A methodology to reconstruct small and short-lived ice-dammed lakes in the Appalachians of Southern Québec

Previous studies on the deglaciation of the Appalachians of southern Québec reconstructed only the most extensive ice-dammed lakes and the most stable glaciolacustrine water levels. They only used the best developed shoreline features, and thus were not able to reconstruct small or short-lived ice-dammed lakes, both being characterized by a weak development of their features. We propose a methodology to reconstruct glacial lakes which follows three main steps: (1) the mapping of shoreline features, generally the best developed ones, as in previous studies; (2) the delineation of the former shoreline for each water level, by also considering the less well-developed shoreline features which were found during field surveys designed as a function of the presumed shoreline position; and (3) the mapping of the maximum extension of the water plane, which includes the location of the former ice dam and of the former glacial lake spillway. In southern Québec, small ice-dammed lakes were numerous and important because they shaped the geomorphology of the region during the deglaciation. They are thus among the key components of a deglaciation model for this area.     

Paleomagnetism of the 1.88-Ga Sokoman Formation in the Schefferville–Knob Lake area,Québec,Canada, and implications for the genesis of iron oxide deposits in the central New Québec Orogen

Thirty-nine oriented block samples of iron-formation were collected at 13 sites, including opposite limbs of major folds, from the 1.88-Ga Sokoman Formation (Knob Lake Group) in the Schefferville–Knob Lake area of the central New Québec Orogen, northern Québec. The samples assayed up to 80.24% Fe₂O₃T (54.08% Fe), implying Fe-enrichment of the iron-formation up to ore grade. Anisotropy of magnetic susceptibility measurements on 245 standard specimens indicate a well preserved bedding-parallel fabric in the iron-formation, suggesting minimal alteration of the magnetic mineralogy since deposition and/or a mimetic secondary magnetic mineralogy. The iron-formation has not been internally deformed since the magnetic mineralogy was established. Analyses by variable-field translation balance and X-ray diffraction showed that the predominant magnetic mineral is hematite but a small amount of magnetite also is present in most samples. Following low-temperature pre-treatment as appropriate, stepwise thermal and alternating-field demagnetization of 218 specimens revealed a low-temperature, post-folding component (maximum T_ub≈400 °C, D=27.1°, I=20.1°, α₉₅=10.9°, from seven sites; pole position of 40.6°S, 257.0°E), and components carried by magnetite (maximum T_ub≈580 °C, D=35.8°, I=3.9°, α₉₅=9.1°, from 10 sites; pole position of 29.6°S, 250.9°E) and hematite (maximum T_ub≈680 °C, D=40.0°, I=1.6°, α₉₅=18.6°, from seven sites; pole position of 26.8°S, 247.0°E). The components carried by magnetite and hematite are pre-, syn- and post-folding depending on the sampling site, indicating that the magnetization was acquired continuously with deformation in the New Québec Orogen at 1.84–1.83 Ga. No evidence was found for acquisition of magnetization during the Mesozoic, when many of the iron oxide orebodies in the Schefferville–Knob Lake area are thought to have formed. Our findings imply that an episode of Fe-enrichment of iron-formation in the Sokoman Formation involved the circulation of hydrothermal fluids related to late Paleoproterozoic orogenesis. Such orogenic circulation of fluids may have contributed to the development of hematitic orebodies in the central New Québec Orogen.     

Social actors and their role in metropolitan governance in Montréal: towards an inclusive coalition?

The article is about the role of civil society organizations in the governance of the Montréal metropolitan region. It identifies a high level of cooperation around metropolitan scale issues on the part of these organizations. In the Montréal region, government agencies as well as private corporations demonstrate readiness to work alongside civil society organizations on joint projects. Evidence of this type of collaboration is particularly strong in the case of economic development, neighbourhood revitalization and cultural initiatives. This form of cooperation is perceived as a manifestation of the so-called “Québec model” and is an asset for the Montréal metropolitan region. The article demonstrates that interventions that involve social organizations are more likely to be successful than those that turn their back on these organizations.     

Age and origin of uranium mineralization in the Camie River deposit (Otish Basin,Québec,Canada)

The Camie River uranium deposit is located in the southeastern part of the Paleoproterozoic Otish Basin (Québec). The uranium mineralization consists of disseminated and vein uraninite and brannerite precipitated close to the unconformity between Paleoproterozoic fluviatile, pervasively altered, sandstones and conglomerates of the Matoush Formation and the underlying sulfide-bearing graphitic schists of the Archean Hippocampe greenstone belt. Diagenetic orange/pink feldspathic alteration of the Matoush Formation consists of authigenic albite cement partly replaced by later orthoclase cement, with the Na₂O content of clastic rocks increasing with depth. Basin-wide green muscovite alteration affected both the Matoush Formation and the top of the basement Tichegami Group. Uraninite with minor brannerite is mainly hosted by subvertical reverse faults in basement graphitic metapelites ± sulfides and overlying sandstones and conglomerates. Uranium mineralization is associated with chlorite veins and alteration with temperatures near 320 °C, that are paragenetically late relative to the diagenetic feldspathic and muscovite alterations. Re-Os geochronology of molybdenite intergrown with uraninite yields an age of 1724.0 ± 4.9 Ma, whereas uraninite yields an identical, although slightly discordant, 1724 ± 29 Ma SIMS U-Pb age. Uraninite has high concentrations in REE with flat REE spectra resembling those of uraninite formed from metamorphic fluids, rather than the bell-shaped patterns typical of unconformity-related uraninite. Paragenesis and geochronology therefore show that the uranium mineralization formed approximately 440 million years after intrusion of the Otish Gabbro dykes and sills at ∼2176 Ma, which constrains the minimum age for the sedimentary host rocks. The post-diagenetic stage of uraninite after feldspathic and muscovite alterations, the paragenetic sequence and the brannerite-uraninite assemblage, the relatively high temperature for the mineralizing event (∼320 °C) following the diagenetic Na- and K-dominated alteration, lack of evidence for brines typical of unconformity-related U deposits, the older age of the Otish Basin compared to worldwide basins hosting unconformity-related uranium deposits, the large age difference between basin fill and mineralization, the older age of the uranium oxide compared to ages for worldwide unconformity-related U deposits, and the flat REE spectra of uraninite do not support the previous interpretation that the Camie River deposit is an unconformity-associated uranium deposit. Rather, the evidence is more consistent with a PaleoProterozoic, higher-temperature hydrothermal event at 1724 Ma, whose origin remains speculative.     

Fluid-rock interaction between syenites and marbles at Stephen Cross Quarry,Québec,Canada: petrological and stable isotope data

Grenville dolomitic marbles and calc-silicates at Stephen Cross Quarry, Québec, underwent contact metamorphism and metasomatism associated with the intrusion of the Wakefield syenite at ambient pressures of 0.4GPa at 1090–1070Ma. Fluid infiltration produced exoskarns, calcite+periclase+forsterite±diopside±orthoclase assemblages in the marbles, and quartz±calcite±wollastonite±diopside±anorthite assemblages in the calc-silicates. Phase-equilibria in the CaO–MgO–Al₂O₃–SiO₂–H₂O–CO₂ system suggest that fluid infiltration occurred close to the thermal peak of contact metamorphism (715–815°C) and that the fluids hadXCO₂0.15. In the metasediments, ¹⁸O values of calcite (Cc) are as low as 8.6, suggesting that the fluids were in isotopic equilibrium with the syenites (¹⁸O =8.8–10.2). Marble ¹³C(Cc) values are-0.1 to-3.2; the lack of correlation between ¹³C(Cc) and ¹⁸O(Cc) is consistent with the infiltration of water-rich fluids. The resetting of stable isotopes and the mineralogical changes can be explained by time-integrated fluid fluxes of up to 110 m³/m² (4×10⁶ mol/m²), corresponding to actual fluxes of 3×10^-11 to 3×10^-12 m³/m²-s and intrinsic permeabilities of 10^-18 to 10^-20 m² for fluid flow lasting 0.1-1Ma. Marble ¹⁸O(Cc) values do not correlate well with distance from the syenite, and fluids were probably channelled across lithological layering. The correlation between the degree of resetting of marble ¹⁸O(Cc) values with the abundance of submillimetre-wide veins, suggests that fluid focussing may have resulted from variations in fracture density. Late, lower temperature (<500°C), fluid flow formed serpentine (Serp) and brucite (Br) from periclase and forsterite. ¹⁸O(Br) and ¹⁸O(Scrp) values correlate with ¹⁸O(Cc), suggesting that retrogression involved only limited volumes of fluid. The observation that ¹⁸O(Cc-Br) and ¹⁸O(Cc-Serp) values are higher in marbles that have lower ¹⁸O(Cc) values is interpreted as indicating that fluid flow persisted to lower temperatures in those rocks due to higher intrinsic permeabilities. Calcite in the syenite was also formed by the influx of fluids during cooling. Syenite ¹⁸O(Cc) values are approximately in isotopic equilibrium with the high-temperature silicate minerals, suggesting that again only minor volumes of fluid were involved. In detail fluid flow was prolonged and complex, creating problems for the application of quantitative fluid flow models.This paper is a contribution to IGCP 304, Lower Crustal Processes     

Logistic models as a forecasting tool for snow avalanches in a cold maritime climate: northern Gaspésie,Québec,Canada

Snow avalanches are a major natural hazard for road users and infrastructure in northern Gaspésie. Over the past 11 years, the occurrence of nearly 500 snow avalanches on the two major roads servicing the area was reported. No management program is currently operational. In this study, we analyze the weather patterns promoting snow avalanche initiation and use logistic regression (LR) to calculate the probability of avalanche occurrence on a daily basis. We then test the best LR models over the 2012–2013 season in an operational forecasting perspective: Each day, the probability of occurrence (0–100%) determined by the model was classified into five classes avalanche danger scale. Our results show that avalanche occurrence along the coast is best predicted by 2 days of accrued snowfall [in water equivalent (WE)], daily rainfall, and wind speed. In the valley, the most significant predictive variables are 3 days of accrued snowfall (WE), daily rainfall, and the preceding 2 days of thermal amplitude. The large scree slopes located along the coast and exposed to strong winds tend to be more reactive to direct snow accumulation than the inner-valley slopes. Therefore, the probability of avalanche occurrence increases rapidly during a snowfall. The slopes located in the valley are less responsive to snow loading. The LR models developed prove to be an efficient tool to forecast days with high levels of snow avalanche activity. Finally, we discuss how road maintenance managers can use this forecasting tool to improve decision making and risk rendering on a daily basis.     

Interpreting amenities,envisioning the future: common ground and conflict in North Carolina’s rural coastal communities

This paper contributes to ongoing discussions about the implications of rural change and amenity migration for members of diverse rural communities. We engage with recent amenity migration and political ecology literature that focuses on social constructions of nature and landscapes, and how these constructions affect the attitudes and opinions of community members. We use our case study of a mail-based survey in Down East, North Carolina to suggest that the ways in which people conceptualize the particular ‘natures’ and landscapes of a place matters in terms of shaping people’s attitudes with respect to ongoing processes of change. We find that people’s opinions about environment, culture, and land use are often superficially similar but that when conflicts arise or particular actions are considered, substantial differences in people’s underlying conceptual frameworks are revealed. In particular we find that despite widespread shared appreciation of the environment and culture Down East, differing interpretations of these key terms lead to potential misunderstandings and land use planning challenges.     

Is area affected by flood or stagnant water independently associated with poorer health outcomes in urban slums of Dhaka and adjacent rural areas?

This study investigated the association of flood/stagnant water (FSW) with various health outcomes among respondents living in urban slums of Dhaka and adjacent rural areas. We also assessed the differences of individual-, household- and area-level characteristics between the FSW-affected and non-affected areas. Bangladesh as a whole and slums in the megacity of Dhaka in particular are severely affected by the FSW. Data were collected from 3,207 subjects (aged 10+ years) through baseline surveys conducted in March 2008 and 2009. Twelve big slums in Dhaka and three adjacent villages were selected as study areas. Face-to-face interviews using a multidimensional pre-tested questionnaire were conducted by the trained university graduates. We performed various types of analyses ranging from the simple frequency analysis to the multivariable-adjusted logistic regression modelling. Our empirical findings suggest that slums were more affected by the FSW as compared to the rural areas. People living in the FSW-affected areas were more vulnerable in terms of individual-, household- and area-level characteristics than non-affected people. Age was also significantly associated with various health outcomes. According to multivariable analyses controlled for various factors, the FSW-affected people reported significantly higher likelihoods of health symptoms (namely fever, cold/cough, weakness), communicable diseases (namely diarrhoea and gastric disease) and poor mental well-being as compared to the non-affected people. Only the burden of non-communicable diseases was lower in the FSW-affected areas than the non-affected areas. Our findings lead us to conclude that the FSW-affected area is an independent risk factor for various physical and mental health problems. Urban slums are more affected than rural areas by the FSW. Therefore, we underscore the necessities of well-designed and comprehensive public health interventions focusing on individual, community and higher levels of interventions to reduce the FSW-related health and other consequences among the people living in the FSW-affected areas and urban slums in the rapidly growing city of Dhaka, Bangladesh.     

Characterization of deep saline aquifers in the Bécancour area,St. Lawrence Lowlands,Québec,Canada: implications for CO2 geological storage

The present paper provides a case study of the assessment of the potential for CO₂ storage in the deep saline aquifers of the Bécancour region in southern Québec. This assessment was based on a hydrogeological and petrophysical characterization using existing and newly acquired core and well log data from hydrocarbon exploration wells. Analyses of data obtained from different sources provide a good understanding of the reservoir hydrogeology and petrophysics. Profiles of formation pressure, temperature, density, viscosity, porosity, permeability, and net pay were established for Lower Paleozoic sedimentary aquifers. Lateral hydraulic continuity is dominant at the regional scale, whereas vertical discontinuities are apparent for most physical and chemical properties. The Covey Hill sandstone appears as the most suitable saline aquifer for CO₂ injection/storage. This unit is found at a depth of more than 1 km and has the following properties: fluid pressures exceed 14 MPa, temperature is above 35 °C, salinity is about 108,500 mg/l, matrix permeability is in the order of 3 × 10^?16 m² (0.3 mDarcy) with expected higher values of formation-scale permeability due to the presence of natural fractures, mean porosity is 6 %, net pay reaches 282 m, available pore volume per surface area is 17 m³/m², rock compressibility is 2 × 10^?9 Pa^?1 and capillary displacement pressure of brine by CO₂ is about 0.4 MPa. While the containment for CO₂ storage in the Bécancour saline aquifers can be ensured by appropriate reservoir characteristics, the injectivity of CO₂ and the storage capacity could be limiting factors due to the overall low permeability of aquifers. This characterization offers a solid basis for the subsequent development of a numerical hydrogeological model, which will be used for CO₂ injection capacity estimation, CO₂ injection scenarios and risk assessment.     

What local people? Examining the Gállok mining conflict and the rights of the Sámi population in terms of justice and power

The global extraction of minerals is commonly located in areas populated by indigenous people; and while conflicts between multinational corporations and local activists and indigenous people are widespread today, the understanding of their dynamics are lacking. The Swedish government’s encouragement to an expanding mining industry has caused resistance due to environmental and social implications, particularly its effect on Sámi reindeer husbandry. The resistance to a mine in Gállok is based on the belief that the right to decide about land use historically falls on the Sámi people, and the right to affect land use is detrimental for the survival of Sámi culture and reindeer husbandry. Although the conflict may be perceived as concerning access to natural resources, we argue that the perceived environmental conflict can be viewed as part of a larger struggle over social status and recognition. Data have been collected using qualitative methods such as observations, interviews and documents. The subsequent analysis relies on a meta-theoretical framework of justice as recognition using a typology of relations of power. Our findings suggest that relations of power constitute different categories of social actors. Stakeholders like the Sámi population are subordinated to more dominant stakeholders such as the government, the company and media, who have ‘more’ power or ‘different’ kinds of power ‘over’ others. Through these asymmetric power relations, historical state-Sámi relations are continuously reproduced within prevailing institutions, and also in this mining conflict. Interviewees from business and the municipality testified to the discourses driven by a neoliberal and profit-focused worldview. Challenging the neoliberal discourse, other stakeholders, namely civil society and Sámi, expressed an alternative discourse based on a local, traditional, cultural, environmental and anti-neoliberal worldview.     

NIMBY or how do the rural neighbours respond to genetically modified (GM) crops? An exploration of the structure of reactions by inhabitants in rural communities in The Netherlands to the commercial cultivation of GM crops in their community

The debate on genetic modification (GM) is persistent, polarized and mainly involves organized groups at the national level. With the European Union’s new policy of coexistence, commercial cultivation of GM crops is expected by the Dutch Ministry of Agriculture, Nature and Food Quality within the next few years, especially maize (BT) and potato (Phytophthera resistance and starch production). This makes the debate relevant for those directly confronted with this cultivation: the inhabitants of local rural communities. In The Netherlands, stakeholders formulated coexistence rules to prevent problems between conventional, organic and GM farmers that grow their crops in the same limited land area. Little is known, however, regarding the perceptions of the non-farming inhabitants of rural communities (“the neighbours”) in the debate. This paper presents the results of a focus group-based argumentative analysis of whether (and how) the GM issues play a decisive role among non-farming inhabitants of four rural communities in the Netherlands. We analysed the arguments in relation to a conceptual model that describes the potential rise and dynamics from a pre-Nimby ambivalence towards an outspoken Nimby position. We observed that the GM debate was given very little priority relative to other national issues on the political agenda and that more social cohesion correlates with fewer arguments in the national debate. It is argued that this mechanism keeps the Nimby ambivalence in an undetermined mode, which in turn diminishes the chances of radical rural-based protest against local GM cultivation of crops.     

Trace elements and their correlations in hand-dug wells in a laterite environment in a semi-arid region: case study of Tikaré, Northern Burkina Faso

In many regions of the world and especially in arid and semi-arid areas, groundwater is the major source of drinking water for most of the rural population. The main reason is probably its accessibility through hand-dug wells. However, the resource is supplied in most of the cases to the population as raw water because groundwater is assumed to be safe. In that situation, the water chemistry and quality is usually not well known. Therefore, a study in Tikaré, northern Burkina Faso (West Africa) was carried out analysing fourteen trace elements to characterise their concentration patterns and correlations. The assessment of the quality and the chemistry of water resources is also done in order to forecast if any danger to the population might exist regarding the trace elements. The samples analysed were from 22 wells, 2 boreholes and 1 surface water location (small dam) in a laterite environment. This dam is recharging water to the underlying aquifer during and short after the rainy season. It was found that the most dominated trace elements are Fe and Mn. In summary, nearly all the studied trace elements were below the recommended limit in the drinking water guidelines of the WHO (Guidelines from Drinking Water Standards, 1984). The main source of the trace elements in groundwater seems to be the bedrock dominated by volcano-sedimentary schist and basalt. At least for the analysed area, with only limited traditional mining activities close to the sampling zone, there is no danger for humans to consume the extracted water regarding the analysed trace elements. Some good relationships were also found between some trace elements and major ions.     

Modern volcanism in the Earth’s northern hemisphere and its relations with the evolution of the North Pangaea modern supercontinent and with the spatial distribution of hotspots on the Earth: The hypothesis of relations between mantle plumes and deep subduction

The paper reports results of the analysis of the spatial distribution of modern (younger than 2 Ma) volcanism in the Earth’s northern hemisphere and relations between this volcanism and the evolution of the North Pangaea modern supercontinent and with the spatial distribution of hotspots of the Earth’s mantle. Products of modern volcanism occur in the Earth’s northern hemisphere in Eurasia, North America, Greenland, in the Atlantic Ocean, Arctic, Africa, and the Pacific Ocean. As anywhere worldwide, volcanism in the northern hemisphere of the Earth occurs as (a) volcanism of mid-oceanic ridges (MOR), (b) subduction-related volcanism in island arcs and active continental margins (IA and ACM), (c) volcanism in continental collision (CC) zones, and (d) within-plate (WP) volcanism, which is related to mantle hotspots, continental rifts, and intercontinental belts. These types of volcanic areas are fairly often neighboring, and then mixed volcanic areas occur with the persistent participation of WP volcanism. Correspondingly, modern volcanism in the Earth’s northern hemisphere is of both oceanic and continental nature. The latter is obviously related to the evolution of the North Pangaea modern supercontinent, because it results from the Meso-Cenozoic evolution of Wegener’s Late Paleozoic Pangaea. North Pangaea in the Cenozoic comprises Eurasia, North and South America, India, and Africa and has, similar to other supercontinents, large sizes and a predominantly continental crust. The geodynamic setting and modern volcanism of North Pangaea are controlled by two differently acting processes: the subduction of lithospheric slabs from the Pacific Ocean, India, and the Arabia, a process leading to the consolidation of North Pangaea, and the spreading of oceanic plates on the side of the Atlantic Ocean, a process that “wedges” the supercontinent, modifies its morphology (compared to that of Wegener’s Pangaea), and results in the intervention of the Atlantic geodynamic regime into the Arctic. The long-lasting (for >200 Ma) preservation of tectonic stability and the supercontinental status of North Pangaea are controlled by subduction processes along its boundaries according to the predominant global compression environment. The long-lasting and stable subduction of lithospheric slabs beneath Eurasia and North America not only facilitated active IA + ACM volcanism but also resulted in the accumulation of cold lithospheric material in the deep mantle of the region. The latter replaced the hot mantle and forced this material toward the margins of the supercontinent; this material then ascended in the form of mantle plumes (which served as sources of WP basite magmas), which are diverging branches of global mantle convection, and ascending flows of subordinate convective systems at the convergent boundaries of plates. Subduction processes (compressional environments) likely suppressed the activity of mantle plumes, which acted in the northern polar region of the Earth (including the Siberian trap magmatism) starting at the latest Triassic until nowadays and periodically ascended to the Earth’s surface and gave rise to WP volcanism. Starting at the breakup time of Wegener’s Pangaea, which began with the opening of the central Atlantic and systematically propagated toward the Arctic, marine basins were formed in the place of the Arctic Ocean. However, the development of the oceanic crust (Eurasian basin) took place in the latter as late as the Cenozoic. Before the appearance of the Gakkel Ridge and, perhaps, also the oceanic portion of the Amerasian basin, this young ocean is thought to have been a typical basin developing in the central part of supercontinents. Wegener’s Pangaea broke up under the effect of mantle plumes that developed during their systematic propagation to the north and south of the Central Atlantic toward the North Pole. These mantle plumes were formed in relation with the development of global and local mantle convection systems, when hot deep mantle material was forced upward by cold subducted slabs, which descended down to the core-mantle boundary. The plume (WP) magmatism of Eurasia and North America was associated with surface collision- or subduction-related magmatism and, in the Atlantic and Arctic, also with surface spreading-related magmatism (tholeiite basalts).     

Calcium and magnesium isotope systematics in rivers draining the Himalaya-Tibetan-Plateau region: Lithological or fractionation control?

In rivers draining the Himalaya-Tibetan-Plateau region, the ²⁶Mg/²⁴Mg ratio has a range of 2‰ and the ⁴⁴Ca/⁴²Ca ratio has a range of 0.6‰. The average δ²⁶Mg values of tributaries from each of the main lithotectonic units (Tethyan Sedimentary Series (TSS), High Himalayan Crystalline Series (HHCS) and Lesser Himalayan Series (LHS)) are within 2 standard deviation analytical uncertainty (0.14‰). The consistency of average riverine δ²⁶Mg values is in contrast to the main rock types (limestone, dolostone and silicate) which range in their average δ²⁶Mg values by more than 2‰. Tributaries draining the dolostones of the LHS differ in their values compared to tributaries from the TSS and HHCS. The chemistry of these river waters is strongly influenced by dolostone (solute Mg/Ca close to unity) and both δ²⁶Mg (−1.31‰) and (0.64‰) values are within analytical uncertainty of the LHS dolostone. These are the most elevated values in rivers and rock reported so far demonstrating that both riverine and bedrock values may show greater variability than previously thought.Although rivers draining TSS limestone have the lowest values at −1.41 and 0.42‰, respectively, both are offset to higher values compared to bedrock TSS limestone. The average δ²⁶Mg value of rivers draining mainly silicate rock of the HHCS is −1.25‰, lower by 0.63‰ than the average silicate rock. These differences are consistent with a fractionation of δ²⁶Mg values during silicate weathering. Given that the proportion of Mg exported from the Himalaya as solute Mg is small, the difference in ²⁶Mg/²⁴Mg ratios between silicate rock and solute Mg reflects the ²⁶Mg/²⁴Mg isotopic fractionation factor () between silicate and dissolved Mg during incongruent silicate weathering. The value of of 0.99937 implies that in the TSS, solute Mg is primarily derived from silicate weathering, whereas the source of Ca is overwhelmingly derived from carbonate weathering. The average value in HHCS rivers is within uncertainty of silicate rock at 0.39‰. The widespread hot springs of the High Himalaya have an average δ²⁶Mg value of −0.46‰ and an average value of 0.5‰, distinct from riverine values for δ²⁶Mg but similar to riverine values. Although rivers draining each major rock type have and δ²⁶Mg values in part inherited from bedrock, there is no correlation with proxies for carbonate or silicate lithology such as Na/Ca ratios, suggesting that Ca and Mg are in part recycled. However, in spite of the vast contrast in vegetation density between the arid Tibetan Plateau and the tropical Lesser Himalaya, the isotopic fractionation factor for Ca and Mg between solute and rocks are not systematically different suggesting that vegetation may only recycle a small amount of Ca and Mg in these catchments.The discrepancy between solute and solid Ca and Mg isotope ratios in these rivers from diverse weathering environments highlight our lack of understanding concerning the origin and subsequent path of Ca and Mg, bound as minerals in rock, and released as cations in rivers. The fractionation of Ca and Mg isotope ratios may prove useful for tracing mechanisms of chemical alteration. Ca isotope ratios of solute riverine Ca show a greater variability than previously acknowledged. The variability of Ca isotope ratios in modern rivers will need to be better quantified and accounted for in future models of global Ca cycling, if past variations in oceanic Ca isotope ratios are to be of use in constraining the past carbon cycle.     

Necessary restructuring or globalization failure? Shifts in regional supplier relations after the merger of the former German Hoechst and French Rhône-Poulenc groups

A large part of the work in economic geography and other social sciences surrounding globalization processes has focused on the prospects of economic growth due to the establishment of global production chains and the rise of new clusters of industrial activity. In recent years, much less attention has been paid to former growth industries and regions that have suffered from the negative consequences of internationalization processes. This paper will explore the cases of two chemical regions, i.e. southern Hessen, Germany and Rhône-Alpes, France. Both regions were forced to undergo drastic restructuring since the mid 1990s due to the merger of the chemical groups Hoechst and Rhône-Poulenc into Aventis. The paper argues that it is beneficial to develop a relational perspective of economic action and interaction in order to better understand these regional transformations and restructuring processes and their consequences. Instead of investigating the development of activities, which became the core operations at Aventis, we will focus on other activities that were considered less important and, consequently, split off. In analyzing the logic of restructuring and the associated changes in regional supplier relations, this paper aims to contribute to a relational understanding of economic globalization and its associated threats to regional development by focusing on agents who are subject to negative restructuring consequences.     

Sr,Nd and Pb isotopic and geochemical constraints for the origin of magmas in Popocatépetl volcano (central Mexico) and their relationship with the adjacent volcanic fields

We present new geochemical data (major- and trace-elements, as well as Sr and Nd isotopic compositions) of volcanic rocks erupted from Popocatépetl volcano during the volcanic event from December 2000 to January 2001. These data along with an exhaustive compilation of geochemical and Sr, Nd, and Pb isotope data reported for Popocatépetl rocks and nearby volcanic areas are used to examine the origin and geochemical evolution of the magmas in the central Mexican volcanic belt (CMVB). During this period of volcanic eruptions Popocatépetl produced ash columns as high as 7 km. Pyroclastic flows and lahars were observed after the completion of the activity. Samples of banded pumice and a bomb fragment transported by the lahar were chemically analysed for this work. Rocks show an andesitic composition with 58.5–61.7 wt.% SiO₂ and 5.9–4.0 wt.% MgO. Contents of large ion lithophile elements (LILE), rare-earth elements (REE) and Zr are nearly constant through the compositional range. No significant Eu anomaly is present, but the samples show Nb-anomaly relative to LILE and high-field strength elements (HFSE). Nd- and Sr-isotopic compositions of these samples range from ¹⁴³Nd/¹⁴⁴Nd = 0.51291 to 0.51287 and ⁸⁷Sr/⁸⁶Sr = 0.70399 to 0.70422. Comparison of Popocatépetl products with volcanic rocks from the nearby areas shows that the magmas in CMVB were generated in a heterogeneously veined-mantle source enriched in LILE, HFSE, and REE. Additional crustal assimilation as well as fractional crystallization could account for the great chemical variability of rocks in the CMVB. Statistical comparison of the geochemical compositions of the volcanic products ejected from 1994 to 2000 to those ejected during the 2001 event shows that most geochemical parameters (major- and trace-elements, normative minerals, Sr and Nd isotopic composition, as well some elemental ratios) present no statistically significant differences. Statistically significant differences in the mean only were computed for the major-elements SiO₂, FeO, MgO, CaO, and K₂O, as well as for the rare-earth elements Nd, Sm, Eu, Gd, Dy, Ho, Tm, and Yb.     

Selenium enrichment in Carboniferous Shales,Britain and Ireland: Problem or opportunity for shale gas extraction?

The Carboniferous Bowland Shale in England, and its correlatives in Ireland, contain anomalously high concentrations of trace elements, including selenium (Se), molybdenum (Mo) and arsenic (As). High levels of these elements reflect high sulphur contents as these elements occur as trace constituents of pyrite. Anomalous Se in particular may have a volcanic provenance, from contemporary volcanic activity and/or drainage from Ordovician volcanogenic sulphide deposits. Following concern over the release of Se and As into groundwater during shale gas extraction in the US, the potential fate of Se and As during any future shale gas extraction from the Bowland Shale merits attention. It is at least an environmental issue that must be managed, but at best it could be an opportunity for extraction of Se in an environmentally sensitive manner.