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1.
In order to understand the distribution characteristics of biomarkers in source rocks,which may be related to organic input,Quaternary sediments from the Caohai Basin and the Chaiwobu Lake were analyzed for sterols,As a result,various sterols,have been found in the sediments.The composition of sterols in the sediments revealed that cholesterols and cholestadienols are more abundant than their C29 counterparts in the Chaiwobu Lake sediments and that C29 sterols are more abundant in the peats from the Caohai Basin,It is also found that stanol/sterol ratios in clays are higher than in peats.Studies show that organic input to the Chaiwobu Lake is mainly plankton and zooplankton and to the Caohai Basin is mainly terrestrial high plant.The authors have proposed that the relative abundance of C27 or C29 sterane in source rocks may reflect input characteristics to some extent and the stanol/sterol ratios may reflect the redox conditions of the depositional environments.  相似文献   

2.
A preliminary organic geochemical study shows that the sulphide ores from the hydrothermal deposit of the Okinawa Trough are generally low in the total organic carbon and extremely low in the soluble organic matter. In the aliphatic hydrocarbon fraction, the n-alkanes range from C15 to C35, with usual maxima in the middle n-C20 region and strong odd-carbon number predominance when n > C25 (CPI = 1.2). The dominant analog in the aromatic fraction is phenanthrene, a polynuclear aromatic hydrocarbon, which provides evidence for hydrothermal activity. The organic matter derived mainly from marine planktonic and terrigenous vascular plants is entrapped in a high-temperature regime such as an active chimney and cooled quickly in the sulphide ores on the seafloor. Organic matter and sulphides are definitely products of a high-temperature alteration. The biomarker compounds indicate that the ores are formed under low Eh and pH conditions-a reducing to anoxic environment, which is favourable for sulphates to be  相似文献   

3.
Paired organic and carbonate carbon isotope compositions of Late Permian Wujiaping (吴家坪) and Dalong (大隆) formations at Shangsi (上寺), Northeast Sichuan (四川) were analyzed by MAT 251. An abrupt negative excursion in the two isotope records was observed in the middle part of Dalong Formation, in association with a drop in the carbon isotope difference of the two records and an increase of total organic carbon (TOC) content. The negative drop of the paired carbon isotope records issuggestive of the input of 12C-enriched CO2. The molecular ratios of pristane to phytane and dibenzothiophene to phenanthrene indicate the anoxic condition in this interval. The enhanced TOC content is indicative of the elevated preservation of organic matter due to the anoxic condition. These isotopic and organic geochemical data probably infer the occurrence of the upwelUng in this interval. The additional contribution of volcanism activity observed in South China cannot be excluded to the input of 12C-enriched CO2 and the negative shifts in carbon isotope composition of bulk organic matter and carbonate.  相似文献   

4.
Benthic foraminifera, preserved in the Late Cretaceous organic carbon-rich sediments of Gamba, southern Tibet, provide high-resolution proxies for sea-level changes and dissolved oxygen fluctuations of southeastern Tethys. The fossils were statistically analyzed and divided into three faunas of "Cenomanian fauna", "Turonian fauna", and "Coniacian fauna". A middle neritic-upper bathal environment (50-250m) was estimated considering the ratios of planktonic and epifaunal benthic foraminifera (P/(P+E)), the morphological analysis according to the studies of recent foraminifera and the abundant distributions of depth-related species such as Alabamina creta, Laevidentalina sp., Praebulimina spp., Pleurostomella cf. naranjoensis, Pyrulina sp., Quinqueloculina spp., Haplophragmoides spp., etc. The result shows an almost parallel trend with the global transgressive and regressive cycles, but the former fluctuates more frequently at upper Cenomanian, which probably indicates tectonic instability of the continental margin. According to the benthic foraminiferal richness (BFN), Shannon-Weiner diversity (H(s)), as well as benthic foraminiferal oxygen index (BFOI), five periods of oxygen depleted conditions (dysoxic-anoxic) have been recognized. They correspond to the OAE2, the lower Turonian, the upper Turonian, the Turonian-Caniacian boundary event and the probably OAE3. In addition, the oxygen fluctuations in Gamba might be controlled directly by sea-level changes, while the paleoproductivity and oxygen conditions interacted with each other under oxygen deficiency environments.  相似文献   

5.
Based on gas chromatography and gas chromatography mass spectrometry techniques, the authors examined biomarker characteristics of the Ganquan Formation source rocks in the area of Dahulishan, Ejina, and analyzed the information and petroleum geological significance that were indicated by the source of organic matter, sedimentary environment and maturity and so on. Gas chromatography peak of saturated hydrocarbons from the Ganquan Formation source rocks showed "the former peak" of the single peak distribution, the main peak of carbon being C18 , indicating the main sources of organic matter with marine organic matter. Pr/Ph ranges from 0.3 to 0.6, indicating a strongly reducing sedimentary environment. Biomarker assemblages of the Ganquan Formation source rocks are abundant in tricyclic terpane with long side chains, with a high level of gammacerane, showing dominant distribution of C27 sterane. High contents of gammacerane in organic matter show organic facies of source rocks in the saltwater sedimentary environment. That average hopane/sterane ratio is 0.59, showing that algae have made more contributions to organic matter than bacteria. And the high level of C27 steranes shows that algae are the main source of hydrocarbon precursors. The Ganquan Formation’s methylphenanthrene index, which is an effective molecular parameter index to measure thermal evolution of organic matter, ranges from 0.35 to 0.50, and the conversion of vitrinite reflectance Rc from it is within the range of 2.00-2.09, indicating that the Ganquan Formation source rocks are in the over-mature stage of thermal evolution.  相似文献   

6.
A primary study on palynofacies, which concerns the paleoenvironments from the sight of association of sedimentary organic matter preserved in sedimentary rocks, is conducted for a Late Jurassic-Cretaceous succession at Gyangzê, southern Tibet. Two palynofacies are recognized, which are formed in different sedimentary environments. The one in the pelagic is infertile in organic productivity and monotonous in component and is dominated by AOMA, while the other, being closely bound up with the slope, is characterized by abundant black phytoclasts that are possibly of algal origin and contains much AOM. The influence of terrestrial input is clear in the latter, for particles generated from terrestrial plants are common. A number of fossil spores and pollen together with some dinocysts are discovered, but they are normally in a bad condition of preservation. Nevertheless, this convinces us that the late Jurassic-Cretaceous succession in the Gyangzê area has a potential for palynological stratigraphy. We have also proved that the volume of PM can achieve similar results in presenting the productivity of organic matter as the weight of TOC does. This technique is much easier in the laboratory than that we do with TOC.  相似文献   

7.
A primary study on palynofacies,which concerns the paleoenvironments from the sight of association of sedimentary organic matter preserved in sedimentary rocks,is conducted for a Late Jurassic-Cretaceous succession at Gyangz(?),southern Tibet.Two palynofacies are recognized,which are formed in different sedimentary environments.The one in the pelagic is infertile in organic productivity and monotonous in component and is dominated by AOMA,while the other,being closely bound up with the slope,is characterized by abundant black phytoclasts that are possibly of algal origin and contains much AOM.The influence of terrestrial input is clear in the latter,for particles generated from terrestrial plants are common.A number of fossil spores and pollen together with some dinocysts are discovered,but they are normally in a bad condition of preservation.Nevertheless,this convinces us that the late Jurassic-Cretaceous succession in the Gyangz(?)area has a potential for palynological stratigraphy.We have also proved that the volume of PM can achieve similar results in presenting the productivity of organic matter as the weight of TOC does.This technique is much easier in the laboratory than that we do with TOC.  相似文献   

8.
The Honggang member of the early Paleogene Buxin Formation is the main source rock in the Sanshui Basin, characterized by organic-rich black shales with the cyclic recurrence of organic- poor sediments. The geochemical characteristics of the Honggang member have been documented to determine the organic matter types and depositional environments in this paper. The organic matter of the black shales mainly consists of a mixture of land plant-derived and phytoplankton-derived organic matter. Total organic carbon content (TOC)–sulfur–iron (Fe) relationships suggest that the organic- rich black shales were deposited under dysoxic-to-euxinic water conditions. The time that iron minerals remained in contact with H2S in anoxic waters possibly influenced the formation of syngenetic pyrite, and organic carbon controlled the formation of diagenetic pyrite. Organic-poor intervals usually show pyrite sulfur enrichment and higher degree of pyritization values relative to low organic carbon contents. This resulted from HS– diffusing downward from overlying organic-rich sediments and formed Fe sulfides through reactions with sufficient Fe. Trace elements generally exhibit low concentrations and little TOC dependence, suggesting some degree of depletion in these elements in the early Paleogene sediments of the Sanshui Basin. This probably resulted from cyclic recurrences of oxic benthic conditions, which promoted the remobilization of trace elements and caused the low concentration of trace elements.  相似文献   

9.
Surface lake sediments,28 from Hoh Xil,24 from northeastern China,99 from Lake Bosten,31 from Ulungur and 26 from Heihai were collected to determine δ13C and δ18O values.Considering the impact factors,conductivity,alkalinity,pH,TOC,C/N and carbonate-content in the sediments,Cl,P,S,and metal element ratios of Mg/Ca,Sr/Ca,Fe/Mn of bulk sediments as environmental variables enable evaluation of their influences on δ13C and δ18O using principal component analysis(PCA) method.The closure and residence time of lakes can influence the correlation between δ13C and δ18O.Lake water will change from fresh to brackish with increasing reduction and eutrophication effects.Mg/Ca in the bulk sediment indicates the characteristic of residence time,Sr/Ca and Fe/Mn infer the salinity of lakes.Carbonate formation processes and types can influence the δ13C–δ18O correlation.δ18O will be heavier from Mg-calcite and aragonite formed in a high-salinity water body than calcite formed in freshwater conditions.When carbonate content is less than 30%,there is no relationship with either δ13C or δ18O,and also none between δ13C and δ18O.More than 30%,carbonate content,however,co-varies highly to δ13C and δ18O,and there is also a high correlation between δ13C and δ18O.Vegetation conditions and primary productivity of lakes can influence the characteristics of δ13C and δ18O,and their co-variance.Total organic matter content(TOC) in the sediments is higher with more terrestrial and submerged plants infilling.In northeastern and northwestern China,when organic matter in the lake sediments comes from endogenous floating organisms and algae,the δ13C value is high.δ13C is in the range of 4‰ to 0‰ when organic matter comes mainly from floating organisms(C/N<6);in the range of 4‰ to 8‰ when organic matter comes from diatoms(C/N=6 to 8);and 8‰ to 4‰ when organic matter comes from aquatic and terrestrial plants(C/N>8).  相似文献   

10.
The comparative study of organic matter in carbonate rocks and argillaceous rocks from the same horizon indicates that the organic thermal maturities of carbonate rocks are much lower than those of argillaceous rocks .Ana extensive analysis of extracted and inclused organic matter from the same sample shows that inclused organic matter is different from extracted organic matter,and the thermal maturity of the former is usually lower than that of the latter in terms of biomarker structural parameters.It seems that carbonate mineras could preserve organic matter and retard organic maturation.The inclused organic matter,abundant in most carbonate rocks,will be released from minerals and transformed into oil and gas during the high-thermal maturity stage.  相似文献   

11.
The stable carbon isotopic compositions of free and sulfur (S)-bound biomarkers derived from algae, (cyano)bacteria, archaea and higher plants and total organic carbon (TOC) during the first phase of the late Cenomanian/Turonian oceanic anoxic event (OAE) were measured in black shales deposited in the southern proto-Atlantic Ocean in the Cape Verde basin (DSDP Site 367) to determine the response of these organisms to this major perturbation of the global carbon cycle resulting from widespread burial of marine organic matter. The average positive isotope excursions of TOC and biomarkers varied from 5.1‰ to 8.3‰. The δ13C values were cross correlated to infer potential common sources of biomarkers. This revealed common sources for C31 and C32 hopanes but no 1:1 relationship for pristane and phytane. The correlation of δ13CTOC with the δ13C value of sulfur (S)-bound phytane is the strongest. This is because S-bound phytane is derived from phytol that originates from all marine primary producers (algae and cyanobacteria) and thus represents a weighted average of their carbon isotopic compositions. The δ13C values of S-bound phytane and C35 hopane were also used to estimate pCO2 levels. Before the OAE burial event, pCO2 levels are estimated to be ca. 1300 ppmv using both biomarkers and the independent maximum Rubisco fractionation factors. At times of maximum organic carbon burial rates during the OAE, reconstructed pCO2 levels are estimated to be ca. 700 ppmv. However, compared to other C/T OAE sections the positive isotope excursion of S-bound phytane is also affected by an increased production during the OAE. When we compensate for this, we arrive at pCO2 levels around 1000 ppmv, a reduction of ca. 25%. This indicates that burial of organic matter can have a large effect on atmospheric CO2 levels.  相似文献   

12.
李祥辉  王成善  崔杰 《地学前缘》2005,12(2):171-177
介绍了高分辨率碳氧同位素的应用成果;指出半远洋、远洋碳酸盐全岩高分辨率碳同位素高值正偏可作为甄别大洋缺氧事件的指示剂和分析古气候变化的指针,碳同位素偏移型式可为长期海平面变化和短期海平面波动提供参照对比的依据。西藏南部岗巴地区的高分辨率偏移曲线显示,碳同位素Cenomanian Tu ronian界线时期的正偏幅度达2.90‰,Turonian期长期持续负偏,并在M. sigali带中、下部呈现两个负偏凹陷区。这表明,该区白垩纪中期Cenomanian Turonian期存在可以在特提斯甚至全球类比的碳同位素变化趋势,表现为Cenomanian Turonian界线时期的缺氧事件、Turonian期的长期海平面下降趋势和Turonian晚期短暂气候变冷的响应。  相似文献   

13.
西藏南部定日地区在白垩纪中期为一套浅灰色-深灰色的陆源碎屑岩(钙质页岩)及碳酸盐岩(泥灰岩及微晶灰岩)的混积型沉积物,其中的地球化学特征变化反映了古海洋发生的重大变革。δ13 C的同位素曲线变化具有明显的低-高-低旋回变化,δ13 C正偏与有机碳大量埋藏、海平面上升及缺氧事件密切相关。铀、钍、钾的含量变化及Th/U比值的变化特征表明由海平面上升所形成的全球大洋缺氧的重要时期,由于有机物质及粘土矿物的增多,它们的含量均比标准平均值偏高。而87Sr/ 86Sr比值在该时期偏低,这也与当时的构造背景及海平面发生重大变化相一致。  相似文献   

14.
Detailed chemostratigraphy across the Cenomanian-Turonian boundary in northern Tunisia points to several prevailing paleoceanographic conditions during the deposition of organic-rich beds of Bahloul Formation. The sedimentological study shows that there is no correlation between color and CaCO3 content because both dark and light-colored intervals of Bahloul Formation are carbonate-rich. Stable isotope analysis displays a positive carbon isotope excursion characterized by four significant peaks (I to IV) which are ranging from 3.2 to 3.5‰. These peaks represent episodes of elevated rates of organic carbon burial during the C/T oceanic anoxic event (C/T boundary OAE2). The Cenomanian-Turonian boundary could be situated between the third isotopic peak and the filament event. The total organic carbon (TOC) measurements show values ranging from 0.28 to 6.19% with average value of 3.5%. This indicates that the Bahloul Formation shale is a very good oil source rock. The Hydrogen Index (HI) values range from 359 to 698 mg HC/g TOC. The T max values range from 390 to 438 °C. Binary diagrams HI vs. T max indicate a type II with values falling within the immature organic-matter range. The concentrations major elements reveal low values of Ti and K. The correlation between Al and Ti and K shows a significant correlation pointing to homogeneous provenance. Primary productivity indicators (Cu, Ba, and Ni) record its association with organic matter. Redox-sensitive elements such as U, V, and Mo and the high values of V/(V + Ni) ratio indicate a strongly reducing environment which led to the better preservation of the organic matter.  相似文献   

15.
藏南地区白垩纪时期广泛沉积了一套海相富有机质沉积物,而其中与C-T界线缺氧事件有关的黑色页岩引起了广泛关注。但是,其有机碳含量与西特提斯相比明显偏低。因此,有关该区对海相白垩纪富有机质沉积影响机制的认识显得尤为重要。文中选取前人研究程度较高的岗巴宗山Ⅱ剖面、定日贡扎剖面和江孜加不拉剖面、床得剖面,利用其相关数据,定量计算了这些剖面的沉积速率、堆积速率和古生产力值。结果表明,藏南地区沉积速率以C-T界线时期最高,而岗巴、定日地区与江孜地区的沉积速率表现出较大的差异,这主要与沉积环境有关;并且在沉积速率<4cm/ka时,随着沉积速率的增加,有机碳含量随之增加,而沉积速率较大时,则关系不明显。江孜地区初级生产力较低,其缺氧期黑色页岩的形成并不是高生产力的结果,可能与缺氧条件的保存作用相关;对于岗巴和定日地区而言,尽管计算的古生产力较低,但碳同位素正偏以及推测存在的沿岸上升洋流表明,该区白垩纪富有机质沉积拥有高的初级生产力和缺氧的保存条件,表明该区有良好的古海洋条件,富有机质沉积的形成是高生产力、缺氧的保存条件以及低的沉积速率(<4cm/ka)共同作用的结果。而产生有机碳偏低,从而使得计算的古生产力值偏低的原因,则可能与成岩后期强烈的风化作用,导致有机碳的损失有关;另外定日地区C-T期有机碳含量偏低则还与其沉积物粒度有关。  相似文献   

16.
地质历史时期曾发过许多对生命的演化进程造成过重大影响与制约的全球性地质事件,白垩纪—古近纪就是一个重大地质事件频发的时期。随着冈瓦纳大陆在中生代时期的解体,全球海陆格局发生了根本的变化,地球的表层和岩石圈层均发生了重大的改变,由此引发了构造运动空前活跃,发生过诸如大洋缺氧事件(OAE)、大洋富氧事件(CORBs)、白垩纪/古近纪(K/Pg)生物大灭绝事件、古新世—始新世极热(PETM)事件、印度-亚洲板块碰撞、新特提斯洋的演化及最终消亡等一系列的全球性重大地质事件。对这些重大地质事件的研究,有助于加深我们对古海洋、古地理、古环境的认识。尝试追踪和捕捉这些重大地质事件,恢复和重建古地理,其基础是建立精确的年代地层格架。西藏南部保存了中国最为完整的海相白垩纪—古近纪沉积,完整地记录了上述的全球性重大地质事件,通过对札达、岗巴、定日、亚东、江孜、萨嘎和吉隆等地区高分辨率浮游和底栖有孔虫、介形虫、钙质超微化石和放射虫生物地层学研究,可直接约束全球性重大地质事件发生的时间,并为重建新特提斯洋古海洋环境和古地理提供证据。此外,在重大地质环境突变期间生物的演化过程,也可为探明极端环境变化发生时期气候-环境-生物之间的协同演化关系提供证据。本文系统总结了课题组为主的近年来对藏南白垩纪—古近纪海相地层中微体古生物学的研究成果及重要进展,并对未来研究提出展望。  相似文献   

17.
New stable carbon and oxygen isotope data from an Upper Cretaceous section in Tibet are presented, and compared to carbon isotope records from England, Italy, and Germany. Together with a stratigraphic re-interpretation of published carbon isotope data from a nearby section in Tibet, our data can surprisingly well be correlated with the European sections. This indicates that, similar to the distinct positive carbon isotope excursion at the Cenomanian-Turonian boundary, also the broad positive carbon isotope shift in the middle-late Coniacian and early Santonian reflects a major perturbation of the carbon cycle on a global scale, even though organic-rich sediments related to the OAE3 appear to be mainly restricted to the Atlantic Ocean and adjacent basins. The data further show that, apart from the broad Coniacian-Santonian carbon isotope excursion, also isotopic shifts on a smaller scale in the Turonian and Coniacian, such as the Round Down, Pewsey, and Hitchwood Events, can be correlated over both hemispheres. This demonstrates that the development of global oceanic anoxic conditions and associated burial of large amounts of organic carbon do not constitute a prerequisite for globally reflected carbon isotopic shifts. The data from Tibet support the concept of a relation between main carbon isotope excursions and major sea-level variations. Cyclic fluctuations of geochemical and lithological parameters are likely to be orbitally driven. These cycles appear to be preferably reflected in the sediments during periods of lower or variable sea-level, whereas the ocean-atmosphere system seems to have operated in a different mode during long phases of high, stable sea-level, as during the Coniacian-Santonian OAE3.  相似文献   

18.
Investigation of biogeochemistry and amino acids on a 30-m-long core from Mansar Lake has thrown light on palaeoclimate variability during the Holocene period. The C/N ratio between 6 and 10 with some deviations and δ13C mostly between −20 and −22‰ in the shallow core, as well as a C/N ratio greater than 13 reaching from 19 to 20 and correspondingly lower δ13C of –28‰ in the deeper core suggest an aquatic source of carbon in the former and a cellulose-rich land plant source in the latter. This is supported by the abrupt increase in organic carbon content in the deeper core compared to the shallow core, which indicates a hot and wet climatic regime during the early Holocene and dry and cold during the late Holocene period. The amino acid data AA-C/C% and AA-N/N% are higher in shallow sediments compared to deeper sediments, indicating an aquatic plant source in the shallow core and greater supply of land plant sources in the deeper core. The lower percentage of the non-protein amino acids β-alanine (ALA) and γ-amino-butyric acid in the shallow core compared to the deeper core indicates different sources of organic matter in the lake basin. The higher amino acid ratio Asp/β-Ala (16.99 av.) and Glu/γ-Aba (18.18 av.) in the shallow core and lower ratios (10.32 and 12.41 av.) in the deeper core, and Asp/Glu (1.52 av.) and β-Ala/γ-Aba (1.61 av.) ratios in the former, which are potential indicators of the nature of the organic matter, are higher in the shallow core relative to the deeper core (1.33 and 1.23 av.), indicating relative biodegradation of organic matter in deeper sediments. It has been observed that the organic matter associated with the dry season is relatively less biodegraded, as evidenced from their higher ratios, and is more biodegraded in the wet season as their ratios are lower in the river sediments. In the absence of a bacterial contribution of organic matter from the soil source in this lake, since Mansar Lake is a non-drainage type, it is envisaged that the climatic variation may be responsible for biodegradation in the deeper core sediments. Therefore, the C/N ratio and δ13C values supported by amino acid data, the latter being significant in revealing primary productivity and a terrestrial source of organic matter, suggest a hot and wet climatic regime during the early Holocene (ca. 7580 bp) and a dry and cold in the late Holocene period (ca. 4050 bp).  相似文献   

19.
藏南定日地区Cenomanian/Turonian界线附近的生物古海洋事件   总被引:4,自引:0,他引:4  
赵文金  万晓樵 《地质科学》2003,38(2):155-164
藏南定日地区在白垩纪中期发育一套浅灰色深灰色的以钙质页岩、泥灰岩及微晶灰岩为主的浅海陆棚相沉积,岩石中除含较高的粘土矿物及陆源石英矿物颗粒以外,还含有十分丰富的有孔虫化石。依据浮游有孔虫Helvetoglobotruncana praehelvetica的首次出现将C/T界线置于样品9922及9923之间,该界线位于Whiteinella archaeocretacea化石带之中。通过定量分析,该区有孔虫的丰度、分异度以及浮游与底栖有孔虫比率、具旋脊与不具旋脊有孔虫的比率等指标在剖面纵向上表现出3个明显的演化阶段,即Rotalipora cushmani带上部、W.archaeocretacea带及H.helvetica带下部,有孔虫动物群的变化特征完整地记录了C/T界线附近古海洋事件的全过程。该次事件中,碳稳定同位素δ13C值存在着明显的异常变化——正向偏移,元素地球化学U、Th及K的丰度也表现出明显的异常变化,其丰度值均比标准平均值偏高。所有这些特征均是在全球洋脊迅速扩张这一背景下海平面发生剧烈变化的结果。  相似文献   

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