西秦岭甘南早子沟石英闪长玢岩岩石成因及其地质意义

西秦岭造山带位于华北板块和华南板块之间,是我国中央造山带的重要组成部分,记录了东亚古特提斯洋东北支的演化历史,对于探讨华北板块和华南板块的碰撞过程具有重要意义。西秦岭广泛发育的早-中三叠世火成岩与勉略洋壳向北俯冲有关,但勉略洋壳的闭合时限仍有争议。因此本文对采自早子沟地区的石英闪长玢岩进行锆石U-Pb年代学、Lu-Hf同位素和全岩主微量地球化学分析,查明早子沟石英闪长玢岩成因及其构造演化背景,并进一步约束勉略洋壳闭合时间。锆石LA-ICP-MS U-Pb定年结果表明,石英闪长玢岩侵位年龄为～232Ma,为中三叠世岩浆活动的产物。石英闪长玢岩含有较高的Si O₂(56.18%～68.26%),K₂O为1.82%～3.70%,A/CNK值为0.73～1.07,是准铝质-弱过铝质的钙碱性-高钾钙碱性岩石。其富钾的特征,与中高钾基性下地壳部分熔融产生的熔体成分一致。轻重稀土分异明显,(La/Yb)_N比值为8.10～61.2,富集大离子亲石元素(K、Sr、Ba、Cs),亏损高场强元素Nb、Ta,具有弱负铕异常(δEu=0.65～0...     

西秦岭与赛什塘铜矿床有关的花岗质岩石岩浆源区特征及大地构造背景探讨

西秦岭赛什塘铜矿区内出露的三叠纪花岗质岩石有闪长玢岩、石英闪长岩、石英闪长玢岩、花岗斑岩和石英斑岩,其岩浆源区与形成构造环境可为古特提斯洋演化和区域成矿作用研究提供证据。岩石地球化学特征共同表明,这些花岗质岩石属于准铝质钙碱性-高钾钙碱性系列,为I型花岗岩;Mg#值变化较大(39~68),LREE富集,HREE亏损,(La/Yb)N比值介于8.50~22.9,具有Eu负异常,δEu介于0.28~0.78,同时富集大离子亲石元素Cs、Rb、K、Pb,亏损高场强元素Nb、Ta、Ti,呈现出与典型俯冲作用密切相关岛弧花岗岩相一致地球化学特征。石英闪长玢岩和石英斑岩SHRIMP锆石U-Pb年龄分别为219.0±2.3Ma和220.0±2.0Ma,锆石εHf(t)分别为-4.5~-2.1和-2.5~+1.0,对应二阶段模式年龄分别为1392~1544Ma和1190~1415Ma。结合前人对西秦岭三叠纪花岗岩以及其南侧阿尼玛卿蛇绿混杂带研究成果,本文认为赛什塘铜矿区花岗质岩石与西秦岭同时期花岗岩形成于与古特提斯洋向北俯冲密切相关的大陆边缘弧环境,其岩浆源区为中元古代下地壳变基性岩,且岩浆可能受到地幔物质混染。     

西秦岭早子沟金矿中酸性侵入岩地球化学、年代学特征及成矿地质体的确定

西秦岭早子沟金矿是与岩浆活动有关的特大型金矿床,矿区中酸性侵入岩集中发育,主要有闪长玢岩、黑云石英闪长玢岩、花岗斑岩、石英闪长岩4种岩石类型。岩石微量元素均表现出富集大离子亲石元素Rb、K,亏损高场强元素Nb、Ta、P、Ti的特征。稀土元素总量整体上黑云石英闪长玢岩>闪长玢岩>石英闪长岩,闪长玢岩、黑云母石英闪长玢岩、花岗斑岩具有弱-中等的负铕异常(δEu=0.60～0.89),深部石英闪长岩以不具Eu异常(δEu=0.96～1.07)、“Nb-Ta谷”较深明显区别于浅部脉岩。石英闪长岩锆石U-Pb年龄为230 Ma,晚于浅部脉岩10～20 Ma,与蚀变矿物绢云母年龄基本一致,推测金成矿可能始于230 Ma,主成矿期为230～211 Ma,深部石英闪长岩为早子沟金矿的成矿地质体。     

新疆东天山玉海铜钼矿区志留纪侵入体岩石成因及构造意义

文章对东天山玉海铜钼矿区含矿岩体石英闪长(玢)岩及围岩二长花岗岩的成岩年龄进行研究。LAMC-ICP-MS锆石U-Pb定年结果显示石英闪长(玢)岩形成于(427.80±0.98)Ma,即中志留世;二长花岗岩形成于(318.40±0.66)Ma,即晚石炭世。石英闪长(玢)岩w(SiO_2)为58.30%~64.28%,w(Al2O3)为15.24%~17.36%,w(MgO)为1.73%~4.80%,w(Y)为10.20×10~(-6)~17.40×10~(-6),w(Yb)为1.33×10~(-6)~1.98×10~(-6),石英闪长(玢)岩Sr/Y比值为41.58~79.22,(La/Yb)N为4.19~10.04,为类埃达克岩(adakite-like)。石英闪长(玢)岩具轻稀土元素富集、重稀土元素亏损的配分型式,Eu无异常或正异常,富集大离子亲石元素,亏损高场强元素,具有典型岛弧岩浆岩的特征。Sr-Nd同位素(εNd(t)=+5.4~+7.1,(87Sr/86Sr)i=0.703 59~0.703 83)表明其源区是亏损地幔。通过与土屋-延东斑岩矿床含矿岩体的对比研究,认为玉海石英闪长(玢)岩也形成于岛弧环境,但源区可能是俯冲流体改造过的地幔楔。综合区域早古生代岩浆岩的资料,认为大南湖-头苏泉岛弧带早古生代为不成熟弧环境,与准噶尔洋向南俯冲有关。     

新疆东准噶尔北缘顿巴斯套地区晚泥盆世石英闪长玢岩地球化学特征及构造意义

新疆顿巴斯套矿区石英闪长玢岩的研究对厘清古亚洲洋晚泥盆世的演化具有重要意义.新疆顿巴斯套矿区石英闪长玢岩位于东准噶尔盆地北缘,为确定其岩浆侵入活动时限和岩石成因,讨论准噶尔地块北侧的古亚洲洋在晚古生代早期的俯冲作用,开展锆石LA-ICP-MS U-Pb年代学、Hf同位素地球化学,全岩主微量元素地球化学、Sr-Nd同位素地球化学研究.矿区内石英闪长玢岩单颗粒锆石LA-ICP-MS U-Pb定年结果为378±2 Ma,指示晚泥盆世岩浆活动.石英闪长玢岩全岩SiO₂含量为54.94%~68.64%,富Na₂O（平均含量为4.34%）,Na₂O/K₂O为1.19~2.72,里特曼指数（σ）大多小于3.3,Fe₂O₃T含量为2.23%~5.65%、MgO含量为0.81%~2.77%、Al₂O₃含量为14.31%~16.99%,TiO₂含量为0.32%~1.02%,CaO含量为2.58%~4.97%,Mg#变化于38.1~51.2,A/CNK为0.83~1.08,属准铝质钙碱性-高钾钙碱性系列.岩石富集大离子亲石元素（LILE）和轻稀土元素（LREE）,亏损高场强元素（HFSE,如Nb、Ta、P、Ti）,稀土元素配分曲线右倾,具有明显的轻重稀土分异,基本无Eu异常.全岩有较低的（87Sr/86Sr）_i（0.703 783~0.703 901）,较高的ε_Nd（378 Ma）（+6.2~+6.7）,年轻的T_DM（560~608 Ma）,锆石ε_Hf（t）相对较高,变化于+12.1~+15.1,对应的一阶段模式年龄T_DM1（Hf）为403~516 Ma,显示亏损地幔源区特征.综合上述地球化学特征认为石英闪长玢岩为俯冲环境下洋壳部分熔融的产物,俯冲洋壳脱水产生的流体、熔体在上升过程中与地幔楔发生了交代反应.结合新疆北部蛇绿岩及东准噶尔北缘、阿尔泰南缘相关岛弧花岗岩、火山岩等综合对比,认为区内中-晚泥盆世存在古亚洲洋的南北双向俯冲.      

新疆巴尔鲁克地区石屋岩体的成因:锆石U-Pb年代学、岩石地球化学和Sr-Nd-Pb-Hf同位素制约

新疆巴尔鲁克地区石屋岩体主要由石英闪长玢岩、石英闪长岩组成。本文通过锆石U-Pb年代学、岩石地球化学和Sr-Nd-Pb-Hf同位素等研究,探讨其构造背景、岩石成因和成矿意义。LA-ICP-MS锆石U-Pb定年表明:石屋石英闪长玢岩的成岩年龄为322.1±1.5Ma,石英闪长岩的形成年龄为322.4±1.5Ma,二者形成时代为晚石炭世。石屋石英闪长玢岩和石英闪长岩地球化学特征相似,Mg~#为32.4~57.2,轻重稀土分馏较明显且富集轻稀土((La/Yb)N=2.36~6.04),Eu异常不明显,相对富集LILEs等,亏损Nb、Ta、P、Ti等高场强元素。Sr-Nd-Pb-Hf同位素显示:样品具有低的ISr值(0.7036~0.7045),正εNd(t)值(+4.61~+7.03),年轻的tDM1年龄(0.59~0.78Ga),初始铅同位素比值为(~(206)Pb/~(204)Pb)i=18.173~18.450,(~(207)Pb/~(204)Pb)i=15.542~15.562,(~(208)Pb/~(204)Pb)i=37.830~38.036,锆石εHf(t)值为+4.5~+15.3,t_(DM2)=0.36~0.62Ga。综合石屋岩体的地质、地球化学和年代学特征,认为石英闪长玢岩和石英闪长岩源区相同,它们均形成于晚石炭世早期俯冲背景下的岛弧环境,可能是在亏损玄武质岩浆(俯冲板片脱水交代地幔楔产生的上涌岩浆)底侵作用下,新生地壳发生部分熔融,并有部分玄武质岩浆加入,发生混合、侵位的产物。石屋岩体的形成环境及其岩浆演化过程可能有利于区内斑岩型铜矿化,其含矿性值得做进一步评价。     

江西省船坑铜矿成矿岩体地球化学特征、锆石U-Pb定年及地质意义

分析了船坑铜矿成矿岩体石英闪长玢岩主微量、稀土元素特征及锆石U-Pb测年数据,表明岩石具高钾偏铝质I型花岗岩特征,及岛弧成因岩浆特点;锆石稀土元素表明有地壳物质的加入,属壳幔混源。锆石U-Pb年龄162.9±3.6Ma,大致代表含矿岩体成岩年龄。该矿床形成于钦杭成矿带铜矿主成矿期,处于岩石圈拆沉或伸展-减薄的构造环境,受太平洋板块往欧亚大陆的俯冲的影响。     

滇西北松诺斑岩体岩石化学、锆石U-Pb年龄、Hf同位素特征及其构造背景

近年来,随着普朗和红山-红牛等大型-超大型铜矿的投产,滇西北格咱地区已成为我国重要的铜资源勘查开发基地,在该区寻找类似“普朗-红山式”斑岩-矽卡岩型大型-超大型铜多金属矿床是本区找矿勘查的热点。本次在开展松诺地区铜资源远景调查的基础上,对松诺含矿石英闪长玢岩开展了锆石U-Pb年代学研究,结果显示石英闪长玢岩体锆石U-Pb年龄分别为229.7±1.1Ma和222.3±0.7Ma,早于矿区石英二长斑岩体,为晚三叠世岩浆活动的产物。石英闪长玢岩和石英二长斑岩岩石地球化学特征显示,为准铝-弱过铝质的高钾钙碱性系列I型花岗岩,稀土元素配分曲线均表现为轻稀土元素富集,重稀土元素相对亏损,具弱的负Eu异常,富集Rb、Ba等大离子亲石元素,亏损Ta、Nb、Ti等高场强元素。综合岩相学、岩石化学、锆石Hf同位素和全岩Sr-Pb同位素等特征,认为松诺含矿斑岩体形成于印支期甘孜-理塘洋壳向西俯冲的岩浆弧环境,岩浆源区为俯冲流体交代的岩石圈富集地幔,岩浆上升过程经历了壳源沉积物质混染。矿区具备弧环境斑岩型铜多金属矿床的成矿条件,且蚀变矿化强烈,找矿前景良好,值得进一步深入研究和开展勘查工作。     

江西德兴斑岩铜矿石英闪长玢岩成因及成矿学意义

为探究石英闪长玢岩成因及幔源基性岩浆对斑岩铜矿的贡献,本文选取德兴矿床石英闪长玢岩开展了锆石U-Pb定年、Hf同位素和全岩地球化学研究。获得石英闪长玢岩LA-ICP-MS锆石U-Pb年龄为169 Ma,与成矿花岗闪长斑岩侵位时间一致,岩体为中侏罗世岩浆活动的产物。石英闪长玢岩具有低的SiO₂(58.41%~63.12%)和K₂O(1.68%~2.94%)含量及A/CNK值(0.85~1.04),富集大离子亲石元素和轻稀土元素,亏损高场强元素Nb、Ta、Ti和重稀土元素,属于钙碱性到高钾钙碱性系列岩石。具有相对亏损的锆石Hf同位素组成,εHf(t)=2.20~7.93(最大值7.93),指示其源区为岩石圈地幔。锆石稀土元素配分模式图显示出明显的正Ce异常,岩浆氧逸度(lg f_O2)为-20.05~-6.66,达到磁铁矿-赤铁矿氧逸度等级,指示石英闪长玢岩结晶自高氧逸度岩浆。全岩地球化学特征显示,德兴石英闪长玢岩与成矿花岗闪长斑岩及其暗色包体符合岩浆混合的演化趋势,说明成矿花岗闪长斑岩可能是中侏罗世幔源基性岩浆和地壳酸性岩浆大规模混合作用的产物,并且石英闪长玢岩代表了岩浆混合过程中的幔源基性端员。结合前人研究成果,认为在中侏罗世伸展构造背景下,软流圈物质上涌导致新元古代受交代的岩石圈地幔部分熔融形成幔源基性岩浆,基性岩浆的底侵作用诱发下地壳物质熔融并与之发生一定程度的岩浆混合作用,形成了花岗闪长斑岩的母岩浆。高氧逸度幔源岩浆的加入可抑制斑岩体系硫化物的过早饱和,同时为德兴矿床注入了成矿所需的部分挥发分和金属元素。     

藏南努日铜-钨-钼矿床晚白垩世石英闪长岩U-Pb定年及其地球化学特征

藏南努日矿床位于冈底斯成矿带南缘,前人获得的辉钼矿Re-Os同位素年龄为23 Ma,与明则和程巴矿床成矿时代一致,但矿区内至今未发现与矿化有关的成矿斑岩体。本文报道了努日矿区新发现的与矿化关系密切的石英闪长岩的地球化学特征,获得石英闪长岩的LA-ICP-MS锆石U-Pb年龄为93.42±0.76 Ma,与同一成矿带内桑布加拉和克鲁铜金矿成矿时代一致(90~93 Ma),表明矿区可能存在两期成矿事件。石英闪长玢岩的主量微量元素SiO_2含量为57.19%~58.23%,A1_2O_3含量为15.78%~16.03%,MgO含量为4.74%~5.32%,Mg~#指数为65.2~67.3;富集大离子亲石元素(Rb、Sr、Ba、U等)及轻稀土元素,亏损高场强元素,显示出埃达克岩特征。研究表明石英闪长玢岩形成于洋壳俯冲阶段的弧岩浆岩,洋壳熔融形成的母岩浆侵入近地表形成早期铜多金属矽卡岩矿化。晚白垩世成矿事件的发现进一步佐证了研究区存在两期矿化叠加事件,拓展了研究区找矿方向。     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Geology, mineralogy, and PGE mineralization of the copper-nickel occurrences of the Kvinum ore field, Sredinny Range, Kamchatka

The geology and mineralogy of host metamorphic rocks, the mineralogy of sulfide ores, and the distribution of PGE mineralization were studied in detail for the Kvinum-1 and Kvinum-2 copper-nickel occurrences of the Kvinum ore field, which are the most promising targets for the copper-nickel-PGE mineralization of the Sredinny Range of Kamchatka. It was established that stringer-disseminated and massive copper-nickel ores are localized in amphibole peridotites, cortlandites, and form ore bodies varying from tens of centimeters to 5–20 m thick among the layered cortlandite-gabbroid massifs. The massive sulfide ores were found only at the bottom of cortlandite bodies and upsection grade into stringer-disseminated and disseminated ores. Pyrrhotite, chalcopyrite, and pentlandite are the major ore minerals with a sharply subordinate amount of pyrite, sphalerite, galena, arsenopyrite, and löllingite. Besides pentlandite, the Ni-bearing minerals include sulforasenides (gersdorffite), arsenides (nickeline), and tellurides (melonite) of nickel. It was found that PGE mineralization represented by antimonides (sudburyite) and tellurobismuthides (michenerite) of Pd with sharply subordinate platinum arsenide (sperrylite) is confined to the apical parts of massive sulfide zones and the transition zone to the stringer-disseminated ores. Ore intervals enriched in arsenides and tellurides of Ni, Pd, and Bi contain high-purity gold. In the central parts of the orebodies, the contents of PGE and native gold are insignificant. It is suggested that the contents of major sulfide minerals and the productivity of PGE mineralization in the cortlandites are defined by combined differentiation and sulfurization of ultramafic derivatives under the effect of fluids, which are accumulated at the crystallization front and cause layering of parental magmas with different sulfur contents. The fluid-assisted layering of mafic-ultramafic massifs resulted in the contrasting distribution of PGM in response to uneven distribution of sulfur (as well as As, Te, and Bi) during liquid immiscibility. The productivity of PGE mineralization significantly increases with increasing contents of S, As, Te, and Bi (elements to which Pt and, especially, Pd have high affinity) in fluids.     

Depth of the base of the Jackson aquifer, based on geophysical exploration, southern Jackson Hole, Wyoming, USA

 A geophysical survey was conducted to determine the depth of the base of the water-table aquifer in the southern part of Jackson Hole, Wyoming, USA. Audio-magnetotellurics (AMT) measurements at 77 sites in the study area yielded electrical-resistivity logs of the subsurface, and these were used to infer lithologic changes with depth. A 100–600 ohm-m geoelectric layer, designated the Jackson aquifer, was used to represent surficial saturated, unconsolidated deposits of Quaternary age. The median depth of the base of the Jackson aquifer is estimated to be 200 ft (61 m), based on 62 sites that had sufficient resistivity data. AMT-measured values were kriged to predict the depth to the base of the aquifer throughout the southern part of Jackson Hole. Contour maps of the kriging predictions indicate that the depth of the base of the Jackson aquifer is shallow in the central part of the study area near the East and West Gros Ventre Buttes, deeper in the west near the Teton fault system, and shallow at the southern edge of Jackson Hole. Predicted, contoured depths range from 100 ft (30 m) in the south, near the confluences of Spring Creek and Flat Creek with the Snake River, to 700 ft (210 m) in the west, near the town of Wilson, Wyoming. Received, May 1997 · Revised, February 1998 · Accepted, April 1998     

西藏南木林县秦马弄地区二长花岗岩体岩石成因

以出露在西藏南木林县秦马弄地区二长花岗岩体为研究对象,从野外地质调查、岩石学、LA-ICP-MS锆石U-Pb定年、元素和Lu-Hf同位素地球化学等方面对其进行了分析研究。结果显示：秦马弄地区二长花岗岩体类似于A型花岗岩,形成于古近纪(E1),其LA-ICP-MS锆石U-Pb年龄为(62.0±0.5)~(63.0±0.5) Ma;岩体形成的温度较高(锆石饱和温度为745~805 ℃,平均766 ℃);岩石富SiO2(72.6%~75.0%)、Na2O(2.86%~3.59%)和K2O(4.12%~5.25%),贫CaO(0.72%~1.39%)和MgO(0.26%~0.36%),高FeOT/MgO值(7.26~10.3),属高钾钙碱性系列,弱过铝质;岩石具明显的负Eu异常(Eu/Eu*=0.40~0.70),普遍表现出Ba、Sr、P、Ti元素的亏损和Rb、Th、K、Zr、Hf元素的富集。εHf(t)值为-4.7~-1.8,其两阶段地壳Hf模式年龄tDM2为(1.1~1.3) Ga。秦马弄A型花岗岩体是冈底斯基底地壳物质部分熔融的岩浆产物,形成于古近纪印度板块与欧亚板块俯冲碰撞引起的总体为岛弧背景下的局部拉张构造环境。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.