Management and sediment dynamics of the St. Lucia Estuary mouth,Zululand, South Africa

St. Lucia Estuary is on the subtropical, predominantly microtidal Zululand coast of South Africa. Lake St. Lucia's surface area fluctuates between 420 and 215 km² and has a mean depth of less than 1 m. The 21-km-long narrows connects Lake St. Lucia with the Indian Ocean. Tidal effects penetrate 14 km up the narrows. The St. Lucia system has changed substantially since the 1930s due to bad farming techniques within its catchment. Large amounts of sediment were deposited in the estuary mouth, resulting in relocation of the Mfolozi River mouth to the south at Mapelane. The St. Lucia catchment was subjected to two devastating floods in the last ten years: Cyclone Domoina during February 1984 and the September 1987 cutoff low flood. After floods scoured out the estuary, marine sand advanced up the estuary at a rate of 1200 m/y as a series of flood-tidal deltas. Over 600,000 m³ of sediment accumulated in the St. Lucia Estuary mouth from February 1988 to November 1989. Of this amount, 466,000 m³ of sediment was removed by dredging, although this has not stopped the shoaling. During high rainfall years, the estuary mouth is able to maintain an open outlet to the sea, but as lake levels drop, shoaling causes the mouth to constrict and eventually close. Without the dredging program the mouth would ultimately close during low rainfall years, causing management problems.     

Wind-driven estuarine turbidity maxima in Mandovi Estuary,central west coast of India

Systematic studies on the suspended particulate matter (SPM) measured on a seasonal cycle in the Mandovi Estuary, Goa indicate that the average concentrations of SPM at the regular station are ∼20mg/l, 5mg/l, 19mg/l and 5mg/l for June–September, October–January, February–April and May, respectively. SPM exhibits low-to-moderate correlation with rainfall indicating that SPM is also influenced by other processes. Transect stations reveal that the SPM at sea-end stations of the estuary are at least two orders of magnitude greater than those at the river-end during the monsoon. Estuarine turbidity maximum (ETM) of nearly similar magnitude occurs at the same location in two periods, interrupted by a period with very low SPM concentrations. The ETM occurring in June–September is associated with low salinities; its formation is attributed to the interactions between strong southwesterly winds (5.1–5.6ms⁻¹) and wind-induced waves and tidal currents and, dominant easterly river flow at the mouth of the estuary. The ETM occurring in February–April is associated with high salinity and is conspicuous. The strong NW and SW winds (3.2–3.7ms⁻¹) and wind-driven waves and currents seem to have acted effectively at the mouth of the estuary in developing turbidity maximum. The impact of sea breeze appears nearly same as that of trade winds and cannot be underestimated in sediment resuspension and deposition     

Tidally-induced shear stress variability above intertidal mudflats in the macrotidal seine estuary

Tidal currents and the spatial variability of tidally-induced shear stress were studied during a tidal cycle on four intertidal mudflats from the fluvial to the marine part of the Seine estuary. Measurements were carried out during low water discharge (<400 m³ s⁻¹) in neap and spring tide conditions. Turbulent kinetic energy, covariance, and logarithmic profile methods were used and compared for the determination of shear stress. The c_TKE coefficient value of 0.19 cited in the literature was confirmed. Shear stress values were shown to decrease above mudflats from the mouth to the fluvial part of the estuary due to dissipation of the tidal energy, from 1 to 0.2 N m⁻² for spring tides and 0.8 to 0.05 N m⁻² for neap tides. Flood currents dominate tidally-induced shear stress in the marine and lower fluvial estuary during neap and spring tides and in the upper fluvial part during spring tides. Ebb currents control tidally-induced shear stress in the upper fluvial part of the estuary during neap tides. These results revealed a linear relationship between friction velocities and current velocities. Bed roughness length values were calculated from the empirical relationship given by Mitchener and Torfs (1996) for each site; these values are in agreement with the modes of the sediment particle-size distribution. The influence of tidal currents on the mudflat dynamics of the Seine estuary was examined by comparing the tidally-induced bed shear stress and the critical erosion shear stress estimated from bed sediment properties. Bed sediment resuspension induced by tidal currents was shown to occur only in the lower part of the estuary.     

Temporal and spatial variations in density and velocity fields of the waters of Gareloch,Scotland

 Spatial variations in the density and velocity fields have been observed in the Gareloch (Scotland) during surveys in 1987–1988 and 1993–1994. The variation of the density field has been analyzed on a variety of time scales from semidiurnal to seasonal in order to quantify effects caused by the forcing factors of tidal mixing, freshwater input, and wind. Initial results indicate that water density in the loch is controlled (to a major degree) by the freshwater input from runoff from the local catchment area and from freshwater entering on the flood tide from the Clyde Estuary. It is estimated that during winter periods the high freshwater flows from the rivers Leven and Clyde into the Clyde Estuary account for up to 75% of the freshwater creating the density structure in the loch. Analysis of long-term dissolved oxygen data reveals that major bottom water renewals occurred between July and January in the years 1987–1994. Major bottom water dissolved oxygen renewals have a general trend but during the year sporadic renewals can take place due to abnormal dry spells increasing the density of the water entering from the Clyde, or consistently strong winds from the north reducing stratification in the loch and producing better mixed conditions. Velocities vary spatially, with the highest velocities of up to 0.6 m s^–1 being associated with the velocity jet effect at the constriction at the sill of the loch. Observed near-surface mid-loch velocities increased as the vertical density gradients in the upper layers increased. This indicates for the observed conditions that increased stratification in the upper layers inhibits the entrainment rate and hence rate of gain of thickness of the wind-driven surface layer, resulting in increased surface velocities for a given wind speed and direction. The main flow is concentrated in the upper 10 m and velocities below 10 m are low. Observed mean spring tide surface velocities are on average 30% greater than mean neap tide surface velocities. Received: 22 May 1995 · Accepted: 23 August 1995     

Two-dimensional horizontal modeling of fine-sediment transport at the South Channel–North Passage of the partially mixed Changjiang River estuary,China

Tidal flow and fine-sediment transport at the South Channel–North Passage of the partially-mixed Changjiang River estuary were studied using a two-dimensional horizontal (2DH) numerical model. This 2DH model was achieved by depth-integrating the momentum and convection–diffusion equations. The Alternating Direction Implicit scheme was used to solve the governing equations. The iterative method was adopted for the calculation of convection and diffusion terms of momentum equation. Comparisons between calculated and measured results (tidal elevations and depth-averaged velocities) have shown reasonable agreement. Horizontal distributions of tidal current velocity and suspended sediment concentration were qualitatively consistent with observations. Those modeled results were analyzed to elucidate the mechanisms for the formation of the turbidity maximum and intratidal variations in fine-sediment transport processes.     

Tidal sediment transport versus freshwater flood events in the Konkouré Estuary, Republic of Guinea

In comparison to their temperate counterparts, sediment processes in tropical estuaries are poorly known and especially in African ones. The hydrodynamics of such environments is controlled by a combination of multiple processes including morphology, salinity, mangrove vegetation, tidal processes, river discharge, settling and erosion of mud and by physico-chemical processes as well as sediment dynamics.The aim of this study is to understand the sediment processes in this transitional stage of the estuary when the balance between river discharges and marine processes is reversing. Studying the hydrodynamics and sediment dynamics of the Konkouré Estuary has recently been made possible thanks to new data on bathymetry, sedimentary cover, salinity, water elevations, and current velocities. The Lower Konkouré is a shallow, funnel shaped, mesotidal mangrove-fringed, tide-dominated estuary, well mixed during low river discharge and stratified during high river discharge. The Konkouré Estuary is turbid despite the small amount of terrestrial input and its residual velocity at the mouth during low river discharges, landwards for two of the three branches, suggests a landward migration by tidal pumping of the suspended particulate matter. A Turbidity Maximum Zone (TMZ) is identified for typical states of the estuary with regard to fluvial and tidal components. Suspended sediment transport during a transitional stage between the rainy and dry seasons is known thanks to current velocity and Suspended Sediment Concentration (SSC) measurements taken in November 2003. The Richardson layered number calculation assesses that turbulence is the major mixing process in the water column, at least during the flood and ebb stages, whereas stratification occurs during the slack water periods. Tidal currents generate bottom erosion, and turbulence mixes the suspended sediment throughout the water column. As a result, a net sediment input is calculated from the western Konkouré outlet for two consecutive tidal cycles. Despite the net water export, almost 300 tons per tide reach the estuary through this outlet, for a moderate river flow.     

Dissolved and particulate trace metals and their partitioning in a hypoxic estuary: The Tanshui Estuary in Northern Taiwan

The distribution and partitioning of trace metals (Co, Cu, Fe, Mn, Ni, and Zn) between dissolved and particulate phases were studied in the Tanshui Estuary. The upper reach of the estuary is hypoxic and heavily polluted due to domestic and industrial discharges. The concentration ranges of dissolved and leachable particulate trace metals in the Tanshui Estuary were: Co: 0.3–6.1 nM, 1.8–18.6 mg kg⁻¹; Cu: 5–53 nM, 22–500 mg kg⁻¹; Fe: 388–3,364 nM, 1.08–6.67%; Mn: 57–2,914 nM, 209–1,169 mg kg⁻¹; Ni: 7–310 nM, 6–108 mg kg⁻¹; and Zn: 12–176 nM, 62–1,316 mg kg⁻¹; respectively. The dissolved concentrations of the metals were 2–35 times higher than the average values of the world river water. The distributions of dissolved and particulate studied metals, except Mn, in the estuary showed scattering, which could be attributed to the discharges from many industrial wastewater disposal works located in the upper tributaries. The daily input of dissolved metals from the disposal works to the Tanshui Estuary ranged from 0.1–0.4 tons. Dissolved Mn was nearly conservative in the region with salinity higher than 10 psu, while particulate Mn decreased in the region with salinity of 10–15 psu. The concentration increased significantly seawards, corresponding with the distribution of dissolved oxygen. The distribution coefficient (K_D) for Mn in the lower estuary was nearly three orders of magnitude higher than in the upper estuary. This phenomenon may be attributed to the diffusion of Mn from the anoxic sediment in the upper estuary and gradual oxidation into particulate Mn in the middle and lower estuary as the estuarine water became more oxygenated. The distribution coefficient for Cu decreased with increasing salinity. The percentages of trace metals bound by suspended particulate matter decreased in the following order: Fe>Zn, Cu>Co>Mn>Ni.     

Seasonal and tidal monthly patterns of particulate matter dynamics in the Columbia River estuary

We investigated seasonal and tidal-monthly, suspended particulate matter (SPM) dynamics in the Columbia River estuary from May to December 1997 using acoustic backscatter (ABS) and velocity data from four long-term Acoustic Doppler Profiler (ADP) moorings in or near the estuarine turbidity maximum (ETM). ABS profiles were calibrated and converted to total SPM profiles using pumped SPM samples and optical backscatter (OBS) data obtained during three seasonal cruises. Four characteristic settling velocity (W _s) classes were defined from Owen Tube samples collected during the cruises. An inverse analysis, in the form of a non-negative least squares minimization, was used to determine the contribution of the four,W _s-classes to each, total SPM profile. The outputs from the inverse analyses were 6–8 mo time-series ofW _s-specific SPM concentration and transport profiles at each mooring. The profiles extended from the free surface to 1.8–2.7 m from the bed, with 0.25–0.50 m resolution. These time series, along with Owen Tube results and disaggregated size data, were used to investigate SPM dynamics. Three non-dimensional parameters were defined to investigate how river flow and tidal forcing affect particle trapping: Rouse numberP (balance between vertical mixing and settling) trapping efficiencyE (ratio of maximum SPM concentration in the estuary to fluvial source concentration), and advection numberA (ratio of height of maximum SPM concentration to friction velocity). The most effective particle trapping (maximum values ofE) occurs on low-flow neap tides. The location of the ETM and the maximal trapping migrated seasonally in a manner consistent with the increase in salinity intrusion length after the spring freshet. Maximum advection (high values ofA) occurred during highly stratified neap tides.     

Sediment dynamics of turbidity maximum in Changjiang River mouth in dry season

High-resolution current velocity and suspended sediment concentration (SSC) data were collected by using an Acoustic Doppler Current Profiler (ADCP) at two anchor stations and a cross-section in the South Channel of the Changjiang River mouth during meso and neap tides on Nov. 16, 2003. In addition, tidal cycle (13-hour) observation at two stations was carried out with traditional methods during the spring tide. Results indicated that resuspension occurred not only at the flood and ebb maximum, but also in the early phase of ebb in the meso and neap tide. When tidal current transited from high to ebb phase, current speed accelerated. Subsequently, fine-grained sediment with low critical threshold was resuspended and increased concentration. The river mouth area remained in siltation in the meso and neap tidal phase during the observation season, with calculated resuspension flux in the order of magnitude of 10⁻⁴–10⁻⁷ kg·m−2/s. Suspended sediment transport in the South Channel was dominated by freshwater discharge, but the Storks drift, vertical circulation and vertical shear effect due to tidal oscillation also played an important role in resuspension and associated sediment transport. In contrast, resuspension sediment flux in the spring tide was larger than that in meso and neap tide, especially at the ebb maximum and flood maximum. The present study revealed that intensive resuspension corresponded well with the larger current velocity during winter. In addition, the ‘tidal pumping’ effect and tidal gravity circulation were also vital for forming the turbidity maximum in the Changjiang River estuary.     

Sedimentation in a fluvially infilling, barrier-bound estuary on a wave-dominated, microtidal coast: the Ouémé River estuary, Benin, west Africa

The Ouémé River estuary is located on the seasonally humid tropical coast of Benin, west Africa. A striking feature of this microtidal estuary is the presence of a large sand barrier bounding a 120 km² circular central basin, Lake Nokoué, that is being infilled by heterogeneous fluvial deposits supplied by a relatively large catchment (50 000 km²). Borehole cores from the lower estuary show basal Pleistocene lowstand alluvial sediments overlain by Holocene transgressive–highstand lagoonal mud and by transgressive to probably early highstand tidal inlet and flood‐tidal delta sand deposited in association with non‐preserved transgressive sand barriers. The change in estuary‐mouth sedimentation from a transgressive barrier‐inlet system to a regressive highstand barrier reflects regional modifications in marine sand supply and in the cross‐barrier tidal flux associated with barrier‐inlet systems. As barrier formation west of the Ouémé River led to an increasingly rectilinear shoreline, the longshore drift cell matured, ensuring voluminous eastward transport of sand from the Volta Delta in Ghana, the major purveyor of sand, to the Ouémé embayment, 200 km east. Concomitantly, the number of tidal inlets, and the tidal flux associated with a hitherto interlinked lagoonal system on this coast, diminished. Complete sealing of Lake Nokoué has produced a large, permanently closed estuary, where tidal intrusion is assured through the interconnected coastal lagoon via an inlet located 60 km east. Since 1885, tides have entered the estuary directly through an artificial outlet cut across the sand barrier. Although precluding the seaward loss of fluvial sediments, permanent estuary‐mouth closure has especially deprived the highstand estuary of marine sand, a potentially important component in estuarine infill on wave‐dominated coasts. In spite of a significant fluvial sediment supply, estuarine infill has been moderate, because of the size of the central basin. Estuarine closure has resulted in two co‐existing highstand sediment suites, with limited admixture, the marine‐derived, estuary‐mouth barrier and upland‐derived back‐barrier sediments. This situation differs from that of mature barrier estuaries characterized by active fluvial‐marine sediment mixing and facies interfingering.     

Nitrogen budget for low and high freshwater inflows, Nueces Estuary, Texas

Nueces Estuary is a relatively shallow, microtidal estuary which receives inputs from a significant industrial and urban area and from a semi-arid drainage basin. Nitrogen (N) loadings were compiled using FLUX model and flow x concentration calculations for four annual periods spanning a range of inflow volumes. For each annual period, N budgets were developed, supported by water and total dissolved solids dudgets. Budget compilations include materials transported in tidal exchange with the Gulf of Mexico and with neighboring bays. Wastewater discharge contributes twice as much N to the bay than inflows from the Nueces River. Net flows and tidal entrainment of materials from neighboring bays contribute 24–32% of total loadings except during flood flows of the Nueces River. Atmospheric deposition to the estuary surface provides 8% of N loading. Despite low tidal amplitude and a restricted Gulf pass tidal entrainment losses are the main vehicle of export, except during flood flows, when net flows to the Gulf become important. The system exports much more of its total N load than would be expected from its water residence time, possibly facilitated by ship channel longitudinal transport. Denitrification accounts for 30–40% of all N lost. Uncertainties in components of the budget are estimated and included in compilations of confidence bounds for N budget components.     

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.     

Sources, input pathways, and distributions of Fe, Cu, and Zn in a Chesapeake Bay tidal freshwater marsh

Tidal freshwater marshes exist at the interface between watersheds and estuaries, and thus may serve as critical buffers protecting estuaries from anthropogenic metal pollution. Bi-weekly samples of newly deposited marsh sediments were collected and analyzed for Cu, Zn, and Fe concentrations over 21 months from July 1995 to March 1997 in five distinct habitats at the head of Bush River, Maryland. Bi-weekly anthropogenic metal enrichments ranged from 0.9–4.7. Anthropogenic excess metal loadings averaged over 1996 ranged from 6–306 and 25–1302 μg cm⁻² year⁻¹ between sites for Cu and Zn, respectively. Based on Fe-normalized trace metal signatures, Susquehanna River sediment does not significantly contribute to upper Bush River. Organic matter was found to dilute total metal concentrations, whereas past studies suggested organics enhance labile metal content. Analysis of metal input pathways shows that marsh metals are primarily imported from nearby subtidal accumulations of historic watershed material by tidal flushing. Received: 29 April 1999 / Accepted: 7 December 1999     

Tidal nitrogen exchanges across a freshwater wetland succession gradient in the upper Cooper River,South Carolina

Tidal freshwater sections of the Cooper River Estuary (South Carolina) include extensive wetlands, which were formerly impounded for rice culture during the 1,700s and 1,800s. Most of these former rice fields are now open to tidal exchange and have developed into productive wetlands that vary in bottom topography, tidal hydrography and vegetation dominants. The purpose of this project was to quantify nitrogen (N) transport via tidal exchange between the main estuarine channel and representative wetland types and to relate exchange patterns to the succession of vegetation dominants. We examined N concentration and mass exchange at the main tidal inlets for the three representative wetland types (submerged aquatic vegetation [SAV], floating leaf vegetation, and intertidal emergent marsh) over 18-21 tidal cycles (July 1998–August 2000). Nitrate + nitrite concentrations were significantly lower during ebb flow at all study sites, suggesting potential patterns of uptake by all wetland types. The magnitude of nitrate decline during ebb flow was negatively correlated with oxygen concentration, reflecting the potential importance of denitrification and nitrate reduction within hypoxic wetland waters and sediments. The net tidal exchange of nitrate + nitrite was particularly consistent for the intertidal emergent marsh, where flow-weighted ebb concentrations were usually 18–40% lower than during flood tides. Seasonal patterns for the emergent marsh indicated higher rates of nitrate + nitrite uptake during the spring and summer (> 400 μmol N m^-2 tide^-1) with an annual mean uptake of 248 ± 162 μmol m^–2 tide^–1. The emergent marsh also removed ammonium through most of the year (207 ± 109 μmol m^–2 tide^–1), and exported dissolved organic nitrogen (DON) in the fall (1,690 ± 793 μmol m^–2 tide^–1), suggesting an approximate annual balance between the dissolved inorganic N uptake and DON export. The other wetland types (SAV and floating leaf vegetation) were less consistent in magnitude and direction of N exchange. Since the emergent marsh site had the highest bottom elevation and the highest relative cover of intertidal habitat, these results suggest that the nature of N exchange between the estuarine waters and bordering wetlands is affected by wetland morphometry, tidal hydrography, and corresponding vegetation dominants. With the recent diversion of river discharge, water levels in the upper Cooper estuary have dropped more than 10 cm, leading to a succession of wetland communities from subtidal habitats toward more intertidal habitats. Results of this study suggest that current trends of wetland succession in the upper Cooper River may result in higher rates of system-wide inorganic N removal and DON inputs by the growing distributions of intertidal emergent marshes.     

A Preliminary Sediment Budget for the Corsica River (MD): Improved Estimates of Nitrogen Burial and Implications for Restoration

The Corsica River, located on Maryland’s eastern shore, has been the site of restoration efforts targeting sediment and nutrient load reductions. Previous work has indicated that agricultural activities supply most of these materials; however, their dynamics and fate are largely unknown. To address these needs, bottom sediments have been collected and analyzed for their chemical and textural properties. Long-term (decadal) accumulation rates are determined with ²¹⁰Pb (half-life 22.3 years), verified with ¹³⁷Cs, and range from 0.18 to 0.84 g/cm²/year in the subtidal region and 0.3–1.89 g/cm²/year in the marshes. These estimates are compared with likely sediment sources to determine the direction of exchange with the adjacent estuary (Chester River), which is a subtributary of Chesapeake Bay, with the Chester River likely supplying 0.94 × 10³ t/year of sediment to the Corsica, ∼16% of the total sediment input. The radiochemical data are used to interpret profiles of grain size and nitrogen and to provide improved estimates of nitrogen burial. Comparison of the Corsica River to similar systems highlights the importance of marshes in trapping sediment and nutrient inputs from the watershed.     

Net aboveground primary production and soil properties of floating and attached freshwater tidal marshes in the Río de la Plata estuary,Argentina

In the lower delta of the Paraná River, at the head of the Río de la Plata estuary (Argentina), we compared net aboveground primary production (NAPP) and soil properties of the dominant macrophyteScirpus giganteus (Kunth) in a floating and an attached marsh community. Both marshes are tidally influenced but in different ways. The floating marsh site is relatively isolated from tidal influences because its ability to float makes it resistant to overland flow and to sediment inputs from the estuary. The attached marsh lacks the capacity to float and receives sediment supplies from the estuary through overland flow. These hydrologic differences are reflected in lower mineral content in sediments of the floating marsh. Using a leaf tagging technique, estimated NAPP was 1,109 ± 206 g m⁻² yr⁻¹ for the floating marsh and 1,866 ±258 g m⁻² yr⁻¹ for the attached marsh. We attribute the lower NAPP of the floating marsh to isolation from sediment input from overland flow.     

Behavior of arsenic and antimony in the surface freshwater reaches of a highly turbid estuary, the Gironde Estuary, France

This study reports on the behavior of two redox-sensitive elements, As and Sb, along the turbidity gradient in the freshwater reaches of the turbid Gironde Estuary. During a 17-month survey, surface water and suspended particulate matter (SPM) were sampled monthly at six sites representing both fluvial branches of the Gironde Estuary. Additionally, two longitudinal high resolution profiles were sampled along the fluvial estuary of the Garonne Branch during two contrasted seasons, i.e. with and without the presence of the maximum turbidity zone (MTZ). Seasonal variability and spatial distribution of dissolved (<0.2 μm; <0.02 μm) and particulate As, Sb and Fe were measured and combined with SPM data to understand metalloid behavior in the estuarine freshwater turbidity gradient.At the two main fluvial entries of the Gironde Estuary, dissolved As and Sb concentrations showed strong (by a factor of 2–4) seasonal variations, that were only partly controlled by discharge-related dilution. Seasonal addition of dissolved As and Sb was attributed to the degradation of particulate As and Sb carrier phases in bottom sediment and/or in the adjacent aquifers, rather than release from SPM. In the surface freshwater reaches of the Gironde Estuary, Sb behaved conservatively under all hydrological conditions. In contrast, As was strongly reactive in the presence of the MTZ, with opposite behaviors in the two fluvial branches of the estuary: in the Garonne Branch As was removed from the dissolved phase, whereas in the Dordogne Branch As was added. Redistribution of As between the dissolved and the particulate phases along the turbidity gradient in estuarine freshwater only affected the <0.02 μm fraction, as the 0.02–0.2 μm fraction remained constant (300 ng L⁻¹ in September 2005). Accordingly, As removal seemed to be decoupled from concomitant “colloidal” (0.02–0.2 μm) Fe flocculation in the turbidity gradient. The contrasting behavior of dissolved As in the fluvial estuaries of the Garonne and Dordogne Branches was attributed to sorption processes during equilibration of river-borne dissolved As with estuarine SPM forming the MTZ. This equilibrium, described by a distinct distribution coefficient K_d(As)  11,000 L kg⁻¹ in the MTZ, resulted in either As release (desorption; Dordogne Branch) or removal (adsorption; Garonne Branch) in the respective fluvial estuaries. A mixing experiment under controlled laboratory conditions tended to support that equilibration between the dissolved phase and MTZ particles may induce both As release and removal in the estuarine freshwater reaches, with As distribution evolving towards a distinct K_d value for increasing SPM concentrations. The long-term survey allowed estimating annual (2004) dissolved fluxes of As and, for the first time Sb, at the main fluvial entries of the Gironde Estuary at 30.7 t a⁻¹ and 3.2 t a⁻¹ (Garonne River) and at 8.0 t a⁻¹ and 2.3 t a⁻¹ (Dordogne River), respectively.     

Remotely sensed observations of the turbidity maximum in the highly turbid Humber Estuary, UK

The Humber Estuary, UK, divides into the Ouse and Trent estuaries at the so-called Apex within its upper reaches. Remotely sensed Compact Airborne Spectrographic Imager (CASI) images and boat measurements were used to observe a strong turbidity maximum in the upper Humber and Ouse during a spring tide in November 1995. Surface suspended particulate matter (SPM) concentrations during the late ebb, as estimated from the CASI data, increased from approximately 6 to 13 g I⁻¹ moving up-estuary into the Ouse. Greater SPM concentrations (∼10 g I⁻¹) were evident in the deeper channels of the Ouse, compared with shallower areas, possibly due to faster ebb currents there and differential down-estuary advection of the turbidity maximum. Ribbons, or streaks, of lower SPM and slightly cooler waters were observed. It appears that slightly cooler and lower turbidity waters from the confluent Trent estuary remained fairly distinct for distances of approximately 2 km down-stream of its confluence with the upper Humber and Ouse. These waters eventually broke into ribbon-like or streak-like structures within the higher SPM-laden and slightly warmer waters of the Humber. They were discernible for more than 5 km down-estuary of the confluence of the Humber, Ouse, and Trent. Boat measurements showed that the turbidity maximum occurred over a fairly restricted region of the upper Humber, between about 20 to 50 km from the tidal limit at high water. The turbidity maximum’s sediment load was largely suspended in the water column during stronger currents. SPM rapidly settled close to the bed during high water and low water slack periods. At these times, SPM concentrations in a thin, near-bed layer were >60 g I⁻¹ in the turbidity maximum region of the Ouse and >30 g 1⁻¹ in the upper Humber (where channel volumes were much greater). SPM within the turbidity maximum comprised very fine-grained material and its low organic content demonstrated that the SPM was essentially mineral, clastic sediment derived originally from erosion and decay of crustal rocks.     

The chemistry of suspended particulate material in a highly contaminated embayment of Port Jackson (Australia) under quiescent,high-wind and heavy-rainfall conditions

This study investigated physico-chemical characteristics of the water column and chemistry of suspended particulate material (SPM) under quiescent, high-wind and high-wind/heavy-rainfall conditions in Homebush Bay, a highly contaminated embayment of Port Jackson (Australia) to distinguish source and possible adverse effects to benthic and pelagic animals. Mean concentrations in surficial sediment were <1, 14, 181, 141, 37, 290 and 685 μg g⁻¹ for Cd, Co, Cr, Cu, Ni, Pb and Zn, respectively. Sediment chemistry indicated these metals had multiple sources, i.e. the estuary, stormwater and industry. Mean total suspended solids (TSS) were 7, 17 and 20 mg L⁻¹ during quiescent, high-rainfall and heavy rainfall/high wind conditions, respectively, whereas SPM Cd, Co, Cr, Cu, Ni, Pb and Zn concentrations varied between 13–25, 166–259, 127–198, 38–82, 236–305 and 605–865 μg g⁻¹, respectively under these conditions. TSS and total water metal concentrations were lowest during quiescent conditions. High TSS and metal loads in surface water characterised high-rainfall events. Wind-induced resuspension contributed the greatest mass of SPM and metals to the water column. Benthic animals may be adversely affected by Pb and Zn in sediment. Total water Cu and Zn concentrations may pose a risk to filter-feeding animals in the water column due to resuspension of contaminated sediment.     

Seasonal Variability and Estuary–Shelf Interactions in Circulation Dynamics of a River-dominated Estuary

The long-term response of circulation processes to external forcing has been quantified for the Columbia River estuary using in situ data from an existing coastal observatory. Circulation patterns were determined from four Acoustic Doppler Profilers (ADP) and several conductivity–temperature sensors placed in the two main channels. Because of the very strong river discharge, baroclinic processes play a crucial role in the circulation dynamics, and the interaction of the tidal and subtidal baroclinic pressure gradients plays a major role in structuring the velocity field. The input of river flow and the resulting low-frequency flow dynamics in the two channels are quite distinct. Current and salinity data were analyzed on two time scales—subtidal (or residual) and tidal (both diurnal and semidiurnal components). The residual currents in both channels usually showed a classical two-layer baroclinic circulation system with inflow at the bottom and outflow near the surface. However, this two-layer system is transient and breaks down under strong discharge and tidal conditions because of enhanced vertical mixing. Influence of shelf winds on estuarine processes was also observed via the interactions with upwelling and downwelling processes and coastal plume transport. The transient nature of residual inflow affects the long-term transport characteristics of the estuary. Effects of vertical mixing could also be seen at the tidal time scale. Tidal velocities were separated into their diurnal and semidiurnal components using continuous wavelet transforms to account for the nonstationary nature of velocity amplitudes. The vertical structure of velocity amplitudes were considerably altered by baroclinic gradients. This was particularly true for the diurnal components, where tidal asymmetry led to stronger tidal velocities near the bottom.