Phreatomagmatic boulder conglomerates at the tip of the ca 2772 Ma Black Range dolerite dyke,Pilbara Craton,Western Australia

Unusual volcanic conglomerates with a mixture of well-rounded granitic boulders (to 1.2 m diameter) derived from adjacent basement rocks, and smaller (1 – 10 cm) subspherical basaltic droplets with chilled margins occupy a linear zone along strike of the northern end of the Late Archaean Black Range dolerite dyke in the Pilbara Craton, Western Australia. The matrix of the volcanic conglomerates becomes more angular with decreasing grainsize and grades to rock flour, a trend opposite to that in sedimentary conglomerates. In other places, the matrix consists of chlorite that cuts through, and resorbs, granitic clasts, indicating an origin as volcanic melt. The volcanic conglomerates have peperitic contacts with immediately adjacent flows of the Mt Roe Basalt of the Fortescue Group. A welded volcanic tuff at the peperitic contact is dated at 2767 ± 3 Ma, within error of the 2772 ± 2 Ma Black Range dolerite dyke and the Mt Roe Basalt (2775 ± 10 Ma), confirming the contemporaneity of formation of these geological elements. Subsequent normal faulting has juxtaposed the higher level conglomerates down into their present exposure level along strike of the Black Range dolerite dyke. The linear zone of volcanic conglomerates is interpreted to represent a phreatomagmatic pebble dyke that formed immediately above, and as a result of intrusion of, the Black Range dolerite dyke. Interaction of magma with groundwater caused phreatomagmatic brecciation of the country rock, in situ milling of granitic boulders, incorporation of basaltic melt droplets, and the formation of a mixed matrix of devitrified volcanic glass and granitic material. This process was accompanied by along-strike epithermal Cu – Hg – Au mineralisation.     

An <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar,Rb/Sr,and stable isotope study of micas in low-grade fold-and-thrust belt: an example from the Swiss Helvetic Alps

White micas in carbonate-rich tectonites and a few other rock types of large thrusts in the Swiss Helvetic fold-and-thrust belt have been analyzed by ⁴⁰Ar/ ³⁹Ar and Rb/Sr techniques to better constrain the timing of Alpine deformation for this region. Incremental ⁴⁰Ar/ ³⁹Ar heating experiments of 25 weakly metamorphosed (anchizone to low greenschist) samples yield plateau and staircase spectra. We interpret most of the staircase release spectra result from variable mixtures of syntectonic (neoformed) and detrital micas. The range in dates obtained within individual spectra depends primarily on the duration of mica nucleation and growth, and relative proportions of neoformed and detrital mica. Rb/Sr analyses of 12 samples yield dates of ca. 10–39 Ma (excluding one anomalously young sample). These dates are slightly younger than the ⁴⁰Ar/ ³⁹Ar total gas dates obtained for the same samples. The Rb/Sr dates were calculated using initial ⁸⁷Sr/ ⁸⁶Sr ratios obtained from the carbonate-dominated host rocks, which are higher than normal Mesozoic carbonate values due to exchange with fluids of higher ⁸⁷Sr/ ⁸⁶Sr ratios (and lower ¹⁸O/ ¹⁶O ratios). Model dates calculated using ⁸⁷Sr/ ⁸⁶Sr values typical of Mesozoic marine carbonates more closely approximate the ⁴⁰Ar/ ³⁹Ar total gas dates for most of the samples. The similarities of Rb/Sr and ⁴⁰Ar/ ³⁹Ar total gas dates are consistent with limited amounts of detrital mica in the samples. The d ¹⁸O values range from 24–15‰ (VSMOW) for 2–6 µm micas and 27–16‰ for the carbonate host rocks. The carbonate values are significantly lower than their protolith values due to localized fluid-rock interaction and fluid flow along most thrust surfaces. Although most calcite-mica pairs are not in oxygen isotope equilibrium at temperatures of ca. 200–400 °C, their isotopic fractionations are indicative of either 1) partial exchange between the minerals and a common external fluid, or 2) growth or isotopic exchange of the mica with the carbonate after the carbonate had isotopically exchanged with an external fluid. The geological significance of these results is not easily or uniquely determined, and exemplifies the difficulties inherent in dating very fine-grained micas of highly deformed tectonites in low-grade metamorphic terranes. Two generalizations can be made regarding the dates obtained from the Helvetic thrusts: 1) samples from the two highest thrusts (Mt. Gond and Sublage) have all of their ⁴⁰Ar/ ³⁹Ar steps above 20 Ma, and 2) most samples from the deepest Helvetic thrusts have steps (often accounting for more than 80% of ³⁹Ar release) between 15 and 25 Ma. These dates are consistent with the order of thrusting in the foreland-imbricating system and increase proportions of neoformed to detrital mica in the more metamorphosed hinterland and deeply buried portions of the nappe pile. Individual thrusts accommodated the majority of their displacement during their initial incorporation into the foreland-imbricating system, and some thrusts remained active or were reactivated down to 15 Ma.     

Geology of the 2018 Winter Olympic site,Pyeongchang, Korea

We review the geology of the Gyeonggi Massif, Gyeonggi Marginal Belt, and Taebaeksan Basin of the Korean Peninsula, which are relevant to the 2018 Winter Olympic sites. Neoarchaean–Palaeoproterozoic gneisses and schists of the Gyeonggi Massif underwent two distinct collisional orogenies at the Palaeoproterozoic (1.88–1.85 Ga) and Triassic (245–230 Ma). These basement rocks are structurally overlain by a suite of Mesoproterozoic to Early Permian supracrustal rocks of the Gyeonggi Marginal Belt, consisting primarily of medium-pressure schists and amphibolites metamorphosed at ~270–250 Ma. In contrast, sedimentary successions in the Taebaeksan Basin, commonly fossiliferous, consist primarily of Early Cambrian–Middle Ordovician Joseon Supergroup and Late Carboniferous–Early Triassic Pyeongan Supergroup. The ‘Great Hiatus’ between the two supergroups is characteristic for the North China Craton. The marked contrast in tectonometamorphic evolution between the Taebaeksan Basin and Gyeonggi Marginal Belt suggests an existence of major suture in-between, which is most likely produced by the Permian–Triassic continental collision between the North and South China cratons. Finally, recent tectonics of the Korean Peninsula is governed by the opening of East Sea/Sea of Japan during the Late Oligocene–Early Miocene. This back-arc rifting event has resulted in an exhumation of the Taebaek Mountain Range, estimated to be 22 ± 3 Ma on the basis of apatite (U–Th)/He ages. Thus, high topography in the 2018 Winter Olympic sites is the consequence of Tertiary tectonics associated with the opening of a back-arc basin.     

Contact zone permeability at intrusion boundaries: new results from hydraulic testing and geophysical logging in the Newark Rift Basin, New York, USA

Hydraulic tests and geophysical logging performed in the Palisades sill and the underlying sedimentary rocks in the NE part of the Newark Rift Basin, New York, USA, confirm that the particular transmissive zones are localized within the dolerite-sedimentary rock contact zone and within a narrow interval below this contact zone that is characterized by the occurrence of small layers of chilled dolerite. Transmissivity values determined from fluid injection, aquifer testing, and flowmeter measurements generally fall in the range of 8.1E-08 to 9.95E-06 m²/s and correspond to various scales of investigation. The analysis of acoustic and optical BHTV images reveals two primary fracture sets within the dolerite and the sedimentary rocks—subhorizontal fractures, intersected by subvertical ones. Despite being highly fractured either with subhorizontal, subvertical or both fracture populations, the dolerite above and the sedimentary rocks below the contact zone and the zone with the layers of chilled dolerite are significantly less conductive. The distribution of the particular conductive intervals is not a function of the two dominant fracture populations or their density but rather of the intrusion path of the sill. The intrusion caused thermal fracturing and cracking of both formations, resulting in higher permeability along the contact zone.     

<Superscript>10</Superscript>Be, <Superscript>18</Superscript>O and radiogenic isotopic constraints on the origin of adakitic signatures: a case study from Solander and Little Solander Islands,New Zealand

Subduction-related Quaternary volcanic rocks from Solander and Little Solander Islands, south of mainland New Zealand, are porphyritic trachyandesites and andesites (58.20–62.19 wt% SiO₂) with phenocrysts of amphibole, plagioclase and biotite. The Solander and Little Solander rocks are incompatible element enriched (e.g. Sr ~931–2,270 ppm, Ba ~619–798 ppm, Th ~8.7–21.4 ppm and La ~24.3–97.2 ppm) with MORB-like Sr and Nd isotopic signatures. Isotopically similar quench-textured enclaves reflect mixing with intermediate (basaltic-andesite) magmas. The Solander rocks have geochemical affinities with adakites (e.g. high Sr/Y and low Y), whose origin is often attributed to partial melting of subducted oceanic crust. Solander sits on isotopically distinct continental crust, thus excluding partial melting of the lower crust in the genesis of the magmas. Furthermore, the incompatible element enrichments of the Solander rocks are inconsistent with partial melting of newly underplated mafic lower crust; reproduction of their major element compositions would require unrealistically high degrees of partial melting. A similar argument precludes partial melting of the subducting oceanic crust and the inability to match the observed trace element patterns in the presence of residual garnet or plagioclase. Alternatively, an enriched end member of depleted MORB mantle source is inferred from Sr, Nd and Pb isotopic compositions, trace element enrichments and εHf ? 0 CHUR in detrital zircons, sourced from the volcanics. ¹⁰Be and Sr, Nd and Pb isotopic systematics are inconsistent with significant sediment involvement in the source region. The trace element enrichments and MORB-like Sr and Nd isotopic characteristics of the Solander rocks require a strong fractionation mechanism to impart the high incompatible element concentrations and subduction-related (e.g. high LILE/HFSE) geochemical signatures of the Solander magmas. Trace element modelling shows that this can be achieved by very low degrees of melting of a peridotitic source enriched by the addition of a slab-derived melt. Subsequent open-system fractionation, involving a key role for mafic magma recharge, resulted in the evolved andesitic adakites.     

Apatite fission track and (U-Th)/He thermochronology from the Archean Tanzania Craton: Contributions to cooling histories of Tanzanian basement rocks

Borehole and surface samples from the Archean Tanzania Craton were analysed for apatite fission track(AFT) and(U-Th)/He data with the aim of deciphering cooling histories of the basement rocks. Fission track dates from borehole and outcrop samples are Carboniferous-Permian(345± 33.3 Ma to271±31.7 Ma) whereas(U-Th)/He dates are Carboniferous-Triassic(336±45.8 Ma to 213±29 Ma) for outcrop grains and are consistently younger than corresponding AFT dates. Single grain(U-Th)/He dates from the borehole are likely to be flawed by excessive helium implantation due to their very low effective uranium contents, radiation damage and grain sizes. All AFT and(U-Th)/He dates are significantly younger than the stratigraphic ages of their host rocks, implying that the samples have experienced Phanerozoic elevated paleo-temperatures. Considerations of the data indicate removal of up to 9 km overburden since the Palaeozoic.Thermal modelling reveals a protracted rapid cooling event commencing during the early Carboniferous(ca. 350 Ma) at rates of 46 m/Ma ending in the Triassic(ca. 220 Ma). The model also suggests minor cooling during the Cretaceous of the samples to surface temperatures. The suggested later cooling event remains to be tested. The major cooling phase during the Carboniferous is interpreted to be associated with compressional tectonics during the Variscan Orogeny sensu far field induced stresses. Coeval sedimentation in the Karoo basins in the region suggests that most of the cooling of cratonic rocks during the Carboniferous was associated with denudation.     

New <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar age constraints on cooling and unroofing history of the metamorphic host rocks (and igneous intrusion associates) from the Bulfat Complex (Bulfat area), NE-Iraq

The Northern Zagros Suture Zone (NZSZ), formed as a result of the collision between Arabian and Sanandaj-Sirjan microplate, is considered as part of the Zagros orogenic belt. NZSZ is marked by two allochthonous thrust sheets in upward stacking order: lower and upper allochthon. The Bulfat complex is a part of the upper allochthon or “Ophiolite-bearing terrane” of Albian-Cenomenion age (97–105 Ma). Voluminous highly sheared serpentinites associated with ophiolites occur within this upper allochthon. In addition, the Gemo-Qandil Group is characterized by gabbroic to dioritic Bulfat intrusion with a crystallization age spanning from ~45 to ~?40 Ma, as well as extensive metapelites with contact to the Walash-Naupurdam metavolcanic rocks. Due to the deformation in the Sanandaj-Sirjan Zone along the eastern side of the Iraqi segment of NZSZ, the Gemo-Qandil Group was regionally metamorphosed during late Cretaceous (~?80 Ma). This tectono-compressional dynamics ultimately caused an oscillatory deformation against Arabian continental margin deposits as well. During these events, gabbro-diorite intrusion with high-grade contact metamorphic aureoles occurred near Bulfat. Thus, there is an overlap between regional and contact metamorphic conditions in the area. The earlier metamorphic characteristic can be seen only in places where the latter contact influence was insignificant. Generally, this can only observed at a distance of more than 2.5 km from the contact. According to petrographic details and field observations, the thermally metamorphosed metapelitic units of the metasediment have been completely assimilated, with only some streaks of biotite and relicts of initial foliation. They strongly resemble amphibolite-grade slices from the regional metamorphic rocks in the region. Metapelitic samples far from the intrusion give similar biotite cooling ages as the intrusive rocks. Thus, they may be affected by the same thermal event. ⁴⁰Ar/³⁹Ar dating of biotite in metapelite rocks of Bulfat by step-wise heating with laser gave average weighted isotopic ages of 34.78?±?0.06 Ma. This is interpreted as crystallization/recrystallization age of biotite possibly representing the time of cooling and uplift history of the Bulfat intrusion. Cooling and exhumation rates for the Bulfat gabbro-diorite rocks were estimated as ~?400 °C/Ma and ~?3.3 mm/year respectively. According to petrographic details, field observations and Ar/Ar dating concerning the contact metamorphism near Bulfat due to the gabbro-diorite intrusion, no significant deformation is visible during exhumation processes after the Paleogene tectono-thermal event, indicating that isotopic ages of 34.78?±?0.06 Ma could mark the timing of termination of the island arc activity in the Ophiolite-bearing terrane (upper allochthon).     

Jurassic volcaniclastic – basaltic andesite – dolerite sequence in Tasmania: new age constraints for fossil plants from Lune River

Jurassic plants excavated from a 12 × 5 m site, at Lune River, southern Tasmania, include an araucarian tree and numerous pteridophytes, belonging to the orders Osmundales, Filicales and Bennettitales. The fossils occur in 2 – 3 m of immature volcanilithic sandstone beds. The sandstone consists primarily of clasts from granitic basement rocks underlying much of southeast Tasmania and mafic clasts containing feldspathic microliths, and primary, phreatomagmatic quartz crystals. Detrital zircons from the sandstones are mostly Early Jurassic (Toarcian) in age (182 ± 4 Ma) with minor Triassic (226 Ma), Devonian (380 – 360 Ma) and Proterozoic populations. Basaltic andesite, hereafter referred to as andesite, caps the volcanilithic units and displays similar ratios of fluid-immobile trace elements (e.g. Zr/Nb, Ti/V), to the Jurassic dolerite found in Tasmania, indicative of a common source. The andesites are correlated with the Jurassic Kirkpatrick Basalts (Trans-Antarctic Mountains, Antarctica) based on their field relationships with bounding strata, age, and distinctive similarities in major-element composition and fluid-immobile trace-element ratios. The andesite is interpreted as an extrusive equivalent of the Tasmanian dolerite. Importantly, drillcore from Lune River contains stoped clasts of andesite in fine-grained dolerite, indicating that the andesite pre-dates the dolerite. Thermal alteration index of microfossils (3 – 3.3) and reflectance of organic material within the sediments (0.54 – 0.77 Ro) resulted from contact metamorphism associated with the emplacement of this basalt. The sedimentology and stratigraphy of the depositional environment, plus the presence of hydrophilic pteridophytes and gymnosperms, indicates that the Toarcian environment was temperate to warm and humid, with an abundant supply of water.     

内蒙古自治区牙克石市西尼气林场安山岩锆石LA-MC-ICP-MS U-Pb定年及地质意义

内蒙古自治区牙克石市西尼气林场一带出露的面积型安山岩,前人多划为早白垩世次火山岩或早白垩世的浅成侵入岩。本次安山岩U-Pb测年结果为226.0±1.9 Ma,为晚三叠世的产物,是大兴安岭中北部地区首次识别出三叠纪安山岩。结合地质特征,将其划为晚三叠世浅成侵入岩,说明在三叠纪大兴安岭中北部存在火山活动。本次测年结果对大兴安岭中北部火山岩地区面积型安山岩及安山玢岩的归属划分具有参照意义。     

40^Ar／39^Ar Ages of Auriferous Quartz Veins from the Fengyang and Zhangbaling Regions and Their Geological Significance

Geotectonically the Fengyang and Zhangbaling regions belong to the North China craton and the Dabie-Sulu oragene, respectively. Neo-Archean gneiss and amphibolite and metamor-phosed sea-facies sodic volcanic rocks axe the main outcrops in the two regions, respectively. The Zhangbaling terrane strike-skipped along the Tancheng-Lujiang fault zone in Mesozoic and Cenozo-ic eras and got close to the Fengyang terrane. Mesozoic Yanshanian intrusions occur broadly in thetwo regions. Gold-beating quartz veins occur in the metamorphic rocks in the Fengyang region and in the granodiorite and metamorphosed sea-facies sodic volcanic rocks in the Zhanghaling region.Generally, the formation of the auriferous quartz veins involved three stages. At the first stage,gold-poor sulfide quartz veins were formed; at the second stage gold-rich quartz sulfide veins wereformed; and at the third stage gold-poor barite and/or carbonate veins were formed. The 40^Ar/29^Ar step-heating plateau ages of the first-stage and the second-stage quartz aggregates from the Zhuding, Maoshan and Shangeheng gold deposits range between 116.1 0.6 Ma and 118.3 0.5 Ma and are pretty close to their least apparent ages and isoehronal ages, respectively. All plat-eau, least apparent and isoehronal ages range between 113.4 0.4 Ma and 118.3 0.5 Ma,which are considered as the formation age range of the quartz. It is reasonable and reliable to takethe 40^Ar/39^Ar age range of the quartz as the formation age range of gold-bearing quartz veins onthe basis of spatial relationship between gold-bearing quartz veins and their country rocks. Thegold deposits in the two regions were formed in Aptian, Cretaceous, when the Tancheng-Lujiangfault zone moved as a normal fault with slightly right-lateral strike-skip, was extensional and expe-rienced very strong magnmtic process. It is shown that the magnmtic hydrothermal fluid is a veryimportant part of the gold ore-forming hydrothermal fluid in the Fengyang and Zhanghaling re-gions. The formation of the gold ore deposits in the Fengyang and Zhanghaling regions had genetic relations with the extensional movement of the Tancheng-Lujiang fault zone and magmatic activities and took place under the extensional dynamic condition in Late Cretaceous. Therefore, the exten-sional movement of the Tancheng-Lujiang fault zone presented the energy and space for magmatic and gold ore-forming processes.     

Thermal modeling of Carboniferous to Triassic sediments of the Karawanken Range (Southern Alps) as a tool for paleogeographic reconstructions in the Alpine–Dinaridic–Pannonian realm

Vitrinite reflectance was measured in Late Carboniferous to Triassic shales, siltstones and marls of the Karawanken Range. Thermal models of the central South-Karawanken Range were calibrated on the basis of these data. They suggest an eroded overburden of more than 3,200 m of Jurassic to Cretaceous sediments and a heat flow in the range of 42 to 60 mW m^?2 during the time of maximum subsidence. Because the reconstructed thermal history of the South-Karawanken Range is very similar to the thermal history of the Generoso basin (western Southern Alps), these data provide strong evidence for a deep basinal position of the Southern Karawanken Range during Jurassic to Cretaceous times. A vitrinite reflectance anomaly at the northern margin of the South-Karawanken Range is explained by advective heat transport during the Oligocene. The heat source for the anomalies at the western margin of the Seeberg Rise and in the area between the Periadriatic Lineament and the Donat Fault Zone is unknown. Vitrinite reflectance in Late Triassic sediments indicates the South-Karawanken Range and the South-Zala Unit of the Pannonian basement as exotic blocks in the Sava Composite Unit. This is explained by Miocene displacement of structural units, which were derived from different paleogeographical segments of the Permo-Mesozoic western Tethyan margin.     

郯庐断裂带肥东段烟头山及桃源地区构造变形特征研究

郯庐断裂带肥东段烟头山及桃源地区,发育多条左行韧性剪切带,岩性以糜棱岩和糜棱岩化片麻岩为主,岩石变形强烈。通过详细的野外观测及室内分析发现：肥东北部烟头山及桃园地区几何学形态呈一背形构造,其枢纽走向NE-SW,轴面倾向SE,自核部向两翼岩性出露具有一定的规律性和对称性。古应力方向及运动学涡度研究表明：研究区内构造体主要受到近南北方向的挤压,涡度值W_k在0.73～0.90之间,指示区域内的韧性剪切活动以简单剪切为主。对区内变形岩石展开精细化的构造变形分析,包括石英的分形特征、变质变形温度估计、差应力和应变速率的计算等,结果显示：区内动态重结晶石英颗粒边界具有统计学上的自相似性,分维值D在1.111～1.187之间,变质变形温度集中在520 ℃～610 ℃之间,为高绿片岩相到低角闪岩相变质;韧性剪切带的差异应力Δσ介于18.493～95.266 MPa之间,应变速率ε范围在5.418×10^-15 s^-1～4.748×10^-11 s^-1之间。对比以上参数发现：韧性剪切带核部和背形转折端附近,岩石变形强烈,变质变形温度高,动态重结晶石英颗粒粒径较小,分维值较大,差异应力和应变速率也较大,远离剪切带核部和背形两翼则相反。本文从几何学、运动学特征以及显微构造变形分析等方面展开精细化研究,对进一步认识郯庐断裂带乃至大型韧性剪切带的构造样式和演化过程有着重要的意义。     

Geochronology of Precambrian rocks in the Laramie Range and implications for the tectonic framework of Precambrian southern Wyoming

From Casper Mountain; at its northern end, to the northwestern margin of the Laramie anorthosite—syenite complex, in its central parts, the Laramie Range is underlain by granite and granitic gneiss that has a minimum age of 2.54 ± 0.04 Ga (Rb/Sr whole-rock isochron) and by metasedimentary rocks, including marble and quartzite, that appear to overlie the granitic gneiss nonconformably (minimum age: 1.7 Ga based on several horn-blende K/Ar dates). Southward from the anorthosite—syenite complex into Colorado, the Range is underlain chiefly by the Sherman Granite (1.41 Ga; Peterman and Hedge, 1968) and scattered patches of gneiss that are not dated, but are tentatively correlated wit similar gneiss in the southern Medicine Bow Mountains and in the Colorado Front Range, where they are dated as ? 1.7 Ga (Peterman and Hedge, 1968).The Laramie anorthosite—syenite complex (minimum age: ? 1.42 Ga or ? 1.51 Ga if a hornblende K/Ar date is accepted) apparently intruded the suture separating the old (? 2.5 Ga) continental edge from younger (? 1.7 Ga) geosynclinal rocks. The suture, which manifests itself as the Mullen Creek—Nash Fork shear zone in the Medicine Bow Mountains, also is the boundary between ensialic and ensimatic geosynclinal deposition that occurred during the interval 1.7–2.5 Ga ago.K/Ar dates on biotite and muscovite from rocks north of the anorthosite—syenite complex grade from 2.5 Ga on Casper Mountain down to 1.38 Ga near the complex. Near its northern tip, the Laramie Range is crossed by a geochronologic front, separating 2.5 Ga old gneiss whose K/Ar dates were not lowered by subsequent metamorphism from 2.5 Ga old gneiss whose mica dates were reset between 1.4 and 1.6 Ga ago.     

南华北盆地断裂构造特征与油气勘探

南华北盆地主要发育3期断裂:第一期是在三叠纪末挤压构造背景下形成的逆冲断裂,断裂走向以近E-W向为主、主要由南向北逆冲;第二期是与晚侏罗世—早白垩世构造运动相关的走滑拉张断裂,断裂走向以NNE向为主,左行走滑,常沿印支期挤压断裂带发育;第三期是与晚白垩世—古近纪构造运动相关的正断裂,断裂走向以近S-N向或NEE向为主。三叠纪末印支期断裂的冲断抬升作用一方面使该区主力烃源岩石炭—二叠系受严重剥蚀,另一方面破坏了烃源岩的连续性和稳定性;晚侏罗世—早白垩世的走滑拉张断裂与印支期断裂一起,呈棋盘格式平面切割了南华北盆地,与之伴生的火成岩对烃源岩也有一定的破坏作用;晚白垩世—古近纪的拉张断裂则进一步加强了烃源岩的不连续性。后两期拉张断裂常常通天,对前期形成的油气藏有一定的破坏作用。因此,对于南华北盆地的油气勘探,需要避开走滑断裂或拉张断裂,避开火成岩体;针对上古生界,要寻找连续性较好的烃源岩层;针对中、新生界,要寻找有利于烃源岩发育的沉积相带。     

Extraction of potassium from biotite by Ba<Superscript>2+</Superscript>/K<Superscript>+</Superscript> ion exchange and the structural transformation

Potassium has been extracted successfully from biotite by Ba²⁺/K⁺ ion exchange. The potassium release rate increased along S-curve versus reaction time. The maximum of potassium release rate was about 96 %. Powder X-ray diffraction spectroscopy, Fourier transform infrared spectroscopy, and transmission electron microscopy were used to characterize the obtained samples to reveal the exchanging behavior and structural transformation. The results showed that after treated with Ba(NO₃)₂ four times the original biotite transformed to vermiculite-type hydrated Ba-mica. The (001) basal plane was expanded from 1.000 nm of biotite to 1.221 nm of hydrated Ba-mica. Because of the “vacancy effect,” the Ba²⁺ has two different statuses, causing the structural water vibration of vermiculite-type hydrated Ba-mica split. The edge of vermiculite-type hydrated Ba-mica was crimped compared with the flat edge of original biotite. The (001) basal plane of dehydrated Ba-mica was also split, supporting the “vacancy effect.”     

Provenance analyses of early Mesozoic sediments in the Ningwu basin: Implications for the tectonic–palaeogeographic evolution of the northcentral North China Craton

This paper reports results from detrital zircon U–Pb geochronology, Hf isotopic geochemistry, sandstone modal analysis, and palaeocurrent analysis of the early Mesozoic strata within the Ningwu basin, China, with the aims of constraining the depositional ages and sedimentary provenances and shedding new light on the Mesozoic tectonic evolution of the northcentral North China Craton (NCC). The zircons from early Mesozoic sandstones are characterized by three major populations: Phanerozoic (late Palaeozoic and early Mesozoic), late Palaeoproterozoic (with a peak at approximately 1.8 Ga), and Neoarchaean (with a peak at approximately 2.5 Ga). Notably, three Phanerozoic zircons in the Early Triassic Liujiagou Formation were found to have positive ε_Hf(t) values and characteristics typical of zircons from the Central Asian Orogenic Belt (CAOB). Therefore, the CAOB began to represent the provenance of sediment in the sedimentary basins in the northern NCC no later than the Early Triassic (261 Ma), implying that the final amalgamation of the NCC and CAOB occurred before the Early Triassic. The U–Pb geochronologic and Hf isotopic results show that the Lower Middle Triassic sediments were mainly sourced from the Yinshan–Yanshan Orogenic Belt (YYOB), and that a sudden change in provenances occurred, shifting from a mixed YYOB and CAOB source in the Middle Jurassic to a primarily YYOB source in the Late Jurassic. The results of the sandstone modal analysis suggest that the majority of the samples from the Lower Middle Jurassic rocks were derived from either Continental Block or Recycled Orogen sources, whereas all the samples from the Upper Jurassic rocks were derived from Mixed sources. The change in source might be ascribed to the southward subduction and closure of the Okhotsk Ocean and the resulting intense uplift of the YYOB during the Late Jurassic. This uplift likely represents the start of the Yanshan Orogeny.     

Deducing the source and composition of rare earth mineralising fluids in carbonatites: insights from isotopic (C,O, <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr) data from Kangankunde,Malawi

Carbonatites host some of the largest and highest grade rare earth element (REE) deposits but the composition and source of their REE-mineralising fluids remains enigmatic. Using C, O and ⁸⁷Sr/⁸⁶Sr isotope data together with major and trace element compositions for the REE-rich Kangankunde carbonatite (Malawi), we show that the commonly observed, dark brown, Fe-rich carbonatite that hosts REE minerals in many carbonatites is decoupled from the REE mineral assemblage. REE-rich ferroan dolomite carbonatites, containing 8–15 wt% REE₂O₃, comprise assemblages of monazite-(Ce), strontianite and baryte forming hexagonal pseudomorphs after probable burbankite. The ⁸⁷Sr/⁸⁶Sr values (0.70302–0.70307) affirm a carbonatitic origin for these pseudomorph-forming fluids. Carbon and oxygen isotope ratios of strontianite, representing the REE mineral assemblage, indicate equilibrium between these assemblages and a carbonatite-derived, deuteric fluid between 250 and 400 °C (δ¹⁸O + 3 to + 5‰_VSMOW and δ¹³C ? 3.5 to ? 3.2‰_VPDB). In contrast, dolomite in the same samples has similar δ¹³C values but much higher δ¹⁸O, corresponding to increasing degrees of exchange with low-temperature fluids (< 125 °C), causing exsolution of Fe oxides resulting in the dark colour of these rocks. REE-rich quartz rocks, which occur outside of the intrusion, have similar δ¹⁸O and ⁸⁷Sr/⁸⁶Sr to those of the main complex, indicating both are carbonatite-derived and, locally, REE mineralisation can extend up to 1.5 km away from the intrusion. Early, REE-poor apatite-bearing dolomite carbonatite (beforsite: δ¹⁸O + 7.7 to + 10.3‰ and δ¹³C ?5.2 to ?6.0‰; ⁸⁷Sr/⁸⁶Sr 0.70296–0.70298) is not directly linked with the REE mineralisation.     

Late Cretaceous subduction initiation and Palaeocene–Eocene slab breakoff magmatism in South-Central Anatolia,Turkey

The Late Cretaceous Alihoca ophiolite in the Inner Tauride suture zone (ITSZ) of South-Central Turkey represents part of a single ophiolitic thrust sheet that originated from the Inner Tauride ocean. The ophiolite contains upper mantle peridotites, cumulate wehrlites, layered-to-isotropic gabbros, and microgabbroic-to-doleritic dikes. An ophiolitic mélange beneath the Alihoca ophiolite includes blocks of limestone, peridotite, dolerite, basalt, and deep-sea sedimentary rocks (radiolarite, chert) in a matrix comprising sheared serpentinite and mudstone. Isotropic gabbro and dolerite dike rocks show enrichment in Sr, K, Rb, Ba, and Th (LILE) and depletion of Ta, Nb, Zr, Ti, and Y (HFSE), indicating an island arc tholeiite (IAT) affinity. Relatively younger dolerite rocks display low TiO₂ (<0.5 wt.%) contents, concave REE profiles with low HREE concentrations, and high LREE values, typical of boninitic affinities. The Alihoca ophiolite, hence, displays an IAT to boninitic geochemical progression in its magmatic evolution, reminiscent of many other Tethyan ophiolites in the region. It represents the remnant of a forearc oceanic crust, which developed during the early stages of subduction within the Inner Tauride ocean. Volcanic, volcano-sedimentary, and sedimentary rocks of the Uluk??la–Çamard? basin north of the ITSZ disconformably overlie the mafic-ultramafic rocks of the Alihoca ophiolite. Pillowed and massive lavas of the latest Cretaceous–Palaeocene Uluk??la Formation have alkaline basalt-to-basaltic andesite compositions, displaying relatively enriched LILE and LREE patterns with negative Nb and Ta anomalies. These geochemical features suggest that magmas of the Uluk??la–Çamard? volcanic rocks formed from partial melting of a metasomatized lithospheric mantle. This melting event was triggered by the influx of asthenospheric heat through a slab breakoff-induced window in the downgoing Tethyan oceanic lithosphere.     

Cosmogenic radionuclide <Superscript>7</Superscript>Be concentration in seven species of lichens and its correlation with <Superscript>40</Superscript>K, <Superscript>137</Superscript>Cs and <Superscript>226</Superscript>Ra

In this work, accumulation of cosmogenic radionuclide ⁷Be in seven species of lichens was determined using HPGe detectors in autumn season. Ramsar city which is located in the north of Iran as one of the high-level natural radiation areas in the world was considered. Lichen species represented good potential in accumulation of ⁷Be radionuclide. The foliose species of Xanthoria parietina with the highest activity concentration value of 112.8 ± 1.8 Bq kg^?1 was introduced as bioindicator for accumulation of ⁷Be radionuclide. Cladonia rangiformis species has got minimum concentration of 64.5 ± 0.8 Bq kg^?1. Also from thallus morphology viewpoint, results showed that ⁷Be accumulation in foliose species is higher than in fruticose and crustose lichens species. Also there was relatively large positive correlation between ⁷Be and ²²⁶Ra activity concentrations in lichens species.     

Cut Slope Design Recommendations for Sub-Horizontal Hard Sedimentary Rock Units in Ohio, USA

Although most cut slopes in Ohio consist of inter-layered, sub-horizontal units of hard and soft sedimentary rocks (sandstone, limestone, dolostone, shale, claystone, mudstone), slopes consisting of relatively thick hard rock units are not uncommon. Design of stable cut slopes in hard rock units needs to consider rock mass strength and orientation of discontinuities with respect to slope face. Results of kinematic stability analyses show that hard-rock cut slopes are less likely to have conventional plane and wedge failures, caused by unfavorable orientation of discontinuities. The main cause of failure is identified to be the undercutting-induced toppling, which is not amenable to traditional kinematic or rock mass strength-based analyses. Therefore, to recommend a suitable slope angle, numerical models, using UDEC software, were employed to study how various slope angles affect the process of undercutting-induced toppling failures. The UDEC models showed a slope angle of 45° (1H:1 V) to be the most stable angle. However, a 63° (0.5H:1 V) slope angle can significantly reduce the potential for such failures and is therefore more appropriate than the widely used angle of 76° (0.25H:1 V).