Biostratigraphy of the Bajocian–Bathonian boundary beds in the basin of the Bolshoi Zelenchuk River (Northern Caucasus)

The study of ammonites from the upper part of the upper Bajocian and lower part of the lower Bathonian in the sections of the basin of the Bolshoi Zelenchuk (Karachay-Cherkessia) allowed the recognition of Beds with Parkinsonia djanelidzei (approximate equivalent of the middle part of the Parkinsonia parkinsoni Chronozone) and Beds with Oraniceras scythicum (lower part of the Zigzagiceras zigzag Chronozone). The taxonomic composition and distribution of foraminifers, ostracodes, dinoflagellate cysts, and miospores were studied in the samples from these deposits (upper part of the upper member of Djangura Formation). The recognized characteristic assemblages of microfauna and palynomorphs allowed ostracode and dinocyst subdivisions to be proposed for the Bajocian–Bathonian boundary beds of the Northern Caucasus for the first time. The most important taxa, including ammonites, foraminifers, ostracodes, and dinocysts, are illustrated.     

Biogeochemical properties of bituminous deposits in the Miocene Himmetoǧlu basin (Turkey)

In this study, geochemical and biogeochemical investigations by means of organic carbon (Corg) and element chemistry were performed on deposits in the Miocene Himmeto lu basin which is represented by various depositional characteristics. As a result of Corg and element analyses conducted on more than 50 samples, precious and rare metals such as Ag, Hg, Bi, In and U were found to have wide accumulation ranges. The average concentrations of these metals in bitumen-rich sediments in the area are 0.9, 1.17, 0.9, 0.85 and 10.0 ppm, respectively. Enrichment coefficients (EC) of these metals are 12.86, 58.5, 4.5, 14.2 and 3.7 times greater than the earth crust. However, in some sediment units enrichment coefficients are much higher such as 34.3 for Ag, 100 for Hg, 13.3 for Bi, 33.3 for In and 12.44 for U. The average Corg values of sediments studied is 37.21%. Except for two samples (2.78 and 2.65%), Corg values range from 11.09 to 80.03 wt % indicating that this part of Miocene basin has unique paleobionomic and paleogeographic characteristics. The main source of OM is algal/amorphous Type I and also Type II kerogens consisting of vegetal sources such as spore-pollen and leaf cuticle. Results show that region under investigation is important by means of energy and metal sources.     

Distribution and concentrations of anthropogenic platinum group elements in the surface environment of Hong Kong

Ecotourism environmental impact assessment is a traveling activity relevant influence prediction and appraisal. And the setting-up of the index system is very important to implement the appraisal of environmental impact of ecological travel. According to the index system, natural ecological environment, humane social environment, the environment of tourist resources and the atmosphere of capacity of tourist environment, four major systems form the first index. Each system formed the second index of several key elements. In addition, it is a key step to appraise the sureness of the factor weight, which influences the rationality of the result directly. Daily method of weighting has the Delphi＇s and the AHP. According to ＂Grade form of characteristic value of Standard of rating for quality of tourist attractions＂ which the National Tourism Administration issues, the paper takes the Jingshan mountains ecological tourist zone as an example and adopts AHP to weight the factors mainly, assisted with the Delphi＇s by the help of computer. The Jingshan ecological tourist zone is good. The result of calculation, comprehensive value of 8.35 after establishment, shows that it doesn＇t change dramatically, attributing to the index of natural ecological environment like atmosphere, quality of surface water, acoustics environment and vegetation coverage. Improvement of traffic states and sanitation caused by the project in the region increases the comprehensive value, while the water and soil loss in partial area caused by construction decrease.     

First find of platinum group metals in the ore of Kirganik copper–porphyry deposit (Kamchatka)

The Kirganik copper–porphyry deposit is situated in the central part of the Sredinnyi Mountain Range of Kamchatka and is confined to fields of development of potassic orthoclase metasomatite and hypabyssal intrusions of shonkinite. Platinum group metals (PGMs), such as merenskyite, kotulskite, keithconnite, and temagamite, were discovered in the chalcopyrite–bornite and chalcopyrite–bornite–chalcosine ore of the deposit for the first time.     

Sedimentation control over the oil and gas contents in the cretaceous deposits of the Russkoe–Chaselka Mega-Arch (West Siberian oil and gas basin)

Most of the hydrocarbon resources of the Russkoe–Chaselka Mega-Arch are related to the Pokur Formation reservoirs. They are generally composed of alluvial sandstones and shales. Due to their genesis the Pokur reservoirs have a complex structure and a localized spread within ancient alluvial plains. The performed integrated interpretation of the well and 3D seismic data made it possible to estimate new perspective fields and to geometrize the oil and gas deposits.     

The occurrences of the rare earth elements and the platinum group elements in relation to base metal zoning in the vicinity of Rote Fäule in the Kupferschiefer of Poland

The concentrations of the lanthanide rare earth elements (REE) and Pt group elements (PGE) were measured in the Kupferschiefer from the Polish Zechstein Basin at, and in proximity to, the Rote Fäule near the Lubin Mining District. The Rote Fäule is a zone of post-depositional oxidation characterized by the presence of extensive amounts of Fe(III) oxides replacing syn-sedimentary framboidal pyrite. Outward from the Rote Fäule, the remainder of the Kupferschiefer is composed of Cu- and Pb/Zn-mineralized shale surrounding the Rote Fäule and a non-mineralized pyritic black shale in the central basin.The leading hypothesis explaining the high concentrations of PGE, and REE in the Kupferschiefer states that PGE, REE and the associated base metals were mobilized by oxidizing Cl⁻ brines which migrated outward from the Rote Fäule into the reduced Kupferschiefer. According to available thermodynamic data, PGE were in all likelihood present as chloro-complexes in these oxidizing brines, as geologically realistic concentrations of Pt, Pd and Au could be transported as chloro-complexes. The Eh of these brines decreased as they migrated further from the Rote Fäule and into the Kupferschiefer. Base metals and PGE were precipitated in the order of their decreased solubility in these brines. As a result, the concentrations of least soluble PGE (Pt) are highest in the Rote Fäule and in the transition zone adjacent to the Rote Fäule (e.g. [Pt]=202–537 ppb) while the concentrations of the more soluble metals in these brines (Ag, Cu, Pb, and Re) are highest in the reduced-mineralized Kupferschiefer. The sources of the PGE and REE are enigmatic. It is likely that the metals were derived either from the underlying Rotliegendes sandstones and volcanics, the Variscan basement rocks, or the Kupferschiefer shale whose metals were mobilized by saline, oxidizing fluids released during intra-continental rifting in the Triassic period.     

Faulting and folding in quaternary deposits of Tehran’s piedmont (Iran)

Tehran lies on the southern flank of the Central Alborz, an active mountain belt characterized by many historical earthquakes, some of which have affected Tehran itself. The border between the Alborz Mountain and the Tehran’s piedmont (northern part of Tehran City) is marked by the North Tehran Fault (NTF), dividing the Eocene rock formation from the alluvial units of different ages (Early Pleistocene to the recent alluvium). A detail mapping of the piedmont, combined with structural study reveal that two active thrust faults (situated south of the NTF) are of importance for hazard assessment of the City. The geomorphological evidences along the NTF are not in agreement with an active fault, indicating that the fault activity may have been shifted southward. Furthermore differentiation of newly recognized alluvial units and their inferred ages, together with the mapped fault pattern permit us to characterize the Quaternary deformation. The Late Pleistocene alluvial deposits consist of three alluvial fans among them the youngest one together with the modern alluvial fan defines the Holocene deposit. The present deformation in the piedmont is accommodated along vertically left-lateral strike-slip faults and low-angle thrust faults trending in range from N070 to N110E.     

Fluorine and chlorine in mantle minerals and the halogen budget of the Earth’s mantle

The fluorine (F) and chlorine (Cl) contents of arc magmas have been used to track the composition of subducted components, and the F and Cl contents of MORB have been used to estimate the halogen content of depleted MORB mantle (DMM). Yet, the F and Cl budget of the Earth’s upper mantle and their distribution in peridotite minerals remain to be constrained. Here, we developed a method to measure low concentrations of halogens (≥0.4 µg/g F and ≥0.3 µg/g Cl) in minerals by secondary ion mass spectroscopy. We present a comprehensive study of F and Cl in co-existing natural olivine, orthopyroxene, clinopyroxene, and amphibole in seventeen samples from different tectonic settings. We support the hypothesis that F in olivine is controlled by melt polymerization, and that F in pyroxene is controlled by their Na and Al contents, with some effect of melt polymerization. We infer that Cl compatibility ranks as follows: amphibole > clinopyroxene > olivine ~ orthopyroxene, while F compatibility ranks as follows: amphibole > clinopyroxene > orthopyroxene ≥ olivine, depending on the tectonic context. In addition, we show that F, Cl, Be and B are correlated in pyroxenes and amphibole. F and Cl variations suggest that interaction with slab melts and fluids can significantly alter the halogen content of mantle minerals. In particular, F in oceanic peridotites is mostly hosted in pyroxenes, and proportionally increases in olivine in subduction-related peridotites. The mantle wedge is likely enriched in F compared to un-metasomatized mantle, while Cl is always low (<1 µg/g) in all tectonic settings studied here. The bulk anhydrous peridotite mantle contains 1.4–31 µg/g F and 0.14–0.38 µg/g Cl. The bulk F content of oceanic-like peridotites (2.1–9.4 µg/g) is lower than DMM estimates, consistent with F-rich eclogite in the source of MORB. Furthermore, the bulk Cl budget of all anhydrous peridotites studied here is lower than previous DMM estimates. Our results indicate that nearly all MORB may be somewhat contaminated by seawater-rich material and that the Cl content of DMM could be overestimated. With this study, we demonstrate that the halogen contents of natural peridotite minerals are a unique tool to understand the cycling of halogens, from ridge settings to subduction zones.     

Chemical transformation of the runoff of dissolved matters in the mouth areas of the Onega and Mezen’ rivers

Natural observations were analyzed to study the distribution of dissolved species of major and trace elements in the Onega and Mezen’ mouth areas and the tendencies in the chemical transformations of the is continental runoff in the river mouths of the White Sea drainage system. It is shown that the migration of major ions and dissolved species of Li, Rb, Cs, Sr, B, F and Mo is consistent with a conservative behavior and is controlled by hydrodynamic processes. The amounts of uranium and barium additionally supplying in the Mezen’ mouth exceed those removed with a continental runoff, whereas the Onega, Severnaya Dvina, and other rivers of the White Sea drainage system are characterized by the conservative behavior of uranium, while barium desorption from particulate matter reaches no more than 33% of its content in the riverine waters. The growth of concentrations of these elements in the Mezen’ mouth is caused by the long-term interaction of solid matters of the continental runoff with saline waters in the tide-affected estuary. 28–59, 12–63, 25–67 and 20–63% of concentrations of iron, aluminum, lanthanum, and cerium are removed from the riverine waters in the mouth areas of all studied rivers of the White Sea drainage system mainly owing to the coagulation and flocculation of organic and organomineral colloids. The distribution of dissolved species of mineral phosphorus and silicon in the Mezen’ mouth is presumably controlled by the remineralization of the organic matter in the bottom sediments, which due to the hydrological features of estuary are regularly stirred up and interact with vertically mixing water sequence. Up to 20–46% of dissolved phosphates and 3–22% of silicon are removed from the continental runoff during vegetation period in the mouths of the Onega, Severnaya Dvina, and other rivers of the White Sea drainage system mainly owing to their biological consumption.     

History of the geological evolution of the Tsil’ma River basin (midle Timan) in the Devonian

The results of bio- and lithostratigraphic studies of the Givetian-Frasnian rocks in the Tsil’ma River basin are reported. They suggest regularities in sedimentation: distinct rhythmicity and similar succession in the structure of formations. We have identified five palynocomplexes that characterize the formations and make it possible to accomplish a confident biostratigraphic subdivision of sections. Their correlation with coeval complexes in the adjacent areas has been accomplished. The results made it possible to unravel specific features of miospore assemblages formed in the continental and coastal-marine facies.     

Graphite of the Turgenevskoe and Tamginskoe deposits of the Lesozavodsk area in the Primor’e region

The regional carbonization of the Riphean metamorphic complexes is discussed using as an example the Tamginskoe and Turgenevskoe graphite deposits located in the northern part of the Khanka terrane. It is shown that the noble metal mineralization associates closely with the graphitization. Isotopic, X-ray, and thermal analyses and Raman spectroscopy were first used for investigating the structural state of the graphite with defining its two varieties. The first of them is represented by nanocrystalline fluidogenic graphite that was formed during gas condensate crystallization from deep-seated reduced ore-bearing fluid. The second variety (large-flake graphite) represents a product of metamorphic recrystallization of carbonaceous terrigenous protoliths. The recrystallization was accompanied by the granitization of the sedimentary protolith, mobilization, and the transfer of the carbonaceous and ore matter of the host rocks. It is inferred that the graphitization associated with noble metal mineralization is a polygenic process. The graphite of the first generation associates closely with amorphous diamond-like carbon. This unexpected find may bear genetic information useful for geological and geochemical reconstructions.     

Development characteristics and mechanisms of the Taigu–Qixian earth fissure group in the Taiyuan basin,China

Since the 1980s, increasing human activity and continuing over-exploitation of groundwater resources have caused the earth fissures in the rift basin in Shanxi, China, to enter an active phase. Buildings along these earth fissures have been seriously damaged. Four massive earth fissures that developed in the Taigu and Qixian areas of the eastern Taiyuan basin endanger the operational safety of the high-speed railway that passes through this region. Using field observations, measurements, and exploration, we determined that the four earth fissures are parallel to each other, have a northeast trend, and are separated by approximately equal distances. The rupture zones of these earth fissures are generally 10–50 m wide and are formed by the main fissures and secondary fissures. The width of the zone affected by the earth fissures is 20–50 m based on deformation and the damage done to buildings. These fissures formed on the Earth’s surface; their hanging walls are lower than their foot walls, forming normal faults; and the ground surface around the fissures exhibits ridges and depressions. The fissures are connected to deep hidden faults. The fault displacement increases with increasing depth, which is characteristic of syn-sedimentary faults. These earth fissures are characterized by vertical displacement, and their average annual activity rate is 1–3 cm. We believe that the formation of this large-scale fissure group may be related to the tectonic structure of the hidden faults in the basin and may also be affected by the continuous regional extensional stress of the basin. The current increased level of activity could be caused by the over-exploitation of groundwater in the area.     

Stratigraphy and sedimentary environments for cretaceous deposits in the southern part of the Var’egansk Megabar (Western Siberia)

Results of comprehensive studies of the Var’egansk Megabar sections in boreholes which penetrated the upper part of the Pokur Formation and the lower part of the Kuznetsovo Formation are presented. The stratigraphic range of the studied deposits spans the upper Albian-lower Turonian. Palynological and lithofacies studies resulted in the refinement of sedimentary paleoenvironments in the region under study. It has been confirmed that the upper part of the Pokur Formation was formed under coastal-marine conditions; it characterizes mainly different deltaic facies. Sandy rocks of the Pokur Formation upper part mostly formed in delta channels, whereas silty-clayey rocks, in marshy-swamp environments. Deposition of the Kuznetsovo Formation is confined to a major sea transgression, and it proceeded under normal sea conditions.     

Comparative analysis of megaflood deposits and alluvium of the Chuya and Katun’ river valleys (Gorny Altai)

Sedimentary indicators of catastrophic glacial megafloods—plane-bedded angular gravel, cobbles, and boulders—are described in several sections of the high terraces of the Chuya River valley. The principal difference of these sediments from typical alluvium of this area is demonstrated. The clast roundness, grain size of clasts, and sedimentary structures of the high-terrace deposits of the Chuya and Katun’ valleys indicate the same facies originated through megaflood deposition. These results are at odds with ideas of alluvial, glacial, or glaciofluvial genesis of the high-terrace deposits of the Chuya River.     

The uranium content in Dictyonema shale of the Kaibolovo–Gostilitsy Area in the Baltic basin (Leningrad Region)

This paper reports the data on the uranium content in Dictyonema shale and phosphate rock in the Kaibolovo–Gostilitsy Area of the Baltic Basin (Leningrad Region). Specific features of the uranium ore in the studied area and stratigraphic rock sequence of the Early Ordovician Pakerort horizon are considered. A high uranium concentration in the Dictyonema shale layer has been determined, the correlation of uranium with other elements was defined, probable conditions of uranium ore genesis are described, and predicted uranium resources within the studied area are estimated.     

The distribution of calcareous nannofossils in the late Santonian–Late Maastrichtian deposits in the southwest of Iran (Khuzestan Province)

The first data on the distribution of calcareous nannofossils in the Behbehan section, the Kuh-e-Rish, are considered. According to the distribution of nannofossils, the Upper Cretaceous deposits of the section are subdivided into nine biostratigraphic zones. CC17 (Calculites obscurus zone) indicate the Late Santonian. Biozones CC18 (Aspidolithus parcus zone), CC19 (Calculites ovalis zone), CC20 (Ceratolithoides aculeus zone), CC21 (Quadrum sissinghii zone), and CC22 (Quadrum trifidum zone) represent the Campanian. Biozone CC23 (Tranolithus phacelosus zone) indicate the Late Campanian–Early Maastrichtian. Biozones CC24 (Reinhardtites levis zone) and CC25 (Arkhangelskiella cymbiformis zone) suggest the Middle and Late Maastrichtian, respectively. In the late Late Maastrichtian, due to decreasing in water depth at the study area, Nephrolithus frequens zone (CC26) defined in Tethysian domain was not recognized. The boundary between Gurpi–Pabdeh Formations represented a non-depositional period from the late Late Maastrichtian to the end of Early Paleocene. Also, it seems that predominant conditions of the sedimentary environment of Neotethys basin with the presence of index species calcareous nannofossils specified, which itself indicates that the warm climate and high depth of the basin in Late Santonian to Late Maastrichtian, in low latitudes has been prevalent.