粘土矿物研究在塔里木盆地石油勘探中的应用

以塔里木盆地粘土矿物的分布特征及其组合形式、演化与形成机理为依据,探讨了粘土矿物在地层划分对比中的应用及其与有机质热演化、成岩阶段的关系和对储层物性的影响。研究表明,在侏罗系和白垩系两个不同古环境中形成的粘土矿物及其组合特征,为地层对比提供了一定的证据。泥岩中伊利石／蒙皂石间层中蒙皂石含量的纵向变化与有机质热演化及成岩阶段的关系不大。对储层物性影响不大但有利于储集性能的是以高岭石为主的粘土矿物组合类型及粘土矿物的早期自生（伊利石／蒙皂石间层矿物）衬垫式以及非自生（伊利石）衬垫式产状。     

苏北盆地粘土矿物转化模式与古地温

以苏北盆地为例,系统研究了火成岩发育区粘土矿物组合特征及其控制因素;建立了粘土矿物转化模式;根据粘土矿物成岩演化特点,进行古地温分析。研究表明,苏北地区粘土矿物的分布主要受埋藏成岩作用、岩浆侵入、母质来源三种因素的影响,发育四种类型的粘土矿物组合和三种粘土矿物转化模式;火山碎屑岩母岩区和基性岩浆侵入区具有特殊的粘土矿物组合和成岩演化模式,前者以富含蒙皂石矿物为特点;后者出现高岭石与伊/蒙有序间层矿物共生组合,并具有不连续的演化序列;苏北盆地短有序I/S矿物出现于镜质组反射率 0.5 %～ 0.5 5 %的深度,伊/蒙间层矿物转变成伊利石在镜质组反射率 0.75 %～ 0.8%,可以用于热成熟度和古地温的估算;而蒙皂石消失的界面则不具有指标意义     

鄂东黄石地区下三叠统大冶组风暴沉积

鄂东黄石地区下三叠统大冶组灰岩中发育了典型的风暴沉积,风暴岩由砾屑灰岩、颗粒灰岩和泥灰岩组成,其中风暴沉积构造包括丘状交错层理、递变层理、砾屑的撕裂构造及水平层理等,不同层位具有不同的风暴沉积构造类型和组合特征。根据风暴沉积的岩石特征、构造类型、规模、组合特点,并结合沉积背景分析,风暴沉积序列可进一步分为深水远源型、过渡型和浅水近源型。大冶组一段风暴沉积具有深水远源特点,沉积环境为水体较深的外陆棚; 大冶组二段风暴沉积具有过渡型特点,沉积环境为向上变浅的内陆棚; 大冶组三、四段风暴沉积具有浅水近源特点,沉积环境为浅水陆棚至滨岸。大冶组沉积序列具有向上变浅的特点,沉积环境由深水陆棚逐渐向滨岸转变。风暴沉积的识别对重建鄂东黄石地区早三叠世古地理具有重要意义。     

北京西山下苇甸中上寒武统风暴沉积特征及模式

通过对北京西山下苇甸剖面中典型风暴成因竹叶状灰岩的野外实测和镜下薄片分析，明确了59套风暴沉积特征，确定了风暴沉积序列并建立了陆表海风暴作用沉积模式，主要取得如下认识：(1)北京西山下苇甸寒武系共有泥晶灰岩相、含砾屑泥晶灰岩相、颗粒泥晶灰岩相和泥晶颗粒灰岩相4种岩相类型。(2)鲕粒灰岩-砾屑灰岩型序列发育原地型风暴岩，泥岩和粉砂岩-砾屑灰岩型序列发育近源型风暴岩，泥晶灰岩-砾屑灰岩型序列发育远源型风暴岩。(3)原地型风暴岩发育侵蚀面，砾屑含量高，长短轴比大；近源型风暴岩砾屑定向性好，可见递变层理；远源型风暴岩基质含量高。(4)竹叶状灰岩沉积在陆表海背景下的潮下带，原地型、近源型和远源型风暴岩沉积范围以正常浪基面和风暴浪基面为界，距风暴中心距离和搬运距离依次增加。本次研究不仅补充了下苇甸寒武系的风暴沉积记录，而且为该时期的古环境研究提供了证据。     

东海盆地西湖凹陷天台区始新世平湖组风暴岩的发现及其地质意义

风暴岩对于古地理和古环境具有良好的指相意义。东海盆地西湖凹陷天台区始新世平湖组发育典型的风暴岩。通过详细的岩心观察,发育的风暴沉积标志主要有冲刷-充填构造、风暴撕扯构造和丘状-洼状交错层理构造等。根据风暴岩垂向上的组合特征及沉积构造差异,识别出了近源和远源两种风暴沉积类型,分别指示了不同的沉积背景：近源风暴岩表现为不完整的风暴岩垂向沉积序列,呈风暴砾屑层段（A）+泥岩段（E）叠加,为潮坪潮下带沉积;远源风暴岩具完整和不完整的风暴岩垂向沉积序列,以粒序段（B）+平行层理段（C）+丘状（洼状）层理段（D）叠加为特征,属浅海陆棚沉积。风暴层序自下而上沉积环境为浅海陆棚→潮坪,风暴岩的分布差异表明形成环境向上变浅的沉积特征。该发现为本区古环境的演变提供了重要依据。     

蒙皂石含量与膨胀土膨胀势指标相关关系研究

对沿南水北调中线工程邯郸永年、南阳、平顶山等地区及襄樊、荆门钟祥地区采集的各类地表、近地表膨胀土样品5 6件 ,运用现代XRD定量方法和有机染料吸附方法测量了粘土矿物成分和蒙皂石含量 ,同时测定了它们的液限、塑限、自由膨胀率、比表面积、粘粒、胶粒含量等指标。蒙皂石含量与各种膨胀势判别指标研究表明 ,蒙皂石含量是各种膨胀势的主要控制因素。当然 ,各种测量误差 (主要是蒙皂石含量的测量误差 )也是影响膨胀势判别的因素。Seed膨胀势较本文采用的推荐方案划分结果高 1～ 2个级次。蒙皂石含量与各参量之间呈线性、对数、指数关系 ,与粘土矿物的诊断吸收特性一起 ,这为膨胀土遥感提供了基础.     

杭州湾潮滩沉积物黏土矿物空间差异与物源指示

通过对杭州湾潮滩沉积物中主要黏土矿物成分及组合类型的研究,分析了杭州湾潮滩沉积物黏土矿物的空间分布特征。借助聚类分析等手段,同时结合杭州湾水动力特征,探讨了研究区黏土矿物的来源和成因。研究结果表明,杭州湾潮滩表层沉积物主要为黏土质粉砂,其余为砂质粉砂。本区沉积物黏土矿物成分复杂,主要为伊利石,其次是高岭石和绿泥石;还有少量蒙皂石和蛭石及1.4 nm过渡矿物。根据其相对含量可分为3种组合类型:Ⅰ型为伊利石-高岭石-绿泥石-蛭石类-蒙皂石型,Ⅱ型为伊利石-绿泥石-高岭石-蒙皂石-蛭石类型,Ⅲ型为伊利石-高岭石-绿泥石-蒙皂石-蛭石类型。在空间上,北岸的蒙皂石和绿泥石平均含量高于南岸,而伊利石、高岭石和蛭石(含1.4 nm过渡矿物)平均含量则低于南岸。高潮滩和中潮滩黏土矿物对比,除了蒙皂石含量高潮滩大于中潮滩外,其他矿物含量均无明显规律。表层沉积物黏土矿物的分布特征与水动力条件和物质来源密切相关,杭州湾北岸乍浦以东潮滩受潮流和长江沿岸流影响明显,沉积物主要为长江和东海源的;南岸由于曹娥江和甬江两条河流的注入,流域物质所占比例明显比北岸高。柱状岩芯样品中各黏土矿物含量自下而上的变化则反映了物源区风化强度的波动特征。     

相山矿田热液水云母化及其与铀矿化关系研究

相山铀矿田广泛发育热液水云母化,且水云母以伊利石、蒙皂石混层矿物居多。对典型矿床围岩、蚀变岩石和矿石中粘土组成的定量分析和化学成分分析表明：随着Ｕ元素的逐渐富集,粘土矿物存在蒙皂石→伊利石、蒙皂石混层矿物→伊利石的转化过程,而且这一转化过程在本区是一个动态的平衡过程,这一研究结果很好解释了相山矿田以群脉矿床的为主的特征;蚀变岩石中高蒙皂石含量的粘土矿物为后期富大矿起了富集Ｕ的作用。     

准噶尔盆地南缘新生界粘土矿物分布及影响因素

根据粘土矿物的相对含量研究了准噶尔盆地南缘新生界砂岩粘土矿物类型、组合特征及纵、横向分布规律及其主要影响因素。划分出无序伊/蒙混层型、部分有序伊/蒙混层型、伊利石+伊/蒙混层型、蒙皂石型以及含坡缕石型等5类粘土矿物组合。按照伊/蒙混层相对含量的变化,粘土矿物纵向上演化呈正常转化型(伊/蒙混层相对含量降低)、反向转化型(伊/蒙混层相对含量增加)和“S”型(伊/蒙混层相对含量呈曲线变化)3种形式。平面上,伊/蒙混层和伊利石这两类主要粘土矿物从湖盆的边缘向中心分别呈现减少和增多的趋势,湖盆边缘相带以无序伊/蒙混层型、蒙皂石型和含坡缕石型为主,湖盆中心则为部分有序伊/蒙混层型和伊利石+伊/蒙混层型组合等类型。上述分布规律的控制因素主要有沉积环境、构造运动及层序发育等。     

鄂尔多斯盆地纳岭沟地区直罗组砂岩粘土矿物特征及初步对比研究

纳岭沟铀矿床位于鄂尔多斯盆地东北部,含铀岩系为中侏罗统直罗组。文章通过薄片鉴定、扫描电镜、X射线衍射 等分析测试手段,对纳岭沟地区直罗组砂岩粘土矿物的镜下特征、成分及含量进行了系统的观察和研究,探讨了直罗组砂 岩粘土的矿物特征,并初步与伊犁盆地及二连盆地做了对比。研究表明,纳岭沟地区直罗组砂岩的粘土矿物主要为蒙皂 石,其次为高岭石、绿泥石,少量伊利石 。蒙皂石与高岭石存在相互转化现象,部分绿泥石由蒙皂石和高岭石转化而来, 成岩过程中蒙皂石并未大规模自发的向伊利石转化。砂岩的粘土总量较高,与伊犁盆地相比,富含蒙皂石,高岭石含量较 低,粘土矿物的吸附能力较强。在直罗组砂岩的成岩过程中,粘土矿物的吸附作用为直罗组富集了大量的铀,这是鄂尔多 斯盆地东北部地区能形成众多铀矿床乃至超大型铀矿床的重要条件。     

Palaeoenvironmental significance of the clay mineral composition of Olduvai basin deposits,northern Tanzania

Quaternary deposits in the southeastern part of the Olduvai basin, northern Tanzania, consist of lake margin deposits, followed by a series of fluvial sediments. The clay mineral fraction of the lake margin deposits (Bed I and lower part of Bed II) is composed of smectite and subordinate illite. All smectite is largely dioctahedral and shows indications for a limited degree of irregular interstratification by illite. In the overlying fluvial deposits (Beds II–IV), illite is the most abundant clay mineral. Smectite only occurs in lower parts of the fluvial deposits (up to the middle of Bed III), where it generally shows a high degree of irregular interstratification. Differences in clay mineral composition between the lake margin deposits and the fluvial deposits record differences in sediment source area and degree of alteration. Dioctahedral smectite in the lake margin deposits and the oldest fluvial deposits is derived from a region with volcanic material extending to the east and south of the basin, which also supplies a certain amount of illite. Illite in the fluvial deposits of Bed IV originates from an area with a metamorphic bedrock to the west and north. Alteration of detrital clay minerals resulted in Mg-enrichment of dioctahedral smectite in part of the lake margin deposits and partial illitization of smectite in the older fluvial deposits. Formation of clay minerals during diagenesis or soil development is not documented by analysis of the total clay fraction.     

Illite-smectite Mixed-layer Minerals in the Alteration Volcanic Ashes under Submarine Environment

The clay mineralogy of the clay intervals interbedded with siliceous mudstones across the Permian-Triassic boundary (PTB) in Pengda, Guiyang, Guizhou province, was investigated by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The clay mineral assemblages of the sediments are mainly I/S clays and minor smectite, kaolinite, and illite as reveled by XRD analyses. The peak-shape parameters BB1 and BB2 of I/S clays of the representative clay bed PL-01 are 4.7° and 4.4°, and the peak position of the low angle reflection is at 6.8° 2θ (13.6 ), suggesting that the I/S clays has a IS type of ordering. However, the presence of multi-order reflections and their intensities are different from those of completely ordered 1∶1 mixed-layer I/S clay rectorite, indicating that I/S clays of the Pengda section have partially ordered IS structures. HRTEM observations show that most of the I/S clays exhibit an IS stacking ordering. However, in some areas within a IS particle, smectite layer is observed in doublets, triplets, and quartets, which are interstratified by various amounts of illite layers, suggesting the presence of other irregular stacking in addition to the major 1∶1 IS ordered stacking. Transformation of smectite layer into illite layers is also observed in the I/S clays, suggesting that the Pengda I/S clays are derived from smectite illitization, in good agreement with the clay mineral assemblage. The I/S clays of the Pengda section contain up to 45% to 95% smectite layer, the notably higher contents of smectite layer relative to those of other PTB stratigraphic sets in south China can be attributed to difference in alteration and smectite illitization processes due to different sedimentary environments.     

泥质岩成岩作用中的黏土矿物研究

文章通过对泥质岩的黏土质矿物组分、成岩作用中黏土质矿物变化综合研究,认为泥质岩中存在大量黏土矿物,且泥质沉积物由松散到固结成岩实质上是黏土矿物组成的变化。泥质岩中主要黏土矿物包括高岭石、蒙皂石、绿泥石、伊利石以及其组成的混层型矿物伊利石/蒙皂石、绿泥石/蒙皂石,其成岩过程可划分为成岩早期的压实阶段、成岩晚期的黏土矿物转化阶段。压实阶段的泥质沉积物中黏土矿物具有物源的继承性、沉积水体古环境指示意义;受压实作用孔隙水、层间水被排出,原生絮凝团被压破,使片状质点趋于平行排列,黏土矿物与孔隙水发生反应,亦形成少量的新生作用矿物,因而黏土矿物具继承源和新生作用源特性。成岩晚期阶段发生层间水释放及层间阳离子交换,从而使得矿物晶体结构与成分发生变化,主要表现为一元黏土矿物向二元混层型转化,最后再到一元型黏土矿物的转化,最终形成转变源黏土矿物。     

Rare earth element fractionation in authigenic illite–smectite from Late Permian clastic rocks,Bowen Basin,Australia: implications for physico-chemical environments of fluids during illitization

REE analyses were performed on authigenic illitic clay minerals from Late Permian mudrocks, sandstones and bentonites from the Bowen Basin (Australia). The mixed-layer illite–smectite exhibit REE patterns with an obvious fractionation of the HREE from the LREE and MREE, which is an apparent function of degree of illitization reaction. The highly illitic (R≥3) illite–smectite from the northern Bowen Basin show a depletion of LREE relative to the less illitic (R=0 and 1) clays. In contrast, an enrichment of HREE for the illite-rich clays relative to less illitic clays is evident for the southern Bowen Basin samples. The North American Shale Composite-normalized (La/Lu)_sn ratios show negative correlations with the illite content in illite–smectite and positive correlations with the δ¹⁸O values of the clays for both the northern and southern Bowen Basin samples. These correlations indicate that the increasing depletion of LREE in hydrothermal fluids is a function of increasing water/rock ratios in the northern Bowen Basin. Good negative correlations between (La/Lu)_sn ratios and illite content in illite–smectite from the southern Bowen Basin suggest the involvement of fluids with higher alkalinity and higher pH in low water/rock ratio conditions. Increasing HREE enrichment with δ¹⁸O decrease indicates the effect of increasing temperature at low water/rock ratios in the southern Bowen Basin.Results of the present study confirm the conclusions of some earlier studies suggesting that REE in illitic clay minerals are mobile and fractionated during illitization and that this fact should be considered in studies of sedimentary processes and in identifying provenance. Moreover, our results show that REE systematic of illitic clay minerals can be applied as an useful technique to gain information about physico-chemical conditions during thermal and fluid flow events in certain sedimentary basins.     

Clay mineral sedimentation in high northern latitude deep-sea basins since the Middle Miocene (ODP Leg 151, NAAG)

High-resolution clay mineralogical investigations and their comparison with other sedimentological data from ODP Sites 908 and 909 (central Fram Strait) were used to reconstruct the paleoclimate and paleoceanography in the high northern latitudes since the Middle Miocene. Ice rafting has probably occurred since 15 Ma. The comparison of sand-sized components and clay mineral distribution demonstrate that both were not delivered by the same transport process. The input of the clay fraction is related to transport through sea ice and/or oceanic currents. A provenance change at 11.2 Ma is indicated by variations within clay mineral distribution and increased accumulation rates. This is interpreted as a result of an increase in water mass exchange through the Fram Strait. Decreases of the smectite to illite and chlorite ratio at Site 909 suggest a Middle Miocene cooling phase between 14.8 and 14.6 Ma, and a further cooling phase between 10 and 9 Ma. The intensification of glaciation in the Northern Hemisphere is documented by an increase of illite and chlorite from 3.4 to 3.3 Ma, which is synchronous to the onset of major Northern Hemisphere glaciation as indicated by oxygen isotope data.     

Mineralogy of Holocene Sediments from the Southwestern Black Sea Shelf (Turkey) in Relation to Provenance, Sea-level and Current Regimes

Grain size and mineral composition of core sediments were used to investigate influences of various terrestrial and marine conditions, which have prevailed on the southwestern Black Sea shelf during the Holocene. Siliciclastic mud with small amounts of sand and gravel from nearby coastal hinterland is the principal sediment type, whereas sediments deposited near the shelf edge and the Istanbul Strait and off the Duru Lake （a paleo-river mouth） constitued large quantities of sand and gravel of both biogenic and terrigenic origin. Variable amounts of aragonite, 1 nmmicas, quartz, feldspars, calcite and dolomite constitute the dominant non-clay minerals in bulk sediments. The clay mineral assemblage in the 〈 2 μm fraction is made up of smectite, illite, kaolinite and chlorite. Aragonite and calcite are mainly derived from benthic accumulations, whereas feldspars （mainly plagioclase） and smectite reflect magmaticvolcanic provenance and the distribution of 1 nm-micas and chlorite correlate with nearby metamorphic sources onland. Nevertheless, grain size and mineral distribution generally indicate a combination of effects of wind and wave climate, longshore and offshore cyclonic currents, changing sea-level stands and nearby source rock and morphological conditions. It is also suggested that at least part of clay minerals could be derived from the northwesterly Danube River input.     

陆源沉积岩物源分析研究进展与发展趋势

 陆源沉积岩物源分析对于古地理重建、古环境与古气候恢复、沉积盆地分析、沉积矿产预测、大地构造背景分析及盆山耦合研究等均具有重要意义。在大量文献调研的基础上,本文总结了沉积学方法、岩石学方法、重矿物方法、元素地球化学方法、地质年代学方法、粘土矿物学方法、化石及生标化合物方法及地球物理学方法等传统的物源分析方法及其研究进展;并介绍了近年来出现的磁性矿物学方法、矿物颗粒微形貌分析等物源分析新方法。由此展望了物源分析的发展趋势:随着新技术新方法的不断涌现,物源分析将从传统方法向现代测试技术的转化,从单一方法到多方法的综合运用,从单一学科走向多学科联合交叉,从定性分析向定量分析发展。     

Late cainozoic environments of part of Northeastern South Australia∗

In the Lake Frome area of South Australia there is a sedimentary sequence of non‐marine (or possibly distant marginal marine) pale‐green to grey, fine elastics and carbonates (Namba Formation). The base of these deposits is Medial Miocene in age and they are overlain unconformably by Pleistocene (and ? Pliocene) sediments. The Miocene sequence is equivalent to the Etadunna Formation of the Lake Eyre Basin, and the clay mineralogy is similar.

Combining evidence from mineralogy, palynology, and vertebrate palaeontology, a warm high‐rainfall climate operating on a subdued topography is indicated for the lower part of the Miocene Lake Frome sequence. This caused the illite‐chlorite‐kaolinite suite of the largely Precambrian provenance to be transformed to smectite and randomly‐interstratified clay. A palygorskite‐dolomite assemblage accumulated in alkaline lakes of extreme marginal marine situation during periods of seasonal dry intervals superposed on the previous climate.

A change to illite‐dominated clay, stratigraphically about halfway up the sequence, occurred simultaneously with initial uplift of the Flinders Ranges. These ranges were previously represented by, at the most, a region of low hills. Uplift, without intervention of climatic change, is sufficient to alter the clay mineralogy by promoting increased leaching. Higher in the sequence, and correlated with the major phase of uplift in the Flinders Ranges, smectite re‐appears. In this case the clay suite is believed to have resulted from increased aridity. The smectite‐rich sediments accumulated above the water table in extensive fan and mud‐flow deposits.

The Neogene sequence records a major palaeogeographic change from low energy rivers, swamps, and lakes in a low relief terrain, probably connected to the sea, to a landscape approaching that of the present during Miocene‐Pliocene times. When the Pleistocene Millyera Formation accumulated, the landscape resembled the present, though the ancestral Lake Frome was larger, and rainfall higher.     

粘土矿物对有机质生烃的催化作用

烃源岩的有机质主要以有机粘土复合体的形式存在。有机质生烃是一种有机粘土化学反应。反应过程中,有机质与粘土之间存在质子和电子迁移,粘土通过对水分子的吸附和离解为有机质加氢裂解提供H+,而有机质生成的有机酸激活了粘土的催化活性,也为蒙皂石伊利石化反应创造了条件。烃源岩不同粘土矿物的选择性催化特征是影响油气组成的最重要因素。粘土的催化活性大小和发育时间是决定烃源岩生烃潜力大小的因素。由于烃源岩在蒙皂石伊利石化阶段具有最大的催化活性,而且与有机质生烃反应同步,因此富含伊$蒙混合层的烃源岩是世界含油气盆地的最有利烃源岩。不同地质时期的烃类地质储量与烃源岩膨胀性粘土的丰度有密切关系。