An Upper Pliocene coarse pumice breccia generated by a shallow submarine explosive eruption,Milos, Greece

The Filakopi Pumice Breccia (FPB) is a very well exposed, Pliocene volcaniclastic unit on Milos, Greece, and has a minimum bulk volume of 1 km³. It consists of three main units: (A) basal lithic breccia (4–8 m) mainly composed of angular to subangular, andesitic and dacitic clasts up to 2.6 m in diameter; (B) very thickly bedded, poorly sorted pumice breccia (16–17 m); and (C) very thick, reversely graded, grain-supported, coarse pumice breccia (6.5–20 m), at the top. The depositional setting is well constrained as shallow marine (up to a few hundred metres) by overlying fossiliferous and bioturbated mudstone. This large volume of fine pumice clasts is interpreted to be the product of an explosive eruption from a submarine vent because: (1) pumice clasts are the dominant component; (2) the coarse pumice clasts (>64 mm) have complete quenched margins; (3) very large (>1 m) pumice clasts are common; (4) overall, the formation shows good hydraulic sorting; and (5) a significant volume of ash was deposited together with the coarsest pyroclasts.The bed forms in units A and B suggest deposition from lithic-rich and pumiceous, respectively, submarine gravity currents. In unit C, the coarse (up to 6.5 m) pumice clasts are set in matrix that grades upwards from diffusely stratified, fine (1–2 cm) pumice clasts at the base to laminated shard rich mud at the top. The coarse pumice clasts in unit C were settled from suspension and the framework was progressively infilled by fine pumice clasts from waning traction currents and then by water-settled ash. The FPB displays important features of the products of submarine explosive eruptions that result from the ambient fluid being seawater, rather than volcanic gas or air. In particular, submarine pyroclastic deposits are characterised by the presence of very coarse juvenile pumice clasts, pumice clasts with complete quenched rims, and good hydraulic sorting.Electronic Supplementary Material Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.Editorial responsibility: J. Donelly-Nolan     

Complex changes in eruption dynamics during the 79 AD eruption of Vesuvius

The 79 AD eruption of Vesuvius included 8 eruption units (EU1–8) and several complex transitions in eruptive style. This study focuses on two important transitions: (1) the abrupt change from white to gray pumice during the Plinian phase of the eruption (EU2 to EU3) and (2) the shift from sustained Plinian activity to the onset of caldera collapse (EU3 to EU4). Quantification of the textural features within individual pumice clasts reveals important changes in both the vesicles and groundmass crystals across each transition boundary. Clasts from the white Plinian fall deposit (EU2) present a simple story of decompression-driven crystallization followed by continuous bubble nucleation, growth and coalescence in the eruptive conduit. In contrast, pumices from the overlying gray Plinian fall deposit (EU3) are heterogeneous and show a wide range in both bubble and crystal textures. Extensive bubble growth, coalescence, and the onset of bubble collapse in pumices at the base of EU3 suggest that the early EU3 magma experienced protracted vesiculation that began during eruption of the EU2 phase and was modified by the physical effects of syn-eruptive mingling-mixing. Pumice clasts from higher in EU3 show higher bubble and crystal number densities and less evidence of bubble collapse, textural features that are interpreted to reflect more thorough mixing of two magmas by this stage of the eruption, with consequent increases in both vesiculation and crystallization. Pumice clasts from a short-lived, high column at the onset of caldera collapse (EU4) continue the trend of increasing crystallization (enhanced by mixing) but, unexpectedly, the melt in these clasts is more vesicular than in EU3 and, in the extreme, can be classified as reticulite. We suggest that the high melt vesicularity of EU4 reflects strong decompression following the partial collapse of the magma chamber.Editorial responsibility: D.B. Dingwell     

Volcanology of trachytic and associated basaltic pyroclastic deposits at Roccamonfina volcano, Roman Region, Italy

The 274 ka “Basalt-Trachytic Tuff of Tuoripunzoli” (TBTT) from Roccamonfina volcano (Roman Region, Italy) consists of a basaltic scoria lapilli fall (Unit A) overlain by a trachytic sequence formed by a surge (Unit B), repetitive pumice lapilli and ash-rich layers both of fallout origin (Unit C) and a pyroclastic flow deposit (Unit D). The TBTT is widespread (40 km²) in the northern sector of the volcano, but limited to a small area on the southern slopes of the main cone. Interpolation between the northern deposits and the latter one yields a minimum depositional area of 123 km², and an approximate bulk volume of 0.2-0.3 km³. Isopach and isopleth maps are consistent with a source vent within the main caldera of Roccamonfina.Unit A shows a fairly good sorting and a moderate grain size; glass fragments are cuspate and vesicular. Unit B is fine grained and poorly sorted; shards are blocky and nonvesicular. Pumice lapilli of Unit C are moderately sorted and moderately coarse grained. Glass shards are equant and vesicular. Lithic clasts are strongly comminuted to submillimetric sizes. By contrast, the ash-rich internal divisions are very fine grained and poorly sorted. They consist of a mixture of equant shards which are prevailingly blocky and poorly vesicular. Unit D is a massive, poorly sorted, moderately coarse-grained deposit. Glass fragments are nearly equant and slightly or nonvesicular.The TBTT is interpreted as due to eruption of a basaltic magma followed in rapid succession by one trachyte magma. Unit A formed by Subplinian fallout of a moderate, purely magmatic column. Interaction between a trachyte magma and water resulted in eruption of surge Unit B. A high-standing eruption column erupted alternating fallout pumice lapilli and fallout ashes. Pumice lapilli originated prevailingly from the inner part of the eruption column, whereas magma-water interaction on the external parts of the column resulted in ash fallout. The uppermost pyroclastic flow Unit D is interpreted as due to final collapse of the eruption column.     

Young pumice deposits on Nisyros,Greece

The island of Nisyros (Aegean Sea) consists of a silicic volcanic sequence upon a base of mafic-andesitic hyaloclastites, lava flows, and breccias. We distinguish two young silicic eruptive cycles each consisting of an explosive phase followed by effusions, and an older silicic complex with major pyroclastic deposits. The caldera that formed after the last plinian eruption is partially filled with dacitic domes. Each of the two youngest plinian pumice falls has an approximate DRE volume of 2–3 km³ and calculated eruption column heights of about 15–20 km. The youngest pumice unit is a fall-surge-flow-surge sequence. Laterally transitional fall and surge facies, as well as distinct polymodal grainsize distributions in the basal fall layer, indicate coeval deposition from a maintained plume and surges. Planar-bedded pumice units on top of the fall layer were deposited from high-energy, dry-steam propelled surges and grade laterally into cross-bedded, finegrained surge deposits. The change from a fall-to a surge/flow-dominated depositional regime coincided with a trend from low-temperature argillitic lithics to high-temperature, epidote-and diopside-bearing lithic clasts, indicating the break-up of a high-temperature geothermal reservoir after the plinian phase. The transition from a maintained plume to a surge/ash flow depositional regime occurred most likely during break-up of the high-temperature geothermal reservoir during chaotic caldera collapse. The upper surge units were possibly erupted through the newly formed ringfracture.     

Stratigraphy, chronology, and sedimentology of ignimbrites from the white trachytic tuff, Roccamonfina Volcano, Italy

We describe the stratigraphy, chronology, and grain size characteristics of the white trachytic tuff (WTT) of Roccamonfina Volcano (Italy). The pyroclastic rock was emplaced between 317 and 230 Ma BP during seven major eruptive events (units A to G) and three minor events (units BC, CD, and DE). These units are separated by paleosol layers and compositionally well-differentiated pyroclastic successions. Stratigraphic control is favored by the occurrence at the base of major units of marker layers. Four WTT units (1 to 4) occur within the central caldera. These are not positively correlated with specific extracaldera units.The source of most of the WTT units was the central caldera. Units B and C were controlled by the western wall of the caldera, whereas units D and E were able to overcome this barrier, spreading symmetrically along the flanks of MC. The maximum pumice size (MP) of units increases with distance from the caldera, whereas the maximum lithic size (ML) decreases. MP and ML of the marker layer of unit D (MKDa–MKDp) do not show any systematic variations with respect to the central caldera. In contrast, the thickness of surge MKDa decreases with distance from the source, and MKDp accumulates to the north of MC probably controlled, respectively, by mobility-transport power and by wind blowing northwards.The grain size characteristics of the WTT deposits are used for classifying the units. There is no systematic variation of the grain size as a function of stratigraphic height either among units or within single units. Large variation of components in subunit E1, with repetitive alternation of pyroclastic flow to surge through fallout vs. surge deposits, suggests that the process of eruption took place in a complex or piecemeal fashion.Pumice concentration zones (PCZ) occur at all WTT levels on the volcano, but they are much thicker and pumice clasts are much larger within the central caldera. These were probably originated by the disruption of lava (flow or dome) to pumice fragments and fine ash due to sudden depressurization and interaction with lake waters of the molten lava. Local basal PCZ are, in some cases, similar to the lapilli-rich “layer 1P” that has been described elsewhere, and may have been deposited from currents transitional between pyroclastic surge and flow. Other basal PCZ formed in response to small undulations in the substrate, or can be originated by fallout. Lenticular PCZ within ignimbrite interiors and tops are interpreted to record marginal pumice levees and pumice rafts, some of which were buried by subsequant pyroclastic flows.Lithic concentration zones (LCZ) also occur at various stratigraphic height within the extracaldera ignimbrites, whereas intracaldera LCZ are absent, probably due to the fact that ignimbrite currents are strongly energetic and erosive near vent. LCZ at the top of basal inversely graded layers are formed by mechanical sieving or dispersive pressure in response to variable velocity gradients and particle concentration gradients (a segregation process). Coarse LCZ and coarse lithic breccias (LB), that reside in the interior or tops of pyroclastic flows and that occur in medial to distal areas, are interpreted to be the result of slugs of lithic-rich debris introduced by vent collapse or rockslides into the moving pyroclastic flows along their flow paths. These LCZ become mixed to varying degrees due to differential densities and velocities relative to the pyroclastic flows (desegregation processes).     

Emplacement of small-volume pyroclastic flows at Laacher See (East-Eifel,Germany)

We distinguish three eruptive units of pyroclastic flows (T1, T2, and T3; T for trass) within the late Quaternary Laacher See tephra sequence. These units differ in the chemical/mineralogical composition of the essential pyroclasts ranging from highly differentiated phonolite in T1 to mafic phonolite in T3. T1 and T2 flows were generated during Plinian phases, and T3 flows during a late Vulcanian phase. The volume of the pyroclastic flow deposits is about 0.6 km³. The lateral extent of the flows from the source vent decreases from > 10 km (T1) to < 4.5 km (T3). In the narrow valleys north of Laacher See, the total thickness of the deposits exceeds 60 m.At least 19 flow units in T1, 6 in T2, and 4 in T3 can be recognized at individual localities. Depositional cycles of 2 to 5 flow units are distinguished in the eruptive units. Thickness and internal structure of the flow units are strongly controlled by topography. Subfacies within flow units such as strongly enriched pumice and lithic concentration zones, dust layers, lapilli pipes, ground layers, and lithic breccias are all compositionally related to each other by enrichment or depletion of clasts depending on their size and density in a fluidized flow. While critical diameters of coarse-tail grading were found to mark the boundary between the coarse nonfluidized and the finer fluidized grain-size subpopulations, we document the second boundary between the fluidized and the very fine entrained subpopulations by histograms and Rosin-Rammler graphs. Grain-size distribution and composition of the fluidized middle-size subpopulations remained largely unchanged during transport.Rheological properties of the pyroclastic flows are deduced from the variations in flow-unit structure within the valleys. T1 flows are thought to have decelerated from 25 m/s at 4 km to < 15 m/s at 7 km from the vent; flow density was probably 600–900 kg/m³, and viscosity 5–50 P. The estimated yield strength of the flows of 200– > 1000 N/m² is consistent with the divergence of lithic size/distance curves from purely Newtonian models; the transport of lithics must be treated as in a Bingham fluid. The flow temperature probably decreased from T1 (300°–500°C) to T3 (<200°C).A large-scale longitudinal variation in the flow units from proximal through medial to distal facies dominantly reflects temporal changes during the progressive collapse of an eruption column. Only a small amount of fallout tephra was generated in the T1 phase of eruption. The pyroclastic flows probably formed from relatively low ash fountains rather than from high Plinian eruption columns.     

Magma mingling in an andesite pyroclastic flow of the Pourahu Member, Ruapehu volcano, New Zealand

We describe a magma mingling episode from Ruapehu volcano between two andesite magmas, one very much minor in volume relative to the other. The event acted to trigger eruption of the andesitic Pourahu pyroclastic flow which is preserved in a thick sequence of tephras and laharic deposits in the southeastern ring plain of the volcano. The predominant andesite is pale brown coloured and porphyritic containing phenocrysts of plagioclase-clinopyroxene-orthopyroxene-Fe-Ti oxides. Rare clasts of a darker andesite are different texturally, less vesicular, and contain distinctive microphenocrysts of plagioclase and quench olivine. Equally rare clasts, of streaky pumice consisting of interbanded ‘dark’ and ‘light’ andesite attest to mingling between these two andesite components.Chemical analyses of discrete clasts demonstrate that the Pourahu pyroclastic flow andesites span much of the compositional spectrum of Ruapehu andesites. This observation demonstrates heterogeneity in the products of a relatively small eruption. The darker clast analyses and those from associated distal fall deposits lie within the fields defined by the dominant light coloured clasts. Phenocryst and microphenocryst geothermometry suggest slightly higher temperatures in the dark component. However, glasses from groundmass and phenocryst inclusions in the same specimen may differ considerably, leading us to conclude that many phenocrysts are in fact xenocrystic and were incorporated in the melts as they migrated towards the surface.We prefer a model in which a small volume of hot andesite magma injects a vent-feeding magma chamber, triggering vesiculation and eruption. We infer that the process of magma withdrawal extended downward into the magma body causing the dark component to intermingle with the lighter (dominant) component, ‘sucking’ more dark magma into the chamber. Our observations are entirely consistent with the existence of a plexus of small, possibly interlinked magma chambers beneath Ruapehu.     

Facies architecture of a silicic intrusion-dominated volcanic centre at Highway–Reward, Queensland, Australia

The Highway–Reward massive sulphide deposit is hosted by a silicic volcanic succession in the Cambro-Ordovician Seventy Mile Range Group, northeastern Australia. Three principal lithofacies associations have been identified in the host succession: the volcanogenic sedimentary facies association, the primary volcanic facies association and the resedimented syn-eruptive facies association. The volcanogenic sedimentary facies association comprises volcanic and non-volcanic siltstone and sandstone turbidites that indicate submarine settings below storm wave base. Lithofacies of the primary volcanic facies association include coherent rhyolite, rhyodacite and dacite, and associated non-stratified breccia facies (autoclastic breccia and peperite). The resedimented volcaniclastic facies association contains clasts that were initially formed and deposited by volcanic processes, but then redeposited by mass-flow processes. Resedimentation was more or less syn-eruptive so that the deposits are essentially monomictic and clast shapes are unmodified. This facies association includes monomictic rhyolitic to dacitic breccia (resedimented autoclastic facies), siltstone-matrix rhyolitic to dacitic breccia (resedimented intrusive hyaloclastite or resedimented peperite) and graded lithic-crystal-pumice breccia and sandstone (pumiceous and crystal-rich turbidites). The graded lithic-crystal-pumice breccia and sandstone facies is the submarine record of a volcanic centre(s) that is not preserved or is located outside the study area. Pumice, shards, and crystals are pyroclasts that reflect the importance of explosive magmatic and/or phreatomagmatic eruptions and suggest that the source vents were in shallow water or subaerial settings.The lithofacies associations at Highway–Reward collectively define a submarine, shallow-intrusion-dominated volcanic centre. Contact relationships and phenocryst populations indicate the presence of more than 13 distinct porphyritic units with a collective volume of 0.5 km³. Single porphyritic units vary from <10 to 350 m in thickness and some are less than 200 m in diameter. Ten of the porphyritic units studied in the immediate host sequence to the Highway–Reward deposit are entirely intrusive. Two of the units lack features diagnostic of their emplacement mechanism and could be either lavas and intrusions. Direct evidence for eruption at the seafloor is limited to a single partly extrusive cryptodome. However, distinctive units of resedimented autoclastic breccia indicate the presence nearby of additional lavas and domes.The size and shape of the lavas and intrusions reflect a restricted supply of magma during eruption/intrusion, the style of emplacement, and the subaqueous emplacement environment. Due to rapid quenching and mixing with unconsolidated clastic facies, the sills and cryptodomes did not spread far from their conduits. The shape and distribution of the lavas and intrusions were further influenced by the positions of previously or concurrently emplaced units. Magma preferentially invaded the sediment, avoiding the older units or conforming to their margins. Large intrusions and their dewatered envelope may have formed a barrier to the lateral progression and ascent of subsequent batches of magma.     

Submarine eruption-fed and resedimented pumice-rich facies: the Dogashima Formation (Izu Peninsula,Japan)

In the Izu Peninsula (Japan), the Pliocene pumice-rich Dogashima Formation (4.55?±?0.87 Ma) displays exceptional preservation of volcaniclastic facies that were erupted and deposited in a below wave-base marine setting. It includes high-concentration density current deposits that contain clasts that were emplaced hot, indicating an eruption-fed origin. The lower part of the Dogashima 2 unit consists of a very thick sequence (<12 m) of massive grey andesite breccia restricted to the base of a submarine channel, gradationally overlain by pumice breccia, which is widespread but much thinner and finer in the overbank setting. These two breccias share similar mineralogy and crystal composition and are considered to be co-magmatic and derived from the destruction of a submarine dome by an explosive, pumice-forming eruption. The two breccias were deposited from a single, explosive eruption-fed, sustained, sea floor-hugging, water-supported, high-concentration density current in which the clasts were sorted according to their density. At the rim of the channel, localised good hydraulic sorting of clasts and stratification in the pumice breccia are interpreted to reflect local current expansion and unsteadiness rather than to be the result of hydraulic sorting of clasts during fall from a submarine eruption column and/or umbrella plume. A bimodal coarse (>1 m) pumice- and ash-rich bed overlying the breccias may be derived from delayed settling of pyroclasts from suspension. In Dogashima 1 and 2, thick cross- and planar-bedded facies composed of sub-rounded pumice clasts are intercalated with eruption-fed facies, implying inter-eruptive mass-wasting on the flank of a submarine volcano, and reworking and resedimentation by high-energy tractional currents in a below wave-base environment.     

Plinian-type eruptions in the medicine lake highland, california, and the nature of the underlying magma

Contemporaneous Plinian eruptions of rhyolite pumice from Glass Mountain and Little Glass Mountain during the last 1100 years B.P. were followed by extrusion of lava flows. 1.2 km of material was erupted and 10% by volume is tephra. All of the tephra deposits consist of very poorly sorted coarse ash and lapilli that are mostly pumice pyroclasts.Eruptive sequences, chemical composition and petrographic character of the rhyolites at Little Glass Mountain and Glass Mountain suggest that they came from the same magma body. The 1:9 ratio of tephra to lavas is typical of small silicic magma chambers. Eruption from a small chamber, 4–6 km deep, at vents 15 km apart is possible if magma rose along cone sheets with dips of 45–60°. The caldera rim and arcuate lines of vents near it may represent the surface expression of several concentric cone sheets.Pumice pyroclasts erupted at Glass Mountain and Little Glass Mountain may have formed in the following manner: (1) vesicle growth and coalescence beginning at 1–2 km depths; (2) elongation of the vesicles by flow within the cone sheets; (3) disruption of the vesiculated magma when it reached the surface by an expansion wave passing down through it; and (4) eruption of comminution products as pumice pyroclasts. Plinian activity at Little Glass Mountain and Glass Mountain continued until the volatile-rich top of the magma chamber had been depleted.     

Structure and physical characteristics of pumice from the climactic eruption of Mount Mazama (Crater Lake), Oregon

The vesicularity, permeability, and structure of pumice clasts provide insight into conditions of vesiculation and fragmentation during Plinian fall and pyroclastic flow-producing phases of the ~7,700 cal. year B.P. climactic eruption of Mount Mazama (Crater Lake), Oregon. We show that bulk properties (vesicularity and permeability) can be correlated with internal textures and that the clast structure can be related to inferred changes in eruption conditions. The vesicularity of all pumice clasts is 75-88%, with >90% interconnected pore volume. However, pumice clasts from the Plinian fall deposits exhibit a wider vesicularity range and higher volume percentage of interconnected vesicles than do clasts from pyroclastic-flow deposits. Pumice permeabilities also differ between the two clast types, with pumice from the fall deposit having higher minimum permeabilities (~5᎒^-13 m²) and a narrower permeability range (5-50᎒^-13 m²) than clasts from pyroclastic-flow deposits (0.2-330᎒^-13 m²). The observed permeability can be modeled to estimate average vesicle aperture radii of 1-5 µm for the fall deposit clasts and 0.25-1 µm for clasts from the pyroclastic flows. High vesicle number densities (~10⁹ cm^-3) in all clasts suggest that bubble nucleation occurred rapidly and at high supersaturations. Post-nucleation modifications to bubble populations include both bubble growth and coalescence. A single stage of bubble nucleation and growth can account for 35-60% of the vesicle population in clasts from the fall deposits, and 65-80% in pumice from pyroclastic flows. Large vesicles form a separate population which defines a power law distribution with fractal dimension D=3.3 (range 3.0-3.5). The large D value, coupled with textural evidence, suggests that the large vesicles formed primarily by coalescence. When viewed together, the bulk properties (vesicularity, permeability) and textural characteristics of all clasts indicate rapid bubble nucleation followed by bubble growth, coalescence and permeability development. This sequence of events is best explained by nucleation in response to a downward-propagating decompression wave, followed by rapid bubble growth and coalescence prior to magma disruption by fragmentation. The heterogeneity of vesicle sizes and shapes, and the absence of differential expansion across individual clasts, suggest that post-fragmentation expansion played a limited role in the development of pumice structure. The higher vesicle number densities and lower permeabilities of pyroclastic-flow clasts indicate limited coalescence and suggest that fragmentation occurred shortly after decompression. Either increased eruption velocities or increased depth of fragmentation accompanying caldera collapse could explain compression of the pre-fragmentation vesiculation interval.     

Submarine silicic volcanism of the Healy caldera,southern Kermadec arc (SW Pacific): I – volcanology and eruption mechanisms

The submarine Healy volcano (southern Kermadec arc), with a 2-2.5 km wide caldera, is pervasively mantled with highly vesicular silicic pumice within a water depth of 1,150-1,800 m. Pumices comprise type 1 white-light grey pumice with ⢾ mm vesicles and weak-moderate foliation, type 2 grey pumice with millimetre-scale laminae, flow banded foliation, including stretched vesicles ⣗ mm in length, and a minor finely vesicular type 3 pumice. All types are sparsely porphyritic, with undevitrified glassy groundmass (68-70% SiO₂), which is microlite and lithic free. Coexisting pyroxenes yield magma temperatures of ~950 °C. Pumice density is А.5 g cm^-3 and vesicularity is 78-83%. Vesicle size distributions for types 1 and 2 pumice, range from ~20 µm to >20 mm, with a strong power-law relation (with d=-2.5ǂ.4) for vesicles <1-2 mm. Larger vesicles have variable size modes. The vesicle size distribution and packing indicates rapid magma decompression and ascent. Consideration of the pressure dependent, solubility of H₂O at a magma temperature of 𙧶 °C and water content of Ж wt%, with pumice petrography and vesicle granulometry, strongly suggests a pyroclastic eruption. Reconstructions of the submarine edifice between water depths of 1,000 and 550 m constrain the ambient hydrostatic pressure to ~6-9 MPa. Pressures >~9 MPa will limit vesicularity to less than the observed 78-83%, whereas pressure <~6 MPa require a more shallower reconstruction of the edifice and larger-volume syn-eruptive collapse. Uniformly high vesicularity is interpreted as evidence of insulation within an eruption column comprising steam and hot pyroclasts. Most pyroclasts cool, condensing and ingesting water into steam-inflated vesicles, and then sink. Progression into pyroclastic mode would expand the eruption column, displace ambient water, reduce the hydrostatic load, and further promote vesiculation and fragmentation. Pyroclasts within the column would quench at these reduced pressures. We argue that Healy eruptions deeper than ~1,000 m cannot be pyroclastic. Volumes for the lower and upper bounds of edifice size are 2.36 and 3.58 km³, respectively, but do not account for intra-caldera pumice fill. These volumes are considered to be predominantly primary eruption output, as shown by a dearth of accessory lithics in all pumice, yielding (at an average 81% vesicularity) eruptive pumice volumes of between 10 and 15 km³. Some pyroclasts may have risen to the sea surface and be a correlative of the sea-rafted Loisels pumice; the latter occurs in some New Zealand Holocene beach sequences and has a estimated age of 590ᇤ calendar years.     

Pumice

Cold pumice floating on water slowly absorbs water into the vesicles and eventually sinks. Experiments show that some pumice can remain afloat for over 1 1/2 years. The time taken for enough water to be adsorbed to sink depends on the pumice size, initial density, the size distribution of vesicles and the connectedness of the vesicles. Hot pumice often sinks immediately on immersion in water despite having a lower density than water. Experiments demonstrate that for any pumice there is a critical temperature above which the pumice will sink. Even pumice with a density of 0.2 g/cm³ will sink if the temperature exceeds 700 °C. The critical temperature correlates well with initial pumice density with lower-density pumice requiring higher temperatures to sink. The mechanism at low temperatures (< 150 °C) involves the absorption of water by contraction of hot air within the pumice. However, at higher temperatures conversion of absorbed water to steam in the hot pumice flushes out air, and further cooling results in condensation and absorption of water into the pumice. The experiments on hot and cold pumice suggest that all the vesicles in pumice are interconnected. This was confirmed by vacuum impregnation of pumice with resins. The behaviour of hot and cold pumice indicates that the deposits of hot and cold pyroclastic flow deposits may be distinguishable. Hot deposits will contain a significant proportion of low-density pumice, whereas cold deposits will not. Pumice falling hot onto water could also sink immediately to form subaqueous pumice-fall deposits. The physical properties of pumice were further examined by a nitrogen absorption technique and by mercury porosimetry. The former method shows that pumice has a typical surface area of 0,5 m²/g, corresponding to a sheet of material of 1 m² and 0,87µm Thick. Porosimetry shows that there are often three apparent vesicle-size populations in pumice. However, the porosimetry data gives surface areas which often greatly exceed those measured by the absorption method. The calculation of surface area by porosimetry assumes that vesicles are open cylinders. The large discrepancy with nitrogen absorption data suggests that the surface areas and proportion of small vesicles are overestimated by porosimetry and that pumice vesicles have narrow entrances. The porosimetry size distributions reflect the dimensions of pore entrances rather than the vesicles themselves. A three stage degassing history was proposed by Sparks and Brazier (1982). However, the small size population of sub-micron vesicles they identified probably represent larger ( 1µm) vesicles with narrow entrances. The experimental data indicate that pumice can degas very quickly because of the connectedness of vesicles and high internal surface areas.     

Incursion of a large-volume,spatter-bearing pyroclastic density current into a caldera lake: Pavey Ark ignimbrite,Scafell caldera,England

The Scafell caldera-lake volcaniclastic succession is exceptionally well exposed. At the eastern margin of the caldera, a large andesitic explosive eruption (>5 km³) generated a high-mass-flux pyroclastic density current that flowed into the caldera lake for several hours and deposited the extensive Pavey Ark ignimbrite. The ignimbrite comprises a thick (≤125 m), proximal, spatter- and scoria-rich breccia that grades laterally and upwards into massive lapilli-tuff, which, in turn, is gradationally overlain by massive and normal-graded tuff showing evidence of soft-state disruption. The subaqueous pyroclastic current carried juvenile clasts ranging from fine ash to metre-scale blocks and from dense andesite through variably vesicular scoria to pumice (<10³ kg m⁻³). Extreme ignimbrite lithofacies diversity resulted via particle segregation and selective deposition from the current. The lacustrine proximal ignimbrite breccia mainly comprises clast- to matrix-supported blocks and lapilli of vesicular andesite, but includes several layers rich in spatter (≤1.7 m diameter) that was emplaced in a ductile, hot state. In proximal locations, rapid deposition of the large and dense clasts caused displacement of interstitial fluid with elutriation of low-density lapilli and ash upwards, so that these particles were retained in the current and thus overpassed to medial and distal reaches. Medially, the lithofacies architecture records partial blocking, channelling and reflection of the depletive current by substantial basin-floor topography that included a lava dome and developing fault scarps. Diffuse layers reflect surging of the sustained current, and the overall normal grading reflects gradually waning flow with, finally, a transition to suspension sedimentation from an ash-choked water column. Fine to extremely fine tuff overlying the ignimbrite forms ∼25% of the whole and is the water-settled equivalent of co-ignimbrite ash; its great thickness (≤55 m) formed because the suspended ash was trapped within an enclosed basin and could not drift away. The ignimbrite architecture records widespread caldera subsidence during the eruption, involving volcanotectonic faulting of the lake floor. The eruption was partly driven by explosive disruption of a groundwater-hydrothermal system adjacent to the magma reservoir.     

Sedimentation of tephra by volcanic plumes: I. Theory and its comparison with a study of the Fogo A plinian deposit,Sao Miguel (Azores)

Sedimentation of ejecta from volcanic plumes has been studied as a function of distance from the source in the Fogo A plinian deposit, Sao Miguel, Azores. The Fogo A trachytic pumice deposit is reversely graded and can be divided into two parts on the basis of pumice colour, abundance of syenite accessory lithic clasts and distribution. The lower syenite-poor part was dispersed to the south and was clearly influenced by wind. The upper syenite-rich part is coarsegrained and has a nearly symmetrical distribution around the vent. Elongation of isopachs to the east indicate a weak wind influence. The grain-size variations of lithic and crystal components in the upper coarse part were studied. Total accumulation and accumulation per unit area (expressed in kg/m²) show good fits to a gaussian function at distances greater than 7 km for grain diameters less than 2 cm. These results agree with a theoretical model for a radially spreading turbulent current moving over a quiescent fluid. The gaussian coefficient is shown to be a function of grain size and the flow rate of material into the umbrella region of the eruption column. The coefficient is therefore also a function of column height. The column height deduced from these data is 21 km, which is in broad agrrement with the column height of 27 km deduced from maximum clast dispersal using the method of Carey and Sparks (1986). The accumulation of clasts larger than 2 cm agrees with a theory for the fallout of clasts from the margins of the ascending eruption column, which treats the plume as a succession of large eddies that decrease their mass of particles as an exponential function of time. Calculations are also presented for the influence of the radial inflow of surrounding air into the column on the deposition of clasts. These calculations constrain the wind speed during the later part of the Fogo A eruption to be at most a few metres per second. The study has allowed four different dynamic categories of clast behaviour to be recognised in eruption columns.     

Remanent magnetism of poorly sorted deposits from the Minoan eruption of Santorini

Thick, poorly sorted ash deposits produced during the Minoan cruption have differing palacomagnetic histories. Included clasts from deposits produced in the second phase of the eruption have random NRM and cleaned directions and were emplaced as cold mudflows. Clasts from ignimbrite flow units erupted in the third phase have significant directions and their palacomagnetic pole is consistent with today’s geomagnetic pole. These deposits acquired a TRM on deposition and were emplaced as hot pumice flows.     

Endogenous growth of a Miocene submarine dacite cryptodome, Rebun Island, Hokkaido, Japan

Momo-iwa, Rebun Island, Hokkaido, Japan, is a dacite cryptodome 200–300 m across and 190 m high. The dome is inferred to have intruded wet, poorly consolidated sediment in a shallow marine environment. The internal structure of the dome is concentric, with a massive core, banded rim, and narrow brecciated border, all of which are composed of compositionally uniform feldspar-phyric dacite. Boundaries between each of the zones are distinct but gradational. The massive core consists of homogeneous coherent (unfractured) dacite and is characterized by radial columnar joints 60–200 cm across. The banded rim encircles the massive core and is 40 m wide. It is characterized by large-scale flow banding parallel to the dome surface. The flow banding comprises alternating partly crystalline and more glassy bands 80–150 cm thick. The outermost brecciated border is up to 80 cm thick, and consists of in situ breccia and blocky peperite. The in situ breccia comprises polyhedral dacite clasts 5–20 cm across and a cogenetic granular matrix. The blocky peperite consists of polyhedral dacite clasts 0.5–2 cm across separated by the host sediment (mudstone). The internal structures of the dome suggest endogenous growth involving a continuous magma supply during a single intrusive phase and simple expansion from the interior. Although much larger, the internal structures of Momo-iwa closely resemble those of lobes in subaqueous felsic lobe-hyaloclastite lavas.     

Palaeomagnetic estimates of emplacement temperatures of pyroclastic deposits on Santorini,Greece

Thermal remanent magnetism provides a method of quantitatively determining the emplacement temperature of individual lithic clasts in a volcaniclastic rock. The technique is reviewed and applied to two types of Quaternary pyroclastic deposit on Santorini. Emplacement-temperature estimates for lithic clasts from two co-ignimbrite lithic breccias (Cape Riva and Middle Pumice eruptions) range from 250°C to 580°C, showing unambiguously that the breccias were emplaced hot. Good precision on temperature estimates (about ±20°C) were obtained from the Cape Riva breccias. Lithics in a Plinian airfall deposit from the Middle Pumice eruption give less precise results because the primary magnetisation has been partly overprinted by chemical (and/or viscous) remanence, and some clasts may have rotated during compaction of the deposit. Temperatures from proximal airfall are consistent with welding of the deposit within 1.5 km from vent. Temperature estimates for lithic clasts further from vent scatter, but a falloff of temperature away from vent can be recognised if an average emplacement temperature for the whole deposit is identified at each location. The study highlights some difficulties in interpreting quantitative temperature estimates for prehistoric pyroclastic deposits.     

Shifting styles of basaltic explosive activity during the 2002–03 eruption of Mt. Etna, Italy

The 2002–03 flank eruption of Etna was characterized by two months of explosive activity that produced copious ash fallout, constituting a major source of hazard and damage over all eastern Sicily. Most of the tephra were erupted from vents at 2750 and 2800 m elevation on the S flank of the volcano, where different eruptive styles alternated. The dominant style of explosive activity consisted of discrete to pulsing magma jets mounted by wide ash plumes, which we refer to as ash-rich jets and plumes. Similarly, ash-rich explosive activity was also briefly observed during the 2001 flank eruption of Etna, but is otherwise fairly uncommon in the recent history of Etna. Here, we describe the features of the 2002–03 explosive activity and compare it with the 2001 eruption in order to characterize ash-rich jets and plumes and their transition with other eruptive styles, including Strombolian and ash explosions, mainly through chemical, componentry and morphology investigations of erupted ash. Past models explain the transition between different styles of basaltic explosive activity only in terms of flow conditions of gas and liquid. Our findings suggest that the abundant presence of a solid phase (microlites) may also control vent degassing and consequent magma fragmentation and eruptive style. In fact, in contrast with the Strombolian or Hawaiian microlite-poor, fluidal, sideromelane clasts, ash-rich jets and plumes produce crystal-rich tachylite clasts with evidence of brittle fragmentation, suggesting that high groundmass crystallinity of the very top part of the magma column may reduce bubble movement while increasing fragmentation efficiency.     

The Quetzalapa Pumice: a voluminous late Pleistocene rhyolite deposit in the eastern Trans-Mexican Volcanic Belt

The study area is located in the east part of the Trans-Mexican Volcanic Belt, in the Las Cumbres Volcanic Complex (LCVC) which lies between two large stratovolcanoes: Pico de Orizaba (5700 m a.s.l.) to the south, and Cofre de Perote (4200 m a.s.l.) to the NNE. The most conspicuous structure of the LCVC is a 4-km-diameter circular crater with a dacitic dome in the center, which constitutes the remains of a destroyed stratovolcano.The Quetzalapa Pumice (QP) was produced by a plinian eruption that was dated by the ¹⁴C method at 20 000 yr. BP. The eruptive sequence consists predominantly of pumice fall deposits and scarce intra-plinian pyroclastic flow deposits, which crop out on the west flank of the LCVC. The absence of post-plinian ignimbrite deposits is striking.The deposits are well sorted, clast-supported with reverse grading at the base, with a medium to high accessory lithics content. The maximum average thickness of the deposit in the proximal areas is about 15 m and has been divided into three members: the Basal Member (BM), 2 m thick with four submembers (BMf₁, BMf₂, BMf₃, and BMafl), the Intermediate Member (IM), 10 m thick with two submembers (IMpf and IMaf), and the Upper Member (UM), 3 m thick with four submembers (UMpl, UMsdf, UMwaf, and UMpls).The predominant component of the fall deposits is a white, highly vesiculated pumice with 71% SiO₂ content. Plagioclase is the most abundant mineral followed by 1–3-mm-long biotite phenocrysts. The accessory lithics are lavas mostly of andesitic composition. Their abundance increases toward the uppermost levels of the sequence.We calculate a minimum volume of 8.4 km³ (2.22 km³ dense rock equivalent), for the entire QP deposit. Isopach and isopleth maps show that the IM deposit has an elongated distribution with a NNE–SSW direction, whereas the UM deposit has a circular distribution.We estimate a maximum eruptive column height for the IM of 20 km. Field studies and isopach and isopleth maps indicate that the eruptive column was affected by a strong wind.Previous studies located the QP source in the Las Cumbres crater. However, based on the isopach and isopleth distribution, and the lack of pumice fall deposits inside the Las Cumbres crater, we consider that the QP emission center is located on the west flank of the LCVC, and was buried by its own pumice fall deposits. It coincides with an explosion crater called La Capilla formed during the closing phase of the QP eruption.A ‘pumice fountain’ model is proposed to explain the observed sequence of deposits. According to this model, the material was emitted through a ‘hose-type’ conduit during a monogenetic eruption of rhyolitic composition. This kind of volcanic activity is not extensively reported in the literature.