Estimating shock pressures based on high‐pressure minerals in shock‐induced melt veins of L chondrites

Abstract— Here we report the transmission electron microscopy (TEM) observations of the mineral assemblages and textures in shock‐induced melt veins from seven L chondrites of shock stages ranging from S3 to S6. The mineral assemblages combined with phase equilibrium data are used to constrain the crystallization pressures, which can be used to constrain shock pressure in some cases. Thick melt veins in the Tenham L6 chondrite contain majorite and magnesiowüstite in the center, and ringwoodite, akimotoite, vitrified silicate‐perovskite, and majorite in the edge of the vein, indicating crystallization pressure of ?25 GPa. However, very thin melt veins (5–30 μm wide) in Tenham contain glass, olivine, clinopyroxene, and ringwoodite, suggesting crystallization during transient low‐pressure excursions as the shock pressure equilibrated to a continuum level. Melt veins of Umbarger include ringwoodite, akimotoite, and clinopyroxene in the vein matrix, and Fe₂SiO₄‐spinel and stishovite in SiO₂‐FeO‐rich melt, indicating a crystallization pressure of ?18 GPa. The silicate melt veins in Roy contain majorite plus ringwoodite, indicating pressure of ?20 GPa. Melt veins of Ramsdorf and Nakhon Pathon contain olivine and clinoenstatite, indicating pressure of less than 15 GPa. Melt veins of Kunashak and La Lande include albite and olivine, indicating crystallization at less than 2.5 GPa. Based upon the assemblages observed, crystallization of shock veins can occur before, during, or after pressure release. When the assemblage consists of high‐pressure minerals and that assemblage is constant across a larger melt vein or pocket, the crystallization pressure represents the equilibrium shock pressure.     

High‐pressure phases in shock‐induced melt veins of the Umbarger L6 chondrite: Constraints of shock pressure

Abstract— We report a previously undocumented set of high‐pressure minerals in shock‐induced melt veins of the Umbarger L6 chondrite. High‐pressure minerals were identified with transmission electron microscopy (TEM) using selected area electron diffraction and energy‐dispersive X‐ray spectroscopy. Ringwoodite (Fa₃₀), akimotoite (En₁₁Fs₈₉), and augite (En₄₂Wo₃₃Fs₂₅) were found in the silicate matrix of the melt vein, representing the crystallization from a silicate melt during the shock pulse. Ringwoodite (Fa₂₇) and hollandite‐structured plagioclase were also found as polycrystalline aggregates in the melt vein, representing solid state transformation or melting with subsequent crystallization of entrained host rock fragments in the vein. In addition, Fe₂SiO₄‐spinel (Fa₆₆‐Fa₉₉) and stishovite crystallized from a FeO‐SiO₂‐rich zone in the melt vein, which formed by shock melting of FeO‐SiO₂‐rich material that had been altered and metasomatized before shock. Based on the pressure stabilities of the high‐pressure minerals, ringwoodite, akimotoite, and Ca‐clinopyroxene, the melt vein crystallized at approximately 18 GPa. The Fe₂SiO₄‐spinel + stishovite assemblage in the FeO‐SiO₂‐rich melts is consistent with crystallization of the melt vein matrix at the pressure up to 18 GPa. The crystallization pressure of ?18 GPa is much lower than the 45–90 GPa pressure one would conclude from the S6 shock effects in melt veins (Stöffler et al. 1991) and somewhat less than the 25–30 GPa inferred from S5 shock effects (Schmitt 2000) found in the bulk rock.     

Shock metamorphism and impact melting in small impact craters on Earth: Evidence from Kamil crater,Egypt

Kamil is a 45 m diameter impact crater identified in 2008 in southern Egypt. It was generated by the hypervelocity impact of the Gebel Kamil iron meteorite on a sedimentary target, namely layered sandstones with subhorizontal bedding. We have carried out a petrographic study of samples from the crater wall and ejecta deposits collected during our first geophysical campaign (February 2010) in order to investigate shock effects recorded in these rocks. Ejecta samples reveal a wide range of shock features common in quartz‐rich target rocks. They have been divided into two categories, as a function of their abundance at thin section scale: (1) pervasive shock features (the most abundant), including fracturing, planar deformation features, and impact melt lapilli and bombs, and (2) localized shock features (the least abundant) including high‐pressure phases and localized impact melting in the form of intergranular melt, melt veins, and melt films in shatter cones. In particular, Kamil crater is the smallest impact crater where shatter cones, coesite, stishovite, diamond, and melt veins have been reported. Based on experimental calibrations reported in the literature, pervasive shock features suggest that the maximum shock pressure was between 30 and 60 GPa. Using the planar impact approximation, we calculate a vertical component of the impact velocity of at least 3.5 km s^?1. The wide range of shock features and their freshness make Kamil a natural laboratory for studying impact cratering and shock deformation processes in small impact structures.     

High‐pressure phase transitions of α‐quartz under nonhydrostatic dynamic conditions: A reconnaissance study at PETRA III

Hypervelocity collisions of solid bodies occur frequently in the solar system and affect rocks by shock waves and dynamic loading. A range of shock metamorphic effects and high‐pressure polymorphs in rock‐forming minerals are known from meteorites and terrestrial impact craters. Here, we investigate the formation of high‐pressure polymorphs of α‐quartz under dynamic and nonhydrostatic conditions and compare these disequilibrium states with those predicted by phase diagrams derived from static experiments under equilibrium conditions. We create highly dynamic conditions utilizing a mDAC and study the phase transformations in α‐quartz in situ by synchrotron powder X‐ray diffraction. Phase transitions of α‐quartz are studied at pressures up to 66.1 and different loading rates. At compression rates between 0.14 and 1.96 GPa s^?1, experiments reveal that α‐quartz is amorphized and partially converted to stishovite between 20.7 GPa and 28.0 GPa. Therefore, coesite is not formed as would be expected from equilibrium conditions. With the increasing compression rate, a slight increase in the transition pressure occurs. The experiments show that dynamic compression causes an instantaneous formation of structures consisting only of SiO₆ octahedra rather than the rearrangement of the SiO₄ tetrahedra to form a coesite. Although shock compression rates are orders of magnitude faster, a similar mechanism could operate in impact events.     

The first MEMIN shock recovery experiments at low shock pressure (5–12.5 GPa) with dry,porous sandstone

Abstract– As part of the MEMIN research program this project is focused on shock deformation experimentally generated in dry, porous Seeberger sandstone in the low shock pressure range from 5 to 12.5 GPa. Special attention is paid to the influence of porosity on progressive shock metamorphism. Shock recovery experiments were carried out with a high‐explosive set‐up that generates a planar shock wave, and using the shock impedance method. Cylinders of sandstone of average grain size of 0.17 mm and porosity of about 19 vol%, and containing some 96 wt% SiO₂, were shock deformed. Shock effects induced with increasing shock pressure include: (1) Already at 5 GPa the entire pore space is closed; quartz grains show undulatory extinction. On average, 134 fractures per mm are observed. Dark vesicular melt (glass) of the composition of the montmorillonitic phyllosilicate component of this sandstone occurs at an average amount of 1.6 vol%. (2) At 7.5 GPa, quartz grains show weak but prominent mosaicism and the number of fractures increases to 171 per millimeter. Two additional kinds of melt, both based on phyllosilicate precursor, could be observed: a light colored, vesicular melt and a melt containing large iron particles. The total amount of melt (all types) increased in this experiment to 2.4 vol%. Raman spectroscopy confirmed the presence of shock‐deformed quartz grains near the surface. (3) At 10 and 12.5 GPa, quartz grains also show weak but prominent mosaicism, the number of fractures per mm has reached a plateau value of approximately 200, and the total amount of the different melt types has increased to 4.8 vol%. Diaplectic quartz glass could be observed locally near the impacted surface. In addition, local shock effects, most likely caused by multiple shock wave reflections at sandstone‐container interfaces, occur throughout the sample cylinders and include locally enhanced formation of PDF, as well as shear zones associated with cataclastic microbreccia, diaplectic quartz glass, and SiO₂ melt. Overall findings from these first experiments have demonstrated that characteristic shock effects diagnostic for the confirmation of impact structures and suitable for shock pressure calibration are rare. So far, they are restricted to the limited formation of PDF and diaplectic quartz glass at shock pressures of 10 GPa and above.     

Shock‐induced formation of wüstite and fayalite in a magnetite‐quartz target rock

Projectile–target interactions as a result of a large bolide impact are important issues, as abundant extraterrestrial material has been delivered to the Earth throughout its history. Here, we report results of shock‐recovery experiments with a magnetite‐quartz target rock positioned in an ARMCO iron container. Petrography, synchrotron‐assisted X‐ray powder diffraction, and micro‐chemical analysis confirm the appearance of wüstite, fayalite, and iron in targets subjected to 30 GPa. The newly formed mineral phases occur along shock veins and melt pockets within the magnetite‐quartz aggregates, as well as along intergranular fractures. We suggest that iron melt formed locally at the contact between ARMCO container and target, and intruded the sample causing melt corrosion at the rims of intensely fractured magnetite and quartz. The strongly reducing iron melt, in the form of μm‐sized droplets, caused mainly a diffusion rim of wüstite with minor melt corrosion around magnetite. In contact with quartz, iron reacted to form an iron‐enriched silicate melt, from which fayalite crystallized rapidly as dendritic grains. The temperatures required for these transformations are estimated between 1200 and 1600 °C, indicating extreme local temperature spikes during the 30 GPa shock pressure experiments.     

Revision and recalibration of existing shock classifications for quartzose rocks using low‐shock pressure (2.5–20 GPa) recovery experiments and mesoscale numerical modeling

A combination of shock recovery experiments and numerical modeling of shock deformation in the low‐shock pressure range from 2.5 to 20 GPa for two dry sandstone types of different porosity, a completely water‐saturated sandstone, and a well‐indurated quartzite provides new insights into strongly heterogeneous distribution of different shock features. (1) For nonporous quartzo‐feldspathic rocks, the traditional classification scheme (Stöffler 1984 ) is suitable with slight changes in pressure calibration. (2) For water‐saturated quartzose rocks, a cataclastic texture (microbreccia) seems to be typical for the shock pressure range up to 20 GPa. This microbreccia does not show formation of PDFs but diaplectic quartz glass/SiO₂ melt is formed at 20 GPa (~1 vol%). (3) For porous quartzose rocks, the following sequence of shock features is observed with progressive increase in shock pressure (1) crushing of pores, (2) intense fracturing of quartz grains, and (3) increasing formation of diaplectic quartz glass/SiO₂ melt replacing fracturing. The formation of diaplectic quartz glass/SiO₂ melt, together with SiO₂ high‐pressure phases, is a continuous process that strongly depends on porosity. This experimental observation is confirmed by our concomitant numerical modeling. Recalibration of the shock classification scheme results in a porosity versus shock pressure diagram illustrating distinct boundaries for the different shock stages.     

Shocked rocks and impact glasses from the El'gygytgyn impact structure,Russia

Abstract— The El'gygytgyn impact structure is about 18 km in diameter and is located in the central part of Chukotka, arctic Russia. The crater was formed in volcanic rock strata of Cretaceous age, which include lava and tuffs of rhyolites, dacites, and andesites. A mid‐Pliocene age of the crater was previously determined by fission track (3.45 ± 0.15 Ma) and ⁴⁰Ar/³⁹Ar dating (3.58 ± 0.04 Ma). The ejecta layer around the crater is completely eroded. Shock‐metamorphosed volcanic rocks, impact melt rocks, and bomb‐shaped impact glasses occur in lacustrine terraces but have been redeposited after the impact event. Clasts of volcanic rocks, which range in composition from rhyolite to dacite, represent all stages of shock metamorphism, including selective melting and formation of homogeneous impact melt. Four stages of shocked volcanic rocks were identified: stage I (≤35 GPa; lava and tuff contain weakly to strongly shocked quartz and feldspar clasts with abundant PFs and PDFs; coesite and stishovite occur as well), stage II (35–45 GPa; quartz and feldspar are converted to diaplectic glass; coesite but no stishovite), stage III (45–55 GPa; partly melted volcanic rocks; common diaplectic quartz glass; feldspar is melted), and stage IV (>55 GPa; melt rocks and glasses). Two main types of impact melt rocks occur in the crater: 1) impact melt rocks and impact melt breccias (containing abundant fragments of shocked volcanic rocks) that were probably derived from (now eroded) impact melt flows on the crater walls, and 2) aerodynamically shaped impact melt glass “bombs” composed of homogeneous glass. The composition of the glasses is almost identical to that of rhyolites from the uppermost part of the target. Cobalt, Ni, and Ir abundances in the impact glasses and melt rocks are not or only slightly enriched compared to the volcanic target rocks; only the Cr abundances show a distinct enrichment, which points toward an achondritic projectile. However, the present data do not allow one to unambiguously identify a meteoritic component in the El'gygytgyn impact melt rocks.     

Silica as a shock index in shergottites: A cathodoluminescence study

Abstract— Silica in shergottites is a minor phase of great significance. Determining its structural state as either silica glass, quartz, cristobalite, tridymite, coesite, stishovite, or post‐stishovite could provide informations about their shock history. The purpose of this work is to assess the shock intensity in shergottites using two spectroscopic methods. On a conventional polished section, a scanning electron microscope (SEM) enables us to study the cathodoluminescence (CL) of silica at variable magnification. The results were crosschecked by systematic Raman spectroscopy of the selected areas. CL spectra differ substantially from one another and enable separating stishovite, high and low pressure silica glass, quartz, and cristobalite. We studied a set of five shergottites: Northwest Africa (NWA) 480, NWA 856, Zagami, Shergotty, and Los Angeles. Stishovite is common in Shergotty, Zagami, NWA 856, and NWA 480 and absent in the studied section of Los Angeles. High‐pressure glass is very common, particularly in close association with stishovite. According to the textural relationship, it may be a product of the retromorphosis (amorphization during decompression) of stishovite. Large stishovite areas result from the transformation of preexisting low‐pressure silica crystals, while needles result from the high‐pressure transformation of pyroxene to glass (melt) and silica. In the latter case, they are found in melt pockets and represent a small fraction of areas of overall pyroxene composition. Needles exhibit square sections of about 1 μm. Silica spots identical to those described previously as post‐stishovite are found in Shergotty, Zagami, NWA 480, and NWA 856. At present, the spectroscopic distinction of post‐stishovite from stishovite is difficult. Post‐stishovite is destroyed under the Raman beam, and CL spectra are possible mixtures of several phases (e.g., glass and post‐stishovite). It is concluded that the shock intensity is highly heterogeneous, and the pressure probably exceeded 60 GPa in all shergottites studied here.     

Experimental shock synthesis of diamonds in a graphite gneiss

Abstract— The occurrence of diamonds in terrestrial impact craters and meteorites is related to dynamic shock loading during hypervelocity impacts. To understand the mechanism of impact diamond formation in natural rocks, shock‐recovery experiments with graphite gneiss were carried out at shock pressures between 35 and 79 GPa. This is the first report on the successful shock synthesis of microdiamonds in a natural rock. Micrometer‐size diamonds and a wide range of intermediate, presently unclassified, amorphous, and disordered carbon phases were observed within vesiculated biotite melts in the vicinity of relic graphite grains using microRaman spectrometry. We explain these findings by jetting mechanisms of carbon and graphite clusters, originating at the edges of graphite grains, into the very hot and volatile rich biotitic melt veins during shock loading. This environment enabled the thermally activated crystallization of diamonds during shock compression in a period of less than 0.5 μsec. Regraphitization of diamonds during pressure release was widespread and caused the formation of the amorphous to disordered carbon phases recorded frequently with microRaman spectroscopy. The surviving diamonds must have cooled down to 2000 K during the compression phase at local thermal sinks and cooler interfaces to avoid regraphitization.     

Shock‐induced phase transformation of anorthitic plagioclase in the eucrite meteorite Northwest Africa 2650

Anorthite is an important constituent mineral in basaltic achondrites from small celestial bodies. Its high‐pressure phase transformation in shocked meteorites has not been systematically studied. In this study, we report the diverse phase transformation behaviors of anorthite in a shocked eucrite Northwest Africa (NWA) 2650, which also contains coesite, stishovite, vacancy‐rich clinopyroxene, super‐silicic garnet, and reidite. Anorthite in NWA 2650 has transformed into anorthite glass (anorthite glassy vein, maskelynite, and glass with a schlieren texture and vesicles), tissintite and dissociated into three‐phase assemblage grossular + kyanite + silica glass. Different occurrences of anorthite glass might have formed via the mechanism involving shear melting, solid‐state transformation, and postshock thermally melting, respectively. Tissintite could have crystallized from a high‐pressure plagioclase melt. The nucleation of tissintite might be facilitated by relict pyroxene fragments and the early formed vacancy‐rich clinopyroxene. The three‐phase assemblage grossular, kyanite, and silica glass should have formed from anorthitic melt at high‐pressure and high‐temperature conditions. The presence of maskelynite and reidite probably suggests a minimum peak shock pressure up to 20 GPa, while the other high‐pressure phases indicate that the shock pressure during the crystallization of shock melt veins might vary from >8 GPa to >2 GPa with a heterogeneous temperature distribution.     

Localized shock-induced melting of sandstone at low shock pressures (<17.5 GPa): An experimental study

Shock-induced recovery experiments were performed to investigate melt formation in porous sandstones in the low shock pressure regime between 2.5 and 17.5 GPa. The sandstone shocked at 2.5 and 5 GPa is characterized by pore closure, fracturing of quartz (Qtz), and compression and deformation of phyllosilicates; no melting was observed. At higher pressures, five different types of melts were generated around pores and alongside fractures in the sandstone. Melting of kaolinite (Kln), illite (Ill), and muscovite (Ms) starts at 7.5, 12, and 15 GPa, respectively. The larger the amount of water in these minerals (Kln ~14 wt%, Ill ~6–10 wt%, and Ms ~4 wt% H₂O), the higher the shock compressibility and the lower the shock pressure required to induce melting. Vesicles in the almost dry silicate glasses attest to the loss of structural water during the short shock duration of the experiment. The compositions of the phyllosilicate-based glasses are identical to the composition of the parental minerals or their mixtures. Thus, this study has demonstrated that phyllosilicates in shocked sandstone undergo congruent melting during shock loading. In experiments at 10 GPa and higher, iron melt from the driver plate was injected into the phyllosilicate melts. During this process, Fe is partitioned from the metal droplets into the surrounding silicate melts, which induced unmixing of silicate melts with different chemical properties (liquid immiscibility). At pressures between 7.5 and 15 GPa, a pure SiO₂ glass was formed, which is located as short and thin bands within Qtz grains. These bands were shown to contain tiny crystals of experimentally generated stishovite.     

Quartz–coesite–stishovite relations in shocked metaquartzites from the Vredefort impact structure,South Africa

Coesite and stishovite are developed in shock veins within metaquartzites beyond a radius of ~30 km from the center of the 2.02 Ga Vredefort impact structure. This work focuses on deploying analytical field emission scanning electron microscopy, electron backscattered diffraction, and Raman spectrometry to better understand the temporal and spatial relations of these silica polymorphs. α-Quartz in the host metaquartzites, away from shock veins, exhibits planar features, Brazil twins, and decorated planar deformation features, indicating a primary (bulk) shock loading of >5 < 35 GPa. Within the shock veins, coesite forms anhedral grains, ranging in size from 0.5 to 4 μm, with an average of 1.25 μm. It occurs in clasts, where it displays a distinct jigsaw texture, indicative of partial reversion to a less dense SiO₂ phase, now represented by microcrystalline quartz. It is also developed in the matrix of the shock veins, where it is typically of smaller size (<1 μm). Stishovite occurs as euhedral acicular crystals, typically <0.5 μm wide and up to 15 μm in length, associated with clast–matrix or shock vein margin–matrix interfaces. In this context, the needles occur as radiating or subparallel clusters, which grow into/over both coesite and what is now microcrystalline quartz. Stishovite also occurs as more blebby, subhedral to anhedral grains in the vein matrix (typically <1 μm). We propose a model for the evolution of the veins (1) precursory frictional melting in a microfault (~1 mm wide) generates a molten matrix containing quartz clasts. This is followed by (2) arrival of the main shock front, which shocks to 35 GPa. This generates coesite in the clasts and in the matrix. (3) On initial shock release, the coesite partly reverts to a less dense SiO₂ phase, which is now represented by microcrystalline quartz. (4) With continued release, stishovite forms euhedral needle clusters at solid–liquid interfaces and as anhedral crystals in the matrix. (5) With decreasing pressure–temperature, the matrix completes crystallization to yield a microcrystalline quasi-igneous texture comprising quartz–coesite–stishovite–kyanite–biotite–alkali feldspar and accessory phases. It is possible that the shock vein represents the locus of a thermal spike within the bulk shock, in which case there is no requirement for additional pressure (i.e., the bulk shock was ≃35 GPa). However, if that pressure was not realized from the main shock, then supplementary pressure excursions within the vein would have been required. These could have taken the form of localized reverberations from wave trapping, or implosion processes, including pore collapse, phase change–initiated volume reduction, and melt cavitation.     

The distinct morphological and petrological features of shock melt veins in the Suizhou L6 chondrite

Abstract– The morphology and petrology of distinct melt veins in the Suizhou L6 chondrite have been investigated using scanning electron microscopy, electron microprobe analyses, and Raman spectroscopy, synchrotron energy‐dispersive diffraction, and transmission electron microscopy. It is found that the melt veins in the Suizhou meteorite morphologically are the simplest, straightest, and thinnest among all shock veins known from meteorites. At first glance, these veins look like fine fractures, but petrologically they are solid melt veins of chondritic composition and consist of fully crystalline materials of two distinct lithological assemblages, with no glassy material remaining. The Suizhou melt veins contain the most abundant high‐pressure mineral species when compared with all other veins known in chondrites. Thus, these veins in Suizhou are classified as shock veins. All rock‐forming and almost all accessory minerals in the Suizhou shock veins have been transformed to their high‐pressure polymorphs, and no fragments of the precursor minerals remain in the veins. Among the 11 high‐pressure mineral phases identified in the Suizhou veins, three are new high‐pressure minerals, namely, tuite after whitlockite, xieite, and the CF phase after chromite. On the basis of transformation of plagioclase into maskelynite, it is estimated that the Suizhou meteorite experienced shock pressures and shock temperatures up to 22 GPa and 1000 °C, respectively. Shearing and friction along shock veins raised the temperature up to 1900–2000 °C and the pressure up to 24 GPa within the veins. Hence, phase transition and crystallization of high‐pressure minerals took place only in the Suizhou shock veins. Fast cooling of the extremely thin shock veins is regarded as the main reason that up to 11 shock‐induced high‐pressure mineral phases could be preserved in these veins.     

High‐pressure polymorphs in Yamato‐790729 L6 chondrite and their significance for collisional conditions

Shock pressure recorded in Yamato (Y)‐790729, classified as L6 type ordinary chondrite, was evaluated based on high‐pressure polymorph assemblages and cathodoluminescence (CL) spectra of maskelynite. The host‐rock of Y‐790729 consists mainly of olivine, low‐Ca pyroxene, plagioclase, metallic Fe‐Ni, and iron‐sulfide with minor amounts of phosphate and chromite. A shock‐melt vein was observed in the hostrock. Ringwoodite, majorite, akimotoite, lingunite, tuite, and xieite occurred in and around the shock‐melt vein. The shock pressure in the shock‐melt vein is about 14–23 GPa based on the phase equilibrium diagrams of high‐pressure polymorphs. Some plagioclase portions in the host‐rock occurred as maskelynite. Sixteen different CL spectra of maskelynite portions were deconvolved using three assigned emission components (centered at 2.95, 3.26, and 3.88 eV). The intensity of emission component at 2.95 eV was selected as a calibrated barometer to estimate shock pressure, and the results indicate pressures of about 11–19 GPa. The difference in pressure between the shock‐melt vein and host‐rock might suggest heterogeneous shock conditions. Assuming an average shock pressure of 18 GPa, the impact velocity of the parent‐body of Y‐790729 is calculated to be ~1.90 km s^?1. The parent‐body would be at least ~10 km in size based on the incoherent formation mechanism of ringwoodite in Y‐790729.     

Shock experiments with the H6 chondrite Kernouvé: Pressure calibration of microscopic shock effects

Abstract— Shock‐recovery experiments were carried out on samples of the H6 chondrite Kernouvé at shock pressures of 10, 15, 20, 25, 30, 35, 45, and 60 GPa and preheating temperatures of 293 K (low‐temperature experiments) and 920 K (high‐temperature experiments). Using a calculated equation of state of Kernouvé, pressure‐pulse durations of 0.3 to 1.2 μs were estimated. The shocked samples were investigated by optical microscopy to calibrate the various shock effects in olivine, orthopyroxene, oligoclase, and troilite. The following pressure calibration is proposed for silicates: (1) undulatory extinction of olivine <GPa; (2) weak mosaicism of olivine from 10–15 GPa to 20–25 GPa; (3) onset of strong mosaicism of olivine at 20–25 GPa; (4) transformation of oligoclase to diaplectic glass completed at 25–30 GPa (low‐temperature experiments) and at 20–25 GPa (high‐temperature experiments); (5) onset of weak mosaicism in orthopyroxene at 30–35 GPa (low‐temperature experiments) and at 25–30 GPa (high‐temperature experiments); and (6) recrystallization or melting of olivine starting at 45–60 GPa (low‐temperature experiments) and at 35–45 GPa (high‐temperature experiments), and completed above 45–60 GPa in the high‐temperature experiments. Troilite displays distinct differences between the samples shocked at low and high temperatures. In the low‐temperature experiments, the following effects can be observed in troilite: (1) undulatory extinction up to 25 GPa, (2) twinning up to 45 GPa, (3) partial recrystallization from 30 to 60 GPa, and (4) complete recrystallization >35 GPa; whereas in the high‐temperature experiments, troilite shows (1) complete recrystallization from 10 up to 45 GPa and (2) melting and crystallization above 45 GPa. Localized shock‐induced melting is observed in samples shocked to pressures >15 GPa in the high‐temperature experiments and >30 GPa for the low‐temperature experiments in the form of FeNi metal and troilite melt injections and intergrowths and as pockets and veins of whole‐rock melt. Obviously, the onset and abundance of shock‐induced localized melting strongly depends on the initial temperature of the sample.     

Effect of moderate shock waves on magnetic susceptibility and microstructure of a magnetite‐bearing ore

This study demonstrates a relationship between changes of magnetic susceptibility and microstructure developing in minerals of a magnetite‐bearing ore, experimentally shocked to pressures of 5, 10, 20, and 30 GPa. Shock‐induced effects on magnetic properties were quantified by bulk magnetic susceptibility measurements while shock‐induced microstructures were studied by high‐resolution scanning electron microscopy. Microstructural changes were compared between magnetite, quartz, amphibole, and biotite grains. In the 5 GPa sample, a sharp drop of magnetic susceptibility correlates with distinct fragmentation as well as with formation of shear bands and twins in magnetite. At 10 GPa, shear bands and twins in magnetite are accompanied by droplet‐shaped nanograins. In this shock pressure regime, quartz and amphibole still show intensive grain fragmentation. Twins in quartz and foam‐shaped, highly porous amphibole are formed at 20 and 30 GPa. The formation of porous minerals suggests that shock heating of these mineral grains resulted in localized temperature spikes. The identified shock‐induced features in magnetite strongly advise that variations in the bulk magnetic susceptibility result from cooperative grain fragmentation, plastic deformation and/or localized amorphization, and probably postshock annealing. In particular, the increasing shock heating at high pressures is assumed to be responsible for a partial defect annealing which we suggest to be responsible for the almost constant values of magnetic susceptibility above 10 GPa.     

Laser‐induced melting experiments: Simulation of short‐term high‐temperature impact processes

This study introduces an experimental approach using direct laser irradiation to simulate the virtually instantaneous melting of target rocks during meteorite impacts. We aim at investigating the melting and mixing processes of projectile (iron meteorite; steel) and target material (sandstone) under idealized conditions. The laser experiments (LE) were able to produce features very similar to those of impactites from meteorite craters and cratering experiments, i.e., formation of lechatelierite, partial to complete melting of sandstone, and injection of projectile droplets into target melts. The target and projectile melts have experienced significant chemical modifications during interaction of these coexisting melts. Emulsion textures, observed within projectile‐contaminated target melts, indicate phase separation of silicate melts with different chemical compositions during quenching. Reaction times of 0.6 to 1.4 s could be derived for element partitioning and phase‐separation processes by measuring time‐depended temperature profiles with a bolometric detector. Our LE allow (i) separate melting at high temperatures to constrain primary melt heterogeneities before mixing of projectile and target, (ii) quantification of element partitioning processes between coexisting projectile and target melts, (iii) determination of cooling rates, and (iv) estimation of reaction times. Moreover, we used a thermodynamic approach to calculate the entropy gain during laser melting. The entropy changes for laser‐melting of sandstone and iron meteorite correspond to shock pressures and particle velocities produced during the impact of an iron projectile striking a quartz target at a minimum impact velocity of ~6 km s^?1, inducing peak shock pressures of ~100 GPa in the target.     

Revising the shock classification of meteorites

The current shock classification scheme of meteorites assigns shock levels of S1 (unshocked) to S6 (very strongly shocked) using shock effects in rock‐forming minerals such as olivine and plagioclase. The S6 stage (55–90 GPa; 850–1750 °C) relies solely on localized effects in or near melt zones, the recrystallization of olivine, or the presence of mafic high‐pressure phases such as ringwoodite. However, high whole rock temperatures and the presence of high‐pressure phases that are unstable at those temperatures and pressures of zero GPa (e.g., ringwoodite) are two criteria that exclude each other. Each type of high‐pressure phase provides a minimum shock pressure during elevated pressure conditions to allow the formation of this phase, and a maximum temperature of the whole rock after decompression to allow the preservation of this phase. Rocks classified as S6 are characterized not by the presence but by the absence of those thermally unstable high‐pressure phases. High‐pressure phases in or attached to shock melt zones form mainly during shock pressure decline. This is because shocked rocks (<60 GPa) experience a shock wave with a broad isobaric pressure plateau only during low velocity (<4.5 km s^?1) impacts, which rarely occur on small planetary bodies; e.g., the Moon and asteroids. The mineralogy of shock melt zones provides information on the shape and temporal duration of the shock wave but no information on the general maximum shock pressure in the whole rock.     

High‐pressure minerals in shocked meteorites

Heavily shocked meteorites contain various types of high‐pressure polymorphs of major minerals (olivine, pyroxene, feldspar, and quartz) and accessory minerals (chromite and Ca phosphate). These high‐pressure minerals are micron to submicron sized and occur within and in the vicinity of shock‐induced melt veins and melt pockets in chondrites and lunar, howardite–eucrite–diogenite (HED), and Martian meteorites. Their occurrence suggests two types of formation mechanisms (1) solid‐state high‐pressure transformation of the host‐rock minerals into monomineralic polycrystalline aggregates, and (2) crystallization of chondritic or monomineralic melts under high pressure. Based on experimentally determined phase relations, their formation pressures are limited to the pressure range up to ~25 GPa. Textural, crystallographic, and chemical characteristics of high‐pressure minerals provide clues about the impact events of meteorite parent bodies, including their size and mutual collision velocities and about the mineralogy of deep planetary interiors. The aim of this article is to review and summarize the findings on natural high‐pressure minerals in shocked meteorites that have been reported over the past 50 years.