New upper limits for hydrogen halides on Saturn derived from Cassini-CIRS data

Far infrared spectra (10-600 cm⁻¹) from Cassini's Composite InfraRed Spectrometer (CIRS) were used to determine improved upper limits of hydrogen halides HF, HCl, HBr, and HI in Saturn's atmosphere. Three observations, comprising a total of 3088 spectra, gave 3σ upper limits on HF, HCl, HBr, and HI volume mole fractions of 8.0×¹⁰⁻¹², 6.7×¹⁰⁻¹¹, 1.3×¹⁰⁻¹⁰, and 1.4×¹⁰⁻⁹, respectively, at the 500 mbar pressure level. These upper limits confirm sub-solar abundances of halide species for HF, HCl, and HBr in Saturn's upper atmosphere—consistent with predictions from thermochemical models and influx of material from meteoroids. Our upper limit for HCl is 16 times lower than the tentative detection at 1.1×¹⁰⁻⁹ reported by Weisstein and Serabyn [Weisstein, E.W., Serabyn, E., 1996. Icarus 123, 23-36]. These observations are not sensitive to the deep halide abundance, which is expected to be enriched relative to the solar composition.     

Solar radiation scattered in the Venus atmosphere: The Venera 11,12 data

Results of the scattered solar radiation spectrum measurements made deep in the Venus atmosphere by the Venera 11 and 12 descent probes are presented. The instrument had two channels: spectrometric (to measure downward radiation in the range 0.45 < γ < 1.17 μm) and photometric (four filters and circular angle scanning in an almost vertical plane). Spectra and angular scans were made in the height range from 63 km above the planet surface. The integral flux of solar radiation is 90 ± 12 W m^?2 measured on the surface at the subsolar point. The mean value of surface absorbed radiation flux per planetary unit area is 17.5 ± 2.3 W m^?2. For Venera 11 and 12 landing sites the atmospheric absorbed radiation flux is ～15 W m^?2 for H >; 43 km and ～45 W m^?2 for H < 48 km in the range 0.45 to 1.55 μm. At the landing sites of the two probes the investigated portion of the cloud layer has almost the same structure: it consists of three parts with boundaries between them at about 51 and 57 km. The base of clouds is near 48 km above the surface. The optical depth of the cloud layer (below 63 km) in the range 0.5 to 1 μm does not depend on the wavelength and is ～29 and ～38 for the Venera 11 and 12 landing sites, respectively. The single-scattering albedo, ω₀, in the clouds is very close to 1 outside the absorption bands. Below 58 km the parameter (1 ? ω₀) is <10^?3 for 0.49 and 0.7 μm. The parameter (1 ? ω₀) obviously increases above 60 km. Below 48 km some aerosol is present. The optical depth here is a strong function of wavelength. It varies from 1.5 to 3 at λ = 0.49 μm and from 0.13 to 0.4 at 1.0 μm. The mean size of particles below the cloud deck is about 0.1 μm. Below 35 km true absorption was found at λ < 0.55 μm with the (1 ? ω₀) maximum at H ≈ 15 km. The wavelength and height dependence of the absorption coefficient are compatible with the assumption that sulfur with a mixing ratio ～2 × 10^?8 normalized to S₂ molecules is the absorber. The upper limits of the mixing ratio for Cl₂, Br₂, and NO₂ are 4 × 10^?8, 2 × 10^?11, and 4 × 10^?10, respectively. The CO₂ and H₂O bands are confidently identified in the observed spectra. The mean value of the H₂O mixing ratio is 3 × 10^?5 < F_H2O < 10^?4 in the undercloud atmosphere. The H₂O mixing ratio evidently varies with height. The most probable profile is characterized by a gradual increase from F_H2O = 2 × 10^?5 near the surface to a 10 to 20 times higher value in the clouds.     

Flowing afterglow studies of temperature dependencies for electron dissociative recombination of HCNH, CH3CNH and CH3CH2CNH and their symmetrical proton-bound dimers

A study has been made using a variable temperature flowing afterglow Langmuir probe technique (VT-FALP) to determine the equilibrium temperature dependencies of the dissociative electron-ion recombination of the protonated cyanide ions (RCNH⁺, where R=H, CH₃ and C₂H₅) and their symmetrical proton-bound dimers (RCNH⁺NCR). The power law temperature dependencies of the recombination coefficients, α_e, over the temperature range 180 to 600 K for the protonated ions are α_e(T)(cm³ s⁻¹)=3.5±0.5×10⁻⁷ (300/T)^1.38 for HCNH⁺, α_e(T)=3.4±0.5×10⁻⁷ (300/T)^1.03 for CH₃CNH⁺, and α_e(T)=4.6±0.7×10⁻⁷ (300/T)^0.81 for CH₃CH₂CNH⁺. The equivalent values for the proton-bound dimers are α_e(T)(cm³ s⁻¹)=2.4±0.4×10⁻⁶(300/T)^0.5 for (HCN)₂H⁺ to α_e(T)=2.8±0.4×10⁻⁶(300/T)^0.5 for (CH₃CN)₂H⁺, and α_e(T)=2.3±0.3×10⁻⁶(300/T)^0.5 for (CH₃CH₂CN)₂H⁺. The relevance of these data to molecular synthesis in the interstellar medium and the Titan ionosphere are discussed.     

Prebiotic organic synthesis in early Earth and Mars atmospheres: Laboratory experiments with quantitative determination of products formed in a cold plasma flow reactor

The goal of this study was to explore prebiotic chemistry in a range of plausible early Earth and Mars atmospheres. To achieve this laboratory continuous flow plasma irradiation experiments were performed on N₂/H₂/CO/CO₂ gas mixtures chosen to represent mildly reducing early Earth and Mars atmospheres derived from a secondary volcanic outgassing of volatiles in chemical equilibrium with magmas near present day oxidation state. Under mildly reducing conditions (91.79% N₂, 5.89% H₂, 2.21% CO, and 0.11% CO₂), simple nitriles are produced in the gas phase with yield (G in molecules per 100 eV), for the key prebiotic marker molecule HCN at G∼1×¹⁰⁻³ (0.1 nmol J⁻¹). In this atmosphere localized HCN concentrations possibly could approach the 10⁻² M needed for HCN oligomerization. Yields under mildly oxidizing conditions (45.5% N₂, 0.1% H₂, 27.2% CO, 27.2% CO₂) are significantly less as expected, with HCN at G∼3×¹⁰⁻⁵ (). Yields in a Triton atmosphere which can be plausibly extrapolated to represent what might be produced in trace CH₄ conditions (99.9% N₂, 0.1% CH₄) are significant with HCN at G∼1×¹⁰⁻² (1 nmol J⁻¹) and tholins produced. Recently higher methane abundance atmospheres have been examined for their greenhouse warming potential, and higher abundance hydrogen atmospheres have been proposed based on a low early Earth exosphere temperature. A reducing (64.04% N₂, 28.8% H₂, 3.60% CO₂, and 3.56% CH₄), representing a high CH₄ and H₂ abundance early Earth atmosphere had HCN yields of G∼5×¹⁰⁻³ (0.5 nmol J⁻¹). Tholins generated in high methane hydrogen gas mixtures is much less than in a similar mixture without hydrogen. The same mixture with the oxidizing component CO₂ removed (66.43% N₂, 29.88% H₂, 0% CO₂, and 3.69% CH₄) had HCN yields of G∼1×¹⁰⁻³ (0.1 nmol J⁻¹) but more significant tholin yields.     

Collisional vibrational quenching of O2+(v) and other molecular ions in planetary atmospheres

New experimental techniques have yielded several thermal energy vibrational quenching rate constants for O₂⁺(v). Rates for quenching of O₂⁺(v = 1) by O₂, N₂, Ar, CO₂, H₂, and CH₄ are 3(?10), 2(?12), 1(?12), 1(?10), 2.5(?12), and 6(?10) cm³s^?1 at 300 K. The quenching is somewhat faster for O₂⁺(v = 2). The triatomic ions CO₂⁺, NO₂⁺, N₂O⁺, SO₂⁺, and H₂O⁺ are all vibrationally deexcited with an efficiency greater than 10^?3 in Ar or Ne collisions. A theoretical rationalization of the experimental results leads to the prediction that vibrational quenching in planetary atmospheres will generally be efficient, k > 1(?12) cm³s^?1 for almost all ion and neutral gas pairs.     

Upper limits for the ethyl-cyanide abundances in TMC-1 and L134N: Chemical implications

We have sought interstellar ethyl-cyanide via its 2₀₂–1₀₁ transition towards two cold, dark clouds and report upper limits of the total column densities of 3×10¹²cm^–2 and 2×10¹²cm^–2 for TMC-1 and L134N, respectively. We also observed the 2₀₂–1₀₁ transition of vinyl cyanide previously identified in TMC-1 by Matthews and Sears (1983b). The detection of vinyl cyanide and the non-detection of ethyl cyanide in TMC-1 are consistent with gas phase ion-molecule chemical models, and there is thus no necessity of invoking grain surface synthesis for vinyl cyanide in cold clouds.     

Titan’s atmosphere from ISO mid-infrared spectroscopy

We have analyzed Titan observations performed by the Infrared Space Observatory (ISO) in the range 7-30 μm. The spectra obtained by three of the instruments on board the mission (the short wavelength spectrometer, the photometer, and the camera) were combined to provide new and more precise thermal and compositional knowledge of Titan’s stratosphere. With the high spectral resolution achieved by the SWS (much higher than that of the Voyager 1 IRIS spectrometer), we were able to detect and separate the contributions of most of the atmospheric gases present on Titan and to determine disk-averaged mole fractions. We have also tested existing vertical distributions for C₂H₂, HCN, C₂H₆, and CO₂ and inferred some information on the abundance of the first species as a function of altitude. From the CH₃D band at 1161 cm⁻¹ and for a CH₄ mole fraction assumed to be 1.9% in Titan’s stratosphere, we have obtained the monodeuterated methane-averaged abundance and retrieved a D/H isotopic ratio of 8.7−1.9+3.2 × 10⁻⁵. We discuss the implications of this value with respect to current evolutionary scenarios for Titan. The ν₅ band of HC₃N at 663 cm⁻¹ was observed for the first time in a disk-averaged spectrum. We have also obtained a first tentative detection of benzene at 674 cm⁻¹, where the fit of the ISO/SWS spectrum at R = 1980 is significantly improved when a constant mean mole fraction of 4 × 10⁻¹⁰ of C₆H₆ is incorporated into the atmospheric model. This corresponds to a column density of ∼ 2 × 10¹⁵ molecules cm⁻² above the 30-mbar level. We have also tested available vertical profiles for HC₃N and C₆H₆ and adjusted them to fit the data. Finally, we have inferred upper limits of a few 10⁻¹⁰ for a number of molecules proposed as likely candidates on Titan (such as allene, acetonitrile, propionitrile, and other more complex gases).     

Scientific Value of the Laser Ranging of Asteroid Icarus

The space mission of the laser ranging of asteroid Icarus is that a laser reflector and a timer are placed on the No.1566 asteroid and the laser interference ranging is conducted between the asteroid and the ground-based station for making the precise measurements of the PPN parameters γ and β, solar quadrupolar moment J₂, time rate of change ?/G of the gravitational constant and barycentric gravitational constant of the solar system objects. With the development of laser techniques, the timing accuracy of 10 ps (or 3 mm expressed by the amount of ranging) can be realized. In 2015 the asteroid Icarus will be close to the earth, which provides a better launch window for the Icarus lander. In the present article the 2003 interplanetary ephemeris frame of the PMOE is adopted to simulate the laser ranging between the ground-based station and the asteroid for 800 days from 2015 September 25 on and obtain the indeterminacies of 18 parameters, among which those of γ, β, J₂ and ?/G are respectively 7.8 × 10⁻⁸, 9.0 × 10⁻⁷, 9.8 × 10⁻¹¹ and 7.0 × 10−15yr⁻¹, with each being 1 to 3 orders higher than the available experimental accuracy. The simulated result shows that this space mission is of scientific significance to the test of the theory of relativity, determination of the fundamental parameters of solar system and test of the space-time fundamental laws.     

Detection of new hydrocarbons in Uranus' atmosphere by infrared spectroscopy

Ethane (C₂H₆), methylacetylene (CH₃C₂H or C₃H₄) and diacetylene (C₄H₂) have been discovered in Spitzer 10-20 μm spectra of Uranus, with 0.1-mbar volume mixing ratios of (1.0±0.1)×¹⁰⁻⁸, (2.5±0.3)×¹⁰⁻¹⁰, and (1.6±0.2)×¹⁰⁻¹⁰, respectively. These hydrocarbons complement previously detected methane (CH₄) and acetylene (C₂H₂). Carbon dioxide (CO₂) was also detected at the 7-σ level with a 0.1-mbar volume mixing ratio of (4±0.5)×¹⁰⁻¹¹. Although the reactions producing hydrocarbons in the atmospheres of giant planets start from radicals, the methyl radical (CH₃) was not found in the spectra, implying much lower abundances than in the atmospheres of Saturn or Neptune where it has been detected. This finding underlines the fact that Uranus' atmosphere occupies a special position among the giant planets, and our results shed light on the chemical reactions happening in the absence of a substantial internal energy source.     

Europa's atmosphere, gas tori, and magnetospheric implications

A two-dimensional kinetic model calculation for the water group species (H₂O, H₂, O₂, OH, O, H) in Europa's atmosphere is undertaken to determine its basic compositional structure, gas escape rates, and velocity distribution information to initialize neutral cloud model calculations for the most important gas tori. The dominant atmospheric species is O₂ at low altitudes and H₂ at higher altitudes with average day-night column densities of 4.5×¹⁰¹⁴ and 7.7×¹⁰¹³ cm⁻², respectively. H₂ forms the most important gas torus with an escape rate of ∼2×¹⁰²⁷ s⁻¹ followed by O with an escape rate of ∼5×¹⁰²⁶ s⁻¹, created primarily as exothermic O products from O₂ dissociation by magnetospheric electrons. The circumplanetary distributions of H₂ and O are highly peaked about the satellite location and asymmetrically distributed near Europa's orbit about Jupiter, have substantial forward clouds extending radially inward to Io's orbit, and have spatially integrated cloud populations of 4.2×¹⁰³³ molecules for H₂ and 4.0×¹⁰³² atoms for O that are larger than their corresponding populations in Europa's local atmosphere by a factor of ∼200 and ∼1000, respectively. The cloud population for H₂ is a factor of ∼3 times larger than that for the combined cloud population of Io's O and S neutral clouds and provides the dominant neutral population beyond the so-called ramp region at 7.4-7.8 RJ in the plasma torus. The calculated brightness of Europa's O cloud on the sky plane is very dim at the sub-Rayleigh level. The H₂ and O tori provide a new source of europagenic molecular and atomic pickup ions for the thermal plasma and introduce a neutral barrier in which new plasma sinks are created for the cooler iogenic plasma as it is transported radially outward and in which new sinks are created to alter the population and pitch angle distribution of the energetic plasma as it is transported radially inward. The europagenic instantaneous pickup ion rates are peaked at Europa's orbit, dominate the iogenic pickup ion rates beyond the ramp region, and introduce new secondary plasma source peaks in the solution of the plasma transport problem. The H₂ torus is identified as the unknown Europa gas torus that creates both the observed loss of energetic H⁺ ions at Europa's orbit and the corresponding measured ENA production rate for H.     

Recent orbital evolution and the internal structures of Enceladus and Dione

We study the orbital behavior of Saturn’s satellites Enceladus and Dione during their passage through the 2:1 mean-motion resonances to constrain their interior structures, parameterized by the quantity k₂/Q (assumed constant). Enceladus’ evolution after escape from the second-order e-Enceladus e-Dione resonance requires that (k₂/Q)_Enceladus<8×10^-4, for that Q_Saturn>18,000. This result is in agreement with [Meyer, J., Wisdom, J., 2008b. Icarus 193, 213-223]. The present-day libration amplitude of Enceladus requires that (k₂/Q)_Enceladus>1.2×10^-4, assuming that Q_Saturn<10⁵. Dione’s present-day eccentricity indicates that (k₂/Q)_Dione?3×10^-4 for Q_Saturn>18,000. Assuming Maxwellian viscoelastic behavior, we find that for Enceladus a convective ice shell overlying an ocean is too dissipative to match the orbital constraints. We conclude that a conductive shell overlying an ocean is more likely, and discuss the implications of this result. Dione’s ice shell is also likely to be conductive, but our results are less constraining.     

The ion mass loading rate at Io

The Io plasma torus, composed of mostly heavy ions of oxygen and sulfur, is sustained by an Iogenic mass loading rate of ∼10³⁰ amu s⁻¹ = 1.6 × 10²⁸ SO₂ s⁻¹ or approximately 10³ kg s⁻¹(A.L. Broadfoot et al., 1979, Science 204, 979-982). We argue on the basis of available power sources, reanalysis of F. Bagenal (1997, Geophys. Res. Lett. 24, 2111-2114), HST UV remote sensing, and detailed model calculations that at most 20% of this mass leaves Io in the form of ions, i.e., ≤3 × 10²⁷ × (n_e,0/3600 cm⁻³) ions s⁻¹, where n_e,0 is the average torus electron density. For the Galileo spacecraft Io pass in December 1995, the ion mass loading rate was ≤3 × 10²⁷ ions s⁻¹, whereas for the Voyager epoch with lower n_e,0 (=2000 cm⁻³), this rate would be ≤1.7 × 10²⁷ ions s⁻¹, consistent with the D.E. Shemansky (1980, Astrophys. J. 242, 1266-1277) mass loading limit of ≤1 × 10²⁷ ions s⁻¹. We investigate the processes that control Io’s large scale electrodynamic interaction and find that the elastic collision rate exceeds the ionization/pickup rate by at least a factor of 5 for all atmospheric column densities considered (10¹⁶-10²¹ m⁻²) and by a factor of ∼100 for the most realistic column density. Consequently, elastic collisions are mostly responsible for Io’s high conductances and thus generate Io’s large scale electrodynamic interaction such as the generation of Io’s electric current system and the slowing of the plasma flow. The electrodynamic part of Io’s interaction is thus best described as an ionosphere-like interaction rather than a comet-like interaction. An analytic expression for total electron impact rates is derived for Io’s atmosphere, which is independent of any particular model for the 3D interaction of torus electrons with its atmosphere.     

Monte Carlo study on distortion of the space-dimension in COBE monopole data

A concise explanation of studies on distortion of space-time dimension is briefly introduced. Second we obtain the limits (i.e., bounded values) of the dimensionless chemical potential μ, the Sunyaev–Zeldovich (SZ) effect y and distortion of the space-dimension ε by Monte Carlo (MC) analysis of the parameter set (T, d=3+ε, μ, and y) in cosmic microwave data assuming that the SZ effect is positive (y>0). In this analysis, the magnitude of the space-dimension d with distortion of the space-dimension ε is defined by d=3+ε. The limits of μ and y are determined as |μ|<9×10^?5 (2σ) (μ=(?3.9±2.6)×10^?5 (σ)), |y|<5×10^?6 (2σ) (y=(2.0±1.4)×10^?6 (σ)), while the distortion of the space-dimension is |ε|<6×10^?5 (2σ) (ε=(?0.78±2.50)×10^?5 (σ)). The magnitudes of these three estimated limits are ordered as . The estimated limit of |y|<5×10^?6 appears to be related to re-ionization processes occurring at redshift z _ri ～10. We also present data analysis assuming a relativistic SZ effect.     

Jovian auroral spectroscopy with FUSE: analysis of self-absorption and implications for electron precipitation

High-resolution (∼0.22 Å) spectra of the north jovian aurora were obtained in the 905-1180 Å window with the Far Ultraviolet Spectroscopic Explorer (FUSE) on October 28, 2000. The FUSE instrument resolves the rotational structure of the H₂ spectra and the spectral range allows the study of self-absorption. Below 1100 Å, transitions connecting to the v^″?2 levels of the H₂ ground state are partially or totally absorbed by the overlying H₂ molecules. The FUSE spectra provide information on the overlying H₂ column and on the vibrational distribution of H₂. Transitions from high-energy H₂ Rydberg states and treatment of self-absorption are considered in our synthetic spectral generator. We show comparisons between synthetic and observed spectra in the 920-970, 1030-1080, and 1090-1180 Å spectral windows. In a first approach (single-layer model ), the synthetic spectra are generated in a thin emitting layer and the emerging photons are absorbed by a layer located above the source. It is found that the parameters of the single-layer model best fitting the three spectral windows are 850, 800, and 800 K respectively for the H₂ gas temperature and 1.3×¹⁰¹⁸, 1.5×¹⁰²⁰, and 1.3×¹⁰²⁰ cm−2 for the H₂ self-absorbing vertical column respectively. Comparison between the H₂ column and a 1-D atmospheric model indicates that the short-wavelength FUV auroral emission originates from just above the homopause. This is confirmed by the high H₂ rovibrational temperatures, close to those deduced from spectral analyses of H⁺₃ auroral emission. In a second approach, the synthetic spectral generator is coupled with a vertically distributed energy degradation model, where the only input is the energy distribution of incoming electrons (multi-layer model ). The model that best fits globally the three FUSE spectra is a sum of Maxwellian functions, with characteristic energies ranging from 1 to 100 keV, giving rise to an emission peak located at 5 μbar, that is ∼100 km below the methane homopause. This multi-layer model is also applied to a re-analysis of the Hopkins Ultraviolet Telescope (HUT) auroral spectrum and accounts for the H₂ self-absorption as well as the methane absorption. It is found that no additional discrete soft electron precipitation is necessary to fit either the FUSE or the HUT observations.     

An Observational Study of the Molecular Cloud Core Toward IRAS 23133+6050

This paper reports ¹³CO, C¹⁸O, HCO⁺ (J = 1−0) spectral observations toward IRAS 23133+6050 with the 13.7 m millimeter-wave telescope at Qinghai Station of PMO. Corresponding to the ¹³CO, C¹⁸O, HCO⁺ line emissions, the size of the observed molecular cloud core is 4.0 pc, 2.1 pc and 2.3 pc, the virial mass is 2.7 × 10³ M_⊙, 0.9 × 10³ M_⊙ and 2.3 × 10³ M_⊙, and the volume density of H₂ is 2.7 × 10³ cm⁻³, 5.1 × 10³ cm⁻³ and 4.6 × 10³ cm⁻³, respectively. Using the power-law function n(r) ∼r^−p, the spatial density distribution of the cloud core was analyzed, the obtained exponent p is respectively 1.75, 1.56 and 1.48 for the ¹³CO, C¹⁸O and HCO⁺ cores, and it is found that the density distribution becomes gradually flatter from the outer region to the inner region of the core. The HCO⁺ abundance is 4.6 × 10⁻¹⁰, one order of magnitude less than the value for dark clouds, and slightly less than that for giant molecular clouds. The ¹³CO/C¹⁸O relative abundance ratio is 12.2, comparable with the value 11.8 for dark clouds, and the value 9.0 ∼ 15.6 for giant molecular clouds. A ¹³CO bipolar outflow is found in this region. The IRAS far-infrared luminosity and the virial masses give the luminosity-mass ratios 18.1, 51.1 and 21.2 from the three lines.     

Removal of Titan's noble gases by their trapping in its haze

Titan's haze, formed by photolysis of C₂H₂, C₂H₄ and HCN, was found experimentally to trap Ar, Kr and Xe with efficiencies of 3.5 × 10⁻⁴, 1.9 × 10⁻³ and 6.5 × 10⁻² [noble gas atom]/[carbon atom] in the polymer, respectively. The rate of aerosol formation and settling down of 3 × 10⁻¹³ kg m⁻² s⁻¹, as inferred from our experiments on CH₄ photolysis in the far UV [Podolak, M., Bar-Nun, A., 1979. Icarus 39, 272-276], is sufficient to reduce the mixing ratios of ³⁶Ar and ⁴⁰Ar to their low values of (2.8 ± 0.3) × 10⁻⁷ and (4.3 ± 0.1) × 10⁻³, respectively, and those of Kr and Xe to below the detection limit of 10⁻⁸.     

First Spitzer observations of Neptune: Detection of new hydrocarbons

We present the first spectra of Neptune taken with the Spitzer Space Telescope, highlighting the high-sensitivity, moderate-resolution 10-20 μm (500-1000 cm⁻¹) spectra. We report the discovery of methylacetylene (CH₃C₂H) and diacetylene (C₄H₂) with derived 0.1-mbar volume mixing ratios of (1.2±0.1)×¹⁰⁻¹⁰ and (3±1)×¹⁰⁻¹² respectively.     

How much oxygen is too much? Constraining Saturn's ring atmosphere

The discovery of a molecular oxygen atmosphere around Saturn's rings has important implications for the electrodynamics of the ring system. Its existence was inferred from the Cassini in situ detection of molecular oxygen ions above the rings during Saturn Orbit Insertion in 2004. Molecular oxygen is difficult to observe remotely, and theoretical estimates have yielded only a lower limit (Nn?¹⁰¹³ cm⁻²) to the O₂ column density. Comparison with observations has previously concerned matching ion densities at spacecraft altitudes far larger than the scale height of the neutral atmosphere. This is further complicated by charged particle propagation effects in Saturn's offset magnetic field. In this study we adopt a complementary approach, by focusing on bulk atmospheric properties and using additional aspects of the Cassini observations to place an upper limit on the column density. We develop a simple analytic model of the molecular atmosphere and its photo-ionization and dissociation products, with Nn a free parameter. Heating of the neutrals by viscous stirring, cooling by collisions with the rings, and torquing by collisions with pickup ions are all included in the model. We limit the neutral scale height to h?3000 km using the INMS neutral density nondetection over the A ring. A first upper limit to the neutral column is derived by using our model to reassess O₂ production and loss rates. Two further limits are then obtained from Cassini observations: corotation of the observed ions with the planet implies that the height-integrated conductivity of the ring atmosphere is less than that of Saturn's ionosphere; and the nondetection of fluorescent atomic oxygen over the rings constrains the molecular column from which it is produced via photo-dissociation. These latter limits are independent of production and loss rates and are only weakly dependent on temperature. From the three independent methods described, we obtain similar limits: Nn?2×¹⁰¹⁵ cm⁻². The mean free path for collisions between neutrals thus cannot be very much smaller than the scale height.     

Observations of CO in the atmosphere of Mars with PFS onboard Mars Express

We have analyzed spectra of CO recorded with the instrument PFS onboard Mars Express in the (1-0) band. The dataset we used ranges in time from January until June 2004 (L_S=331^°.17 until L_S=51^°.61; end of Mars Year 26, beginning of Mars Year 27). The aim of this work was to determine the amplitude of the CO mixing ratio departures from the mean globally averaged value currently admitted (8±3×10^-4) [Kaplan, L.D., Connes, J., Connes, P., 1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187-L192] as a function of season, local time and location on the planet. We therefore processed the data from 90 calibrated orbits. The globally averaged CO mixing ratio value we derive from our dataset, 11.1×10^-4, is compatible with the range found by Kaplan et al. [1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187-L192], although somewhat higher than the “standard” value. However, the CO mixing ratio we retrieve exhibits large variations (roughly between 3×10^-4 and 18×10^-4). Such relative variations have been used on a statistical basis to derive main trends as a function of latitude for three L_S ranges: 331-360^°, 0-30^° and 30-52^°. For the first L_S range, we seem to have an enhancement of the CO mixing ratio towards the northern latitudes, probably linked to the CO₂ condensation in winter on the north polar cap. The situation for the two other L_S ranges is not so clear, mainly as we lack data on the southern hemisphere. We roughly agree with the work of Krasnopolsky [2007. Long-term spectroscopic observations of Mars using IRTF/CSHELL: mapping of O2 dayglow, CO and search for CH4. Icarus 190, 93-102] for L_S=331-360^°, thus confirming the effect of seasonal condensation of CO₂ on the north polar cap, but we have no agreement for other seasons.     

CN, C2 radicals and dust in Comets Shoemaker-Levy 1991 T2 and P/deVico 1995 S1

The results of the multiaperture photometry of Comet Shoemaker-Levy 1991 T2 in the pre-perihelion and P/deVico in the post-perihelion period with the narrowband CN, C₂ and Blue Continuum (BC) IHW filters are presented. A Haser model of the molecular coma was used for the determination of the parent and daughter scale-lengths and production rates of the radicals. The comets showed some substantial differences between their parent scale-lengths. The CN parent scale-length (at 1.0 AU) was 16×¹⁰³ km for Comet Shoemaker-Levy and 39×¹⁰³ for P/deVico, the C₂ parent scale-lengths were respectively 29×¹⁰³ and 54×¹⁰³ km. Such divergences could be interpreted in the frame of different scenarios of emission of cometary parents, either from a nucleus or from a volume source. The daughter scale-lengths for these comets were quite similar, namely: 306×¹⁰³ and 318×¹⁰³ km for CN and 69×¹⁰³ and 66×¹⁰³ km for C₂. We determined the Afρ parameter for apertures of different radii. A Monte Carlo model of the dust coma was used to obtain the dust ejection velocity. It was of the order of 0.1 km s⁻¹ for both comets. The power index of the distribution of the β-parameter of dust particles (ratio of light pressure to the solar gravitation) was of the order of 3 for C/Shoemaker-Levy and close to 2 for P/deVico. The dependence on heliocentric distance (rh) of the radical and dust production rates for P/deVico in the range of 0.7-1.0 AU was described by the power law function with a power index equal to: 5.55±0.14 for CN, 5.70±0.24 for C₂ and 5.22±0.19 for dust. Relative abundances of the dynamically new Comet Shoemaker-Levy and short-period P/deVico were quite similar with an enhancement of C₂ comparing with standard values taken from A'Hearn et al. (1995).