鲁西北平原地下水高氟与高碘成因分析

地下水作为鲁西北平原的主要水源,查明高氟、高碘地下水的成因和联系十分必要,可为当地的饮用水安全及解决地方病的研究提供借鉴。目前中国对鲁西北地区浅层高氟地下水的研究较多,但对深层高氟地下水的成因、高氟地下水和高碘地下水的联系有待加强。本文旨在揭示鲁西北平原地下水中氟与碘的空间分布特征,推测高氟地下水的形成机制,查清碘在地下水系统中富集的关键水文地球化学过程,探讨地下水中高氟与高碘的关系。采集浅层（0～55m）、中层（55～225m）、深层（＞225m）地下水样品326件,并对18个水化学参数进行层次聚类分析,将地下水样品划分为高氟地下水、高碘地下水和高氟高碘地下水。再结合常规水化学指标和沉积物组分特征进行相关性分析,探讨高氟、高碘地下水的成因及联系。结果表明：高氟地下水与高碘地下水通常伴生出现,且高氟地下水和高碘地下水分布区水化学环境类似,高氟地下水主要集中在地面以下0～40m、50～110m以及225～305m深度内,其最大值（13.71mg/L）出现在地面以下110m深度处;高碘地下水主要集中在地面以下0～10m、55～65m以及225～285m深度内,其最大值（4.601mg/L）出现在234m深度处。含氟矿物萤石（CaF2）的溶解、强烈的蒸发浓缩作用、离子交换可能是高氟地下水的主要形成机制;地下水中的碘主要来自鲁西北平原沉积物中海洋生物和有机质,地下水受强烈的蒸发作用,水走盐留,水中碘浓度不断增加,沉积物淋溶以及氨氮和硫化物的还原溶解可能是导致地下水高碘的主要过程,弱碱性的水环境、还原条件和有机质的存在都是高碘水形成的重要因素。研究区强烈的蒸发浓缩作用、弱碱性的还原条件同时促进了氟和碘的富集。     

Hydrogeochemical analysis of salinization processes in the coastal aquifer of Oropesa (Castellón, Spain)

 The coastal aquifer of Oropesa is affected by salinization processes undoubtedly associated with intense groundwater exploitation for agriculture supply. The aquifer corresponds geologically to a tectonic depression with Plioquaternary fill. Hydrogeologically, this aquifer is detrital, with intergranular porosity, which receives substantial recharge from adjacent Mesozoic aquifers. Contact with the sea, in addition to the presence of cultivated soil requiring extreme exploitation of groundwater, frequently give rise to processes of seawater intrusion. The present research is an attempt to understand the saltwater intrusion in this aquifer, using hydrochemical analyses of the behavior of certain minor ions that could help in the characterization process. In the case of the Oropesa sector, groundwater salinization does not appear to be attributable solely to the intrusion of seawater, but there are also anomalies related largely to the geology of the sector and its surroundings, the type of recharge, the hydrodynamic conditions in the specific area, etc. Received: 23 January 1995 · Accepted: 12 September 1995     

Palaeoenvironmental analysis of Cenomanian-Turonian dinocyst assemblages from the Castilian Platform (Northern-Central Spain)

The palynological assemblages from three Cenomanian-Turonian sections from the Castilian Platform are described. The 49 levels analysed yielded a well-diversified palynological content including dinoflagellate cysts, acritarchs, prasinophytes and miospores. The comparison of the terrestrial and marine assemblages from these three sections reveals significant differences that are mainly related to their relative palaeogeographical locations. The quantitative study performed on dinocyst assemblages suggests an association interpreted as inner neritic including Xenascus ceratioides, Cribroperidinium exilicristatum, Canningia reticulata and Kallosphaeridium? ringnesiorum. On the contrary, the group inferred to show outer neritic preferences is integrated by Palaeohystrichophora infusorioides, Spiniferites spp., Odontochitina spp., Trichodinium castanea and Impletosphaeridium polytrichum. In the Castilian Platform, the Cenomanian-Turonian Boundary Event (CTBE) may be manifested by a higher proportion of Cyclonephelium spp. in the distal dinocyst assemblages.     

A new titanosaur (Dinosauria,Sauropoda) from the Upper Cretaceous of Lo Hueco (Cuenca,Spain)

The upper Campanian-lower Maastrichtian site of Lo Hueco (Cuenca, Spain) has provided a set of well-preserved partial skeletons in anatomical connection or with a low dispersion of their skeletal elements. One partial skeleton is herein described and a new titanosaurian sauropod is established, Lohuecotitan pandafilandi. This titanosaur is diagnosed by eight autapomorphic features: dorsally and ventrally widened or bifurcated posterior centrodiapophyseal lamina in anterior and middle dorsal vertebrae; short postspinal lamina with a transversely expanded distal end represented by smooth scars in the dorsal vertebrae; anteriormost caudals with the medial spinoprezygapophyseal and medial spinopostzygapophyseal laminae ventrally connected with the prespinal and postspinal laminae, respectively; anterior caudal neural spines with a dorsal projection of the prespinal and postspinal laminae; anterior caudal neural spines bears a “greek-cross”-like cross-section; middle caudal centra having two round and rough structures in the dorsal edge of the posterior articulation, which extends to the dorsal surface of the centrum; the articular ends of the rami of the haemal arches are divided in two articular surfaces; and tuberosity between the anterior and the lateral trochanter of the fibula. The herein performed phylogenetic analysis considered L. pandafilandi as a member of Lithostrotia more derived than Malawisaurus. The known palaeodiversity of the Late Cretaceous Ibero-Armorican titanosaurs is increasing, and further analyses focused on this group will be necessary to better understand the evolutionary history of European titanosaurs and to clarify their relationships within Titanosauria.     

Historical analysis of heavy metal pollution in three estuaries on the north coast of Galicia (NW Spain)

This research focuses on the development of metal pollution in sediment cores from three estuaries in Northwest Spain: Viveiro, Ortigueira and Barqueiro. Pb, Cu, Co, Cr, Cd and Zn and total organic carbon were assessed using principal component analysis (PCA) in order to obtain background values, measure pollution levels and identify pollution sources. Results were interpreted by considering the local industrial history, grain size and C/N relationship. The pollution levels obtained bear a strong resemblance to those documented for of a moderately industrialised area. PCA identifies factors that reflect mainly temporal associations with metals. Sedimentation rates between 0.9 and 1.1 cm/year were determined. In Viveiro core levels of Cr pollution are associated with tanneries. In Ortigueira, high core levels of Cu and Co are linked to mining, and Cr levels to adjacent ultramafic rocks. Erosion of Holocene sediment causes high values of Co and Cr in the Barqueiro core. Cu increase in the three estuaries is related to fungicide use since 1910. Sea level rise appears to be affecting the marine characteristics of the sediments in Barqueiro. In Viveiro, the nature of the sediment reflects engineering work and land reclamation.     

Centuries of artificial recharge on the southern edge of the Sierra Nevada (Granada,Spain)

In the Alpujarra (southern Spain), every year between the March and June, an ancestral practice continues in the form of diverting water from the rivers by way of an extensive network of irrigation channels (acequias) to well-defined, highly permeable areas. This practice, known ascareos, constitutes an ancient example of artificial recharge. The objective is to guarantee a supply of drinking water during the dry months, as well as improve the physicochemical characteristics of the water. In addition, this system helps maintain moisture in the immediate environment, and thus has a positive effect on local vegetation.     

Perinates of a new species of Iguanodon (Ornithischia: Ornithopoda) from the lower Barremian of Galve (Teruel,Spain)

Although Iguanodon is one of the most abundant and well-known of Europe's dinosaur genera, fossils of young specimens are very rare. Indeed, the fossil record contains very few examples of the young of any non-hadrosaurid iguanodontian. Here we report the discovery of 13 Iguanodon perinates from the Lower Cretaceous of Galve (Teruel, Spain). The characteristics of an adult and juvenile found nearby show these perinates to belong to a new species: Iguanodon galvensis sp. nov. The histological and osteological features of these young animals indicate them to have been in their first year of life. The taphonomic features of their remains, plus the finding of clearly embryonic vertebrae alongside them, suggest the perinates of this species remained in the vicinity of their nests for some time, possibly congregating in nursery areas.     

Early Serpukhovian (late Mississippian) microflora from the Guadiato Area (southwestern Spain)

Calcareous microflora occur commonly in the early Serpukhovian (late Mississippian) rocks from the Guadiato Area (southwestern Spain) despite the fact that this area contains mostly siliciclastic sediments. The microflora recorded in the carbonate beds is regarded as representative of both relatively deep‐water and shallow‐water facies and can be compared with the slope and shelf facies environments distinguished in the Guadiato Area. Up to 45 algal taxa have been identified in the carbonate beds, of which 26 taxa occur in the relatively deep‐water assemblages, whereas the shallow‐water assemblages are composed of up to 43 taxa. The entire algal assemblage is dominated by calcifoliids, common cyanobacteria and incertae sedis, but the shallow‐water assemblages contain more commonly dasyclads, red algae and aoujgaliids. Most of these taxa are present, but poorly known, in other Serpukhovian carbonate platforms in the western Palaeotethys. Some algae (Hortonella uttingii, Kamaenella tenuis and Koninckopora inflata), usually regarded as being restricted to the Viséan, have been found in Serpukhovian rocks in the Guadiato Area, and also in Algeria, thus their stratigraphic ranges might be extended up to the Serpukhovian. Other important taxa include: Archaeolithophyllum, Cabrieropora, Calcifolium, Falsocalcifolium, Fourstonella, Frustulata, Kulikia, Neoprincipia and ‘Windsoporella’, which are exceptionally recorded in Serpukhovian rocks, or not recorded at all, because they are typically recorded in the Pennsylvanian (cf. Clavaporella), although some of them show earlier occurrences in Viséan rocks (Claracrusta, Paraepimastopora and Sparaphralysia). Some of the algal taxa can be considered as potential regional markers for the Serpukhovian, such as Archaeolithophyllum, cf. Clavaporella, Frustulata and Girvanella (?) sp. The algal assemblages found in the Guadiato Area show the greatest similarities with those in the Béchar‐Mézarif (Algeria), Pyrenees and Montagne Noire (southern France). Copyright © 2005 John Wiley & Sons, Ltd.     

Biting midges (Diptera: Ceratopogonidae) from the Early Cretaceous El Soplao amber (N Spain)

Three new species, Lebanoculicoides excantabris, Archiaustroconops borkenti, and Atriculicoides szadziewskii are described from the Early Cretaceous (early Albian) El Soplao amber deposit (Rábago, Cantabria, northern Spain). Protoculicoides skalskii Szadziewski and Arillo, found in the other Albian Spanish ambers from Peñacerrada I (in Burgos) and San Just (in Teruel), and Austroconops sp., are identified from this new outcrop. The find of a new species of Lebanoculicoides Szadziewski is especially significant since this genus is considered the basalmost known among ceratopogonids. To date, the new species of Atriculicoides Remm is the oldest occurrence for this genus. A general review of the taxonomy and phylogeny of the family Ceratopogonidae, and the palaeoecological significance and palaeogeographic distribution of its basalmost lineages are given. The new data extend knowledge about biting midges during the Early Cretaceous, a key period for understanding the phylogenetic relationships of the ancient members of the family.     

Organic matter accumulation during the Holocene in the Guadalquivir marshlands (SW Spain)

The distribution of biomarker compounds and magnetic susceptibility observed in the sediment from a 20 m core drilled in the marshlands of the estuarine region of the Guadalquivir River (southwest coast of Spain) has allowed us to reconstruct the palaeoenvironmental evolution of this area during the Holocene. Several organic compounds (n‐alkanes, n‐ketones, n‐alkanols, n‐alkanoic acids and organic sulphur), as well as different biomarker ratios, have been used to show changing environmental conditions through time. These geochemical proxies suggest good preservation of the organic matter, although some diagenesis has occurred to particular organic compounds, especially the n‐alkanoic acids. Our data indicate a major allochthonous supply of terrestrial plants, with less influence from aquatic plants or algae through the core. There are markedly different palaeoenvironmental conditions between the uppermost 5 m (last 6 ka cal. B.P.) and the rest of the core. From 5 m (ca 6 ka cal. B.P.) to 19 m (ca 8 ka cal. B.P.) depth the palaeoenvironmental conditions were almost constant. Based on organic sulphur content and n‐alkane content logs, anoxic conditions prevailed from 8 to 6 ka cal. B.P., while oxic conditions with enhanced convection of water (prevalence of fluvial input), and consequently a greater organic matter supply, predominated in the upper 5 m of the core. Similarly, little variation in the magnetic susceptibility profile below 5 m indicates stable environmental conditions, while in the upper 5 m conditions shifted to one with elevated water input and clastic sediment supply. This is linked to palaeofloral alterations in the Guadiamar/Guadalquivir drainage basins and/or anthropogenic effects. We propose that from ca 8 to 6 ka cal. B.P. a stable landscape physiognomy in the surroundings of the estuarine area of the Guadalquivir River, with a predominance of pines and grassland. However, over the last 6 ka cal. B.P. a variation in the terrestrial plant biomarker compounds suggests an alternation of relatively dry and humid phases and/or the impact of human populations on altering the vegetation community have occurred. Copyright © 2007 John Wiley & Sons, Ltd.     

Earliest record of semi-aquatic fern leaves (Family Marsileaceae) in the Mesozoic of Eurasia (Lower Cretaceous,Spain)

In this paper we present new macrofossils of semi-aquatic fern Family Marsileaceae consisting of leaves and leaflets from the upper Hauterivian- lower Barremian Pinilla de los Moros Formation, Salas de los Infantes village, Burgos province, north of Spain. The leaves show two elliptic to flabellate-shaped leaflets that are joined to a petiole. Leaflets present entire margins and dichotomous anastomosed vein pattern. Comparison between the studied leaves and other marsileaceous leaves indicates close similarities with Regnellites nagashimae species. These leaves were deposited in a related fluvial environment near to the place where semi-aquatic plants grew. The studied macrofossils constitute at present the earliest record of leaves of Family Marsileaceae in the Mesozoic of Eurasia at the moment.     

Geology and rural landscapes in central Spain (Guadalajara, Castilla—La Mancha)

Methods commonly used in regional geological analysis were employed to study the visual landscapes of the Sigüenza–Molina de Aragón area (Spain). Landscape data were compiled to produce a landscape map and a photograph catalogue. Lithological composition, tectonic structure and recent erosive processes are the main factors controlling the visual landscapes. Territorial properties, such as colours and agricultural capacities, are controlled by these geological characteristics. The landscape map and the photographic catalogue is the main contribution of this paper. The first level of landscape classification distinguishes zones with dominance of either flat, concave or convex areas. Other parts of the territory are, however, composed of concave and convex combinations that originate hybrid orographic structures. In a second level of classification, several subdivisions for each of these types are established.     

New Cretaceous Scoliidae (Vespida=Hymenoptera) from the Lower Cretaceous of Spain and Brazil

A new genus, Cretaproscolia, and three new species of scoliid wasps, Archaeoscolia hispanica, Cretoscolia montsecana and Cretaproscolia josai, are described from the Lower Cretaceous of Spain and Brazil. The species representing the new genus is attributed to the plesiomorphic extant subfamily Proscoliinae, while the two other new species are assigned to two previously described genera in the extinct, archaic subfamily Archaeoscoliinae. The Brazilian species is the first Mesozoic scoliidid to have been described from the New World.     

A case of successful soil geochemistry: the Rubiales Zn-Pb orebody (NW Spain)

The Rubiales Zn-Pb orebody (NW Spain) is a blind deposit developed in a vertical shear zone during the Variscan Orogenesis. It is about 1200 m long in a N-S direction, with an average thickness of 30 m, and is hosted by lower Cambrian limestones and slates, with some quartzite beds. The deposit has a large hydrothermal alteration aureole. The silicified halo contain sphalerite and galena disseminations, with grades between 0.2 and 3% Pb + Zn.The Rubiales orebody was discovered in the late 60s following a soil geochemical survey. In the regional phase of the survey, 28,622 samples were collected in 57 lines; two of the lines over the Rubiales zone yielded 1400 ppm Pb and 1550 ppm Zn. In a local phase, centred on the anomalous zone, 1716 samples were collected in 21 lines. This local survey defined the geochemical anomalies that were subsequent drill-hole targets. Based on 38 surface-holes, geological ore reserves of 18.6 million tons, with 8.6% Zn + Pb, were estimated.Residual soil geochemical anomalies of Zn and Pb were developed over the silicification zone. The Zn anomaly has a greater extent than the Pb anomaly, due to the greater Zn mobility in surficial environments. The Zn and Pb anomalies exhibit an asymmetrical morphology, with greater extent to the south, due to the down slope creep of residual anomalies. The main cross-faults present in the deposit also control the morphology of the anomalies, as a result of Zn and Pb mobilisation and transport by ground waters along the cross-faults. The Cu anomaly defines two maxima over the feeder zones to the orebody. The two feeder zones, also in the silicification zone, are extensively brecciated and contain the highest grades of the deposit (∗> 20% Zn + Pb) and disseminated chalcopyrite.     

New discoveries of vertebrate remains from the Triassic of Riba de Santiuste,Guadalajara (Spain)

The palaeontological sites of Riba de Santiuste and Sienes (Riba de Santiuste area) are located in the province of Guadalajara, Spain. They include a stratigraphic interval in Muschelkalk facies belonging to the “Cuesta del Castillo Sandstones” Formation and “Royuela Dolostones, Marls and Mudstones” Formation. These sites include numerous fossil plants, direct vertebrate remains, and vertebrate swim traces. The vertebrate remains correspond to a multitude of anatomical elements of Sauropterygia (Nothosauroidea, Placodontia) and possible Archosauria (Rauisuchia) remains. The fossil material attributed to nothosaurs includes teeth, coracoids, a thoracic vertebra, some isolated vertebral centra, humerus, rib fragments, and some dorsal and caudal vertebrae. The remains attributed to placodonts correspond to fragments of skull, quadrate, teeth and osteoderms. Other undetermined sauropterygian remains, such as ulnas, fragments of long bones, fragments of ribs, and articular facets of ribs have been also recovered. Additionally, a fragment of mandible and an intervertebral disk of indeterminate reptiles whose size could be compatible with archosaurs are also described. These bones are exceptionally well-preserved because the fossilization processes have preserved the microstructure of the tissues. The sites also show vertebrate traces, with parallel scratch impressions interpreted as swim traces. The relative stratigraphic position and the palaeontological content of these sites suggest a Ladinian age (Middle Triassic). The interpretation of the sedimentary facies here described also suggests that the sites could correspond to detrital-carbonate mixed deposits of coastal intertidal to supratidal environments.     

Chemical mass balance of calcrete genesis on the Toledo granite (Spain)

The chemical mass balance of calcrete genesis is studied on a typical sequence developed in granite, in the Toledo mountains, Central Spain.

Field evidence and petrographic observations indicate that the texture and the bulk volume of the parent rock are strictly preserved all along the studied calcrete profile.

Microscopic observations indicate that the calcitization process starts within the saprolite, superimposed on the usual mechanisms of granite weathering: the fresh rock is first weathered to secondary clays, mainly smectites, which are then pseudomorphically replaced by calcite. Based on this evidence, chemical mass transfers are calculated, assuming iso-volume transformation from the parent rock to the calcrete.

The mass balance results show the increasing loss of matter due to weathering of the primary phases, from the saprolite towards the calcrete layers higher in the sequence. Zr, Ti or Th, which are classically considered as immobile during weathering, are also depleted along the profile, especially in the calcrete layer. This results from the prevailing highly alkaline conditions, which could account for the simultaneous precipitation of CaCO₃ and silicate dissolution.

The calculated budget suggests that the elements exported from the weathering profile are provided dominantly by the weathering of plagioclase and biotite. We calculate that 8–42% of the original Ca remains in granitic relics, while only 15% of the authigenic Ca released by weathering is reincorporated in the calcite. This suggests that 373 kg/m² of calcium (i.e., three times the original amount) is imported into the calcrete from allochtonous sources, probably due to aeolian transport from distant limestone formations.     

Quantitative subsidence-uplift analysis of the Bajo Segura Basin (eastern Betic Cordillera, Spain): tectonic control on the stratigraphic architecture

The Bajo Segura Basin is located in the eastern Betic Cordillera, at present connected with the Mediterranean Sea to the east. It has a complete stratigraphic record from the Tortonian to the Quaternary, which has been separated into six units bounded by unconformities. This paper is concerned with the northern edge of the basin, controlled by a major strike–slip fault (the Crevillente Fault Zone, CFZ), where the most complete stratigraphic successions are found. The results obtained (summarised below) are based on an integrated analysis of the sedimentary evolution and the subsidence-uplift movements. Unit I (Early Tortonian) is transgressive on the basin basement and is represented by ramp-type platform facies, organised in a shallowing-upward sequence related to tectonic uplift during the first stages of movement along the CFZ. Unit II (lower Late Tortonian) consists of shallow platform facies at bottom and pelagic basin facies at top, forming a deepening-upward sequence associated with tectonic subsidence due to sinistral motion along the CFZ. Unit III (middle Late Tortonian) is made up of exotic turbiditic facies related to a stage of uplift and erosion of the southern edge of the basin. Unit IV (upper Late Tortonian) consists of pelagic basin facies at bottom and shallow platform facies at top, defining a shallowing-upward sequence related to tectonic uplift during continued sinistral movement on the basin-bounding fault. Units V (latest Tortonian–Messinian) and VI (Pliocene–Pleistocene p.p.) consist of shallowing-upward sequences deposited during folding and uplift of the northern margin of the basin. No definitive evidence of any major eustatic sea-level fall, associated with the ‘Messinian salinity crisis’, has been recorded in the stratigraphic sections studied.     

The axial skeleton of the titanosaur Lirainosaurus astibiae (Dinosauria: Sauropoda) from the latest Cretaceous of Spain

Lirainosaurus astibiae was originally described by Sanz and collaborators in 1999 on the basis of a skull fragment, isolated teeth, several vertebrae (e.g. the holotypic anterior caudal vertebra) and appendicular bones from the Late Cretaceous of Laño (northern Spain). A review of all the vertebral remains, including new material (cervical, dorsal and caudal vertebrae, dorsal ribs, haemal arch), provides additional information about the axial skeleton of Lirainosaurus. A study of the laminae and fossae shows interesting variations in these structures in the axial series, especially concerning the prezygapophyses and diapophyses: e.g. the X-shaped morphology of the centroprezygapophyseal lamina only in the posterior dorsal vertebrae, and the division of the postzygodiapophyseal fossa into two fossae in the posterior dorsal vertebrae and the proximal caudal vertebrae. Two vertebral characters are here considered to be autapomorphic for L. astibiae: the presence of a lamina in the interzygapophyseal fossa in the most proximal caudal vertebrae (a postzygodiapophyseal lamina that separates the ventral postzygapophyseal centrodiapophyseal fossa and the dorsal postzygapophyseal spinodiapophyseal fossa), and the spinopostzygapophyseal structure not posteriorly projected in the posterior caudal vertebrae. The combination of characters present in the axial remains of Lirainosaurus astibiae supports the idea that it is a derived lithostrotian close to Saltasaurinae.