Flume‐ and field‐based evaluation of a time‐integrated suspended sediment sampler for the analysis of sediment properties

Suspended sediment has been identified as a vector for nutrient and contaminant transport in the fluvial environment. A time‐integrated sampler (the Phillips sampler), which emerged over a decade ago as a cost‐effective tool for in situ suspended sediment collection, is increasingly being used to collect samples for the analysis of sediment properties such as particle size composition, and nutrient and contaminant concentrations. This study evaluates the sampler under both flume and field conditions for efficiency in the mass and grain size of the suspended sediment collected. The sampler was tested in a flume using both kaolinite and sediment samples (sieved to < 180 µm) collected from the Quesnel River, British Columbia, Canada. In the kaolinite trails, the sampler preferentially collected coarser grain sizes compared to the original sediment, probably due to finer sediment remaining in suspension and therefore passing through the sampler, and also possibly due to flocculation of the kaolinite upon introduction to the flume. Conversely, the sampler collected river sediment that was finer than the original sediment, probably due to some settling of coarser sediment observed at the bottom of the flume. Once allowance was made for these operational issues associated with the flume, maximum sediment mass efficiency for kaolinite and river sediment was 43% and 87%, respectively. Sediment collected by the time‐integrated sampler during field deployment and adjacent channel bed sediment were also compared. The sampler collected sediment with a representative grain size distribution. However, there were differences in the geochemical (arsenic and selenium) concentrations of channel bed sediment and sediment collected by the Phillips sampler which may be a function of differences in the behavior of geochemical elements associated with the two types of sediment. This work suggests that further research is needed to evaluate the role of the Phillips sampler in collecting sediment for contaminant and nutrient analysis. Copyright © 2014 John Wiley & Sons, Ltd.     

Satellite-derived variability of the Aegean Sea ecohydrodynamics

Eight years of AVHRR-derived sea surface temperature (SST) and SeaWiFS-derived surface chlorophyll (Chl) data (1998–2005) are used to investigate key processes affecting the spatial and temporal variability of the two parameters in the Aegean Sea. Seasonal mean SST and Chl maps are constructed using daily data to study seasonal dynamics whereas empirical orthogonal function (EOF) and correlational analysis is applied to the 8-day composite SST and Chl anomaly time-series in order to study the variability and co-variability of the two parameters from subseasonal to interannual time-scales. The seasonal mean fields show that Black Sea cold and chlorophyll-rich waters enter through the Dardanelles Strait and they are accumulated in the north-eastern part of the Aegean Sea, steered by the Samothraki anticyclone. Large chlorophyll concentrations are encountered in the hydrological front off the Dardanelles Strait as well as in coastal areas affected by large riverine/anthropogenic nutrient loads. The SST seasonal mean patterns reveal strong cooling that is associated with upwelling along the eastern boundary of the basin during summer due to strong northerly winds, a process which is not present in the surface chlorophyll climatology. The Chl dataset presents much stronger sub-seasonal variability than SST, with large variations in the phase and strength of the phytoplankton seasonal cycles. EOF analysis of the anomaly time-series shows that SST non-seasonal variability is controlled by synoptic weather variations and anomalies in the north–south wind-stress component regulating the summer coastal upwelling regime. Mean SST and Chl patterns, and their associated variations, are not closely linked implying that Black Sea and riverine inputs mainly control the intra-annual and interannual variability of the surface chlorophyll in the Aegean Sea rather than mixing and/or upwelling processes.     

Organic carbon transport in the Songhua River,NE China: Influence of land use

Carbon transported by rivers is an important component of the global carbon cycle. Here, we report on organic carbon transport along the third largest river in China, the Songhua River, and its major tributaries. Water samples were collected seasonally or more frequently to determine dissolved organic carbon (DOC) and particulate organic carbon (POC) concentrations and C/N and stable carbon isotopic ratios. Principal component analysis and multiple regression analysis of these data, in combination with hydrological records for the past 50 years, were used to determine the major factors influencing the riverine carbon fluxes. Results indicate that the organic carbon in the Songhua River basin is derived mainly from terrestrial sources. In the 2008–2009 hydrological year, the mean concentrations of DOC and POC were 5.87 and 2.36 mg/L, and the estimated fluxes of the DOC and POC were 0.30 and 0.14 t·km^?2·year^?1, respectively. The riverine POC and DOC concentrations were higher in subcatchments with more cropland, but the area‐specific fluxes were lower, owing to decreased discharge. We found that hydrological characteristics and land‐use type (whether forest or cropland) were the most important factors influencing carbon transport in this system. Agricultural activity, particularly irrigation, is the principal cause of changes in water discharge and carbon export. Over the last 50 years, the conversion of forest to cropland has reduced riverine carbon exports mainly through an associated decrease in discharge following increased extraction of water for irrigation.     

Texture and petrology of modern river, beach and shelf sands in a volcanic back-arc setting, northeastern Japan

Abstract The focus in the present study is on characterizing spatial patterns of textural and petrological variabilities, and on evaluating mechanisms influencing the textural and petrological components of modern river, beach and shelf sands in a volcanically active back‐arc tectonic setting. Abashiri Bay and the surrounding area in eastern Hokkaido, Japan, has volcanic source land within a back‐arc region associated with subduction of the Pacific Plate beneath the Okhotsk (North American) Plate. A total of 41 river, beach and shelf sands were obtained for grain‐size and modal composition analyses. Multivariate analytical techniques of hierarchical cluster and principal component analyses were performed on the textural and petrological data for investigating relations among quantitative variables. On the basis of grain‐size data, four sedimentary zones were identified: zone I, palimpsest zone; zone II, relict zone; zone III, modern (proteric) zone; zone IV, coastal sedimentary zone. All sands are feldspatholithic and quartz‐deficient. The framework (quartz, feldspar and rock fragment) modal compositions were also classified into four clusters, A–D. The characteristic components of each cluster are as follows: cluster A, felsic volcanic rock fragments; cluster B, andesitic–basaltic volcanic rock fragments; cluster C, mixed or plagioclase; cluster D, sedimentary rock fragments. Almost all sands in western and central Abashiri Bay belong to cluster A, where the original compositions are influenced by Kutcharo pyroclastic flow deposits. Andesitic–basaltic lava and Neogene volcaniclastic and sedimentary rocks have a major influence on the compositions of shelf sands in eastern Abashiri Bay. The modal compositions are basically controlled by the source lithology. Compositional maturity (percentage of quartz to feldspar and rock fragments; Q/FR%) slightly increased, in order, from river (1.2), zone IV (coastal, 1.7), zone II (relict, 2.2), zone I (palimpsest, 3.6), to zone III (modern proteric, 7.0). Greater maturity in the recycled sediments is indicative of weathering under the sea or abrasion by transportation induced by sea‐level fluctuations, waves, or sea currents. Several controlling factors – (i) source lithological; (ii) mineralogical; (iii) climatic; and (iv) geomorphological controls – might still cause low maturity through all sedimentary zones other than the continental margin sands previously reported.     

The prediction of aquatic sediment-associated trace element concentrations using selected geochemical factors

Multiple linear regression models calculated from readily obtainable chemical and physical parameters can explain a high percentage (70 per cent or greater) of observed sediment-trace element variance for Cu, Zn, Pb, Cr, Ni, Co, As, Sb, Se, and Hg in a widely divergent suite of 61 sediment samples. The independent variables used in the models may be single parameters, principal component scores, or principal component scores combined with their cross-products. The most useful type of variable must be determined on a case-by-case basis. The independent variables (geochemical parameters) incorporated in the models calculated during this study probably are applicable to many aquatic sediments; albeit, use of a larger data set (>61) could alter the magnitude of the calculated coefficients. The geochemical parameters included in the models were of a physical (e.g. grain size, surface area) and a chemical (e.g. organic matter, amorphous iron oxides) nature. Comparison between actual and predicted trace element concentrations obtained from the models may provide a means of defining ‘average’ sediment-trace element concentrations. In this context, the models may also help identify either naturally or anthropogenically impacted sites for additional study.     

Spatial and temporal variability in nutrient concentrations in Liverpool Bay,a temperate latitude region of freshwater influence

This paper presents data for the temporal and spatial distribution of nutrients in Liverpool Bay between 2003 and 2009 and an analysis of inputs of nutrients from the major rivers. The spatial distribution of winter nutrient concentrations are controlled by the region of freshwater influence (ROFI) in Liverpool Bay through the mixing of riverine freshwater and Irish Sea water, with strong linear relationships between nutrient concentration and salinity between December and February. The location of highest spring and summer phytoplankton biomass reflects the nutrient distributions as controlled by the ROFI. Analysis of 7 years of data showed that the seasonal cycle of winter maximum nutrient concentrations in February and drawdown in April/May is a recurrent feature of this location, with the timing of the drawdown varying by several weeks between years. A comparison of observed nutrient concentrations in Liverpool Bay with those predicted from inputs from rivers has been presented. Nutrient concentrations in the rivers flowing into Liverpool Bay were highly variable and there was reasonable agreement between predicted freshwater nutrient concentrations using data from this study and riverine nutrient concentrations weighted on the basis of river flow, although the exact nature of mixing between the rivers could not be determined. Predicted Irish Sea nutrient concentrations in the winter were lower than those reported for the input waters of the North Atlantic, supporting findings from previous work that nitrogen is lost through denitrification in the Irish Sea.     

Investigation of natural and anthropogenic hydrocarbon inputs in sediments using geochemical markers. I. Santos, SP--Brazil

A study on the inputs of organic matter to marine sediments of Santos Bay and Estuary, located in southeastern S?o Paulo State, Brazil, is presented here. The following geochemical markers were identified and quantified: aliphatic hydrocarbons (normal and isoprenoid alkanes), petroleum biomarkers, linear alkylbenzenes (LABs) and polycyclic aromatic hydrocarbons (PAHs). Sediment samples, collected at 15 sites in the bay and surrounding channels, were extracted and analyzed by gas chromatography with flame ionization and mass spectrometer detectors. Total concentrations varied from 0.17 to 107.80 microg g(-1) for aliphatics, from 47.2 to 2560.1 ng g(-1) for petroleum biomarkers, from 16.9 to 430.6 ng g(-1) for LABs and from 79.6 to 15389.1 ng g(-1) for PAHs. Anthropogenic contributions were apparent, indicating the influences of the Cubatao industrial complex, sewage outfalls along the area, the waste deposit of Santos city and storage facilities for petroleum and derivatives, based on the higher concentrations of geochemical markers detected.     

Spatial variability of metals in the inter-tidal sediments of the Medway Estuary,Kent, UK

Concentrations of major and trace metals were determined in eight sediment cores collected from the inter-tidal zone of the Medway Estuary, Kent, UK. Metal associations and potential sources have been investigated using principal component analysis. These data provide the first detailed geochemical survey of recent sediments in the Medway Estuary. Metal concentrations in surface sediments lie in the mid to lower range for UK estuarine sediments indicating that the Medway receives low but appreciable contaminant inputs. Vertical metal distributions reveal variable redox zonation across the estuary and historically elevated anthropogenic inputs. Peak concentrations of Cu, Pb and Zn can be traced laterally across the estuary and their positions indicate periods of past erosion and/or non-deposition. However, low rates of sediment accumulation do not allow these sub surface maxima to be used as accurate geochemical marker horizons. The salt marshes and inter-tidal mud flats in the Medway Estuary are experiencing erosion, however the erosion of historically contaminated sediments is unlikely to re-release significant amounts of heavy metals to the estuarine system.     

Textural and geochemical characteristics of off shore sediment of North Bay of Bengal:A statistical approach for marine metal pollution

Metal pollution study on sediments of North Bay of Bengal sediments presented in this paper is based on existing Lithostratigraphy of upstream,mineralogy and geochemical analysis of 42 sediment samples.The statistical analysis identifies the metal pollution as well as its apparent source in the off shore regions.Samples were analyzed for grain size,organic content and heavy metals(Fe,Mn,Cr,Cu,Ni,Pb,Cd,Zn and Co) using the sequential extraction method to evaluate geochemical processes and pollution load.In an effort to surmise anthropogenic input,several approaches including classification by quantitative indexes such as enrichment factor,contamination factor,degree of pollution,pollution load index and geo accumulation index,were attempted.Metal speciation results indicate high%of Cd in exchangeable fraction of Mahanadi transect sediments where as a considerable amount of oxidizable fraction of Cr was detected at Dhamra.Quantitative indexes place North Bay of Bengal under moderately polluted zone due to high level of Cd.Normalization of metals to Fe indicated relatively high enrichment factors for Cd and Cr.Factor analysis identified seven possible types of geochemical associations where sediment pH plays a major role for the heavy metal mobility.The higher Cd concentration in exchangeable fraction as well as the higher EF for Cd and Cr present in sediment may pose a risk of secondary water pollution under slightest disturbance in the geo-chemistry of sediments.Comparison study with available data of near costal zones and upstream stratigraphy revealed that open cast mining,overburden dumping,mineral based industrial effluents were the major source of pollution for catchment area contamination.Bay of Bengal is likely to face a serious threat of metal pollution with the present deposition rates unless rigorous pollution control norms are applied.     

北黄海盆地烃渗漏蚀变带“磁亮点”的识别研究

北黄海盆地是我国近海海域尚未取得油气勘探突破的盆地之一.在海洋环境中应用海底油气藏的烃渗漏现象寻找油气有利区具有良好应用前景,为了给该区的含油气远景评价及下一步油气勘探缩小靶区提供地球物理依据,本文利用磁法这一经济、有效的油气渗漏异常地球物理判别手段,开展了识别海底烃渗漏引发磁异常的方法研究.给出一种根据“有导师”的模式识别技术,在充分利用磁异常多种数值特征及纹理特征的基础上,提取烃渗漏蚀变带磁异常的方法.通过已知约束信息（如见油井位等）的点、线、面三种基元及其邻近数据网格点组成基类,将其提取的模式或特征向量作为待识别异常匹配或学习的模板,利用加权欧氏距离函数计算待识别异常特征向量与模板向量之间的相似性,进行模式匹配,从而识别出与模板相似程度较高的异常.应用此方法圈定了北黄海盆地的烃渗漏“磁亮点”分布,从“磁亮点”异常区与中生代地层的分布以及地球化学异常（低层大气烃类检测和海底微生物异常）的对应情况来看,表明该识别方法是识别烃渗漏弱磁异常的一种有效手段.对研究区构造特征、磁异常及地球化学异常特征的综合分析表明,位于北黄海研究区东部和北部的“磁亮点”异常区可能是北黄海盆地较好的含油气远景区.     

PCBs and its coupling with eco-environments in Southern Yellow Sea surface sediments

In this paper, the spatial distribution and source of the PCBs in surface sediments of the Southern Yellow Sea (SYS) and influencing factors, such as the sediment characteristics (components, relative proportions and total organic carbon contents), and hydrodynamic conditions were analyzed. PCB concentrations in the surface sediments ranged from 518-5848 pg/g, with average values of 1715 pg/g decreasing sharply compared to last year. In the study area, the PCB pollution level in the middle area was the highest, followed by that of the east coast and the west coast, respectively. Although the PCB level in the coastal areas was lower than that in the middle areas, it was proven in our study that the Yellow Sea obtained PCBs by virtue of river inputs. There was a positive and pertinent correlation between the clay proportion and PCB concentrations, and the increase of the PCB concentrations was directly proportional to the increase of TOC contents, with r=0.61, but it was contrary to the sediment grain size. Consequently, the factors controlling PCB distribution had direct or indirect relationships with sediment grain size; moreover, the hydrodynamic conditions determined the sediment components and grain size. In conclusion, hydrodynamic conditions of the Yellow Sea were the most important influencing factors effecting the distribution of PCBs in the surface sediments of the SYS.     

祁连山断裂带中东段断层土壤气氡浓度强度时空分布特征及其地震危险性分析

基于祁连山断裂带中东段9个观测点2016—2021年的土壤气体氡浓度观测数据,深入分析其浓度强度时空分布特征。同时结合历史大震背景、现今地震活动与断裂带滑动速率的对比分析,从地球化学的角度对祁连山断裂带中东段进行地震危险区段判定。研究表明：祁连山断裂中东段土壤气体氡浓度强度的空间分布特征为东强西弱,其时间序列变化特征总体呈下降趋势;断层土壤气氡浓度强度的空间分布特征、历史及现今地震活动和断裂滑动速率具有较好的耦合性。研究结论可以提供研究区深部地下流体活动的证据,对进一步研究追踪未来可能发生地震的断层和活动段具有重要意义。     

Tide‐modulated hyperpycnal flows off the Huanghe (Yellow River) mouth,China

Few hyperpycnal flows have ever been observed in marine environments although they are believed to play a critical role in sediment dispersal within estuarine and deltaic depositional systems. The paper describes hyperpycnal flows observed in situ off the Huanghe (Yellow River) mouth, their relationship to tidal cycles, and the mechanisms that drive them. Simultaneous observations at six mooring stations during a cruise off the Huanghe mouth in the flood season of 1995 suggest that hyperpycnal flows observed at the river mouth are initiated by high concentrations of sediment input from river and modulated by tides. Hyperpycnal flows started near the end of ebb tides, when near‐bottom suspended sediment concentration (SSC) increased rapidly and salinity decreased drastically (an inverse salt wedge). The median grain size of suspended particles within the hyperpycnal layer increased, causing strong stratification of the suspended sediments in the water column. Towards the end of flood tides, the hyperpycnal flow attenuated due to frictions at the upper and lower boundaries of the flow and tidal mixing, which collapsed the stratification of the water column. Both sediment concentration and median grain size of suspended particles within the bottom layer significantly decreased. The coarser sediment particles were deposited and the hyperpycnal flows stopped. The intra‐tidal behaviors of hyperpycnal flows are closely associated with the variations of SSC, salinity, and stratification of the water column. As nearly 90% of riverine sediment is delivered to the sea during the flood seasons when hyperpycnal flows are active, hyperpycnal flows at the Huanghe mouth and the river's high sediment loads have caused rapid accretion of the Huanghe delta. Copyright © 2010 John Wiley & Sons, Ltd.     

Aeolian deposition of dust over hills: the effect of dust grain size on the deposition pattern

Wind tunnel experiments were conducted to investigate the effects of topography on the grain size characteristics of aeolian dust deposits. Experiments were performed on three isolated hills having various size and aspect ratios. The longitudinal profile of the median grain diameter was investigated for each hill. The longitudinal dust deposition profile was also studied for nine grain size classes of between 10 and 104 µm, as were wind and dust concentration profiles in the atmosphere upwind of, over and downwind of a hill. The wind tunnel experiments show that the grain size characteristics of aeolian dust deposits are affected by topography. Most apparent is the occurrence of a zone of reduced grain size on the leeside of hills, which extends from just upwind of the summit to a distance of several times the height of the hill. Slightly coarser than normal dust is deposited on the concave windward hill slope and in a zone downwind of the area of reduced grain size, but the increase in grain size in these zones remains very small. Although the normalized dust deposition profile for a hill does not vary substantially as a function of grain size, systematic trends are observed. The most important tendencies are: (1) a progressive extension, in the downwind direction, of a zone of decreased dust deposition on the leeside of a hill (the coarser the grains, the further downwind the zone of reduced deposition extends); (2) a progressive increase in dust deposition immediately upwind of a hill (the finer the grains, the higher the deposition value upwind of a hill becomes). Both tendencies are explained by the difference in inertia of the grains, which is controlled by grain size. Copyright © 2005 John Wiley & Sons, Ltd.     

Hydrocarbons in the water, particulate matter, seston, and bottom sediments of the White Sea in the late summer

Aliphatic and polycyclic aromatic hydrocarbons were studied in water, filtration and separation particulate matter, seston, and bottom sediments with the aim to determine their concentrations and origin and compare them with the concentrations of lipids and C_org (August 2006). The effect of anthropogenic hydrocarbons was identified mostly in the Northern Dvina mouth area and in the apex of Dvina Bay. In other parts of the sea, natural compounds dominate in all examined objects, since anthropogenic hydrocarbon cannot pass through the Northern Dvina-the White Sea geochemical barrier. The low temperatures in the high-latitude water areas are shown not to reduce the rate of diagenetic processes in the sedimentary strata.     

GRAIN SIZE DISTRIBUTION OF SEDIMENT IN THE NORTHERN EAST CHINA SEA AND THE RELATIONSHIP WITH THE SEA CURRENTS

1 INTRODUCTION The East China Sea, one of the largest continental marginal seas in the world, receives large amount of suspended sediment from the land annually (Milliman and Meade, 1983; Shen, 1999). Since late Pleistocene, the deposition of the suspended sediment over the relict sandy sediment induces the complicated distribution of surface sediment (Fig. 1). Many studies have been done on the surface sediment distribution, sedimentation rate, concentration and dispersion of suspen…     

An investigation of the spatial variability of the grain size composition of floodplain sediments

River floodplains have been widely recognized as important sinks for storing suspended sediment and associated contaminants transported by river systems. The grain size composition of floodplain deposits exerts an important influence on contaminant concentrations, and commonly exhibits significant spatial variability in response to the dynamic nature of overbank flow and sediment transport. Information on the spatial variability of the grain size composition of overbank deposits is therefore essential for developing an improved understanding of the processes controlling sediment transport on floodplains, and for investigating the fate of sediment-associated contaminants. Such information is also important for validating existing floodplain sedimentation models. This paper reports the results of a study aimed at investigating the spatial variability of the grain size composition of floodplain sediments at different spatial scales, through analysis of surface sediment samples representative of contemporary floodplain deposits collected from frequently inundated floodplain sites on five British lowland rivers. Significant lateral and downstream variations in the grain size composition of the sediment deposits have been identified in the study reaches. An attempt has been made to relate the observed spatial distribution of the grain size composition of the overbank deposits to the local floodplain geometry and topography. The importance of the particle size characteristics of the suspended sediment transported by the rivers in influencing the spatial variability of the grain size composition of the overbank sediments deposited on these floodplains is also considered. © 1998 John Wiley & Sons, Ltd.     

Magnetic mineral diagenesis in the post-glacial muddy sediments from the southeastern South Yellow Sea: Response to marine environmental changes

Core YSDP103 was retrieved in the muddy deposit under the cold eddy of the southeastern South Yellow Sea, and the uppermost 29.79 m core represents the muddy sediments formed in the shelf since about 13 ka BP. The lower part from 29.79 to 13.35 m, called Unit A2, was deposited during the period from the post-glacial transgression to the middle Holocene (at about 6 14C ka BP) when the rising sea level reached its maximum, while the upper part above 13.35 m (called Unit A1) was deposited in a cold eddy associated with the formation of the Yellow Sea Warm Current just after the peak of post-glacial sea level rise. Rock-magnetic properties of the uppermost 29.79 m core were investigated in detail. The experimental results indicate that the magnetic mineralogy of the core is dominated by magnetite, maghemite and hematite and that, except for the uppermost 2.35 m, the magnetic minerals were subject to reductive diagene-sis leading to significant decline of magnetic mineral content and the proportion of low-coe     

The influence of climate on water chemistry states and dynamics in rivers across Australia

For effective water quality management and policy development, spatial variability in the mean concentrations and dynamics of riverine water quality needs to be understood. Using water chemistry (calcium, electrical conductivity, nitrate-nitrite, soluble reactive phosphorus, total nitrogen, total phosphorus and total suspended solids) data for up to 578 locations across the Australian continent, we assessed the impact of climate zones (arid, Mediterranean, temperate, subtropical, tropical) on (i) inter-annual mean concentration and (ii) water chemistry dynamics as represented by constituent export regimes (ratio of the coefficients of variation of concentration and discharge) and export patterns (slope of the concentration-discharge relationship). We found that inter-annual mean concentrations vary significantly by climate zones and that spatial variability in water chemistry generally exceeds temporal variability. However, export regimes and patterns are generally consistent across climate zones. This suggests that intrinsic properties of individual constituents rather than catchment properties determine export regimes and patterns. The spatially consistent water chemistry dynamics highlights the potential to predict riverine water quality across the Australian continent, which can support national riverine water quality management and policy development.     

Eutrophication in the Polish coastal zone: the past, present status and future scenarios

In the Baltic Sea eutrophication processes have accelerated in the past 50 years of the 20th century and presently there exists a major ecological problem for this sea. The Polish coastal zone of the southern Baltic Sea is the recipient of riverine inputs from two major sources, namely the Odra and Vistula, as well as a number of smaller rivers along the central coast. Hence, the entire coastal zone remains under severe anthropogenic pressure. The variability of nutrient concentrations, especially the winter nutrient pool in the euphotic zone, summer level of total nitrogen and total phosphorus, together with such eutrophication indicators as water oversaturation with oxygen and the summer oxygen minimum, were analysed in the data time series 1959-2001. The temporal trends were investigated using linear regression and the non-parametric Whirsch test. The future characteristics of the Baltic Sea are discussed taking into account the development of driving forces.