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1.
《Applied Geochemistry》2006,21(3):492-514
Geochemical mapping of northern Honshu in the Northeast Japan Arc was carried out using stream sediments at a sampling density of one sample per 130 km2. More than 50 elements were determined in 395 stream sediment samples (<0.18 mm fraction). In geochemical maps, areas with especially low concentrations of large ion lithophile elements (LILE), Be and Li widely overlap with the distribution of Quaternary volcanic rocks along the volcanic front. The areas rich in mafic elements are associated with mafic rocks in many cases. On a regional scale, Ni, Cr and Cu contents are higher in the eastern Paleozoic–Mesozoic basement zone, Pb and Tl tend to be higher on the western zones, and Zn and Cd are high in the western back-arc zone. The areas especially rich in Cu, Zn, Cd, Pb, Bi and Tl coincide with the distribution of large mineral deposits. High concentrations related to Kuroko, hydrothermal-vein, and skarn-type deposits are recognized. High values of As and Sb are related to active geothermal areas near volcanoes and ore deposits. Chemical variations of K, Ce, Th and Sn in the stream sediments are concordant with chemical variations in major rocks. The median and mean concentrations for the stream sediments in northern Honshu, showing arc signatures, are lower in Rb, Cs, Th, Li, K, Be, Ta, LREE, Ni, Hg and Sn, and higher in Sc, Ca and Cd relative to the whole area of Japan, largely because of the contribution of Cenozoic island-arc volcanic rocks that are generally poor in incompatible elements. The averaged chemical compositions of the stream sediments for the geologic zones show systematic variations of many elements. The contrasting variations of LREE and Th contents, which are lower in the zones of Cenozoic rocks relative to the zones of pre-Neogene basements, reflect the regional variations in the main rocks, and also reflect the change of geological settings of the studied area from the continental margin to an island arc during the Cenozoic.  相似文献   

2.
Geochemical mapping of Shikoku in the SW Japan Arc was conducted using stream sediments (<0.18 mm fraction) with sample densities of 1 site per 106 km2. Concentrations of 51 elements in 173 stream sediments were determined. Areas with especially high Cr, Ni, Mg and Co concentrations run intermittently and linearly through Shikoku, and coincide with exposures of the Mikabu greenstone complex composed of oceanic basaltic and gabbroic rocks with minor ultramafic bodies. Areas with higher concentrations of Fe, V, Sc, Ti, Mn, Cr, Ni, Mg, Co and Eu are distributed widely along the Shikoku Island axis; they mainly overlap with the zones of the high-pressure type metamorphic rocks (Sanbagawa Belt) and of the Jurassic accretionary complexes with sedimentary rocks (Chichibu Belt): in contrast, areas with lower concentrations spread over the northern coastal zone of Cretaceous granitoids (Ryoke Belt) and in the southern coastal zone of Cretaceous-Paleogene accretionary complexes (Shimanto Belt). Distribution patterns of these elements reflect that various amounts of mafic and ultramafic materials, possibly of oceanic origin, are associated with the rocks in the Sanbagawa and Chichibu Belts, although such components occur sparsely in the Shimanto and Ryoke Belts. Calcium, Sr, Na, Nb, Sm and Gd contents are lower along the southern coastal zone. High values of Th, U, La, Ce and Ba are associated with granitic rocks. The positive anomalies of Cu and Cd coincide with the distribution of stratabound Cu deposits in the Sanbagawa Belt. Positive anomalies of Sb in the northern area are associated with Sb deposits near the large Median Tectonic Line fault zone. A high-Hg zone is present in the southern fore-arc area. The median concentrations for stream sediments in Shikoku are higher in Hg, Cu, Ni, Cr, Rb, Li, Cs, K, slightly higher in Nb, Ta, La, Ce, Sn and lower in Ca than those for average Japanese stream sediments. The median concentrations for the four geologic zones show systematic wide variations of mafic associated elements, and narrow variations of lithophile elements generally more abundant in felsic rocks. The chemical compositions of the stream sediments in Shikoku largely reflect the concentrations in the pre-Neogene accretionary complexes and in the high-P metamorphic rocks mainly formed from clastic materials derived from continental margins, and ratios of mafic and ultramafic materials within surface rocks; they are partly influenced by sulfide mineralization and fluid migration.  相似文献   

3.
A geochemical soil survey was made over outcropping Cambrian and Lower Devonian formations in the Belgian Ardennes. About 300 soil samples were collected in an area of 2.5 × 1.1 km2.Analysis of rock samples from scarce, but stratigraphically well-known outcrops show that the Cambrian rocks are richer in copper than those of the Lower and Upper Gedinnian (Lower Devonian). The Upper Gedinnian rocks are more nickeliferous than the other horizons.In the well-drained soils, copper and lead distributions permit precise location of the boundary between Cambrian and Lower Gedinnian formations. The nickel distribution seems to be a good stratigraphic indicator for distinguishing Upper from Lower Gedinnian. Zinc distribution seems unrelated to underlying bedrock geology.Regression analysis confirms that the content of Cu, Pb and Ni is essentially a function of lithostratigraphy. However, the distribution of these elements is more influenced by pedological factors in the poorly drained soils.  相似文献   

4.
《Applied Geochemistry》2006,21(3):419-436
Geochemical maps expressing areal distributions of chemical elements in the earth’s land surface have been published in several countries in relation to various global environment issues. The authors have applied a radiogenic isotope ratio, 87Sr/86Sr, to geochemical mapping in order to understand the geological origin, transportation and dispersion system of chemical elements in the earth’s land surface. The Sr isotope ratio is a useful tracer for distinguishing the geological origin of surficial deposits, especially in areas where surface exposure of bedrocks is low, because it is not significantly altered by the processes of weathering and transportation. Most bedrocks in the Japanese islands are covered by plants, soils and urban areas. In this study, 142 of 1219 stream sediments (<180 μm) collected from the northeastern part of Aichi Prefecture, in the central part of Japan (75 km × 30 km), were analyzed. Their Sr isotope ratios range from 0.7086 to 0.7315 with an average of 0.7129, except for one sample. This average is higher than the mean of the upper crust of the Japan Arc (the Japanese Island Crustal Composite, JICC), 0.7077. This difference can be attributed to the below-average presence of young volcanic rocks, generally having lower 87Sr/86Sr values, and the above-average presence of granitic rocks, in the study area compared with the surface exposure of the Japan Arc. The first factor controlling the distribution of Sr isotope ratios is the bedrock distributed around the sampling points. Regional variation in the 87Sr/86Sr value shows that it is higher in the western and southeastern parts, where sedimentary rocks and metamorphic rocks are distributed, and that it is lower mainly in the central part, where granitic rocks are distributed. The 87Rb/86Sr–87Sr/86Sr plot for stream sediments more clearly reveals the differences and similarities of bedrocks. In some locations, the distribution of Sr isotope ratios does not correspond to that of bedrocks on the geological map. One reason is the existence of unmapped bedrock, for example, small intrusive masses of granite. The other is fluvial transportation and dispersion. The distribution of the isotope ratios suggests that some stream sediments include surficial deposits from a few km upstream. Application of the Sr isotope ratio to geochemical mapping is useful for revealing both the distribution of unexposed bedrocks and the transportation of surficial deposits. Information on unexposed bedrocks will be expected to contribute to the improvement of geological mapping.  相似文献   

5.
西藏多格错仁南岸钙华地球化学特征与钾盐地质意义   总被引:2,自引:0,他引:2  
西藏多格错仁南岸地区发育有一系列正在沉积的钙华丘和盐泉,泉水具有较高的含钾异常,属于含钾溶滤卤水,因此确定泉水中的矿物质来源成为找钾的关键问题,研究钙华的地球化学特征和成因机制则有助于解决这一问题。区内钙华有原地钙华和碎屑钙华两种类型,且明显富集K、Fe等元素,具有明显的轻稀土富集特征。不同泉眼周围的钙华样品的稀土分配模式基本相同,表明区内钙华的钙物质具有同一来源层位。经过将钙华与区内主要地层的稀土元素特征进行比对,发现这些钙华和索瓦组具有明显的亲缘关系,针对两者的相关性分析也再次表明钙华和索瓦组的亲缘特征。在此基础上,结合区内古地理和古气候资料,认为索瓦组具有较好的找钾潜力。此外,盐泉和钙华的碳、氢、氧同位素数据说明,盐泉的水物质属于大气降水,形成钙华的CO2则具有深部来源特征,研究区的钙华属热成因钙华。  相似文献   

6.
7.
福建太姥山位于中国东南沿海地带,是晚中生代太平洋板块与欧亚板块相互作用的重要地区。野外和岩相学分析表明该地区花岗岩岩类分布广泛,岩性以钾长花岗岩为主。岩石中发育典型的显微文象结构,缺少暗色矿物。岩石具高硅、富碱、贫钙镁和高分异指数等特点,属高钾钙碱性系列和准铝质-弱过铝质花岗岩类。岩石稀土元素含量较高,配分模式呈轻稀土富集并缓向右倾斜、重稀土较为平坦、呈明显铕负异常的海鸥型展布;多数花岗岩具有Rb、U、Th、La等元素强烈富集而Ba、Sr、P、Ti等元素相对亏损的特点。锆石LA-ICP-MSU-Pb同位素定年结果表明,太姥山地区花岗岩的成岩年龄为96.6±1.6Ma(MSWD=0.65),属燕山晚期岩浆活动的产物。岩石学、岩相学和地球化学特征均表明太姥山地区花岗岩属于A型花岗岩范畴。其岩浆来源为地壳物质的部分熔融,并可能有少量地幔物质的加入。结合多组地球化学图解、野外地质和区域背景及年代学判定该地区花岗岩形成于后碰撞的伸展构造环境。在早、晚白垩世之交,中国东南大陆边缘处于不断伸展之中,导致大量的构造-岩浆活动,太姥山地区A型花岗岩正是在这样的背景下形成的。  相似文献   

8.
内蒙古贝力克玄武岩地球化学特征及地质意义   总被引:3,自引:2,他引:3  
内蒙贝力克地区存在一片面积为400km2、以发育三级熔岩台地为特征的新生代玄武岩,台地时代分别为2.31 ~2.41Ma、1.56~1.61Ma、0.51~0.61Ma.岩性为具有过渡性质的拉斑玄武岩,分为石英拉斑玄武岩与橄榄拉斑玄武岩,它们都起源于具有交代性质的石榴石橄榄岩源区.地球化学特征显示这两种岩性之间没有演化关系,而是源区不同程度、深度部分熔融的结果;并且在上升过程中,都受到下地壳麻粒岩的混染作用,其中石英拉斑玄武岩混染程度最大.大地构造背景上,贝力克与赤峰同处在兴蒙造山带南缘,它们表现出与华北西部北缘(集宁、大同、汉诺坝、繁峙)相似的岩浆源区和岩石圈地幔热状态,但不同的富集岩石圈地幔类型,即兴蒙造山带南源呈现DMM-EMⅡ特点,而华北西部北缘具有DMM-EM Ⅰ混合趋势.这种差异可能与岩石圈地幔不同的时代及构造背景有关.在软流圈熔体与上覆岩石圈地幔相互反应的拉斑玄武岩成因模式基础上,认为华北岩石圈减薄现象不仅局限于克拉通内部,其处在克拉通西北部,乃至兴蒙造山带南缘也同样经历了岩石圈减薄过程,只是存在不同时间、程度的岩石圈减薄过程.  相似文献   

9.
郑岩  杨言辰  韩世炯  杨宇 《世界地质》2017,36(3):785-795
石榴云母片岩是高家堡子银矿区重要的容矿围岩。岩石地球化学分析显示,石榴云母片岩具有副变质岩特征,富集大离子亲石元素(Th,K),亏损高场强元素(Nb,Ta,Ti),稀土元素总量较高(ΣREE均值169.28×10~(-6)),轻、重稀土元素分馏明显,轻稀土元素富集,具有δCe弱正异常,δEu中等负异常。野外观察结合地球化学特征研究,高家堡子银矿区石榴云母片岩原岩为泥岩、砂岩、杂砂岩,具有上地壳长英质物源特征,形成环境为被动大陆边缘环境。  相似文献   

10.
根据文献报导及作者的研究,分别对Sedex型铅锌矿床、浅成低温热液金矿床、岩浆期后高温热液型石英脉状黑钨矿矿床和沉积岩为主岩的微细浸染型(卡林型)金矿床进行了矿床地球化学分类:Sedex型铅锌矿床分为Selwyn型矿床和McArthur型矿床,前者的成矿热卤水产生于开阔海盆或大陆斜坡的浊积岩建造,后者的成矿热卤水产生于氧化的海底裂谷沉积建造,浅成低温热液型金矿床分为酸性-硫酸盐型(明矾石-高岭石型)金矿床和冰长石-绢云母型金矿床,前一类金矿床的成矿流体,f(S2)和f(O2)较高,pH值较低,后一类金矿床的成矿流体,f(S2)和f(O2)较低,pH值较高.岩浆期后高温热液型石英脉状黑钨矿矿床分为钨-铍-钼-铋型黑钨矿矿床和钨-锡-硫化物型黑钨矿矿床,钨-铍-钼-铋型黑钨矿矿床的成矿作用是在pH值较高的弱碱性、Eh值较高的环境中进行的,钨-锡-硫化物型黑钨矿床的成矿作用是在pH值较低的弱酸性的,Eh值较低的环境中进行的.沉积岩为主岩的微细浸染型(卡林型)金矿床分为金-砷-(锑)型金矿床、金-汞-(铊)型金矿床和金-锑-黄铁矿型金矿床.金-砷-(锑)型金矿床的成矿流体是地层建造水(为主)与改造后的大气降水混合形成的热液,其pH值为3.6~5.2,且Eh值较低;金-汞-(铊)型金矿床的成矿流体是大气降水与地层建造水混合形成的热液,其pH值为5.0~7.5,Eh值较高;金-锑-黄铁矿金矿床的成矿流体是改造后的大气降水与岩浆演化成的流体混合形成的热液,其pH值为5.4~6.77,Eh值较高.  相似文献   

11.
针对双江701和凤庆901铀矿点,对临沧地区富铀花岗岩体进行岩相学、地球化学和U-Pb定年研究,旨在探讨岩石成因类型、成岩构造背景与铀成矿的关系。结果表明:临沧富铀花岗岩体具有高硅(最高达90.11%,平均含量71.6%)、富碱、高钾、高钙特征,属于强过铝质、高钾钙碱性系列岩石。U-Pb锆石定年结论为214±12 Ma,表明临沧富铀花岗岩体形成于印支晚期。稀土元素呈微右倾"V"字形,轻、重稀土分馏明显(w(LREE)/w(HREE)平均为7.26),Eu负异常明显(δEu=0.28~0.49),相对富集Rb、U、Th,相对亏损Ba、Nb、Sr、Ti和Eu。综合分析认为,临沧富铀花岗岩属于分异明显的S型花岗岩,源于上地壳物质熔融,形成于碰撞后期造山环境之中,属于S澜沧江碰撞带有关的同碰撞花岗岩,其高含量的铀为铀成矿过程提供了部分铀源,铀元素经过淋滤作用被搬运到断层破碎带附近富集形成花岗岩型铀矿。  相似文献   

12.
为探讨夏甸金矿床不同元素的地球化学成矿行为,本次以夏甸金矿床外围花岗岩、构造碎裂岩和金矿石的主微量和稀土元素地球化学资料为依据,研究其化学成分、微量元素和稀土元素在不同岩矿石中丰减富集变化及成矿过程.在化学成分方面,招平断裂带碎裂岩中具有较高的SiO2、K2 O值,Fe2 O3、Na2 O、CaO降幅较多,反映了成矿阶...  相似文献   

13.
四川红原地区三叠纪花岗岩的地球化学特征及地质意义   总被引:1,自引:0,他引:1  
红原地区三叠纪花岗岩位于松潘-甘孜造山带的北部,侵位于三叠纪西康群砂板岩系中,岩石类型主要为中细粒花岗闪长岩和二长花岗岩。岩石地球化学分析结果表明该区岩体属于准铝质-过铝质富钾钙碱性系列,大部分为I型花岗岩(羊拱海和达盖寨岩体部分表现为A型),稀土元素总量变化较大,轻稀土元素相对富集,稀土元素球粒陨石标准化配分型式为右倾型,Eu异常不明显。轻重稀土元素分馏明显,轻稀土元素分镏大于重稀土元素。岩石地球化学特征指示该区花岗岩体可能为同源的地壳物质的部分熔融作用所形成,源岩可能为变杂砂岩和变中性火山岩,热源可能来自于地幔岩浆的底侵作用。  相似文献   

14.
Geochemical maps can provide us with much information on geology, earth surface processes and anthropogenic pressure and are valuable tools for ore prospecting and land management. Stream sediments represent an integral of the various possible sources of sediments upstream from the sampling point therefore there can be multiple signal sources but generally the prevailing signal source is the one related to bedrock geology. Stream sediments collected from active second-order channels including singular geological units, were selected in order to determine the geochemical characteristics of each unit. The aim of this study was to analyze their potential for using them to integrate geological interpretation and produce a geologically-oriented geochemical map. From the 770 samples collected for a regional geochemical mapping program, we selected 149 samples whose catchment basin included only one of the members recognized within the Marnoso-arenacea formation. This middle–upper Miocene (Langhian–Tortonian) turbiditic unit forms the backbone of the Romagna Apennines and has been subdivided into 14 members according to age and lithostratigraphic criteria. The results indicate that there are marked differences in the composition of the members of the Marnoso arenecea formation which indicate the provenance of the sediment and the palaeogeographic evolution of the units. By means of univariate and multivariate statistical analyses (Factor analyzes) two main types of sediment compositions are identified: Tortonian members are characterized by sialic coarse grain-sediments while the Langhian–Serravallian members are richer in carbonate fraction, slightly enriched in a mafic contribution. This study elaborated the geochemical data from a geological point of view by integrating the information available in literature to spatially extend the interpretation based on limited site observation as for petrographic studies. In general, the geochemical map based on a geological unit could be a useful tool for carrying out the geological reconstruction of a complex area.  相似文献   

15.
河南经山寺铁矿床位于华北板块南缘,矿体形态为似层状和透镜状,铁建造以条带状铁矿石为主,含有少量的块状矿石,其顶、底板围岩及矿体夹层主要为太华群铁山庙组大理岩。矿床地球化学分析结果表明,本区条带状铁建造是与海相火山沉积有关的前寒武纪火山沉积变质型铁矿。Sr/Ba平均值20.55,Ti/V平均值104.24,Ni/Co平均值2.31,Y/Ho平均值62.67,具La的正异常(La/La*=0.807~1.564),Eu的正异常(Eu/Eu*=1.246~2.821),Y的正异常(Y/Y*=2.426~3.310),反映出经山寺条带状铁矿床形成于火山热液和海水混合的环境。极低的Zr、Hf、Th含量,表明陆源碎屑物质对BIF的贡献极少。无明显Ce负异常(Ce/Ce*=0.809~0.955),揭示条带状铁建造沉积于海水缺氧环境。流体包裹体均一温度主要集中在150~320℃,成矿流体具有低盐度〔w(NaCleq)=2.07%~18.80%〕、低密度(0.846~0.979 g/cm3)特征,流体包裹体成分显示成矿热液是一种低盐度的Na+、Cl-型水,并含有较高的CO2。经山寺铁矿床经历了海底火山喷流沉积和区域变质作用2个成矿期,成矿流体具多源性,且发生过强烈的不混溶作用,影响铁质发生进一步的迁移和富集。  相似文献   

16.
对杭州湘湖剖面高密度连续采集的样品,分析了Fe2O3、FeO、TiO2、C2CO3、Al2O3及Fe2O3/FeO比值的高分辨记录,发现它们对全新世的重要地层界面都有较清晰的反映,同时揭示了不同沉积环境下地球化学背景值存在显著的差异。运用Fe^2 /Fe^2 与年平均温度的关系式推算了各样品点的古温度值,并结合多种地球化学指标、^14C测年结果以及岩性岩相组合特征,将湘湖地区全新世早、中期(10-3ka B.P.)初步划分为4个气候发展阶段,并指出7.5~5.1 ka B.P之间为本区的全新世气候适宜期。  相似文献   

17.
攀枝花二叠纪火山岩发育有玄武岩和粗面岩的基性和碱性两个端元,区域上明显缺失中间过渡类型。玄武岩SiO_2含量处于45.65%~49.32%范围内,粗面岩SiO_2含量介于64.39%~69.17%之间,构成经典的"双峰式"火山岩特征组合。两者均具有富Na、贫K、轻稀土富集、轻重稀土明显分馏的特征。特征微量元素Nb/Ta、Th/Ta、Th/U比值变化相对较小,玄武岩分别为15.16、2.70和4.13,粗面岩分别为15.40、2.55和4.12,显示两者具有相似的地球化学属性。微量元素特征显示,除了Ti和Y等少数高场强元素不协调以外,玄武岩与粗面岩绝大多数微量元素变化规律相似,且Rb、Ce、Y、Nb、Hf、Ta等元素与洋岛玄武岩(OIB)特征一致,说明它们具有地幔柱构造系统下的岩浆属性,岩浆源于石榴石二辉橄榄岩岩石圈地幔的部分熔融。结合前人资料,攀枝花二叠纪双峰式火山岩的厘定,不仅暗示了岩浆形成于拉张的裂谷构造环境,也为西南地区二叠纪峨眉山大火成岩地幔柱成因提供支撑。  相似文献   

18.
张越  陈隽璐  孙吉明  唐卓  李平  白建科 《地质通报》2019,38(9):1431-1442
阿尔曼太蛇绿岩带位于新疆东准噶尔地区,蛇绿岩中变质橄榄岩、堆晶岩、基性火山岩较发育,层序组合虽受构造破坏,但从总体来看仍是一套组合比较完整的蛇绿岩,岩石变形变质强烈,普遍发生绿泥石化、绿帘石化。蛇绿岩中基性熔岩可分为3种类型,即洋岛玄武岩(OIB)、洋中脊玄武岩(MORB)和岛弧玄武岩(IAT)。其中洋岛玄武岩不属于蛇绿岩成分,是后期卷入蛇绿岩带随其他组分一同构造就位而成;基性熔岩主量和微量元素特征揭示岩浆源于亏损的地幔源区,且存在消减组分加入的交代作用,表明其成因与俯冲作用有关。结合岩石地球化学特征和构造环境判别图解,基性熔岩显示出IAT和MORB兼具并呈现过渡的特点,推断该蛇绿岩的形成与岛弧相关,其形成可能介于洋脊到海沟之间的偏海沟区域。  相似文献   

19.
席振 《地质与勘探》2023,59(3):664-677
安托尼奥(Antonio)铁矿位于秘鲁中东部阿普里马克(Apurimac)始新世-渐新世斑岩-矽卡岩型铜-钼(铁-金)成矿带,矿体的空间展布受到安达胡拉斯-雅乌里(Andahuaylas-Yauri)岩基岩石与弗若巴木巴(Ferrobamba)组碳酸盐岩的接触带控制。矿区花岗闪长岩具有高硅和钠,低铁、镁和钙的特征,铝饱和指数(A/CNK)为0.92~0.99,富集Rb、Ba、K、Sr等大离子亲石元素和活泼不相容元素,亏损Nb、Ti、P等高场强(HFSE)元素,表现出准铝质I型花岗岩的特征。结合区域构造演化认为,花岗闪长岩为幔源镁铁质岩浆结晶分异,可能有俯冲洋壳与下地壳部分熔体物质参与,形成于纳兹卡(Nazca)大洋板片低角度俯冲到南美大陆板块之下的挤压背景向拉伸背景过渡时期。动力背景的转变有利于区域大量斑岩型及相伴生的热液型、矽卡岩型矿化的形成。结合矿区地球物理勘查结果,安托尼奥出露的多个铁矿体在矿区深部合并为一个矿体,向南西侧倾伏延深,并可能有其他类型矿体(矿石)出现。  相似文献   

20.
黑龙江东风沟金矿赋矿岩石地球化学特征及其地质意义   总被引:1,自引:0,他引:1  
东风沟金矿床位于东宁县老黑山晚古生代断陷盆地内。围岩蚀变类型主要为硅化、碳酸盐化、绢云母化和绿泥石化。赋矿岩石地球化学研究表明,赋矿岩石主要为一套英安质、流纹质火山岩,属于高硅、低碱钙碱性系列岩石(σ3.3)。Rb、Ba、K、Pb等大离子亲石元素(LILE)相对富集,Nb、Ta、P、Ti等高场强元素(HFSE)相对亏损;轻稀土元素(LREE)相对重稀土元素(HREE)轻度富集。Nb/Ta值(平均14.7)和Zr/Hf值(26.23~38.37)显示岩浆具有壳源特征,形成于与俯冲带有关的陆缘环境,与库拉板块俯冲关系密切。  相似文献   

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