Determination of the equilibrium fO2 in bulk samples of H,L, and LL ordinary chondrites by solid‐state electrochemistry

High‐temperature solid‐state electrochemistry techniques (EMF method) were used to measure the oxygen fugacity (fO₂) of the ordinary chondrites Ochansk (H4), Savtschenskoje (LL4), Elenovka (L5), Vengerovo (H5), and Kharkov (L6). The fO₂ results are presented in the form of the following equations: It was found that fO₂ regularly increases from H chondrites to LL chondrites. Measured fO₂ are ~1.5 higher than those previously calculated from mineral assemblages. Kharkov (L6) is a little more oxidized than Elenovka (L5) in agreement with the progressive oxidation model. At the same time, Ochansk (H4) is more oxidized than Vengerovo (H5) and exhibits a slightly different slope compared to other chondrites and at T > 1200 K, becomes more reduced than Kharkov (L6) or Elenovka (L5). Measured oxygen fugacity values of meteorites fall within (0.1–1.0)·log fO₂ of one another. The possible explanation of discrepancies between measured and calculated values is discussed.     

Saqqar: A 34 km diameter impact structure in Saudi Arabia

Here we present the first proof of an impact origin for the Saqqar circular structure in northwestern Saudi Arabia (Neville et al. 2014 ), with an apparent diameter of 34 km, centered at 29°35′N, 38°42′E. The structure is formed in Cambrian–Devonian siliciclastics and is unconformably overlain by undeformed Cretaceous and Paleogene sediments. The age of impact is not well constrained and lies somewhere between 410 and 70 Ma. The subsurface structure is constrained by 2‐D reflection seismic profiles and six drilled wells. First‐order structural features are a central uplift that rises approximately 2 km above regional datums, surrounded by a ring syncline. The crater rim is defined by circumferential normal faults. The central uplift and ring syncline correspond to a Bouguer gravity high and an annular ring‐like low, respectively. The wells were drilled within the central uplift, the deepest among them exceed 2 km depth. Sandstone core samples from these wells show abundant indicators of a shock metamorphic overprint. Planar deformation features (PDFs) were measured with orientations along (0001), {103}, and less frequently along {101} and {104}. Planar fractures (PFs) predominantly occur along (0001) and {101}, and are locally associated with feather features (FFs). In addition, some shocked feldspar grains and strongly deformed mica flakes were found. The recorded shock pressure ranges between 5 and 15 GPa. The preserved level of shock and the absence of an allochthonous crater fill suggest that Saqqar was eroded by 1–2 km between the Devonian and Maastrichtian. The documentation of unequivocal shock features proves the formation of the Saqqar structure by a hypervelocity impact event.     

Basaltic volcanism on the angrite parent body: Comparison with 4 Vesta

Carbon and nitrogen data from stepped combustion analysis of eight angrites, seven eucrites, and two diogenites, alongside literature data from a further nine eucrites and two diogenites, have been used to assess carbon and nitrogen incorporation and isotope fractionation processes on the angrite parent body (APB), for comparison with volatile behavior on the HED parent body (4 Vesta). A subset of the angrite data has been reported previously (Abernethy et al. 2013 ). Two separate families of volatile components were observed. They were (1) moderately volatile material (MVM), mostly combusting between ~500 and 750 °C and indistinguishable from terrestrial contamination and (2) refractory material (RM), mainly released above 750 °C and thought to be carbon (as ) and nitrogen (as N₂ or ) dissolved within the silicate lattice, fitting with the slightly oxidized (~IW to IW+2) angrite fO₂ conditions. Isotopic fractionation trends for carbon and nitrogen within the plutonic and basaltic (quenched) angrites suggest that the behavior of the two volatile elements is loosely coupled, but that the fractionation process differs between the two angrite subgroups. Comparison with results from eucrites and diogenites implies similarities between speciation of carbon and nitrogen on 4 Vesta and the APB, with the latter being more enriched in volatiles than the former.     

A new calibration to determine the closure temperatures of Fe‐Mg ordering in augite from nakhlites

Recently it has been shown that the relatively low closure temperature (T_c) of 500 (100)°C calculated for augite from Miller Range nakhlite (MIL 03346,13) using the available geothermometers would correspond to a slow cooling rate inconsistent with the petrologic evidence for an origin from a fast‐cooled lava flow. Moreover, previous annealing experiments combined with HR‐SC‐XRD on an augite crystal from MIL 03346 clearly showed that at 600 °C, the Fe²⁺‐Mg degree of order remained unchanged, thus suggesting that the actual T_c is close to this temperature. In order to clarify this discrepancy, we undertook an ex situ annealing experimental study at 700, 800, and 900 °C, until the equilibrium in the intracrystalline Fe²⁺‐Mg exchange is reached, using an augite crystal from Miller Range nakhlite (MIL 03346,13) with a composition of about En₃₆Fs₂₄Wo₄₀. These data allowed us to calculate the following new geothermometer calibration for Martian nakhlites: where The application of this new equation to other Martian nakhlites (NWA 988 and Nakhla) suggests that for augite with composition close to that of MIL 03346, the T_c is up to 170 °C higher with respect to the one calculated using the previous available geothermometer equation, thus suggesting a significantly faster cooling in agreement with petrologic evidence.     

Chondrule formation during low-speed collisions of planetesimals: A hybrid splash–flyby framework

Chondrules probably formed during a small window of time ~1–4 Ma after CAIs, when most solid matter in the asteroid belt was already in the form of km-sized planetesimals. They are unlikely, therefore, to be “building blocks” of planets or abundant on asteroids, but more likely to be a product of energetic events common in the asteroid belt at that epoch. Laboratory experiments indicate that they could have formed when solids of primitive composition were heated to temperatures of ~1600 K and then cooled for minutes to hours. A plausible heat source for this is magma, which is likely to have been abundant in the asteroid belt at that time, and only that time, due to the trapping of ²⁶Al decay energy in planetesimal interiors. Here, we propose that chondrules formed during low-speed ( $\lesssim 1\mathrm{km}{\mathrm{s}}^{-1}$) collisions between large planetesimals when heat from their interiors was released into a stream of primitive debris from their surfaces. Heating would have been essentially instantaneous and cooling would have been on the dynamical time scale, $1/\sqrt{\left(\mathit{G\rho }\right)}$ ~30 min, where $\rho$ is the mean density of a planetesimal. Many of the heated fragments would have remained gravitationally bound to the merged object and could have suffered additional heating events as they orbited and ultimately accreted to its surface. This is a hybrid of the splash and flyby models: We propose that it was the energy released from a body's molten interior, not its mass, that was responsible for chondrule formation by heating primitive debris that emerged from the collision.     

WIP: A Web‐based program for indexing planar features in quartz grains and its usage

Planar deformation features (PDFs) in quartz are the most important diagnostic features that allow the unambiguous identification of impact structures on Earth. In order to confirm that these features (that are characterized by planar character and form along specific crystallographic planes) are indeed PDFs, they need to be properly investigated and indexed. Following universal‐stage measurements, the process of indexing is usually performed manually, using a Wulff stereonet and following a strict procedure, which is time consuming and error prone. In this article, we present WIP, a new Web‐based program for indexing planar deformation features in quartz. The correctness of our program is shown by its application to measurements that had previously been indexed manually. The observed minor differences, especially in the absolute frequency percentage of PDFs, are negligible and not significant enough to influence the estimation of shock pressure that could be calculated from the indexed results. Usability of this program is shown using the spatial relationships between a statistically significant number of 278 quartz grains with 409 sets of PDFs analyzed within the area (~35 mm²) of a single thin section of a meta‐greywacke from the Bosumtwi impact structure. Our program is not only more accurate and faster than the manual (graphical) method but also removes the human error from the plotting process and allows control of several parameters, such as the value of estimated measurement error used in the indexing calculation or method of aggregated error handling. The program also provides information about the angles between the planes of the measured PDF sets present in a grain, which allows determination of the angles between (for example) indexed {} and {} sets.     

Crystallization temperature determination of Itokawa particles by plagioclase thermometry with X‐ray diffraction data obtained by a high‐resolution synchrotron Gandolfi camera

The crystallization temperatures of Itokawa surface particles recovered by the space probe Hayabusa were estimated by a plagioclase geothermometer using sodic plagioclase triclinicity. The Δ131‐index required for the thermometer, which is the difference in X‐ray diffraction peak positions between the 131 and 11 reflections of plagioclase, was obtained by a high‐resolution synchrotron Gandolfi camera developed for the third generation synchrotron radiation beamline, BL15XU at SPring‐8. Crystallization temperatures were successfully determined from the Δ131‐indices for four particles. The observed plagioclase crystallization temperatures were in a range from 655 to 660 °C. The temperatures indicate crystallization temperatures of plagioclases in the process of prograde metamorphism before the peak metamorphic stage.     

Experimental simulation of oxygen isotopic exchange in olivine and implication for the formation of metamorphosed carbonaceous chondrites

We have conducted hydration–dehydration experiments on terrestrial olivine to investigate the behavior of oxygen isotopic fractionation to test the hypothesis that multiple cycles of aqueous and thermal processing on a parent asteroid comprise a genetic relationship between CM2s and metamorphosed carbonaceous chondrites (MCCs). Two experiments were undertaken. In the first experiment, serpentine was obtained by hydrating terrestrial olivine (Fo_90.9) in the laboratory. During this experiment, olivine was reacted with isotopically heavy water (δ¹⁸O 21.5‰) at T = 300 °C,  = 300 bar, for 100 days. The oxygen isotopic composition of the experimental serpentine was enriched in ¹⁸O (by 10 ‰ in δ¹⁸O) due to exchange of oxygen isotopes between olivine and the ¹⁸O‐rich water. Dehydrated serpentine was then produced during laboratory heating experiment in vacuum, at T = 930 °C, for 1 h. The oxygen isotopic composition of the dehydrated serpentine was enriched in ¹⁸O by a further 7 ‰. The net result of the hydration–dehydration process was an enrichment of ¹⁸O in the final material by approximately 17‰. The new experimental results suggest that the oxygen isotopic compositions of MCCs of the Belgica‐like group, including Dhofar 225 and Dhofar 725, could be derived from those of typical CM2 chondrites via several cycles of hydration–dehydration caused by aqueous alteration and subsequent thermal metamorphism within their parent asteroids.     

Hydrogen and major element concentrations on 433 Eros: Evidence for an L‐ or LL‐chondrite‐like surface composition

A reanalysis of NEAR X‐ray/gamma‐ray spectrometer (XGRS) data provides robust evidence that the elemental composition of the near‐Earth asteroid 433 Eros is consistent with the L and LL ordinary chondrites. These results facilitated the use of the gamma‐ray measurements to produce the first in situ measurement of hydrogen concentrations on an asteroid. The measured value,  ppm, is consistent with hydrogen concentrations measured in L and LL chondrite meteorite falls. Gamma‐ray derived abundances of hydrogen and potassium show no evidence for depletion of volatiles relative to ordinary chondrites, suggesting that the sulfur depletion observed in X‐ray data is a surficial effect, consistent with a space‐weathering origin. The newfound agreement between the X‐ray, gamma‐ray, and spectral data suggests that the NEAR landing site, a ponded regolith deposit, has an elemental composition that is indistinguishable from the mean surface. This observation argues against a pond formation process that segregates metals from silicates, and instead suggests that the differences observed in reflectance spectra between the ponds and bulk Eros are due to grain size differences resulting from granular sorting of ponded material.     

The age of Wolfe Creek meteorite crater (Kandimalal), Western Australia

Wolfe Creek crater lies in northwestern Australia at the edge of the Great Sandy Desert. Together with Meteor Crater, it is one of the two largest craters on Earth from which meteorite fragments have been recovered. The age of the impact is poorly constrained and unpublished data places the event at about 300,000 years ago. In comparison, Meteor Crater is well constrained by exposure dating. In this paper, we present new ages for Wolfe Creek Crater from exposure dating using the cosmogenic nuclides ¹⁰Be and ²⁶Al, together with optically stimulated luminescence ages (OSL) on sand from a site created by the impact. We also present a new topographic survey of the crater using photogrammetry. The exposure ages range from ~86 to 128 ka. The OSL ages indicate that the age of the impact is most likely to be ~120 ka with a maximum age of 137 ka. Considering the geomorphic setting, the most likely age of the crater is 120 ± 9 ka. Last, we review the age of Meteor Crater in Arizona. Changes in production rates and scaling factors since the original dating work revise the impact age to 61.1 ± 4.8 ka, or ~20% older than previously reported.     

A short review of the pulsar magnetic inclination angles (II)

The pulsar magnetic inclination angle is a key parameter for pulsar physics. It influences the observable properties of pulsars, such as the pulse beam width, braking index, polarization, and emission geometry. In this study, we give a brief overview of the current state of knowledge and research on this parameter and its implications for the internal physics of pulsars. We use the observed pulsar data of magnetic inclination angle and braking index to constrain the star's number of precession cycles, $\xi$, which reflects the interaction between superfluid neutrons and other particles inside a neutron star (NS). We apply the method proposed by Cheng et al. (Cheng, Q., Zhang, S. N., Zheng, X. P., & Fan, X. L., 2019, Phys. Rev. D, 99, 083011) to analyze the data of PSR J2013 + 3845 and obtain the constraints for $\xi$ ranging from $2.393\times 10^5$ to $1.268\times 10^6$. And further analysis suggests that the internal magnetic field structure of PSR J2013 + 3845 is likely dominated by toroidal components. This study may help us understand the process of internal viscous dissipation and the related evolution of the inclination angles of pulsars, and may have important implications for the study of continuous gravitational wave emissions from NS.     

Depositional processes of impactites from the YAX-1 drill core in the Chicxulub impact structure inferred from vertical profiles of PDF orientations and grain size distributions of shocked quartz

Core samples from the Chicxulub impact structure provide insights into the formation processes of a shallow-marine-target, complex crater. Although previous studies investigated the impactites (generally suevitic and polymict breccias) of the Yaxcopoil-1 (YAX-1) drill core in the Chicxulub impact structure, the interpretation of its deposition remains controversial. Here, we analyze planar deformation features (PDFs), grain size, and abundance of shocked quartz throughout the YAX-1 impactite sequence (794–895 m in depth). PDF orientations of most quartz grains in YAX-1 impactites show a distribution of both low angles ({104}, {103}, {102}) and high angles (orientations higher than 55° to c-axis), while the lower part of the impactite sequence contains quartz showing only PDF orientations of low angles. High-abundance, coarse-grained shocked quartz is found from the lower to middle parts of the impactites, whereas it abruptly changes to low-abundance, fine-grained shocked quartz within the upper part. In the uppermost part of the impactites, repeated oscillations in contents of these two components are observed. PDF orientation pattern suggests most of the shocked quartz grains experienced a range of shock pressure, except two samples in the lower part of impactites, which experienced only a high level of shock. We suggest that the base and lower part of the impactite sequence were formed by ejecta curtain and melt surge deposits, respectively. Our results are also consistent with the interpretation that the middle part of the impactite sequence is fallback ejecta from the impact plume. Additionally, we support the contention that massive seawater resurges into the crater occurred during the deposition of the upper and uppermost part of the impactites.     

Long-term stability of planetary orbits between Jupiter and Saturn

We extend our two previous studies on the existence of stable orbits in the Solar System by examining the domain between Jupiter and Saturn. We place (1) a massless object, (2) a Moon-mass object, (3) a Mars-mass object, (4) an Earth-mass object, and (5) a Uranus-mass object in the said region. Note that these objects are considered separately in the framework of our simulations. Our goal is to explore the orbital stability of those objects. We employ the Lie-integration method, which is fast and well established, allowing us to solve the respective differential equations for the $N$-body system. Hence, we consider the celestial bodies spanning from Jupiter to Neptune, including the aforementioned test object, the main focus for our model simulations. The integrations indicate that in some models the test objects placed in the region between Jupiter and Saturn reside in that region for more than 600 Myr. Between 5 and 10 au, mean-motion resonances (MMRs) take place acting upon the test objects akin to simulations of Paper I and II. Our models indicate relatively small differences for the long-term stability of the five test objects notwithstanding their vastly different masses. Generally, it is found that between $a_{\text{ini}}=7.04$ and 7.13 au the orbits become unstable mostly within 5 million years and further out, that is, up to $a_{\text{ini}}=7.29$ au, the duration of stability lengthens to up to hundreds of millions of years.     

Bidirectional reflectance distribution function measurements of the Winchcombe meteorite using the Visible Oxford Space Environment Goniometer

A laboratory study was performed using the Visible Oxford Space Environment Goniometer in which the broadband (350–1250 nm) bidirectional reflectance distribution function (BRDF) of the Winchcombe meteorite was measured, across a range of viewing angles—reflectance: 0°–70°, in steps of 5°; incidence: 15°, 30°, 45°, and 60°; and azimuthal: 0°, 90°, and 180°. The BRDF dataset was fitted using the Hapke BRDF model to (1) provide a method of comparison to other meteorites and asteroids, and (2) to produce Hapke parameter values that can be used to extrapolate the BRDF to all angles. The study deduced the following Hapke parameters for Winchcombe: w = 0.152 ± 0.030, b = 0.633 ± 0.064, and h_S = 0.016 ± 0.008, demonstrating that it has a similar w value to Tagish Lake (0.157 ± 0.020) and a similar b value to Orgueil (0.671 ± 0.090). Importantly, the surface profile of the sample was characterized using an Alicona 3D® instrument, allowing two of the free parameters within the Hapke model φ and $\overline{\theta }$, which represent porosity and surface roughness, respectively, to be constrained as φ = 0.649 ± 0.023 and $\overline{\theta }$ = 16.113° (at 500 μm size scale). This work serves as part of the characterization process for Winchcombe and provides a reference photometry dataset for current and future asteroid missions.     

Mg and Si isotopic fractionation patterns in types B1 and B2 CAIs: Implications for formation under different nebular conditions

Magnesium and silicon isotopic profiles across melilite grains in two type B1 and two type B2 calcium‐aluminum‐rich inclusions (CAIs) reveal differing but constant enrichments in heavy isotopes everywhere except ≤1000 μm from the CAI margins. There is no close correlation in the B1s or the B2s between isotopic composition and åkermanite content of the melilite, a measure of progressive igneous crystallization, yet such a correlation might be expected in a type B2: without a melilite mantle (as in B1s) to seal the interior off and prevent further evaporation, the melt would have maintained communication with the external gas. These observations indicate a model in which B1s and B2s solidified under differing conditions. The B2s solidified under lower hydrogen pressures ( ≤ 10^?4 – 10^?5 bars) than did B1s ( > 10^?4 bars), so surface volatilization was slower in the B2s and internal chemical and isotopic equilibrium was maintained over the interval of melilite crystallization. The outermost zones of the CAIs (≤1000 μm from the edge) are not consistently enriched in heavy isotopes relative to the interiors, as might be expected from diffusion‐limited surface evaporation of the melt. In all cases, the magnesium in the CAI margins is lighter than in the interiors. In one case, silicon in the margin also is lighter, but locally in some CAIs, it is isotopically heavier near the surface. If melt evaporation played a role in the formation of these outer zones, a later event in many cases caused isotopic re‐equilibration with an external and isotopically near‐normal reservoir.     

Petrographic investigation of shatter cone melt films recovered from MEMIN impact experiments in sandstone and iSALE modeling of their formation boundary conditions

Shatter cones are diagnostic for the recognition of meteorite impact craters. They are unambiguously identifiable in the field and the only macroscopic shock deformation feature. However, the physical boundary conditions and exact formation mechanism(s) are still a subject of debate. Melt films found on shatter cone surfaces may allow the constraint of pressure–temperature conditions during or immediately after their formation. Within the framework of the MEMIN research group, we recovered 24 shatter cone fragments from the ejecta of hypervelocity impact experiments. Here, we focus on silicate melt films (now quenched to glass) found on shatter cone surfaces formed in experiments with 20–80 cm sized sandstone targets, impacted by aluminum and iron meteorite projectiles of 5 and 12 mm diameter at velocities of 7.0 and 4.6 km s⁻¹, respectively. The recovered shatter cone fragments vary in size from 1.2 to 9.3 mm. They show slightly curved, striated surfaces, and conical geometries with apical angles of 36°–52°. The fragments were recovered from experiments with peak pressures ranging from 46 to 86 GPa, and emanated from a zone within 0.38 crater radii. Based on iSale modeling and petrographic investigations, the shatter coned material experienced low bulk shock pressures of 0.5–5 GPa, whereas deformation shows a steep increase toward the shatter cone surface leading to localized melting of the rock, resulting in both vesicular as well as polished melt textures visible under the SEM. Subjacent to the melt films are zones of fragmentation and brittle shear, indicating movement away from the shatter cone apex of the rock that surrounds the cone. Smearing and extension of the melt film indicates subsequent movement in opposite direction to the comminuted and brecciated shear zone. We believe the documented shear textures and the adjacent smooth melt films can be related to frictional melting, whereas the overlying highly vesiculated melt layer could indicate rapid pressure release. From the observation of melting and mixing of quartz, phyllosilicates, and rutile in this overlying texture, we infer high, but very localized postshock temperatures exceeding 2000 °C. The melted upper part of the shatter cone surface cross-cuts the fragmented lower section, and is accompanied by PDFs developed in quartz parallel to the {112} plane. Based on the overprinting textures and documented shock effects, we hypothesize shatter cones start to form during shock loading and remain an active fracture surface until pressure release during unloading and infer that shatter cone surfaces are mixed mode I/II fracture surfaces.     

The Erbisberg drilling 2011: Implications for the structure and postimpact evolution of the inner ring of the Ries impact crater

The 26 km diameter Nördlinger Ries is a complex impact structure with a ring structure that resembles a peak ring. A first research drilling through this “inner crystalline ring” of the Ries was performed at the Erbisberg hill (SW Ries) to better understand the internal structure and lithology of this feature, and possibly reveal impact‐induced hydrothermal alteration. The drill core intersected the slope of a 22 m thick postimpact travertine mound, before entering 42 m of blocks and breccias of crystalline rocks excavated from the Variscan basement at >500 m depth. Weakly shocked gneiss blocks that show that shock pressure did not exceed 5 GPa occur above polymict lithic breccias of shock stage Ia (10–20 GPa), with planar fractures and planar deformation features (PDFs) in quartz. Only a narrow zone at 49.20–50.00 m core depth exhibits strong mosaicism in feldspar and {102} PDFs in quartz, which are indicative of shock stage Ib (20–35 GPa). Finally, 2 m of brecciated Keuper sediments at the base of the section point to an inverse layering of strata. While reverse grading of clast sizes in lithic breccias and gneiss blocks is consistent with lateral transport, the absence of diaplectic glass and melt products argues against dynamic overthrusting of material from a collapsing central peak, as seen in the much larger Chicxulub structure. Indeed, weakly shocked gneiss blocks are rather of local provenance (i.e., the transient crater wall), whereas moderately shocked polymict lithic breccias with geochemical composition and ⁸⁷Sr/⁸⁶Sr signature similar to Ries suevite were derived from a position closer to the impact center. Thus, the inner ring of the Ries is formed by moderately shocked polymict lithic breccias likely injected into the transient crater wall during the excavation stage and weakly shocked gneiss blocks of the collapsing transient crater wall that were emplaced during the modification stage. While the presence of an overturned flap is not evident from the Erbisberg drilling, a survey of all drillings at or near the inner ring point to inverted strata throughout its outer limb. Whether the central ring of the Ries represents remains of a collapsed central peak remains to be shown. Postimpact hydrothermal alteration along the Erbisberg section comprises chloritization, sulfide veinlets, and strong carbonatization. In addition, a narrow zone in the lower parts of the polymict lithic breccia sequence shows a positive Eu anomaly in its carbonate phase. The surface expression of this hydrothermal activity, i.e., the travertine mound, comprises subaerial as well as subaquatic growth phases. Intercalated lake sediments equivalent to the early parts of the evolution of the central crater basin succession confirm a persistent impact‐generated hydrothermal activity, although for less time than previously suggested.     

Improving the descendant relationship of cluster galaxies at z < 1

In this work, we study how to improve well-known techniques for detecting progenitors/descendants of galaxies, such as the NDpredict program, when applied to galaxies in clusters. The improvement of this particular method is based on the use of the red sequence of galaxies in those environments. Objects close to the red sequence in the color and magnitude diagram are more likely to belong to the cluster. This defines a probability scale which is then combined with the one generated by NDpredict. This procedure is optimized for the study of galaxies in clusters over different epochs. Our main result is that, for a sample composed of $120$ clusters, with masses greater than ${10}^{13.25}{M}_{\odot }$, selected from the IllustrisTNG simulations (namely, the TNG100 runs). In $99\%$ of the cases (i.e., $119$ systems), we obtain better performance with the red sequence method in comparison to the original NDpredict, and the average gain obtained is $28\%$ in the identification of descendants for this sample of cluster galaxies.     

Presolar grains in primitive ungrouped carbonaceous chondrite Northwest Africa 5958

We report a correlated NanoSIMS‐transmission electron microscopy study of the ungrouped carbonaceous chondrite Northwest Africa (NWA) 5958. We identified 10 presolar SiC grains, 2 likely presolar graphite grains, and 20 presolar silicate and/or oxide grains in NWA 5958. We suggest a slight modification of the commonly used classification system for presolar oxides and silicates that better reflects the grains’ likely stellar origins. The matrix‐normalized presolar SiC abundance in NWA 5958 is ppm (2σ) similar to that seen in many classes of unmetamorphosed chondrites. In contrast, the matrix‐normalized abundance of presolar O‐rich phases (silicates and oxides) is ppm (2σ), much lower than seen in interplanetary dust particles and the least‐altered CR, CO, and ungrouped C chondrites, but close to that reported for CM chondrites. NanoSIMS mapping also revealed an unusual ¹³C‐enriched (δ¹³C≈100–200‰) carbonaceous rim surrounding a 1.4 μm diameter phyllosilicate grain. Transmission electron microscopy (TEM) analysis of two presolar grains with a likely origin in asymptotic giant branch stars identified one as enstatite and one as Al‐Mg spinel with minor Cr. The enstatite grain amorphized rapidly under the electron beam, suggesting partial hydration. TEM data of NWA 5958 matrix confirm that it has experienced aqueous alteration and support the suggestion of Jacquet et al. (34) that this meteorite has affinities to CM2 chondrites.