Facies analysis and depositional environments of the Oligocene–Miocene Asmari Formation, Zagros Basin, Iran

The Asmari Formation(a giant hydrocarbon reservoir)is a thick carbonate sequence of the Oligocenee Miocene in the Zagros Basin,southwest of Iran.This formation is exposed at Tang-e-Lendeh in the Fars interior zone with a thickness of 190 m comprising medium and thick to massive bedded carbonates.The age of the Asmari Formation in the study area is the late Oligocene(Chattian)eearly Miocene(Burdigalian).Ten microfacies are defned,characterizing a gradual shallowing upward trend;the related environments are as follows:open marine(MF 8e10),restricted lagoon(MF 6e7),shoal(MF 3e5),lagoon(MF 2),and tidal fat(MF 1).Based on the environmental interpretations,a homoclinal ramp consisting of inner and middle parts prevails.MF 3e7 are characterized by the occurrence of large and small porcelaneous benthic foraminifera representing a shallow-water setting of an inner ramp,infuenced by wave and tidal processes.MF 8e10,with large particles of coral and algae,represent a deeper fair weather wave base of a middle ramp setting.     

http://www.sciencedirect.com/science/article/pii/S1674987111000600

Detailed studies on Late Devonian to Early Carboniferous carbonate rocks in central Hunan, southern China have led to the recognition of 25 lithofacies which can be grouped into:(1) inner ramp peritidal platform,(2) inner ramp organic bank and mound.(3) mid ramp,(4) outer ramp,and(5) shelf basin fades associations.The peritidal platform fades association dominates the Zimenqiao Formation (Namurian A or late Datangian) and is characterized by gypsum and dolostone-containing sequences, indicating a peritidal platform environment.The other four fades associations dominate the Menggongao Formation(late Famennian).Liujiatang Formation(Tournaisian or Yangruanian).Shidengzi Formations (early Visean or early Datangian).Five upward-shallowing cycles were distinguished in these three Formations.The predominant fades associations developed in each Formation demonstrate an overall transgression-regression cycle in the Late Devonian to Early Carboniferous in central Hunan.The overall transgressive sequence was preserved in the Shaodong.Menggongao.and Liujiatang Formations,and the overall regressive sequence was preserved in the Liujiatang.Shidengzi.Ceshui and Zimenqiao Formations.     

http://www.sciencedirect.com/science/article/pii/S1674987111000478

Convective heat transfer associated with the circulation of pore-fluid in porous rocks and fractures within the upper crust of the Earth is substantial when the temperature gradient is sufficiently high.In order to understand the process of Sn-polymetallic mineralization in the Dachang ore district of Guangxi,a finite element method has been used in this study to simulate both pore-fluid flow and heat transfer in this district.On the basis of related geological,tectonic and geophysical constraints,a computational model was established.It enables a computational simulation and sensitivity analysis to be carried out for investigating ore-forming pore-fluid flow and other key factors that may affect hydrothermal ore genesis in the district.The related simulation results have indicated that:(1) permeable fault zones in the Dachang ore district can serve as preferential pathways for pore-fluid flow on a regional-scale;and(2) the pore-fluid flow can affect the salinity distribution.This latter factor is part of the reason why Sn-polymetallic mineralization has taken place in this district.     

http://www.sciencedirect.com/science/article/pii/S1674987114000589

At peak granulite-facies metamorphic conditions, lower continental crust is arguably fluxed by large amounts of two key low water activity fluids： （i） high-density CO2 and/or （ii） concentrated saline so- lutions. These fluids are either internally-derived, generated by mineral reactions or dehydration melting or, notably for CO2, externally-derived, issued from the underlying mantle. Postmetamorphic evolution results in complete disappearance of these fluids, except for minute remnants preserved in minerals as fluid inclusions. Two major processes are involved： （i） at peak conditions, granitoid magmas form, migrate upward, and crystallize as shallow intrusions in the upper crust （mineralized porphyry types or reduced intrusions）; （ii） during the rapid decompression which almost systematically follows a period of post-peak isobaric cooling, especially for ultrahigh-temperature granulites （anticlockwise P-T paths）, quartz-carbonate megashear zones are formed by repeated periods of seismic activity. Seismic activity may continue until all free fluids have disappeared, resulting in the ultramylonites and pseudotachylites that are found in many granulite domes. A great majority of vein-type Au deposits worldwide occur in the above-mentioned settings or nearby. We suggest that the Au has been scavenged by the granulite fluids, then redistributed and concentrated during the formation of veins and related phenomena.     

http://www.sciencedirect.com/science/article/pii/S1674987110000368

In this paper,we show that geo-anomalies can be delineated for mineral deposit prediction according to singularity theories developed to characterize nonlinear mineralization processes.Associating singularity and geo-anomalies makes it possible to quantitatively study geo-anomalies with modern nonlinear theories and methods.This paper introduces a newly developed singularity analysis of nonlinear mineralization processes and nonlinear methods for characterizing and mapping geo-anomalies for mineral depos...     

http://www.sciencedirect.com/science/article/pii/S1674987112001478

REE composition of the carbonates of the auriferous quartz carbonate veins (QCVs) of the Neoarchean Ajjanahalli gold deposit, Chitradurga schist belt, Dharwar Craton, is characterized by U-shaped chondrite normalized REE patterns with both LREE and HREE enrichment and a distinct positive Eu anomaly. As positive Eu anomaly is associated with low oxygen fugacity, we propose that the auriferous fluids responsible for gold mineralization at Ajjanahalli could be from an oxygen depleted fluid. The observed positive Eu anomaly is interpreted to suggest the derivation of the auriferous fluids from a mantle reservoir. The location of Ajjanahalli gold deposit in a crustal scale shear zone is consistent with this interpretation.     

http://www.sciencedirect.com/science/article/pii/S167498711200028X

Most Phanerozoic oolites are marked by ooids with a diameter less than 2 mm.Observations on a Neoproterozoic oolite have resulted in a change of concept.The term "pisolite" that traditionally referred to oolites with a grain size of more than 2 mm,is now restricted to those coated carbonate grains formed by meteoritic freshwater diagenesis;oolites with a grain size of more than 2 mm are now defined as "giant".Particular unusual giant oolites within a set of oolitic-bank limestones with thicknesses of more than 40 m in the top part of the Lower Triassic(Induan) Daye(Ruiping) Formation at the Lichuan section in the western part of Hubei Province in South China,represent an important sedimentological phenomenon in both the specific geological period and the geological setting that is related to the end-Permian biological mass extinction.Like the giant oolites of the Neoproterozoic that represent deposits where oolites formed in a vast low-angle carbonate ramp at that special geological period,the Triassic Daye Formation at the study section are significant because they provide a comparative example to help understand the evolving carbonate world reflected by oolites,the origin of which is still uncertain. and they give insight into the sedimentation pattern of the desolate sea floor,which resulted from the mass extinction at the turn of the Permian into the Tnassic.     

http://www.sciencedirect.com/science/article/pii/S1674987111000430

Mineral assemblages formed during hydrothermal alteration reflect the geochemical composition of ore-forming fluids. Gold is mainly transported in solution as AueCl and AueS complexes. The change of physicochemical conditions such as temperature, pressure, oxygen fugacity, and sulfur fugacity are effective mechanisms for gold precipitation. Gold tends to be concentrated in the vapor phase of fluids at high temperatures and pressures. AueAs and AueSb associations are common in gold deposit. Native antimony and/or arsenic e native gold assemblages may precipitate from hydrothermal fluids with low sulfur fugacity. Hydrothermal fluids forming epithermal gold deposits are Au-saturated in most cases, whereas fluids of Carlin-type are Au-undersaturated. Quasi-steady As-bearing pyrite extracts solid solution Au from hydrothermal fluids through absorption. The capability of As-bearing pyrite to absorb Au from under-saturated fluid is the key to the formation of large-scale Carlin-type deposits. With increasing new data, studies on the geochemistry of gold deposits can be used to trace the origin of ore-forming fluids, the source of gold, and the transporting form of Au and other ore-forming elements, such as Si, S, F, Cl, As and Ag.     

http://www.sciencedirect.com/science/article/pii/S1674987112000643

Incipient charnockites represent granulite formation on a mesoscopic scale and have received considerable attention in understanding fluid processes in the deep crust.Here we report new petrological data from an incipient charnockite locality at Rajapalaiyam in the Madurai Block,southern India,and discuss the petrogenesis based on mineral phase equilibrium modeling and pseudosection analysis. Rajapalaiyam is a key locality in southern India from where diagnostic mineral assemblages for ultrahigh-temperature（UHT） metamorphism have been reported.Proximal to the UHT rocks are patches and lenses of charnockite（Kfs + Qtz + Pl + Bt + Opx + Grt + Ilm） occurring within Opx-free Grt-Bt gneiss（Kfs + Pl + Qtz + Bt + Grt + Ilm + Mt） which we report in this study.The application of mineral equilibrium modeling on the charnockitic assemblage in NCKFMASHTO system yields a p-T range of～820℃and～9 kbar.Modeling of the charnockite assemblage in the MnNCKFMASHTO system indicates a slight shift of the equilibrium condition toward lower p and T（～760℃and～7.5 kbar）. which is consistent with the results obtained from geothermobarometry（710—760℃,6.7—7.5 kbar）. but significantly lower than the peak temperatures（>1000℃） recorded from the UHT rocks in this locality,suggesting that charnockitization is a post-peak event.The modeling of T versus molar H₂O content in the rock（M（H₂O）） demonstrates that the Opx-bearing assemblage in charnockite and Opxfree assemblage in Grt-Bt gneiss are both stable at M（H₂O） = 0.3 mol%-0.6 mol%.and there is no significant difference in water activity between the two domains.Our finding is in contrast to the previous petrogenetic model of incipient charnockite formation which envisages lowering of water activity and stabilization of orthopyroxene through breakdown of biotite by dehydration caused by the infiltration of CO₂-rich fluid.T-X_Fe³⁺（= Fe₂O₃/（FeO + Fe₂O₃） in mole） pseudosections suggest that the oxidation condition of the rocks played a major role on the stability of orthopyroxene:Opx is stable at X_Fe³⁺ <0.03 in charnockite.while Opx-free assemblage in Grt-Bt gneiss is stabilized at X_Fe³⁺ >0.12.Such low oxygen fugacity conditions of X_Fe³⁺ <0.03 in the charnockite compared to Grt-Bt gneiss might be related to the infiltration of a reduced fluid（e.g.,H₂O + CH₄） during the retrograde stage.     

http://www.sciencedirect.com/science/article/pii/S1674987112000096

According to the metallogenic theory by transmagmatic fluid(TMF).one magmalic intrusion is a channel of ore-bearing fluids,but not their source.Therefore,it is possible to use TMF’s ability for injection into and for escaping from the magmatic intrusion to evaluate its ore-forming potential.As the ore-bearing fluids cannot effectively inject into the magmatic intrusion when the magma fully crystallized, the cooling time and rates viscosity varied can be used to estimate the minimum critical thickness of the intrusion.One dimensional heat transfer model is used to determine the cooling time for three representative dikes of different composition(granite porphyry,quartz diorite and diabase) in the Shihu gold deposit.It also estimated the rates viscosity varied in these lime interval.We took the thickness of dike at the intersection of the cooling time—thickness curve and the rates viscosity varied versus thickness curve as the minimum critical thickness.For the ore-bearing fluids effectively injecting into the magma,the minimum critical thicknesses for the three representative dikes are 33.45 m for granite porphyry,8.22 m for quartz diorite and 1.02 m for diabase,indicating that ore-bearing dikes must be thicker than each value.These results are consistent with the occurrence of ore bodies,and thus they could be applied in practice.Based on the statistical relationship between the length and the width of dikes.these critical thicknesses are used to compute critical areas:0.0003—0.0016 km~2 for diabase. 0.014—0.068 km~2 for quartz diorite and 0.011—0.034 km~2 for granite porphyry.This implies that orebearing minor intrusions have varied areas corresponding to their composition.The numerical simulation has provided the theoretical threshold of exposed thickness and area of the ore-bearing intrusion.These values can be used to determine the ore-forming potentials of dikes.     

http://www.sciencedirect.com/science/article/pii/S1674987114000644

正1.Introduction This special issue of Geoscience Frontiers is a tribute volume honoring the life and career of Jacques Touret.A set of research papers has been assembled,which broadly reflect his research interests over his 50 plus year career.These papers focus on the role that fluids play during the formation and evolution of the Earth's crust.Below I provide a brief summary of the life of Jacques Touret,along with a select bibliography of his more important papers.This is then followed by a brief introduction to the papers assembled for this special issue.     

A review of the ～1600 Ma sedimentation, volcanism, and tectono-thermal events in the Singhbhum craton, Eastern India

The Palaeoproterozoic–Mesoproterozoic transition (～1600 Ma) is a significant event in the Earth history as a global thermal perturbation affected the pre-1600 Ma landmasses. Like other cratonic blocks of the world, lithospheric thinning, sedimentation, magmatism, metamorphism and crustal melting/anatexis are associated with this significant geological event in the Singhbhum cratonic province of India. This paper is a review of sedimentological, magmatic and tectono-thermal events in the Singhbhum craton at ～1600 Ma. The Palaeo-Mesoproterozoic sedimentation and volcanism in the Singhbhum craton took place in a terrestrial intracontinental rift setting. The available geochronological data are indicative of late Palaeoproterozoic to Neoproterozoic tectono-thermal events in the Chhotanagpur Granite Gneissic Complex (CGGC), an east–west trending arcuate belt of granite gneisses, migmatites and metasedimentary rocks. A detailed multidisciplinary geo-scientific investigation of the Dalma volcanic belt and the area to its north (Chandil Formation) and further north in CGGC will enable us to constrain the extant surface processes and crust-mantle interactions, the collision events between the North and South Indian cratonic blocks, and the position of India in the Columbia supercontinent.     

http://www.sciencedirect.com/science/article/pii/S1674987112000679

Quasi-integrity of continental crust between Mid-Archaean and Ediacaran times is demonstrated by conformity of palaeomagnetic poles to near-static positions between～2.7-2.2 Ca,～1.5-1.2 Ga and～0.75-0.6 Ga.Intervening data accord to coherent APW loops turning at "hairpins" focused near a continental-centric location.Although peripheral adjustments occurred during Early Proterozoic （～2.2 Ga） and Grenville（～1.1 Ga） times,the crust retained a low order symmetrical crescent-shaped form constrained to a single global hemisphere until break-up in Ediacaran times.Conformity of palaeomagnetic data to specific Eulerian parameters enables definition of a master Precambrian APW path used to estimate the root mean square velocity(v_RMS) of continental crust between 2.8 and 0.6 Ga.A long interval of little polar movement between～2.7 and 2.2 Ga correlates with global magmatic shutdown between～2.45 and 2.2 Ga,whilst this interval and later slowdown at～0.75-0.6 Ga to velocities of <2 cm/year correlate with episodes of widespread glaciation implying that these prolonged climatic anomalies had an internal origin;the reduced input of volcanically-derived atmospheric greenhouse gases is inferred to have permitted freeze-over conditions with active ice sheets extending into equatorial latitudes as established by low magnetic inclinations in glaciogenic deposits.v_RMS variations through Precambrian times correspond to the distribution of U-Pb ages in orogenic granitoids and detrital zircons and demonstrate that mobility of continental crust has been closely related to crustal tectonism and incrementation.Both periods of near-stillstand were followed by rapid v_RMS recording massive heat release from beneath the continental lid at～2.2 and 0.6 Ga.The first coincided with the Lomagundi-Jatuli isotopic event and led to prolonged orogenesis accompanied by continental flooding and reconfiguration of the crust on the Earth’s surface;the second led to continental break-up and instigated the comprehensive Plate Tectonics that has characterised Phanerozoic times.The Mesoproterozoic interval characterised by anorogenic magmatism correlates with low v_RMS between～1.5 and 1.1 Ga.Insulation of the sub-continental mantle evidently permitted high temperature melting and weakening of the crustal lid to enable buoyant emplacement of large plutons at high crustal levels during this magmatic event unique to Mesoproterozoic and early Neoproterozoic times.     

http://www.sciencedirect.com/science/article/pii/S1674987111000545

By applying the ’theory of synchronization’ from the science of complexity to studying the regional regularity of ore formation within the Nanling region of southern China,a characteristic target-pattern regional ore zonality has been discovered.During the early and late Yanshanian epoch(corresponding respectively to the Jurassic and Cretaceous periods),two centers of ore formation emerged successively in the Nanling region;the former is mainly for rare metals(W,Sn,Mo,Bi,Nb) and one rare-earth element (La) and was generated in the Jurassic period;whereas the latter is mainly for base metals(Cu,Pb,Zn,Sb, Hg),noble metals(Au,Ag),and one radioactive element(U) and was generated in the Cretaceous period. Centers of ore formation were brought about by interface dynamics respectively at the Qitianling and Jiuyishan districts in southern Hunan Province.The characteristic giant nonlinear target-pattern regional ore zonality was generated by spatio-temporal synchronization process of the Nanling complex metallo-genic system.It induced the collective dynamics and cooperative behavior of the system and displayed the configuration of the regional ore zonality.Then dynamical clustering transformed the configuration into rudimentary ordered coherent structures.Phase dynamics eventually defined the spatio-temporal structures of the target-pattern regional ore zonality and determined their localization and distribution.A new methodology for revealing regional ore zonality is developed,which will encourage further investigation of the formation of deep-seated ore resources and the onset of large-scale mineralization.     

http://www.sciencedirect.com/science/article/pii/S1674987114000267

Habitable Trinity is a newly proposed concept of a habitable environment.This concept indicates that the coexistence of an atmosphere(consisting largely of C and N),an ocean(H and O).and a landmass(supplier of nutrients) accompanying continuous material circulation between these three components driven by the Sun is one of the minimum requirements for life to emerge and evolve.The life body consists of C,0,H,N and other various nutrients,and therefore,the presence of water,only,is not a sufficient condition.Habitable Trinity environment must be maintained to supply necessary components for life body.Our Habitable Trinity concept can also be applied to other planets and moons such as Mars,Europa,Titan,and even exoplanets as a useful index in the quest for life-containing planetary bodies.     

http://www.sciencedirect.com/science/article/pii/S1674987114000565

During granulite-facies metamorphism of metasedimentary rocks by the infiltration of carbonic fluids, the disappearance of hydrated minerals leads to the liberation of aqueous fluids. These fluids are strongly enriched in F and C1, and a series of Large-lon-Lithophile （LIL） elements and rare metals, resulting in their depletion in granulites. To sum up the fate of these elements, we focus on three domains representing different crustal levels and showing distinct behaviours with respect to these elements. The Lapland metasedimentary granulites illustrate the behaviour of the LILE and rare metals during lower crustal metamorphism. There is no change in Ba, moderate loss in Rb, and extreme depletion in Cs, Li, and Sn. F and CI contents are also very low compared to the protoliths or average upper continental crust. Biotite and amphibole breakdown leads to the incorporation of their partitioning into a fluid or a melt. The Tranomaro metasomatized marbles recrystallizing under granulite-facies conditions represent a demonstrative example of fluid transfer from granulite-facies supracrustals to traps represented by regional scale skarns. Such fluids may be at the origin of the incompatible element enrichment detected in leucosomes of migmatites from St Malo in Brittany （France） and Black Hills in South Dakota, The northern French Massif Central provides us with an example of a potential association between incompatible element enrichment of granitic melts and granulite-facies metamorphism. U- and F- enriched fine-grained granites are emplaced along a crustal scale shear zone active during the emplacement within the St Sylvestre peraluminous leucogranitic complex, We propose that during granulite-facies metamorphism dominated by carbonic waves in a deep segment of the continental crust, these shear zones control： （i） the percolation of F-, LILE-, rare metal-rich fluids liberated primarily by the breakdown of biotite; （ii） the enhancement of partial melting by F-rich fluids at intermediate crustal lev     

http://www.sciencedirect.com/science/article/pii/S1674987112001569

The southeastern Anatolia comprises numbers of tectono-magmatic/stratigraphic units such as the metamorphic massifs,the ophiolites,the volcanic arc units and the granitoid rocks.All of them play important role for the late Cretaceous evolution of the southern Neotethys.The spatial and temporal relations of these units suggest the progressive development of coeval magmatism and thrusting during the late Cretaceous northward subduction/accretion.Our new U-Pb zircon data from the rhyolitic rocks of the wide-spread volcanic arc unit show ages of(83.1±2.2)-(74.6±4.4) Ma. Comparison of the ophiolites,the volcanic arc units and the granitoids suggest following late Cretaceous geological evolution.The ophiolites formed in a suprasubduction zone(SSZ) setting as a result of northward intra-oceanic subduction.A wide-spread island-arc tholeiitic volcanic unit developed on the top of the SSZ-type crust during 83-75 Ma.Related to regional plate convergence, northward under-thrusting of SSZ-type ophiolites and volcanic arc units was initiated beneath the Tauride platform(Malatya-Keban) and followed by the intrusion of l-type calc-alkaline volcanic arc granitoids during 84-82 Ma.New U-Pb ages from the arc-related volcanic-sedimentary unit and granitoids indicate that under-thrusting of ophiolites together with the arc-related units beneath the Malatya-Keban platform took place soon after the initiation of the volcanic arc on the top of the SSZtype crust.Then the arc-related volcanic-sedimentary unit continued its development and lasted at～75 Ma until the deposition of the late Campanian—Maastrichtian shallow marine limestone.The subduction trench eventually collided with the Bitlis-Ptrge massif giving rise to HP-IT metamorphism of the Bitlis massif.Although the development of the volcanic arc units and the granitoids were coeval at the initial stage of the subduction/accretion both tectono-magmatic units were genetically different from each other.     

Biostratigraphy of a Paleocene–Eocene Foreland Basin boundary in southern Tibet

This study of the Paleocene–Eocene boundary within a foreland basin of southern Tibet, which was dominated by a carbonate ramp depositional environment, documents more complex environmental conditions than can be derived from studies of the deep oceanic environment. Extinction rates for larger foraminiferal species in the Zongpu-1 Section apply to up to 46% of the larger foraminiferal taxa. The extinction rate in southern Tibet is similar to rates elsewhere in the world, but it shows that the Paleocene fauna disappeared stepwise through the Late Paleocene, with Eocene taxa appearing abruptly above the boundary. A foraminifera turnover was identified between Members 3 and 4 of the Zongpu Formation—from the Miscellanea–Daviesina assemblage to an Orbitolites–Alveolina assemblage. The Paleocene and Eocene boundary is between the SBZ 4 and SBZ 5, where it is marked by the extinction of Miscellanea miscella and the first appearance of Alveolina ellipsodalis and a large number of Orbitolites. Chemostratigraphically, the δ13C values from both the Zongpu-1 and Zongpu-2 Sections show three negative excursions in the transitional strata, one in Late Paleocene, one at the boundary, and one in the early Eocene. The second negative excursion of δ13C, which is located at the P–E boundary, coincides with larger foraminifera overturn. These faunal changes and the observed δ13C negative excursions provide new evidence on environmental changes across the Paleocene–Eocene boundary in Tibet.     

Did natural fission of 235U in the earth lead to formation of the supercontinent Columbia?

Steady decline in the percentage of 235U in terrestrial uranium made natural fission impossible after about 1.8 Ga.Fission before 1.8 Ga disturbed the lead isotope system at various places worldwide,su...