火成岩数据库的发展与现状

火成岩数据库是岩石学根据自身研究的需要,与计算机、通信和网络     

火成岩油气储层的水岩相互作用:研究进展与发展方向

火成岩油气储层具有与其他类型油气储层不同的岩石学特征和流体特征。火成岩冷却后所形成的原生孔隙受压实作用的影响较小,而次生孔隙的形成演化对于火成岩储集空间的发育有重要意义。其中,水岩相互作用更是火成岩储层次生孔隙形成演化的重要自然营力之一,因此,这一领域的相关研究对火成岩油气藏的预测有重要意义。作者在调研文献的基础上发现,已有的火成岩储层研究多集中在对一些现象的描述和地质背景的相关性研究,而比较欠缺对油气储层水岩相互作用的系统研究。目前,火成岩油气储层领域需要引进新概念和新技术,重视火成岩储层水岩相互作用的综合分析与系统研究,尤其需要加深对火成岩油气储层次生孔隙形成和演化的理解,以促进油气资源的勘探与开发。     

Zircon LA-P-MS U-Pb age,Ce4+/Ce3+ ratios and the geochemical features of the Machangqing complex associated with copper deposit

The Machangqing complex is composed of early syenitic-monzonitic porphyry and late granite-porphyry. Geochemically, they are similar in major and trace element characteristics, and are characterized by relatively low TiO2 (＜0.5) and P2O5(＜0.4) and high alkali contents ( K2O Na2O＞8% ), with K2O/Na2O ＞ 1, the absence of significant Eu anomaly and pronounced negative anomalies in Nb, Ta, Ti, and enrichment in large-ion lithophile elements and light rare-earth elements. Zircon U-Th-Pb ELA-ICP-MS age determination of the Machangqing complex has revealed two discrete igneous events.The syenitic-monzonitic porphyry has an age of 35.6 ± 3 Ma, MSWD = 2.80; the granite-porphyry, 35.0±0.2 Ma, MSWD = 2.91. The lifespan of magmatic activities of the Machangqing complex associated with Cu Mo mineralization is about 0.6 Ma. The late-stage ore-bearing granite-porphyry has higher Ce4 /Ce3 ratios (264) than the early-stage barren syenitic-monzonitic porphyry (102). The increase of zircon Ce4 /Ces ratios from the early- to late-stage porphyries indicates that the oxidation state of the magmas associated with copper mineralization increases with time.     

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…     

沉积地球科学的历史回顾与展望

沉积地球科学自上世纪初从地层学中分出 ,成为独立的地球科学分支 ,经历了沉积岩石学、沉积学和沉积地质学三个发展阶段。沉积岩石学以沉积岩的特征、分类、产状和成因为主要研究对象 ;沉积学以沉积作用及沉积岩的形成为主要研究任务 ;沉积地质学探讨四维空间里沉积物运动的规律性 ,是沉积地球科学的新的拓展和升华。本文回顾了沉积岩石学、沉积学、沉积地质学的发展历史及其中蕴含的科学思维与方法学的重要变革 ,从认识论和方法学方面总结和讨论了本学科的发展轨迹。并在此基础上讨论了未来的发展方向。     

Genesis and Geodynamic Significance of Chromitites from the Fuchuan Ophiolite, Southern China, as Evidenced by Trace Element Fingerprints of Chromite, Olivine and Pyroxene

The Fuchuan ophiolite is located in the northeasternmost segment of the Neoproterozoic Jiangnan orogen and consists mainly of harzburgites, with minor dunites, pyroxenite and gabbro veins and dykes. In order to investigate the genesis and tectonic setting of the Fuchuan ophiolite and chromitites, in situ analyses of unaltered chromites and silicates were carried out. Trace element analyses of unaltered chromites from the Fuchuan chromitites indicate the parental magma is of mid-ocean ridge basal...     

A self-consistent top–down model for differentiation in bimodal suites: application to the Sonju Lake Intrusion–Finland granite system (MN)

The Sonju Lake Intrusion (SLI) is a 1200-meter thick layered mafic intrusion that directly underlies an equally large silicic pluton, the Finland granophyre (FG) within the Beaver Bay Complex of the Mid-Continent Rift (MN, USA). The SLI, with a simple mineralogical and compositional stratigraphy, provides an excellent case study for examining the changes in iron isotope ratios (δ⁵⁶Fe). Here new Fe isotope data along with ⁸⁷Sr/⁸⁶Sr for a set of stratigraphically controlled samples from the SLI and FG are presented. The Fe isotope data show systematic changes within two differentiation sequences found in the lowermost FG as well as the upper portion of the SLI. Specifically, δ⁵⁶Fe is observed to start at low values and increase to heavy values going stratigraphically up through each differentiation sequence. Within the middle portion of the SLI, δ⁵⁶Fe varies between 0 and 0.1. Two samples from the SLI bottom are isotopically lighter than the middle SLI. The origin of the Fe isotope variations is discussed in terms of recently proposed explanations. A quantitative model shows that the observed spatial variation is consistent with the prediction of a temperature gradient model. Using present constraints on equilibrium phase partitioning, the iron isotope variations do not appear consistent with production by fractional crystallization. Based on these observations, a top–down sill emplacement process coupled with in situ differentiation remains a viable alternative model for forming this layered intrusion.     

Basaltoids and carbonatite tuffs of Ambinsky volcano (Southwestern Primorye): Geology and genesis

Geological-petrological data were first obtained on the Early Miocene basaltoids and spinel-fassaite carbonatite tuffs of the Ambinsky volcanic structure in southwestern Primorye. The geological study of Ambinsky volcano allowed the reconstruction of stratigraphic sections across lava and pyroclastic basaltic rocks and stratified carbonatite tuffs. The chemical compositions of rocks and mineral phenocrysts from basalts and carbonatite tuffs are reported. The basaltoids are classed with undifferentiated moderately alkaline within-plate basalts. Evidence of carbonate-silicate immiscibility was found in the basaltoids and carbonatite tuffs. It was suggested that the formation of the carbonatite melt associated with simultaneous basification and abundant crystallization of spinel, fassaite, as well as oversaturation of the silicate system in Ca was caused by limestone assimilation, subsequent transformation of the melt, and liquid immiscibility. Thermal decomposition of carbonates with dissolution of released CaO in magma and accumulation of CO₂ in a closed magmatic chamber gave rise to the autoclave gas effect and, correspondingly, heavy explosive eruptions atypical of such volcanic rocks. The genesis of carbonatite tuffs of Ambinsky volcano can serve as a model example of exsolution of carbonate melt in the moderately alkaline nonagpaitic basaltic system.     

Metamorphic petrology and geology in China: A review

The development of metamorphic petrology to metamorphic geology in China has a long history. Ancient basement metamorphic rocks are distributed primarily in the North China Craton, the Yangtze Block and Tarim Craton. They are mainly made up of plutonic gneiss and metamorphosed supercrust rock, transformed to granulite facies through Archean Paleoproterozoic. Many of the Paleoproterozoic metamorphic rocks have undergone high-pressure granulite facies metamorphism with a clockwise metamorphic evolution path. The ultrahigh temperature (UHT) granulites from the Late Paleoproterozoic are found in North China Craton. Many high-precision chronological data have allowed preliminary construction of the formation and evolutionary framework of different metamorphic basements. Primarily there are low-temperature and high-pressure blue schist, high-temperature and high-pressure granulite and ultrahigh-pressure (UHP) eclogite facies metamorphic rocks in the Phanerozoic orogenic belt. The discovery of eclogite in the Sulu orogen and a large quantity of coesite in its country rocks show that there was a deep subduction of voluminous continental materials during the collision process between the Yangtze block and the North China Craton in the Early Mesozoic phase. From the studies of, for instance, organic matter vitrinite reflectance, illite crystallinity, illite (muscovite) polytype and illite (muscovite) b dimension, the Late Paleozoic strata in the eastern region of Inner Mongolia and the north-central region of NE China have only experienced diagenesis to an extremely low-grade metamorphism. The discovery of impact-metamorphosed rocks in Xiuyan area of Liaoning province has enriched the type and category of metamorphic rocks in China. The phase equilibrium method has been widely used in the study of metamorphism of middle and high-grade metamorphic rocks. On the basis of existing geologic surveys and monographic study results, different scholars have respectively compiled 1:1500000 Metamorphic Geological Map and Specifications of Qinghai Tibet Plateau and its Adjacent Areas, 1:2500000 Metamorphic Tectonic Map of China, and the 1:5000000 Metamorphic Geological Map and Specifications of China, among others repectively, which have systematically summarized the research results of metamorphic petrology and metamorphic geology in China.     

Lithospheric Mantle Evolution during Continental Break-Up: The West Iberia Non-Volcanic Passive Margin

Ultramafic (lherzolites, metasomatized peridotites, harzburgites,websterites and clinopyroxenites) and mafic igneous (basalts,dolerites, diorites and gabbros) rocks exposed at the sea-flooralong the West Iberia continental margin represent a rare opportunityto study the transition zone between continental and oceaniclithosphere. The igneous rocks are enriched in LREE, unlikeNorth Atlantic MORB. A correlation between their ¹⁴³Nd/¹⁴⁴Ndisotopic composition and Ce/Yb ratio suggests that they originatefrom mixing between partial melts of a depleted mantle sourcesimilar to DMM and of an enriched mantle source which may residewithin the continental lithosphere. Clinopyroxenes and amphibolesin the ultramafic rocks are LREE depleted and have flat HREEpatterns with concentrations higher than those of abyssal peridotites.Clinopyroxenes in the harzburgites are less LREE depleted buthave lower HREE concentrations. The clinopyroxenes in the GaliciaBank (GB) lherzolites have radiogenic Nd (¹⁴³Nd/¹⁴⁴Nd rangingfrom 0·512937 to 0·513402) and unradiogenic Sr(⁸⁷Sr/⁸⁶Sr ranging from 0·702100 to 0·702311)isotopic ratios similar to, or higher than, DMM (Depleted MORBMantle) whereas the clinopyroxenes in the Iberia Abyssal Plainwebsterites have low-Nd isotopic compositions (¹⁴³Nd/¹⁴⁴Nd rangingfrom 0·512283 to 0·512553) with high-Sr isotopicratios (⁸⁷Sr/⁸⁶Sr ranging from 0·704170 to 0·705919).Amphiboles in Galicia Bank lherzolites and diorites have Nd–Srisotopic compositions (¹⁴³Nd/¹⁴⁴Nd from 0·512804 to 0·512938and ⁸⁷Sr/⁸⁶Sr from 0·703243 to 0·703887) intermediatebetween those of the clinopyroxenes from the Galicia Bank andthe Iberia Abyssal Plain, but similar to the clinopyroxenesin the 5100 Hill harzburgite (¹⁴³Nd/¹⁴⁴Nd = 0·512865and ⁸⁷Sr/⁸⁶Sr = 0·703591) and to the igneous rocks (¹⁴³Nd/¹⁴⁴Ndranging from 0·512729 to 0·513121 and ⁸⁷Sr/⁸⁶Srranging from 0·702255 to 0·705109). The majorand trace element compositions of cpx in the Galicia Bank spinellherzolites provide evidence for large-scale refertilizationof the lithospheric upper mantle by MORB-like tholeiitic melts.The associated harzburgites did not undergo partial meltingduring the rifting stage, but, in earlier times, probably during,or even before, the Hercynian orogeny. Iberia Abyssal Plainwebsterites are interpreted as high-pressure cumulates formedin the mantle. Their high Sm/Nd ratios (from 0·43 to0·67) coupled with very low-Nd isotopic compositionsare best explained by a two-stage history: formation of thecumulates from the percolation of enriched melts long beforethe rifting, followed by low-degree partial melting of the pyroxenites,accounting for their LREE depletion. This last event probablyoccurs during the rifting episode, 122 Myr ago. The isotopicheterogeneities observed in the ultramafic rocks of the Iberiamargin were already present at the time of the rifting event.They reflect a long and complex history of depletion and enrichmentevents in an old part of the mantle, and provide strong argumentsfor a sub-continental origin of this part of the upper mantle. KEY WORDS: Iberia margin; mantle peridotites; igneous rocks; petrology; geochemistry     

大数据驱动下变质岩岩石学研究展望

变质岩记录了地球特别是大陆形成以来的演化历史。变质作用是地球出现固态岩石后构造演化的物质记录,是地球岩石圈的黑匣子、深部探针和指示剂,是深时地质记录最典型的地质指纹。变质岩及变质作用承载了地球特别是大陆构造演化过程以及构造体制随时代演化的研究重任。随着变质相平衡研究的发展以及相关数据资料的积累,因应大数据时代的到来,如何完善变质岩岩石学知识体系,对分散的数据进行整合,形成新一代数据平台,运用大数据方法解决前沿科学问题,成为变质岩岩石学新的学科生长点。文章总结介绍了国内外与变质岩有关的数据库（如MetPetDB、PetDB等）,并对近年的研究热点做了综述。笔者认为,大数据驱动下,可以针对一些相关科学问题先行开展研究,如：（1）早期大陆的物质、形成机制、生长过程和稳定化; （2）造山带、克拉通结构以及洋陆相互作用的过程;（3）壳-幔相互作用、接触带结构、能量、相转换与物质交换;（4）地球的热体制演化及其与大陆结构与成分演变的时空联系。     

Effect of trends on correlation in open and closed three-component systems

It is well known among geologists that closure of an open-number system, as when stratigraphic rock thicknesses are converted to percentages, introduces correlations among the components even in the absence of correlations in the open system. In closed three-component systems the covariances are single-valued functions of the closed variances and are exactly predictable. If the open system has inherent correlation (point correlations) among its components the corresponding closed covariances reflect their presence in a predictable manner. If areal trends are present in the open system, the open covariances are themselves affected, but this trend effect can be completely removed to recover the initial point correlations among the components. Areal trends in open systems strongly influence the structure of the closed variance-covariance matrices, and the situation becomes increasingly complicated if the open system has both point correlations and areal trends. The paper considers the problems involved, and includes Monte Carlo runs to compare computed and predicted variances and covariances as data sets are followed from open systems with correlation but no trend to the closed equivalent of open systems with point correlations and trends.     

The You Yangs batholith in Southeastern Australia,the sources of its magmas and inferences for local crustal architecture

The 365-Ma You Yangs batholith is a mainly I-type monzogranitic body, containing rocks with both clinopyroxene and hornblende, but with a 2–2.5?km-wide rim of S-type rocks. In places, the margins of the intrusion wedge out laterally. A laccolithic shape may explain there being only low-grade contact metamorphism of the Ordovician metasedimentary wall rocks. The chemical and isotopic characteristics of the granitic rocks suggest that the magmas formed by partial melting of a source that contained some meta-igneous rocks but was dominated by chemically immature metasedimentary types, to impart an evolved Sr isotope signature (⁸⁷Sr/⁸⁶Sr_t?=?0.70877–0.71066 for the main monzogranitic rocks), combined with relatively non-radiogenic εNd_t (–2.4 to –1.9). Crystal fractionation played little role in shaping the compositions of the granitic magmas, with the main variations interpreted to be source-inherited. Igneous-textured microgranular enclaves (IMEs) are prominent in the monzogranitic rocks. The IMEs probably had an ultimate enriched-mantle source, and their magmas did not mix significantly with the crustally derived granitic host magmas. The characteristics of the monzogranitic rocks hosting the enclaves suggest the possibility that an unrecognised metasediment-dominated terrane of ancient arc crust may be present beneath the Bendigo Zone.     

Volcan Popocatepetl, Mexico. Petrology, Magma Mixing, and Immediate Sources of Volatiles for the 1994-Present Eruption

Volcán Popocatépetl has been the site of voluminousdegassing accompanied by minor eruptive activity from late 1994until the time of writing (August 2002). This contribution presentspetrological investigations of magma erupted in 1997 and 1998,including major-element and volatile (S, Cl, F, and H₂O) datafrom glass inclusions and matrix glasses. Magma erupted fromPopocatépetl is a mixture of dacite (65 wt % SiO₂, two-pyroxenes+ plagioclase + Fe–Ti oxides + apatite, 3 wt % H₂O, P= 1·5 kbar, f_O2 = NNO + 0·5 log units) and basalticandesite (53 wt % SiO₂, olivine + two-pyroxenes, 3 wt % H₂O,P = 1–4 kbar). Magma mixed at 4–6 km depth in proportionsbetween 45:55 and 85:15 wt % silicic:mafic magma. The pre-eruptivevolatile content of the basaltic andesite is 1980 ppm S, 1060ppm Cl, 950 ppm F, and 3·3 wt % H₂O. The pre-eruptivevolatile content of the dacite is 130 ± 50 ppm S, 880± 70 ppm Cl, 570 ± 100 ppm F, and 2·9 ±0·2 wt % H₂O. Degassing from 0·031 km³ of eruptedmagma accounts for only 0·7 wt % of the observed SO₂emission. Circulation of magma in the volcanic conduit in thepresence of a modest bubble phase is a possible mechanism toexplain the high rates of degassing and limited magma productionat Popocatépetl. KEY WORDS: glass inclusions; igneous petrology; Mexico; Popocatépetl; volatiles     

The Significance of Multiple Saturation Points in the Context of Polybaric Near-fractional Melting

Experimental petrologists have successfully located basalticliquid compositions parental to mid-ocean ridge basalt thatare, within experimental resolution, multiply saturated withthree-phase harzburgite or four-phase lherzolite assemblageson their liquidus at some elevated pressure. Such an experimentalresult is a necessary consequence of any paradigm in which eruptedbasalts derive from single-batch primary liquids that equilibratewith a mantle residue and undergo no subsequent magma mixingbefore differentiation and eruption. Here we investigate whether,conversely, such evidence of multiple saturation is sufficientto exclude dynamic melting models wherein increments of meltare mixed after segregation from residues, during melt transportor in magma chambers. Using two independent models of crystal–liquidequilibria to simulate polybaric near-fractional peridotitemelting, we find that aggregate liquids from such melting processescan display near-intersections of liquidus surfaces too closeto distinguish experimentally from exact multiple saturationpoints. Given uncertainties in glass compositions, fractionationcorrections, experimental temperature and pressure conditions,and achievement of equilibrium, these results suggest that polybaricmixtures can in fact masquerade as mantle-equilibrated single-batchprimary liquids. Multiple saturation points on the liquidussurfaces of primitive basalts do, however, preserve informationabout the average pressure of extraction of their constituentincrements of liquid. KEY WORDS: mantle melting; basaltic volcanism; experimental igneous petrology; thermodynamic modelling; inverse method     

关于火成岩常用图解的正确使用:讨论与建议

本文讨论和评述火成岩常用图解,包括火成岩分类命名,岩石的化学参数与构造环境判别图解,原作者构建时的岩石学含义与随后文献中应用时的各种误解,或不同学者对相同参数的图解提出不同的划分和处理方案,或对同一个术语在不同参数图解中岩石学含义有不同的理解,以及数据处理中的正确与错误途径。进而讨论复杂的火成岩多元系统需要通过不同参数构建的多种图解的相互制约,才能较全面的描述火成岩的特征,提出火成岩常用图解的正确理解与使用,以及采用"统一平台"的某些建议,以利于区域岩石学的对比和研究。     

Zircon Inheritance Reveals Exceptionally Fast Crustal Magma Generation Processes in Central Iberia during the Cambro-Ordovician

The Variscan basement of the Central Iberian Zone contains abundantCambro-Ordovician calc-alkaline to peraluminous metagranitesand metavolcanic rocks with two notable features: first, theywere apparently produced with no connection to any major tectonicor metamorphic event; second, they have an unusually high zirconinheritance. U–Pb dating combined with cathodoluminescenceimaging reveals that about 70–80%, in some samples nearer100%, of the zircon grains contain inherited pre-magmatic cores,despite the temperature reached by the magmas (about 900°C,calculated using the Ti-in-zircon thermometer) being high enoughto dissolve all the available zircon (from the rock's zirconsaturation temperature, 770–860°C). The fact thatthe dissolution of zircon was so incomplete can only be attributedto the kinetics of heat transfer to and from the magmas. Three-dimensionalmodeling of zircon dissolution behavior in melts with a compositionsimilar to the Iberian Cambro-Ordovician magmas indicates thatthe survival of zircons from the suggested late Pan-Africanprotolith would be possible only if melt production was rapid,specifically less than 10⁴ years, and probably about 2 x 10³years, from the beginning of melting (700°C) to the thermalpeak (900°C). Melt production was followed by fast magmatransfer to upper crustal levels resulting either in surfaceeruption or in the emplacement of small (< 400 m thick) sillsor laccoliths. We suggest that these elevated rates of crustalmelting could only have been caused by intrusion of mantle-derivedmafic magmas, most probably at the base of the crust. This scenariois consistent with a rifting regime in which crust and mantlewere mechanically decoupled; this would explain the scarcityof contemporaneous crustal deformation. Furthermore, fast meltingrates in the lower crust followed by fast melt transportationto the upper crust could also explain the lack of contemporaneousmetamorphism. The speed of the partial melting process resultedin the production of felsic magmas that inherited the geochemicalcharacteristics of their granitoid crustal protolith. This explainsthe apparent contradiction between the calc-alkaline to peraluminousgeochemical characteristics of the magmas and the inferred extensional(i.e. rift-related) tectonic setting. Our model is compatiblewith the hypothesis of fragmentation and dispersal of terranesfrom the northern margin of Gondwana that led to the openingof the Rheic and Galicia–South Brittany oceans and, ultimately,caused the detachment of the Iberian microplate from Armoricaand Gondwana during the early Paleozoic. KEY WORDS: igneous petrology; migmatite; granite; geochemistry; crustal contamination; ICP-MS; laser ablation     

Petrogenesis of the Chaihulanzi Gneiss and its Tectonic Implications for the North China Craton

The Chaihulanzi area in eastern Inner Mongolia is tectonically situated on the northern margin of the North China Craton (NCC). The main Precambrian lithologies of the area have been referred to the Archean Jianping Group meta-supracrustal sequences. Based on field observations, petrographic, whole-rock geochemical, and zircon U-Pb geochronological results, a magmatic origin for the units is proposed. Our results show that the Chaihulanzi gneisses are mainly of granitic, dioritic and granodioritic compositions, and show typical magmatic rock textures and mineral assemblages. The dioritic and granodioritic gneisses show Na-rich tonalite–trondhjemite–granodiorite (TTG)-like affinity with zircon U-Pb dates of ca. 2.57–2.59 Ga, representing a juvenile continental growth for the northeastern NCC. The granitic gneiss is indeed potassic granite and yielded a zircon U-Pb date of ~2.50 Ga, which is contemporaneous with the Jining–Jiaoliao microblock collision (2.53–2.49 Ga), implying another crustal growth event. The well-developed gneissosity in 2.57–2.59 Ga dioritic and granodioritic gneisses together with the 2.5 Ga potassic granite, which crosscuts the gneissosity implies a 2.57–2.50 Ga (mainly 2.53–2.51 Ga) collisional orogeny, probably related to the Jining–Jiaoliao microblock collision. Our new geology and chronological results provide new evidence for the early Precambrian tectonic evolution of the NCC.     

四川攀西地区几个小型镁铁-超镁铁岩体含矿性的铂族元素示踪

峨眉山大火成岩省内带,四川攀西地区的杨合伍、黄草坪和清水河等镁铁-超镁铁岩体分布在南北向的安宁河断裂和磨盘山-元谋断裂之间。分析表明,这些岩体无矿岩石与金宝山、杨柳坪、力马河等含矿岩体无矿岩石具有相似的铂族元素组成,普遍较高的Cu/Pd比值暗示这些岩体的母岩浆在侵入到目前层位前经历过硫化物熔离作用。定量模拟计算表明,原始岩浆经过大约0.01%的硫化物熔离作用形成了杨合伍岩体母岩浆,经过0.035%硫化物熔离形成了黄草坪和清水河岩体的母岩浆。根据硫化物熔离情况,认为杨合伍等岩体底部可能形成Ni-Cu-(PGE)硫化物矿床,而黄草坪和清水河岩体之下及附近可能存在Ni-Cu硫化物矿化的岩体。