阳澄湖近代沉积物的古湖泊学研究

对阳澄湖两上短柱状样进行了地上代以及各种环境指标分析。结果表明,湖底沉积物由被长期沉积间断所分割的３个岩性层组成：下部层Ｃ属再沉积的更新世晚硬土层;中部层Ｂ为全新世沉积;上部层Ａ为近１００年以来的表层沉积。对层Ａ的详细分析显示,本世纪以来,特别是７０－８０年代以来,金属元素,营养元素和色素的沉积通量明显提高,说明湖泊重金属污染和富营养化程度的不断加重。     

底泥释磷及其对杭州西湖富营养化的影响

杭州西湖是一个小型浅水湖泊,底泥由上部藻骸腐泥和下部泥炭层构成,其显著特点是有机碳含量特别高,氮含量也相当高,而磷的富集程度相对较低。通过实验室和现场模拟研究,考察了pH值、温度、溶解氧、氧化还原电位及上覆水种类等环境因素对底泥释磷量和释磷速率的影响。上覆水pH值在6.5—7.0范围内底泥释磷量最低;在较高或较低pH值时,释磷量倍增。升高水温或降低上覆水溶解氧浓度均能加速释磷。实验室模拟西湖底泥最大释磷量为0.368μgP/g。夏季现场模拟平均释磷速率为1.02mg P/m~2·d;由此估算底泥释磷量达1.346tP/a,相当于年平均外部入湖磷负荷的36.4％。底泥释磷对西湖富营养化起着不容忽视的影响。     

Impact of an extreme melt event on the runoff and hydrology of a high Arctic glacier

On 28–30 July 2000, an extreme melt event was observed at John Evans Glacier (JEG), Ellesmere Island (79° 40′N, 74° 00′W). Hourly melt rates during this event fell in the upper 4% of the distribution of melt rates observed at the site during the period 1996–2000. Synoptic conditions during the event resulted in strong east‐to‐west flow over the northern sector of the Greenland Ice Sheet, with descending flow on the northwest side reaching Ellesmere Island. On JEG, wind speeds during the event averaged 8·1 m s^?1 at 1183 m a.s.l., with hourly mean wind speeds peaking at 11·6 m s^?1. Air temperatures reached 8°C, and rates of surface lowering measured by an ultrasonic depth gauge averaged 56 mm day^?1. Calculations with an energy balance model suggest that increased turbulent fluxes contributed to melt enhancement at all elevations on the glacier, while snow albedo feedback resulted in increased melting due to net radiation at higher elevations. The event was responsible for 30% of total summer melt at 1183 m a.s.l. and 15% at 850 m a.s.l. Conditions similar to those during the event occurred on only 0·1% of days in the period 1948–2000, but 61% of events occurred in the summer months and there was an apparent clustering of events in the 1950s and 1980s. Such events have the potential to impact significantly on runoff, mass balance and drainage system development at high Arctic glaciers, and changes in their incidence could play a role in determining how high Arctic glaciers respond to climate change and variability. Copyright © 2003 John Wiley & Sons, Ltd.     

Phosphorus in groundwater—an overlooked contributor to eutrophication?

This paper presents the first international assessment of phosphorus concentrations in groundwater, using data from the Republic of Ireland, Northern Ireland, Scotland, England and Wales. Phosphorus is considered to be the main limiting nutrient in most freshwater ecosystems. Controlling phosphorus inputs is thus considered the key to reducing eutrophication and managing ecological quality. Very little attention has been paid to evaluating transfers via groundwater due to the long‐held belief that adsorption and metal complex formation retain the majority of potentially mobile phosphorus. In each country, ecologically‐important phosphorus thresholds are exceeded in a significant number of groundwater samples. The relative contributions of potential sources for these elevated concentrations are currently unclear but there is evidence to suggest that they are at least partly anthropogenic. The results suggest that groundwater P concentrations are such that they may be a more important contributor to surface water phosphorus than previously thought. Copyright © 2008 John Wiley & Sons, Ltd.     

The impact of agricultural land use on stream chemistry and inputs to an inland reservoir: case of the Sauce Grande River,Argentina

Abstract

Water quality in the Paso Piedras Reservoir has deteriorated, primarily due to periodic blue-green algal blooms, making it temporarily unfit for human consumption. This phenomenon results from the eutrophication of waters of the watershed, and nutrients are considered to be the primary contributors to degradation of freshwater quality. In order to reduce the levels of nitrogen and, most of all, phosphorus, entering the Paso Piedras Reservoir, it is necessary to understand the incidence of diffuse transfers of nutrients from agricultural soils. The nitrogen composition, soluble reactive phosphorus (SRP) and other physico-chemical parameters of the water were analysed in various different parts of the watershed in order to characterize water input to the reservoir from areas with different anthropogenic activity. The upper Sauce Grande basin was divided into three areas with different edaphic characteristics. The physico-chemical parameters measured in sampling surveys included: SRP, ammonium and nitrate, pH, conductivity, turbidity, and total solids. The results showed that the water of the Sauce Grande (areas 1 and 2) was not strongly contaminated, but in El Divisorio (Area 3, which is a sub-watershed whose stream flows directly into the Paso Piedras Reservoir), the levels of conductivity, total suspended sediments and SRP were so high that its contribution to the reservoir accounts for nearly 50% of the total SRP input. The main characteristics of El Divisorio watershed that make it a diffuse source of SRP were not only that its soils, under agricultural-livestock production, have significant slopes, so that water and wind erosion are faster, but also that human intervention had caused the destruction of aggregates. The results showed the influence of the soil characteristics, production systems and the micro-environment developed in the reservoir on the characteristics of waters flowing out of the reservoir. The two villages located in Area 2 had no significant influence on the concentration of nitrogen compounds and SRP found downstream.     

Biogeochemical responses over 37 years to manipulation of phosphorus concentrations in an Arctic river: The Upper Kuparuk River Experiment

The climate of the Arctic region is changing rapidly, with important implications for permafrost, vegetation communities, and transport of solutes by streams and rivers to the Arctic Ocean. While research on Arctic streams and rivers has accelerated in recent years, long-term records are relatively rare compared to temperate and tropical regions. We began monitoring the upper Kuparuk River in 1983 as part of a long-term, low-level, whole-season phosphorus enrichment of a 4–6 km experimental reach, which was subsequently incorporated into the Arctic Long-Term Ecological Research (Arctic LTER) programme. The phosphorus enrichment phase of the Upper Kuparuk River Experiment (UKRE) ran continuously for 34 seasons, fundamentally altering the community structure and function of the Fertilized reach. The objectives of this paper are to (a) update observations of the environmental conditions in the Kuparuk River region as revealed by long-term, catchment-level monitoring, (b) compare long-term trends in biogeochemical characteristics of phosphorus-enriched and reference reaches of the Kuparuk River, and (c) report results from a new ‘ReFertilization’ experiment. During the UKRE, temperature and discharge did not change significantly, though precipitation increased slightly. However, the UKRE revealed unexpected community state changes attributable to phosphorus enrichment (e.g., appearance of colonizing bryophytes) and long-term legacy effects of these state changes after cessation of the phosphorus enrichment. The UKRE also revealed important biogeochemical trends (e.g., increased nitrate flux and benthic C:N, decreased DOP flux). The decrease in DOP is particularly notable in that this may be a pan-Arctic trend related to permafrost thaw and exposure to new sources of iron that reduce phosphorus mobility to streams and rivers. The trends revealed by the UKRE would have been difficult or impossible to identify without long-term, catchment level research and may have important influences on connections between Arctic headwater catchments and downstream receiving waters, including the Arctic Ocean.     

Tracking hydrological responses of a thermokarst lake in the Old Crow Flats (Yukon Territory,Canada) to recent climate variability using aerial photographs and paleolimnological methods

Recent studies using remote sensing analysis of lake‐rich thermokarst landscapes have documented evidence of declining lake surface area in response to recent warming. However, images alone cannot identify whether these declines are due to increasing frequency of lake drainage events associated with accelerated thermokarst activity or to increasing evaporation in response to longer ice‐free season duration. Here, we explore the potential of combining aerial photograph time series with paleolimnological analyses to track changes in hydrological conditions of a thermokarst lake in the Old Crow Flats (OCF), Canada, and to identify their causes. Images show that the water level in lake OCF 48 declined markedly sometime between 1972 and 2001. In a sediment core from OCF 48, complacent stratigraphic profiles of several physical, geochemical, and biological parameters from ～1874–1967 indicate hydro‐limnological conditions were relatively stable. From ～1967–1989, declines in organic matter content, organic carbon isotope values, and pigment concentrations are interpreted to reflect an increase in supply of minerogenic sediment, and subsequent decline in aquatic productivity, caused by increased thermo‐erosion of shoreline soils. Lake expansion was likely caused by increased summer rainfall, as recorded by increased cellulose‐inferred lake‐water oxygen isotope compositions. Stratigraphic trends defining the lake expansion phase terminated at ～1989, which likely marks the year when the lake drained. Above‐average precipitation during the previous year probably raised the lake level and promoted further thermo‐erosion of the shoreline soils that caused the lake to drain. These are meteorological conditions that have led to other recent lake‐drainage events in the OCF. Thus, the decline in lake level, evident in the aerial photograph from 2001, is unlikely to have been caused by evaporation, but rather is a remnant of a drainage event that took place more than a decade earlier. After drainage, the lake began to refill, and most paleolimnological parameters approach levels that are similar to those during the stable phase. These findings indicate that combined use of aerial images and paleolimnological methods offers much promise for identifying the hydrological consequences of recent climatic variations on thermokarst lakes. Copyright © 2011 John Wiley & Sons, Ltd.     

Early spring turbulent mixing in an ice-covered Arctic fjord during transition to melting

Observations are presented of currents, hydrography and turbulence in a jet-type tidally forced fjord in Svalbard. The fjord was ice covered at the time of the experiment in early spring 2004. Turbulence measurements were conducted by both moored instruments within the uppermost 5 m below the ice and a microstructure profiler covering 3–60 m at 75 m depth. Tidal choking at the mouth of the fjord induces a tidal jet advecting relatively warmer water past the measurement site and dominating the variability in hydrography. While there was no strong correlation with the observed hydrography or mixing and the phase of the semidiurnal tidal cycle, the mean structure in dissipation of turbulent kinetic energy, work done under the ice and the mixing in the water column correlated with the current when conditionally sampled for tidal jet events. Observed levels of dissipation of turbulent kinetic energy per unit mass, 1.1×10⁻⁷ W kg⁻¹, and eddy diffusivity, 7.3×10⁻⁴ m² s⁻¹, were comparable to direct measurements at other coastal sites and shelves with rough topography and strong forcing. During spring tides, an average upward heat flux of 5 W m⁻² in the under-ice boundary layer was observed. Instantaneous (1 h averaged) large heat flux events were correlated with periods of large inflow, hence elevated heat fluxes were associated with the tidal jet and its heat content. Vertical heat fluxes are derived from shear-probe measurements by employing a novel model for eddy diffusivity [Shih et al., 2005. Parameterization of turbulent fluxes and scales using homogeneous sheared stably stratified turbulence simulations. Journal of Fluid Mechanics 525, 193–214]. When compared to the direct heat flux measurements using the eddy correlation method at 5 m below the ice, the upper 4–6 m averaged heat flux estimates from the microstructure profiler agreed with the direct measurements to within 10%. During the experiment water column was stably, but weakly, stratified. Destabilizing buoyancy fluxes recorded close to the ice were absent at 5 m below the ice, and overall, turbulence production was dominated by shear. A scaling for dissipation employing production by both stress and buoyancy [Lombardo and Gregg, 1989. Similarity scaling of viscous and thermal dissipation in a convecting boundary layer. Journal of Geophysical Research 94, 6273–6284] was found to be appropriate for the under-ice boundary layer.     

Hydrological and sediment yield response to summer rainfall in a small high Arctic watershed

In cold regions, the response and related antecedent mechanisms that produce flood flows from rainfall events have received limited study. In 2007, a small watershed at Cape Bounty, Melville Island, Nunavut, was studied in detail during the melt season. Two rainfall events on June 30 and July 22, totalling 9·2 and 10·8 mm, respectively, represented significant contributions to seasonal discharge and sediment transport in a year with a low winter snowpack. The precipitation events elevated discharge and suspended sediment concentrations to twice the magnitude of the nival melt, and generated the only measurable downstream lacustrine turbidity current of the season. In two days, rainfall runoff transported 35% of the seasonal suspended sediment load, in contrast to 29% transported over the nival freshet. The magnitude and intensity of the rain events were not unusual in this setting, but the rainfall response was substantial in comparison with equivalent past events. Exceptional temperatures of July 2007 generated early, deep permafrost thaw, and ground ice melt. The resultant increase in soil moisture amplified the subsequent rainfall runoff and sediment transport response. These results demonstrate the importance of antecedent moisture conditions and the role of permafrost active layer development as an important factor in the rainfall runoff and sediment transport response to precipitation events. Copyright © 2009 John Wiley & Sons, Ltd.     

Bioassessment Techniques for Monitoring of Eutrophication and Nutrient Limitation in Coastal Ecosystems

Bioassesment by the use of the macroalga, Ulva lactuca L., was carried out in the Limfjord, Denmark, to assess the significance of nitrogen and phosphorus as limiting factors for primary production during 1985, 1993, 1994 and 1995 and for the detection of changes in eutrophication levels.

Minimum and critical tissue concentrations for nitrogen and phosphorus in macroalgae were identified. The concentrations of nitrogen were generally below the critical concentration level in June–October in 1985, 1993, and 1995 but in 1994 nitrogen was only limiting for primary production in short periods. Only in early spring in 1985 and 1993 were the tissue concentrations of phosphorus below the critical concentration level, whereas in 1994 up to 3–4 months showed phosphorus limited growth, indicating that significant changes in limitation patterns can occur between different years.

It was concluded that the use of biomonitoring techniques is well suited as a bioassessment method for direct detection and for providing a time-integrated measure of nutrient availability in coastal waters, and thus for assessing ecosystem health with regard to eutrophication. It is recommended that biomonitors and the concept of critical tissue concentrations should be used in environmental management and incorporated in future monitoring programmes.     

Groundwater – the disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients

Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer‐lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater‐borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N₂ in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer‐lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater‐borne P loads vary from 0.74 to 2900 mg PO₄‐P m^?2 year^?1; for N, these loads vary from 0.001 to 640 g m^?2 year^?1. Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management. Copyright © 2014 John Wiley & Sons, Ltd.     

Contributions of phosphatase and microbial activity to internal phosphorus loading and their relation to lake eutrophication

Phosphatase may accelerate the process of lake eutrophication through improving phosphorus bioavailability. This mechanism was studied in three Chinese eutrophic shallow lakes (Lake Taihu, Lake Longyang and Lake Lianhua). Phosphatase activity was related to the concentration of soluble reactive phosphorus (SRP) and chlorophyll a. Stability of dissolved phosphatase in reverse micelles may be attributed to molecular size, conformation and active residues of the enzyme. At the site with Microcystis bloomed in Lake Taihu, dissolved phosphatase activity was higher and more stable in micelles, SRP concentrations were lower in interstitial water, the contents of different forms of phosphorus and the amounts of aerobic bacteria were lower while respiration efficiency was higher in sediments. Phosphobacteria, both inorganic and organic and other microorganisms were abundant in surface water but rare in sediments. Therefore, internal phosphorus may substantially flux into water column by enzymatic hydrolysis and anaerobic release, together with mobility of bacteria, thereby initiating the bloom. In short, biological mechanism may act in concert with physical and chemical factors to drive the internal phosphorus release and accelerate lake eutrophication.     

Analysis of trends in annual streamflow to the Arctic Ocean

There is increasing interest in the magnitude of the flow of freshwater to the Arctic Ocean due to its impacts on the biogeophysical and socio‐economic systems in the north and its influence on global climate. This study examines freshwater flow based on a dataset of 72 rivers that either directly or indirectly contribute flow to the Arctic Ocean or reflect the hydrologic regime of areas contributing flow to the Arctic Ocean. Annual streamflow for the 72 rivers is categorized as to the nature and location of the contribution to the Arctic Ocean, and composite series of annual flows are determined for each category for the period 1975 to 2015. A trend analysis is then conducted for the annual discharge series assembled for each category. The results reveal a general increase in freshwater flow to the Arctic Ocean with this increase being more prominent from the Eurasian rivers than from the North American rivers. A comparison with trends obtained from an earlier study ending in 2000 indicates similar trend response from the Eurasian rivers, but dramatic differences from some of the North American rivers. A total annual discharge increase of 8.7 km³/y/y is found, with an annual discharge increase of 5.8 km³/y/y observed for the rivers directly flowing to the Arctic Ocean. The influence of annual or seasonal climate oscillation indices on annual discharge series is also assessed. Several river categories are found to have significant correlations with the Arctic Oscillation, the North Atlantic Oscillation, or the Pacific Decadal Oscillation. However, no significant association with climate indices is found for the river categories leading to the largest freshwater contribution to the Arctic Ocean.     

基于ELCOM-CAEDYM模型的淀山湖营养物投入响应关系的模拟

针对淀山湖严重富营养化的问题,应用三维水动力-水质耦合模型ELCOM-CAEDYM对淀山湖水质进行了模拟,确定了一套可应用于淀山湖水质模拟的参数,并对模拟结果进行了验证;验证结果显示,ELCOM-CAEDYM耦合模型较好地模拟了常规水质和藻类浓度动态变化,模拟结果的总体变化趋势与实测结果相符合.同时运用该模型对淀山湖营...     

Excess of bottom-released methane in an Arctic shelf sea polynya in winter

Latent heat polynyas are regions generating strong ice formation, convection and extensive water mass formation. Here we report on the effects of these processes on resuspension of sediments and subsequent methane release from the seafloor and on the resulting excess methane concentration in surface water on a polar shelf during winter. The study is based on measurements of concentration and δ¹³C values of methane, water temperature, salinity, light transmission and sea ice data collected in March 2003 in Storfjorden, southern Svalbard. In winter, strong and persistent northeasterly winds create polynyas in eastern Storfjorden and cause ice formation. The resulting brine-enriched water cascades from the Storfjordbanken into the central depression thereby enhancing the turbulence near the seafloor. A distinct benthic nepheloid layer was observed reflecting the resuspension of sediments by the cascading dense bottom water. High concentrations of ¹³C-depleted methane suggest submarine discharge of methane with the resuspended sediments. As the source of the submarine methane, we propose recent bacterial methanogenesis near the sediment surface because of extremely high accumulation rates of organic carbon in Storfjorden. Convective mixing transports newly released methane from the bottom to the sea surface. This eventually results in an excess concentration in surface water with respect to the atmospheric equilibrium, and a sea-air flux of methane during periods of open water. When a new ice cover is formed, methane becomes trapped in the water column and subsequently oxidized. Thus, the residual methane is strongly enriched in ¹³C in relation to the δ¹³_CCH4${\delta }^{13}{\mathrm{C}}_{{\mathrm{CH}}_4}$ signature of atmospheric methane. Our results show that latent heat polynyas may induce a direct pathway for biogases like methane from sediments to the atmosphere through coupling of biogeochemical and oceanographic processes. Extrapolating these processes to all Arctic ocean polynyas, we estimate a transfer of CH₄ between 0.005 and 0.02 Tg yr⁻¹. This is not a large contribution but the fluxes from the polynyas are 20–200 times larger than the ocean average and the methane evasion process in polynyas is certainly one that can be altered under climate change.     

富营养化湖泊围隔中重建水生植被及其生态效应

水体富营养化导致水生植被衰退、蓝藻水华暴发、水质恶化和水生生态系统崩溃.恢复水生植被被认为是改善受损水体水质和提高其生态系统稳定性的重要手段.本研究通过构建大型围隔,根据水生植物的耐污程度及其对水质和底质等条件的需求,选取几种适宜的水生植物在围隔内进行移栽与群落构建,并以不移栽水生植物的围隔和围隔外水体作为对照.实验期间(2011年4月至2012年6月),围隔内移栽的几种水生植物全部存活,并建立了相对稳定的群落.同时还跟踪监测了3个处理组的水质情况,结果显示,移栽水生植物的围隔内水质明显优于围隔外,与未移栽水生植物围隔相比,也有很大程度的改善,其中移栽水生植物围隔内水体的总氮、铵态氮、总磷、水下消光系数相比于围隔外水体分别低30.55%、44.09%、36.04%和42.13%,相比于未移栽水生植物围隔内水体分别低5.96%、13.40%、6.70%和7.60%,透明度分别比围隔外水体和未移栽水生植物围隔水体高74.59%和8.70%,浮游植物生物量也大大低于围隔外,而浮游动物生物量却明显高于后者.此外,实验后移栽水生植物围隔内沉积物氮、磷含量及其间隙水总氮、总磷、铵态氮浓度明显低于围隔外和未移栽水生植物围隔.研究表明,在富营养化浅水湖泊中通过建立围隔进行合理的群落配置,进而逐步恢复水生植物是完全可行的,而水生植物恢复后加强对其管理和维护至关重要.     

A distributed analysis of lateral inflows in an Alaskan Arctic watershed underlain by continuous permafrost

Lateral inflows control the spatial distribution of river discharge, and understanding their patterns is fundamental for accurately modelling instream flows and travel time distributions necessary for evaluating impacts of climate change on aquatic habitat suitability, river energy budgets, and fate of dissolved organic carbon. Yet, little is known about the spatial distribution of lateral inflows in Arctic rivers given the lack of gauging stations. With a network of stream gauging and meteorological stations within the Kuparuk River watershed in northern Alaska, we estimated precipitation and lateral inflows for nine subcatchments from 1 July to 4 August,2013, 2014, and 2015. Total precipitation, lateral inflows, runoff ratios (area-normalized lateral inflow divided by precipitation), percent contribution to total basin discharge, and lateral inflow per river kilometre were estimated for each watershed for relatively dry, moderate, or wet summers. The results show substantial variability between years and subcatchments. Total basin lateral inflow depths ranged 24-fold in response to a threefold change in rainfall between dry and wet years, whereas within-basin lateral inflows varied fivefold from the coastal plain to the foothills. General spatial trends in lateral inflows were consistent with previous studies and mean summer precipitation patterns. However, the spatially distributed nature of these estimates revealed that reaches in the vicinity of a spring-fed surficial ice feature do not follow general spatial trends and that the coastal plain, which is typically considered to produce minimal runoff, showed potential to contribute to total river discharge. These findings are used to provide a spatially distributed understanding of lateral inflows and identify watershed characteristics that influence hydrologic responses.