SME observations of O2 (1 delta g) nightglow: an assessment of the chemical production mechanisms

Solar Mesosphere Explorer (SME) observations of the 3 a.m. 1.27 micrometers nightglow at 45 N latitude, averaged over the period 10-31 July 1984, are reported. From the deduced volume emission rates, we derive the O2(a1 delta g) night-time production rates for the 80-100 km altitude range. Utilizing the mean SME-acquired 3 p.m. ozone profile for the same latitude and time period and an updated photochemical model, we determine night-time O, O3, H, OH, HO2, and H2O2 profiles. These are used in calculating the rates of reactions which are sufficiently exothermic to produce O2(1 delta) or excited states of OH or HO2, which could transfer their energy to O2 to form O2(1 delta). Of these reactions, most have rates that are quite small compared with the observed night-time O2(1 delta) production rate. For several others, laboratory experiments have found O2(1 delta) yields which are insufficient for simulating the observed O2(1 delta). Using yields of O2(1 delta) based on published laboratory and observational studies, we find that the sum of two reaction sequences can approximate the SME measurements: (1) O+O+M and (2) H+O3 followed by OH*+O2.     

Chemical enrichment by massive stars

Heavy element abundances derived from high-quality ground-based and Hubble Space Telescope (HST) spectroscopic observations of low-metallicity blue compact galaxies (BCGs) with oxygen abundances 12+log O/H between 7.1 and 8.3 are discussed. None of the heavy element-to-oxygen abundance ratios studied here (C/O, N/O, Ne/O, Si/O, S/O, Ar/O, Fe/O) depend on oxygen abundance for BCGs with 12+log O/H≤7.6 (Z≤Z_⊙/20). This constancy implies that all these heavy elements have a primary origin and are produced by the same massive (M≥10 M_⊙) stars responsible for O production. The dispersion of the C/O and N/O ratios in these galaxies is found to be remarkably small, being only ±0.03 dex and ±0.02 dex respectively. This very small dispersion is strong evidence against any time-delayed production of C and primary N in the lowest-metallicity BCGs, and hence against production of these elements by intermediate-mass (3 M_⊙≤M≤9 M_⊙) stars at very low metallicities, as commonly thought.In higher metallicity BCGs (7.6<12+log O/H<8.2), the Ne/O, Si/O, S/O, Ar/O and Fe/O abundance ratios retain the same constant value they had at lower metallicities. By contrast, there is an increase of the C/O and N/O ratios along with their dispersions at a given O. We interpret this increase as due to the additional contribution of C and primary N production in intermediate-mass stars, on top of that by high-mass stars. BCGs show the same O/Fe overabundance with respect to the Sun (∼0.4 dex) as galactic halo stars, suggesting the same chemical enrichment history.     

D/O and D/H ratios in the local interstellar medium from FUSE observations

Since HI, OI, and DI have nearly the same ionization potential, the deuterium-to-oxygen ratio (D/O) is an important tracer of the D/H ratio and of its putative spatial variations. D/O is indeed very sensitive to astration, both because of deuterium destruction and oxygen production. Moreover, D/O measurements are less subject to systematic errors than D/H.A survey of D/O in the interstellar medium is performed by the Deuterium Working Group of the FUSE PI Team. The first results show that D/O is a better D/H proxy than D/N, and that D/O is homogeneous in the local interstellar medium, at least within about 100pc. The stability of D/O appears as a strong argument which supports both D/H and O/H spatial stability in the local interstellar medium.     

Galactic chemical evolution and the oxygen isotopic composition of the solar system

Abstract– We review current observational and theoretical constraints on the galactic chemical evolution (GCE) of oxygen isotopes to explore whether GCE plays a role in explaining the lower ¹⁷O/¹⁸O ratio of the Sun, relative to the present‐day interstellar medium, or the existence of distinct ¹⁶O‐rich and ¹⁶O‐poor reservoirs in the solar system. Although the production of both ¹⁷O and ¹⁸O are related to the metallicity of progenitor stars, ¹⁷O is most likely produced in stars that evolve on longer timescales than those that produce ¹⁸O. Therefore, the ¹⁷O/¹⁸O ratio need not have remained constant over time, contrary to preconceptions and the simplest models of GCE. An apparent linear, slope‐one correlation between δ¹⁷O and δ¹⁸O in the ISM need not necessarily reflect an O isotopic gradient, and any slope‐one galactocentric gradient need not correspond to evolution in time. Instead, increasing ¹⁷O/¹⁸O is consistent both with observational data from molecular clouds and with modeling of the compositions of presolar grains. Models in which the rate of star formation has decelerated over the past few Gyr or in which an enhanced period of star formation occurred shortly before solar birth (“starburst”) can explain the solar‐ISM O‐isotopic difference without requiring a local input of supernova ejecta into the protosolar cloud. “Cosmic chemical memory” models in which interstellar dust is on average older than interstellar gas predict that primordial solar system solids should be ¹⁶O‐rich, relative to the Sun, in conflict with observations. However, scenarios can be constructed in which the ¹⁶O‐rich contribution of very massive stars could lead to ¹⁶O‐poor solids and a ¹⁶O‐rich bulk Sun, if the solar system formed shortly after a starburst, independent of the popular scenario of photochemical self‐shielding of CO.     

Theoretical investigation of interstellar C–C–O and C–O–C bonding backbone molecules

There are numerous complex organic molecules containing carbon and oxygen atoms which show either C–C–O or C–O–C bonding backbone. This paper examines altogether 51 C–C–O and C–O–C bonding backbone molecules from ten different isomeric groups (C₂H₂O, C₃H₂O, C₂H₄O, C₂H₄O₂, C₃H₄O, C₂H₆O, C₂H₆O₂, C₃H₆O, C₃H₆O₂, C₃H₈O) to summarize the present astronomical status of these molecules. Accurate calculations of enthalpy of formation of these molecules show that the isomers with C–C–O backbone are more stable than the C–O–C backbone. Interestingly, a detailed analysis of relevant astromolecules indicates that most of the observed astromolecules have the C–C–O backbone. As a matter of fact, of all the molecules examined in this study, 80% of the astronomically observed species have the C–C–O backbone while only 20% have the C–O–C backbone. In general, interstellar abundance of a molecule is controlled by some factors such as kinetics, formation and destruction pathways,thermodynamics etc. A proper consideration of these factors could explain the observed abundances of these molecules. All these possible key factors are discussed in this paper.     

Oxygen isotopic composition of the solar nebula gas inferred from high‐precision isotope imaging of melilite crystals in an Allende CAI

Abstract– High‐precision isotope imaging analyses of reversely zoned melilite crystals in the gehlenitic mantle of Type A CAI ON01 of the Allende carbonaceous chondrite reveal that there are four types of oxygen isotopic distributions within melilite single crystals: (1) uniform depletion of ¹⁶O (δ¹⁸O ≈ ?10‰), (2) uniform enrichment of ¹⁶O (δ¹⁸O ≈ ?40‰), (3) variations in isotopic composition from ¹⁶O‐poor core to ¹⁶O‐rich rim (δ¹⁸O ≈ ?10‰ to ?30‰, ?20‰ to ?45‰, and ?10‰ to ?35‰) with decreasing åkermanite content, and (4) ¹⁶O‐poor composition (δ¹⁸O ≥ ?10‰) along the crystal rim. Hibonite, spinel, and perovskite grains are ¹⁶O‐rich (δ¹⁸O ≈ ?45‰), and adjoin ¹⁶O‐poor melilites. Gas‐solid or gas‐melt isotope exchange in the nebula is inconsistent with both the distinct oxygen isotopic compositions among the minerals and the reverse zoning of melilite. Fluid‐rock interaction on the parent body resulted in ¹⁶O‐poor compositions of limited areas near holes, cracks, or secondary phases, such as anorthite or grossular. We conclude that reversely zoned melilites mostly preserve the primary oxygen isotopic composition of either ¹⁶O‐enriched or ¹⁶O‐depleted gas from which they were condensed. The correlation between oxygen isotopic composition and åkermanite content may indicate that oxygen isotopes of the solar nebula gas changed from ¹⁶O‐poor to ¹⁶O‐rich during melilite crystal growth. We suggest that the radial excursions of the inner edge of the protoplanetary disk gas simultaneously resulted in both the reverse zoning and oxygen isotopic variation of melilite, due to mixing of ¹⁶O‐poor disk gas and ¹⁶O‐rich coronal gas. Gas condensates aggregated to form the gehlenite mantle of the Type A CAI ON01.     

Oxygen isotope characteristics of chondrules from the Yamato‐82094 ungrouped carbonaceous chondrite: Further evidence for common O‐isotope environments sampled among carbonaceous chondrites

High‐precision secondary ion mass spectrometry (SIMS) was employed to investigate oxygen three isotopes of phenocrysts in 35 chondrules from the Yamato (Y) 82094 ungrouped 3.2 carbonaceous chondrite. Twenty‐one of 21 chondrules have multiple homogeneous pyroxene data (?¹⁷O 3SD analytical uncertainty: 0.7‰); 17 of 17 chondrules have multiple homogeneous pyroxene and plagioclase data. Twenty‐one of 25 chondrules have one or more olivine data matching coexisting pyroxene data. Such homogeneous phenocrysts (1) are interpreted to have crystallized from the final chondrule melt, defining host O‐isotope ratios; and (2) suggest efficient O‐isotope exchange between ambient gas and chondrule melt during formation. Host values plot within 0.7‰ of the primitive chondrule mineral (PCM) line. Seventeen chondrules have relict olivine and/or spinel, with some δ¹⁷O and δ¹⁸O values approaching ?40‰, similar to CAI or AOA‐like precursors. Regarding host chondrule data, 22 of 34 have Mg#s of 98.8–99.5 and ?¹⁷O of ?3.9‰ to ?6.1‰, consistent with most Acfer 094, CO, CR, and CV chondrite chondrules, and suggesting a common reduced O‐isotope reservoir devoid of ¹⁶O‐poor H₂O. Six Y‐82094 chondrules have ?¹⁷O near ?2.5‰, with Mg#s of 64–97, consistent with lower Mg# chondrules from Acfer 094, CO, CR, and CV chondrites; their signatures suggest precursors consisting of those forming Mg# ~99, ?¹⁷O: ?5‰ ± 1‰ chondrules plus ¹⁶O‐poor H₂O, at high dust enrichments. Three type II chondrules plot slightly above the PCM line, near the terrestrial fractionation line (?¹⁷O: ~+0.1‰). Their O‐isotopes and olivine chemistry are like LL3 type II chondrules, suggesting they sampled ordinary chondrite‐like chondrule precursors. Finally, three Mg# >99 chondrules have ?¹⁷O of ?6.7‰ to ?8.1‰, potentially due to ¹⁶O‐rich refractory precursor components. The predominance of Mg# ~99, ?¹⁷O: ?5‰ ± 1‰ chondrules and a high chondrule‐to‐matrix ratio suggests bulk Y‐82094 characteristics are closely related to anhydrous dust sampled by most carbonaceous chondrite chondrules.     

Intervening O vi Quasar Absorption Systems at Low Redshift: A Significant Baryon Reservoir

Far-UV echelle spectroscopy of the radio-quiet QSO H1821+643 (zem=0.297), obtained with the Space Telescope Imaging Spectrograph (STIS) at approximately 7 km s-1 resolution, reveals four definite O vi absorption-line systems and one probable O vi absorber at 0.15相似文献   

NGC 1333/IRA6-9 区域中的致密分子云核

利用紫金山天文台青海站的13．7m毫米波望远镜,对NGC1333／IRAS6－9附近的一个10．3'X10'和6．8'X8'的恒星形成区,进行了13CO（1－0）和C18O（1－0）的成图观测,发现了多个新的分子云核和沿SSV12－IRASS方向的13CO（1－O）双极外向流．本文给出了每个云核的观测特性和物理参数．分析了这一区域的云核分布和速度场结构．详细讨论了该区域的云核分布、双极外向流和群集的年轻天体、红外源以及HH天体的关系．     

The effect of oxygen as a light element in metallic liquids on partitioning behavior

Oxygen has been considered a potentially important light element in metallic liquids during a range of planetary processes, yet the influence of O in a metallic melt on element partitioning behavior is largely unknown. To investigate the effect of O in such systems, we conducted experiments in the Fe‐S‐O system, doped with 25 trace elements, which produced two immiscible metallic liquids. Our results indicate that the presence of O in the metallic liquid produces a distinctive chemical signature for W and Ga in particular. Tungsten shows an affinity for O in the metallic liquid and partitions more strongly into the metallic melt in the presence of O. The partitioning of Ga is relatively constant despite the presence of O, which is in contrast to the majority of the other siderophile elements in the study. Our experiments from 1400 to 1600 °C show no significant effect from temperature on the partitioning behavior of any trace elements over this limited temperature range. This distinctive chemical signature due to the presence of O in the metallic liquid has potential implications for modeling core formation, evaluating isotopic signatures produced by core crystallization, and interpreting chemical assemblages observed in meteorites.     

Influence of Inelastic Collisions with Hydrogen Atoms on Non-LTE Oxygen Abundance Determinations

We present the results of our modeling of the O I line formation under non-LTE conditions in the atmospheres of FG stars. The statistical equilibrium of O I has been calculated using Barklem’s quantum-mechanical rates of inelastic collisions with hydrogen atoms. We have determined the non-LTE oxygen abundance from atomic O I lines for the Sun and 46 FG stars in a wide metallicity range, ?2.6 < [Fe/H] < 0.2. The application of accurate atomic data has led to an increase in the departures from LTE and a decrease in the oxygen abundance compared to the use of Drawin’s theoretical approximation. The change in the non-LTE abundance from the infrared O I 7771-5 Å triplet lines is 0.11 dex for solar atmospheric parameters and diminishes in absolute value with decreasing metallicity. We have revised the [O/Fe]–[Fe/H] relationship derived by us previously. The change in [O/Fe] is small in the [Fe/H] range from ?1.5 to 0.2. For stars with [Fe/H] < ?1 the [O/Fe] ratio has increased so that [O/Fe] = 0.60 at [Fe/H] = ?0.8 and rises to [O/Fe] = 0.75 at [Fe/H] = ?2.6.     

大质量年轻星体新的C18O(1-0)发射

利用紫金山天文台青海观测站13.7米的毫米波望远镜对74个大质量年轻星体或候选进行了C^18O(1-0)的谱线观测。在63个源中观测到了C^18O(1-0)发射，其中57个天体第一次探测到C^18O(1-0)谱线发射。根据谱线辐射温度（TR^*)和半宽（△V），利用LTE方法计算了每个测量源的C^18O(1-0)发射的光学厚度和C^18O(1-0)分子的柱密度。讨论了^13CO(1-0)和C^18O(1-0)的谱线强度比和积分强度比。     

Oxygen isotopes in chondrule olivine and isolated olivine grains from the CO3 chondrite Allan Hills A77307

Abstract— We have measured O‐isotopic ratios in a variety of olivine grains in the CO3 chondrite Allan Hills (ALH) A77307 using secondary ion mass spectrometry in order to study the chondrule formation process and the origin of isolated olivine grains in unequilibrated chondrites. Oxygen‐isotopic ratios of olivines in this chondrite are variable from δ¹⁷O = ?15.5 to +4.5% and δ¹⁸O = ?11.5 to +3.9%, with Δ¹⁷O varying from ?10.4 to +3.5%. Forsteritic olivines, Fa_<1, are enriched in ¹⁶O relative to the bulk chondrite, whereas more FeO‐rich olivines are more depleted in ¹⁶O. Most ratios lie close to the carbonaceous chondrite anhydrous minerals (CCAM) line with negative values of Δ¹⁷O, although one grain of composition Fa₄ has a mean Δ¹⁷O of +1.6%. Marked O‐isotopic heterogeneity within one FeO‐rich chondrule is the result of incorporation of relic, ¹⁶O‐rich, Mg‐rich grains into a more ¹⁶O‐depleted host. Isolated olivine grains, including isolated forsterites, have similar O‐isotopic ratios to olivine in chondrules of corresponding chemical composition. This is consistent with derivation of isolated olivine from chondrules, as well as the possibility that isolated grains are chondrule precursors. The high ¹⁶O in forsteritic olivine is similar to that observed in forsterite in CV and CI chondrites and the ordinary chondrite Julesburg and suggests nebula‐wide processes for the origin of forsterite that appears to be a primitive nebular component.     

Molecules of Non-Photospheric Origin in Red Giants and Supergiants Revealed by the ISO SWS

Overall SEDs based on ISO SWS observations show fair agreement with photospheric model predictions for red (super)giant stars. However, some details of molecular spectra cannot be explained by a photospheric origin. In particular, fine structure in the H2O 2.7 μm band can be clearly resolved by the SWS and is identified in an early M giant, whose photosphere will never produce H2O. This is definite evidence for H2O of non-photospheric origin in an early M giant. Also, the observed H2O and CO2 bands in a late M giant are too strong to be explained by a photospheric origin alone. Further, the H2O 2.7 μm band is found in four early M supergiants in the h + χ Persei clusters (three of which show UIRs) and is especially strong in the M4 supergiant S Per (which also shows a highly peculiar SED). Thus, against a belief that H2O is found only in the latest M giants such as Miras, the SWS has revealed the presence of H2O in a wider region of the HR diagram. The origin of this H2O is unknown but is probably in a non-photospheric extra envelope. Such a H2O envelope appears to be a general feature through early M (super)giants to cool supergiants such as S Per, where the envelope has finally developed to be optically thick. This revised version was published online in August 2006 with corrections to the Cover Date.     

Oxygen isotopic record of silicate alteration in the Shergotty—Nakhla—Chassigny meteorite Lafayette

Abstract— Samples from a suite of Shergotty—Nakhla—Chassigny (SNC) meteorites were analyzed for their O isotopic ratios by a modified version of the laser fluorination technique. Measured isotopic ratios (¹⁷O/¹⁶O and ¹⁸O/¹⁶O) from bulk samples of the Shergottites, EETA79001, Shergotty and Zagami; the Nakhlite Lafayette; and Chassigny are similar to those reported in the literature, as are those from olivine and pyroxene mineral separates from Lafayette. Iddingsite, a preterrestrial alteration product of Lafayette, was measured for the first time as a separate phase. Oxygen isotopic ratios increase with the percentage of iddingsite in a sample to a maximum δ¹⁸O of 14.4% for a ～90% separate. Based on these measurements, end-member iddingsite has a δ¹⁸O of 15.6%, which places it among other ¹⁸O-enriched secondary phases (carbonate and silica) observed in SNC meteorites. The relatively large difference in δ¹⁸O between iddingsite and the olivine and pyroxene it replaces (～11%) is typical of low-temperature alteration products. A range of crustal fluid δ¹⁸O values can be interpreted from the δ¹⁸O for end-member iddingsite, assuming isotopic equilibrium was achieved during low-temperature hydrous alteration (<100 °C; Treiman et al., 1993). The calculated range of values, ?15 to 5%, depends on many factors including: (1) the modal mineralogy of iddingsite, (2) potential isotopic exchange among other O-bearing phases such as host silicate and carbonate, and (3) exchange with evolved or exotic O reservoirs on Mars. Despite the lack of constraints, the calculated range is consistent with isotopic exchange, and possibly equilibria, among components of the CO₂-carbonate-iddingsite-H₂O system at low temperature. The SNC meteorite samples in this study have Δ¹⁷O values that are indistinguishable from bulk Mars (0.30%), except for a single, small sample of iddingsite that has an anomalous Δ¹⁷O of ～1.4%. While analytical difficulties make isotopic measurements for this sample problematic, the Δ¹⁷O is similar in direction to Δ¹⁷O reported for waters extracted from bulk samples of Lafayette (Karlsson et al., 1992). If the Δ¹⁷O for iddingsite is confirmed, it can be concluded that evolved or exotic fluids on Mars have contributed volatiles to the O reservoir from which iddingsite formed 130 to 700 Ma ago.     

Fine‐grained,spinel‐rich inclusions from the reduced CV chondrite Efremovka: II. Oxygen isotopic compositions

Abstract— Oxygen isotopes have been measured by ion microprobe in individual minerals (spinel, Al‐Ti‐diopside, melilite, and anorthite) within four relatively unaltered, fine‐grained, spinel‐rich Ca‐Al‐rich inclusions (CAIs) from the reduced CV chondrite Efremovka. Spinel is uniformly ¹⁶O‐rich (Δ¹⁷O ≤ ?20‰) in all four CAIs; Al‐Ti‐diopside is similarly ¹⁶O‐rich in all but one CAI, where it has smaller ¹⁶O excesses (‐15‰ ≤ Δ¹⁷O ≤ ?10‰). Anorthite and melilite vary widely in composition from ¹⁶O‐rich to ¹⁶O‐poor (‐22‰ ≤ Δ¹⁷O ≤ ?5‰). Two of the CAIs are known to have group II volatility‐fractionated rare‐earth‐element patterns, which is typical of this variety of CAI and which suggests formation by condensation. The association of such trace element patterns with ¹⁶O‐enrichment in these CAIs suggests that they formed by gas‐solid condensation from an ¹⁶O‐rich gas. They subsequently experienced thermal processing in an ¹⁶O‐poor reservoir, resulting in partial oxygen isotope exchange. Within each inclusion, oxygen isotope variations from mineral to mineral are consistent with solid‐state oxygen self‐diffusion at the grain‐to‐grain scale, but such a model is not consistent with isotopic variations at a larger scale in two of the CAIs. The spatial association of ¹⁶O depletions with both elevated Fe contents in spinel and the presence of nepheline suggests that late‐stage iron‐alkali metasomatism played some role in modifying the isotopic patterns in some CAIs. One of the CAIs is a compound object consisting of a coarse‐grained, melilite‐rich (type A) lithology joined to a fine‐grained, spinel‐rich one. Melilite and anorthite in the fine‐grained portion are mainly ¹⁶O‐rich, whereas melilite in the type A portion ranges from ¹⁶O‐rich to ¹⁶O‐poor, suggesting that oxygen isotope exchange predated the joining together of the two parts and that both ¹⁶O‐rich and ¹⁶O‐poor gaseous reservoirs existed simultaneously in the early solar nebula.     

The impact of the nitrogen-to-oxygen ratio on ionized nebula diagnostics based on [N ii] emission lines

We study the relation between nitrogen and oxygen abundances as a function of metallicity for a sample of emission-line objects for which a direct measurement of the metallicity has been possible. This sample is representative of the very different conditions in ionization and chemical enrichment that we can find in the Universe. We first construct the N/O versus O/H ratio diagram, and discuss its large dispersion at all metallicity regimes. Using the same sample and a large grid of photoionization models covering very different values of the N/O ratio, we then study the most widely used strong-line calibrators of metallicity based on [N  ii ] emission lines, such as N2 and O3N2. We demonstrate that these parameters underestimate the metallicity at low N/O ratios and vice versa. We also investigate the effect of the N/O ratio on different diagnostic diagrams used to discriminate narrow-line active galactic nuclei from star-forming regions, such as the [O  iii ]/Hβ versus [N  ii ]/Hα, and show that a large fraction of the galaxies catalogued as composite in this diagram can be, in fact, star-forming galaxies with a high value of the N/O ratio. Finally, using strong-line methods sensitive to the N/O abundance ratio, like N2O2 and N2S2, we investigate the relation between this ratio and the stellar mass for the galaxies of the Sloan Digital Sky Survey. We find, as in the case of the mass–metallicity relation, a correlation between these two quantities and a flattening of the relation for the most massive galaxies, which could be a consequence of the enhancement of the dispersion of N/O ratio in the high-metallicity regime.     

Water in tektites and impact glasses by fourier-transformed infrared spectrometry

Abstract— To improve the scarce data base of H₂O content in tektites and impact glasses, we analyzed 26 tektites from all four strewn fields and 25 impact glass samples for their H₂O content. We used the fourier-transformed infrared (FTIR) spectrometry method, which permits measurement of areas of ～40 μm in diameter. Our results show that the tektites have H₂O contents ranging from 0.002 to 0.030 wt% (average 0.014 ± 0.008 wt%). Ivory Coast tektites have the lowest H₂O abundances (0.002–0.003 wt%), and Muong Nong-type indochinites and some North American tektites having the highest contents (up to ～0.03 wt%). Impact glass samples (from the Zhamanshin, Aouelloul, and Rio Cuarto craters) yielded H₂O contents of 0.008 to 0.13 wt% H₂O. Typical impact glasses from the Aouelloul and Zhamanshin craters have low H₂O contents (0.008 to 0.063 wt%). Libyan Desert Glasses and Rio Cuarto glasses have higher H₂O contents (～0.11 wt%). We also analyzed glasses of unknown origin (e.g., urengoites; glass fragments from Tikal), which showed very low H₂O contents, in agreement with an origin by impact. Our data confirm that all tektites found on land have very low H₂O contents (<0.03 wt% H₂O), while impact glasses have slightly higher H₂O contents. Both glass types are very dry compared to volcanic glasses. This study confirms that the low H₂O contents (<0.05 wt%) of such glasses can be considered good evidence for an origin by impact.     

The solar oxygen-isotopic composition: Predictions and implications for solar nebula processes

Abstract— The outer layers of the Sun are thought to preserve the average isotopic and chemical composition of the solar system. The solar O-isotopic composition is essentially unmeasured, though models based on variations in meteoritic materials yield several predictions. These predictions are reviewed and possible variations on these predictions are explored. In particular, the two-component mixing model of Clayton and Mayeda (1984) (slightly revised here) predicts solar compositions to lie along an extension of the calcium-aluminum-rich inclusion (CAI) ¹⁶O line between (δ¹⁸O, δ¹⁷O) = (16.4, 11.4)%0 and (12.3, 7.5)%0. Consideration of data from ordinary chondrites suggests that the range of predicted solar composition should extend to slightly lower δ¹⁸O values. The predicted solar composition is critically sensitive to the solid/gas ratio in the meteorite-forming region, which is often considered to be significantly enriched over solar composition. A factor of two solid/gas enrichment raises the predicted solar (δ¹⁸O, δ¹⁷O) values along an extension of the CAI ¹⁶O line to (33, 28)%0. The model is also sensitive to the nebular O gas phase. If conversion of most of the gaseous O from CO to H₂O occurred at relatively low temperatures and was incomplete at the time of CM aqueous alteration, the predicted nebular gas composition (and hence the solar composition) would be isotopically heavier along a slope 1/2 line. The likelihood of having a single solid nebular O component is discussed. A distribution of initial solid compositions along the CAI ¹⁶O line (rather than simply as an end-member) would not significantly change the predictions above in at least one scenario. Even considering these variations within the mixing model, the predicted range of solar compositions is distinct from that expected if the meteoritic variations are due to non-mass-dependent fractionation. Thus, a measurement of the solar O composition to a precision of several permil would clearly distinguish between these theories and should clarify a number of other important issues regarding solar system formation.     

Oxygen isotopes in magnetite and fayalite in CV chondrites Kaba and Mokoia

Abstract— We report in situ measurements of O‐isotopic compositions of magnetite and primary and secondary olivine in the highly unequilibrated oxidized CV chondrites Kaba and Mokoia. In both meteorites, the magnetite and the secondary olivine (fayalite, Fa_90–100) have O‐isotopic compositions near the terrestrial fractionation (TF) line; the mean Δ¹⁷O (= δ¹⁷O‐0.52 × δ¹⁸O) value is about ?1%‰. In contrast, the compositions of nearby primary (chondrule), low‐FeO olivines (Fa_1–2) are well below the TF line; Δ¹⁷O values range from ?3 to ?9%‰. Krot et al. (1998) summarized evidence indicating that the secondary phases in these chondrites formed by aqueous alteration in an asteroidal setting. The compositions of magnetite and fayalite in Kaba and Mokoia imply that the O‐isotopic composition of the oxidant was near or somewhat above the TF line. In Mokoia the fayalite and magnetite differ in δ¹⁸O by ～20%‰, whereas these same materials in Kaba have virtually identical compositions. The difference between Mokoia magnetite and fayalite may indicate formation in isotopic equilibrium in a water‐rich environment at low temperatures, ～300 K. In contrast, the similar compositions of these phases in Kaba may indicate formation of the fayalite by replacement of preexisting magnetite in dry environment, with the O coming entirely from the precursor magnetite and silica. The Δ¹⁷O of the oxidant incorporated into the CV parent body (as phyllosilicates or H₂O) appears to have been much (7–8%‰) lower than that in that incorporated into the LL parent body (Choi et al, 1998), which suggests that the O‐isotopic composition of the nebular gas was spatially or temporally variable.