Late Quaternary landscape reconstruction and geochronology in the northern Pampas of Buenos Aires province,Argentina

This paper reports the main sedimentary characteristics, soil micromorphology and optically-stimulated luminescence (OSL) ages, and details the pedosedimentary reconstruction, of the Hudson site situated in the northern Pampas of Buenos Aires province. It also provides the OSL chronology and a reinterpretation of previously reported micromorphological features for the nearby site of Gorina. Finally, the stratigraphic records of both sites are compared and the main environmental events discussed in a regional context.At Hudson, situated at a low altitude environment close to the coastal plain, the basal fine-grained paludal deposits were unconformably covered by coastal marine sediments with an OSL age of ca. 128 ka supporting its correlation with the high stand of sea level of marine isotope stage 5e. A paleosol developed on the marine deposits and the underlying paludal sediments. OSL ages suggest that soil development and its subsequent erosion occurred over some period between ca. 128 and 54 ka. Fine sediment accumulation in a paludal environment continued until prior to ca. 23 ka when the accumulation of the uppermost loess mantle started. It continued until the early Holocene when present soil development began. At Gorina, OSL ages suggest that the upper part of the pedocomplex formed at some stage between ca. 194 and 56 ka. Loess then accumulated followed by an erosional phase; loess deposition restarted by ca. 29 ka and continued until the beginning of the Holocene (ca. 9 ka) when the present land surface was established.The stratigraphic and paleoenvironmental differences exhibited by the Hudson and Gorina records result from their contrasting geomorphological settings. The OSL geochronology suggests that the last interglacial (MIS 5) at Hudson is marked by the accumulation of marine deposits (MIS 5e) and the subsequent development of a paleosol. The equivalent soil-forming interval at Gorina is represented by the upper part of the buried pedocomplex. Both at Gorina and Hudson, loess accumulation was dominant especially during MIS 2. Loess accumulation continued during MIS 1 until the early Holocene with apparently somewhat higher sedimentation rates in Hudson. Pedogenesis has been predominant during the rest of the Holocene, resulting in the formation of the surface soil profiles.     

Mineral magnetic record of paleoclimate variation in loess and paleosol from the Buenos Aires formation (Buenos Aires, Argentina)

Environmental magnetic techniques were applied to a loess–paleosol sequence of the Chacopampean plain (Buenos Aires, Argentina). Mineral magnetic carriers and their grain size were identified in order to detect magnetic mineral fluctuations associated with climatic changes. Multidomain magnetite of detrital origin dominates the record. In paleosols, a high coercivity fraction was identified. Horizons with no visual evidence of pedogenesis, but showing magnetic behavior analogous to that of paleosols were observed and are thought to represent environmental conditions similar to those prevailing during paleosol formation.The results suggest that the magnetic signal yielded by paleosols in these South American loess deposits is different from that in the Chinese loess. This may be due to differences in parent materials, diagenetic processes and/or differences in paleoclimatic conditions in both regions.     

Short and medium-term coastal evolution of Necochea Municipality, Buenos Aires province, Argentina

The short and medium-term coastal evolution of Necochea Municipality, Buenos Aires province (Argentina) was studied. The medium-term evolution study was based on aerial photographs from 1967 and 1984, and satellite images from 2004, using the dune or cliff toe as coastline indicator. The short-term evolution was studied from February 2006 to December 2009 by means of seasonal beach profiles and sediment sampling. Results showed that in the medium-term at Necochea, the coastline has remained stable or has advanced. Whereas in the short-term, the analysis has evidenced incipient erosion processes. On the other hand, at Quequén the retreat of the coastline and the negative sedimentary balances (medium and short-term) are clearly indicating an accentuated erosion process. The different degrees of coastal erosion are related in part to beach vulnerability to wave storms but mainly to anthropogenic actions, which have affected the beach sediment supply. These results evidence the necessity to develop a coastal management programme.     

Biogenic silica in wetlands and their relationship with soil and groundwater biogeochemistry in the Southeastern of Buenos Aires Province,Argentina

Although phytoliths constitute part of the wetland suspended load, there are few studies focused on the quantification of them in the biogenic silica (BSi) pool. So, the aim of this paper is both to determine BSi content (diatoms and phytoliths) and its relationship with dissolved silica in surface waters, and the influence of soil and groundwater Si biogeochemistry in Los Padres wetland (Buenos Aires Province, Argentina). In the basin of the Los Padres wetland, dissolved silica (DSi) concentration is near 840 ± 232 μmol/L and 211.83 ± 275.92 μmol/L in groundwaters and surface waters, respectively. BSi represents an 5.6–22.1% of the total suspension material, and 8–34% of the total mineralogical components of the wetland bottom sediments. DSi and BSi vary seasonally, with highest BSi content (diatoms specifically) during the spring–summer in correlation to the lowest DSi concentration. DSi (660–917.5 μmol/L) and phytolith (3.35–5.84%) concentrations in the inflow stream are higher than in the wetland and its outflow stream (19.1–113 μmol/L; 0.45–3.2%, respectively), probably due to the high phytolith content in soils, the high silica concentration in the soil solution, and the groundwater inflow. Diatom content (5–16.8%) in the wetland and its outflow stream is higher than in the inflow stream (0.45–1.97%), controlling DSi in this system. The understanding of the groundwater–surface water interaction in an area is a significant element for determining the different components and the role that they play on the local biogeochemical cycle of Si.     

Microstructural analysis and P–T conditions of the Azul megashear zone, Tandilia, Buenos Aires province, Argentina

A microstructural analysis was carried out on mylonitic rocks of the Azul megashear zone (AMSZ), Tandilia, which were formed in a range of metamorphic conditions from lower greenschist to amphibolite facies. Tailed porphyroclasts are common and mostly symmetric. Scarce asymmetric rotated porphyroclasts show both sinistral and dextral senses of shear. In sections parallel to the mylonitic foliation, porphyroclasts are round. The AMSZ is probably related to the late Transamazonian orogenic cycle and may be due to NNE–SSW-directed convergence. In weakly deformed protolith and protomylonites, quartz deforms by dynamic recrystallization, mainly subgrain rotation in dislocation creep Regime 2. K-feldspar porphyroclasts and plagioclase show scarce fracturation and deform by dynamic recrystallization along grain boundaries. Quartz microstructures in mylonites indicate predominantly Regime 3 grain boundary migration recrystallization. Feldspar structures indicate recrystallization through the nucleation and growth of new grains at grain boundaries. The temperatures of deformation from mineral assemblages in the CNKFMASH system in four bulk compositions are in the range of 400–450 °C, and the pressures are more than 6 kb.     

Surface and groundwater quality in the northeastern region of Buenos Aires Province, Argentina

This work studies the water quality of the Pergamino–Arrecifes River zone in the Rolling Pampa, northeast Buenos Aires Province, Argentina. Temperature, pH, specific conductivity, Na, K, Mg, Ca, , Cl⁻, , , Si, Ag, Al, As, B, Ba, Be, Br, Cd, Co, Cr, Cu, Fe, Hg, Li, Mn, Mo, Ni, P, Pb, Se, Tl, U, V, Zn, and the environmental stable δ¹⁸O and δ²H isotope ratios were determined in 18 sampling stations. Natural and anthropogenic features influence surface and groundwater quality. Point pollution sources (septic wells and other domestic and farming effluents) increase the nitrate concentration. The values of pH, , Al, As, B, Fe, and Mn exceed the respective Argentine reference thresholds in different sampling stations for human drinking water; B, Mo, U, and V for irrigation; and V and Zn for cattle consumption.     

Origin of flooding water through hydrogeochemical identification,the Buenos Aires plain,Argentina

Hydrogeochemical behaviour of samples of surface and groundwater collected on a cross-section from Mendoza to the Buenos Aires provinces was studied based on chemical trends, mass balance and water mixing. Hydrogeochemical modelling included major, minor elements as well as stable isotopes (deuterium and 18-O). The area investigated is located in the “Médanos Longitudinales” (longitudinal dunes) of the northwest of Buenos Aires province, Argentina. The study area is subject to alternating flooding and drought. Rainfall and surface water subsequently transferred by rivers, canals and lagoons have been usually considered responsible for local flooding. For this study, origins of excess water were investigated using physical and chemical characteristics of the water involved. The prevalence of groundwater inflow to rainfall events was proposed based on data interpretation. Groundwater influence of flows of local and intermediate nature were defined and the importance of recharge, transit and discharge zones was highlighted. Lagoon floodwater, as well as groundwater from observation wells and production boreholes, show components of intermediate origin. Regional recharge water was identified in Mendoza and San Luis provinces. Their discharge zone was inferred to be located beyond the Buenos Aires province.     

Recent changes in flood risk in the Gran La Plata,Buenos Aires province,Argentina: causes and management strategy

The paper analyses the causes of flood occurrence in the Gran La Plata, Buenos Aires Province, Argentina, and the changes that have occurred since the 1970s. The area is characterized by serious deficiencies in the use and management of water resources. The main factors are: (1) flood risk information is not updated; (2) urban building organization does not consider the flood risk; (3) the topography and other physical features are not taken into account in urban development. This research considers some specific problems, especially in data availability, and suggests ways to solve them, including improved analytical methodology. One of the main objectives is to analyse flood risk in social terms, producing a map of flood risk from the “human social vulnerability” point of view. The results suggest that flood risk has increased since the 1980s and that this is associated with changes in precipitation patterns that have also been aggravated by lack of controls on urban development. The poorer areas with the lowest level of infrastructure and public services, many of them developed over the last quarter-century, are especially vulnerable.     

Geology and geochronology of type Chasicoan (late Miocene) mammal-bearing deposits of Buenos Aires (Argentina)

The late Miocene Chasicoan mammal-bearing deposits exposed along the lower reach of Arroyo Chasicó are composed of cross-bedded, very fine sandstones interpreted as a channel-bar deposit (lithofacies association 1) grading upward into sandy siltstones (lithofacies association 2), probably accumulated through relatively high-density flows in a marginal channel and/or floodplain environment. The uppermost levels are dominantly composed of mudstones and sandy siltstones (lithofacies association 3) deposited in generally low-energy conditions of sedimentation in a swampy environment. Several paleosols (lithofacies P) are present, indicating that the succession was the result of episodic fluvial sedimentation. The volcaniclastic composition (primary and reworked pyroclastics) suggests that the fluvial system drained the westward region by the Andean foothills. An impact event dated at 9.23 ± 0.09 Ma and recorded by impact glasses (escorias) during deposition of lithofacies Sp enables the fine tuning of the chronology of the deposits through high-resolution magnetostratigraphic profiles, which indicate that the approximately 9.4 m thick succession recorded by lithofacies association 1 and 2 accumulated between 9.43 and 9.07 Ma. The lithofacial arrangement of the succession does not support the current differentiation of the Arroyo Chasicó Formation into the Vivero and Las Barrancas members. Previous biostratigraphic interpretations contain significant inconsistencies in light of the revised stratigraphy proposed here.     

Prediction of seasonal water-table fluctuations in La Pampa and Buenos Aires, Argentina

The fluctuation of the water table east of La Pampa province and northwest of Buenos Aires province, Argentina, influences agricultural production in the region because it is closely related to the alternation of dry and wet periods. Sea-surface temperature (SST) anomalies have been used as predictors to forecast atmospheric variables in different regions of the world. The objective of this work is to present a simple model to forecast seasonal rainfall using SST distribution in the Pacific Ocean as a predictor. Once the relationship between precipitation and water-table fluctuations was established, a methodology for the prediction of water-table fluctuations was developed. A good agreement between observed and predicted water-table fluctuations was found when estimating water-table fluctuations in the summer and autumn seasons. Electronic Publication     

Relationship between precipitation and water-table fluctuation in a coastal dune aquifer: northeastern coast of the Buenos Aires province, Argentina

The water-table fluctuation (WTF) method is one of the most widely used means to estimate aquifer recharge. In the northeastern coast of the Buenos Aires province, Argentina, the geomorphological and climatic characteristics, as well as the presence of a shallow, homogeneous unconfined aquifer, make it possible to apply this methodology. The relationship between water-table fluctuations and precipitation in a humid climate, considering its seasonal variations, is assessed. Water tables were measured monthly between February 2008 and September 2010 in a monitoring network; rainfall data were analysed. The water table rises when the accumulated precipitation between measurements is more than 53?mm/month in the dry season and more than 97?mm/month in the rainy season. The index, relating water-table fluctuations and precipitation occurring between measurements, shows that values below 0 suggest no increase in the water reserves, whereas higher values entail an increase. In the study area, where there is a lack of historical data, finding out the relationship between water-table fluctuations and precipitation will constitute a tool for groundwater use and management, and set up an early warning system for dry periods. It could also be extrapolated to other regions with similar hydrological conditions lacking in data.     

Soil-forming rates and processes on Quaternary moraines near Lago Buenos Aires, Argentina

Thirty-four pedons on four moraine groups spanning the last 1 myr are used to investigate mechanisms and rates of soil development in Santa Cruz province, Argentina. All soils are coarse-loamy, mesic, Typic Haplocalcids or Calcic Haploxerolls occurring under short grass-shrub steppe, in a semi-arid climate. The dominant soil-forming processes are the accumulation of organic matter, carbonate, and clay-sized particles. Organic carbon accumulates rapidly in these soils, but significantly higher amounts in the oldest two moraine groups are likely the result of slight differences in soil-forming environment or grazing practices. Accumulation rates of carbonate and clay decrease with age, suggesting either decreased influx in the earliest part of the record or attainment of equilibrium between influx and loss. There are no changes in soil redness, and preservation of weatherable minerals in the oldest soils indicates there is little chemical weathering in this environment. Measured dust input explains the accumulation of both clay and carbonate. We present a carbonate cycling model that describes potential sources and calcium mobility in this environment. Calibration of rates of soil formation creates a powerful correlation tool for comparing other glacial deposits in Argentina to the well-dated moraines at Lago Buenos Aires.     

Hydrochemical and isotopic characterization of the hydrological budget of a MAB Reserve: Mar Chiquita lagoon,province of Buenos Aires,Argentina

Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study was to perform a hydrochemical and stable isotopes characterization in order to better the understanding of the hydrology of the Mar Chiquita lagoon’s catchment and its water budget. Groundwater samples were taken from 144 wells and 21 samples from main streams, and seven lagoon water samples were also collected. Chemical analyses were carried out using standard laboratory methods, and isotopic determinations were made through laser spectroscopy using a DLT-100 liquid–water isotope analyzer. Hydrochemical analysis permits a general classification of groundwater and streamwater as sodium bicarbonate waters, while the lagoon chemical composition shows an evolution toward seawater composition, from the north to its mouth, which is located southerly. Isotopic data show a source of aquifer recharge from rainfall and a groundwater domain into the streams’ flow. Three main components can be recognized as end members in a plot of electrical conductivity (EC) versus δ¹⁸O: seawater, streamwater and groundwater. Obtained EC values for groundwater in the discharge zone (EC average value = 3,516 μS/cm) allow minimizing its direct contribution and to take into consideration two dominating end members: streamwater and seawater. Mar Chiquita lagoon’s water falls close to the line between streamwater and seawater end members according to its EC and δ¹⁸O. The obtained seawater proportion for these samples ranges from 84 % in the lagoon’s mouth to around 0 % in the more distal area.     

Hydrogeochemistry and isotope analyses used to determine groundwater recharge and flow in low-gradient catchments of the province of Buenos Aires,Argentina

The region known as Pampa Plain, in Argentina, is a vast area characterized by slopes of less than 0.05%. The surface sediment is silty sand, mainly Aeolian, referred to as Pampean Loess, which is a phreatic aquifer unit of utmost importance for the water supply of the region. On account of the slight gradient, hydrogeological analyses using only hydraulic measurements are difficult to perform, often leading to confusing results. Thus, the study presented relies on hydrochemical modeling and isotopic determinations as well. The study area comprises three catchments in the inter-mountainous area corresponding to El Moro, Tamangueyú and Seco creeks, and covering 2,570 km² in the province of Buenos Aires. Measurements of piezometric levels and samples of groundwater, surface water and rainwater were carried out between January and March 2005. Major ion results were analyzed by means of hydrochemical graphs and hydrogeochemical modelling using NETPATH. The resulting data show that it is possible to identify local changes in recharge, flow direction and stream/groundwater relationship by using hydrochemical and isotopic information, which may become a useful and more precise tool for the study of particularly flat landscapes.     

Fluoride variations in groundwater of an area in Buenos Aires Province,Argentina

Spatial variations of fluoride concentration in groundwater in the town of Saldungaray, Argentina affect water quality for human supply and decrease the aquifer reserves. The study region is a piedmont area, located near a hill area (west) and the fluvial valley of the Sauce Grande River (east). Two hydrogeological units can be identified: bedrock and clastic sediments. These sediments consist of sandy silt with a variable amount of calcium carbonate. Its greatest thickness occurs near the river where it is 60 m. Groundwater flow coincides with topography. Fresh water is exploited from this unit and it has low salt contents (dissolved solids 400 to 800 mg/l). Fluoride concentration varies between 0.2 and 5 mg/l. The groundwater flow and hydrogeological characteristics related to spatial variations of fluoride content are analyzed. The quality of water is a critical parameter in determining the overall quality of human lives, and the occurrence of high fluoride concentrations can have a pronounced impact on groundwater quality.     

Soil properties evaluation in horticultural farms of Florencio Varela,Buenos Aires,Argentina

The south of the green belt of Buenos Aires is one of the most important producers of fresh vegetables in the province. Only few of the horticultural farmers receive professional agronomic advice. For this reason, an excess of supplies are being used, irrigation water quality is unknown and soils are not analyzed. The aim of this work was to evaluate chemical and physico-chemical characteristics of soils from Florencio Varela, Buenos Aires Argentina, which have not been cultivated for over 20 years (NC), under open-Fields Cultivation systems (FC) and under Greenhouses Cultivation systems (GC). The variables analyzed were: pH in water (pH), Electrical Conductivity (EC), Total Nitrogen (TN), Extractable Phosphorus (EP), Total Oxidizable Carbon (TOC), Oxidizable Carbon associated to Mineral fraction (MOC) and Particulate Oxidizable Carbon (POC). The results showed excess of EP, high pH and loss of oxidizable carbon for FC and GC with respect to NC. Furthermore, an incipient salinity was found in GC. Under FC, EC and TN were lower than GC, probably associated with leaching due to rain. Overfertilization is common in horticultural farming in the green belt, where the worst-case scenario is represented by phosphorus due to its low mobility and high residuality. The problems detected show the need for chemical analysis on soils and irrigation water. This will avoid imbalances due to overfertilization and the use of unsuitable water, thereby preventing soil degradation and aquifer contamination.     

Effect of agrochemicals on macroinvertebrate assemblages in Pampasic streams,Buenos Aires,Argentina

Agricultural practices have been intensified in recent decades in Argentina. The Pampa plain is the main agricultural region of the country. The effect of increased application of agrochemicals on the invertebrate fauna of the Pampasic streams remains unreported. In the present study, we compared the abundance and composition of invertebrate assemblages in seven Pampasic streams with contrasting soil use in their basins. Two streams run through intensively cropped plots, two drain basins with livestock fields, while the other three are located within a biosphere Reserve. Higher nutrient and insecticide concentrations were measured in the streams draining cropped basins, related with pesticide applications and crop fertilization. The invertebrate assemblage composition of the cropped streams differed significantly from the others and between the two. Present evidence suggests that the impact of agrochemicals results in a change in composition with decreased abundance or absence of sensitive species such as Hyalellidae, Caenidae, Baetidae and Curculionidae and increased abundance of more tolerant taxa: Ostracoda, Glossiphoniidae (Hirudinea), Ancylidae (Gundlanchia), Ampullariidae (Pomacea canaliculata), Sphaeriidae and Dugesiidae. Available information suggests that macrophyte cover and composition also influence the invertebrate assemblages of the Pampasic streams.     

Late pleistocene/early holocene environments and climates,fauna, and human occupation in the argentine altiplano

The Barro Negro site (23°S lat., 65°37′W long.) in the Altiplano (Puna) of northwestern Argentina contains a well stratified sequence of remains of Hippidion, the American extinct horse, camelids, and archaeological materials, which is the focus of this study. In addition to establishing a reliable chronology, paleoenvironmental information was obtained based on analyses of pollen and stable isotopes (oxygen and carbon) from bone and marl. The data indicate that Hippidion was present at the site between 12,000 and 10,000 yr B. P., at a time when Altoandean grasslands had expanded to lower elevations. By 10,000 yr B.P., when modern semi-arid sub-puna scrub had replaced the Altoandean grasslands, only camelids (Lama or Vicugna) were present, simultaneous with the first evidence of local human occupation. This suggests that a climatic shift from cool and moist (winter rain regime) to warm and dry (summer rain regime) conditions took place simultaneously with the disappearance of the American horse and the appearance of camelids and man.