Identification of hydrogeochemical processes and pollution sources of groundwater resources in the Marand plain,northwest of Iran

The main aims of the present study are to identify the major factors affecting hydrogeochemistry of groundwater resources in the Marand plain, NW Iran and to evaluate the potential sources of major and trace elements using multivariate statistical analysis such as hierarchical clustering analysis (HCA) and factor analysis (FA). To achieve these goals, groundwater samples were collected in three sampling periods in September 2013, May 2014 and September 2014 and analyzed with regard to ions (e.g., Ca²⁺, Mg²⁺, Na⁺ and K⁺, HCO₃ ^?, SO₄ ^2?, Cl^?, F^? and NO₃ ^?) and trace metals (e.g., Cr, Pb, Cd, Mn, Fe, Al and As). The piper diagrams show that the majority of samples belong to Na–Cl water type and are followed by Ca–HCO₃ and mixed Ca–Na–HCO₃. Cross-plots show that weathering and dissolution of different rocks and minerals, ion exchange, reverse ion exchange and anthropogenic activities, especially agricultural activities, influence the hydrogeochemistry of the study area. The results of the FA demonstrate that 6 factors with 81.7% of total variance are effective in the overall hydrogeochemistry, which are attributed to geogenic and anthropogenic impacts. The HCA categorizes the samples into two clusters. Samples of cluster C1, which appear to have higher values of some trace metals like Pb and As, are spatially located at the eastern and central parts of the plain, while samples of cluster C2, which express the salinization of the groundwater, are situated mainly westward with few local exceptions.     

Hydrological and hydrogeological characteristics of Wadi el Mujib catchment area,Jordan

Hydrological and hydrogeological data in the area have been verified to evaluate the availability and the potentiality of the water resources for the proposed damsites in the Wadi el Mujib catchment area, which is considered a semiarid to arid region. The quantity of the surface waters is very small compared with the surface area of the basin, however, due to the shortage of precipitation in the country and the necessity to attain socioeconomic objectives, the investigation of these waters has become more vital. The most reliable exploitation can be essentially achieved by constructing small storage dams on the suitable sites in order to benefit from the flood waters coming from the main wadis. For the above purpose, the hydrogeological and hydrological study of Wadi el Mujib catchment area was carried out, where the Wadi Mujib dam site will be constructed. The hydrogeological investigation of the groundwater was performed by constructing a groundwater contour map of the Amman-Wadi Es Sir aquifer (B2/A7) so as to verify the groundwater flow system and to determine the potentiality of the aquifer from the hydraulic parameters obtained from the pumping test analysis. The hydrological feasibility study of the dam was carried out by evaluating the water balance for a long-term period (1970 to 1990) in order to obtain reliable data that can be used to estimate the recharge to B2/A7 aquifer. In addition, a frequency analysis was performed to estimate the flood design of the reservoir area as well as the spillway at the proposed dam site.     

Identification of hydrogeochemical processes and their influence on groundwater quality for drinking and agricultural usage in Wadi Nisah,Central Saudi Arabia

Groundwater quality of a region is often controlled by the geochemical processes that operate with respect to the aquifer-water interaction, especially in arid regions where rainfall recharge is minimal. The goal of the present research was to understand the hydrochemical processes influencing groundwater chemistry and to evaluate groundwater quality for drinking and agricultural usage in Wadi Nisah and Wadi Al-Awsat, south of Riyadh. Twenty-nine groundwater samples were analyzed for major physio-chemical parameters. Ionic plots, chloro-alkaline indices, and modified Piper plots point towards reverse ion exchange. Saturation indices and correlation coefficients indicate halite, calcite, and dolomite dissolution. The Piper plot shows that most of the groundwater samples (82.76%) are of the (Ca + Mg)–(Cl-SO₄) type. The groundwater quality is not good for drinking due to its high total dissolved solid (TDS) content. The groundwater is found to be suitable for irrigation in terms of residual sodium carbonate, sodium adsorption ratio, soluble sodium percentage, Kelly’s index, and magnesium hazard. The high salinity is unsuitable for irrigation; however, this can be overcome by using salinity-resistant crop varieties.     

Identification and evolution of hydrogeochemical processes in the groundwater environment in an area of the Palar and Cheyyar River Basins,Southern India

The Palar and Cheyyar River Basins in Tamil Nadu state of Southern India are characterised by different geological formations, and groundwater is the major source for domestic, agricultural and other water-related activities. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes and their relation to groundwater quality. Groundwater samples were collected once a month from 43 groundwater wells in this area from January 1998 to July 1999. Sampling procedures and chemical analysis were carried out as per the standard methods. Chemical data are used for mathematical calculations and graphical plots to understand the chemical process and its relation to the groundwater quality. The chemical composition of groundwater in the central part of the study area mainly depends on the recharge from lakes and the river, which is explained by a mixing mechanism. In addition, weathering of silicate minerals controls the concentration of major ions such as sodium, calcium, magnesium and potassium in the groundwater of this area. Further, the activity ratios indicate that the groundwater is in equilibrium with kaolinite, smectite and montmorrillonite. The reverse ion exchange process controls the concentration of calcium, magnesium and sodium in hard rock formations, and dissolution of carbonate minerals and accessory minerals is the source of Ca and Mg, in addition to cation exchange in the sedimentary formations. In general, the chemical composition of the groundwater in this area is influenced by rock–water interaction, dissolution and deposition of carbonate and silicate minerals, ion exchange, and surface water interactions.     

Geoelectrical and hydrogeochemical studies for delineating seawater intrusion in the outlet of Wadi Ham, UAE

The Quaternary aquifer of Wadi Ham, UAE has been overexploited during the last two decades to meet the increasing water demands. As a result, the dynamic balance between freshwater and seawater has been disturbed and the quality of the groundwater has deteriorated. In this paper, a 2D earth resistivity survey was conducted in Wadi Ham in the area between Fujairah and Kalba to delineate the seawater intrusion. Existing monitoring wells were used to measure the horizontal and vertical variations in water salinity and thus to improve the interpretation of earth resistivity imaging data. Results of vertical electrical soundings and chemical analyses of collected water samples were used to obtain an empirical relationship between the inferred earth resistivity and the amount of total dissolved solids. This relationship was used along with the true resistivity sections resulting from the inversion of 2D resistivity data to identify three zones of water-bearing formation (fresh, brackish, and salt-water zones). Along the four 2D resistivity profiles, the depth to the fresh-brackish interface exceeded 50 m at the western part of the area and was in the order of 10 m or less in the eastern side near the shoreline. Depth to the brackish-saline water interface reached about 70 m in the western side and was in the order of 20 m in the eastern side. The thickness of the fresh water zone decreases considerably in the farming areas toward Kalba and thus the degree of seawater intrusion increases.     

Evidence for the occurrence of hydrogeochemical processes in the groundwater of Khoy plain,northwestern Iran,using ionic ratios and geochemical modeling

Rapid population growth, industrialization, and agricultural expansion in the Khoy area (northwestern Iran) have led to its dependence on groundwater and degradation of groundwater quality. This study attempts to decipher the major processes and factors that degrade the groundwater quality of the Khoy plain. For this purpose, 54 groundwater samples from unconfined and confined aquifers of the plain were collected in July 2017 and analyzed for major cations and anions (Na, K, Ca, Mg, HCO₃, SO_4, and Cl), minor ions (NO₃ and F), and Al. Magnesium and bicarbonate were identified as the dominant cation and anion, respectively. Several ionic ratios and geochemical modeling using PHREEQC indicated that the most important hydrogeochemical processes to affect groundwater quality in the plain were weathering and dissolution of evaporitic and silicate minerals, mixing, and ion exchange. There were smaller effects from evaporation and anthropogenic factors (e.g., industries). Results showed that the high salinity of the groundwater in the northeast area of the plain was due to the high solubility of the evaporitic minerals, e.g., halite and gypsum. Reverse ion exchange and the contribution of mineral dissolution were more significant than ion exchange in the northeastern part of the plain. Elevated salinity of the groundwater in the southeast was attributed mostly to reverse ion exchange and somewhat to evaporation.     

Geochemistry and assessment of hydrogeochemical processes in groundwater in the southern part of Bathinda district of Punjab, northwest India

Hydrogeochemistry of groundwater is important for sustainable development and effective management of the groundwater resource. Fifty-six groundwater samples were collected from shallow tube wells of the intensively cultivated southern part of district Bathinda of Punjab, India, during pre- and post-monsoon seasons. Conventional graphical plots were used to define the geochemical evaluation of aquifer system based on the ionic constituents, water types, hydrochemical facies and factors controlling groundwater quality. Negative values of chloroalkaline indices suggest the prevalence of reverse ion exchange process irrespective of the seasons. A significant effect of monsoon is observed in terms chemical facies as a considerable amount of area with temporary hardness of Ca²⁺–Mg²⁺–HCO₃ ^? type in the pre-monsoon switched to Ca²⁺–Mg²⁺–Cl^? type (18%) followed by Na⁺–HCO₃ ^? type (14%) in the post-monsoon. Evaporation is the major geochemical process controlling the chemistry of groundwater process in pre-monsoon; however, in post-monsoon ion exchange reaction dominates over evaporation. Carbonate weathering is the major hydrogeochemical process operating in this part of the district, irrespective of the season. The abundance of Ca²⁺ + Mg²⁺ in groundwater of Bathinda can be attributed mainly to gypsum and carbonate weathering. Silicate weathering also occurs in a few samples in the post-monsoon in addition to the carbonate dissolution. Water chemistry is deteriorated by land-use activities, especially irrigation return flow and synthetic fertilisers (urea, gypsum, etc.) as indicted by concentrations of nitrate, sulphate and chlorides. Overall, results indicate that different natural hydrogeochemical processes such as simple dissolution, mixing, weathering of carbonate minerals locally known as ‘‘kankar’’ and silicate weathering are the key factors in both seasons.     

Origin of flooding water through hydrogeochemical identification,the Buenos Aires plain,Argentina

Hydrogeochemical behaviour of samples of surface and groundwater collected on a cross-section from Mendoza to the Buenos Aires provinces was studied based on chemical trends, mass balance and water mixing. Hydrogeochemical modelling included major, minor elements as well as stable isotopes (deuterium and 18-O). The area investigated is located in the “Médanos Longitudinales” (longitudinal dunes) of the northwest of Buenos Aires province, Argentina. The study area is subject to alternating flooding and drought. Rainfall and surface water subsequently transferred by rivers, canals and lagoons have been usually considered responsible for local flooding. For this study, origins of excess water were investigated using physical and chemical characteristics of the water involved. The prevalence of groundwater inflow to rainfall events was proposed based on data interpretation. Groundwater influence of flows of local and intermediate nature were defined and the importance of recharge, transit and discharge zones was highlighted. Lagoon floodwater, as well as groundwater from observation wells and production boreholes, show components of intermediate origin. Regional recharge water was identified in Mendoza and San Luis provinces. Their discharge zone was inferred to be located beyond the Buenos Aires province.     

Hillslope processes and archaeology in Wadi Ziqlab,Jordan

Record levels of precipitation during February 1992 generated 290 earth flows and earth slumps in Wadi Ziqlab, Jordan. Geomorphologic and sedimentological characteristics of these landslides and older colluvial deposits were used to identify the dominant mass-wasting processes active in the wadi. Earth flows in 1992 left long linear scars on the steep hillsides and deposited thin, fine and coarse-grained, sheets on the well-developed colluvial slopes below. Older colluvial deposits exposed along the wadi bottom are crudely stratified, heavily bioturbated, and contain paleosols, suggesting colluviation was episodic and occurred through a slow accumulation of successive earth flows. Earth slumps in 1992 produced crescentic scarps, flat benches, and thick colluvial masses; similar features preserved on the wadi slopes were formed by the same process at an earlier time. Annual slope wash does not appear important on the steep, heavily landslide-scarred, slopes. The uneven distribution and episodic occurrence of earth flows and earth slumps in Wadi Ziqlab have resulted in highly variable burial depths of archaeological material, as illustrated in one locality where Roman artifacts are buried over 1 m deeper than a Neolithic site only 200 m away. The ability of earth flows to transport artifacts great distances has given rise to inverted stratigraphy on colluvial slopes and has produced large artifact scatters located beyond the margins of the colluvial slopes. These complex postoccupation disturbances and prehistoric land-use practices would have been difficult to interpret without a full understanding of the hillslope processes active in Wadi Ziqlab and the landscape features they have produced. © 1998 John Wiley & Sons, Inc.     

Integrated geophysical study to explore the groundwater in the tectonic plain between Wadi El Mahash and Wadi Um Markhah,Southwest Sinai,Egypt

South Sinai Governorate acts as one of the most vital regions in Egypt for its location and natural resources. This governorate has a special economic importance to increase the national income due to its tourism expansion and petroleum. The fresh water is transferred from Cairo through pipelines to cover the demands of local inhabitants in the north Sinai governorate and the capital city of south Sinai governorate. The groundwater exploration and exploitation in this area have a great importance to cover the need of water for the different activities (tourism, petroleum, and agriculture) and to achieve a maximum development in this region. Therefore, the present study deals with using the different geophysical exploration techniques (magnetic, geoelectrical resistivity and shallow refraction seismic) to detect the groundwater aquifer or aquifers in the area between latitudes 27°52′ and 28°05′?N and longitudes 33°55′ and 34°05′?E. in southwestern Sinai—Egypt. The main results of these tools are the maximum depth to the basement surface 180 m and structure elements which affected on this area are represented by a number of normal faults have a trends (NNW–SSE and ENE–WSW) making two grabens isolated by one horst. Tariff Sandstone bed recorded as water-bearing formation and the basement ridge gates in the gulf direction are not capable to pass the ground water from the study area to the Gulf of Suez. Finally, the best locations for drilling groundwater wells were selected from the decision map which generated by using the GIS technique.     

The western part of the Shuqra volcanic field,South Yemen

The western part of the Shuqra volcanic field consists of a wide area of geologically recent alkali basalt flows and numerous cinder cones, overlying a faulted monoclinal sequence of Jurassic limetones dipping towards the Gulf of Aden and themselves overlying Precambrian basement. The volcanic activity is substantially younger than the series of central vent volcanoes forming the Aden line somewhat to the west along the coast, and the volcanic products are more uniformly basaltic and more silica-undersaturated than those of the Aden volcanoes. Preliminary chemical data reveal an unusual whole-rock compositional trend within the Shuqra lavas which is not explicable in terms of the fractionation of the sparse phenocrysts they contain. A widespread suite of megacrysts not in equilibrium with their host liquids includes hornblende, pleonaste spinel, olivine, plagioclase and clinopyroxene. These may have a close genetic connection with the lavas and possibly represent fragments of refractory source material.     

Evidence of tidal processes from the lower part of the Witwatersrand Supergroup,South Africa

A 1600-m succession of quartz arenites and associated shaley deposits comprising the Hospital Hill Subgroup at the base of the Witwatersrand Supergroup is considered to have been deposited largely under the influence of tidal processes. Facies analysis indicates that deposition occurred in the following environments: (1) marine shalf; (2) shallow subtidal to intertidal; (3) intertidal flat; and (4) tidal inlet. The presence of strong tidal currents implies that the Witwatersrand Basin was open to an ocean basin, at least during the early stages of its evolution. Palaeocurrent trends and isopach data suggest that this probably lay to the southwest, an area now occupied by the high grade Natal—Namaqua metamorphic belt. The contrast between the supermature quartz arenites of the Hospital Hill Subgroup and the overlying gold-bearing immature subgreywackes, feldspathic quartzites and conglomerates of fluvial origin is believed to be a function of tidal reworking of sediments.     

Characterization and assessment of groundwater resources using hydrogeochemical analysis,GIS, and field data in southern Wadi Qena,Egypt

An integrated approach using hydrogeochemical analysis, remote sensing, GIS, and field data was employed to characterize the groundwater resources in southern Wadi Qena, Egypt. Various thematic maps showing topography, lineaments, wadi deposits, slope, and stream networks were combined through GIS analysis to discriminate groundwater potential zones on the valley floor. The resulting map classifies the area into five groups of groundwater potentiality from very high to very low zones, supported by the groundwater level, well locations, and by the results of previous geophysical studies. Thirty-seven groundwater well data were tested from the Quaternary and Nubian Sandstone aquifers and analyzed for physio-chemical parameters. Results of hydrochemical analysis show that water quality varies widely through the aquifers, and groundwater in the Quaternary aquifer shows the highest salinity values and a predominance of Na and Cl in water chemical facies. Overlay GIS maps of alkalinity (SAR and RSC) and salinity hazards (EC and Cl) of the Quaternary aquifer were prepared. The resulting maps show that samples do not present an alkalinity hazard in most areas but are potentially salinity hazard. Therefore, the water is fit for agricultural use with certain restrictions, but is not suitable for direct human consumption because it is either very hard or too saline.     

Influence of hydrogeochemical processes on temporal changes in groundwater quality in a part of Nalgonda district, Andhra Pradesh, India

Geochemical processes that take place in the aquifer have played a major role in spatial and temporal variations of groundwater quality. This study was carried out with an objective of identifying the hydrogeochemical processes that controls the groundwater quality in a weathered hard rock aquifer in a part of Nalgonda district, Andhra Pradesh, India. Groundwater samples were collected from 45 wells once every 2 months from March 2008 to September 2009. Chemical parameters of groundwater such as groundwater level, EC and pH were measured insitu. The major ion concentrations such as Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl⁻, and SO₄ ²⁻ were analyzed using ion chromatograph. CO₃ ⁻ and HCO₃ ⁻ concentration was determined by acid–base titration. The abundance of major cation concentration in groundwater is as Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ while that of anions is HCO₃ ⁻ > SO₄ ²⁻ > Cl⁻ > CO₃ ⁻. Ca–HCO₃, Na–Cl, Ca–Na–HCO₃ and Ca–Mg–Cl are the dominant groundwater types in this area. Relation between temporal variation in groundwater level and saturation index of minerals reveals the evaporation process. The ion-exchange process controls the concentration of ions such as calcium, magnesium and sodium. The ionic ratio of Ca/Mg explains the contribution of calcite and dolomite to groundwater. In general, the geochemical processes and temporal variation of groundwater in this area are influenced by evaporation processes, ion exchange and dissolution of minerals.     

三江平原建三江地下水位下降区地面形变监测、评估与预测

三江平原地下水开采量随着水稻种植规模快速扩张而大幅增加, 2021年水位相对1980年下降5~12 m, 是否因此引发地面形变甚至地面沉降成为社会关注的问题。采用二等水准测量方法和比拟法, 分析研究了三江平原建三江垦区地下水位降落漏斗地面形变现状与发展趋势及危险性。研究表明, 研究区50个二等水准测量点2019-2021年连续3期测量数据对比发现, 地表垂向形变量整体较小(最大-18.00 mm, 平均变化速率-4.6 mm/a)。预测到2040年, 地下水位降落漏斗中心水位埋深由2021年的19.88 m降至25 m左右, 考虑到研究区"上粘下砂"的二元岩性结构, 地下水位下降疏干的地层位于浅上部且厚度有限, 地面沉降量仍较小, 地质灾害发育程度弱、危险性小。本研究不仅回应了社会关切, 也为进一步开展相关研究奠定了基础。     

Sedimentological and geoenvironmental evaluation of the coastal area between Al-Khowkhah and Al-Mokha,southeastern Red Sea,Republic of Yemen

The increasing anthropogenic activities (e.g., constructing touristic resorts) have led to notable changes in the Yemeni Red Sea coastal regions. In this context, recent sediments have been investigated to infer possible natural and man-induced processes on these coastal areas. The target area lies between longitudes 43°13′–43°30′E and latitudes 13°15′–13°55′N. It extends about 90 km along the coastline as a part of the Tihama plain. Geomorphologically, it forms a long-curved stretch with pronounced headlands, embayments and bays. Generally, it is covered by recent sediments (wadi, lagoon, beach and spit deposits along with sabkha, coastal dunes and mangrove). Textural studies reveal that most of the studied sediments are mainly poorly to moderately sorted and are composed mainly of sandy fractions with few gravel and mud, mostly bimodal with minor unimodal patterns. The igneous (granites) as well as basic (basalt, andesite and andesitic pyroclastics) and acidic (dacite and rhyolite) volcanic rocks of Tertiary age, which are exposed to the east of the study area, are believed to be the source of pyroxenes, amphiboles, epidotes, biotite, sphene, zircon, tourmaline and rutile, in a decreasing order of abundance. Moreover, smectite, kaolinite, chlorite, illite and palygorskite are the predominant clay minerals, mainly of detrital origin. The total carbonate content fluctuates from 37.41% (lagoon sediments) to 53.74% (sabkha sediments). The high amount of sea grasses, which covers the tidal flat zone and relates to the fine-grained sediments, accounts for the high organic matter content. The mineralogy of the source rocks has controlled the general distribution of major elements (Fe, Mg, Na, K and Mn) in the beach sediments. In such sediments, the concentrations of the heavy metals (Cu, Zn, Cd, Ni, Pb and Co) may reflect the sediment pollution using different approaches. The enrichment factors (EFs) of the trace metals for most samples reveal values that are greater than 1, referring to three groupings, which are: moderate to moderately severe (Zn, Cu and Mn), minor to moderate (Pb and Co) and zero to minor (Cd and Ni) enrichment. The EFs for Pb, Cd, Ni and Co metals (<5) may be attributed to the crustal materials and/or natural weathering processes. But, those for Zn, Cu and Mn (>5), especially in Al-Khowkhah–Abu-Zahr, Moushij–Zahari–Ruays, Yokhtol and Mokha localities, are possible of anthropogenic contributions.     

Evaluation of groundwater vulnerability in the lower Varuna catchment area,Uttar Pradesh,India using AVI concept

Groundwater vulnerability assessments calculate the sensitivity of quality of groundwater to an imposed contaminant load which is essential element of the aquifer management plans. Seventy five groundwater samples have been analyzed for different chemical parameters to understand the groundwater quality of the lower Varuna river basin, Uttar Pradesh, India. The intrinsic groundwater vulnerability map of the lower Varuna catchment area in the north of the city of Varanasi (India) shows a high dependency on the depth to groundwater. The topmost layer of alluvial silty clay, protects the groundwater against contamination in this urban area, but the retention time in the unsaturated zone can be estimated to several months only. The input dataset is very sparse i.e. groundwater levels were measured twice (pre- and post-monsoon 2009) and the geological map shows only alluvium as the outcrop. Several boreholes in this area show, that the alluvium has a thickness of about 4 m and below that are fine grained sands. The surface information does not allow the development of a risk map since land use changes very fast and contamination areas can not be identified accurately. The vulnerability maps developed in this study have become important tools for environmental planning and predictive management of the groundwater resources in the fast urbanizing region in the Varanasi area.     

Groundwater hydrochemistry and origin in the south-eastern part of Wadi El Natrun,Egypt

The demand for water is rapidly increasing in Egypt, because of high population and agriculture production growth rate, which makes research of water resources necessary. The regional multi-aquifer system of the Miocene–Pleistocene age is discharged in Wadi El Natrun area. Intensive aquifer overexploitation and agricultural development in the area are related to groundwater quality deterioration. Hydrochemical and hydrogeological data was evaluated to determine the groundwater origin and quality in the south-eastern part of wadi, which appears to be more significant for water supply owing to lower groundwater salinity. The dominance of the high mineralised Cl groundwater type was found; however, also less mineralised SO₄ and HCO₃ types were identified there. Based on the ion relations, halite and gypsum dissolution and ion exchange are the most important hydrochemical processes forming the groundwater chemical composition. The Cl dominated groundwater matches the discharge part of the regional hydrogeological system. Contrary, the presence of HCO₃ and SO₄ hydrochemical types corresponds to the infiltration and transferring parts of the hydrogeological system indicating the presence of zones conducting low mineralised groundwater. The discharge area of the over-pumped aquifer in Wadi El-Natrun lies 23 m beneath the sea level with the shoreline being at the distance of 100 km, thus there is a real risk of seawater intrusion. Using the hydrochemical facies evolution diagram, four samples in the centre of the discharge area indicate advanced seawater intrusion. The zones of the highest demand for groundwater quality protection were indicated based on a spatial pattern of hydrogeochemical composition.