北秦岭老君山、秦岭梁环斑结构花岗岩岩浆混合的岩相学证据及其意义

老君山和秦岭梁岩体具有明显的岩浆混合特征.岩体中暗色包体发育,主要类型为细粒闪长质和二长质的岩浆包体,有的岩浆包体具有细粒边,有的和寄主岩石呈过渡关系.包体的矿物组合明显不平衡:出现石英-角闪石眼斑;暗色矿物中有石英包裹体;磷灰石呈针状.在包体、寄主岩石及其边界上广泛出现卵球状的碱性长石斑晶.这些混合特征表明:老君山和秦岭梁环斑结构花岗岩、环斑结构与岩浆混合关系紧密;岩浆作用也具双峰式的特点,表现为基性岩浆和酸性岩浆的混合.这为探讨该类花岗岩和环斑结构的成因提供了直接的岩石学依据.同时,也为探讨北秦岭中生代壳幔混合作用和地壳增生提供了新的信息.     

北秦岭老君山、秦岭梁环斑结构花岗岩岩浆混合的岩相学证据及其意义

老君山和秦岭梁岩体具有明显的岩浆混合特征。岩体中暗色包体发育,主要类型为细粒闪长质和二长质的岩浆包体,有的岩浆包体具有细粒边,有的和寄主岩石呈过渡关系。包体的矿物组合明显不平衡：出现石英－角闪石眼斑;暗色矿物中有石英包裹体;磷灰石呈针状。在包体、寄主岩石及其边界上广泛出现卵球状的碱性长石斑晶。这些混合特征表明：老君山和秦岭梁环斑结构花岗岩、环斑结构与岩浆混合关系紧密;岩浆作用也具双峰式的特点,表现为基性岩浆和酸性岩浆的混合。这为探讨该类花岗岩和环斑结构的成因提供了直接的岩石学依据。同时,也为探讨北秦岭中生代壳幔混合作用和地壳增生提供了新的信息。     

北秦岭老君山环斑花岗岩的成因及大地构造意义

老君山环斑花岗岩分布于北秦岭造山带中，是沙河湾、朱厂沟脑、秦岭梁北秦岭环斑花岗岩带的一部分，以特殊的环斑结构，富含基性暗色微粒包体为特征，通过对其地质、岩石、地化资料研究，结合区域大地构造环境，认为老君山环斑花岗岩，具有岩浆混合成因类型，为造山后伸展环境的产物，标志着印支期末秦岭地区俯冲碰撞的板块构造体制已经结束，转入板内构造演化阶段。     

西秦岭天水地区晚三叠世柴家庄二长花岗岩及其暗色包体地球化学——岩石成因及岩浆混合作用

晚三叠世花岗岩类在秦岭-大别造山带西端广泛分布,其成因机制及地球动力学背景的研究对于反演华北、扬子两大板块沿秦岭-大别造山带在三叠纪时期的拼合历史具有重要意义.本文选择西秦岭天水地区柴家庄晚三叠世二长花岗岩及其中的暗色包体进行精细的岩石学和地球化学研究.暗色包体中普遍发育针状磷灰石及斜长石捕掳晶,暗示岩浆混合作用;暗色包体具有较低的SiO2（60.27%~60.38%）、高的Mg#（54~55）和Nb/Ta比值（14.8~16.6）,表明其来源于富集岩石圈地幔的部分熔融作用;寄主二长花岗岩表现出典型埃达克岩的地球化学特征,其富集Sr、Ba,亏损Y和HREE,岩石的Sr/Y比值介于88~98之间,Y/Yb比值介于13~15之间,暗示源区有石榴石残余.结合前人的研究结果,提出柴家庄二长花岗岩可能为增厚的造山带下地壳在碰撞后伸展环境下发生部分熔融作用的产物,可能与晚三叠世时期秦岭造山带的板片断离作用有关     

桂东北里松花岗岩中暗色包体的岩浆混合成因

在桂东北姑婆山地区的里松花岗岩中,暗色包体广泛分布,包体的形貌、结构构造和矿物学特征表明,它们是岩浆快速冷凝结晶产物;主元素和微量元素组成说明它们属钾玄岩系列,其源岩具OIB型微量元素特征;包体与寄主花岗岩中锆石U-Pb年龄的相同性,排除了来源于深部固体岩石熔融残留体或浅部围岩捕虏体的可能性,而两种岩石化学成分、岩石结构暗色包体和寄主花岗岩在岩石结构和全岩Sr-Nd同位素组成方面的明显差别性,又排除了同源包体或析离体、堆积体的可能性。里松花岗岩在很多地质-地球化学特征上都介于里松暗色包体和姑婆山主体花岗岩之间,里松暗色包体的总体特征显示了岩浆混合成因,是里松暗色包体岩浆与姑婆山主体花岗岩岩浆发生混合时不完全混合的残留物。     

内蒙古土牧尔台地区黑云母二长花岗岩及其暗色包体的成因及构造意义

内蒙古中部土牧尔台地区位于华北克拉通北缘,区内广泛发育黑云母二长花岗岩及暗色闪长岩包体,绝大多数包体与寄主岩石呈渐变过渡的接触关系.锆石LA-ICP-MS U-Pb定年结果显示,寄主岩石年龄为273 ～ 271Ma,包体年龄为268±2Ma,两者均形成于早-中二叠世.其中,寄主岩石具有高钾钙碱性、弱过铝质、高分异Ⅰ型花...     

普朗斑岩铜矿岩浆混合作用：岩石学及元素地球化学证据

普朗斑岩铜矿花岗闪长斑岩中存在大量的随机分布的镁铁质微粒包体,包体与寄主岩存在渐变接触关系。包体成分为闪长质,具有岩浆结构,存在针状磷灰石,显示了快速冷却结晶的特征。包体内可见具有暗色矿物镶边的眼球状石英,表明存在岩浆混合作用。寄主岩岩体规模较小,呈岩枝状产出,包体和寄主岩均为似斑状结构,说明两种岩浆侵位和发生岩浆混合作用的深度较浅。元素地球化学特征显示包体与寄主岩的之间有成分交换。包体和寄主岩强不相容元素均富集,高场强元素Nb、Ta、Ti均表现出显著的负异常,具有典型的岛弧岩浆岩的微量元素特征,包体和寄主岩Mg＃较高,在同等Si条件下比玄武岩部分熔融体富K2O和MgO,意味着源区必须有幔源岩浆的贡献。普朗斑岩铜矿蚀变矿化模式反映了其成矿环境偏基性,暗示镁铁质岩浆的加入对成矿具有贡献。     

北秦岭老君山和秦岭梁环斑结构花岗岩及构造环境——一种可能的造山带型环斑花岗岩

老君山和秦岭梁岩体产于秦岭造山带商丹缝合带北侧,其岩石普遍发育环斑结构,表现为碱性长石巨晶多为卵球状,有些发育斜长石外壳,有些不发育。这不同于一般花岗岩局部出现的具斜长石外壳自形碱性长石巨晶结构。在地球化学上,该岩石显示I—A型花岗岩过渡特点。区域背景、构造被动定位特点和地球化学综合分析表明,它们可能定位于后碰撞或后造山环境。这些特征与典型的元古代克拉通非造山环境中的环斑花岗岩既有相似之处,也有一定差异,而与巴西造山带中环斑花岗岩较为相似。本文认为,它们不是一般的斑状花岗岩,而是最近注意研究的环斑结构花岗岩,有可能是一种造山带型环斑花岗岩,即产于造山带中的非典型环斑花岗岩。     

松潘—甘孜造山带万里城花岗岩及其岩浆包体的成因与地球动力学意义

松潘—甘孜造山带广泛分布着三叠纪花岗岩体,其成因对正确认识研究区花岗岩浆的动力学背景具有重要意义。地球化学分析表明,万里城岩体寄主花岗岩具有高的Si O2含量(69.43%~73.10%)和较高的全碱含量,具弱过铝质(A/CNK=1.01~1.12)特征,属于高钾钙碱性—钾玄岩系列I型花岗岩类。暗色微粒包体具较低的Si O2含量(52.85%~59.50%)和较高的Mg#值(45~63),为准铝质高钾钙碱性二长(闪长)岩。包体为典型的岩浆细粒结构,发育针状磷灰石、环带结构斜长石、瞳状石英、反鲍文序列的不平衡岩浆结构等。微量与稀土元素分析表明,包体起源于壳幔混合作用,是底侵的幔源玄武质岩浆与上覆壳源长英质岩浆混合的产物,混合的熔体经历了钛铁矿、黑云母等矿物的分离结晶,最终形成万里城暗色微粒包体。而寄主花岗岩则起源于纯的长英质陆壳,岩石具有较低的Mg#值(21~39)、中等的Ca O/(Mg O+TFe O)值、较高的K2O/Na2O和(Na2O+K2O)/(TFe O+Mg O+Ti O2)值等,指示源区主要为变杂砂岩类。综合区域地质资料,提出松潘—甘孜造山带内大规模花岗质岩体的形成主要受控于碰撞后伸展背景下的玄武质岩浆底侵加热。     

松潘—甘孜造山带万里城花岗岩及其岩浆包体的成因与地球动力学意义

松潘—甘孜造山带广泛分布着三叠纪花岗岩体,其成因对正确认识研究区花岗岩浆的动力学背景具有重要意义。地球化学分析表明,万里城岩体寄主花岗岩具有高的SiO2含量（69.43%~73.10%）和较高的全碱含量,具弱过铝质（A/CNK=1.01~1.12）特征,属于高钾钙碱性—钾玄岩系列I型花岗岩类。暗色微粒包体具较低的SiO2含量（52.85%~59.50%）和较高的Mg#值（45~63）,为准铝质高钾钙碱性二长（闪长）岩。包体为典型的岩浆细粒结构,发育针状磷灰石、环带结构斜长石、瞳状石英、反鲍文序列的不平衡岩浆结构等。微量与稀土元素分析表明,包体起源于壳幔混合作用,是底侵的幔源玄武质岩浆与上覆壳源长英质岩浆混合的产物,混合的熔体经历了钛铁矿、黑云母等矿物的分离结晶,最终形成万里城暗色微粒包体。而寄主花岗岩则起源于纯的长英质陆壳,岩石具有较低的Mg#值(21~39)、中等的CaO/(MgO+TFeO)值、较高的K2O/Na2O和(Na2O+K2O)/(TFeO+MgO+TiO2)值等,指示源区主要为变杂砂岩类。综合区域地质资料,提出松潘—甘孜造山带内大规模花岗质岩体的形成主要受控于碰撞后伸展背景下的玄武质岩浆底侵加热。     

Multiple sources for the origin of granites: Geochemical and Nd/Sr isotopic evidence from the Gudaoling granite and its mafic enclaves, northeast China

Geochemical and Sr- and Nd-isotopic data have been determined for mafic to intermediate microgranular enclaves and host granitoids from the Early Cretaceous Gudaoling batholith in the Liaodong Peninsula, NE China. The rocks include monzogranite, porphyric granodiorite and quartz diorite. Monzogranites have relatively high ⁸⁷Rb/⁸⁶Sr ratios (0.672-0.853), low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7052-0.7086) and ε _Nd(t) values (−18.5 to −20.9) indicating that they were mainly derived from a newly underplated crustal source with a short crustal residence time. Quartz diorites have high initial ⁸⁷Sr/⁸⁶Sr ratios (0.7118-0.7120) and negative ε _Nd(t) values (−13.2 to −18.1) coupled with high Al₂O₃ and MgO contents, indicating they were derived from enriched lithospheric mantle with contributions of radiogenic Sr from plagioclase-rich metagreywackes or meta-igneous rocks, i.e., ancient lower crust. Two groups of enclaves with igneous textures and abundant acicular apatites are distinguished: dioritic enclaves and biotite monzonitic enclaves. Dioritic enclaves have low Al₂O₃ (13.5-16.4 wt%) and high MgO (Mg# = ∼72.3) concentrations, low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7058-0.7073) and negative ε _Nd(t) values (∼−7.2), and are enriched in LILEs and LREEs and depleted in HFSEs, suggesting they were derived from an enriched lithospheric mantle source. Biotite monzonitic enclaves have Sr and Nd isotopic compositions similar to the monzogranites, indicating they were crystal cumulates of the parental magmas of these monzogranites. Granodiorites have transitional geochemistry and Nd- and Sr-isotopic compositions, intermediate between the monzogranites, quartz diorites and the enclaves.Geochemical and Sr- and Nd-isotopic compositions rule-out simple crystal-liquid fractionation or restite unmixing as the major genetic link between enclaves and host rocks. Instead, magma mixing of mafic mantle-derived and juvenile crustal-derived magmas, coupled with crystal fractionation and assimilation of ancient lower crust, is compatible with the data. This example shows that at least some calc-alkaline granitoids are not produced by pure intracrustal melting, but formed through a complex, multi-stage hybridization process, involving mantle- and crustal-derived magmas and several concomitant magmatic processes (crystal fractionation, crustal assimilation and crustal anatexis).     

南秦岭地体东江口花岗岩及其基性包体的锆石U-Pb年龄和Hf同位素组成

东江口花岗岩体位于商丹与勉略缝合带之间的南秦岭中部,其中存在大量基性暗色微粒包体.锆石的LA-MCICPMS联机U-Pb年代学分析表明,东江口岩体的形成年龄为223Ma,其包体锆石的结晶年龄为222Ma,与寄主岩体大致同时形成,指示秦岭造山带印支晚期岩石圈构造体制属性从挤压.伸展转变发生在220Ma左右.锆石的Lu-Hf同位素原位分析结果表明,南秦岭晚三叠纪花岗岩是壳幔混合作用的产物,亏损的幔源岩浆与南秦岭(或扬子)的基底地壳物质可能为南秦岭地区晚三叠纪花岗岩的源区物质,它们的形成起因于秦岭造山带在主造山期后发生的岩石圈拆沉作用.大约220Ma开始,南秦岭岩石圈构造应力性质从挤压向伸展构造体制转变,岩石圈发生拆沉作用,地幔软流圈物质上涌并底侵于下地壳,诱发下地壳物质的部分熔融,当岩浆沿构造薄弱带上升过程中,幔源岩浆与寄主岩浆发生成份的交换,两种岩浆混合过程中不完全混溶,最终形成寄主岩体和暗色基性微粒包体.     

Trace Elements and Sr, Nd Isotope Geochemistry of the Lajimiao Norite-Gabbro from the North Qinling Belt

The Lajimiao norite-gabbro complex, as a part of the ophiolites on the southern side of the North Qinling belt, consists of gabbro and norite-gabbro. They were derived from different magma series: the gabbro was derived from tholeiitic magma series with higher TiO2, REE abundance and Fe3+/Fe2+ ratio ; norite-gabbro was derived from calc-alkali magma series with lower TiO2, Fe3+/Fe2+ ratio and REE abundance and much lower HREE abundance, which suggests that the source of the norite-gabbro magma was deeper and controlled by eclogite facies. Geochemical characteristics of both plutonic rocks are similar to those of island-arc basalts, such as relatively high contents of Ba, Pb and Sr and relatively low contents of Nb, Zr and N j.The Sr, Nd isotopic characteristics of the Lajimiao norite-gabbro complex are similar to those of ophiolites. Its εNd values are constant, about+2; whereas εst values have wide variation from - 6.4 to +31.2 and positively correlate with Na2O, H2O+ and CO2 contents and the Fe3+/Fe     

Trace Elements and Sr,Nd Isotope Geochemistry of the Lajimiao Norite-Gabbro from the North Qinling Belt1

Abstract The Lajimiao norite-gabbro complex, as a part of the ophiolites on the southern side of the North Qinling belt, consists of gabbro and norite-gabbro. They were derived from different magma series: the gabbro was derived from tholeiitic magma series with higher TiO₂, REE abundance and Fe³⁺ / Fe²⁺ ratio; norite-gabbro was derived from calc-alkali magma series with lower TiO₂, Fe³⁺ / Fe²⁺ ratio and REE abundance and much lower HREE abundance, which suggests that the source of the norite-gabbro magma was deeper and controlled by eclogite facies. Geochemical characteristics of both plutonic rocks are similar to those of island-arc basalts, such as relatively high contents of Ba, Pb and Sr and relatively low contents of Nb, Zr and Ni. The Sr, Nd isotopic characteristics of the Lajimiao norite-gabbro complex are similar to those of ophiolites. Its 8_Nd values are constant, about +2; whereas 8_Sr values have wide variation from — 6.4 to +31.2 and positively correlate with Na₂O, H₂O⁺ and CO₂ contents and the Fe³⁺ / Fe²⁺ ratio. The ?_Nd—Nd / Th, ?_Nd—La/Nb and ?_Nd—Ba/Nb diagrams clearly show that there were significant components of terrigenous sediments in the mantle source of the Lajimiao norite-gabbro complex. It suggests that large amount of sediments had been carried into the mantle by the subducted ancient Qinling sea plate during the Palaeozoic.     

北山造山带红柳河槽-跃进山地区石炭纪花岗岩成因及构造岩浆演化研究SCIEI北大核心CSCD

北山造山带位于中亚造山带南缘,区内广泛发育古亚洲洋-陆演化的岩浆记录,是研究北山造山带构造-岩浆-成矿作用及其动力学背景的重要窗口。红柳河槽-跃进山地区是北山造山带中北部的重要组成部分,区内与成矿有关花岗岩的形成时代、成因及构造背景尚不明确,由此制约了对北山造山带内成岩成矿动力学背景的探讨。本次在系统、详细的野外地质调查、岩石(相)学观察的基础上,结合岩浆岩地球化学、锆石U-Pb年代学和Lu-Hf同位素等证据,深入剖析了北山造山带内红柳河槽-跃进山地区的花岗岩形成时代、类型、源区和动力学背景,取得了以下认识:(1)通过锆石LA-ICP-MS U-Pb定年测得与成矿有关的狼娃山二长花岗岩、红柳河槽正长花岗岩、跃进山北正长花岗岩、跃进山二长花岗岩形成时代分别为327.1±2.4Ma、326.7±2.4Ma、321.3±2.4Ma和309.7±2.2Ma,表明红柳河槽-跃进山地区铜、钨、钼、铅、锌等元素成矿与石炭纪(327.1~309.7Ma)岩浆活动有关;(2)通过花岗岩地球化学研究表明,红柳河槽-跃进山地区的花岗岩均属于钙碱性-高钾钙碱性、准铝质-弱过铝质系列,强烈富集LREE、LILE,亏损HREE、HSFE,具有典型弧岩浆的地球化学特征,花岗岩成因类型均为I型;(3)本次获得狼娃山二长花岗岩和红柳河槽正长花岗岩的εHf(t)值分别为5.90~9.92(平均值7.93)和5.87~10.28(平均值8.11),t DM2分别为0.703~0.959Ga和0.93~1.03Ga,且具有较低的Nb/Ta比值(5.1~14.2,平均值8.5),与典型新生下地壳来源岩浆(8.3)相似,表明岩浆物质可能源于新生下地壳岩石部分熔融;(4)根据锆石Ti温度计查明北山造山带红柳河槽-跃进山地区狼娃山二长花岗岩、红柳河槽正长花岗岩、跃进山北正长花岗岩、跃进山二长花岗岩的平均结晶温度分别为765℃、765℃、816.4℃、771.5℃,锆石Ce^(Ⅳ)/Ce^(Ⅲ)平均值分别为85.27、108.4、103.6、135.7,表明从石炭纪早期到晚期,岩浆的氧逸度呈逐渐升高的趋势。根据以上研究,结合前人研究成果,初步建立了北山造山带构造-岩浆演化模型如下:石炭纪北山造山带北部红石山洋向南侧公婆泉-明水-旱山复合构造单元(弧)之下发生俯冲,诱发新生下地壳部分熔融形成的壳源岩浆;其侵入到地壳浅部,并最终形成红柳河槽-跃进山花岗岩体。     

北秦岭西段早侏罗世A型花岗岩及其地质意义

本文通过岩相学、岩石地球化学、锆石U?Pb定年和Lu?Hf同位素组成分析等方法,对出露于北秦岭西段宝鸡岩体王家山一带的黑云母花岗岩和其中的包体进行了研究。结果表明,该花岗岩形成时代为187±2 Ma,属于高钾钙碱性—钾玄岩系列岩石,富集Rb、Th、U等大离子亲石元素以及Nb、Zr和Hf等高场强元素,亏损Ba、Sr和Eu,具有高的全岩锆石饱和温度(825℃~838℃),显示A型花岗岩特征,形成于造山后的板内环境,可能为秦岭岩群副变质岩与安山质岩石部分熔融的产物。暗色包体显示塑性流变特征,具有岩浆结构,发育针状磷灰石和具有复杂成分环带的更长环斑结构长石,是幔源岩浆注入酸性岩浆发生混合作用的产物,形成时代为191±2 Ma,其锆石Hf同位素组成变化范围较大,εHf(t)值介于-11.26~-2.51,主要为富集地幔部分熔融产物。综合本文及前人已有研究结果,认为~190 Ma的早侏罗世早期秦岭地区早中生代碰撞造山过程已经结束,区域开始逐渐进入板内伸展构造演化阶段。     

西秦岭印支期高Sr/Y花岗岩类的成因及动力学背景——以同仁地区舍哈力吉岩体为例

西秦岭印支期花岗岩类分布十分广泛,形成时代集中于248~234Ma和224~211Ma两个阶段.其中,夏河岩体(248~238Ma)和温泉岩体(223~216Ma)的部分样品被厘定为埃达克岩(Sr>400×10^-6,Yb<2×10^-6),指示陆壳厚度大于50km.本文对西秦岭同仁地区舍哈力吉岩体进行了锆石U-Pb定年、岩石学、地球化学和Sr-Nd同位素研究.舍哈力吉岩体主要由石英二长岩组成,同时含有许多暗色镁铁质微粒包体(MME).寄主岩中发育少量的钾长石巨晶,并且部分巨晶具有环斑结构.舍哈力吉石英二长岩化学成分比较均一,而且也显示出类似埃达克岩的一些地球化学特点,如富SiO₂(66.07%~67.52%)和Al₂O₃(14.85%~15.95%),高Sr(560×10^-6~692×10^-6),低Y(11.4×10^-6~12.9×10^-6)和Yb(0.99×10^-6~1.09×10^-6),并具有较高的(La/Yb)_N比值(27.8~34.3)和微弱的负Eu异常(δEu=0.77~0.95).锆石U-Pb测年结果为234.1±0.5Ma,表明其形成于印支早期.岩石为偏铝质、高钾钙碱性系列且K₂O/Na₂O>1,高Mg^#(59~60)、Cr(69.1×10^-6~81.2×10^-6)和Ni(31.6×10^-6~36.1×10^-6),以富集大离子亲石元素(Rb、Ba、Th、U)而相对亏损高场强元素(Nb、Ti、P)为特征,(⁸⁷Sr/⁸⁶Sr)_i=0.7075~0.7077,ε_Nd(t)=-6.3~-6.1,亏损地幔模式年龄为1.25~1.33Ga.舍哈力吉石英二长岩起源于石榴角闪岩相古老下地壳的部分熔融,之后经历了壳幔岩浆混合作用和以斜长石为主的分离结晶作用.寄主岩的环斑结构和相对一致的地球化学特征,很可能是高温幔源熔体对壳源富钾高黏度岩浆改造所导致的晶粥快速再活化的结果.西秦岭在印支早期可能并未经历显著的地壳加厚过程.西秦岭印支早期花岗岩类形成于活动大陆边缘局部伸展环境,可能与古特提斯洋壳俯冲极性的改变有关.     

Tectonic significance of Late Neoproterozoic granites from the Tibesti massif in southern Libya inferred from Sr and Nd isotopes and U–Pb zircon data

The Neoproterozoic crust of the Tibesti massif was stabilized by magmatism that included subduction-generated batholithic suites and post-orogenic granite plutons. All of the magmatism occurred in a period of about 20 million years centered around 550 Ma, and nearly all of the granites have initial ⁸⁷Sr/⁸⁶Sr ratios of about 0.706. The Wadi Yebigue pluton has U–Pb zircon ages of 563 Ma and 558 Ma on two different phases and ε_Nd at 550 Ma from −0.5 to −2.2. These isotopic data and the geologic history of the massif suggest that granites in the Tibesti massif developed during and shortly after closure of a short-lived ocean basin that developed by fragmentation of pre-existing continental crust of the Saharan region.     

阿尔泰造山带南缘镁铁质-超镁铁质杂岩体的Sr、Nd、O同位素地球化学及其源区特征探讨

对阿尔泰造山带南缘喀拉通克和锡泊渡两个杂岩体的Sr—Nd-O同位素研究表明,两个杂岩体的同位素特征相似,均具有低的（^87Sr／^86Sr）,和高的εNd（t）值（6．3～9．1）,表明其来源于亏损的软流圈地幔,但是其δ^18O值（‰）大多大于6（5．4～10．2）,表明有地壳物质的加入。Sr和O同位素表明,这种地壳物质的混入主要是源区的混入。根据Nd同位素模式年龄以及区域构造演化特征,可能是混入有早期俯冲的洋壳（可能是早古生代）的亏损地幔熔融的结果。然而,与锡泊渡杂岩体不同的是,喀拉通克杂岩体局部还经历了上部地壳的混染作用。此外,额尔齐斯深大断裂南北两侧镁铁质-超镁铁质杂岩体源区特征的相似性可能暗示了该断裂可能不是阿尔泰造山带和准噶尔造山带的分界线。     

Mineralogy and Geochemistry of Pyrite and Arsenopyrite from the Zaozigou Gold Deposit in West Qinling Orogenic Belt,Central China: Implications for Ore Genesis

The Zaozigou gold deposit lies in the West Qinling orogenic belt, Gansu Province, China. It is one of the largest gold deposits, and the orebodies are hosted in fine‐grained slates intercalated with limestone of the Middle‐Triassic Gulangdi Formation and varied dykes. The gold orebodies are strictly controlled by the NE‐, NW‐, and SN‐trending tensional and shearing faults with high dipping angle. The mineralogy and geochemistry of pyrite and arsenopyrite are measured by electron microprobe. Pyrite has up to 0.12 wt.% Au, and arsenopyrite contains up to 0.17 wt.% Au. The antithetic correlation between S and As indicates the substitution of As for S in pyrite, and arsenic occurs in anionic As^1? state in the pyrite structure under the reduced conditions. Pyrite has relatively high Co (~364–2248 ppm) but relatively low Ni (~109–497 ppm) contents, with Co/Ni ratios ranging from ~1.63 to 10.50, indicating that the deposit originated from a volcanogenic fluid and remobilized by hydrothermal fluid. Au in arsenopyrite occurs as cationic Au in solid solution, whereas Au in pyrite is in solid solution and metal nanoparticles (Au⁰). The texture characteristics and trace element geochemistry among cores, transition zones, and rims of pyrites demonstrate that there are at least four pulses of fluid participating in the generation of pyrite in the deposit. The calculated formation temperatures of the Zaozigou deposit vary from 148°C to 304°C, with an average temperature of 213°C based on Au contents in pyrite. The Pb isotopic compositions of pyrite samples suggest that the metallogenic materials of the Zaozigou deposit were derived from the mantle and upper crust. All the characteristics above lead us to draw the conclusion that the Zaozigou gold deposit is classified as an epithermal deposit.