Geochemistry and petrogenesis of the tertiary alkaline volcanic suite of the Labe tectonovolcanic zone,Czech Republic

Summary The Tertiary alkaline, nepheline-normative olivine melanephelinite-basanite-phonolite suite in the Labe tectono-volcanic zone, Czech Republic, displays mineralogical and geochemical features indicative of the presence of products of more than one fractionation series and of more than one parental magma. The Mg- and Ni-rich olivine melanephelinites (ankaratrites), which contain disintegrated lherzolite xenoliths, represent low degree (c. 4%) partial melts of a highly enriched mande source. Many of the abundant basanitic rocks also represent primary or near-primary basaltic melts subject to a small but variable degree Fof olivine fractionation. Other basanites with lower mg-numbers and Mg and Ni contents had a crystallization history involving hornblende and phlogopite.Melaphonolites (tephriphonolites) provide a link between basaltic rocks and phonolites with plagioclase fractionation progressively playing a more significant role. The phonolites represent products of crystallization of highly evolved melts but poor correlation between SiO₂, MgO, CaO, Na₂O and degree of undersaturation as well as between major and trace element contents indicate that a single line of descent cannot have been in operation: the products of different parental magmas showing a wide compositional range that evolved under different conditions of fractionation are represented. A very advanced stage of magma evolution, characterized by the dominance of alkali feldspar fractionation is represented by phonolites that contain the highest Hf, Nb, Rb, Ta, Th, Y, Zr and REE in the whole Tertiary volcanic suite.

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Geochemie und Petrogenese der tertiären alkalischen Vulkanit-Serie der Labe tektonovulkanischen Zone, Tschechische Republik

Zusammenfassung Die tertiäre alkalische Nephelin-normative Olivin Melanephelinit-Basanit-Phonolit Serie in der Labe tektono-vulkanischen Zone, Tschechische Republik, zeigt mineralogische und geochemische Eigenschaften, die auf die Anwesenheit von Produkten von mehr als einer Fraktionierungsserie und von mehr als einem Ausgangsmagma hinweisen. Die Mg- und Ni-reichen Olivin Melanephelinite (Ankaratrite), die umgewandelte LherzolitXenolite enthalten, stellen einen niedrigen Grad (ca. 4%) teilweiser Aufschmelzung einer stark angereicherten Mantelquelle dar. Viele der verbreiteten basanitischen Gesteine stellen auch primäre oder fast-primäre basaltische Schmelzen dar, die in kleinem, aber schwankendem Ausmaß von Olivinfraktionierung betroffen wurden. Andere Basanite mit niedrigen Mg-Zahlen und Mg- und Ni-Gehalten hatten eine Kristallisationsgeschichte in der Hornblende und Phlogopit eine Rolle spielte.Melaphonolite (Tephriphonolite) stellen ein Verbindungsglied zwischen basaltischen Gesteinen und Phonoliten dar, wobei Plagioklas-Fraktionierung eine zunehmend größere Rolle spielt. Phonolite sind Produkte der Kristallisation von Schmelzen, aber die schlechte Korrelation zwischen SiO₂, MgO, CaO, Na₂O und dem Grad der Untersättigung, wie auch zwischen Haupt- und Spurenelementen weist darauf hin, daß eine einzelne Entwicklungslinie nicht in Frage kommt. Die Produkte verschiedener Ausgangsmagmen zeigen ein weites Spektrum verschiedener Zusammensetzung, das sich unter verschiedenen Bedingungen der Fraktionierung entwickelt hat. Ein sehr fortgeschrittenes Stadium der Magmaentwicklung, charakterisiert durch die Vorherrschaft von Alkali-Feldspat-Fraktionierung wird durch Phonolite dargestellt, die die höchsten Gehalte an Hf, Nb, Rb, Ta, Th, Y, Zr und REE in der gesamten tertiären vulkanischen Abfolge führen.

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With 7 Figures     

Alkaline and ultramafic carbonate lamprophyres in Central Bohemian carboniferous basins,Czech Republic

Summary Dykes of alkaline and ultramafic carbonate lamprophyres (monchiquite-ouachitite and aillikite) intrude the Carboniferous sediments of Central Bohemia. Their characteristic feature is the presence of substantial amounts of a sodalite group mineral (presumably haüyne), carbonate and barite. Isotopic compositions of ¹³C (–3.4 to –6.2) and ¹⁸O ( + 13.5 to + 15.9) indicate that the carbonate is of primary magmatic origin and that fluids were formed at temperatures of 500 to 350°C. High contents of CO₂ (3.6 to 17.6 wt.%) and incompatible elements, high LREE/HREE ratios (30.0 to 57.7), and low Rb/Sr (0.025 to 0.078) and⁸⁷Sr/⁸⁶Sr (0.7038 to 0.7042) ratios suggest the ultramafic lamprophyres are related to deep-seated carbonated magmas of mantle origin. Low degree of partial melting ( < 1%) of the mantle peridotite is envisaged, with additional transport of fluids rich in incompatible elements into the crustal chamber. Alkaline lamprophyres are fractionated derivatives which originated from the same source. Magma intrusion from different levels of a magma chamber into fracture zones under horizontal tension without a central intrusion could result in variability in lamprophyre composition (cumulates or evolved derivatives).

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Alkalische und ultramafische Karbonat-Lamprophyre der zentralen böhmischen Karbonbecken, Tschische Republik

Zusammenfassung Alkalische und ultramafische Karbonat-Lamprophyrgänge (Monchiquit-Ouachitit und Aillikit) intrudieren in karbonische Sedimente Zentralböhmens. Sie sind charakterisiert durch das Auftreten von beträchtlichen Mengen an Mineralen der Sodalith-Gruppe (v.a. Haüyn), Karbonaten und Baryt. Ihre Isotopenzusammensetzung von ¹³C (–3.4 bis –6.2) und ¹⁸O (13.5 bis 15.9) zeigt, daß die Karbonate primär magmatischen Ursprungs sind und daß assoziierte Fluide in einem Temperaturbereich von 350 bis 500°C gebildet wurden. Hohe Gehalte an CO₂ (3.6 bis 17.6 Gew. %), inkompatiblen Elementen, hohe LREE/HREE-Verhältnisse (30.0 bis 57.7), sowie niedrige Rb/Sr—(0.025 bis 0.078) und⁸⁷Sr/⁸⁶Sr-(0.7038 bis 0.7042) Verhältnisse lassen vermuten, daß die ultramafischen Lamprophyre mit karbonatischen Magmen des Mantels in Beziehung stehen. Eine niedrige Aufschmelzungsrate ( < 1%) von Mantelperidotit mit zusätzlichem Transport von, an inkompatiblen Elementen angereicherten Fluiden, in die krustale Magmenkammer wird diskutiert. Alkalische Lamprophyre sind als stärker fraktionierte Magmen, die derselben Quelle entstammen, zu verstehen. Die Intrusion der aus verschiedenen Bereichen der Magmenkammer stammenden Magmen in durch horizontale Dehnung verursachte Störungszonen könnte das Fehlen eines zentralen Intrusionskörpers und die unterschiedliche Zusammensetzung der Lamprophyre (Kumulate oder entwickelte Derivate) erklären.

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With 8 Figures     

煌斑岩的分类、特征及成因

作为最早被识别出的碱性岩石之一,煌斑岩因富含金和金刚石等矿产资源以及对理解深部地球动力学过程的重要作用而受到广泛重视,但是目前对于煌斑岩的成因还存在不同的认识。本文基于近年来对煌斑岩的研究成果,对它们的分类、特征以及岩石成因进行综述。根据国际地科联(IUGS)的分类标准,煌斑岩可以分为超镁铁质煌斑岩、钙碱性煌斑岩和碱性煌斑岩。研究发现,超镁铁质煌斑岩往往是伸展环境下岩浆作用的产物,与金伯利岩和碳酸岩有密切的成因关系;钙碱性煌斑岩通常发育在汇聚或被动大陆边缘环境,其岩石成因可能有多种机制(如基性岩浆的分异、岩浆混合以及交代富集地幔的部分熔融);碱性煌斑岩出露在离散型大陆边缘和板内构造环境,通常和碱性玄武质岩浆作用密切相关。不管岩石的形成环境和过程如何,超镁铁质煌斑岩、钙碱性煌斑岩和碱性煌斑岩被普遍认为是来自于经历了交代富集作用的地幔源区。最后,文章指出了煌斑岩研究过程中存在的一些科学问题,如富集的地幔源区存在的矿物相(金云母和角闪石)对产生钠质还是钾质岩浆的影响,控制岩浆在结晶过程中影响含水矿物斑晶形成的因素以及部分煌斑岩中碳酸岩球粒和钠长石的形成原因等。     

The geochemistry and petrogenesis of K-rich alkaline volcanics from the Batu Tara volcano,eastern Sunda arc

Mineralogical, major and trace element, and isotopic data are presented for leucite basanite and leucite tephrite eruptives and dykes from the Batu Tara volcano, eastern Sunda arc. In general, the eruptives are markedly porphyritic with phenocrysts of clinopyroxene, olivine, leucite ±plagioclase±biotite set in similar groundmass assemblages. These K-rich alkaline volcanics have high concentrations of large-ion-lithophile (LIL), light rare earth (LRE) and most incompatible trace elements, and are characterized by high ⁸⁷Sr/⁸⁶Sr (0.70571–0.70706) and low ¹⁴³Nd/ ¹⁴⁴Nd (0.512609–0.512450) compared with less alkaline volcanics from the Sunda arc. They also display the relative depletion of Ti and Nb in chondrite-normalized plots which is a feature of subalkaline volcanics from the eastern Sunda arc and arc volcanics in general. Chemical and mineralogical data for the Batu Tara K-rich rocks indicate that they were formed by the accumulation of variable amounts of phenocrysts in several melts with different major and trace element compositions. The compositions of one of these melts estimated from glass inclusions in phenocrysts is relatively Fe-rich (100 Mg/(Mg + Fe²⁺)=48–51) and is inferred to have been derived from a more primitive magma by low-pressure crystal fractionation involving olivine, clinopyroxene and spinel. Mg-rich (mg 90) and Cr-rich (up to 1.7 wt. % Cr₂O₃) zones in complex oscillatory-zoned clinopyroxene phenocrysts probably also crystallized from such a magma. The marked oscillatory zoning in the clinopyroxene phenocrysts is considered to be the result of limited mixing of relatively evolved with more primitive magmas, together with their phenocrysts, along interfaces between discrete convecting magma bodies.     

大兴安岭东北部早白垩世秀山火山-侵入杂岩体特征及成因

大兴安岭东北部秀山林场一带的早白垩世花岗质火山-侵入杂岩体由喷发旋回期的流纹岩、流纹质熔结凝灰岩-粗面英安岩、粗安岩和浅成侵入期的二长花岗斑岩-晶洞正长花岗岩-文象碱长正长花岗岩构成。晚期侵入岩体充填于火山喷发形成的塌陷破火山口中央, 岩石具文象结构、晶洞构造等特征, 未见碱性暗色矿物。流纹岩(118.20 ±1.90 Ma) 与侵入岩形成时代(116.86～118.3 Ma) 相近。杂岩体岩石大多数属碱性系列, 具高硅、富碱、铝、Ga和高场强元素(HFSE) 的特征, 各岩石微量元素蛛网图上曲线形态基本一致, 均出现Sr、Ba谷, 稀土配分曲线也相似, 呈轻稀土富集的不对称右倾“海鸥”型, δEu 中等亏损。流纹岩与石英正长岩的86 Sr /87 Sr 初始值( 0.708 734 ～ 0.711 488) 、143Nd /144Nd初始值(0.512 485～0.512 503) 相近。杂岩体具时、空、源的一致性, 为铝质A1型火山-侵入杂岩体, 形成于岩石圈伸展机制下的非造山板内拉张构造环境。     

赣东北地区瑶里花岗岩年代学、地球化学及其岩石成因

瑶里花岗岩位于钦杭结合带赣东北地区,侵位于双桥山岩群和溪口岩群中,主要由石英、钾长石、斜长石、黑云母和少量白云母组成。LA-ICP-MS锆石U-Pb测年结果显示,该岩体形成年龄为132.0±1.9 Ma,获得的捕获锆石年龄表明该区在141.7±2.6 Ma发生过岩浆活动事件。岩体地球化学特征表现出具较高的SiO2含量和K2O/Na2O值,低的Al2O3、MgO、CaO和TiO2含量,铝饱和指数(A/CNK)为0.92~1.17,大部分大于1.1,属于高钾钙碱性过铝质花岗岩。岩石富集大离子亲石元素,亏损Nb和Ti元素,具有明显的轻稀土元素富集特征,δEu值为0.30~0.86。通过与相邻岩体的对比,发现瑶里岩体与同时期的鹅湖和卧龙谷岩体的地球化学特征相似,均可能由地壳深处变质泥质岩发生部分熔融形成。但是,瑶里岩体与中侏罗世德兴铜厂花岗闪长斑岩岩石学特征和地球化学性质不同,表明中侏罗世至早白垩世,花岗岩的形成温度和压力降低,深度变浅,指示钦杭结合带赣东北地区中侏罗世至早白垩世为碰撞后的伸展环境。     

Sr-Nd isotopic constraints on the petrogenesis of the Central Bohemian Pluton,Czech Republic

The Sr-Nd isotopic data for selected granitoids of the Central Bohemian Pluton show a broad negative correlation with the total range of (⁸⁷Sr/⁸⁶Sr)₃₃₀ = 0.7051–0.7129 and _Nd ³³⁰ = +0.2 to –8.9. The older intrusions have more depleted Sr-Nd compositions and calc-alkaline geochemistry (Sázava suite), whereas the younger intrusions shift towards K-rich calc-alkaline (Blatná suite) and shoshonitic rocks (íany and ertovo bemeno suites) with more evolved isotopic signatures. The distribution of the data is interpreted as reflecting a diversity of sources and processes, rather than a single progressive crustal contamination trend. The Sázava suite could have originated by partial melting of metabasites, or of a mantle source with an isotopic composition close to bulk earth, or by hybridization of crustally-derived tonalitic and mantle-derived magmas. Variation within the Blatná suite is modelled by mixing between a moderately enriched [(⁸⁷Sr/⁸⁶Sr)₃₃₀ 0.708, _Nd ³³⁰ –3] mantle component with either an isotopically evolved metasedimentary component, or with more evolved magmas of the suite. The íany suite was most probably produced by partial melting of peraluminous lithologies, possibly of the adjacent Moldanubian unit. The ertovo bemeno suite evolved from strongly enriched mantle-derived magmas [(⁸⁷Sr/⁸⁶Sr)₃₃₀0.7128, _Nd ³³⁰ –7], either through closed-system fractional crystallization or interaction with magma corresponding to leucogranites of the Central Bohemian Pluton.     

Middle/Late Cambrian intracontinental rifting in the central West Sudetes,NE Bohemian Massif (Czech Republic): geochemistry and petrogenesis of the bimodal metavolcanic rocks

The Early Palaeozoic East Krkonoše Complex (EKC) situated in the central West Sudetes, NE Bohemian Massif, is a volcano‐sedimentary suite containing abundant mafic and felsic volcanics metamorphosed to greenschist facies. The trace element distribution patterns and Nd isotope signatures (E_Nd500 = + 3.1 to + 6.6) of the metabasites (metabasalts) indicate that they may be related to a rising mantle diapir associated with intracontinental rifting. At the early stage, limited melting of an upwelling asthenosphere produced alkali basalts and enriched tholeiites which compositionally resemble oceanic island basalts. A later stage of rifting with larger degrees of melting at shallower depths generated tholeiitic basalts with E‐MORB to N‐MORB characteristics. The values of (⁸⁷Sr/⁸⁶Sr)_i = 0.706 and E_Nd500 = − 5 ±1 of the porphyroids (metarhyolites) as well as the lack of rocks with intermediate compositions suggest that the felsic rocks were formed by a partial melting event of continental crust triggered by mantle melts. The geochemistry of the EKC bimodal metavolcanics and their association with abundant terrigenous metasediments suggest that the felsic–mafic volcanic suite was generated during intracontinental rifting. This process, widespread in Western and Central Europe during the Early Palaeozoic, is evidence of large‐scale fragmentation of the northern margin of the Gondwana supercontinent. Copyright © 2001 John Wiley & Sons, Ltd.     

下扬子地区姚村A型花岗岩年代学、地球化学特征及岩石成因

姚村岩体位于下扬子江南造山带东北端,主要由中心相的中粗粒正长花岗岩和边缘相的细粒似斑状正长花岗岩组成.本文对该岩体进行了详细的锆石U-Pb年代学、主量元素、微量元素以及Nd-Hf同位素研究.LA-ICP-MS锆石U-Pb定年表明姚村岩体的形成年龄为(127.6±1.4)Ma,为燕山晚期岩浆活动的产物.岩石地球化学研究表...     

南天山川乌鲁碱性杂岩体的岩石学和地球化学特征及其岩石成因

位于中国南天山西侧阔克萨彦岭一带的川乌鲁碱性杂岩体,与该区川乌鲁铜金多金属矿床有着直接的成因联系,该杂岩体由早期的辉长岩—闪长岩岩、主期的二长岩—正长岩和晚期的正长花岗斑岩脉组成,各期岩石在矿物组成和化学成分上有明显的变化。从早到晚,SiO2含量增加,变化范围是50.52%～70.64%;全碱含量先增后减,在SiO2含量小于61.69%时,随SiO2含量增加而增加,而当SiO2含量大于61.69%时,与SiO2含量负相关。在AR-SiO2图解上,大多样品落入碱性区间,在A/CNK-A/NK图解上表现出由准铝质向过碱性演化的趋势。微量元素表现为大离子亲石元素相对高场强元素富集,Rb、Ba、Th、Sr等元素的相对富集和Nb、Ta、P、Ti等元素的负异常。稀土元素表现为轻稀土相对富集的特征,其(La/Yb)N为14.13～25.09,具有Eu的正异常或极微弱的Eu负异常。一些元素比值的线性关系暗示了该杂岩体为岩浆混合成因,基性岩浆的源区为富水的岩石圈地幔,而酸性岩浆是中下地壳中性火成岩在含饱和水条件下部分熔融的产物。这些性质指示川乌鲁杂岩体是在后碰撞拉张环境中由岩石圈地幔熔融的基性岩浆的底侵作用导致地壳的熔融以及后期的岩浆混合作用有关。     

滇西马厂箐煌斑岩成因:地球化学、年代学及Sr-Nd-Pb-Hf同位素约束

滇西马厂箐煌斑岩脉分为早晚两期,早期为云斜煌岩,晚期为云煌岩.对煌斑岩样品进行锆石LA-MC-ICP-MS U-Pb定年,获得33.77±0.11Ma的岩浆侵位年龄,表明马厂箐煌斑岩为马厂箐复式杂岩体中期岩浆结晶作用的产物,也是金沙江-哀牢山断裂带新生代早期岩浆活动的产物.岩石地球化学分析表明马厂箐煌斑岩高钾(K2O/NaO=2.88 ～4.60)、富碱(K2O+ Na2O =6.40％ ～7.55％)、高Mg# (74.3～76.9),富集大离子亲石元素(LILE) (K、Rb、Ba)和轻稀土元素(LREE),亏损高场强元素(HFSE)(Nb、Zr、P)和重稀土元素.同位素以高(87Sr/86Sr)i(0.707406～0.706506),低εNd(t)(-1.78～-7.64),富集放射性Pb(208 pb/204 Pb=38.87 ～ 39.35,207Pb/204 Pb=15.6390～15.6431,206Pb/204 Pb=18.6579 ～ 18.8093)为特征.176Hf/177Hf为0.282712 ～0.282864,εHf(t)为-1.4～4.0,εNd(t)与εHf(t)存在Nd-Hf同位素解耦.根据岩石地球化学和同位素特征以及区域构造演化历史分析,马厂箐煌斑岩起源于金沙江洋壳俯冲交代作用形成的富集地幔,区域上软流圈物质上涌可能促使EMII的部分熔融形成煌斑岩岩浆,而金沙江-哀牢山断裂及其与其他断裂的交汇处则为岩浆上侵提供了良好的通道.     

大兴安岭东北部塔河地区早白垩世高Sr低Yb型侵入岩的年代学、地球化学特征及地质意义

东北地区是中国显生宙花岗岩极其发育的地区,构造演化复杂。研究大兴安岭东北部塔河地区早白垩世侵入岩是解决大兴安岭地区中生代岩浆演化及构造背景的重要突破口。塔河地区早白垩世侵入岩的岩性主要有石英闪长岩、花岗闪长岩、二长花岗岩、正长花岗岩和花岗闪长斑岩。运用LA-ICP-MS测年方法对花岗闪长岩和石英闪长岩进行测年,锆石U-Pb年龄分别为131±1Ma (MSWD=0.73)和130±1Ma (MSWD=2.2)。早白垩世侵入岩SiO₂含量为61.32%~71.68%,为中酸性岩类。Al₂O₃含量为13.53%~15.62%,显示为准铝质或过铝质、高钾钙碱性花岗岩。∑REE为(152.28~253.85)×10^-6。地球化学特征可分为高Sr低Yb型和低Sr高Yb型两类侵入岩,起源于地壳的不同深度。研究区早白垩世侵入岩形成于蒙古-鄂霍次克洋洋盆自西向东的剪切式收缩闭合作用,可能与蒙古-鄂霍次克造山带陆-陆碰撞导致下地壳加厚作用有关。     

The Lapland charnockitic complex: REE geochemistry and petrogenesis

The Lapland charnockitic complex is mainly composed of basic and intermediate granulites, with more restricted types including ultramafic rocks and one high-Mg enderbite occurrence. All these rocks are interbedded with or intrude the metasedimentary granulites (khondalites).The charnockites can be subdivided on the basis of their Y and REE contents into three groups. The first group is characterized by an increase in Y content with progressive differentiation and by fractionated LREE-enriched patterns quite similar to those of some Archean granulites. The REE distribution patterns of these rocks suggests an origin by partial melting of a LREE-enriched mantle source (metasomatism). The other groups and the high-Mg enderbite are depleted in Y and display strongly fractionated REE patterns either with U-shaped HREE and positive Eu anomalies similar to Archean TTG rocks despite more basic major element composition (group II and the high-Mg enderbite) or with strong HREE depletion (group III). The high-Mg enderbite approximates closely high-Mg andesites with respect to major and some trace elements and its REE pattern is identical to those of early Archean group III komatiites of the Onverwacht Group, South Africa. Parental magmas for group II rocks and the high-Mg enderbite are assumed to derive by partial melting of a garnet-enriched mantle source metasomatized by a LREE-enriched fluid, whereas those of group III could be produced by melting of quartz-eclogites or garnet-amphibolites with fractionated REE patterns similar to those of group I.The overall petrographical and geochemical features of the Lapland charnockitic complex are consistent with an evolution of the Belomorian fold belt according to a collision model.     

Cretornis hlavaci Frič, 1881 from the Upper Cretaceous of Czech Republic (Pterosauria,Azhdarchoidea)

Cretornis hlavaci Frič, 1881 from the Upper Cretaceous (Turonian) of Czech Republic is a valid taxon referred to Azhdarchoidea based on having a saddle-shaped humeral head, pneumatic foramen on proximal humerus present on anterior side and absent on posterior side, elongate deltopectoral crest with subparallel proximal and distal margins, pneumatic foramen absent on distal side of humerus, metacarpals I–III not articulated with carpus and displaced on anterodorsal side of wing metacarpal, and wing metacarpal much longer than humerus. Absence of a pneumatic foramen on posterior side of proximal humerus suggests attribution of Cretornis hlavaci to Neoazhdarchia. It has a unique construction of the distal ulna with a dorsal articulation surface placed distinctly proximal to the tuberculum shared only with the non-azhdarchid azhdarchoid Montanazhdarcho minor from the Campanian of North America. Cretornis hlavaci differs from the latter taxon by the structure of its humerus and distinctly longer wing metacarpal. It is more derived than “Tapejaridae” but shares with Azhdarchidae the deltopectoral crest of the humerus displaced distally from humeral head. Cretornis cannot be assigned to Azhdarchidae because of the oval cross section of the second wing phalanx. A unique rhombic outline of the distal humerus of Cretornis hlavaci is a possible autapomorphy for this taxon. Its wing span estimated as 1.5–1.6 m. This is the first taxon of non-azhdarchid pterosaurs known from the Upper Cretaceous of the Eastern Hemisphere.     

湘东北金井地区花岗岩成因及地球动力学暗示：岩石学、地球化学和Sr-Nd同位素制约

出露于湘东北地区的燕山期花岗质岩岩体,呈岩基或岩株状广泛侵位于中元古界冷家溪群浅变质碎屑沉积岩中, 部分岩体为白垩纪红层覆盖。文章详细研究了金井岩体的岩石学、地球化学及Sr-Nd同位素特征,并与其围岩冷家溪群进行了对比。该岩体具有较高的SiO2(71．44-74．31wt．％)、K2O(3．86-4．98wt．％)和Na2O(3．24-3．84wt．％),以及较低的 FeO Fe2O3 MgO TiO2(均小于3％),结合高含量的Al2O3(13．25-14．89wt．％)及高ASI值(普遍大于1．1),为典型的强过铝质(SP)高钾钙碱性花岗岩。金井花岗岩富硅、碱和高Sr、Ba丰度、高LILE／HSFE和LREE／HREE比值,低镁铁质及REE 含量,表明金井岩体为高度分异的花岗岩,其源区的残留物中黑云母含量高。REE配分图和原始地幔多元素标准化图谱上 Rb、Th、U、K和LREE相对富集,而Ba、Sr和高强场元素(Nb、Ta、P和Ti)相对亏损,Eu可变的负异常(δEu:0．53-0．78),表明存在角闪石、黑云母、堇青石、磷灰石和钛铁矿等分异演化的影响,类似于同碰撞型花岗岩地球化学特征。高Rb／Sr(3-6)、低 Sr／Ba(0．2-0．7)、高P2O5含量(0．09-0．15wt．％)、低Al2O3／TiO2比值(40-700．4和<0．2两组)以及Nd同位素的不同(高Nd和低Nd两组),类似于围岩冷家溪群砂质和泥质沉积岩特征,以及高Sr[(87Sr／86Sr)i=0．72204-0．72540]、低Nd[εNd(145 Ma)=-10--12]等均表明花岗质岩浆主要起源于中元古代冷家溪群变质砂岩(高Ca)和变质泥岩(低Ca)的部分熔融或中下地壳物质的熔融,但有少量地幔物质的加入。结合印支期以来华南及湘东北地区地球动力学演化史,作者认为金井燕山期花岗岩形成于陆内碰撞造山晚期,是160-140Ma 陆内俯冲(A型俯冲)碰撞造山作用增温减压体制达到鼎盛阶段的产物,标志湘东北地区由此全面转入陆内伸展阶段。     

蒙阴盆地早白垩世火山岩地球化学特征及其岩石成因

蒙阴盆地早白垩世火山岩主要出露于青山群八亩地组和方戈庄组中。火山岩SiO₂含量为53.71%~69.08%,主要为安山质岩石和流纹岩,以钙碱性系列为主(σ平均3.42);富集Rb、Ba等大离子亲石元素和轻稀土元素,相对亏损Nb、Ta、P、Ti等高场强元素和重稀土元素;具有富集的Sr-Nd-Pb同位素组成(⁸⁷Sr/⁸⁶Sr(t)=0.7051~0.7110,ε_Nd(t)=-5.16~-16.4)。根据MgO含量和Mg^﹟值,可将安山质火山岩划分为高镁(Mg^﹟>60)和低镁(Mg^﹟<60)两个系列。高镁安山质岩石的MgO、Cr、Ni及不相容元素的含量明显高于低镁安山质岩石,且具有相对高的⁸⁷Sr/⁸⁶Sr(t)和较低的ε_Nd(t)值,Sr-Nd同位素组成趋向于EMⅡ型富集地幔端元。低镁安山质岩石地球化学特征类似于埃达克岩,其同位素组成介于EMⅠ型富集地幔端元与华北麻粒岩相下地壳之间。流纹岩具有较低的MgO、Cr、Ni含量和明显的负Eu、Sr异常,同位素组成类似于扬子中、上地壳。研究表明,蒙阴盆地高镁安山质岩石由曾遭受俯冲扬子陆壳熔体改造的华北岩石圈地幔部分熔融形成,且岩浆在上升 过程中经历了华北下地壳物质一定程度的混染或混合作用;低镁安山质岩石主要由华北下地壳部分熔融形成;流纹岩为岩石圈伸展减薄背景下仰冲至华北克拉通之上的扬子中、上地壳部分熔融的产物。地质现象显示,郯庐断裂带的伸展活动控制着蒙阴断陷盆地的发育,与蒙阴盆地早白垩世火山岩的成因有着密切的联系,在华北克拉通破坏中可能起到了重要的作用。     

云南永平卓潘碱性杂岩体岩石学和地球化学特征及成因研究

卓潘碱性杂岩体为"三江"地区富碱(高钾)侵入岩的重要组成部分,位于哀牢山-金沙江缝合带的中部,侵位于兰坪盆地南部的白垩系砂岩中,主要由碱性辉长岩、辉石正长岩和霞石正长岩组成。对卓潘碱性杂岩体的岩相学、岩石学、主元素和稀土微量及同位素地球化学特征的系统研究表明,该杂岩体主量元素显示低硅、富钾、高碱(K2O+Na2O为6.92%~13.43%)、低TiO 2(0.31%~1.20%)的特征,属钾质碱性系列岩石;杂岩体的各种岩石均富集Rb、Sr、Ba、Th等大离子亲石元素、亏损Nb、Ta、Ti等高场强元素,并具有轻稀土富集的右倾型稀土元素分布模式、具较高的87Sr/86Sr、206Pb/204Pb、207Pb/204Pb、208Pb/204Pb及较低的143Nd/144Nd等特征,表明源区具有较明显的EMⅡ型富集地幔特征,源区明显受到壳源物质的混染。卓潘岩体形成于印度-欧亚大陆后碰撞的剪切和拉张的构造环境,古扬子板片向西俯冲,诱发了经过陆壳交代混染了的岩石圈地幔的部分熔融。由于兰坪走滑拉分盆地东缘断裂拉伸强度大,岩浆起源的深度大,以及岩浆源区成分(特别是CO2含量)与其它部位不同,因此在卓潘地区形成一套与金沙江-哀牢山-红河断裂带其它新生代富碱斑岩完全不同的过碱性的岩石。     

Paleozoic alkaline volcanism: geochemistry and petrogenesis of Um Khors and Um Shaghir trachytes of the central Eastern Desert, Egypt

The Um Khors and Um Shaghir trachyte (UKT and UST) plugs and sheets represent two conspicuous outcrops of Paleozoic alkaline volcanism in the central Eastern Desert of Egypt. The trachyte magmatisms erupted along the Pan-African NW-trending shear zone (302?±?15 and 273?±?15?Ma, respectively) and intruded the Late Proterozoic rocks of the studied area. The trachyte rocks consist mainly of sanidine, anorthoclase, albite, and quartz with a noticeable amount of aegirine?Caugite, aegirine, hedenbergite, and arvedsonite. The studied trachytes are moderately evolved in composition (with 62?C67.5?wt.% SiO₂) and exhibit a limited compositional range in most of the major elements. They are alkaline in nature and considered as silica-oversaturated rocks. The rare earth elements (REE) patterns are somewhat uniform and highly fractionated, being enriched in light REE over heavy REE and show prominent negative Eu anomalies. The UKT and UST are enriched in high field strength elements Nb, Zr, and Y, consistent with typical within-plate alkaline magmatisms of extensional tectonic regimes. They were generated through the fractional crystallization of mantle-derived magmas. Although the UST is younger than the UKT, they show approximately similar chemical compositional ranges of the most major and trace elements, with somewhat higher MgO, Cr, Ni, and Ba contents in the former. This may argue against the evolution of the UST via a continuous fractional crystallization of the residual magmatic melt of the UKT. Thus, the UKT and UST are genetically related but could be emplaced through two various magmatic pulses of the same parent source (i.e., asthenospheric mantle source) at different times. The ascending magmatisms were subjected to variable significant degrees of crustal contamination during their generation.     

滇西北衙煌斑岩的岩石成因及动力学背景:年代学、地球化学及Sr-Nd-Pb-Hf同位素约束

北衙地区出露有多条煌斑岩脉,锆石LA-ICP-MS定年表明岩脉的侵位时间为34.96±0.66Ma,与滇西地区新生代岩浆活动的高峰期一致.岩石地球化学分析表明北衙煌斑岩具有高钾(K₂O/Na₂O为1.03~10.38)、富碱((K₂O+Na₂O)(平均7.55%)、高Mg^#(30~73),富集大离子亲石元素(LILE)(K、Rb、Ba)和轻稀土元素(LREE),亏损高场强元素(HFSE)和重稀土元素的特征.同位素以高(⁸⁷Sr/⁸⁶Sr)_i(0.70615~0.70825),低ε_Nd(t)(-5.3~-1.3),富集放射性Pb(²⁰⁸Pb/²⁰⁴Pb=38.542~38.856,²⁰⁷Pb/²⁰⁴Pb=15.553~15.617,²⁰⁶Pb/²⁰⁴Pb=18.482~18.612)为特征,¹⁷⁶Hf/¹⁷⁷Hf为0.282631~0.282882,ε_Hf(t)为-4.2~1.8.岩石地球化学和同位素特征表明该煌斑岩源自经俯冲板片交代富集了的岩石圈地幔,推测源区可能为含金云母的尖晶石相橄榄岩地幔与石榴石相橄榄岩地幔的过渡区,起源深度大致在75~85km,明显高于同区富碱斑岩的起源深度.构造和地球动力学背景分析表明,该煌斑岩以及滇西地区新生代岩浆作用都是对印度-欧亚大陆强烈碰撞的响应,都产在强烈伸展的动力学背景下,为岩石圈减薄的产物.