郯庐断裂带肥东段剪切活动锆石U-Pb测年

郯庐断裂带肥东段出露的桃源韧性剪切带内发育有长英质超糜棱岩、长英质伟晶岩脉体等。这两种构造岩与剪切带呈现不同的穿切关系, 分别代表着剪切活动不同时期的产物, 它们可以为郯庐断裂带的剪切年限提供重要的年代学制约。本次研究从长英质超糜棱岩的U-Pb锆石测年得出了133.3±4.1 Ma的变质锆石年龄。结合笔者先前得出的伟晶岩脉129±3.3 Ma年龄判断, 郯庐断裂带在133 Ma左右有一次剪切活动, 该次剪切活动在129 Ma左右仍有着较弱的持续, 指示肥东地区在137~126 Ma的时间段内, 有一次挤压活动叠加。此外, 长英质超糜棱岩样品中捕获的1.9 Ga和2.4 Ga的锆石, 很可能来自华南板块基底。     

肥东花岗质岩脉的变形及年代学特征对郯庐断裂带早白垩世构造活动的指示

郯庐断裂带肥东段位于大别造山带与苏鲁造山带之间。在肥东段西韦采石场内发育了大规模的北北东向左行走滑韧性剪切带和一条低角度的韧性滑脱正断层。走滑韧性剪切带为郯庐断裂带走滑活动的产物,低角度滑脱正断层则代表了伸展背景下的构造活动。低角度滑脱正断层上、下盘发育未变形和变形的岩脉,走滑韧性剪切带内外也发育有受剪切带活动而变形的岩脉。对采石场内岩脉的构造和同位素年代学研究表明,低角度韧性滑脱正断层在129~126Ma之间发生过剪切活动,走滑韧性剪切带的活动时间在125Ma之后。综合研究认为,郯庐断裂带的伸展活动可能开始于早白垩世早期(130Ma),但在早白垩世并非一直处于伸展活动之中,125Ma之后的左行走滑活动很可能发生在早白垩世的晚期。     

郯庐断裂带肥东段早白垩世中期走滑运动的年代学证据

郯庐断裂带肥东段西韦地区和桃花源地区出露了大规模的北北东向韧性剪切带。桃花源地区韧性剪切带显示出2期构造变形的叠加。野外构造和显微构造分析皆指示为左行走滑韧性剪切带。糜棱岩中石英与长石的变形行为指示其变形温度分别为400~450℃和500℃。通过对这两处走滑剪切带内糜棱岩化花岗岩脉的锆石LA-ICP-MS定年,获得了3个样品的侵位年龄分别为(133.2±1.9)Ma,(131.3±2.0)Ma,(130.3±2.0)Ma。再结合已有的研究成果,认为在128~124Ma(早白垩世中期)郯庐断裂带发生过左行走滑活动。综合分析表明,郯庐断裂带在晚侏罗世和早白垩世中期分别经历了2期左行走滑活动,而期间和之后的早白垩世则处于伸展活动之中。伸展活动持续较长,控制发育了西侧的合肥盆地及断裂带内一系列岩浆活动;而区域挤压背景下出现的走滑活动则相对短暂。这些演化规律显示该断裂带在晚侏罗世—早白垩世呈现为交替式的走滑和伸展活动。新发现的早白垩世中期走滑活动,与太平洋区伊泽纳崎板块板块运动方向的调整相对应,是大洋板块运动方向短暂调整的构造响应。     

郯庐断裂带肥东韧性剪切带的变形规律同位素年龄及其构造意义

郯庐断裂带肥东韧性剪切带的几何学形态为一正花状左行平移断裂带，目前出露的为该韧性剪切带的根部，具有典型的深层次左行走滑变形特征，肥东韧性剪切带中糜棱岩，超糜棱岩测得的^40Ar/^39Ar全岩年龄分别为120.48Ma和118.75Ma，说明郯庐断裂带的大规模左行平移时代为早白垩世，对该带构造变形和构造叠加的研究表明，肥东浮槎山一带是被郯庐断裂带截切，牵引，叠加，改造的印支期大别一胶南造山带的残块，郯庐断裂带与大别-胶南造山带是不同时期，不同构造系统的产物，前者属于滨太平洋构造系统，后者属于特提斯构造系统。     

郯庐断裂带热年代学信息及其与大别造山带折返的关系

大别山东缘早期郯庐韧性剪切带内的 T28- 12和 T28- 13白云母的 (181.4± 0.5) Ma和 (181.6± 0.8) Ma的 40Ar/39Ar坪年龄指示了郯庐早期左旋剪切的冷却时间为 181 Ma,这些年代学数据指示了郯庐同造山期左旋走滑热事件的存在.起源于华北、华南板块陆-陆碰撞过程中的这期断裂平移活动,发生在高压-超高压带主体部分折返至中地壳后的早侏罗世,推测其活动形式表现为造山带折返过程中高压-超高压带向 SE的斜向折返中形成的转换断层.郯庐晚期韧性剪切带内糜棱岩中白云母、黑云母的 40Ar/39Ar年龄,指示了 139 Ma前(早白垩世)发生的又一次左旋走滑冷却事件.在这期断裂带左行平移的同时,大别造山带东段出现了大规模的岩浆侵入及穹状隆升.剪切带糜棱岩中斜长石 40Ar/39Ar年龄指示剪切带在晚白垩世存在一期快速冷却事件,此次快速冷却事件的时间为 97～ 92 Ma.磷灰石裂变径迹研究成果揭示了 45～ 58 Ma前郯庐断裂带的一次快速冷却事件.这两次快速冷却事件分别对应于断裂带晚白垩世、古近纪两次伸展活动,并控制发育了断裂带东侧的潜山断陷盆地.而钾长石和磷灰石所在地记录的冷却时间显示,造山带内部的抬升都相应早于东缘的郯庐断裂带,反映造山带晚白垩世-古近纪的隆升并不受该断裂带伸展控制,而应是岩石圈拆沉的结果.     

郯庐断裂带肥东桃源韧性剪切带构造分析及时限探究

郯庐断裂带在肥东桃源地区为一混合杂岩带,温压数据显示区域内变形变质环境为中下地壳构造环境。本文对剪切带的应变大小、应变速率、涡度以及应力场等构造特征进行分析测量,结果显示该剪切带所受应力方向为170°左右,夹角为40°～50°,并以简单剪切为主,其变形矿物被拉长。此外,带内发育的长英质糜棱岩流体以及伟晶岩流体均发生同构造变形,本文结合前期年代学研究结果,整合出了3种不同流体之间的关系,并有效限定出带内韧性剪切活动发生在140～124 Ma之间。同时,通过对郯庐断裂带中南段年代学数据统计,发现郯庐断裂带肥东段主要记录了早白垩世的剪切活动,而大别造山带东缘、苏鲁西缘分别记录了同造山年代学数据,断裂带中南段在年代学分布上呈现出明显的空间差异性,反映出郯庐断裂带递进变形的特征。     

郯庐高压走滑韧性剪切带特征及其^40Ar／^39Ar定年

本文首次报导苏鲁造山带西缘新发现的北东向郯庐高压左旋走滑韧性剪切带。剪切带糜棱岩中长石与石英皆广泛发生了动态重结晶,其重结晶型式指示变形温度高达600～700℃。糜棱岩基质中新结晶的白云母,经电子探针分析指示为多硅白云母,所计算的形成压力为1.03～1.45 GPa,表明形成于地壳底部的高压榴辉岩相环境。工作中对剪切带糜棱岩中6个多硅白云母样品进行了~(40)Ar/~(39)Ar测年,其中2个超糜棱岩基质中新结晶多硅白云母分别给出了209.9±1.5Ma 和214.3±1.4Ma(皆晚三叠世)的~(40)Ar/~(39)Ar 坪年龄,指示了左旋走滑的冷却年龄。这些年龄值与苏鲁超高压变质带内已有的多硅白云母~(40)Ar/~(39)Ar 年龄基本一致,表明郯庐断裂带形成于华北与华南板块的碰撞造山期。结合其它地质现象,笔者认为在这两个板块碰撞中郯庐断裂带是以陆内左旋变换断层的型式出现的,从而将大别与苏鲁造山带大规模左行错开。     

郯庐断裂带肥东段走滑运动的40Ar/39Ar法定年

郯庐断裂带在华北与华南板块碰撞之后是否发生过大规模左行平移及其准确的时间,仍然是存在着争议的重要问题。郯庐断裂肥东段地表出露了大规模的、北北东走向的韧性剪切带。野外构造、显微构造与石英C轴组构分析皆指示为左旋走滑韧性剪切带。糜棱岩中变形矿物组合与矿物变形行为指示该韧性剪切带形成于中—高绿片岩相环境。通过对该段走滑糜棱岩中角闪石与黑云母的40Ar/39Ar年代学研究,本次工作中获得了一个角闪石(N14)的40Ar/39Ar坪年龄为143.3±1.3Ma(早白垩世初),据变形温度判断其代表了该断裂带左行平移中的变形年龄。该糜棱岩(N14)中新生的黑云母40Ar/39Ar坪年龄为134.1±0.6Ma,而同一采场中另一糜棱岩(N13)中新生黑云母40Ar/39Ar坪年龄为130.3±0.6Ma,皆指示了左行平移活动的冷却年龄。另外4处走滑糜棱岩中黑云母的40Ar/39Ar坪年龄分别为137.2±0.8Ma(N47)、135.6±0.6Ma(N17)、124.8±0.7Ma(N21)和125.9±0.4Ma(N22),也都属于冷却年龄,反映了该走滑韧性剪带内的不均匀冷却现象。由此变形年龄与冷却年龄可以判断该断裂带的左行平移持续时间不超过6Ma左右。由N14糜棱岩中的角闪石与黑云母坪年龄得到该处的平均冷却速率为21.7℃/Ma,属于较快速的冷却。本次40Ar/39Ar测年结果,更可靠地证实了郯庐断裂     

与时俱进,发展中国大地构造学

郯庐断裂带的起源时间与型式仍然存在着很大的分歧。最近在大别山东缘早白垩世左旋走滑韧性剪切带中 ,发现了早期左旋走滑韧性剪切带。其中三处早期糜棱岩中白云母分别给出了( 188.7± 0 .7)Ma、( 189.7± 0 .6 )Ma、( 192 .5± 0 .7)Ma的40 Ar/ 3 9Ar坪年龄 ,指示了同造山走滑热事件。前陆沉积与变形构造也表明该断裂带在华北与华南板块碰撞中就发生了活动。郯庐断裂带内的造山期构造及旁侧的前陆沉积与变形构造特征 ,指示断裂带同造山运动为转换断层型式 ,并将大别—苏鲁造山带左行错移了约 35 0km ,同时苏鲁造山带发生逆时针旋转。在早白垩世滨太平洋构造活动中 ,该断裂进一步向北延伸 ,发生了约 2 0 0km的左行平移。因而 ,该断裂带起源于华北与华南板块的碰撞之中 ,其同造山运动与这两大板块的碰撞过程相伴生     

佳木斯—伊通断裂韧性剪切变形时代及其地质意义

作为郯庐断裂北段主干断裂的佳木斯-伊通断裂（简称佳-伊断裂）,其最早开始活动的时代一直以来都存在争议。为了更好确定其活动时代,对佳-伊断裂昌图段南城水库附近的韧性剪切带展开了详细研究。野外构造解析和显微构造特征显示,剪切带糜棱面理走向北北东-南南西,其上发育北东方向的缓倾拉伸线理,指示该剪切带为逆冲-走滑韧性剪切特征。锆石U-Pb年龄测试结果表明,剪切带中糜棱花岗岩形成在174~173 Ma,该糜棱岩带被后期未变形辉绿岩脉侵入,辉绿岩脉的锆石U-Pb年龄为164 Ma,从而限定该期次韧性变形发生在174~164 Ma之间的中侏罗晚期。取自剪切带糜棱花岗岩内的变形黑云母40Ar/39Ar测试结果表明,糜棱花岗岩在187~166 Ma左右受到了显著的热事件的扰动。这些证据证明,佳-伊断裂在中侏罗晚期发生过显著的左行走滑韧性剪切,结合对东北地区火成岩研究成果的分析,佳-伊断裂中侏罗晚期的韧性变形可能与古太平洋板块向欧亚大陆的俯冲有关,该时期侵位的岩浆活动开始显著受到俯冲引发的挤压应力作用的影响。      

Titanium in subduction zone fluids: First insights from abinitio molecular metadynamics simulations

The preferential incorporation of High-Field-Strength Elements (HFSE) in rutile (TiO₂), combined with its supposed stability in subduction zone settings, make it an ideal candidate to explain the low HFSE concentrations in subduction-derived magmas. The solubility behaviour of rutile is key to these arguments, but at present experimental and field-based evidence are contradictory.We have used abinitio molecular (meta)dynamics to investigate the coordination environment of Ti(IV) in pure water at 300 and 1000 K and densities ranging from 900-1260 kg m⁻³ (approximate pressures 0.9-3.6 GPa). In all high temperature simulations, the long-range structure of the solvent indicates a breakdown of the hydrogen bonding network as expected for supercritical water. The five-fold coordination of titanium to water is energetically most favourable in aqueous fluids at room temperature and pressure, separated from four and six-fold configurations by ∼175 and ∼200 kJ mol⁻¹, respectively. The average first shell Ti-O distance is 2.00 Å, in excellent agreement with bond lengths obtained from experiments. At similar densities and 1000 K, titanium is on average six-fold coordinate with water, and shows some degree of water dissociation in the first hydration shell. This coordination environment is remarkably persistent with increasing density from 1021 to 1260 kg m⁻³ at constant temperature (1000 K). At lower densities, however, (900 kg m⁻³ at 1000 K), the coordination with first shell water molecules is less than five. The observed coordination changes could promote association of titanium with peralkaline or peraluminous domains in the aqueous fluid, and thereby explain field-and laboratory based evidence of enhanced HFSE concentrations.This study demonstrates that abinitio molecular dynamics has considerable potential to access details of element behaviour in aqueous fluids at geologically relevant conditions that are impossible to examine otherwise. Changes in the solvent structure due to density variations lead to differences in solvent behaviour allowing access to new domains for fluid-solid interaction. Moreover, changes in the solvent structure are strongly linked to the effectiveness of element solvation.     

奥地利东阿尔卑斯山地区杂砂岩带中赋存于碳酸盐岩中的晶质菱镁矿床

奥地利东阿尔卑斯山地区Austroalpine杂砂岩带中的石炭纪Veitsch逆冲推覆体是"Veitsch型"晶质菱镁矿化的典型地区。几十年来,对其成因的解释一直是人们争论的焦点。为了解决这一长久以来的问题,本文对Veitsch推覆体的地质学、矿物学和地球化学制约条件进行了论述。菱镁矿仅仅存在于Veitsch推覆体之中,而其它推覆体中的碳酸盐岩岩层中则无菱镁矿。赋存于Veitsch推覆体中的碳酸盐岩石中的菱镁矿以不规则的岩株状、透镜状和层状产出。块状和厚层状的菱镁矿总是被白云岩包裹。在Veitsch推覆体中,沉积作用开始于晚维宪期的后造山的类磨拉石海相建造,并晚于内部基底带的变形和变质作用("Bretonic期")形成,该基底带位于现代的东阿尔卑斯山地区。沉积序列研究表明,演化从浅海大陆架开始,有时还穿插有高盐度的泻湖和透镜状生物礁,发展到海退的海岸线伴随有发育强烈的三角洲沉积的分支海湾和河流。由于成矿作用有好几个期次,所以对地球化学数据的解释相当复杂。 在Hohentauern／Sunk矿床中,石膏和硬石膏层在菱镁矿质沉积主岩中互层,其δ34S值分别为 17.6±0.2‰和 17.2±0.2‰,表现出石炭纪海水的特征。白云岩和菱镁矿的REE浓度要高于石灰质主岩。在Hohentauern／Sunk矿床中,球形白云岩中的白云岩球体和白云质基质     

Subduction zone geochemistry

Crustal recycling at convergent plate boundaries is essential to mantle heterogeneity.However,crustal signatures in the mantle source of basaltic rocks above subduction zones were primarily incorporated in the form of liquid rather than solid phases.The physicochemical property of liquid phases is determined by the dehydration behavior of crustal rocks at the slab-mantle interface in subduction channels.Because of the significant fractionation in incompatible trace elements but the full inheritance in radiogenic isotopes relative to their crustal sources,the production of liquid phases is crucial to the geochemical transfer from the subducting crust into the mantle.In this process,the stability of specific minerals in subducting crustal rocks exerts a primary control on the enrichment of given trace elements in the liquid phases.For this reason,geochemically enriched oceanic basalts can be categorized into two types in terms of their trace element distribution patterns in the primitive mantle-normalized diagram.One is island arc basalts(IAB),showing enrichment in LILE,Pb and LREE but depletion in HFSE such as Nb and Ta relative to HREE,The other is ocean island basalts(OIB),exhibiting enrichment in LILE and LREE,enrichment or non-depletion in HFSE but depletion in Pb relative to HREE.In either types,these basalts show the enhanced enrichment of LILE and LREE with increasing their incompatibility relative to normal mid-ocean ridge basalts(MORB).The thermal regime of subduction zones can be categorized into two stages in both time and space,The first stage is characterized by compressional tectonism at low thermal gradients.As a consequence,metamorphic dehydration of the subducting crust prevails at forearc to subarc depths due to the breakdown of hydrous minerals such as mica and amphibole in the stability field of garnet and rutile,resulting in the liberation of aqueous solutions with the trace element composition that is considerably enriched in LILE,Pb and LREE but depleted in HFSE and HREE relative to normal MORB.This provides the crustal signature for the mantle sources of IAB.The second stage is indicated by extensional tectonism at high thermal gradients,leading to the partial melting of metamorphically dehydrated crustal rocks at subarc to postarc depths.This involves not only the breakdown of hydrous minerals such as amphibole,phengite and allanite in the stability field of garnet but also the dissolution of rutile into hydrous melts.As such,the hydrous melts can acquire the trace element composition that is significantly enriched in LILE,HFSE and LREE but depleted in Pb and HREE relative to normal MORB,providing the crustal signature for the mantle sources of OIB.In either case,these liquid phases would metasomatize the overlying mantle wedge peridotite at different depths,generating ultramafic metasomatites such as serpentinized and chloritized peridotites,and olivine-poor pyroxenites and hornblendites.As a consequence,the crustal signatures are transferred by the liquid phases from the subducting slab into the mantle.     

荒沟山金矿床原生带与氧化带的划分

本文以荒沟山金矿为例,提出了利用黄铁矿氧化程度划分微细粒浸染型金矿床原生带和氧化带的准则。在荒沟山金矿研究中,利用这种方法将矿体划分为氧化带、混合带和原生眯矿床预测提供了依据。     

北大别的高温超高压变质作用与多阶段折返

近期的变质岩石学、地球化学及同位素年代学研究表明,北大别整体经历了高温超高压变质作用和多阶段折返历史,因而表现为广泛发育的多期减压结构和极少保留早期的超高压变质记录。北大别榴辉岩以高温变质作用以及折返期间因麻粒岩相和角闪岩相退变质变质作用而形成的多期后成合晶为显著特征。石榴子石中伴有放射状胀裂纹的单晶和多晶石英包体指示早期柯石英的转变结果,这已被锆石中发现的柯石英残晶所证实。结合北大别北部榴辉岩和片麻岩中发现的金刚石等超高压证据以及三叠纪变质记录,由此证明北大别整体经历过深俯冲和印支期超高压变质作用。北大别榴辉岩的多阶段高温条件主要来自石榴子石-绿辉石矿物对温度计、单斜辉石中紫苏辉石+石英针状矿物出熔体以及金红石中较高的Zr含量和变质锆石中较高的Ti含量等得出的温度证据。此外,多期后成合晶以及石榴子石和单斜辉石等矿物中成分分带的存在,证明该区榴辉岩经历了一个多阶段、快速折返过程;而不同变质阶段的温度、压力和形成时代,却反映该区榴辉岩经历了长时间的高温变质演化与缓慢冷却过程。长时间的高温变质作用与缓慢冷却过程也许正是北大别长期难以发现柯石英和有关超高压记录的重要原因。因此,这些成果为大别山三个不同超高压岩片的差异折返模型的建立提供了新的证据。     

层间氧化带中褪色带的成因及其找矿意义

本文列举了国内外层间氧化带砂岩型铀矿床中的一些褪色现象 ,从宏观到微观地分析了褪色带的成因 ,认为褪色带的形成是在层间氧化带形成后 ,由深部上升的还原性气体或油气对氧化砂体进行还原的产物。运用国内外典型的事例说明主要工业铀矿体产于褪色带与原生带之间 ,由于褪色带是次生还原的产物 ,往往会将褪色带误认为是原生带 ,从而导致主要工业铀矿体漏失。由此分析推断出 :乌库尔其地区西部的 2 5 3线一带和中部的 3 89～ 42 1线一带第Ⅴ旋回铀矿体可能还在沿倾向向前延伸 ,目前已揭露的铀晕带是褪色带而不是还原带 ,这些地段的铀矿找矿工作应重新认识评价。     

Continental strike-slip rifts and their stratigraphic signature: application to the Bangong/Nujiang zone (Tibet) and the South Penninic zone (Alps)

Our literature studies show that the thermal regime along continental strike-slip rifts is inconspicuous and that they are "low-volcanicity rifts" at best. Along with that, young continental strike-slip rifts exhibit no signs of major thermally controlled doming. We suggest that the larger the strike-slip component of a rift is, the less likely major thermal doming is causally associated with the rift zone. Since vertical lithosphere movements are reflected in the stratigraphic record of a rifted area, different rift modes (strike-slip, dip-slip) may be distinguished by analyzing the relevant sequences. Two ancient and especially suitable strike-slip rift margins in Tethyan mountain belts, the Bangong/Nujiang zone of Tibet and the South Penninic zone of the Alps, were analyzed with regard to their uplift history. The results confirm recent regional rift models which indicate in both cases that rifting was dominated by strike-slip. The stratigraphic approach may provide significant clues as to the mode of paleorifting when structural data are unavailable.