandic provenance have been identified across the North Atlantic region in terrestrial, lacustrine, marine and glacial environments. These tephra layers are used as marker horizons in tephrochronology including climate studies, archaeology and environmental change. The major element chemistries of 19 proximally deposited Holocene Icelandic silicic tephra layers confirm that individual volcanic systems have unique geochemical signatures and that eruptions from the same system can often be distinguished. In addition, glass trace element chemistry highlights subtle geochemical variations between tephra layers which appear to have identical major element chemistry and thus allows for the identification of some, if not all, tephra layers previously considered identical in composition. This paper catalogues the compositional variation between the widespread Holocene Icelandic silicic tephra deposits.     

Geochemical characterization of marker tephra layers from major Holocene eruptions,Kamchatka Peninsula,Russia

Kamchatka Peninsula is one of the most active volcanic regions in the world. Many Holocene explosive eruptions have resulted in widespread dispersal of tephra-fall deposits. The largest layers have been mapped and dated by the ¹⁴C method. The tephra provide valuable stratigraphic markers that constrain the age of many geological events (e.g. volcanic eruptions, palaeotsunamis, faulting, and so on). This is the first systematic attempt to use electron microprobe (EMP) analyses of glass to characterize individual tephra deposits in Kamchatka. Eighty-nine glass samples erupted from 11 volcanoes, representing 27 well-identified Holocene key-marker tephra layers, were analysed. The glass is rhyolitic in 21 tephra, dacitic in two, and multimodal in three. Two tephra are mixed with glass compositions ranging from andesite/dacite to rhyolite. Tephra from the 11 eruptive centres are distinguished by their glass K₂O, CaO, and FeO contents. In some cases, individual tephra from volcanoes with multiple eruptions cannot be differentiated. Trace element compositions of 64 representative bulk tephra samples erupted from 10 volcanoes were analysed by instrumental neutron activation analysis (INAA) as a pilot study to further refine the geochemical characteristics; tephra from these volcanoes can be characterized using Cr and Th contents and La/Yb ratios.

Unidentified tephra collected at the islands of Karaginsky (3), Bering (11), and Attu (5) as well as Uka Bay (1) were correlated to known eruptions. Glass compositions and trace element data from bulk tephra samples show that the Karaginsky Island and Uka Bay tephra were all erupted from the Shiveluch volcano. The 11 Bering Island tephra are correlated to Kamchatka eruptions. Five tephra from Attu Island in the Aleutians are tentatively correlated with eruptions from the Avachinsky and Shiveluch volcanoes.     

A shift in eruption mode of Hekla volcano,Iceland, 3000 years ago: two-coloured Hekla tephra series,characteristics, dispersal and age

Hekla volcano is a major producer of large, widespread silicic tephras. About 3000 years ago, the dominant eruption mode shifted from infrequent large (>1 km³) to more frequent moderate (<1 km³) eruptions. In the following two millennia ≥20 explosive silicic-to-intermediate eruptions occurred, and six or more basaltic. Three categories can be identified with dacite/andesite to basaltic andesite in the oldest eruptions through basaltic andesite to basalt in the youngest eruptions. Ten tephra layers of the first category have distinct field characteristics: a pale lower unit and a dark upper unit (two coloured or TC-layers). Colour separation is sharp indicating a stratified magma chamber origin. The lower unit is dominantly andesitic (61–63% SiO₂), while the upper unit is basaltic andesite (53–57% SiO₂). Volumes of the eight largest TC-layers range from 0.2 to 0.7 km³ as freshly fallen. Radiocarbon and soil accumulation rate dates constrain the TC-layers to between 3000 and 2200 years ago. Two of these (~2890 and ~2920 b2k) are likely to occur overseas. Low SiO₂ in the last erupted tephra of the TC-layers is comparable to that of historical Hekla lavas, implying a final effusive phase. The Hekla edifice may, consequently, be younger than 3000 years.     

Identification and definition of primary and reworked tephra in Late Glacial and Holocene marine shelf sediments off North Iceland

Nine tephra layers in marine sediment cores (MD99‐2271 and MD99‐2275) from the North Icelandic shelf, spanning the Late Glacial and the Holocene, have been investigated to evaluate the effectiveness of methods to detect tephra layers in marine environments, to pinpoint the stratigraphic level of the time signal the tephra layers provide, and to discriminate between primary and reworked tephra layers in a marine environment. These nine tephra layers are the Borrobol‐like tephra, Vedde Ash, Askja S tephra, Saksunarvatn ash, and Hekla 5, Hekla 4, Hekla 3, Hekla 1104 and V1477 tephras. The methods used were visual inspection, magnetic susceptibility, X‐ray photography, mineralogical counts, grain size and morphological measurements, and microprobe analysis. The results demonstrate that grain size measurements and mineralogical counts are the most effective methods to detect tephra layers in this environment, revealing all nine tephra layers in question. Definition of the tephra layers revealed a 2–3 cm diffuse upper boundary in eight of the nine tephra layers and 2–3 cm diffuse lower boundary in two tephra layers. Using a multi‐parameter approach the stratigraphic position of a tephra layer was determined where the rate of change of the parameters tested was the greatest compared with background values below the tephra. The first attempt to use grain morphology to distinguish between primary and reworked tephra in a marine environment suggests that this method can be effective in verifying whether a tephra layer is primary or reworked. Morphological measurements and microprobe analyses in combination with other methods can be used to identify primary tephra layers securely. The study shows that there is a need to apply a combination of methods to detect, define (the time signal) and discriminate between primary and reworked tephra in marine environments. Copyright © 2011 John Wiley & Sons, Ltd.     

The tephrochronology of Iceland and the North Atlantic region during the Middle and Late Quaternary: a review

The tephrochronology of Iceland and the North Atlantic region is reviewed in order to construct a unified framework for the last 400 kyr BP. Nearly all of the tephra layers described are also characterised geochemically. A number of new tephra layers are analysed for the first time for their geochemical signature and a number of pre‐Holocene tephra layers have been given an informal denotation. The tephrostratigraphy of Ash Zone II is highlighted. Where possible the rhyolitic tephra layers found outside Iceland have been correlated to known Icelandic tephra layers or to the volcanic source area. The application of tephra fallout in various depositional environments is described and discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

An outline tephrochronology for the Holocene of the north of Ireland

Geochemically typed thin layers of Icelandic Holocene tephras form a tephrochronology for the north of Ireland. Tephrochronology construction is based on geochemical linkage with dated historic Icelandic eruptions and high-precision multisample radiocarbon dating. Comparison with geochemically typed Holocene layers at sites throughout Scotland and northern England shows that some layers are widespread throughout much of the northern British Isles. Other layers of known historic date have so far been detected only in Ireland.     

Use of magnetic signatures to correlate tephra layers in Holocene loessial soil profiles from a small region, SE Iceland

Rock magnetic measurements have been applied to two adjacent loessial soil sections from a small region, SE Iceland. The soils are composed of reworked locally derived sediment (including airfall tephra) and also contain several visible discrete airfall tephra layers. The main magnetic minerals in the airfall tephras are ferrimagnetic (e.g. magnetite) with paramagnetic minerals also present. The main magnetic grain sizes in the tephras are pseudo single domain. The results show that individual tephras do not have unique magnetic signatures that can be used for identification and correlation between sedimentary sequences. However, a correlation of tephra layers was achieved through the application of statistical techniques to a comprehensive dataset of magnetic parameters. Similarity coefficients and Euclidian distance measures were used to identify the best correlation between tephra layers in the two soil profiles. The technique works well providing some tephras present within both profiles have been formally identified (e.g. Oraefajokulla ad 1362) using electron microprobe analyses. Given this initial framework, the statistical analyses of the magnetic parameters can help in the identification and correlation of unknown tephras between two soil profiles.     

Probabilistic model for eruptions and associated flood events in the Katla caldera,Iceland

Eruptions in the subglacial Katla caldera, South Iceland, release catastrophic jokulhlaups (meltwater floods). The ice surface topography divides the caldera into three drainage sectors (Ko, So and En sectors) that drain onto Myrdalssandur, Solheimasandur and Markarfljot plains, respectively. In historical times, floods from the Ko sector have been dominant, with only two recorded So events. Geological records indicate that floods from the En sector occur every 500–800 years. A probabilistic model for an eruption is formulated in general terms by a stochastic parameter that simulates a series giving the time interval in years between two consecutive events. The model also contains a Markovian matrix that controls the location of the event and thereby what watercourse is hit by the flood. A record of Katla eruptions since the 8th and the 9th century a.d., and geological information of volcanogenic floods towards the west over the last 8,000 years is used to calibrate the model. The model is then used to find the probabilities for floods from the three sectors: Ko, So and En. The simulations predict that the most probable eruption interval for the En sector and the So sector is several times smaller than the average time interval, implying infrequent periods of high activity in these sectors. A correlation is found between the magnitude of eruptions and the following time intervals. Using the statistical approach and considering this magnitude–time interval correlation, the probability of an eruption in Katla volcano is considered to be 20% within the next 10 years. This compares to a probability of 93% if only a simple average is considered. These probabilities do not take account of long-term eruption precursors and should therefore be regarded as minimum values.     

Geochemical stability of fine-grained silicic Holocene tephra in Iceland and Scotland

This paper tests two assumptions fundamental to the use of fine-grained silicic tephras from Iceland for creating chronological frameworks in northwest Europe. It is shown firstly, that glass shards can retain their overall chemical integrity on at least a four millennial time-scale in contrasting depositional environments in Iceland and Scotland, and secondly, that an acid digestion process, the most practical method for extracting tephra from peat, does not significantly bias the results of major element analysis by electron microprobe. The implication is that there is great potential and an appropriate method for developing both the resolution and the spatial coverage of chronologies based on silicic Icelandic tephras in northwest Europe.     

Late Quaternary tephra layers around Raoul and Macauley Islands,Kermadec Arc: implications for volcanic sources,explosive volcanism and tephrochronology

A suite of deep‐sea cores were collected along transects up to 100 km across the fore‐arc and back‐arc regions of the predominantly submarine Kermadec arc near Raoul and Macauley islands, southwest Pacific. The cores reveal a macroscopic tephra record extending back >50 ka. This is a significant addition to the dated record of volcanism, previously restricted to fragmented late Holocene records exposed on the two islands. The 27 macroscopic tephra layers display a wide compositional diversity in glass (～50–78 wt% SiO₂). Many tephra layers comprise silicic shards with a subordinate mafic shard population. This could arise from magma mingling and may reflect mafic triggering of the silicic eruptions. Broadly, the glass compositions can be distinguished on diverging high‐K and low‐K trends, most likely arising from different source volcanoes. This distinction is also reflected in the tephra records exposed on Raoul (low‐K) and Macauley (high‐K) islands, the likely source areas. Heterogeneous tephra comprising shards of both high‐ and low‐K affinity, silicic and mafic compositions, and more homogeneous tephra with subordinate outlier shard compositions, are best explained by post‐depositional mixing of separate eruption deposits or contemporaneous eruptions. Evidently, the slow sedimentation rates of the calcareous oozes (～10¹–10² mm ka^?1) were insufficient to adequately separate and preserve closely spaced eruption deposits. This exemplifies the difficulty in assessing eruption frequencies and magmatic trends, and erecting a tephrostratigraphy, using geochemical fingerprinting in such environments. Despite these difficulties, the ca. 5.7 ka Sandy Bay Tephra erupted from Macauley Island can be correlated over a distance of >100 km, extending east and west of the island, showing that the mostly submerged volcanoes are capable of wide tephra dispersal. Hence there is potential for developing chronostratigraphies for the southwest Pacific beyond the region covered by the extensive rhyolite marker beds from the Taupo Volcanic Zone. Copyright © 2011 John Wiley & Sons, Ltd.     

Holocene tephra horizons at Klocka Bog,west‐central Sweden: aspects of reproducibility in subarctic peat deposits

This paper presents one of the most extensive Holocene tephra records found to date in Scandinavia. Microtephra horizons originating from Icelandic eruptions were recorded in two ca. 2 m thick peat profiles at Klocka Bog in west‐central Sweden. Five of the microtephra horizons were geochemically correlated to the Askja‐1875, Hekla‐3, Kebister, Hekla‐4 and Lairg A tephras respectively. Radiocarbon‐based dating of these tephras broadly agree with previously published ages from Iceland, Sweden, Germany and the British Isles. The identification of the Lairg A tephra demonstrates a more widespread distribution than previously thought, extending the usefulness of Icelandic Holocene tephrochronology further north into west‐central Scandinavia. Long‐lasting snow cover and seasonal wind distribution in the lower stratosphere are suggested as factors that may be responsible for fragmentary tephra deposition patterns in peat deposits of subarctic Scandinavia. Copyright © 2004 John Wiley & Sons, Ltd.     

Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

五大连池火山区气体地球化学特征

根据泉（池）水中气体的组分和同位素组成,讨论了五大连池火山区气体的来源和运移。１９９７年８月从五大连池火山区泉中采用了９个气、水样品,同年９月测定了游离气和水溶气的气体组分、Ｈｅ同位素幽会和ＣＯ２的δ＾１３Ｃ值。气体以ＣＯ２为主,多数样品的ＣＯ２体积分类大于８０％。Ｈｅ和ＣＨ４的体积分数变化范围大,分别为０．７×１０＾－６－３８０×１０＾－６和４．０×１０＾－６－１８０×１０＾－６。＾３Ｈｅ／Ｈｅ     

Hekla 1947, 1845, 1510 and 1158 tephra in Finland: challenges of tracing tephra from moderate eruptions

Several cryptotephra layers that originate from Icelandic volcanic eruptions with a volcanic explosivity index (VEI) of ≤ 4 and tephra volumes of < 1 km³ have previously been identified in Northern Europe, albeit within a restricted geographical area. One of these is the Hekla 1947 tephra that formed a visible fall-out in southern Finland. We searched for the Hekla 1947 tephra from peat archives within the previously inferred fall-out zone but found no evidence of its presence. Instead, we report the first identification of Hekla 1845 and Hekla 1510 cryptotephra layers outside of Iceland, the Faroe Islands, Ireland and the UK. Additionally, Hekla 1158 tephra was found in Finland for the first time. Our results confirm that Icelandic eruptions of moderate size can form cryptotephra deposits that are extensive enough to be used in inter-regional correlations of environmental archives and carry a great potential for refining regional tephrochronological frameworks. Our results also reveal that Icelandic tephra has been dispersed into Finnish airspace at least seven times during the past millennium and in addition to a direct eastward route the ash clouds can travel either via a northerly or a southerly transport pathway.     

Distribution,sediment magnetism and geochemistry of the Saksunarvatn (10 180 ± 60 cal. yr BP) tephra in marine,lake, and terrestrial sediments,northwest Iceland

In 1997, seismic surveys in the troughs off northwest and north Iceland indicated the presence of a major, regional sub‐bottom reflector that can be traced over large areas of the shelf. Cores taken in 1997, and later in 1999 on the IMAGES V cruise, penetrated through the reflector. In core MD99‐2269 in Húnaflóaáll, this reflector is shown to be represented by a basaltic tephra with a geochemical signature and radiocarbon age correlative with the North Atlantic‐wide Saksunarvatn tephra. We trace this tephra throughout northwest Iceland in a series of marine and lake cores, as well as in terrestrial sediments; it forms a layer 1 to 25 cm thick of fine‐ to medium‐grained basaltic volcanic shards. The base of the tephra unit is always sharp but visual inspection and other measurements (carbonate and total organic carbon weight %) indicate a more diffuse upper boundary associated with bioturbation and with sediment reworking. Off northwest Iceland the Saksunarvatn tephra has distinct sediment magnetic properties. This is evident as a dramatic reduction in magnetic susceptibility, an increase in the frequency dependant magnetic susceptibility and ‘hard’ magnetisation in a −0.1T IRM backfield. Geochemical analyses from 11 sites indicate a tholeiitic basalt composition, similar to the geochemistry of a tephra found in the Greenland ice‐core that dates to 10 180 ± 60 cal. yr BP, and which was correlated with the 9000 ¹⁴C yr BP Saksunarvatn tephra. We present accelerator mass spectrometry ¹⁴C dates from the marine sites, which indicate that the ocean reservoir correction is close to ca. 400 yr at 9000 ¹⁴C yr BP off northwest Iceland. Copyright © 2002 John Wiley & Sons, Ltd.     

Characterization and correlation of the Hegawa-Kasamori 5 tephra,a widespread tephra aged c. 450 ka associated with large-scale pyroclastic flows from southern Kyushu,SW Japan

A Middle Pleistocene widespread tephra, defined here as Hegawa-Kasamori 5 tephra (Hgw-Ks5), has been newly recognized over a broad area of Japan. Large-scale pyroclastic flow deposits associated with co-ignimbrite ash fall deposits (CAFDs) of Hgw-Ks5 have been identified in the proximal southern Kyushu area, south-west Japan. Hgw-Ks5 possibly originated from the Aira caldera in southern Kyushu, and it is widely spread and intercalated with deposits of the Kasamori Formation, Honshu Island, more than 1000 km away from the source. In the north-west area of the Aira Caldera, the tephra is sparsely distributed in the form of non-welded ignimbrites, and is exposed stratigraphically above the well-known Kobayashi-Kasamori tephra. Hgw-Ks5 is characterized through petrographic features, major element geochemistry of glass shards, and refractive indices of orthopyroxene. The results of previous stratigraphic isotope studies indicate that the eruptive age of Hgw-Ks5 is 434–458 ka (Marine Isotope Stage 12). Assuming that the CAFDs originating from the Aira Caldera are distributed concentrically, the apparent volume of Hgw-Ks5, estimated from the area of distribution and CAFD thickness, is ~100 km³. Therefore, a volcanic explosivity index of 7 is assigned to the Hgw-Ks5 eruption.