Natural background levels for some ions in groundwater of the Campania region (southern Italy)

The aim of the study was the determination of the natural background levels (NBLs) for the ions Na⁺, Cl^?, SO₄ ^2?, As³⁺, F^?, Fe²⁺, and Mn²⁺, in some groundwater bodies of the Campania region (southern Italy). The ??Protocol to evaluate the natural background concentrations?? proposed in 2009 by ISPRA (Italian Institute for Environmental Protection and Research) has been applied to the chemical data set of groundwater of the examined groundwater bodies. These analyses have also been examined following the guidelines of the BRIDGE project (Background cRiteria for the IDentification of Groundwater thrEshold). These approaches to evaluate the Threshold Values (TVs) and the NBLs, based on probability distribution functions, have been applied in many countries by various authors during the last 5?years. Changes applied to ISPRA Protocol in this study concern mainly the preselection criteria, in particular threshold values of specific ions, deriving from the aquifers geochemical features. The preselection criteria of the ISPRA Protocol have been merged with those of the BRIDGE Project in order to define a procedure suitable for the definition of the NBLs in the examined aquifers. The NBL of fluoride for the ??Phlegrean Fields?? and the ??eastern Plain of Naples?? groundwater bodies shows values deeply exceeding the reference value (REF) of 1,500???g/L, ranging between 3,600 and 15,000???g/L. The cause of this very high fluoride content is in the natural features of the aquifers constituted by volcanic and pyroclastic rocks. The volcanic origin of the aquifers is also the reason for the high arsenic content in ??Phlegrean Fields?? groundwater. Here the NBL calculated was about 47???g/L against the drinking water standard value of 10???g/L. The widespread high content of manganese and iron for the groundwater body of the ??eastern Plain of Naples?? is due to the reducing conditions related to the extensive marshlands present in the past. The very high NBL of all the examined ions for the groundwater body of ??Ischia Island?? depends on the existence of a geothermal system.     

Raw Materials for Archaeological Pottery from the Campania Region of Italy: A Petrophysical Characterization

We performed petrophysical analyses on 34 clayey samples of different geological origin within the Campania region of Italy in order to determine possible sources of raw materials used to produce ancient pottery. Possible raw material sources can be grouped into high‐CaO clays (HCC) and low‐CaO clays (LCC). HCC are mainly represented by more recent (Miocene‐Pleistocene) basinal sediments whereas LCC tend to be associated with basinal, alluvial, and pyroclastic deposits. A chemical comparison between clayey raw materials, modern ceramic replicas, and Campanian archaeological ceramics of several typologies (common ware, cooking ware, fine tableware, amphorae, and bricks) from 8th century B.C. to the Middle Ages (a total of 350 ceramic samples) indicates that HCC were extensively used for common wares and that these were either mixed with temper or levigated. In contrast, most of the LCC were used for the production of cookware. We also analyzed the technological potential of the sampled raw materials, taking into consideration their actual and possible uses. We observed that most HCC deposits were well suited for tableware and amphorae, whereas LCC were better for cookware and some fine tableware.     

Rainfall induced debris flows in pyroclastic deposits, Campania (southern Italy)

A combination of empirical and physically based hydrological models has been used to analyze historical data on rainfall and debris-flow occurrence in western Campania, to examine the correlation between rainfall and debris-flow events.

Rainfall data from major storms recorded in recent decades in western Campania were compiled, including daily series from several rain gauges located inside landslide areas, supplemented by hourly rainfall data from some of the principal storms.

A two-phase approach is proposed. During phase 1, soil moisture levels have been modelled as the hydrological balance between precipitation and evapotranspiration, on a daily scale, using the method of Thornthwaite [Geograph. Rev. 38 (1948) 55].

Phase 2 is related to the accumulation of surplus moisture from intense rainfall, leading to the development of positive pore pressures. These interactions take place on an hourly time scale by the “leaky barrel” (LB) model described by Wilson and Wiezoreck [Env. Eng. Geoscience, 1 (1995) 11]. In combination with hourly rainfall records, the LB model has been used to compare hydrological effects of different storms. The critical level of retained rain water has been fixed by the timing of debris-flow activity, related to recorded storm events.

New rainfall intensity–duration thresholds for debris-flow initiation in western Campania are proposed. These thresholds are related to individual rain gauge and assume a previously satisfied field capacity condition. The new thresholds are somewhat higher than those plotted by previous authors, but are thought to be more accurate and thus need less conservatism.     

Individual and societal risk owing to landslides in the Campania region (southern Italy)

This paper deals with the estimation of both individual and societal risks owing to landslides in the Campania region (southern Italy) thanks to the availability of an extensive catalogue of historical incident data spanning from the 5^th century up to now. Individual risk is estimated by computing the landslide mortality rate. Societal risk is measured by plotting the annual frequency F of events causing N or more fatalities against the number N of fatalities (i.e. an F–N curve). The results obtained show that in Campania both individual and societal risks owing to landslides are very high when compared to similar risks of the Italian territory. Moreover, the analysis of the incident data clearly highlights the most prone areas to catastrophic events, essentially related to the occurrence of flow-like fast-moving phenomena, where the societal risk is proved to be one of the highest in Europe.     

Rockfall hazard assessment along a road in the Sorrento Peninsula,Campania, southern Italy

Rockfalls are common in the steep and vertical slopes of the Campania carbonate massifs and ridges, and frequently represent the main threat to the anthropogenic environment, potentially damaging urban areas, scattered houses, roads, etc. Despite the generally limited volumes involved, the high velocity of movement (from few to tens of metres per second) poses rockfalls among the most dangerous natural hazards to man. Evaluating the rockfall hazard is not an easy task, due to the high number of involved factors, and particularly to the difficulty in determining the properties of the rock mass. In this paper, we illustrate the assessment of the rockfall hazard along a small area of the Sorrento Peninsula (Campania region, southern Italy). Choice of the site was determined by the presence of a road heavily frequented by vehicles. In the area, we have carried out detailed field surveys and software simulations that allow generating simple rockfall hazard maps. Over twenty measurement stations for geo-mechanical characterization of the rock mass have been distributed along a 400-m-long slope of Mount Vico Alvano. Following the internationally established standards for the acquisition of rock mass parameters, the main kinematics have been recognized, and the discontinuity families leading to the different failures identified. After carrying out field experiments by artificially releasing a number of unstable blocks on the rock cliff, the rockfall trajectories along the slope were modelled using 2-D and 3-D programs for rockfall analysis. The results were exploited to evaluate the rockfall hazard along the threatened element at risk.     

Rapid terrain-based mapping of some volcaniclastic flow hazard using Gis-based automated methods: a case study from southern Campania,Italy

Destructive volcaniclastic flows are among the most recurrent and dangerous natural phenomena in volcanic areas. They can originate not only during or shortly after an eruption (syn-eruptive) but also during a period of volcanic quiescence (inter-eruptive), when heavy and/or persistent rains remobilize loose pyroclastic deposits. The area in Italy most prone to such flows is that of the Apennine Mountains bordering the southern Campania Plain. These steep slopes are covered by pyroclastic material of variable thickness (a few cm to several m) derived from the explosive activity of the Somma-Vesuvius and Campi Flegrei volcanoes a few tens of kilometers to the west. The largest and most recent devastating event occurred on May 5, 1998, causing the death of more than 150 people and considerable damage to villages at the foot of the Apennine Mountains. This tragic event was only the most recent of a number of volcaniclastic flows affecting the area in both historical and prehistoric times. Historical accounts report that more than 500 events have occurred in the last five centuries and that more than half of these occurred in the last 100 years, causing hundreds of deaths. In order to improve volcaniclastic flow hazard zonation and risk mitigation in the study area, we produced a zonation map that identifies the drainage basins potentially prone to disruption. This map was obtained by combining morphological characteristics (concavity and basin shape factor) and the mean slope distribution of drainage basins derived from a digital elevation model with a 10-m resolution. These parameters allowed for the classification of 1,069 drainage basins, which have been grouped into four different classes of proneness to disruption: low, moderate, high and very high. The map compiled in a GIS environment, as well as the linked database, can be rapidly queried.     

Seasonal effects of rainfall on the shallow pyroclastic deposits of the Campania region (southern Italy)

The shallow deposits of unsaturated pyroclastic soils covering the slopes in the Campania region (southern Italy) are systematically affected by various rainfall-induced slope instabilities. The type and triggering of these instabilities depend on several factors, among which in situ soil suction—as an initial condition—and rainfall—as a boundary condition—play a fundamental role. Based on the available database—which includes a comprehensive catalogue of historical data, in situ soil suction measurements and soil laboratory tests along with the results of geomechanical analyses—this paper discusses the relationships among in situ soil suction and rainfall conditions and induced slope instability types. The goal is to reach a better understanding of past events and gain further insight into the analysis and forecasting of future events. In particular, the paper outlines how the season strongly affects the spatial distribution and the type of slope instability likely to develop. For example, erosion phenomena essentially occur at the end of the dry season and originate hyperconcentrated flows while first-time shallow slides prevail in the rainy season and later propagate as debris flows or as debris avalanches.     

Discovering the stone heritage of southern Italy: technical properties of the Mondragone marble from Campania region

The results of the geological characterization of an old stone building in southern Italy, are presented here. The Mondragone marble is a slightly metamorphosed carbonate rock, which was widely employed as monumental stone in the 18th century Royal Palaces of Naples and Caserta. In this paper, for the first time, this rock has been investigated with a thorough laboratory testing program, aimed at defining its mineralogical, physical and mechanical parameters. The two most important varieties of Mondragone marble were separately tested: the yellow and grey marbles (hereafter, YM and GM, respectively). The results obtained from physical tests (open porosity, dry density, specific gravity, water absorption coefficients, ultrasonic velocity) did not show marked differences between the two materials; in contrast, the mechanical strength tests (uniaxial compressive strength, point load strength, flexural strength) showed better behaviour of YM than for GM. After a tentative comparison with other well known carbonate rocks from Italy, some considerations on the response of Mondragone marble to local weathering were conducted. In particular, the weathering typologies were related to the particular texture of the brecciated marble and the different strength resistances displayed by the various constituents of the rock.     

A study of the correlation between electrical resistivity and matric suction for unsaturated ash-fall pyroclastic soils in the Campania region (southern Italy)

In the territory of the Campania region (southern Italy), critical rainfall events periodically trigger dangerous fast slope movements involving ashy and pyroclastic soils originated by the explosive phases of the Mt. Somma-Vesuvius volcano and deposited along the surrounding mountain ranges. In this paper, an integration of engineering-geological and geophysical measurements is presented to characterize unsaturated pyroclastic samples collected in a test area on the Sarno Mountains (Salerno and Avellino provinces, Campania region). The laboratory analyses were aimed at defining both soil water retention and electrical resistivity curves versus water content. From the matching of the experimental data, a direct relationship between electrical resistivity and matric suction is retrieved for the investigated soil horizons typical of an ash-fall pyroclastic succession. The obtained relation turns out to be helpful in characterizing soils up to close saturation, which is a critical condition for the trigger of slope failure. In such a regime, the water content and the matric suction have small variations, while electrical resistivity variations can be appreciated in a larger range of values. For this reason, besides suction measurements on very small soil volumes through classical tensiometers, our analyses suggest the direct monitoring of in situ electrical resistivity values as an effective tool to recognise the hydrological state of larger and more representative soil volumes and to improve early warning of dangerous slope movements.     

Activity maps of multi-source mudslides from the Daunia Apennines (Apulia,southern Italy)

Natural Hazards - Flooding poses a serious public health hazard throughout the world. Flood modeling is an important tool for emergency preparedness and response, but some common methods require a...     

Trace-element behavior during weathering of leucite in potassic rocks from the Roccamonfina volcano (Campania, southern Italy) and environmental implications

Trace-element contents in leucite and its alteration mineral phases from the Quaternary potassic rocks of the Roccamonfina volcano have been determined. The dominant weathering phase of leucite is analcite. In the early stages of the conversion process, it concentrates mainly Rb and Sr with minor amounts of Ba, Ni, V, Zn, La, Ce and Zr. At more advanced stages of the conversion process, only Rb and Y persist, while all other elements (except Cu and Cr that are essentially immobile) are lost, particularly Zn and to a lesser extent La, Ce and Nd. Besides analcite, leucite may also subordinately alter to halloysite. This probably occurs by interaction of waters of low cation/H⁺ ratio. Halloysite concentrates mainly Sr and, to a lower extent, Ba. Environmental implications are significant only for K, as the release of this element to groundwaters increases greatly the fertility of soils.     

Influence of man-made cuts on the stability of pyroclastic covers (Campania,southern Italy): a numerical modelling approach

Intense rainfall in May 1998 and December 1999 caused disastrous landslides in the Sarno-Quindici and Cervinara areas (Campania, southern Italy). The landslides began with slips of the local pyroclastic covers mantling the carbonate relief and then evolved into debris flows/avalanches. The study discussed in this paper used a numerical modelling approach to assess the influence of man-made cuts on the stability conditions of pyroclastic covers. The model that was developed took into account initial failure conditions in order to better simulate the impact of man-made cuts along the slopes, with or without water seepage into the permeable pumiceous layers of the pyroclastic multilayer. Numerical analysis of stress-strain field clearly showed that tracks or geomorphological discontinuities had a negative impact on the multilayer stability conditions. Consequently, preservation of this vulnerable environment requires correct forest management practices.     

Effect of antecedent-hydrological conditions on rainfall triggering of debris flows in ash-fall pyroclastic mantled slopes of Campania (southern Italy)

Mountainous areas surrounding the Campanian Plain and the Somma-Vesuvius volcano (southern Italy) are among the most risky areas of Italy due to the repeated occurrence of rainfall-induced debris flows along ash-fall pyroclastic soil-mantled slopes. In this geomorphological framework, rainfall patterns, hydrological processes taking place within multi-layered ash-fall pyroclastic deposits and soil antecedent moisture status are the principal factors to be taken into account to assess triggering rainfall conditions and the related hazard. This paper presents the outcomes of an experimental study based on integrated analyses consisting of the reconstruction of physical models of landslides, in situ hydrological monitoring, and hydrological and slope stability modeling, carried out on four representative source areas of debris flows that occurred in May 1998 in the Sarno Mountain Range. The hydrological monitoring was carried out during 2011 using nests of tensiometers and Watermark pressure head sensors and also through a rainfall and air temperature recording station. Time series of measured pressure head were used to calibrate a hydrological numerical model of the pyroclastic soil mantle for 2011, which was re-run for a 12-year period beginning in 2000, given the availability of rainfall and air temperature monitoring data. Such an approach allowed us to reconstruct the regime of pressure head at a daily time scale for a long period, which is representative of about 11 hydrologic years with different meteorological conditions. Based on this simulated time series, average winter and summer hydrological conditions were chosen to carry out hydrological and stability modeling of sample slopes and to identify Intensity-Duration rainfall thresholds by a deterministic approach. Among principal results, the opposing winter and summer antecedent pressure head (soil moisture) conditions were found to exert a significant control on intensity and duration of rainfall triggering events. Going from winter to summer conditions requires a strong increase of intensity and/or duration to induce landslides. The results identify an approach to account for different hazard conditions related to seasonality of hydrological processes inside the ash-fall pyroclastic soil mantle. Moreover, they highlight another important factor of uncertainty that potentially affects rainfall thresholds triggering shallow landslides reconstructed by empirical approaches.     

Susceptibility regional zonation of earthquake-induced landslides in Campania,Southern Italy

In this paper, we present a GIS-based method for regional zoning of seismic-induced landslide susceptibility and show its application to the territory of the Campania region, Southern Italy. The method employs only three factors that we believe are most significant in the susceptibility assessment: the type of outcropping rock/soil, the slope angle, and the MCS intensity. Each of the three parameters is quantified in terms of relative weight expressed as indices, and the resulting Seismic Landslide Susceptibility index of an area is given by the average of the indices of the first two factors multiplied by the index of the third factor. The result of this susceptibility zonation applied to Campania shows a good agreement between the distribution of the historical earthquake-triggered landslides and the highly susceptible zones.     

Probabilistic seismic hazard maps for the sultanate of Oman

This study presents the results of the first probabilistic seismic hazard assessment (PSHA) in the framework of logic tree for Oman. The earthquake catalogue was homogenized, declustered, and used to define seismotectonic source model that characterizes the seismicity of Oman. Two seismic source models were used in the current study; the first consists of 26 seismic source zones, while the second is expressing the alternative view that seismicity is uniform along the entire Makran and Zagros zones. The recurrence parameters for all the seismogenic zones were determined using the doubly bounded exponential distribution except the zones of Makran, which were modelled using the characteristic distribution. Maximum earthquakes were determined and the horizontal ground accelerations in terms of geometric mean were calculated using ground-motion prediction relationships developed based upon seismic data obtained from active tectonic environments similar to those surrounding Oman. The alternative seismotectonic source models, maximum magnitude, and ground-motion prediction relationships were weighted and used to account for the epistemic uncertainty. Hazard maps at rock sites were produced for 5?% damped spectral acceleration (SA) values at 0.1, 0.2, 0.3, 1.0 and 2.0?s spectral periods as well as peak ground acceleration (PGA) for return periods of 475 and 2,475?years. The highest hazard is found in Khasab City with maximum SA at 0.2?s spectral period reaching 243 and 397?cm/s² for return periods 475 and 2,475 years, respectively. The sensitivity analysis reveals that the choice of seismic source model and the ground-motion prediction equation influences the results most.     

Lava stones from Neapolitan volcanic districts in the architecture of Campania region,Italy

Results of a research carried out on the lavas from Campi Flegrei and Somma-Vesuvius volcanic districts are reported here. The lavas have been widely employed, since Roman age, in several important monumental buildings of the Campania region, mainly in the town of Naples and in its province. They are classified as trachytes (Campi Flegrei products), tephri-phonolites and phono-tephrites (Somma-Vesuvius complex) from a petrographical point of view. Sampling was carried out from well-known exploitation districts. A substantial chemical difference between the products of the two sectors was confirmed, while petrophysical characterization evidenced similarity among the two different materials, although some differences were recorded even in samples coming from the same exploitation site.     

On macroseismic attenuation parameters in the comparison of theoretical seismic hazard maps for Southern Calabria and Eastern Sicily (Southern Italy)

For two different zonations of the Calabro-Sicilian region the macroseismic intensity attenuation parameters are computed using the Grandori model.Some modifications to this relation are proposed here in order to allow its applicability also to those cases in which the data set available for each source zone does not present three successive epicentral intensity levels (I ₀) as required for its application.Maps of theoretical distribution of maximum expected intensities were plotted for both zonations adopted, in order to test the reliability, also using other attenuation models.The results of the analysis show how the proposed modifications to the Grandori relation allow the macroseismic intensity attenuation modelling even in cases in which only one intensity level is available.Finally, the comparison of theoretical maximum expected intensity distribution maps, computed for different attenuation models and seismogenic zonations, shows that the maps plotted using the Grandori model and the zonation adopted by G.N.D.T. (Gruppo Nazionale Difesa dai Terremoti - C.N.R. Italy) are more reliable.     

Stratigraphic architecture and anthropic impacts on subsoil to assess the intrinsic potential vulnerability of groundwater: the northeastern Campania Plain case study, southern Italy

This study attempts to assess the aquifer vulnerability in the northeastern sector of the Campania Plain (southern Italy). The area is a highly populated region with anthropic impacts caused by rapid urban growth, quarrying, agricultural and industrial activities and uncontrolled waste storage. The main geologic feature of this plain is the alternation of alluvial/transitional and volcaniclastic deposits of Late Pleistocene–Holocene age. The study was performed integrating different sets of geologic and environmental data to restore the stratigraphic architecture and to assess anthropic impacts on subsoil. The reconstruction of stratigraphic subsurface architecture was based on remarkable geodatabase, concerning well log stratigraphies. Specific insights have been delineated on the volcaniclastic lithofacies heteropies across the entire area of study to highlight the differences in lithification degree and permeability. The contribution of pedogenesis on the reconstruction of the stratigraphic setting was also considered for the relative implications on groundwater quality concerns, as paleosols are usually regarded as aquitards. All of this information has been managed into a GIS project to produce a detailed 3D geological reconstruction, integrated with hydrogeological information to provide a model of the aquifer under study, highlighting sites of greater vulnerability to pollution. The anthropic impacts on subsoil were assessed by evaluating land-uses and overlaying the ANHI (Agricultural Nitrate Hazard Index) Map. The integration of the above datasets has allowed to check the reliability of the previsional empirical model with respect to the hydrostratigraphic model based on a thorough stratigraphic model and to verify the real potential of contamination.     

Analysis of seismic hazard in landslide-prone regions: criteria and example for an area of Daunia (southern Italy)

In relation to the assessment of earthquake-induced landslide hazard, this paper discusses general principles and describes implementation criteria for seismic hazard estimates in landslide-prone regions. These criteria were worked out during the preparation of a hazard map belonging to the official Italian geological cartography and they are proposed as guidelines for future compilation of similar maps. In the presented case study, we used a procedure for the assessment of seismic hazard impact on slope stability adopting Arias intensity Ia as seismic shaking parameter and critical acceleration a _c as parameter representing slope strength to failures induced by seismic shaking. According to this procedure, after a preliminary comparison of estimated historical maximum values of Ia with values proposed in literature as landslide-triggering thresholds, a probabilistic approach, based on the Newmark’s model, is adopted: it allows to estimate the minimum critical acceleration a _c required for a slope to keep under a prefixed value, the probability of failures induced by seismic shakings expected in a given time interval. In this way, one can prepare seismic hazard maps where seismic shaking is expressed in an indirect way through a parameter (the critical acceleration) representing the “strength” that seismic shakings mobilise in slope materials (strength demand) with a prefixed exceedance probability. This approach was applied to an area of Daunia (Apulia—southern Italy) affected by frequent landslide phenomena. The obtained results indicate that shakings with a significant slope destabilisation potential can be expected particularly in the north-western part of the area, which is exposed to the seismic activity of Apennine tectonic structures.