On the depth-dependent production of long-lived spallogenic53Mn in the St. Severin chondrite

The contents of spallogenic⁵³Mn and target elements for its production were determined in 80- to 400-mg samples from 13 different locations of the LL6 chondrite St. Severin, along the 34.8-cm drill core AIII. The⁵³Mn content increases from the surface to the center of the stone by ≈30%. The variation with depth is satisfactorily described by several models, presuming that appropriate primary and secondary particle fluxes are chosen. The⁵³Mn saturation activities (⁵³Mn^*) are linearly correlated with the spallogenic³He/²¹Ne and²²Ne/²¹Ne ratios, which suggests the possibility to eliminate uncertainties in the determination of⁵³Mn cosmic ray exposure ages arising from depth effects and terrestrial residence times.     

The reaction Mg(n,α)Ne at 14.1 and 14.7 MeV: cross sections and implications for meteorites

Mass spectrometric analyses of neutron-irradiated targets of natural magnesium yield cross sections of59 ± 14,160 ± 8, and11.0 ± 3.3mb for²⁰Ne,²¹Ne, and²²Ne, respectively, at 14.1 MeV and of94 ± 8,152 ± 12, and13.0 ± 2.0mb at 14.7 MeV. With the incorporation of these cross sections, calculations modeling cosmic-ray interactions in stony meteoroids of radii 20 and 26 cm predict that between the surface and center the²²Ne/²¹Ne ratio falls more than 10% while the²¹Ne production rate rises about 30%. The reaction²⁴Mg(n,α)²¹Ne predominantly controls these trends: the²²Ne/²¹Ne ratio due to magnesium decreases over 15% while that due to silicon remains constant with increasing depth. The calculations are compared with published neon measurements for the Keyes and St. Séverin meteorites.     

Cosmic ray exposure ages of chondrites,pre-irradiation and constancy of cosmic ray flux in the past

A systematic calibration of the production rate of one specific cosmic-ray-produced nuclide in chondrites, that of²¹Ne, was achieved by using four independent methods:P₂₁(1.11) = 0.507 ± 0.039, 0.302 ± 0.013, 0.312 ± 0.017and0.292 ± 0.019 (in units of 10^?8 cm³ STP/g My) based on²⁶Al-age,⁵³Mn-age,⁸¹Kr-⁸³Kr and²²Na-²²Ne methods, respectively. These production rates are all normalized to a shielding parameter ratio²²Ne/²¹Ne= 1.11 and to the chemical composition of L chondrites. The results obtained by the latter three methods are in good agreement, but they disagree in a systematic way with the²⁶Al-age calibration. Based on these results, we recommend a valueP₂₁(1.11) = 0.31 and a production rate equation:P₂₁ = 4.845 P₂₁ (1.11) F[21.77(²²Ne/²¹Ne) ? 19.32]^?, whereF = 1.00 for L and LL, andF = 0.93 for H chondrites, for the calculation of cosmic ray exposure ages on the basis of Ne concentrations. In an attempt to assess possible causes for this discrepancy, we discuss the²⁶Al half-life measurements, we evaluate effects resulting from pre-irradiation of meteorites, and we discuss the evidence regarding the constancy of the cosmic ray flux in the past, in the light of some recent astronomical observations.     

Investigations on cosmic-ray-produced nuclides in iron meteorites, 3. Exposure ages,meteoroid sizes and sample depths determined by mass spectrometric analyses of potassium and rare gases

Three physical quantities define the essentials of the cosmic ray exposure history of a sample of an iron meteorite: (1) the cosmic ray exposure age T, (2) the pre-atmospheric “size” S of the irradiated body, and (3) the location, i.e. the “depth” D, of the samples within the body. To establish these quantities for a given sample three independent quantities must be determined experimentally. In the present work T is ascertained by the ⁴¹K/⁴⁰K method and the ⁴He and ²¹Ne concentrations (C₄ and C₂₁) are measured by the isotope dilution method. Signer and Nier's evaluation of the rare gas distribution in the meteorite Grant and the measured exposure age for this meteorite provide the relationships allowing to ascertain for any meteorite the quantities S and D from the ²¹Ne production rate (P₂₁ = C₂₁/T) and the ⁴He/²¹Ne ratio.Earlier measurements have provided data on the isotopic composition of potassium in 74 different iron meteorites. New rare gas measurements are reported for some 40 samples. Results on the age, size and depth are obtained for almost 60 samples. These data suggest that Signer and Nier's model is well suited for describing not only the rare gas distribution in a single selected meteorite (Grant) but also the exposure histories of the great majority of all irons. For a few samples, however, secondary breakups of the meteoroid and a two- or multiple-stage irradiation must be invoked. Further measurements are proposed for testing and, possibly, refining the still somewhat uncertain relationships between the abundances of cosmogenic nuclides and the quantities T, S, and D in very large meteorites.Histograms are presented showing the age distributions for irons of different chemical groups and of different size ranges.The feasibility and the relative merits of other methods for the determination of T, S, and D are discussed.     

Cosmogenic neon in ultramafic nodules from Asia and in quartzite from Antarctica

We have performed systematic analyses of both cosmogenic ³He (³He_c) and cosmogenic ²¹Ne (²¹Ne_c) in ultramafic xenoliths from Central Asia and in a quartz sample from Antarctica. Five xenoliths, which show no or insignificant ²¹Ne_c excesses, were used to estimate the initial ⁴He/³He ratio of 90,470 in the subcontinental lithospheric mantle under the Baikal extension zone. Seven xenoliths show large ²¹Ne/²²Ne anomalies ranging up to 0.204 and ⁴He/³He down to 31,000, due to the presence of cosmogenic ²¹Ne and ³He. The (³He/²¹Ne)_c ratio is 1.41 ± 0.22 in the xenoliths and 2.76 in the quartzite. This difference is due to the dependence of the ²¹Ne_c production rate on the elemental composition of the target material. We estimated the ³He_c and ²¹Ne_c production rates at different locations worldwide and calculated the ³He_c and ²¹Ne_c exposure ages. These ages range between 7100 and 28,000 years for the xenoliths, and we determined their relative positions within the volcanic tuff layer. The mean ³He_c and ²¹Ne_c exposure ages of the quartz sample are 1.35 ± 0.07 and 2.21 ± 0.12 Ma, respectively. This difference is most probably related to ³He_c diffusive losses from the quartz mineral grains, even at low temperatures, due to the relatively high diffusion coefficient for cosmogenic ³He.     

Depth profile of53Mn in the lunar surface

Measurements of cosmic-ray produced⁵³Mn are reported for a series of lunar surface samples down to a depth of 416 g/cm². These results clearly illustrate the decrease in activity with depth as the incident galactic cosmic rays are absorbed. Below 60 g/cm² the production rate decreases exponentially with a mean length, λ, of about 220 g/cm². These results indicate that, at the Apollo 15 site, the lunar regolith has been unmixed, on a meter scale, for the last 5 my. The neutron activation technique for⁵³Mn, which allowed samples smaller than 200 mg to be used for these measurements, is described.     

Cosmogenic neon produced from sodium in meteoritic minerals

Cosmogenic neon in sodium-rich oligoclase feldspar from the ordinary chondrites St. Severin and Guaren?a is characterized by an unusually high²²Ne/²¹Ne = 1.50 ± 0.02. This high ratio is due to the cosmogenic²²Ne/²¹Ne production ratio in sodium which is 2.9 ± 0.3, two to three times the production ratio in any other target element. The relative production rate of²¹Ne per gram sodium is one quarter the production rate per gram magnesium. The striking enrichment of²²Ne relative to²¹Ne in sodium arises from enhanced indirect production from²³Na via²²Na.The unusual composition of cosmogenic neon in sodium and sodium-rich minerals explains the high²²Ne/²¹Ne ratios observed in inclusions of the Allende carbonaceous chondrite, and observed during low-temperature extraction of neon from ordinary chondrites. The isotopic composition of cosmogenic neon released during the stepwise heating of a trapped gas-rich meteorite containing sodium-rich phases can be expected to vary, and use of a constant cosmogenic neon composition to derive the composition of the trapped gas may not be justified. Preferential loss of this²²Ne-enriched cosmogenic neon from meteoritic feldspar can result in a 2–3% drop in the measured cosmogenic²²Ne/²¹Ne ratio in a bulk meteorite sample. This apparent change in composition can lead to overestimation of the minimum pre-atmospheric mass of the meteorite by a factor of two.     

14C-39ArMe correlations in chondrites and their pre-atmospheric size

Cosmogenic¹⁴C has been measured in 12 chondrites and the stone phase of the mesosiderite Bondoc. For the chondrites analysed the activities vary between 44 and 72 dpm/kg; the low value of (4.5 ± 0.9) dpm/kg for Bondoc is essentially due to its large pre-atmospheric size and not to a terrestrial age of several half-lives of¹⁴C.In eight cases³⁹Ar in the metal phase from the same meteorite specimens had been measured previously. The results are combined to derive the pre-atmospheric radiiR₀ of the meteoroids and depth of burial of the samples investigated. Values ofR₀ between 35 and 82 cm are obtained; of 14 samples ten came from a depth of 10 cm or less. The preponderance of samples from shallow depths is ascribed to asymmetrical ablation losses of the meteoroids during their passage through the atmosphere.A compilation of all published¹⁴C concentrations in chondrites shows that the variations between different specimens from thesame meteorites are almost as large as those for samples fromdifferent meteorites. Thus, there is no need to invoke different orbits of the meteoroids and a strong spatial gradient in the primary cosmic-ray intensity to explain variations of low-energy-produced cosmogenic nuclides in different meteorites.     

Evaluation of cosmogenic 3He and 21Ne production rates in olivine and pyroxene from two Pleistocene basalt flows,western Grand Canyon,AZ, USA

Combining cosmogenic ³He and ²¹Ne (³He_c and ²¹Ne_c) measurements on both pyroxene and olivine from the Pleistocene Bar Ten flows (85–107 ka) greatly increases our ability to evaluate the accuracy of ³He_c and ²¹Ne_c production rates and, therefore, ³He_c and ²¹Ne_c surface exposure ages. Comparison of ³He_c and ²¹Ne_c age-pairs yielded by experimentally determined production rates and composition-based model calculations indicates that the former give more accurate surface exposure ages than the latter in this study. However, experimental production rates should be adjusted to the composition of the minerals being analyzed to obtain the best agreement between ³He_c and ²¹Ne_c ages for any given sample. ²¹Ne_c/³He_c values are 0.400 ± 0.029 and 0.204 ± 0.014 for olivine and pyroxene, respectively, in Bar Ten lava flows, in agreement with previously published values, and indicate that ²¹Ne_c/³He_c in olivine and pyroxene is not affected by erosion and remains constant with latitude, elevation, and time (up to 10 Myr). Samples with ²¹Ne_c/³He_c that do not agree with these values may indicate the presence of non-cosmogenic helium and/or neon. The neon three-isotope diagram can also indicate whether or not all excess neon in mineral separates comes from cosmogenic sources. An error-weighted regression for olivine defines a spallation line [y = (1.033 ± 0.031)x + (0.09876 ± 0.00033)], which is indistinguishable from that for pyroxene (Schäfer et al., 1999). We have derived a production rate of 25 ± 8 at/g/yr for ²¹Ne_c in clinopyroxene (En_43–44) based on the ⁴⁰Ar/³⁹Ar age of the upper Bar Ten flow. Our study indicates that the production rate of ²¹Ne_c in olivine may be slightly higher than previously determined. Cosmogenic ³He and ²¹Ne remain extremely useful, particularly when paired, in determining accurate eruption ages of young olivine- and pyroxene-rich basaltic lava flows.     

Determination of both exposure time and denudation rate from an in situ-produced 10Be depth profile: A mathematical proof of uniqueness. Model sensitivity and applications to natural cases

Measurements of radioactive in situ-produced cosmogenic nuclide concentrations in surficial material exposed to cosmic rays allow either determining the long-term denudation rate assuming that the surface studied has reached steady-state (where production and losses by denudation and radioactive decay are in equilibrium) (infinite exposure time), or dating the initiation of exposure to cosmic rays, assuming that the denudation and post-depositional processes are negligible. Criteria for determining whether a surface is eroding or undergoing burial as well as quantitative information on denudation or burial rates may be obtained from cosmogenic nuclide depth profiles. With the refinement of the physical parameters involved in the production of in situ-produced cosmogenic nuclides, a unique well-constrained depth profile now permits determination of both the exposure time and the denudation rate affecting a surface. In this paper, we first mathematically demonstrate that the exponential decrease of the in situ-produced ¹⁰Be concentrations observed along a depth profile constrains a unique exposure time and denudation rate when considering both neutrons and muons. In the second part, an improved chi-square inversion model is described and tested in the third part with actual measured profiles.     

Cosmogenic 3He and 21Ne dating of biotite and hornblende

Stable cosmogenic isotopes such as ³He and ²¹Ne are useful for dating of diverse lithologies, quantifying erosion rates and ages of ancient surfaces and sediments, and for assessing complex burial histories. Although many minerals are potentially suitable targets for ³He and ²¹Ne dating, complex production systematics require calibration of each mineral–isotope pair. We present new results from a drill core in a high-elevation ignimbrite surface, which demonstrates that cosmogenic ³He and ²¹Ne can be readily measured in biotite and hornblende. ²¹Ne production rates in hornblende and biotite are similar, and are higher than that in quartz due to production from light elements such as Mg and Al. We measure ²¹Ne_hbl/²¹Ne_qtz = 1.35 ± 0.03 and ²¹Ne_bio/²¹Ne_qtz = 1.3 ± 0.02, which yield production rates of 25.6 ± 3.0 and 24.7 ± 2.9 at g^? 1 yr^? 1 relative to a ²¹Ne_qtz production rate of 19.0 ± 1.8 at g^? 1 yr^? 1. We show that nucleogenic ²¹Ne concentrations produced via the reaction ¹⁸O(α,n)²¹Ne are manageably small in this setting, and we present a new approach to deconvolve nucleogenic ²¹Ne by comparison to nucleogenic ²²Ne produced from the reaction ¹⁹F(α,n)²²Ne in F-rich phases such as biotite. Our results show that hornblende is a suitable target phase for cosmogenic ³He dating, but that ³He is lost from biotite at Earth surface temperatures. Comparison of ³He concentrations in hornblende with previously measured mineral phases such as apatite and zircon provides unambiguous evidence for ³He production via the reaction ⁶Li(n,α)³H → ³He. Due to the atypically high Li content in the hornblende (~ 160 ppm) we estimate that Li-produced ³He represents ~ 40% of total ³He production in our samples, and must be considered on a sample-specific basis if ³He dating in hornblende is to be widely implemented.     

Investigations on cosmic-ray-produced nuclides in iron meteorites, 2. New results on41K/40K-4He/21Ne exposure ages and the interpretation of age distributions

The cosmic ray exposure ages of 16 iron meteorites were determined by the⁴¹K/⁴⁰K-⁴He/²¹Ne method. The ages measured in the present and in previous experiments are summarized and presented in form of various histograms characterizing the age distributions of the different chemical groups separately. Age clustering at 650 Ma (mega years) is typical for the group IIIAB. Age clustering at 400 Ma is observed for the IVA irons. Quasi-continuous age distributions are found for the groups IA, IIA, IIB, IVB and for the anomalous irons. The following interpretation is offered. The IIIA and IIIB irons have initially been core material of the same parent asteroid and were ejected in consequence of a single impact event about 650 Ma ago. The IVA irons represent core material of another asteroid which was hit and partially disrupted in consequence of an impact event about 400 Ma ago. The group IA exhibits meteorites with ages between 200 and 1200 Ma. The quasi-continuous character of this age distribution and cosmochemical evidence indicate for these irons a raisin-bread-like character of their initial distribution within the silicate mantle of their parent asteroid. In consequence of several or, perhaps, of many crater-forming impact events the mantle material was gradually destructed and ejected. In the age distribution of the IIA hexahedrites, ages <300 Ma predominate and ages >600 Ma seem to be missing. In attempting to understand this, the possibility must be taken into consideration that the mean life-time of hexahedrites in the interplanetary space might be shorter than that of other irons. The cause might be that the hexahedrite single crystals are perhaps easier cleavable in the space environment. A similar kind of selective mass wastage appears also to be the cause for the absence of stone meteorites with high exposure ages.     

26Al in iron meteorites and the constancy of cosmic ray intensity in the past

Cosmic-ray-produced²⁶Al in iron meteorites has been measured by low-level γγ-coincidence counting. The²⁶Al activities, in dpm/kg, are: Aroos3.0 ± 1.0, Braunau2.6 ± 0.5. Kayakent4.6 ± 1.5, N'Goureyma4.4 ± 1.1, Okahandja3.6 ± 0.9, Treysa4.0 ± 0.5. Exposure ages based on²⁶Al/²¹Ne are in agreement, within experimental error(±20%), with those based on³⁶Cl/³⁶Ar and³⁹Ar/³⁸Ar but the ages based on⁴⁰K/⁴¹K are higher by about 50%. The difference in exposure ages is probably caused by a real change of the cosmic ray intensity in the inner solar system.     

Trapped solar wind He,Ne, and Ar and energetic He in Surveyor 3

The Apollo 12 mission brought back sections of the Surveyor 3 vehicle suitable for mass spectrometric studies of implanted solar wind and solar cosmic rays. Using this method, we have determined an average solar wind ⁴He flux of 6.1 × 10⁶ ions/cm² sec for the 31 months of exposure. We have also measured ⁴He/³He= 2700 ± 50;⁴He/²⁰Ne= 410 ± 30;²⁰Ne/²²Ne= 13.5 ± 0.2;²⁰Ne/³⁶Ar= 24.5 ± 2.5; and ³⁶Ar/³⁸Ar= 5.41 ± 0.20. These measurements provide solar wind values averaged over considerably longer periods of time than the Apollo Solar Wind Composition experiments and suggest that the short term SWC measurements during a period of high solar activity may not be a reliable measure of average solar wind composition.     

Trapped solar and cosmogenic noble gas abundances in Apollo 15 and 16 deep drill samples

Abundances and isotopic compositions of all the stable noble gases have been measured in 19 different depths of the Apollo 15 deep drill core, 7 different depths of the Apollo 16 deep drill core, and in several surface fines and breccias. All samples analyzed from both drill cores contain large concentrations of solar wind implanted gases, which demonstrates that even the deepest layers of both cores have experienced a lunar surface history. For the Apollo 15 core samples, trapped⁴He concentrations are constant to within a factor of two; elemental ratios show even greater similarities with mean values of⁴He/²²Ne= 683±44,²²Ne/³⁶Ar= 0.439±0.057,³⁶Ar/⁸⁴Kr= 1.60±0.11·10³, and⁸⁴Kr/¹³²Xe= 5.92±0.74. Apollo 16 core samples show distinctly lower⁴He contents,⁴He/²²Ne(567±74), and²²Ne/³⁶Ar(0.229±0.024), but their heavy-element ratios are essentially identical to Apollo 15 core samples. Apollo 16 surface fines also show lower values of⁴He/²²Ne and²²Ne/³⁶Ar. This phenomenon is attributed to greater fractionation during gas loss because of the higher plagioclase contents of Apollo 16 fines. Of these four elemental ratios as measured in both cores, only the²²Ne/³⁶Ar for the Apollo 15 core shows an apparent depth dependance. No unambiguous evidence was seen in these core materials of appreciable variations in the composition of the solar wind. Calculated concentrations of cosmic ray-produced²¹Ne,⁸⁰Kr, and¹²⁶Xe for the Apollo 15 core showed nearly flat (within a factor of two) depth profiles, but with smaller random concentration variations over depths of a few cm. These data are not consistent with a short-term core accretion model from non-irradiated regolith. The Apollo 15 core data are consistent with a combined accretion plus static time of a few hundred million years, and also indicate variable pre-accretion irradiation of core material. The lack of large variations in solar wind gas contents across core layers is also consistent with appreciable pre-accretion irradiation. Depth profiles of cosmogenic gases in the Apollo 16 core show considerably larger concentrations of cosmogenic gases below ～65 cm depth than above. This pattern may be interpreted either as an accretionary process, or by a more recent deposition of regolith to the upper ～70 cm of the core. Cosmogenic gas concentrations of several Apollo 16 fines and breccias are consistent with ages of North Ray Crater and South Ray Crater of ～50·10⁶ and ～2·10⁶ yr, respectively.     

Noble gases,KrKr ages, andBe of chrondrites from China

A comprehensive study of the cosmic-ray exposure history of five ordinary chondrites from China was carried out using measurements of the noble gas isotopic abundances and¹⁰Be concentrations. The following average cosmic-ray exposure ages, based on cosmogenic²¹Ne and on⁸¹KrKr dating were obtained: Zhaodong (L4) — 15.7 ± 3.0 m.y., Nan Yang Pao (L6) — 48 ± 10.0 m.y., Guangrao (L6) — 16.8 ± 3.5 m.y., and Lunan (H6) — 26.7 ± 5.0 m.y. The H5 chondrite Zaoyang was exposed for only 0.90 ± 0.12 m.y. to galactic cosmic rays as calculated from the¹⁰Be activity and from the low amounts of cosmic-ray-produced noble gases. The Zhaodong chondrite contains large amounts of⁸⁰Kr and⁸²Kr produced by neutron capture of bromine. From the high slowing down density for neutrons we derive a preatmospheric mass of more than 1800 kg for this meteorite.     

Cosmogenic 21Ne analysis of individual detrital grains: Opportunities and limitations

We use a numerical model describing cosmogenic nuclide acquisition in sediment moving through the upper Gaub River catchment to evaluate the extent to which aspects of source area geomorphology and geomorphological processes can be inferred from frequency distributions of cosmogenic ²¹Ne (²¹Ne_c) concentrations in individual detrital grains. The numerical model predicts the pathways of sediment grains from their source to the outlet of the catchment and calculates the total ²¹Ne_c concentration that each grain acquires along its pathway. The model fully accounts for variations in nuclide production due to changes in latitude, altitude and topographic shielding and allows for spatially variable erosion and sediment transport rates. Model results show that the form of the frequency distribution of ²¹Ne_c concentrations in exported sediment is sensitive to the range and spatial distribution of processes operating in the sediment's source areas and that this distribution can be used to infer the range and spatial distribution of erosion rates that characterise the catchment. The results also show that lithology can affect the form of the ²¹Ne_c concentration distribution indirectly by exerting control on the spatial pattern of denudation in a catchment. Model results further indicate that the form of the distribution of ²¹Ne_c concentrations in the exported sediment can also be affected by the acquisition of ²¹Ne_c after detachment from bedrock, in the diffusive (hillslope) and/or advective (fluvial) domains. However, for such post‐detachment nuclide acquisition to be important, this effect needs to at least equal the nuclide acquisition prior to detachment from bedrock. Copyright © 2009 John Wiley and Sons, Ltd.     

Production of radionuclides by cosmic rays at mountain altitudes

Production rates of²²Na (T_1/2 = 2.6years) from aluminium by the action of cosmic rays are measured at the Mont Blanc (altitude 4600 m), the Aiguille du Midi (3840 m), and the Col du Lautaret (2070 m). They are2.3 ± 0.5,1.8 ± 0.3,and0.77 ± 0.18 atoms min^?1 kg^?1, respectively, in good agreement with the calculated production rates, 2.4, 1.7 and 0.6 atoms min^?1 kg^?1, respectively, at the three stations.Production rates of²⁴Na (T_1/2 = 15hours) from aluminium and magnesium are also measured at the Aiguille du Midi; the observed rates of3.4 ± 0.4and6.0 ± 1.7 atoms min^?1 kg^?1, respectively, agree well with the theoretically expected rates of 3.7 and 5.6 atoms min^?1 kg^?1.The production rates of³H,⁷Be,¹⁰Be,¹⁴C,²²Na,²⁶Al,³⁶Cl,³⁷Ar,³⁹Ar,⁵³Mn,⁵⁴Mn, and⁵⁵Fe in terrestrial rocks by the action of cosmic rays are calculated in order to show the possibility of applying the measurements of these cosmogenic radionuclides to the earth science.     

Inter-comparison of cosmogenic in-situ He, Ne and Cl at low latitude along an altitude transect on the SE slope of Kilimanjaro volcano (3°S, Tanzania)

Because the intensity and energy spectrum of the cosmic ray flux are affected by atmospheric depth and geomagnetic-field strength, cosmogenic nuclide production rates increase considerably with altitude and to a lesser degree with latitude. The scaling methods used to account for spatial variability in production rates assume that all cosmogenic nuclides have the same altitude dependence. In this study we evaluate whether the production rates of cosmogenic ³⁶Cl, ³He and ²¹Ne change differently with altitude, which is plausible due to the different threshold energies of their production reactions. If so, nuclide-specific scaling factors would be required.Concentrations of the three cosmogenic nuclides were determined in mafic phenocrysts over an altitude transect between 1000 and 4300 m at Kilimanjaro volcano (3°S). Altitude dependence of relative production rates was assessed in two ways: by determination of concentration ratios and by calculation of apparent exposure age ratios for all nuclide pairs. The latter accounts for characteristics of ³⁶Cl that the stable nuclides ³He and ²¹Ne do not possess (radioactive decay, high sensitivity to mineral composition and significant contributions from production reactions other than spallation). All ratios overlap within error over the entire transect, and altitudinal variation in relative production rates is not therefore evident. This suggests that nuclide-specific scaling factors are not required for the studied nuclides at this low-latitude location. However, because previous studies have documented anomalous altitude-dependent variations in ³He production at mid-latitude sites, the effect of latitude on cross-calibrations should be further evaluated.We determined cosmogenic ²¹Ne/³He concentration ratios of 0.1864 ± 0.0085 in pyroxenes and 0.377 ± 0.018 in olivines, agreeing with those reported in previous studies.Despite the absence of independently determined ages for the studied lava surfaces, the consistency in the dataset should enable progress to be made in the determination of the production rates of all three nuclides as soon as the production rate of one of the nuclides has been accurately defined.To our knowledge this is the first time that ³⁶Cl has been measured in pyroxene. The Cl extraction method was validated by measuring ³⁶Cl in co-existing plagioclase phenocrysts in one of the samples.