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Pavel Ya. TishchenkoDong-Jin Kang Ruslan V. ChichkinAlexander Yu. Lazaryuk Chi Shing WongWilliam Keith Johnson 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(7):778-786
This study evaluated a method to carry out underway pH measurements of surface seawater by means of a cell without liquid junction using glass electrodes for hydrogen and sodium ions as follows:
Glass-electrode-Na+ Test solution (reference solution) H+-glass-electrode - Full-size table
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The conditional acid dissociation constants (pKa′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pKa′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln−1):The estimated accuracy of pH measurements using these calculated pKa′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities. 相似文献
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Wave interaction with T-type breakwaters 总被引:1,自引:0,他引:1
The wave transmission, reflection and energy dissipation characteristics of partially submerged ‘T'-type breakwaters (Fig. 1) were studied using physical models. Regular and random waves, with wide ranges of wave heights and periods and a constant water depth were used. Five different depths of immersions of the ‘T'-type breakwater were selected. The coefficient of transmission, Kt, coefficient reflection, Kr, were obtained from the measurements and the coefficient of energy loss, Kl is calculated using the law of conservation of energy. It is found that the coefficient of transmission generally reduces with increased wave steepness and increased relative water depth, d/L. This breakwater is found to be effective closer to deep-water conditions. Kt values less than 0.35 is obtained for both normal and high input wave energy levels, when the horizontal barrier of the T type breakwater is immersed to about 7% of the water depth. This breakwater is also found to be very efficient in dissipating the incident wave energy to an extent of about 65% (i.e. Kl>0.8), especially for high input wave energy levels. The wave climate in front of the breakwater is also measured and studied.
Fig. 1. Schematic view of the T-type breakwater. 相似文献
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The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2