Observed composition of the ionosphere of Venus: Implications for the ionization peak and the maintenance of the nightside ionosphere

Across the nightside of Venus, daily measurements from the PV Orbiter Ion Mass Spectrometer often indicate an ionosphere of relatively abundant concentration, with a composition characteristic of the dayside ionosphere. Such conditions are interspersed by other days on which the ionosphere appears to largely “disappear” down to about 200 km, with ion concentrations at lower heights also much reduced. These characteristics, coupled with observations of strong day to night flows of O⁺ in the upper ionosphere, support arguments that ion transport from the dayside is important for the maintenance of the nightside ionosphere. Also, U.S. and Soviet observations of nightside energetic electron fluxes have prompted consideration of impact ionization as an additional nightside ion source. The details of the ion and neutral composition at low altitudes on the nightside provide an important input for further analysis of the maintenance process. In the range 140–160 km, strong concentrations of O₂⁺ and NO⁺ indicate that the ionization peak is at times composed of at least two prominent ion species. Nightside concentrations of O₂⁺ and NO⁺ as large as 10⁵ and 10⁴/cm³, respectively, appear to require sources in addition to that provided by transport. The most probable sources are considered briefly, and no satisfactory explanation is yet found for the observed NO⁺ concentrations. Further analysis beyond the scope of this paper is required to resolve this issue.     

Short-term variability of Jupiter’s extended sodium nebula

Ground-based optical observations of D₁ and D₂ line emissions from Jupiter’s sodium nebula, which extend over several hundreds of jovian radii, were carried out at Mt. Haleakala, Maui, Hawaii using a wide field filter imager from May 19 to June 21, 2007. During this observation, the east-west asymmetry of the nebula with respect to the Io’s orbital motion was clearly identified. Particularly, the D₁+D₂ brightness on the western side of Jupiter is strongly controlled by the Io phase angle. The following scenario was developed to explain this phenomenon as follows: First, more ionospheric ions like NaX⁺, which are thought to produce fast neutral sodium atoms due to a dissociative recombination process, are expected to exist in Io’s dayside hemisphere rather than in the nightside one. Second, it is expected that more NaX⁺ ionospheric ions are picked up by the jovian co-rotating magnetic field when Io’s leading hemisphere is illuminated by the Sun. Third, the sodium atom ejection rate varies with respect to Io’s orbital position as a result of the first two points. Model simulations were performed using this scenario. The model results were consistent with the observation results, suggesting that Io’s ionosphere is expected to be controlled by solar radiation just like Earth.     

Transterminator ion flow in the Martian ionosphere

The upper ionospheres of Mars and Venus are permeated by the magnetic fields induced by the solar wind. It is a long-standing question whether these fields can put the dense ionospheric plasma into motion. If so, the transterminator flow of the upper ionosphere could explain a significant part of the ion escape from the planets atmospheres. But it has been technically very challenging to measure the ion flow at energies below 20 eV. The only such measurements have been made by the ORPA instrument of the Pioneer Venus Orbiter reporting speeds of 1-5 km/s for O⁺ ions at Venus above 300 km altitude at the terminator ( [Knudsen et al., 1980] and [Knudsen et al., 1982]). At Venus the transterminator flow is sufficient to sustain a permanent nightside ionosphere, at Mars a nightside ionosphere is observed only sporadically. We here report on new measurements of the transterminator ion flow at Mars by the ASPERA-3 experiment on board Mars Express with support from the MARSIS radar experiment for some orbits with fortunate observation geometry. We observe a transterminator flow of O⁺ and O₂⁺ ions with a super-sonic velocity of around 5 km/s and fluxes of 0.8×10⁹/cm² s. If we assume a symmetric flux around the terminator this corresponds to an ion flow of 3.1±0.5×10²⁵/s half of which is expected to escape from the planet. This escape flux is significantly higher than previously observed on the tailside of Mars. A possible mechanism to generate this flux can be the ionospheric pressure gradient between dayside and nightside or momentum transfer from the solar wind via the induced magnetic field since the flow velocity is in the Alfvénic regime. We discuss the implication of these new observations for ion escape and possible extensions of the analysis to dayside observations which may allow us to infer the flow structure imposed by the induced magnetic field.     

Stochastic models of hot planetary and satellite coronas: A hot oxygen corona of Mars

The processes of the kinetics and transport of hot oxygen atoms in the transition (between thermosphere and exosphere) region of the upper atmosphere of Mars are studied. The reaction of dissociative recombination of the main ionospheric ion O ₂ ⁺ with thermal electrons in the ionosphere of Mars is considered as a source of hot oxygen atoms. The distribution of suprathermal oxygen atoms by kinetic energy is calculated. It is shown that the exosphere is populated by a considerable number of suprathermal oxygen atoms with kinetic energies just below the escape energy of 2 eV; that is, a hot oxygen corona of Mars is formed.     

Model-data comparisons for Titan's nightside ionosphere

Solar and X-ray radiation and energetic plasma from Saturn's magnetosphere interact with the upper atmosphere producing an ionosphere at Titan. The highly coupled ionosphere and upper atmosphere system mediates the interaction between Titan and the external environment. A model of Titan's nightside ionosphere will be described and the results compared with data from the Ion and Neutral Mass Spectrometer (INMS) and the Langmuir probe (LP) part of the Radio and Plasma Wave (RPWS) experiment for the T5 and T21 nightside encounters of the Cassini Orbiter with Titan. Electron impact ionization associated with the precipitation of magnetospheric electrons into the upper atmosphere is assumed to be the source of the nightside ionosphere, at least for altitudes above 1000 km. Magnetospheric electron fluxes measured by the Cassini electron spectrometer (CAPS ELS) are used as an input for the model. The model is used to interpret the observed composition and structure of the T5 and T21 ionospheres. The densities of many ion species (e.g., CH⁺₅ and C₂H⁺₅) measured during T5 exhibit temporal and/or spatial variations apparently associated with variations in the fluxes of energetic electrons that precipitate into the atmosphere from Saturn's magnetosphere.     

Extension of a polar ionospheric current to the nightside equator

A detailed analysis of rapid-run magnetograms from Guam (geomagnetic latitude = 4.2°) revealed that there are two kinds of geomagnetic sudden commencement (SC) observed in nighttime. One is the ordinary SC consisting of a main impulse only which has a smooth rise of the H-component. The other is a superposition by a small positive impulse on the very beginning part of the smooth rise of the main impulse and consequently the SC starts with a small stepwise increase of the H-component. The latter type of SC occurs between 20 and 08 h L.T. and its occurrence rate takes the maximum value of about 50% around 03 h L.T. Corresponding magnetograms from a dayside equatorial station (Huancayo, geomagnetic latitude = ?0.7°) were examined and a good correlation was found between the stepwise SC at the nightside (Guam) and SC¹ with a preliminary reverse impulse (PRI) at the dayside (Huancayo). Since PRI observed at the dayside equator may be interpreted as an extension of an ionospheric current due to an dusk-to-dawn electric field impressed on the polar ionosphere, our results show that a polar originating ionospheric current can extend to the nightside equator and produce a small but observable magnetic effect in spite of much reduced nighttime ionospheric conductivity.     

Solar EUV and Electron-Proton-Hydrogen Atom-Produced Ionosphere on Mars: Comparative Studies of Particle Fluxes and Ion Production Rates Due to Different Processes

The total photoelectron and secondary electron fluxes are calculated at different times and altitudes along the trajectory of Mars Global Surveyor passing through the nightside and dayside martian ionosphere. These results are compared with the electron reflectometer experiment on board Mars Global Surveyor. The calculated electron spectra are in good agreement with this measurement. However, the combined fluxes of proton and hydrogen atom as calculated by E. Kallio and P. Janhunen (2001, J. Geophys. Res.106, 5617-5634) were found to be 1-2 orders of magnitude smaller than the measured spectra. We have also calculated ionization rates and ion and electron densities due to solar EUV, X-ray, and electron-proton-hydrogen atom impacting with atmospheric gases of Mars at solar zenith angles of 75°, 105°, and 127°. In the vicinity of the dayside ionization peak, it is found that the ion production rate caused by the precipitation of proton-hydrogen atom is larger than the X-ray impact ionization rate while at all altitudes, the photoionization rate is always greater than either of the two. Moreover, X-rays contribute greatly to the photoelectron impact ionization rate as compared to the photoion production rate. The calculated electron densities are compared with radio occultation measurements made by Mars Global Surveyor, Viking 1, and Mars 5 spacecraft at these solar zenith angles. The dayside ionosphere produced by proton-hydrogen atom is smaller by an order of magnitude than that produced by solar EUV radiation. X-rays play a significant role in the dayside ionosphere of Mars at the altitude range 100-120 km. Solar wind electrons and protons provide a substantial source for the nightside ionosphere. These calculations are carried out for a solar minimum period using solar wind electron flux, photon flux, neutral densities, and temperatures under nearly the same areophysical conditions as the measurements.     

Non-thermal hydrogen in the venus exosphere: The ionospheric source and the hydrogen budget

A non-thermal, or “hot”, Venus corona of H atoms has been observed by Mariners 5 and 10 and Venera 9. Of the sources investigated, reaction of H₂ with ionospheric O⁺is still the strongest. It can explain the smaller densities but falls somewhat short of the largest (from Mariner 5). The subsequent recombination of OH⁺, supplemented by solar-wind processes, may give an escape flux of 10⁷ atoms cm^?2 s^?1. The low density of thermal H atoms on the day side has previously been attributed to either a large eddy diffusion coefficient or an escape flux tenfold greater than this. We support an alternative mechanism, suggested by Hartle and Mayr: the hydrogen is swept to the night side by strong thermospheric winds. This process is analogous to the “Johnson pump” for the terrestrial winter helium bulge. Large nightside bulges of H and H₂ are predicted; the night/day density ratio is estimated to be as large as 100 for each.     

Suprathermal oxygen and hydrogen atoms in the upper Martian atmosphere

The processes of kinetics and transport of hot oxygen and hydrogen atoms in the transition (from the thermosphere to the exosphere) region of the upper Martian atmosphere are studied. The reaction of dissociative recombination of the principal ionospheric ion O ₂ ⁺ with thermal electrons in the ionosphere of Mars served as the source of hot oxygen atoms. The process of momentum and energy transfer in elastic collisions between hot oxygen atoms and atmospheric hydrogen atoms with thermal energies was regarded as the source of hot hydrogen atoms. The kinetic energy distribution functions are determined for suprathermal oxygen and hydrogen atoms. It is shown that the exosphere is populated with a significant number of suprathermal oxygen atoms with kinetic energies ranging up to the escape energy of 2 eV (i.e., the hot oxygen Martian corona is formed). The transfer of energy from hot oxygen atoms to thermal hydrogen atoms creates an additional nonthermal flux of atomic hydrogen escaping from the Martian atmosphere.     

Ion chemistry in the cometary atmosphere

Dirty ice of a second kind (major components, H₂O, CO, and N₂; minor components less than several percents, NH₃, CH₄, and other organic substances such as HCN, CH₃CN etc.) is assumed for the composition of volatiles in the cometary nucleus. The consistency with the observations of molecular ions and daughter molecules in the cometary atmosphere is argued by taking into account various ion-molecular reactions and dissociative recombinations. There is a satisfactory agreement for the second kind of dirty-ice model, but the presence of large amounts of CH₄ and NH₃ is found to be rather in contradiction with observational evidence. A velocity of 8 km s^?1 for the hydrogen atoms, derived from analysis of the hydrogen Lyman-alpha corona around comets, is found from the dissociative recombination of H₃O⁺, the dominant constituent of cometary ionosphere, in accordance with H₃O⁺+e ^?→OH+H+H.     

Possible H2staggered+ ultraviolet spectrum of Jupiter

An ultraviolet spectral probe for a hydrogen-rich planetary atmosphere, such as that of Jupiter, is suggested, utilizing discrete lines in the H₂^staggered+ 2pπ_u?1sσ_g electronic transition. For the Jovian atmosphere, the dominant mechanism for exciting H₂⁺ to its 2pπ_u state appears to be photoexcitation, principally through absorption of the solar Lyman-α line. We estimate that the Jovian column emission rate of the H₂⁺ 2pπ_u(ν′ = 2, J′ = 1) →1sσ_g(ν″ = 18,J″ = 0) fluorescent line at 1236.6 Å is if1 photon cmsu-2 secsu-1; i.e., that if1 photon secsu-1 of this radiation would strike a 15-cm diameter mirror in a Jupiter fly-by at an impact parameter of 3 × 10⁵km. The critical role of corrections to the Born-Oppenheimer approximation in the use of an H₂⁺ probe is discussed.     

Structure and time variations of the Jovian ionosphere

The problem of the ionospheric formation in the Jovian upper atmosphere is examined. By adopting two plausible atmospheric models, we solve coupled time-dependent continuity equations for ions H₂⁺, H₅⁺, H⁺, H₃⁺ and H_eH⁺ simultaneously. It is shown that both radiative and three body association of H⁺ to H₂ are important for the determination of the structure of the Jovian ionosphere. The maximum electron density in the daytime is found to be about 10⁵ cm^?3. It is also shown that diurnal variation with large-amplitude can exist in the Jovian ionosphere.     

Observations of horizontal transport effects on high latitude metastable O(1D), N(2D) auroral emissions

An analysis is presented of photometric measurements of the NI (λ = 520nm),OI(λ = 630nm)and other emissions made at Nord, where the invariant latitude is Λ = 80°4. The time variations of the intensities are interpreted in the following way by comparison with simultaneous ground based or satellite measurements.The N(²D) atoms formed in the dayside cleft are carried by the neutral wind in a plume across the polar cap, so that the ratio of λ(630 nm) to λ(520 nm) intensities decreases along the plume with increasing distance from the source region.In the polar cap, but outside the plume region, 630 nm emission is produced by electron impact of polar rain and by substorms that reach high latitudes. Ionization produced at the same time, especially by the substorms, will produce further 630 nm emission through dissociative recombination. In any case, the region outside the plume may be regarded as a source region, with a high value of the ratio $\text{I(630)}\text{I(520)}$. This explains in part the diurnal variations, since this ratio is depressed as Nord crosses the dayside plume.The electron energy along the oval increases progressively from the dayside to the nightside. The intensity ratio increases with increasing electron energy because N(²D) is quenched more rapidly than O(¹D). Thus the ratio rises progressively from noon to midnight.An effect of the interplanetary magnetic field is superimposed on this pattern : as its North-South component B_z increases, the oval contracts so that Nord becomes nearer from the cleft source and the intensity ratio increases on the dayside. The inverse effect is also observed. On the nightside, negative B_z is associated with substorms that produce poleward expansions of the poleward oval boundary, that brings more energetic precipitation to Nord. This causes the intensity ratio to increase with decreasing B_z in a way that is opposite to that for the dayside.     

Suprathermal hydrogen produced by the dissociation of molecular hydrogen in the extended atmosphere of exoplanet HD 209458b

The ionization and dissociation of molecular hydrogen by the ultraviolet (UV) radiation of the parent star lead to the formation of hydrogen atoms with an excess of kinetic energy and, thus, are an important source of suprathermal hydrogen atoms in the upper atmosphere of exoplanet HD 209458b. Contemporary aeronomical models did not investigate these processes because they assumed the fast local thermalization of the hot atoms of hydrogen by elastic collisions. However, the kinetics and transfer of these atoms were not calculated in detail, because they require the solving of the Boltzmann equation for a nonthermal atom population. This work estimates the effect of the UV radiation of the parent star and the accompanying photocleacton flux on the production of the suprathermal fraction of atomic hydrogen in the H₂ → H transition region. We also consider the formation of the escaping flux of Hatoms created by this effect in the upper atmosphere of HD 209458b. We calculate the production rate and energy spectrum of the hydrogen atoms with excess kinetic energy during the dissociation of H₂. Using the numerical stochastic model created by Shematovich (2004) for a hot planetary corona, we investigate the molecular-scale kinetics and transfer of suprathermal hydrogen atoms in the upper atmosphere and the emergent flux of atoms evaporating from the atmosphere. The latter is estimated as 3.4 × 10¹² cm⁻² s⁻¹ for a moderate stellar activity level of UV radiation, which leads to a planetary atmosphere evaporation rate of 3.4 × 10⁹ g s⁻¹ due to the process of the dissociation of H₂. This estimate is close to the observational value of ∼10¹⁰ g s⁻¹ for the rate of atmospheric loss of HD 209458b.     

Measurements of positive ion conversion and removal reactions relating to the Jovian ionosphere

Measured rates are presented for the reaction of He⁺ ions with H₂ (and D₂) molecules to form H⁺, H₂⁺, and HeH⁺ ions, as well as for the subsequent reactions of H⁺ and HeH⁺ ions with H₂ to form H₃⁺. The neutralization of H₃⁺ (and H₅⁺) ions by dissociative recombination with electrons is shown to be fast. The reaction He⁺ + H₂ is slow (k = 1.1 × 10^?13 cm³/sec at300°K) and produces principally H⁺ by the dissociative charge transfer branch. It is concluded that there may be a serious bottleneck in the conversion of two of the primary ions of the upper Jovian ionosphere, H⁺ and He⁺ (which recombine slowly), to the rapidly recombining H₃⁺ ion (α[H₃⁺]?3.4 × 10^?7 cm³/sec at 150°K).     

Suprathermal electron fluxes on the nightside of Mars: ASPERA-3 observations

Recently aurora-type UV emissions were discovered on the nightside of Mars [Bertaux, J.-L., Leblanc, F., Witasse, O., et al., 2005. Discovery of an aurora on Mars. Nature 439, doi:10.1038/nature03603]. It was suggested that these emissions are produced by suprathermal electrons with energies of tens of eV, rather than by the electrons with spectra peaked above 100 eV [Leblanc, F., Witasse, O., Winningham J., et al., 2006. Origin of the martian aurora observed by spectroscopy for investigation of characteristics of the atmosphere of Mars (SPICAM) onboard Mars Express. J. Geophys. Res. 111, A09313, doi:10.1029/2006JA011763]. In this paper we present observations of fluxes of suprathermal electrons (E_e≈30-100 eV) on the Martian nightside by the ASPERA-3 experiment onboard the Mars Express spacecraft. Narrow spikes of suprathermal electrons are often observed in energy-time spectrograms of electron fluxes at altitudes between 250 and 600 km. These spikes are spatially organized and form narrow strips in regions with strong upward or downward crustal magnetic field. The values of electron fluxes in such events generally could explain the observed auroral UV emissions although a question of their origin (transport from the dayside or local precipitation) remains open.     

The Venus ionosphere at grazing incidence of solar radiation: Transport of plasma to the night ionosphere

Using a quasi-two-dimensional model of the Venus ionosphere, we calculated the ion number densities and horizontal ion bulk velocities expected for a range of solar zenith angles near the terminator (80 to 100°), and compared them with data obtained from the Pioneer Venus Orbiter retarding potential analyzer. The calculated ion bulk velocity arises entirely from the solar EUV-induced plasma pressure gradient and has a magnitude consistent with observations; ionization by suprathermal electrons is neglected in those computations. We find that while photoionization is the dominant source of ionospheric plasma for solar zenith angles less than 92°, plasma transport from the dayside is the dominant plasma source for solar zenith angles greater than 95°. We also show that the main nightside plasma peak at approximately 140 km altitude is of the F₂ type (i.e., is diffusion controlled). Its altitude and shape are thus quite insensitive to the altitude of the ion source.     

Silicon ion chemistry in the ionosphere

Loss processes which remove Si⁺ ions selectively relative to other meteor-derived atomic ions in the E- and D-regions of the ionosphere have been identified and measured in the laboratory. The major Si⁺ loss in the E-region is the reaction Si⁺ + H₂O → HSiO⁺ + H (1) with a rate constant 2.3 ± 0.9 × 10^?10 cm³s^?1 at 300 K. The corresponding reactions with Fe⁺, Mg⁺ and other metallic meteor ions are endothermic. Presumably (1) is followed by a fast dissociative-recombination with electrons to produce neutral SiO or Si. At lower altitudes Si⁺ ions associate in a three-body reaction with O₂ with a much larger rate constant than the corresponding associations of Fe⁺ and Mg⁺ with O₂.     

The post-terminator ionosphere of Venus

We have modeled the near and post-terminator thermosphere/ionosphere of Venus with a view toward understanding the relative importance of EUV solar fluxes and downward fluxes of atomic ions transported from the dayside in producing the mean ionosphere. We have constructed one-dimensional thermosphere/ionosphere models for high solar activity for seven solar zenith angles (SZAs) in the dusk sector: 90°, 95°, 100°, 105°, 110°, 115° and 125°. For the first 4 SZAs, we determine the optical depths for solar fluxes from 3 Å to 1900 Å by integrating the neutral densities numerically along the slant path through the atmosphere. For SZAs of 90°, 95°, and 100°, we first model the ionospheres produced by absorption of the solar fluxes alone; for 95°, 100°, and 105° SZAs, we then model the ion density profiles that result from both the solar source and from imposing downward fluxes of atomic ions, including O⁺, Ar⁺, C⁺, N⁺, H⁺, and He⁺, at the top of the ionospheric model in the ratios determined for the upward fluxes in a previous study of the morphology of the dayside (60° SZA) Venus ionosphere. For SZAs of 110°, 115° and 125°, which are characterized by shadow heights above about 300 km, the models include only downward fluxes of ions. The magnitudes of the downward ion fluxes are constrained by the requirement that the model O⁺ peak density be equal to the average O⁺ peak density for each SZA bin as measured by the Pioneer Venus Orbiter Ion Mass Spectrometer. We find that the 90° and 95° SZA model ionospheres are robust for the solar source alone, but the O⁺ peak density in the “solar-only” 95° SZA model is somewhat smaller than the average value indicated by the data. A small downward flux of ions is therefore required to reproduce the measured average peak density of O⁺. We find that, on the nightside, the major ion density peaks do not occur at the altitudes of peak production, and diffusion plays a substantial role in determining the ion density profiles. The average downward atomic ion flux for the SZA range of 90–125° is determined to be about 1.2 × 10⁸ cm⁻² s⁻¹.     

The density of the upper martian atmosphere measured by Lyman-α absorption with Mars Express SPICAM

Absorption of interplanetary Lyman-α emission by Mars’ nightside lower thermosphere was observed by Mars Express Spectrometer for Investigation of Characteristics of the Atmosphere of Mars (SPICAM), and is analyzed to derive the CO₂ density at 110 km during a martian year. The observed density seasonal variability is consistent with recent observations obtained by stellar occultations, proving that this method, though not as accurate as stellar occultations could be used complementary to them to characterize large variations of thermospheric density on Mars and provide a better spatial coverage by Lyman-α imagery.