Compositional Variation and Mineral Chemistry of Jinshajiang and Lancangjiang Serpentinites, Yunnan Province, SW China

<正>We present the whole-rock and the mineral chemical data for upper mantle peridotites from the San-Jiang region in Yunnan Province,SW China.These peridotites are part of a Paleo-Tethyan ophiolite belt occurring along the Jinshajiang and Lancangjiang suture zones.All samples of Jinshajiang and Lancangjiang ultramafic rocks are     

滇西北金沙江古特提斯洋早期演化时限及其性质:东竹林层状辉长岩锆石U-Pb年龄及Hf同位素约束

滇西北金沙江蛇绿岩带是古特提斯最重要的缝合带记录之一,本文对该带内的东竹林层状辉长岩进行了年代学、岩石地球化学及锆石Hf同位素研究。LA-ICP-MS锆石U-Pb测年结果显示东竹林层状辉长岩形成于354±3Ma,表明金沙江古特提斯洋在早石炭世已扩张形成洋壳,暗示其裂解时期应为更早的泥盆纪。单颗粒锆石原位Hf同位素分析得到东竹林层状辉长岩锆石ε_Hf(t)=10.3～12.6,平均值为11.5,明显低于结晶时亏损地幔值;单阶段亏损地幔Hf模式年龄t_DM1为478～576Ma,平均值为523Ma,明显大于成岩年龄354Ma。锆石Hf同位素结果显示金沙江古特提斯洋地幔受到了富集组分的影响。岩石微量元素特征显示富集组分可能来自特提斯连续演化过程中早期的俯冲作用带入的壳源物质。结合区域演化特征,认为金沙江古特提斯洋是在弧后盆地基础上发展起来的洋盆,它不能构成古特提斯的主大洋,而是古特提斯洋的一个重要分支,分隔着中咱-中甸地块与昌都-思茅地块。     

滇川西部金沙江石炭纪蛇绿岩SHRIMP测年:古特提斯洋壳演化的同位素年代学制约

本文应用SHRIMP方法精确测定了金沙江蛇绿岩带中蛇绿岩的辉长岩和斜长岩、呈脉状产于辉长岩和变质橄橄岩中的斜长花岗岩、以及呈岩株状侵入蛇绿岩中的花岗闪长岩的锆石U-Pb年龄,提供了古特提斯洋壳演化的年代学制约。滇西之用层状角闪辉长岩的年龄为328±8Ma,书松斜长岩为329±7Ma,白马雪山辉长岩为282～285Ma,它们可能反映了海底扩张不同阶段的时代。研究还表明,在这些辉长岩和斜长岩中,部分锆石记录了375～352Ma的略老的年龄,暗示蛇绿岩浆活动可能始于晚泥盆世。在金沙江蛇绿岩中,滇西娘九丁斜长花岗岩和川西雪堆斜长花岗岩,具有高硅低钾的成分特征。但是,这些岩石的REE总量高,LREE富集;Sr初始值高,达0.7058～0.7070;在其锆石组成中,存在继承锆石。这些证据表明斜长花岗岩中存在陆壳物质的混染,可能与洋壳俯冲消减有关。娘九丁斜长花岗岩的年龄为285±6Ma,雪堆斜长花岗岩为300±5Ma,记录了古特提斯洋壳俯冲消减事件。滇西吉义独花岗闪长岩,呈岩株状侵入蛇绿岩中,年龄为263±6Ma,限定了蛇绿混杂岩的年代上限。     

金沙江河谷巧家段地下水化学特征

金沙江河谷巧家段地形切割强烈,最大相对高差可达2 719 m,水文地质条件差异大,河谷区内泉水出露众多。对河谷区内38组泉水水化学组分进行分析的结果表明:地下水化学类型较简单,主要为HCO3- Ca、HCO3- Ca?Mg、HCO3- Mg?Ca型;地下水溶解性总固体(TDS)浓度变化较大,总体上TDS浓度自河谷斜坡补给-径流区至谷底排泄区,具有逐步增高的趋势;孔隙水TDS浓度明显高于岩溶水;地下水宏量组分HCO3-、Ca2+、Mg2+、SO42-与TDS具有正相关关系。据水化学组分变化分析谷底第四系地层中出露大泉的形成条件,其为孔隙水与岩溶水相混合形成。      

Naquite,FeSi, a New Mineral Species from Luobusha,Tibet, Western China

A new mineral species, named naquite(FeSi), is found in the podiform chromitites of the Luobusha ophiolite in Qusong County, Tibet, China. The detailed composition is Fe 65.65, Si 32.57 and Al 1.78 wt%. The mineral is cubic, space group P213. The irregular crystals range from 15 to 50 μm in diameter and form an intergrowth with luobusaite. Naquite is steel grey in color, opaque, with a metallic lustre and gives a grayish-black streak. The mineral is brittle, has a conchoidal fracture and no apparent cleavage. The estimated Mohs hardness is 6.5, and the calculated density is 6.128 g/cm3. Unit-cell parameters are a 4.486 (4) ?, V 90.28 (6) ?3, Z=4. The five strongest powder diffraction lines [d in ? (hkl) (I/I0)] are: 3.1742 (110) (40), 2.5917(111) (43), 2.0076 (210) (100), 1.8307 (211) (65), and 1.1990 (321) (36). Originally called ‘fersilicite’, the species and new name have now been approved by the CNMNC (IMA 2010–010).     

Platinum-group Mineral (PGM) and Base-metal Sulphide (BMS) Inclusions in Chromitites of the Zedang Ophiolite, Southern Tibet, China and their Petrogenetic Significance

Voluminous platinum-group mineral(PGM) inclusions including erlichmanite(Os,Ru)S_2, laurite(Ru,Os)S_2, and irarsite(Ir,Os,Ru,Rh)As S, as well as native osmium Os(Ir) and inclusions of base metal sulphides(BMS), including millerite(NiS), heazlewoodite(Ni_3S_2), covellite(CuS) and digenite(Cu_3S_2), accompanied by native iron, have been identified in chromitites of the Zedang ophiolite, Tibet. The PGMs occur as both inclusions in magnesiochromite grains and as small interstitial granules between them; most are less than 10 μm in size and vary in shape from euhedral to anhedral. They occur either as single or composite(biphase or polyphase) grains composed solely of PGM, or PGM associated with silicate grains. Os-, Ir-, and Ru-rich PGMs are the common species and Pt-, Pd-, and Rh-rich varieties have not been identified. Sulfur fugacity and temperature appear to be the main factors that controlled the PGE mineralogy during crystallization of the host chromitite in the upper mantle. If the activity of chalcogenides(such as S, and As) is low, PGE clusters will remain suspended in the silicate melt until they can coalesce to form alloys. Under appropriate conditions of ?S_2 and ?O_2, PGE alloys might react with the melt to form sulfides-sulfarsenides. Thus, we suggest that the Os, Ir and Ru metallic clusters and alloys in the Zedang chromitites crystallized first under high temperature and low ?S_2, followed by crystallization of sulphides of the laurite-erlichmanite, solid-solution series as the magma cooled and ?S_2 increased. The abundance of primary BMS in the chromitites suggests that ?S_2 reached relatively high values during the final stages of magnesiochromite crystallization. The diversity of the PGE minerals, in combination with differences in the petrological characteristics of the magnesiochromites, suggest different degrees of partial melting, perhaps at different depths in the mantle. The estimated parental magma composition suggests formation in a suprasubduction zone environment, perhaps in a forearc.     

Possible correlation between a mantle plume and the evolution of Paleo-Tethys Jinshajiang Ocean: Evidence from a volcanic rifted margin in the Xiaru-Tuoding area, Yunnan, SW China

Several Paleozoic sutures in Southwestern China provide a record of the history of the Paleo-Tethys Ocean, whose birth and final closure are associated with the breakup and assembly of Gondwanaland. Recent studies indicate that there are widespread OIB-type mafic volcanic rocks within these suture zones and intervening terranes. This paper examines the geology and geochemistry of volcanic rocks in the Xiaruo-Tuoding area, a remnant passive margin succession of the Jinshajiang Paleo-Tethyan Ocean. The sedimentary and volcanic stratigraphy of this area is interpreted as a seaward dipping margin with a few continentward dipping normal faults. The available geochemistry of these volcanic rocks suggest that they are OIB-like basalts, characterised by SiO₂ = 42.78–50.46 wt.%, high TiO₂ contents (TiO₂ = 2.2–3.55 wt.%), moderate MgO = 4.15–6.49 wt.%, Mg# = 0.37–0.50, high Ti/Y ratios (mostly > 450), large ion lithosphere elements enrichment, high strength field elements and rare earth elements, with La/Nb = 1.04–1.39, Ce/Yb = 18.38–30, Sm/Yb = 2.16–3.52, (⁸⁷Sr/⁸⁶Sr)i = 0.705350–0.707867, and Nd(t) = − 1.43–1.90. These geochemical and isotopic signatures are generally similar to those of the Emeishan flood basalts, which together with stratigraphic constraints, demonstrate that these volcanics were formed in a volcanic rifted margin, probably associated with a mantle plume. A new model is proposed to interpret the evolution of the Jinshajiang Paleo-Tethyan Ocean and its possible relationship to the Emeishan mantle plume. In this model, we argue that the opening of the Jinshajiang Paleo-Tethyan Ocean in the Carboniferous was caused by a mantle plume. The mantle plume was active to the east along the western margin of the Yangtze Craton between 300 and 260 Ma, from which the voluminous Emeishan flood basalts were erupted at 260 Ma. The closure of the Jinshajiang Ocean occurred since the Middle Permian. Continuous westward subduction generated the Jiangda-Weixi magmatic arc to the west of the Jinshajiang suture. This subduction also partly destroyed and/or tectonically sliced the volcanic rifted margin. Some seaward dipping volcanic-sedimentary sequences on the east flank of the Jinshajiang Ocean were preserved, but are strongly deformed.     

Stratigraphic Sequence and Tectonic Evolution of Passive Continental Margin of Jinshajiang Belt in Northwestern Yunnan,China

GeotectonicallytheJinshajiangbeltliesbetweenQamdoandZhongzanmassifsandbelongstoapartoftheSanjiangPaleotethysianorogenicbelt(Liuetal.,l993).Geographi-callyitissituatedinthewestpartsofYunnanandSichuan,andextendslongitudinallyfromBatang,Derong,DeqintoShigu.Intheearly198Os,geologicalinvestigationwasmakeinthisareaaccordingtoascaleofl:2oOOOobyYunnanBu-reauofGeologyandMinerals.Thestrataofthisareaaresys-tematicallyresearched,andthelithostratigraphicalunitsandregionalstratigraphicalframeworkoft…     

三江地区澜沧江带南段南林山基性岩体锆石U-Pb年龄及岩石地球化学特征

南林山基性岩体位于西南三江地区,岩体主要由辉长岩和闪长岩组成。通过ID-TIMS锆石U-Pb年代学方法对南林山岩体中闪长岩进行精确定年,获得其结晶年龄为（298.44±0.33）Ma,表明南林山基性岩体的形成时代为早二叠世。全岩主量、微量元素与稀土元素等研究表明,辉长岩和闪长岩总体上均呈现轻稀土元素（LREEs）相对于...     

澜沧江缝合带吉岔蛇纹岩中闪长岩和俄咱辉长岩中锆石SHRIMP U-Pb定年及其地质意义

白济汛镁铁-超镁铁岩由吉岔蛇纹岩和俄咱辉长岩岩块组成,属澜沧江缝合带中的蛇绿岩块体.锆石SHRIMPU-Pb年龄测定表明,吉岔蛇纹岩(＞297Na)和俄咱辉长岩(303Ma)与金沙江缝合带中蛇绿岩的形成时间(300～294Ma)一致.说明金沙江缝合带和澜沧江缝带中的蛇绿岩,同为三江地区古特提斯洋盆扩张期形成的洋壳残片.     

三江地区澜沧江带南段半坡杂岩体锆石U-Pb年龄、岩石地球化学特征及板块构造环境

半坡杂岩体位于滇西澜沧江构造岩浆带南段,岩体主要由橄榄岩、辉石岩、辉长岩和辉长闪长岩等镁铁 超镁铁质岩组成。通过ID-TIMS锆石U-Pb年代学方法对半坡杂岩体中辉长闪长岩进行精确定年,获得其结晶年龄为(294.9±2.6) Ma,表明半坡杂岩体的形成时代为早二叠世。半坡杂岩体中不同类型岩石微量元素、稀土元素和同位素组成相似,均呈现轻稀土元素(LREEs)相对于重稀土元素(HREEs)弱到中等富集,高场强元素Nb、Ta、Zr和Hf相对亏损的特征,εNd(t=295 Ma)为正值,在+3.4~+6.6,接近亏损地幔值,这些特征与典型的大洋岛弧玄武岩的特征相似。混合计算表明,半坡杂岩体母岩浆为地幔楔部分熔融,加上约2%~7%源于大洋俯冲沉积物的富硅熔浆和蚀变洋壳流体形成的岛弧玄武质岩浆。上述年龄和同位素数据提供了早二叠世早期南澜沧江地区洋内俯冲的可靠证据。     

滇川西部金沙江古特提斯洋的威尔逊旋回

本文对滇川西部金沙江造山带被动大陆边缘、蛇绿岩、洋盆相放射虫硅质岩、岛弧岩浆岩和造山磨拉石建造的形成时代进行了综合研究,结合古生物化石和SHRIMP年龄,论证了金沙江古特提斯洋盆的威尔逊旋回,即大陆裂解(晚泥盆世)、洋盆扩张(石炭纪)、俯冲消减(二叠纪)和碰撞造山(三叠纪)。金沙江洋是滇川西部古特提斯多岛洋中重要的支洋盆。     

云南鸡街碱性超基性岩杂岩体中橄榄石的矿物化学

分析了云南鸡街碱性超基性岩杂岩体主体岩石及包体中橄榄石矿物的化学成分。结果显示,不同类型岩石中橄榄石的矿物化学成分之间具有较好的线性关系;橄榄辉石岩包体中橄榄石的Fo值最高,其亚种属靠近镁橄榄石端元的贵橄榄石;从霞霓钠辉岩→霓霞岩→磷霞岩,橄榄石的Fo值逐渐降低,其亚种从靠近镁橄榄石端元的贵橄榄石→靠近透铁橄榄石端元的贵橄榄石→低铁镁铁橄榄石。这些特征表明,本区三类主体岩石为岩浆结晶分异作用的产物;橄榄辉石岩包体为Ⅱ类包体,可能为杂岩体原始岩浆早期结晶分异作用所形成的堆积岩碎块。     

滇西澜沧江构造带南段沙乐花岗岩的锆石U-Pb年龄、地球化学特征及其地质意义

沙乐花岗岩位于滇西思茅地块南涧县南西沙乐乡一带,主要由黑云母二长花岗岩和花岗闪长岩组成,被少量正长斑岩侵入。LA-ICP-MS锆石U-Pb测年得出黑云母二长花岗岩的形成年龄为246.4±2.6 Ma,花岗闪长岩的形成年龄为245.7±3.6Ma,表明该花岗岩体的形成时代属于早三叠世。岩石SiO₂含量71.44%~76.39%,Al₂O₃含量12.72%~16.15%,K₂O/Na₂O=0.1~1.30,均属高钾钙碱性过铝-强过铝花岗岩。根据地球化学特征和微量元素构造判别图解,样品点主要落入“火山弧花岗岩”、“板内花岗岩”区域,少量落入“碰撞花岗岩”区域,表明其形成于俯冲-碰撞岩浆弧转换环境。在Sr-Yb花岗岩分类图解中,主要属常见的低Sr高Yb花岗岩,少数样品属低Sr低Yb花岗岩,其物质来源为含砂质的变质泥质岩。结合锆石定年结果及岩体产出的区域地质背景,认为沙乐花岗岩形成于缅泰马陆块与思茅地块大陆碰撞造山过程的初始阶段,同时表明昌宁-孟连洋碰撞最早时限为早三叠世。     

滇西澜沧江构造带及邻区几何学、运动学和构造年代学分析

滇西澜沧江构造带自北向南沿碧螺雪山和崇山连续延伸; 按照构造几何学特点和运动学特征我们把该构造带分为3段：北段、中段和南段; 本文对各段的构造、组构、运动学及构造年代学进行了翔实研究,得到以下认识：构造带呈双变质岩带,核部为强变形高级变质岩带,两侧为强变形低级变质岩带,部分剖面几何形态似“花状”构造; 宏观和微观组构特征均指示构造带北段和中?南段存在明显的运动学差异,北段为右旋走滑剪切,中、南段为左旋走滑剪切; 同构造浅色花岗质糜棱岩中分选出白云母(北段)和黑云母(中段),进行单颗粒矿物的激光熔化40Ar?39Ar定年,结果显示,糜棱岩化造成了花岗质岩石同位素时钟的重置和部分重置; 表面年龄指示了该构造带中新世的构造变形事件; 其中,北段右旋韧性剪切作用年龄为17.8～13.4 Ma或更早,至少持续到13.4 Ma,构造带中段记录了17.9～13.1 Ma的左行韧性剪切事件; 构造变形时代表现出同时代和同期次特点。综合分析认为,位于印度与欧亚大陆斜向汇聚带东缘的澜沧江构造带,是调节印支块体陆内变形的重要变形区域,为典型的新生代剪压应变区; 与区内哀牢山-红河构造带新生代左旋走滑相对应; 剪压应变和应变分解过程中,构造带东-西向减薄作用通过韧性物质垂向挤出和沿剪切方向的挤出平衡,垂向挤出导致地壳增厚和高应变体的抬升,形成现今的地貌高位,统一的陡立面理和亚水平拉伸线理是韧性物质沿剪切方向挤出的流变学响应; 构造带南段和北段运动学差异是澜沧江构造带新生代左旋剪压应变分解的必然产物和运动学要求。     

Petrography and Mineral Chemistry of Granites in Western Fengqing, Yunnan, China

Please refer to the attachment(s) for more details.     

Serpentinites of the Zermatt-Saas ophiolite complex and their texture evolution

The Zermatt‐Saas serpentinite complex is an integral member of the Penninic ophiolites of the Central Alps and represents the mantle part of the oceanic lithosphere of the Tethys. Metamorphic textures of the serpentinite preserve the complex mineralogical evolution from primary abyssal peridotite through ocean‐floor hydration, subduction‐related high‐pressure overprint, meso‐Alpine greenschist facies metamorphism, and late‐stage hydrothermal alteration. The early ocean floor hydration of the spinel harzburgites is still visible in relic pseudomorphic bastite and locally preserved mesh textures. The primary serpentine minerals were completely replaced by antigorite. The stable assemblage in subduction‐related mylonitic serpentinites is antigorite–olivine–magnetite ± diopside. The mid‐Tertiary greenschist facies overprint is characterized by minor antigorite recrystallization. Textural and mineral composition data of this study prove that the hydrated mineral assemblages remained stable during high‐pressure metamorphism of up to 2.5 GPa and 650 °C. The Zermatt‐Saas serpentinites thus provide a well documented example for the lack of dehydration of a mantle fragment during subduction to 75 km depth.     

滇西南南澜沧江构造岩浆岩带早侏罗世火山岩的发现——兼论云南省境内印支构造旋回的上限

采用锆石激光剥蚀法(LA-ICP-MS)对滇西南南澜沧江火山岩带普洱市江桥—那澜一带的流纹岩进行了年代测定,获得了(196.7±2.3)Ma、(198.1±3.5)Ma的同位素年龄;表明该地区的流纹岩形成于早侏罗世,而非前人划分的晚三叠世,填补了该地区早侏罗世的火山-沉积记录。从岩石的主元素、稀土元素及微量元素资料分析,南澜沧江构造岩浆岩带早侏罗世的火山岩形成于碰撞后的伸展构造背景,可能与西侧昌宁—孟连古特提斯洋盆关闭后,俯冲岩石圈板片或造山带山根的拆沉作用相关,属后碰撞—后造山阶段岩浆活动的产物。具有典型后造山花岗岩或"A"型花岗岩的特征,其指示了印支构造旋回在滇西南地区最终结束的时间上限。     

金沙江鲁地拉电站库区段地质灾害的发育特征及其工程危害性

库区处于云贵高原西部、青藏高原东南缘,为中国西南地区的活动构造区,显著的内、外动力地质作用致使区内地质灾害十分严重。经野外调查发现,区内主要的地质灾害类型为崩塌、滑坡、泥石流等,且主要集中分布在金江桥以东的高山峡谷区;在实际调查库长为100km的河谷段,共发育着81处地质灾害点,总平均线密度(D)为0.81个/km,其中滑坡为区内最主要的地质灾害,共发育59处,占总灾害点的72.84%。在野外地质调查的基础上,着重阐述了库区段主要地质灾害的类型、发育特征和地质灾害与工程安全的关系,为工程的规划和地质灾害的治理提供科学依据。     

滇西古特提斯俯冲-碰撞过程的岩浆作用记录

三叠纪岩浆作用广泛发育于澜沧江南带,锆石U-Pb年代学结果及岩石组合特征显示:(1)该区残留有少量的早三叠世火山岩(约248Ma),主要为一套薄层的以安山岩为主的火山岩;(2)中三叠世以大规模的酸性岩浆作用为主,部分地段的中部夹有少量的玄武岩,其中晚期的流纹岩与该区出露巨大的临沧花岗岩基主体具有一致的形成时代(约230Ma);(3)晚三叠世则以基性火山岩为主,夹少量流纹岩为特征的"双峰式"火山岩组合。元素地球化学特征表明,早三叠世火山岩具有典型的岛弧火山岩的特征,暗示其很可能形成于俯冲的构造环境;中三叠世晚期的流纹岩与临沧花岗岩基主体具有非常相似的地球化学特征,结合其流纹岩具有A型花岗岩属性,表明该区中三叠世火成岩形成于碰撞后的构造背景;而晚三叠世基性火山岩虽然在地球化学特征上显示出与岛弧火山岩相似的高铝和Nb-Ta的亏损,但其中部分火山岩具有高镁和板内玄武岩的微量元素比值特征,说明这些火山岩可能形成于碰撞后裂谷(post-collisional rifting)环境。结合区域上前人的研究资料,我们认为西南三江地区古特提斯主洋盆的俯冲闭合可能直到早三叠世晚期才完成,其后的陆-陆/弧碰撞作用可能发生在中三叠世早期,中三叠世中晚期该区进入碰撞后演化阶段,晚三叠世开始处于碰撞后的裂谷阶段,古特提斯在该区的演化最终结束于三叠纪末。