Geochemical fingerprint of the primary magma composition in the marine tephras originated from the Baegdusan and Ulleung volcanoes

The intraplate Baegdusan (Changbai) and Ulleung volcanoes located on the border of China, North Korea, and East/Japan Sea, respectively, have been explained by appeals to both hotspots and asthenospheric mantle upwelling (wet plume) caused by the stagnant Pacific plate. To understand the origin of the Baegdusan and Ulleung volcanism, we performed geochemical analyses on the tephra deposits in the East/Japan Sea basins originating from the Baegdusan and Ulleung volcanoes. The volcanic glass in the tephra from the Baegdusan and Ulleung volcanoes ranged from alkaline trachyte to peralkaline rhyolite and from phonolite to trachyte, respectively. The tephra from the two intraplate volcanoes showed highly enriched incompatible elements, such as Tb, Nb, Hf, and Ta, distinct from those of the ordinary arc volcanoes of the Japanese islands. The straddle distribution of the Th/Yb and Ta/Yb ratios of the tephra deposits from the Baegdusan volcano may originate from the alkali basaltic magma resulting from mixing between the wet plume from the stagnant Pacific plate in the transition zone and the overlying shallow asthenospheric mantle. In contrast, the deposits from the Ulleung volcano show a minor contribution of the stagnant slab to the basaltic magma, implying either partial melting of a more enriched mantle, smaller degrees of partial melting of a garnet-bearing mantle source, or a combination of both processes as the magma genesis. Our study indicated that the Baegdusan and Ulleung volcanoes have different magma sources and evolutionary histories.     

Late Quaternary tephra layers around Raoul and Macauley Islands,Kermadec Arc: implications for volcanic sources,explosive volcanism and tephrochronology

A suite of deep‐sea cores were collected along transects up to 100 km across the fore‐arc and back‐arc regions of the predominantly submarine Kermadec arc near Raoul and Macauley islands, southwest Pacific. The cores reveal a macroscopic tephra record extending back >50 ka. This is a significant addition to the dated record of volcanism, previously restricted to fragmented late Holocene records exposed on the two islands. The 27 macroscopic tephra layers display a wide compositional diversity in glass (～50–78 wt% SiO₂). Many tephra layers comprise silicic shards with a subordinate mafic shard population. This could arise from magma mingling and may reflect mafic triggering of the silicic eruptions. Broadly, the glass compositions can be distinguished on diverging high‐K and low‐K trends, most likely arising from different source volcanoes. This distinction is also reflected in the tephra records exposed on Raoul (low‐K) and Macauley (high‐K) islands, the likely source areas. Heterogeneous tephra comprising shards of both high‐ and low‐K affinity, silicic and mafic compositions, and more homogeneous tephra with subordinate outlier shard compositions, are best explained by post‐depositional mixing of separate eruption deposits or contemporaneous eruptions. Evidently, the slow sedimentation rates of the calcareous oozes (～10¹–10² mm ka^?1) were insufficient to adequately separate and preserve closely spaced eruption deposits. This exemplifies the difficulty in assessing eruption frequencies and magmatic trends, and erecting a tephrostratigraphy, using geochemical fingerprinting in such environments. Despite these difficulties, the ca. 5.7 ka Sandy Bay Tephra erupted from Macauley Island can be correlated over a distance of >100 km, extending east and west of the island, showing that the mostly submerged volcanoes are capable of wide tephra dispersal. Hence there is potential for developing chronostratigraphies for the southwest Pacific beyond the region covered by the extensive rhyolite marker beds from the Taupo Volcanic Zone. Copyright © 2011 John Wiley & Sons, Ltd.     

The volcanoes of an oceanic arc from origin to destruction: A case from the northern Luzon Arc

Volcanoes were created, grew, uplifted, became dormant or extinct, and were accreted as part of continents during continuous arc–continent collision. Volcanic rocks in Eastern Taiwan’s Coastal Range (CR) are part of the northern Luzon Arc, an oceanic island arc produced by the subduction of the South China Sea Plate beneath the Philippine Sea Plate. Igneous rocks are characterized by intrusive bodies, lava and pyroclastic flows, and volcaniclastic rocks with minor tephra deposits. Based on volcanic facies associations, Sr–Nd isotopic geochemistry, and the geography of the region, four volcanoes were identified in the CR: Yuemei, Chimei, Chengkuangao, and Tuluanshan. Near-vent facies associations show different degrees of erosion in the volcanic edifices for Chimei, Chengkuangao, and Tuluanshan. Yuemei lacks near-vent rocks, implying that Yuemei’s main volcanic body may have been subducted at the Ryukyu Trench with the northward motion of the Philippine Sea Plate. These data suggest a hypothesis for the evolution of volcanism and geomorphology during arc growth and ensuing arc–continent collision in the northern Luzon Arc, which suggests that these volcanoes were formed from the seafloor, emerging as islands during arc volcanism. They then became dormant or extinct during collision, and finally, were uplifted and accreted by additional collision. The oldest volcano, Yuemei, may have already been subducted into the Ryukyu Trench.     

Volcaniclastic resedimentation in distal fluvial basins induced by large-volume explosive volcanism: the Ebisutoge–Fukuda tephra, Plio-Pleistocene boundary, central Japan

The Ebisutoge–Fukuda tephra (Plio‐Pleistocene boundary, central Japan) has a well‐recorded eruptive style, history, magnitude and resedimentation styles, despite the absence of a correlative volcanic edifice. This tephra was ejected by an extremely large‐magnitude and complex volcanic eruption producing more than 400 km³ total volume of volcanic materials (volcanic explosivity index=7), which extended more than 300 km away from the probable eruption centre. Remobilization of these ejecta occurred progressively after the completion of a series of eruptions, resulting in thick resedimented volcaniclastic deposits in spatially separated fluvial basins, more than 100 km from the source. Facies analysis of resedimented volcaniclastic deposits was carried out in distal fluvial basins. The distal tephra (≈100–300 km from the source) comprises two different lithofacies, primary pyroclastic‐fall deposits and reworked volcaniclastic deposits. The resedimented volcaniclastic succession shows five distinct sedimentary facies, interpreted as debris‐flow deposits (facies A), hyperconcentrated flow deposits (facies B), channel‐fill deposits (facies C), floodplain deposits with abundant flood‐flow deposits (facies D) and floodplain deposits with rare flood deposits (facies E). Resedimented volcaniclastic materials at distal locations originated from unconsolidated deposits of a climactic, large ignimbrite‐forming eruption. Factors controlling inter‐ and intrabasinal facies changes are (1) temporal change of introduced volcaniclastic materials into the basin; (2) proximal–distal relationship; and (3) distribution pattern of pyroclastic‐flow deposits relative to drainage basins. Thus, studies of the Ebisutoge–Fukuda tephra have led to a depositional model of volcaniclastic resedimentation in distal areas after extremely large‐magnitude eruptions, an aspect of volcaniclastic deposits that has often been ignored or poorly understood.     

Central Mediterranean tephrochronology between 313 and 366 ka: New insights from the Fucino palaeolake sediment succession

Thirty-two tephra layers were identified in the time-interval 313–366 ka (Marine Isotope Stages 9–10) of the Quaternary lacustrine succession of the Fucino Basin, central Italy. Twenty-seven of these tephra layers yielded suitable geochemical material to explore their volcanic origins. Investigations also included the acquisition of geochemical data of some relevant, chronologically compatible proximal units from Italian volcanoes. The record contains tephra from some well-known eruptions and eruptive sequences of Roman and Roccamonfina volcanoes, such as the Magliano Romano Plinian Fall, the Orvieto–Bagnoregio Ignimbrite, the Lower White Trachytic Tuff and the Brown Leucitic Tuff. In addition, the record documents eruptions currently undescribed in proximal (i.e. near-vent) sections, suggesting a more complex history of the major eruptions of the Colli Albani, Sabatini, Vulsini and Roccamonfina volcanoes between 313 and 366 ka. Six of the investigated tephra layers were directly dated by single-crystal-fusion ⁴⁰Ar/³⁹Ar dating, providing the basis for a Bayesian age–depth model and a reassessment of the chronologies for both already known and dated eruptive units and for so far undated eruptions. The results provide a significant contribution for improving knowledge on the peri-Tyrrhenian explosive activity as well as for extending the Mediterranean tephrostratigraphical framework, which was previously based on limited proximal and distal archives for that time interval.     

New Age and Geochemical Data from the Southern Colville and Kermadec Ridges,SW Pacific: Insights into the recent geological history and petrogenesis of the Proto-Kermadec (Vitiaz) Arc

The intra-oceanic Kermadec arc system extends ~1300 km between New Zealand and Fiji and comprises at least 30 arc front volcanoes, the Havre Trough back-arc and the remnant Colville and Kermadec Ridges. To date, most research has focussed on the Kermadec arc front volcanoes leaving the Colville and Kermadec Ridges virtually unexplored. Here, we present seven ⁴⁰Ar/³⁹Ar ages together with a comprehensive major and trace element and Sr-, Nd-, and Pb-isotope dataset from the Colville and Kermadec Ridges to better understand the evolution, petrogenesis and splitting of the former proto-Kermadec (Vitiaz) Arc to form these two remnant arc ridges. Our ⁴⁰Ar/³⁹Ar ages range from ~7.5–2.6 Ma, which suggests that arc volcanism at the Colville Ridge occurred continuously and longer than previously thought. Recovered Colville and Kermadec Ridge lavas range from mafic picro-basalts (MgO = ~8 wt%) to dacites. The lavas have arc-type normalised incompatible element patterns and Sr and Pb isotopic compositions intermediate between Pacific MORB and subducted lithosphere (including sediments, altered oceanic crust and serpentinised uppermost mantle). Geochemically diverse lavas, including ocean island basalt-like and potassic lavas with high Ce/Yb, Th/Zr, intermediate ²⁰⁶Pb/²⁰⁴Pb and low ¹⁴³Nd/¹⁴⁴Nd ratios were recovered from the Oligocene South Fiji Basin (and Eocene Three Kings Ridge) located west of the Colville Ridge. If largely trench-perpendicular mantle flow was operating during the Miocene, this geochemical heterogeneity was likely preserved in the Colville and Kermadec sub arc mantle. Between 4.41 ± 0.35 and 3.40 ± 0.24 Ma some Kermadec Ridge lavas record a shift from Colville Ridge- to Kermadec arc front-like, suggesting the proto-Kermadec (Vitiaz-) arc split post 4.41 ± 0.35 Ma. The Colville and Kermadec Ridge data therefore place new constraints on the regional tectonic evolution and highlight the complex interplay between pre-existing mantle heterogeneities and material fluxes from the subducting Pacific Plate. The new data allow us to present a holistic (yet simplified) picture of the tectonic evolution of the late Vitiaz Arc and northern Zealandia since the Miocene and how this tectonism influences volcanic activity along the Kermadec arc at the present.     

Late Quaternary volcanism in New Zealand: Towards an integrated record using distal airfall tephras in lakes and bogs

Studies on distal airfall tephra layers preserved in lake sediments and peats in northern New Zealand have documented the stratigraphic, chronologic, and compositional relationships of 46 eruptives, aged c. 17000–700yr BP, which originated from six North Island volcanic centres: Taupo (9 tephras), Okataina (8), Maroa (1) (rhyolitic); Mayor Island (2) (peralkaline); Tongariro (11), Egmont (15) (andesitic). Sources were distinguished by mineralogy and composition, field relations, and ¹⁴C chronology. All known rhyolitic tephra-producing eruptions from Taupo, Okataina, and Maroa volcanoes since c. 17000yr BP are represented, but only a small proportion of the known tephras erupted from Tongariro, Egmont, or Mayor Island volcanoes is recorded. The distal tephras from these latter volcanic centres may thus reflect atypically powerful (or oblique) eruptions, or dispersal by strong winds. An improved record of volcanism for the Tongariro, Egmont, and Mayor Island centres might be obtainable from suitable lakes or bogs more proximal to them.     

Origin of Late Cenozoic Abaga–Dalinuoer basalts,eastern China: Implications for a mixed pyroxenite–peridotite source related with deep subduction of the Pacific slab

Continental intraplate basalts (15.42–0.16 Ma) from Abaga–Dalinuoer volcanic field (ADVF) in central Inner Mongolia of eastern China, as a part of Cenozoic volcanic province along eastern margin of the Eurasian continent, provide a good opportunity to explore potential links between deep subduction of the Pacific slab and continental intraplate volcanism. In this study, we report an integrated dataset of whole-rock K–Ar ages, major and trace elements and Sr–Nd–Pb isotopes, and olivine major and minor elements for the Abaga–Dalinuoer basalts (ADBs), and propose that mantle source lithology of the ADB magmas may consist of both pyroxenite and peridotite. The ADBs display low SiO₂ (42.3–50.2 wt.%), high MgO (7.3–11.4 wt.%) and moderate K₂O + Na₂O (3.8–6.4 wt.%), and can be subdivided into basanites, alkali basalts and tholeiitic basalts that are all characterized by ocean island basalt (OIB)-like rare earth elements (REE) and enrichment in both large ion lithosphile elements (LILE) and high field strength elements (HFSE). Olivine phenocrysts have higher Ni and Fe/Mn and lower Mn, Ca and Ca/Fe relative to those from peridotite melts, but exhibit clearly lower Ni contents (< 2500 ppm) compared with expected Ni range (> 3000 ppm) for olivines crystallized from olivine-free pyroxenite melts. Estimated compositions of the ADB primary magmas, together with olivine compositions, suggest an iron-rich mantle source related with silica-deficient pyroxenite that is most likely derived from deeply subducted Pacific oceanic crust. Additionally, peridotite and recent subducted sediments are also required to account for high Ni and MgO in primary magmas together with their trace elements and Sr–Nd–Pb isotope systematics. We suggest that a mixed pyroxenite–peridotite source lithology can better match observed whole-rock and olivine signatures in the ADB, compared with either peridotite only or olivine-free pyroxenite only source lithology. In our model, pyroxenite melts would either react with or mechanically mix with peridotite, and the proportion of pyroxenite melts may range from 30% to 45% for mechanical mixing scenario. A continuous spectrum from tholeiitic to alkali melts revealed by melt-peridotite reaction experiment can explain formation of primary magmas of basanites, alkali basalts and tholeiitic basalts by increasing melting degree of a similar mantle source. Relatively higher ²⁰⁶Pb/²⁰⁴Pb of the ADB may suggest more significant role of recent (< 0.5 Ga) subducted Pacific oceanic materials, in contrast to other Cenozoic basalts in eastern China (e.g., Changbai basalts) that exhibit varying contributions from ancient (> 1.5 Ga) subducted continental sediments. We emphasize that coupled geochemical and geodynamic links (i.e., subduction polarity) between deeply subducted Pacific slab and continental intraplate volcanism in eastern China may exist, which directly support the involvement of deeply subducted Pacific materials in petrogenesis of the ADB. From the perspective of plate motion kinetics, decompression partial melting of upwelling fragmented Pacific slab (silica-deficient pyroxenite + recent subducted sediments) may be triggered by rollback of deeply subducted Pacific slab during Late Cenozoic times. Continental intraplate volcanism in the ADVF generally started with termination of opening of the Japan Sea, suggesting that deep subduction of the Pacific slab may have been an important geodynamic mechanism responsible for tectono-magmatic evolution of northeastern Asia. We suggest that the ADBs have the potential to shed light on genetic links between continental intraplate volcanism and deep subduction of the Pacific slab in geochemical and geodynamic processes.     

Mafic Late Miocene–Quaternary volcanic rocks in the Kamchatka back arc region: implications for subduction geometry and slab history at the Pacific–Aleutian junction

New ⁴⁰Ar/³⁹Ar and published ¹⁴C ages constrain voluminous mafic volcanism of the Kamchatka back-arc to Miocene (3–6 Ma) and Late Pleistocene to Holocene (<1 Ma) times. Trace elements and isotopic compositions show that older rocks derived from a depleted mantle through subduction fluid-flux melting (>20%). Younger rocks form in a back arc by lower melting degrees involving enriched mantle components. The arc front and Central Kamchatka Depression are also underlain by plateau lavas and shield volcanoes of Late Pleistocene age. The focus of these voluminous eruptions thus migrated in time and may be the result of a high fluid flux in a setting where the Emperor seamount subducts and the slab steepens during rollback during terrain accretions. The northern termination of Holocene volcanism locates the edge of the subducting Pacific plate below Kamchatka, a “slab-edge-effect” is not observed in the back arc region.     

The role of dispersed ash in orbital-scale time-series studies of explosive arc volcanism: insights from IODP Hole U1437B,Northwest Pacific Ocean

ABSTRACT

Tephra fallout beds in marine sediments provide chronologically precise and highly resolved records of volcanism at time scales relevant to Quaternary climate cycles. While the record of discrete (visible) thin tephra beds is readily accessible, the significance of the dispersed (invisible) tephra record remains unclear. Here we evaluate the role of dispersed tephra for orbital-scale volcanic time variations in the Quaternary (<1.2 Ma) carbonate mud of IODP Hole U1437B (Northwest Pacific). The carbonate mud contains cyclic series of discrete fallout tephra beds from the oceanic Izu Bonin (~85% of tephra beds) and the continental Japan (~15%) volcanic arcs, respectively. Our results show the inorganic aluminosilicate (lithogenic) fraction is a mixture of dispersed Izu Bonin and Japan ash, and Asian dust. The time distribution of the Izu Bonin ash with its distinct composition appears to confirm and enhance the cyclic time variation of the discrete ash beds at Hole U1437B. Dispersed Japan ash resembles Asian dust in trace elements and is only distinguishable in Sr-Nd isotope space. Collectively, our results confirm the existence of periodic, orbital-scale fluctuations of arc volcanic frequency. Orbital-scale time variations of marine ash may be best established by series of discrete marine ash beds, yet the concomitant dispersed ash flux must also be recorded in order to understand the total flux of arc volcanic ash into the ocean basins and thus the role of the volcanism-climate link.     

The Holocene tephrostratigraphic record of Lake Shkodra (Albania and Montenegro)

Two cores were recovered in the southeastern part of Lake Shkodra (Montenegro and Albania) and sampled for identification of tephra layers. The first core (SK13, 7.8 m long) was recovered from a water depth of 7 m, while the second core (SK19, 5.8 m long) was recovered close to the present‐day shoreline (water depth of 2 m). Magnetic susceptibility investigations show generally low values with some peaks that in some cases are related to tephra layers. Naked‐eye inspection of the cores allowed the identification of four tephra layers in core SK13 and five tephra layers in core SK19. Major element analyses on glass shards and mineral phases allowed correlation of the tephra layers between the two cores, and their attribution to six different Holocene explosive eruptions of southern Italy volcanoes. Two tephra layers have under‐saturated composition of glass shards (foiditic and phonolitic) and were correlated to the AD 472 and the Avellino (ca. 3.9 cal. ka BP) eruptions of Somma‐Vesuvius. One tephra layer has benmoreitic composition and was correlated to the FL eruption of Mount Etna (ca. 3.4 cal. ka BP). The other three tephra layers have trachytic composition and were correlated to Astroni (ca. 4.2 cal. ka BP), Agnano Monte Spina (ca. 4.5 cal. ka BP) and Agnano Pomici Principali (ca. 12.3 cal. ka BP) eruptions of Campi Flegrei. The ages of tephra layers are in broad agreement with eight ¹⁴C accelerator mass spectrometric measurements carried out on plant remains and charcoal from the lake sediments at different depths along the two cores. The recognition of distal tephra layers from Italian volcanoes allowed the physical link of the Holocene archive of Lake Shkodra to other archives located in the central Mediterranean area and the Balkans (i.e. Lake Ohrid). Five of the recognised tephra layers were recognised for the first time in the Balkans area, and this has relevance for volcanic hazard assessment and for ash dispersal forecasting in case of renewed explosive activity from some of the southern Italy volcanoes. Copyright © 2009 John Wiley & Sons, Ltd.     

K‐Ar ages of Cainozoic volcanic suites,Bowen‐St Lawrence Hinterland,North Queensland (with some implications for petrologic models)

Thirty K‐Ar dates on Cainozoic volcanic rocks lying at the north end of the Bowen Basin suggest that several episodes of volcanism took place at major structural weaknesses. The oldest volcanism (ca 54 m.y.) was located outside the basin structure. The main volcanism (Nebo and East Clermont Provinces) extended from early Oligocene (34–35 m.y.) to mid‐Cainozoic time (21–22 m.y.?). Isolated Pliocene activity is tentatively suggested by dates on Mt St Martin (ca 3 m.y.).

Dating of the Nebo central volcano (31–33 m.y.) supports the model of Wellman &; McDougall, with volcanic activity related to migration of Australia northwards over a mantle magma source. Consideration of the Nebo dates with those of other central volcanoes in north Queensland, suggests that central felsic activity was surrounded by broad zones of peripheral eruptives, petrologically zoned from outer undersaturated basalts to inner saturated basalts. These zones (super provinces) delineate the size and profile of underlying magma sources and appear to trend back in time and space to sea‐floor spreading episodes in the Coral Sea—southeastern Papua region (55 m.y.).

The basalt dates also assist in fixing periods of lateritization (mid‐Oligocene) and in determining approximate minimum erosion rates in the northern Bowen Basin since the Eocene (3–5m/m.y.).     

Sedimentary processes caused by felsic caldera-forming volcanism in the Late Miocene to Early Pliocene intra-arc Aizu basin, NE Japan arc

Six large Late Miocene to Quaternary calderas, > 10 km in diameter, cluster together with several medium to small calderas and stratovolcanoes in a 60 × 30 km area of the Aizu volcanic field, southern NE Japan arc. These caldera volcanoes were built on a WNW–ESE trending highland coincident with a local uplifted swell since Late Miocene. The flare-up of felsic volcanism occurred synchronously along the NE Japan arc. Pyroclastic flow sheets from the calderas spread over the surrounding intra-arc basins and are interstratified with various sediments. Geochronological data indicates that the large-caldera eruptions have occurred six times since 8 Ma, at intervals of 1 to 2 million years. Late Miocene to Early Pliocene extra-caldera successions in the basin consist of nine sedimentary facies associations: (1) primary pyroclastics, (2) lahars, (3) gravelly fluvial channels, (4) sandy fluvial channels, (5) floodplains, (6) tidal flats, (7) delta fronts, (8) pro-delta slopes, and (9) pro-delta turbidites. The distribution of facies associations show westward prograding of volcaniclastic aprons, made up of braid delta, braidplain, pyroclastic flow sheet, and incised braided river deposits. The extra-caldera successions record: 1) an increase in felsic volcanism with an associated high rate of volcaniclastic sediment supply at about 10 Ma, prior to catastrophic caldera-forming eruptions; and 2) progradation of volcaniclastic aprons toward the back-arc side in response to the succeeding caldera-forming eruptions and sea-level changes, until about 3 Ma.     

Sedimentary record of explosive silicic volcanism in a Cretaceous deep-marine conglomerate succession, northern Antarctic Peninsula

Lower Cretaceous conglomeratic strata exposed on southern Sobral Peninsula were deposited on a deep‐marine apron in the back‐arc Larsen Basin close to its faulted boundary with the Antarctic Peninsula magmatic arc. The succession is dominated by amalgamated beds of clast‐supported conglomerate, which, together with minor intercalated sandstones, consist of varied, but largely basaltic to andesitic, volcanic material and clasts derived from the Palaeozoic–Triassic (meta)sedimentary basement of the arc. Most of the volcanic clasts are thought to have been derived from lithified volcanic successions or older synvolcanic deposits, rather than from sites of coeval eruption. These mixed‐provenance strata enclose a number of intervals, consisting mainly of inverse–normally graded conglomerate and graded–stratified pebbly sandstone, in which the sand fraction is dominated by crystals and vitric grains considered to have been redeposited in the immediate aftermath of explosive silicic arc volcanism. Like syneruption deposits on non‐marine volcaniclastic aprons, these intervals are more sand‐prone than the enclosing strata and appear to show evidence of unusually rapid aggradation. Plagioclase from one such interval has yielded ⁴⁰Ar/³⁹Ar ages concordant at ≈121 Ma, similar to those obtained from the non‐marine Cerro Negro Formation, deposited within the magmatic arc. It is suggested that the two successions can be viewed as counterparts, both recording a history of mainly basaltic to andesitic volcanism, punctuated by relatively infrequent, explosive silicic eruptions. Whereas the Cerro Negro Formation consists mainly of syneruption deposits, most of the volcaniclastic material delivered to the eruption‐distal, deep‐marine apron appears to have been derived by normal degradation processes. Only rare silicic eruptions were capable of supplying pyroclastic material rapidly enough and in sufficient quantities to produce compositionally distinct syneruption intervals.     

Correlation of the Late Cenozoic endogenic events and climatic variations in Central Asia

Trend of climatic changes in geological history of the Earth was determined by gradual decrease in the global surface temperature. Substantial deviations from this trend depended on the prevalent type of volcanism: predominantly explosive volcanism at convergent boundaries between lithospheric plates led to cooling and onset of glacial epochs, while intense intraplate volcanism strengthened greenhouse effect and resulted in global warming. During cold epochs, orogenic processes played an important role in climatic variations. The most frequent and regular climatic variations are controlled by the Earth position in solar orbit (Milankovitch cycles). The Late Cenozoic variations of cold climate were interrelated with orogenic processes caused by collision between the Indian and North Asian lithospheric plates. The first event of considerable cooling in the Northern Hemisphere (2.8–2.5 Ma ago) coincided with a rapid growth of mountains throughout the collision belt. The Tibetan Plateau formed in South Asia. In Central Asia, the large (> 1.5 × 10⁶ km²) Khangai-Altai-Sayan mountain system appeared 3 Ma ago. Total area subjected to orogenic processes in Central and South Asia exceeded 9 × 10⁶ km². The intense intraplate volcanism suggests that sublithospheric mantle was involved into orogenic processes. Alternation of glacial and interglacial climatic epochs during the last 1.8 m.y. is recorded in Central Asia. These climatic variations are compatible with the Milankovitch cycles. As is established, climatic events recognizable in the Baikal sedimentary record are correlative with interglacial and glacial epochs detectable in volcanic lavas of the East Sayan Mountains. There are indications of lava eruptions into ice during the cold periods. It is assumed therefore that all the cooling epochs detectable in the Baikal sedimentary record after 1.8 Ma were associated with development of mountain glaciation that formed glacial sheet up to 3 km thick and 100 000 km² in size. During the Brunhes Chron, there were eight glaciations at least. The endogenic (volcanism and orogeny) and exogenic (glaciation) processes during the last 3 m.y. are shown to be correlative. The intermittent development and degradation of thick ice sheets was responsible for oscillation of lithospheric load on the asthenosphere, and this caused periodical magma generation in marginal parts of volcanic provinces.     

Age and depositional setting of the Permian Black Dyke Formation: implications for the paleogeography and structural evolution of western Nevada

Abstract

In western Nevada, the Black Dyke Formation includes volcanic rocks overlain conformably by volcaniclastic sediments. At the base, hornblende-phyric basalts with cognate hornblende-bearing gabbroic cumulates are interbedded with tuffs and pyroclastic breccia. Amphiboles give ⁴⁰Ar/³⁹Ar ages of 276 Ma. Clinopyroxene-phyric pillow basalts and plagioclase-phyric andesitic lava flows are present higher in the section. Facies changes between exposures reflect development near volcanic centers.

According to our investigations, the Black Dyke Formation is involved in east–west-trending folds overturned toward the south, and overlain unconformably by the Mesozoic Dunlap Formation, which unconformably overlies the Mississippian–Permian Mina Formation. Interpreted until now as tectonic slices within the Luning allochthon, we suggest that the Black Dyke Formation is part of the Sonoma allochthon associated with the Mina Formation. The Sonoma records closure of the Havallah basin (Golconda allochthon), and collision of an arc- trench system with the North American margin.

The Black Dyke Formation exhibits similarities with the Permian arc sequence of the northern Sierra Nevada. Both sequences are characterized by amphibole-bearing breccias, clinopyroxene-phyric pillow-basalts, plagioclase-phyric andesites and overlying volcaniclastic sediments. These sequences developed in the same geodynamic environment (an island- arc). © Elsevier, Paris     

Mud volcanic natural phenomena in the South Caspian Basin: geology,fluid dynamics and environmental impact

The South Caspian sedimentary basin is a unique area with thick Mesozoic-Cenozoic sediments (up to 30–32 km) characterized by an extremely high fluid generation potential. The large amount of active mud volcanoes and the volumes of their gas emissions prove the vast scale of fluid generation. Onshore and offshore mud volcanoes annually erupt more than 10⁹ cubic meters of gases consisting of CH₄ (79–98%), and a small admixture of C₂H₆, C₃H₈, C₄H₁₀, C₅H₁₂, CO₂, N, H₂S, Ar, He. Mud volcanism is closely connected to the processes occurring in the South Caspian depression, its seismicity, fluctuations of the Caspian Sea level, solar activity and hydrocarbon generation.The large accumulations of gas hydrates are confined to the bottom sediments of the Caspian Sea, mud volcanoes crater fields (interval 0–0.4 m, sea depth 480 m) and to the volcanoes body at the depth of 480–800 from the sea bottom. Resources of HC gases in hydrates saturated sediments up to a depth of 100 m and are estimated at 0.2×10¹⁵–8×10¹⁵ m³. The amount of HC gases concentrated in them is 10¹¹–10¹² m³.The Caspian Sea, being an inland closed basin is very sensitive to climatic and tectonic events expressed in sea level fluctuations. During regressive stages as a result of sea level fall and the reducing of hydrostatic pressure the decomposition of gas hydrates and the releasing of a great volume of HC gases consisting mainly of methane are observed.From the data of deep drilling, seismoacoustics, and deep seismic mud volcanic activity in the South Caspian Basin started in the Lower Miocene. Activity reached its highest intensity at the boundary between the Miocene and Pliocene and was associated with dramatic Caspian Sea level fall in the Lower Pliocene of up to 600 m, which led to the isolation of the PaleoCaspian from the Eastern ParaTethys. Catastrophic reduction of PaleoCaspian size combined with the increasing scale of mud volcanic activity caused the oversaturation and intoxication of water by methane and led to the mass extinction of mollusks, fishes and other groups of sea inhabitants. In the Upper Pliocene and Quaternary mud volcanism occurred under the conditions of a semi-closed sea periodically connected with the Pontian and Mediterranean Basins. Those stages of Caspian Sea history are characterized by the revival of the Caspian organic world.Monitoring of mud volcanoes onshore of the South Caspian demonstrated that any eruption is predicted by seismic activation in the region (South-Eastern Caucasus) and intensive fluid dynamics on the volcanoes.     

Geochemistry and mineralogy of REY-rich mud in the eastern Indian Ocean

Deep-sea sediments in parts of the Pacific Ocean were recently found to contain remarkably high concentrations of rare-earth elements and yttrium (REY) of possible economic significance. Here we report similar REY-rich mud in a core section from Deep Sea Drilling Project Site 213 in the eastern Indian Ocean. The sediments consist mainly of siliceous ooze, with subordinate zeolitic clay that contains relatively high REY concentrations. The maximum and average total REY (ΣREY) contents of this material are 1113 and 629 ppm, respectively, which are comparable to those reported from the Pacific Ocean. The REY-rich mud at Site 213 shows enrichment in heavy rare-earth elements, negative Ce anomalies, and relatively low Fe₂O₃/ΣREY ratios, similar to those in the Pacific Ocean. In addition, the major-element composition of the Indian Ocean REY-rich mud indicates slight enrichment in lithogenic components, which probably reflects a contribution from southern African eolian dust. A volcaniclastic component from neighboring mid-ocean ridges or intraplate volcanoes is also apparent. Elemental compositions and X-ray diffraction patterns for bulk sediment, and microscopic observation and elemental mapping of a polished thin section, demonstrate the presence of phillipsite and biogenic apatite, such as fish debris, in the REY-rich mud. The strong correlation between total REY content and apatite abundance implies that apatite plays an important role as a host phase of REY in the present deep-sea sediment column. However, positive correlations between ΣREY and elements not present in apatite (e.g., Fe₂O₃, MnO, and TiO₂) imply that the REY-rich mud is not formed by a simple mixture of REY-enriched apatite and other components.     

Mid-Holocene Glacier Peak and Mount St. Helens We Tephra Layers Detected in Lake Sediments from Southern British Columbia Using High-Resolution Techniques

A Glacier Peak tephra has been found in the mid-Holocene sediment records of two subalpine lakes, Frozen Lake in the southern Coast Mountains and Mount Barr Cirque Lake in the North Cascade Mountains of British Columbia, Canada. The age–depth relationship for each lake suggests an age of 5000–5080 ¹⁴C yr B.P. (5500–5900 cal yr B.P.) for the eruption which closely approximates the estimated age (5100–5500 ¹⁴C yr B.P.) of the Dusty Creek tephra assemblage found near Glacier Peak. The tephra layer, which has not been reported previously from distal sites and was not readily visible in the sediments, was located using contiguous sampling, magnetic susceptibility measurements, wet sieving, and light microscopy. The composition of the glass in pumice fragments was determined by electron microprobe analysis and used to confirm the probable source of this mid-Holocene tephra layer. Using the same methods, the A.D. 1481–1482 Mount St. Helens We tephra layer was identified in sediments from Dog Lake in southeastern British Columbia, suggesting the plume drifted further north than previously thought. This high-resolution method for identifying tephra layers in lake sediments, which has worldwide application in tephrachronologic/paleoenvironmental studies, has furthered our knowledge of the timing and airfall distribution of Holocene tephras from two important Cascade volcanoes.     

Pb and Sr isotopes in volcanic rocks from the Aleutian Islands and Pribilof Islands,Alaska

The Pb and Sr isotope ratios of Plio-Pleistocene volcanic rocks from the Aleutian volcanic arc are used as tracers of the lithospheric subduction process at the converging Pacific and Bering plates. Aleutian arc lavas do not have the same Pb isotopic compositions as volcanic rocks of the subducted Pacific ocean crust or the nearby Pribilof Islands, but appear to contain an ‘old continental crustal component’ with high ²⁰⁷Pb/²⁰⁴Pb ratio, as has been found in some other volcanic arcs.⁸⁷Sr/⁸⁶Sr ratios in the Aleutian volcanic arc rocks average 0.70322, slightly higher than fresh volcanic rocks from normal ridge segments, but within the range of values from ‘Icelandic’ ridge segments, oceanic islands and the Pribolof Islands. The Pb and Sr isotopic compositions of Aleutian lavas show a positive correlation and the range of values does not change for volcanoes distributed along strike in the arc, even though the crustal type in the hanging wall of the Benioff zone changes from oceanic in the west to continental in the east. Since the basement of the continental arc segment is older than the basement of the oceanic segment, and probably has a different isotopic character, the constancy of isotopic ratios along the arc argues against contamination by wall rocks of the type exposed in the arc.A sufficient explanation for the isotopic data is the mixture of several per cent of continent-derived sediment with melt derived from the underthrust oceanic crust and overlying mantle. This small amount of contaminant is difficult to document by geophysical observations. Such a model implies extensive recycling of Ba, Pb, K and Rb through volcanism at convergent plate margins like the Aleutians.