Remediation of the Wells G & H Superfund Site,Woburn, Massachusetts

Remediation of ground water and soil contamination at the Wells G & H Superfund Site, Woburn, Massachusetts, uses technologies that reflect differences in hydrogeologic settings, concentrations of volatile organic compounds (VOCs), and costs of treatment. The poorly permeable glacial materials that overlie fractured bedrock at the W.R. Grace property necessitate use of closely spaced recovery wells. Contaminated ground water is treated with hydrogen peroxide and ultraviolet (UV) oxidation. At UniFirst, a deep well completed in fractured bedrock removes contaminated ground water, which is treated by hydrogen peroxide, UV oxidation, and granular activated carbon (GAC). The remediation system at Wildwood integrates air sparging, soil-vapor extraction, and ground water pumping. Air stripping and GAC are used to treat contaminated water; GAC is used to treat contaminated air. New England Plastics (NEP) uses air sparging and soil-vapor extraction to remove VOCs from the unsaturated zone and shallow ground water. Contaminated air and water are treated using separate GAC systems. After nine years of operation at W.R. Grace and UniFirst, 30 and 786 kg, respectively, of VOCs have been removed. In three years of operation, 866 kg of VOCs have been removed at Wildwood. In 15 months of operation, 36 kg of VOCs were removed at NEP. Characterization work continues at the Olympia Nominee Trust, Whitney Barrel, Murphy Waste Oil, and Aberjona Auto Parts properties. Risk assessments are being finalized that address heavy metals in the floodplain sediments along the Aberjona River that are mobilized from the Industri-Plex Superfund Site located a few miles upstream.     

High-resolution estimates of lithospheric thickness from Missouri to Massachusetts, USA

This paper presents a new three-dimensional (3-D) model, NA00, of the S-velocity of the upper mantle beneath North America. The model differs from its predecessor NA95 in that it exploits seismograms recorded by a recent dense, broadband array, MOMA, and from independent measurements of North American crustal thickness. Model NA00 is derived by fitting the waveforms of broadband seismic S and surface waves recorded by the MOMA array and inverting them together with the database of waveform fits used for NA95 and the crustal thickness estimates. It is demonstrated that including data from the dense, broadband MOMA array yields a resolving power beneath the array that is of unprecedented quality and relatively constant over a large depth range. This improved resolution provides a unique opportunity for quantifying the structure of the upper mantle in and below the lower, thick Precambrian lithosphere. The high-resolution seismic structure of the imaged high-velocity lithosphere is compared with the thermal structure (estimated from heat flow), compositional structure (estimated from xenoliths and electrical conductivity) and the elastic structure (estimated from gravity and topography). There is a remarkable agreement between the seismic, thermal, and compositional estimates. The seismic lithosphere is 180 km thick below Missouri and Illinois, 200 km thick below Indiana, Ohio and Pennsylvania, practically undefined below New York, and 80 km below Massachusetts and the Atlantic continental shelf. The thick lithosphere is underlain by a layer with lower S-velocities that could represent a relatively low-viscosity channel. However, the S-velocities in this layer are much higher than those of typical oceanic asthenosphere.     

Sand wave migration near the southeastern corner of Martha's Vineyard,Massachusetts, USA

Sand waves of approximately 2 m in height were observed to migrate nearly 40 m with counterclockwise rotation between two bathymetric surveys performed three months apart near the southeastern corner of Martha's Vineyard, Massachusetts. The region is characterized by strong tidal currents, intermittent energetic surface wave events, and shallow water with local depth ranging from 2 to 7 m. This study uses the process-based model, Delft3D, with a three-dimensional approach to examine the sand wave dynamics by incorporating surface waves, winds, currents, and bathymetric observations. The model successfully simulates sand wave migration in comparisons to observations. Model sensitivity analyses show that the sand wave migration reduces by 65% with the absence of the surface waves. The modeled sand wave migration speed is correlated with the tidal current Shields parameter, and sharp increases in migration speed occur when the wave-driven Shields parameter increases in response to energetic surface wave events. The combined effect of tides, surface waves, and bathymetry is the origin of the rotational aspect of the sand wave, using the Shields parameter as an indicator of tidal currents and surface wave influence on sand wave dynamics.     

Storm-driven sediment transport in Massachusetts Bay

Massachusetts Bay is a semi-enclosed embayment in the western Gulf of Maine about 50 km wide and 100 km long. Bottom sediment resuspension is controlled predominately by storm-induced surface waves and transport by the tidal- and wind-driven circulation. Because the Bay is open to the northeast, winds from the northeast (‘Northeasters’) generate the largest surface waves and are thus the most effective in resuspending sediments. The three-dimensional oceanographic circulation model Regional Ocean Modeling System (ROMS) is used to explore the resuspension, transport, and deposition of sediment caused by Northeasters. The model transports multiple sediment classes and tracks the evolution of a multilevel sediment bed. The surficial sediment characteristics of the bed are coupled to one of several bottom-boundary layer modules that calculate enhanced bottom roughness due to wave–current interaction. The wave field is calculated from the model Simulating WAves Nearshore (SWAN). Two idealized simulations were carried out to explore the effects of Northeasters on the transport and fate of sediments. In one simulation, an initially spatially uniform bed of mixed sediments exposed to a series of Northeasters evolved to a pattern similar to the existing surficial sediment distribution. A second set of simulations explored sediment-transport pathways caused by storms with winds from the northeast quadrant by simulating release of sediment at selected locations. Storms with winds from the north cause transport southward along the western shore of Massachusetts Bay, while storms with winds from the east and southeast drive northerly nearshore flow. The simulations show that Northeasters can effectively transport sediments from Boston Harbor and the area offshore of the harbor to the southeast into Cape Cod Bay and offshore into Stellwagen Basin. This transport pattern is consistent with Boston Harbor as the source of silver found in the surficial sediments of Cape Cod Bay and Stellwagen Basin.     

Negative correlation between porosity and hydraulic conductivity in sand-and-gravel aquifers at Cape Cod,Massachusetts, USA

Although it may be intuitive to think of the hydraulic conductivity K of unconsolidated, coarse-grained sediments as increasing monotonically with increasing porosity Φ, studies have documented a negative correlation between these two parameters under certain grain-size distributions and packing arrangements. This is confirmed at two sites on Cape Cod, Massachusetts, USA, where groundwater investigations were conducted in sand-and-gravel aquifers specifically to examine the interdependency of several aquifer properties using measurements from four geophysical well logs. Along with K and Φ, the electrical resistivity R₀ and the natural gamma activity γ of saturated deposits were determined as functions of depth. Qualitative examination of results from the first site implies a negative correlation between K and Φ that is substantiated by a rigorous multivariate analysis of log data collected from the second site. A principal components analysis describes an over-determined system of inversion equations, with approximately 92% of the cumulative proportion of the total variance being accounted for by only three of the four eigenvectors. A subsequent R-mode factor analysis projects directional trends among the four variables (K, Φ, R₀ and γ), and a negative correlation between K and Φ emerges as the primary result.     

Transient analysis of the source of water to wells: Cape Cod, Massachusetts

A transient flow modeling analysis for potential public-supply wells on western Cape Cod, Massachusetts, demonstrates the difference between transient and steady-state recharge areas can have important implications for wellhead protection. An example of a single pumping well illustrates that commonly used steady-state time-related capture areas do not represent the recharge area and travel times of water being pumped from the well until sufficient time has elapsed for steady-state flow conditions to be established. Until that time, transient recharge areas are needed to account for the portion of water discharging from the well that entered the aquifer before pumping started. An example of two pumping wells demonstrates the same area at the water table cannot supply water to more than one well under steady-state flow conditions. Transient recharge areas to multiple wells can overlap, however, until steady-state flow conditions are established. The same area can, therefore, be a source of water to more than one well during early pumping times, and the water pumped from a given well may derive from source areas, including contaminated areas, that do not lie within the well's steady-state recharge area.     

Dynamics of planktonic bacteria and heterotrophic microflagellates in the Parker Estuary, northern Massachusetts

The temporal and spatial abundance and activities of members of the planktonic microbial food web in a salt marsh estuary were analysed over the course of a year. Analysis of the data was focused on the factors that control the density and productivity of the heterotrophic bacteria. Temperature exercises a long-term influence on substrate sources, but short-term control is a function of the interaction of grazing and substrate supply. A model has been developed to give a framework for understanding how the microbial food web may work under steady-state assumptions. The model assumptions and predictions appear to be supported by the field data. Equations were generated for estimating substrate flux through the bacteria and estimating bacterial density as a result of grazing and substrate input. The results give some insights into the question of whether the heterotrophic bacteria function as a link to higher organisms or as an energy sink.     

Large internal waves in Massachusetts Bay transport sediments offshore

A field experiment was carried out in Massachusetts Bay in August 1998 to assess the role of large-amplitude internal waves (LIWs) in resuspending bottom sediments. The field experiment consisted of a four-element moored array extending from just west of Stellwagen Bank (90-m water depth) across Stellwagen Basin (85- and 50-m water depth) to the coast (24-m water depth). The LIWs were observed in packets of 5–10 waves, had periods of 5–10 min and wavelengths of 200–400 m, and caused downward excursions of the thermocline of as much as 30 m. At the 85-m site, the current measured 1 m above bottom (mab) typically increased from near 0 to 0.2 m/s offshore in a few minutes upon arrival of the LIWs. At the 50-m site, the near-bottom offshore flow measured 6 mab increased from about 0.1 to 0.4–0.6 m/s upon arrival of the LIWs and remained offshore in the bottom layer for 1–2 h. The near-bottom currents associated with the LIWs, in concert with the tidal currents, were directed offshore and sufficient to resuspend the bottom sediments at both the 50- and 85-m sites. When LIWs are present, they may resuspend sediments for as long as 5 hours each tidal cycle as they travel westward across Stellwagen Basin. At 85-m water depth, resuspension associated with LIWs is estimated to occur for about 0.4 days each summer, about the same amount of time as caused by surface waves.     

Validation of SeaWiFS chlorophyll a in Massachusetts Bay

Massachusetts Bay, a semi-enclosed embayment (50×100 km) in the Northwest Atlantic, is the focus of a monitoring program designed to measure the effects of relocating the Boston Harbor sewage outfall to a site 15 km offshore in Massachusetts Bay. The Massachusetts Water Resources Authority (MWRA) in situ monitoring program samples selected stations up to 17 times per year to observe seasonal changes in phytoplankton biomass and other water quality variables. We investigated the feasibility of augmenting the monitoring data with satellite ocean color data to increase the spatial and temporal resolution of quantitative phytoplankton measurements. In coastal regions such as Massachusetts Bay, ocean color remote sensing can be complicated by in-water constituents whose concentrations vary independently of phytoplankton and by inaccurate modeling of absorbing aerosols that tend to be concentrated near the coast. An evaluation of in situ and sea-viewing wide field-of-view sensor (SeaWiFS) measurements from 1998 to 2005 demonstrated that SeaWiFS overestimated chlorophyll a mainly due to atmospheric correction errors that were amplified by absorption from elevated concentrations of chlorophyll a and colored dissolved organic matter. Negative water-leaving radiances in the 412 nm band, an obvious artifact of inadequate atmospheric correction, were recorded in approximately 60–80% of the cloud-free images along the coast, while the remaining portions of the Bay only experience negative radiances 35–55% of the time with a clear nearshore to offshore decrease in frequency. Seasonally, the greatest occurrences of negative 412 nm radiances were in November and December and the lowest were recorded during the summer months. Concentrations of suspended solids in Massachusetts Bay were low compared with other coastal regions and did not have a significant impact on SeaWiFS chlorophyll a measurements. A regional empirical algorithm was developed to correct the SeaWiFS data to agree with in situ observations. Monthly SeaWiFS composites illustrated the spatial extent of a bimodal seasonal pattern, including prominent spring and fall phytoplankton blooms; and the approximate 115 cloud-free scenes per year revealed interannual variations in the timing, magnitude and duration of phytoplankton blooms. Despite known artifacts of SeaWiFS in coastal regions, this study provided a viable chlorophyll a product in Massachusetts Bay that significantly increased the spatial and temporal synoptic coverage of phytoplankton biomass, which can be used to gain a comprehensive ecosystem-wide understanding of phytoplankton dynamics at event, seasonal and interannual timescales.     

Are toxic contaminants accumulating in Massachusetts coastal sediments following startup of the Massachusetts Bay outfall: a comprehensive comparison of baseline and post-diversion periods

The Massachusetts Water Resources Authority (MWRA) conducts monitoring to address concerns related to the 2000 diversion of secondarily treated effluent discharge into Massachusetts Bay. Baseline data (1992-2000) showed multiple regions defined by physical and chemical composition. Near the Massachusetts Bay outfall, there is a series of heterogeneous sediments in relatively close proximity to the primary historic source of contaminants (Boston Harbor). Farfield sediments exhibited greater compositional definition from one another, which was attributed to the greater spatial separation of the sampling locations. Factors that influence contaminant variability include local and distributed sources, and are primarily related to gradients in depositional environments. Post-diversion sediment data suggest that 4 years of treated effluent discharge has not increased contaminant concentrations to the bay system. However, abundance of the sewage tracer, Clostridium perfringens, has increased variably in sediments located within 2 km of the outfall, providing a distinct effluent signal near the outfall.     

Estimating the timescale of fluvial response to anthropogenic disturbance using two generations of dams on the South River,Massachusetts, USA

Centuries-long intensive land-use change in the north-eastern United States provides the opportunity to study the timescale of geomorphic response to anthropogenic disturbances. In this region, forest-clearing and agricultural practices following EuroAmerican settlement led to deposition of legacy sediment along valley bottoms, including behind mill dams. The South River in western Massachusetts experienced two generations of damming, beginning with mill dams up to 6-m high in the eighteenth–nineteenth century, and followed by construction of the Conway Electric Dam (CED), a 17-m-tall hydroelectric dam near the watershed outlet in 1906. We use the mercury (Hg) concentration in upstream deposits along the South River to constrain the magnitude, source, and timing of inputs to the CED impoundment. Based on cesium-137 (¹³⁷Cs) chronology and results from a sediment mixing model, remobilized legacy sediment comprised % of the sediment load in the South River prior to 1954; thereafter, from 1954 to 1980s, erosion from glacial deposits likely dominated (63 ± 14%), but with legacy sediments still a substantial source (37 ± 14%). We also use the CED reservoir deposits to estimate sediment yield through time, and find it decreased after 1952. These results are consistent with high rates of mobilization of legacy sediment as historic dams breached in the early twentieth century, and suggest rapid initial response to channel incision, followed by a long decay in the second half of the century, that is likely dependent on large flood events to access legacy sediment stored in banks. Identifying sources of sediment in a watershed and quantifying erosion rates can help to guide river restoration practices. Our findings suggest a short fluvial recovery time from the eighteenth–nineteenth century to perturbation during the first half of the twentieth century, with subsequent return to a dominant long-term signal from erosion of glacial deposits, with anthropogenic sediment persisting as a secondary source. © 2020 John Wiley & Sons, Ltd.     

Chlorophyll fluorescence responses to additions of Pinus rigida L. pollen in freshwater kettle ponds of Cape Cod National Seashore (Massachusetts,USA)

Terrestrial ecosystems contribute many different forms of organic matter to adjacent waterbodies. Carbon, nitrogen, and phosphorus in this material can significantly influence the planktonic communities of these systems, especially where there is a large proportion of contributing area relative to waterbody size and where nutrients are generally in short supply. Plant pollen, which upon degradation releases nutrients into the water column, is one such source of allochthonous material. In Cape Cod (Massachusetts, USA), large amounts of pollen from dense pitch pine (Pinus rigida L.) forest are deposited in late spring into small, freshwater lakes scattered across the landscape. This study examines in vivo chlorophyll fluorescence responses of surface-water samples collected from three such lakes within Cape Cod National Seashore (Wellfleet and Truro) to additions of P. rigida pollen in a laboratory setting. The results indicate that where influxes are high enough, pollen can have a stimulatory effect on phytoplankton communities and is a short-term nutrient subsidy in these systems at a time of year (May-June) when warming temperatures and faster growth rates elevate the demand for nutrients.