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1.
Aerosol parameters are measured using a ground-based Multi-wavelength Radiometer (MWR) at Mohal (31.90°N, 77.11°E, 1154 m amsl) in the Kullu valley during clear sky days of a seasonal year. The study shows that the values of spectral aerosol optical depths (AODs) at 500 nm and the Ångstrom turbidity coefficient ‘β’ (a measure of columnar loading in atmosphere) are high (0.41 ± 0.03, 0.27 ± 0.01) in summer, moderate (0.30 ± 0.03, 0.15 ± 0.03) in monsoon, low (0.19 ± 0.02, 0.08 ± 0.01) in winter and lowest (0.18 ± 0.01, 0.07 ± 0.01) in autumn, respectively. The Ångstrom wavelength exponent ‘α’ (indicator of the fraction of accumulation-mode particles to coarse-mode particles) has an opposite trend having lowest value (0.64 ± 0.06) in summer, low (0.99 ± 0.10) in monsoon, moderate (1.20 ± 0.15) in winter and highest value (1.52 ± 0.03) in autumn. The annual mean value of AOD at 500 nm, ‘α’ and ‘β’ are 0.24 ± 0.01, 1.06 ± 0.09 and 0.14 ± 0.01, respectively. The fractional asymmetry factor is more negative in summer due to enhanced tourists’ arrival and also in autumn months due to the month-long International Kullu Dussehra fair. The AOD values given by MWR and satellite-based moderate resolution imaging spectro-radiometer have good correlation of 0.76, 0.92 and 0.97 on diurnal, monthly and seasonal basis, respectively. The AODs at 500 nm as well as ‘β’ are found to be highly correlated, while ‘α’ is found to be strongly anti-correlated with temperature and wind speed suggesting high AODs and turbidity but low concentration of fine particles during hot and windy days. With wind direction, the AOD and ‘β’ are found to be strongly anti-correlated, while ‘α’ is strongly correlated.  相似文献   

2.
首次运用铼-锇同位素方法对滁州琅琊山铜矿床中的辉钼矿进行定年。5件辉钼矿样品的模式年龄为(128.9±1.8)Ma~(130.3±1.9)Ma,187Re-187Os等时线年龄为(128.6±2.2)Ma,其加权平均方差(MSWD)为0.45,为滁州琅琊山铜矿床提供了准确的形成时限。分析结果表明,滁州琅琊山铜矿床是早白垩纪(燕山晚期)区域构造-岩浆活动的产物。琅琊山铜矿床辉钼矿中铼含量较高,推断成矿物质主要是壳幔混源,且主要是幔源。  相似文献   

3.
Kinetic rates of Fe2+-Mg disordering in three orthopyroxenes (mean value of XFe = Fe2+/(Fe2++Mg) = 0.175,0.482,0.770 respectively) have been determined employing heating experiments and single crystal X-ray structural refinements. Disordering rate constants \((\vec K)\) (550800° C) for two pyroxenes are given by: ln \((\vec K)\) = 27.107(±5.177)?32062(±783)T?1(XFe = 0.175) ln \((\vec K)\) = 16.142(±0.057)?18227(±423)T?1(XFe = 0.770) The distribution coefficients KD (representing a steady state of disordering FeM2 + MgM1 ? FeM1 + MgM2) are given by: ln KD = 5.016(±0.223)-7033(±1473) T?1(XFe = 0.175) ln KD = 1.988(±0.122)-3809(±913)T?1(XFe = 0.770) These distribution coefficients provide the constraint of the disordering reaction on the value of the equilibrium constant for Fe2+-Mg order-disorder. Until the low temperature dependence of KD is well constrained, the calculation of cooling rates of pyroxenes and host rocks cannot be done reliably.  相似文献   

4.
Electron spin resonance (ESR) measurements of heated flint from Kebara cave show the presence of two radiation sensitive signals: E' and Al. Both are strongly interfered with by organic signals produced during heating of the flint. The signal subtraction method of Porat and Schwarcz (1991) was used to determine equivalent doses for flint samples from levels VII-XII, for which thermoluminescence (TL) ages on the same samples are known. Ages were determined using dose rates based on analyses of the flint and TLD measurements of external dose rates. The average E' age of 48.5 ± 5.1 ka is much less than the average TL age (62.2 ± 4.3 ka), whereas the average age of 64.6 ± 12 ka given by the Al signal is in good agreement with the TL age, but with much larger dispersion. © 1994 John Wiley & Sons, Inc.  相似文献   

5.
《Precambrian Research》1986,31(1):69-95
Earlier studies of Stromatolites had permitted the dating of the Atar Formation (Mauritania) as late Riphean by comparing these structures with those of the U.S.S.R. Geochronological data (Rb/Sr) obtained subsequently on illite had given ages ranging between 890 ± 36 and 595 ± 43 Ma for the whole Atar Group, the Atar Formation being dated at 890 ± 36 Ma (late Riphean). The microfossils (Acritarchs) studied here come from black shales cored while drilling for water near Atar. These shales are equivalent to the intercalations between the stromatolitic limestones of the Atar Formation. They have yielded 20 species of Acritarchs, six of which are most important as they provide a diagnostic assemblage of the late Riphean (1000 ± 50–650 ± 10 Ma) of the U.S.S.R. and northern Europe. These are: Chuaria circularis, Kildinosphaera chagrinata, K. verrucata, Leiosphaeridia asperata, Stictosphaeridium cf. sinapticuliferum, Trematosphaeridium holtedahli. The late Riphean age of the Atar Formation is thus confirmed by this microfossil assemblage.  相似文献   

6.
河北丰宁县大草坪钼矿区岩体锆石U-Pb年龄研究   总被引:5,自引:1,他引:5  
大草坪钼矿属冀北上黄旗构造岩浆岩带钼多金属成矿带,对其赋矿围岩的年龄、矿床成因及类型一直存在争论。通过对岩浆结晶锆石及捕虏晶锆石U-Pb年龄研究,表明大草坪花岗岩岩浆结晶锆石U-Pb年龄为(220.0±1.7)Ma、(224.0±1.5)Ma和(232.7±1.5)Ma,作者据此重新厘定大草坪花岗岩成岩期为印支期,有别于1989年《河北省、北京市、天津市区域地质志》中厘定的燕山期。根据大草坪花岗闪长岩中岩浆结晶锆石U-Pb年龄(134.3±1.2)Ma和(140.0±1.5)Ma,重新厘定大草坪花岗闪长岩成岩期为燕山期,有别于前人厘定的海西期。表明本区含矿岩体来源于古老基底就地多期改造重熔。  相似文献   

7.
张娟  毛景文  程彦博  李肖龙 《矿床地质》2012,31(6):1149-1162
在个旧锡铜多金属矿集区发育有矽卡岩型和热液脉型等锡铜矿化体,其形成时代是晚白垩世,属与花岗岩有关的岩浆热液成因矿床。赋存于三叠纪蚀变玄武岩层中,呈(似)层状的铜矿体的精确年龄尚未有报道,成因仍备受争议。文章选择赋存于卡房矿田蚀变玄武岩层中,呈(似)层状分布的铜矿体中的金云母,及新山岩体接触带云英岩中的白云母为研究对象,利用40Ar-39Ar阶段加热同位素定年方法对它们进行了年代学研究,获得了金云母和白云母的40Ar-39Ar同位素坪年龄分别为(79.55±0.47) Ma和(79.53±0.57) Ma,对应等时线年龄分别为(79.8±1.3) Ma和(79.7±1.0) Ma,反等时线年龄分别为(79.7±2.0) Ma和(79.61±0.75) Ma,两者年龄基本一致。结合矿物共生组合特征和流体包裹体测温资料,认为金云母的坪年龄(79.55±0.47) Ma,可以代表卡房蚀变玄武岩中(似)层状铜矿的形成时代,而白云母的坪年龄(79.53±0.57) Ma,则代表新山岩体形成后期岩浆热液活动的年龄。这2个年龄与个旧锡铜多金属矿床的成矿时代基本一致,应是同一构造-岩浆-流体活动形成的成矿系列产物。  相似文献   

8.
Mingqin  He  Jiajun  Liu  Chaoyang  Li  Zhiming  Li  Yuping  Liu  Aiping  Yang  Haiqing  Sang 《中国地球化学学报》2004,23(4):342-348
40Ar−39Ar fast neutron activation age spectrum of quartz in ore collected from the Baiyangping Cu−Co polymetallic ore-concentrated area, Lanping Basin, is saddle-shaped. The plateau age, minimum appearance age and isochron age shown on the spectra are 56.53±0.43 Ma, 55.52±1.78 Ma and 55.90±0.29 Ma respectively. The age data are consistent with each other within 1σ uncertainties. Because the given initial40Ar/36Ar value of 294.7±1.14 is very close to Nier's value (295.5±5), both plateau and isochron ages may be considered as the forming time of quartz. So the age of 55.90–56.53 Ma represents the forming age of ore deposits. It is obvious that the ore deposits were formed during the Early Himalayan period. This research project was granted by the State Basic Research, Development and Planning Program (G1999043208) and the Foundation Projects of Yunnan Provincial Education Department (No. 0142104).  相似文献   

9.
The Çöpler epithermal Au deposit and related subeconomic porphyry Cu–Au deposit is hosted by the middle Eocene Çöpler–Kabata? magmatic complex in central eastern Anatolia. The intrusive rocks of the complex were emplaced into Late Paleozoic–Mesozoic metamorphosed sedimentary basement rocks near the northeastern margin of the Tauride-Anatolide Block. Igneous biotite from two samples of the magmatic complex yielded 40Ar/39Ar plateau ages of 43.75?±?0.26 Ma and 44.19?±?0.23, whereas igneous hornblende from a third sample yielded a plateau age of 44.13?±?0.38. These ages closely overlap with 40Ar/39Ar ages of hydrothermal sericite (44.44?±?0.28 Ma) and biotite (43.84?±?0.26 Ma), and Re–Os ages from two molybdenite samples (44.6?±?0.2 and 43.9?±?0.2 Ma) suggesting a short-lived (<1 my) magmatic and hydrothermal history at Çöpler. No suitable minerals were found that could be used to date the epithermal system, but it is inferred to be close in age to the precursor porphyry system. The Çöpler–Kabata? intrusive rocks show I-type calc-alkaline affinities. Their normalized trace element patterns show enrichments in large ion lithophile and light rare earth elements and relative depletions in middle and heavy rare earth elements, resembling magmas generated in convergent margins. However, given its distance from the coeval Eocene Maden–Helete volcanic arc, the complex is interpreted to be formed in a back-arc setting, in response to Paleocene slab roll-back and upper-plate extension. The tectonomagmatic environment of porphyry-epithermal mineralization at Çöpler is comparable to some other isolated back-arc porphyry systems such as Bajo de la Alumbrera (Argentina) or Bingham Canyon (USA).  相似文献   

10.
云南兰坪白秧坪铜钴多金属矿集区矿石中石英的40Ar-39Ar快中子活化年龄谱呈马鞍形,坪年龄为56.53±0.43Ma,最小视年龄为55.52±1.78Ma,等时线年龄为55.90±0.29Ma,三者在误差范围内一致(1σ)。40Ar/36Ar初始值为294.7±1.14,与尼尔值(295.5±5)十分接近,坪年龄和等时线年龄均可作为石英的形成时代。因此,55.90~56.53Ma(喜马拉雅早期)代表了矿床的成矿年龄。  相似文献   

11.
Shao  Tongbin  Xia  Ying  Ding  Xing  Cai  Yongfeng  Song  Maoshuang 《中国地球化学学报》2020,39(3):387-403

Zircon stability in silicate melts—which can be quantitatively constrained by laboratory measurements of zircon saturation—is important for understanding the evolution of magma. Although the original zircon saturation model proposed by Watson and Harrison (Earth Planet Sci Lett 64(2):295–304, 1983) is widely cited and has been updated recently, the three main models currently in use may generate large uncertainties due to extrapolation beyond their respective calibrated ranges. This paper reviews and updates zircon saturation models developed with temperature and compositional parameters. All available data on zircon saturation ranging in composition from mafic to silicic (and/or peralkaline to peraluminous) at temperatures from 750 to 1400 °C were collected to develop two refined models (1 and 2) that may be applied to the wider range of compositions. Model 1 is given by lnCZr(melt) = (14.297 ± 0.308) + (0.964 ± 0.066)·M − (11113 ± 374)/T, and model 2 given by lnCZr(melt) = (18.99 ± 0.423) − (1.069 ± 0.102)·lnG − (12288 ± 593)/T, where CZr(melt) is the Zr concentration of the melt in ppm and parameters M [= (Na + K + 2Ca)/(Al·Si)] (cation ratios) and G [= (3·Al2O3 + SiO2)/(Na2O + K2O + CaO + MgO + FeO)] (molar proportions) represent the melt composition. The errors are at one sigma, and T is the temperature in Kelvin. Before applying these models to natural rocks, it is necessary to ensure that the zircon used to date is crystallized from the host magmatic rock. Assessment of the application of both new and old models to natural rocks suggests that model 1 may be the best for magmatic temperature estimates of metaluminous to peraluminous rocks and that model 2 may be the best for estimating magmatic temperatures of alkaline to peralkaline rocks.

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12.
We report radiocarbon dates that constrain the timing of the deposition of the late-glacial Puerto Bandera moraine system alongside the western reaches of Lago Argentino adjacent to the Southern Patagonian Icefield. Close maximum-limiting radiocarbon ages (n = 11) for glacier advance into the outer moraines, with a mean value of 11,100 ± 60 14C yrs BP (12,990 ± 80 cal yrs BP), were obtained from wood in deformation (soft) till exposed beneath flow and lodgment till in Bahía del Quemado on the northeast side of Brazo Norte (North Branch) of western Lago Argentino. Other exposures of this basal deformation till in Bahía del Quemado reveal incorporated clasts of peat, along with larger inclusions of deformed glaciofluvial and lacustrine deposits. Radiocarbon dates of wood included in these reworked peat clasts range from 11,450 ± 45 14C yrs BP to 13,450 ± 150 14C yrs BP (13,315 ± 60 to 16,440 ± 340 cal yrs BP). The implication is that, during this interval, glacier fronts were situated inboard of the Puerto Bandera moraines, with the peat clasts and larger proglacial deposits being eroded and then included in the basal till during the Puerto Bandera advance.Minimum-limiting radiocarbon ages for ice retreat come from basal peat in cores sampled in spillways and depressions generated during abandonment of the Puerto Bandera moraines. Glacier recession and subsequent plant colonization were initiated close behind different frontal sectors of these moraines prior to: 10,750 ± 75 14C yrs BP (12,660 ± 70 cal yrs BP) east of Brazo Rico, 10,550 ± 55 14C yrs BP (12,490 ± 80 cal yrs BP) in Peninsula Avellaneda, and 10,400 ± 50 14C yrs BP (12,280 ± 110 cal yrs BP) in Bahía Catalana. In addition, a radiocarbon date indicates that by 10,350 ± 45 14C yrs BP (12,220 ± 110 cal yrs BP), the Brazo Norte lobe (or former Upsala Glacier) had receded well up the northern branch of Lago Argentino, to a position behind the Herminita moraines. Furthermore, glacier termini had receded to just outboard of the outer Holocene moraines at Lago Frías and Lago Pearson (Anita) prior to 10,400 ± 40 14C yrs BP (12,270 ± 100 cal yrs BP) and 9040 ± 45 14C yrs BP (10,210 ± 50 cal yrs BP), respectively. The most extensive recession registered during the early Holocene was in Agassiz Este Valley, where the Upsala Glacier had pulled back behind the outer Holocene moraine, reaching close to the present-day glacier terminus before 8290 ± 40 14C yrs BP (9300 ± 80 cal yrs BP).The radiocarbon-dated fluctuations of the Lago Argentino glacier in late-glacial time, given here, are in accord with changes in ocean mixed layer properties, predominately temperature, derived from the isotopic record given here of ODP Core 1233, taken a short distance off shore of the Chilean Lake District. It also matches recently published chronologies of late-glacial moraines in the Southern Alps of New Zealand on the opposite side of the Pacific Ocean from Lago Argentino. Finally, the timing of the late-glacial reversal of the Lago Argentino glacier fits the most recent chronology for the culmination of the Antarctic Cold Reversal (ACR) in the deuterium record of the EPICA Dome C ice core from high on the East Antarctic Plateau. Therefore, we conclude that the climate signature of the ACR was widespread in both the ocean and the atmosphere over at least the southern quarter of the globe.  相似文献   

13.
The solubility of bunsenite (NiO) in Cl-bearing fluids in the range of 450°–700°C, 1–2 kbar was determined using the Ag + AgCl acid buffer technique. Based on the results of the experiments, it is concluded that the associated NiCl02 complex is the dominant Ni species in the fluid over the entire temperature-pressure range investigated. The temperature dependence of the equilibrium constant for the reaction NiO(s) + 2HCl0(aq) = NiCl02(aq) + H2O is given by logK = ?4.17(±0.55) + 4629(±464)/T(K) at 1 kbar, and logK = ?4.75(±0.91) + 5933(±756)/T(K) at 2 kbar. The calculated difference in standard state Gibbs free energy of formation between NiCl02 and 2HCl0 in kcal is G0(NiCl02) ? 2G0(HCl0) = ?20.77(±2.22) + 0.03264(±0.0026)T(K), at 1 kbar and G0(NiCl02) ? 2G0(HCl0) = ?25.01(±1.35) + 0.03264(±0.0016)T(K) at 2 kbar. Comparison of the solubilities of Ni end-member minerals with those of Ca, Mn, Fe, and Mg indicates that nickel minerals generally are the least soluble at a given temperature and pressure. The relatively low solubility of Ni end-member minerals, combined with the relatively low concentration of Ni in most rocks, should result in a quite low mobility of Ni in hydrothermal fluids.  相似文献   

14.
为厘清内蒙古林西县会长地一带出露的一套生物化石匮乏的砂砾岩组合的地质时代、地层归属及其碎屑物质来源,进而探讨西拉木伦河缝合带的形成演化,对研究区砂岩样品进行了碎屑锆石LA-ICP-MS U-Pb年代学研究。测试结果主要分布在6个年龄区间:(285±4)~(246±4) Ma (峰值为264 Ma)、(317±5)~(293±4) Ma (峰值为310 Ma)、(610±10)~(344±6) Ma (主峰值为423 Ma)、(992±14)~(907±13) Ma、(1 467±18)~(1 424±22) Ma、(1 948±14)~(1 768±16) Ma,另具3颗年龄分别为(1 171±17)、(1 238±17)和(2 443±31) Ma的锆石。锆石CL图像与Th/U值共同指示绝大多数锆石为岩浆结晶锆石。264 Ma的峰值年龄限定了地层的沉积下限为晚二叠世,应属林西组;沉积物源区示踪显示砂岩沉积时具佳蒙板块(北方地块群)与华北板块两个物源区,指示佳蒙板块(北方地块群)与华北板块于晚二叠世时已拼合,拼合位置为西拉木伦河一线。  相似文献   

15.
The geology and tectonics in the eastern margin of Tibetan Plateau are complex. The main tectonic framework is composed of blocks and faults. Using discontinuous global positioning system survey data for 2008–2014, the velocity field for the Eurasia reference framework was obtained. Based on the velocity field, the present-day velocities of the blocks and boundary faults were estimated. The results reveal that the movement rates of the Chuan-Qing, South China, Chuan-Dian and Indo-China blocks are(17.02±0.60) mm/a,(8.77±1.51) mm/a,(13.85±1.31) mm/a and(6.84 ± 0.74) mm/a, respectively, and their movement directions are 99.5°, 120.3°, 142.9° and 153.3°, respectively. All blocks exhibit clockwise rotation. The displacement rates of the Xianshuihe, Longmenshan, Anninghe, Zemuhe, Xiaojiang and Red River faults are(7.30±1.25–8.30±1.26) mm/a,(10.07±0.97–11.79±0.89) mm/a,(0.96±0.74–2.98±1.73) mm/a,(2.03±0.49–3.20±0.73) mm/a,(3.45±0.40–6.02±0.50) mm/a and(6.23±0.56) mm/a, respectively. The Xianshuihe, Anninghe, Zemuhe and Xiaojiang faults show leftlateral strike-slip movement, while the Longmenshan and Red River faults show right-lateral strikeslip. These characteristics of the blocks and faults are related to the particular tectonic location and dynamic mechanism.  相似文献   

16.
磷灰石微区原位LA-MC-ICP-MS U-Pb同位素定年   总被引:5,自引:0,他引:5  
利用激光剥蚀多接收器电感耦合等离子体质谱法(LA-MC-ICP-MS), 建立了磷灰石微区原位U-Pb同位素定年新方法, 本文给出了这一新方法的分析流程, 报道了利用这一新方法对5个磷灰石样品的分析结果, 并应用同位素稀释-热电离质谱法(ID-TIMS)对一些样品定年结果进行了验证。磷灰石工作标样SDG的U-Pb同位素年龄: (1596±15) Ma (MSWD=1.5, n=7, LA-MC-ICP-MS), (1602±13) Ma (MSWD=0.578, n=5, ID-TIMS); 某铁矿石中磷灰石的LA-MC-ICP-MS U-Pb同位素年龄: (125±14) Ma (MSWD=0.68, n=25), (124.2±3.5) Ma (MSWD=1.5, n=37); 新疆阿尔金地区片麻岩中磷灰石的LA-MC-ICP-MS U-Pb同位素年龄: (250.8±3.9) Ma (MSWD=8.6, n=26), (245.4±2.9) Ma (MSWD=2.1, n=39)。  相似文献   

17.
Grain-to-grain and stylolitic solution structures in two central Appalachian Siluro–Devonian limestone macroscale folds contain one of four distinct mineral assemblages that are characterized by the dominant iron-phase mineral present: (1) chlorite±illite±pyrite±calcite±quartz±TiO2±goethite, (2) chlorite±illite±pyrite altered to iron oxide/hydroxide±calcite ±quartz±TiO2, (3) chlorite±illite±magnetite±calcite±quartz, and (4) chlorite±illite±goethite±calcite±quartz±TiO2. Optical reflectance microscopy and SEM–EDS was used to characterize the mineralogy and mineral morphology of these structures. Geochemical modeling was used to constrain the conditions of formation and preservation.The primary control on solution structure mineral assemblage was the redox conditions present in the solution structures during burial and deformation. The redox conditions on the microscale may have been controlled by the local fluid chemistry and the presence–absence of hydrocarbons and organic acids within the formation fluids, and the influx of externally derived fluids by fracture formation during the folding process. The wide variation in mineralogy of the solution structures shows that they were ‘chemical factories’ where a variety of chemical reactions took place during rock dissolution. In particular, the formation of authigenic magnetite in solution structures has significant implications for paleomagnetic applications, and use of anisotropy of anhysteretic remanent magnetization and anisotropy of magnetic susceptibility fabrics.  相似文献   

18.
Microstructural measurements of FIAs in staurolite reveal at least 3 periods of growth in the Proterozoic Colorado Front Range and 5 in the Paleozoic Western Maine. Dated monazite inclusions in staurolite have an absolute age of 1760±12 Ma (FIA 1), 1720±7 Ma (FIA 2), 1682±18 Ma (FIA 3) in Colorado, and 408±10 Ma (FIA 2), 388±8 Ma (FIA 3), 372±6 Ma (FIA 4), 352±4 Ma (FIA 5) in Maine, supporting the multiple periods of deformation and metamorphism indicated by the FIA succession in each region. Multiple phases of growth by similar reactions in the same as well as in diverse adjacent rocks in both regions suggest that PT and X are not the only factors controlling the commencement and cessation of metamorphic reactions. The FIAs preserved by the staurolite porphyroblasts indicate that the local partitioning of deformation at the scale of a porphyroblast was the eventual controlling factor on whether or not the staurolite forming reactions took place.  相似文献   

19.

The age data (U–Pb, SHRIMP II) of zircons from rutile eclogites of the Maksutov Complex (MC) (village Shubino, Southern Urals) were subdivided into three age groups. The Neoproterozoic zircons (561 ± 10 Ma) recorded the formation stage of eclogites, the protolith of which was diabase and gabbro-diabase bodies. The Neoarchean ancient zircons (2884 ± 36 Ma) belong to the mantle substratum, which was repeatedly transformed (2303 ± 12, 2008 ± 18, 1626 ± 59 Ma). Zircons of early Ordovician–early Silurian age (433–477 ± 6 Ma; 340 ± 40 Ma) recorded superimposed processes, corresponding to high-pressure metamorphism.

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20.
1 Introduction Metallogenic chronology is one of the keys in the research of mineral deposits. Determination of metallogenetic epoch is very important for understanding the relationships between mineralization and regional tectonomagmatic events, in studying the origin of mineral deposits, and for summarizing regional mineralization and instructing regional prospecting. The eastern Liaoning region hosts the main concentration of boron resources in China. The boron reserve in eastern Liaoning…  相似文献   

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