Assessment of soil erosion and sediment delivery ratio using remote sensing and GIS： a case study of upstream Chaobaihe River catchment, north China

Soil erosion in catchment areas reduces soil productivity and causes a loss of reservoir capacity. Several parametric models have been developed to predict soil erosion at drainage basins, hill slopes and field levels. The well-known Universal Soil Loss Equation （USLE） represents a standardized approach. Miyun reservoir, which sits on Chaobaihe River, is the main surface source of drinking water for Beijing, the capital of China. Water and soil loss are the main reasons for sediment to enter a reservoir. Sediment yield is assessed using a version of the universal soil loss equation modified by Chinese researchers. All year 2001 and 2002 data for factors in the equation are obtained from remote sensing or collected to form an analysis database. These factors are computed and mapped using Geographic Information System tools. Based on the complex database, the modified model is developed. Through pixel-based computing the sediment yield per hydrological unit is calculated. The model does not consider sediment deposition occurring on hillslopes. Gross soil loss is often higher than the sum of those measured at catchment outlets. The sediment delivery ratio （SDR） per hydrological unit is also computed. This study analyzes the main contributions of sediment yields on sub-basins of the Chaobaihe River to the Miyun Reservoir, and discusses the possible reasons for the difference between SDRs in 2001 and 2002 at different outlets. The result shows that in the upper basin of the Miyun Reservoir, in 2001 the area of erosion that could be neglected was 8,202.76 km^2, the area of low erosion 3,269.59 km^2, the area of moderate erosion 3,400.97 km^2, the area of high erosion 436.89 km^2, the area of strong erosion 52.19 km^2 and the area of severe erosion 3.13 km^2. The highest soil loss was 70,353 t/km^2. yr in Fengning County in 2001, followed by 64,418 t/km^2. yr by Chicheng County in 2001. The SDR in 2002 was lower than that in 2001. The main reasons are the decreasing rainfall erosivity and total runoff.     

Bioavailability of heavy metals in water and sediments from a typical Mediterranean Bay (Málaga Bay,Region of Andalucía,Southern Spain)

Concentrations of heavy metals were measured in sediment and water from Málaga Bay (South Spain). In the later twentieth century, cities such as Málaga, have suffered the impact of mass summer tourism. The ancient industrial activities, and the actual urbanization and coastal development, recreation and tourism, wastewaters treatment facilities, have been sources of marine pollution. In sediments, Ni was the most disturbing metal because Ni concentrations exceeded the effects range low (ERL), concentration at which toxicity could start to be observed in 85% of the samples analyzed. The metal bioavailability decreased in the order: Cd > Ni > Pb > Cu > Cr. In the sea water samples, Cd and Pb were the most disturbing metals because they exceeded the continuous criteria concentration (CCC) of US EPA in a 22.5% and 10.0% of the samples, respectively. Statistical analyses (ANOVA, PCA, CA) were performed.     

Specific profiles of polybrominated diphenylethers (PBDEs) and polychlorinated biphenyls (PCBs) in fish and tucuxi dolphins from the estuary of Paraíba do Sul River, Southeastern Brazil

Polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) are ubiquitous pollutants in the environment and subject of several studies due to their adverse effects as endocrine disruptors. Despite the concern over widespread distribution of PBDEs even in sparsely populated regions of the world, few studies have reported their occurrence in Brazil. In this study, PBDEs and PCBs levels were measured in selected fish species and dolphins from Paraiba do Sul River, Brazil. BDE 47 and 85 were the predominant congeners. Low chlorinated congeners showed the highest concentrations in fish; however dolphins presented the highest proportion of PCBs 153, followed by 138 and 180. The daily intake of PBDEs and PCBs was estimated for the population of this region. PCB daily intake through consumption of croaker was above the limits set by the Brazilian Ministry of Agriculture, raising great concern over the existence of a source of PCB contamination in Brazil.     

Fluid circulation in a complex volcano-tectonic setting,inferred from self-potential and soil CO2 flux surveys: The Santa María–Cerro Quemado–Zunil volcanoes and Xela caldera (Northwestern Guatemala)

The region encompassing Santa María, Cerro Quemado, and Zunil volcanoes, close to Quetzaltenango, the second largest city of Guatemala, is volcanically and tectonically complex. In addition, the huge Xela caldera, about 20 km in diameter, crosses this area and links up to the important Zunil fault zone located between the three volcanoes. Two highly active geothermal sites, named Zunil-I and Zunil-II, are also located between these three volcanic edifices at the southeastern boundary of Xela caldera. In order to determine the permeability variations and the main structural discontinuities within this complex volcano-tectonic setting, self-potential and soil CO₂ flux measurements have been coupled, with a step of 20 m, along a 16.880 km-long profile crossing the entire area. Two shallow hydrothermal systems, with maximum lateral extensions of 1.5 km in diameter, are indicated by positive self-potential/elevation gradients below Santa María and Cerro Quemado volcanoes. Such small hydrothermal systems cannot explain the intense geothermal manifestations at Zunil-I and Zunil-II. Another minor hydrothermal system is indicated by self-potential measurements on the flank of Santa María along the edge of the Xela caldera. CO₂ flux measurements display slight variations inside the caldera and decreasing values crossing outside the caldera boundary. We hypothesize the presence of a magmatic body, inside the southeastern border of Xela caldera, to explain the deeper and more intense hydrothermal system manifested by the Zunil-I and the Zunil-II geothermal fields. This magmatic system may be independent from Santa María and Cerro Quemado volcanoes. Alternatively, the hypothesized Xela magmatic system could have a common magmatic origin with the Cerro Quemado dome complex, consistent with previous findings on regional gas emissions. Sectors bordering the Cerro Quemado dome complex also have high amplitude minima-short wavelength anomalies in self-potential, interpreted as preferential rain water infiltration along faults of major permeability, probably related with the most recent stages of Cerro Quemado dome growth.     

Paleomagnetic evidence for a pre-early Eocene (∼ 50 Ma) bending of the Patagonian orocline (Tierra del Fuego,Argentina): Paleogeographic and tectonic implications

The southernmost segment of the Andes of southern Patagonia and Tierra del Fuego forms a ～ 700 km long orogenic re-entrant with an interlimb angle of ～ 90° known as Patagonian orocline. No reliable paleomagnetic evidence has been gathered so far to assess whether this great orogenic bend is a primary arc formed over an articulated paleomargin, or is due to bending of a previously less curved (or rectilinear) chain. Here we report on an extensive paleomagnetic and anisotropy of magnetic susceptibility (AMS) study carried out on 22 sites (298 oriented cores), predominantly sampled in Eocene marine clays from the external Magallanes belt of Tierra del Fuego. Five sites (out of six giving reliable paleomagnetic results) containing magnetite and subordinate iron sulphides yield a positive fold test at the 99% significance level, and document no significant rotation since ～ 50 Ma. Thus, the Patagonian orocline is either a primary bend, or an orocline formed after Cretaceous–earliest Tertiary rotations. Our data imply that the opening of the Drake Passage between South America and Antarctica (probably causing the onset of Antarctica glaciation and global climate cooling), was definitely not related to the formation of the Patagonian orocline, but was likely the sole consequence of the 32 ± 2 Ma Scotia plate spreading. Well-defined magnetic lineations gathered at 18 sites from the Magallanes belt are sub-parallel to (mostly E–W) local fold axes, while they trend randomly at two sites from the Magallanes foreland. Our and previous AMS data consistently show that the Fuegian Andes were characterized by a N–S compression and northward displacing fold–thrust sheets during Eocene–early Miocene times (50–20 Ma), an unexpected kinematics considering coeval South America–Antarctica relative motion. Both paleomagnetic and AMS data suggest no significant influence from the E–W left-lateral Magallanes–Fagnano strike–slip fault system (MFFS), running a few kilometres south of our sampling sites. We thus speculate that strike–slip fault offset in the Fuegian Andes may range in the lower bound values (～ 20 km) among those proposed so far. In any case our data exclude any influence of strike–slip tectonics on the genesis of the great orogenic bend called Patagonian orocline.     

A magmatic source for fumaroles and diffuse degassing from the summit crater of Teide Volcano (Tenerife, Canary Islands): a geochemical evidence for the 2004–2005 seismic–volcanic crisis

The present work reports the results of 15 studies of diffuse CO₂ degassing performed at Teide Volcano crater (Canary Island, Spain) and the chemical and isotopic compositions of fluids discharged from a fumarolic field located at the top of the volcano as measured between 1991 and 2010. A higher contribution of magmatic gases accompanied by enhanced total diffuse CO₂ emissions were observed in relation with a seismic crisis that occurred in Tenerife Island between 2001 and 2005, with the main peak of seismic activity between April and June 2004. A significant pulse in total diffuse CO₂ emission was observed at the crater of Teide (up to 26.3?t day^?1) in 2001. In December 2003, the chemical composition of the Teide fumarole changed significantly, including the appearance of SO₂, an increase in the HCl and CO concentrations and in the C₂H₆/C₂H₄ and C₃H₈/C₃H₆ ratios, and a decrease in the H₂S, CH₄, and C₆H₆ concentrations and in the gas/steam ratio. A few months after a drastic decrease in seismic activity, the SO₂, HCl, and CO concentrations and the C₂H₆/C₂H₄ and C₃H₈/C₃H₆ ratios strongly decreased, whereas the CH₄ and C₆H₆ concentrations and the gas/steam ratios increased. According to the trends shown by both the geochemical parameters and the seismic signals late in the observation period, the risk of a rejuvenation of volcanic activity at Teide is considered to be low. The associated temporal changes in seismic activity and magmatic degassing indicate that geophysical and fluid geochemistry signals in this system are related. Future monitoring programs aimed at mitigating volcanic hazard on Tenerife Island should involve coupled geophysical and geochemical studies.