Imprinting chemical remanent magnetization in claystones at 95 °C

Thermal effects related to burial and hydrothermal alteration leads to chemical remanent magnetization (CRM). We present an experimental study of CRM production by heating claystones at 95 °C. A vertical magnetic field of 2 mT was applied to the claystones during heating and the evolution of the remanence during heating in air is monitored intermittently for up to four months. Solid fragments (9 to 26 g) of claystones are included in a Teflon holder that is placed in the oven under a controlled atmosphere. Newly formed grains acquire a CRM and a thermoviscous magnetization (TVRM), both being parallel to the applied magnetic field. CRM is related to the amount of newly formed grains that pass the critical volume during the reaction. To measure the acquired remanence, the claystones are first cooled in a zero magnetic field and then measured using a 2G SQUID magnetometer.In the frame of the research programme on the feasibility of radioactive waste disposal in a deep geological formation, we investigate the magnetic transformation of Mont Terri Lower Dogger claystones (Switzerland) due to thermal imprinting at 95 °C. We simulate the dehydration that occurs in the walls of galleries after excavation when interstitial water evaporates and rehydration when the galleries are refilled allowing water to move towards dehydrated zones. During dehydration, the remanence gains one order of magnitude at the beginning of the experiment and then it follows a linear rate of 0.23 ± 0.07 mA m^− 1/day between 3 and 14 days. The magnetic susceptibility increases by a few percent. The increase of the remanence and of the magnetic susceptibility stops after 15 days. Mass monitoring indicates that interstitial water evaporates when remanence and magnetic susceptibility stabilizes. During rehydration, the remanence increases again whilst magnetic susceptibility drops by a few percent. After 20 days, the remanence during rehydration follows a rate of 0.42 ± 0.15 mA m^− 1/day. By contrast, when rehydration takes place later, after 66 days, the rate is much lower (0.09 ± 0.04 mA m^− 1/day). Low temperature investigation of magnetic properties indicates an initial magnetic assemblage of magnetite and pyrrhotite. Newly formed magnetite and hematite carry the remanence. We propose that magnetite is formed at the expense of pyrite. Hematite results from the progressive oxidation of newly formed magnetite. Our results suggest the possibility that any claystones that pass the oil window can be remagnetized due to the unique action of temperature.     

Secondary remanent magnetization carried by magnetite inclusions in silicates: a comparative study of unremagnetized and remagnetized granites

Magnetic carriers in remagnetized Cretaceous granitic rocks of northeast Japan were studied using paleomagnetism, rock magnetism, optical microscopy and scanning electron microscopy (SEM) by comparison with unremagnetized granitic rocks. The natural remanent magnetization (NRM) of the remagnetized rocks is strong (0.3–1.7 A/m) and shows a northwesterly direction with moderate inclination (NW remanence), whereas the unremagnetized rocks preserve weak NRM (<0.5 A/m) with westerly and shallow direction (W remanence). Although thermal demagnetization shows that both NRMs are carried by magnetite, the remagnetized rocks reveal a higher coercivity with respect to alternating field demagnetization (20 mT相似文献   

Analysis of the natural remanent magnetization of rocks by measuring the efficiency ratio through alternating field demagnetization spectra

The REM(AF) method is a new tool for the analysis of the origin and alternating field demagnetization coercivity spectra of the remanent magnetization. We applied this method on precambrian Gila diabase sheets from Arizona in order to identify the high coercivity magnetic carrier, and on artificially shocked Rowley Regis basalt from UK in order to analyze the effect of the shock on the natural remanent magnetization. In the Gila diabase the high coercivity magnetic component was identified to be most likely represented by the acicular magnetite (increase in the efficiency ratio in the high coercivity region). In the Rowley Regis basalt, the REM(AF) analysis revealed that comparing to NRM, the shock produced a different distribution of the AF demagnetization coercivity spectra due to the occurrence of the Shock Remanent Magnetization.     

河西走廊早新生代红层次生剩磁及其对原生剩磁影响评价

系统研究了河西走廊火烧沟组陆相红层200个采点岩石的热退磁行为和17个代表性样品的岩石磁学特征,结果表明有102个采点可以分离出A、B、C三个剩磁分量,有82个采点只有一个分量(C分量),16个采点只能分离出A、B分量.A、B分量分别由针铁矿和磁赤铁矿携带,C分量在砂岩中由磁铁矿携带,在泥质砂岩和泥岩中由磁铁矿和赤铁矿共同携带.A、B分量剩磁方向随机分布,不能获得置信水平的古地磁平均方向,为次生剩磁.它们的存在并不影响岩石原生剩磁的分离,也不影响原生剩磁信号的稳定性和获得的古地磁数据的可靠性.16个砂岩采点中不能分离出C分量,是由于后生的赤铁矿彻底改变了由磁铁矿携带的原生剩磁组分,在高密度采样的情况下剔除这些采点并不影响古地磁极性柱的构建和解释.     

岩石磁组构对剩磁稳定性的制约探讨:以印支地块中生代碎屑岩和拉萨林周盆地设兴组红层为例

岩石磁组构因能提供磁性矿物晶体形状、排列方式等赋存信息而被广泛应用于判别岩石剩磁是否受到了后期构造应力的显著影响; 但常规岩石磁化率各向异性(AMS)是否能够准确限定岩石剩磁的稳定性, 目前尚无深入探讨.本文以印支地块Nakhon Thai盆地中生代Nam Phong、Phu Kradung和Phra Wihan组三套碎屑岩样品及拉萨地块林周盆地设兴组红层样品为例, 通过岩石磁化率组构和剩磁组构的对比分析发现, 尽管Nam Phong组绝大多数样品和Phu Kradung组全部样品的AMS组构显示其具有铅笔状至强劈理过渡型构造变形组构特征, 但高场等温剩磁各向异性(hf-AIR)显示其高矫顽力赤铁矿所携带的特征剩磁组构仍具有典型沉积组构特征, 表明其以赤铁矿为主的载磁矿物未遭受后期构造应力的显著影响, 仍然能够准确记录岩石形成时期的古地球磁场方向.另一方面发现有且仅有剩磁组构才是判别碎屑沉积岩特征剩磁是否遭受了后期构造应力影响的充分必要条件.也就是说, 如果岩石剩磁组构(如以赤铁矿为主要载磁矿物的岩石hf-AIR组构)指示其原始沉积组构已被构造组构显著叠加或取代, 则必然说明该岩石剩磁方向已受到构造应力的作用而发生了显著偏转, 因而不能直接用于构造演化和古地理重建等块体运动学研究.

     

河南平顶山平煤矿区天然地震、爆破、塌陷时频特征分析

选取2019年3月—8月河南平顶山市宝丰县平煤矿区发生的ML 2.0—2.9天然地震、爆破、塌陷等9次震动事件,在区域地质构造背景和波形特征分析基础上,采用短时傅里叶变换(STFT)方法开展时频波谱分析,提取不同类型事件的时频特征。结果显示:(1)天然地震频率成分丰富,且高、低频分布均匀,P波在约3 Hz和8 Hz处存在2个峰值,S波存在多个峰值;(2)爆破事件的时频谱相对集中,以低频为主,P波频率峰值约5Hz,信号主频随时间变化,大致呈线性降低至1—2 Hz;(3)塌陷事件频率成分以4 Hz以下的低频为主,P波无明显峰值且频率成分单一,主频出现在2 Hz左右的面波。本文结果可为今后该矿区震动事件类型判断提供参考依据。     

鲁科一井上白垩统沉积岩岩石磁学和天然剩磁分析:兼论利用剩磁方向恢复钻孔岩芯原始方位的可行性

本文对"鲁科一井"（CCSD-LK-Ⅰ）768.9~1112.3 m之间的上白垩统沉积岩样品进行了岩石磁学、磁化率各向异性（AMS）以及天然剩磁组分的研究.在此基础上,分析了利用特征剩磁（ChRM）和黏滞剩磁（VRM）方向恢复岩芯原始方位的可行性.三轴等温剩磁热退磁曲线、磁滞回线、反向场退磁曲线、一阶反转曲线等岩石磁学测量结果表明,沉积岩的主要载磁矿物为磁铁矿和赤铁矿.335块样品的AMS测量结果表明磁化率椭球主轴的最大轴K1和中间轴K2与水平面夹角较小,最小轴K3接近垂直于水平面分布,说明沉积岩保留了原始沉积磁组构特征.系统热退磁实验表明,多数样品在25~350℃和500~690℃温度段分别获得VRM和ChRM分量.利用ChRM偏角方向,并考虑构造旋转量校正,对VRM偏角方向进行恢复,Fisher统计得到DVRM=-1.3°,IVRM=59.6°,与当地现代地磁场方向（D=-6.7°,I=53.9°）基本一致.用ChRM偏角方向对磁化率主轴K1偏角方向进行校正,校正的结果为：Dch_K1=349.2°,Ich_K1=-0.7°.本文研究结果对于地质勘探中利用古地磁学方法恢复钻孔岩芯原始方位具有一定参考意义.     

On the correction of spectra by a displacement reduction factor in direct displacement-based seismic design and assessment

The application of some design and assessment approaches, such as the direct displacement-based design (DDBD) and the capacity spectrum methods, requires the modification of elastic design spectra by some displacement reduction factor, to account for the appropriate energy dissipation capacity of different structures. While several equations to correlate dissipation and hysteresis cycles are available, once the displacement reduction factor has been obtained, the correction of the spectra is operated reducing the displacement demand accordingly and conserving the period of vibration at each point. This procedure is here discussed and proved to be conceptually inappropriate, because the spectral acceleration rather than the period should be kept at each point. The application of this alternative procedure may result in increased shear strength demand in design and in larger required displacement capacity for the same level of strength in assessment, if all other factors are not modified. However, the calibration of the reduction factors applied in DDBD has been extensive, and the method has proved to be effective in predicting displacement demands consistent with those resulting from refined nonlinear time history analysis; therefore, a possible introduction of the proposed correction will require equally extensive studies and possibly compensating corrections in the calculation of the equivalent damping. On the contrary, an appropriate calibration of the factors to be used in the application of the “capacity spectrum” method is still being developed, and the consideration of a constant acceleration may facilitate the derivation of effective equations.     

Multiple injected and natural conservative tracers quantify mixing in a stream confluence affected by acid mine drainage near Silverton,Colorado

The acidic discharge from Cement Creek, containing elevated concentrations of dissolved metals and sulphate, mixed with the circumneutral‐pH Animas River over a several hundred metre reach (mixing zone) near Silverton, CO, during this study. Differences in concentrations of Ca, Mg, Si, Sr, and SO₄^2? between the creek and the river were sufficiently large for these analytes to be used as natural tracers in the mixing zone. In addition, a sodium chloride (NaCl) tracer was injected into Cement Creek, which provided a Cl^? ‘reference’ tracer in the mixing zone. Conservative transport of the dissolved metals and sulphate through the mixing zone was verified by mass balances and by linear mixing plots relative to the injected reference tracer. At each of seven sites in the mixing zone, five samples were collected at evenly spaced increments of the observed across‐channel gradients, as determined by specific conductance. This created sets of samples that adequately covered the ranges of mixtures (mixing ratios, in terms of the fraction of Animas River water, %AR). Concentratis measured in each mixing zone sample and in the upstream Animas River and Cement Creek were used to compute %AR for the reference and natural tracers. Values of %AR from natural tracers generally showed good agreement with values from the reference tracer, but variability in discharge and end‐member concentrations and analytical errors contributed to unexpected outlier values for both injected and natural tracers. The median value (MV) %AR (calculated from all of the tracers) reduced scatter in the mixing plots for the dissolved metals, indicating that the MV estimate reduced the effects of various potential errors that could affect any tracer. Copyright © 2006 John Wiley & Sons, Ltd.