Valences of Ti,Cr, and V in Apollo 17 high-Ti and very low-Ti basalts and implications for their formation

To assess the variability of redox states among mare basalt source regions, investigation of the valence of Ti, Cr, and V and the coordination environment of Ti in pyroxene and olivine in lunar rocks via XANES (X-ray absorption near-edge structure) spectroscopy has been extended to Apollo 17 basalts: two high-Ti (70017 and 74275) hand samples, and three very low-Ti (70006,371, 70007,289B, and 70007,296) basalt fragments from the Apollo 17 deep drill core. Valences of Ti in pyroxene of both suites range from 3.6 to 4, or from 40% to 0% Ti³⁺, averaging 15–20% Ti³⁺. Assuming Ti³⁺ is more compatible in pyroxene than Ti⁴⁺, then even lower Ti³⁺ proportions are indicated for the parental melts. The VLT pyroxene exhibits a slightly wider range of V valences (2.57–2.96) than the high-Ti pyroxene (2.65–2.86) and a much wider range of Cr valences (2.32–2.80 versus 2.68–2.86); Cr is generally reduced in VLT pyroxene compared to high-Ti pyroxene. Valences of Ti and Cr in VLT pyroxene become less reduced with increasing FeO contents, possibly indicating change in oxygen fugacity during crystallization. Olivine in all samples has very low (<20%) proportions of Ti³⁺, with no Ti³⁺ and higher proportions of Ti in tetrahedral coordination in the VLTs than in the high-Ti basalts. Olivine in 74275, including that in a dunite clast, has much higher proportions of Cr²⁺ than the pyroxene in that sample, consistent with previous studies indicating that the olivine grains in this sample are xenocrysts and possibly indicating oxidation just prior to pyroxene crystallization. Results for this sample, the VLTs, and previously studied Apollo 14 and 15 basalts all indicate that mare magmas were in reducing environments at depth, as recorded in early crystallization products, and that later, presumably shallower environments, were relatively oxidizing; single, characteristic fO₂s of formation cannot be assigned to these samples. A process likely to account for this feature seen in multiple samples is loss by degassing of a reducing, H-rich vapor (probably H₂) during ascent and/or eruption, causing oxidation of the residual melt, recorded in relatively late-crystallized pyroxene.     

Investigating the crystallization history of Apollo 15 mare basalts using quantitative textural analysis

Mare basalts collected at the Apollo 15 landing site are classified as belonging to either the quartz-normative suite or the olivine-normative suite, based on differences in whole-rock major element chemistry. A wide range of textures are displayed within samples from both suites, which provide insight into eruption processes on the Moon. Here we use crystal size distribution (CSD) analysis and spatial distribution pattern (SDP) analysis of pyroxene, olivine, and plagioclase crystals in eight Apollo 15 mare basalt samples to investigate the crystallization and emplacement of the quartz-normative and olivine-normative suites. In general, our results show similarities between the CSDs and SDPs for both mare basalt suites. However, we also report two distinct groups of pyroxene CSD trends that likely represent samples with common cooling histories, originating from comparable depths within respective olivine-normative and quartz-normative lava flows. We use our results to determine the relative depths of samples within the lava flows at the Apollo 15 landing site.     

Infrared and Raman spectra of lunar samples from Apollo 11, 12 and 14

We report the room temperature infrared reflectance spectra of several lunar surface rocks in the form of polished slices or butt ends. The spectra were obtained over the frequency range 20-2000 cm^–1 throughout the mid and far infrared (5-500µ) region of the electromagnetic spectrum where the fundamental internal and lattice vibrational modes of all minerals and rocks occur.Some fines samples were examined as pressed pellets and their reflectivities compared with the bulk samples. Several terrestrial minerals and rocks were also investigated. Kramers-Kronig analyses of these reflectance spectra were undertaken and the dispersion of the dielectric response ( and ) and the optical constants (n andk) have been determined over this frequency range. The low frequency and high frequency (infrared) dielectric constants were also calculated from the reflectance data.Raman light scattering measurements were made on all the samples supplied from the first three Apollo missions. Large background scattering proved to be the greatest experimental problem. Successful spectra in nearly all cases were obtained from small crystalline inclusions imbedded in the main ground mass. Some crystalline bulk rocks containing many very fine inclusions gave identifiable spectra and at least three different types were obtained.Supported by NASA Grant NGR 22-011-069 and by a Northeastern University Grant for Basic Research.     

Interpretation of the Apollo 14 Thermal Degradation Sample experiment

The Thermal Degradation Sample (TDS) experiment was one of the many investigations performed on the lunar surface during Apollo 14. Remarkably, the results of this 40 year old experiment were never fully interpreted, perhaps in part because the hardware vanished after its return. Mission records, high resolution photographs returned from the mission, and recent laboratory investigations have been used to glean important results from this experiment. It is most likely that the dust adhesion to the TDS was less than anticipated because of atomic-level contamination of its surfaces. These contaminants were probably removed from most equipment surfaces on the Moon by sputter cleaning by the solar wind, but the TDS experiments were not exposed to the solar wind long enough to affect the cleaning.     

Major element and primary sulfur concentrations in Apollo 12 mare basalts: The view from melt inclusions

Abstract— Major element and sulfur concentrations have been determined in experimentally heated olivine‐hosted melt inclusions from a suite of Apollo 12 picritic basalts (samples 12009, 12075, 12020, 12018, 12040, 12035). These lunar basalts are likely to be genetically related by olivine accumulation (Walker et al. 1976a, b). Our results show that major element compositions of melt inclusions from samples 12009, 12075, and 12020 follow model crystallization trends from a parental liquid similar in composition to whole rock sample 12009, thereby partially confirming the olivine accumulation hypothesis. In contrast, the compositions of melt inclusions from samples 12018, 12040, and 12035 fall away from model crystallization trends, suggesting that these samples crystallized from melts compositionally distinct from the 12009 parent liquid and therefore may not be strictly cogenetic with other members of the Apollo 12 picritic basalt suite. Sulfur concentrations in melt inclusions hosted in early crystallized olivine (Fo₇₅) are consistent with a primary magmatic composition of 1050 ppm S, or about a factor of 2 greater than whole rock compositions with 400–600 ppm S. The Apollo 12 picritic basalt parental magma apparently experienced outgassing and loss of S during transport and eruption on the lunar surface. Even with the higher estimates of primary magmatic sulfur concentrations provided by the melt inclusions, the Apollo 12 picritic basalt magmas would have been undersaturated in sulfide in their mantle source regions and capable of transporting chalcophile elements from the lunar mantle to the surface. Therefore, the measured low concentration of chalcophile elements (e.g., Cu, Au, PGEs) in these lavas must be a primary feature of the lunar mantle and is not related to residual sulfide remaining in the mantle during melting. We estimate the sulfur concentration of the Apollo 12 mare basalt source regions to be ～75 ppm, which is significantly lower than that of the terrestrial mantle.     

Core 14220 and the lateral continuity of soils at Apollo 14 Station G

Three soil samples at Apollo 14 Station G could potentially be used for stratigraphic correlation. Recently dissected core 14220, and core 14230 are 4 m apart and form the east leg of a triangle with an apex 7m to the west that contains trench samples 14145, 14156 and 14149, from top to bottom. Core 14220 penetrated approximately as deeply as the trench and showed a similar lithologic succession. At the base of both sections is a basalt-rich soil, overlain by a series of units that contain distinctive clasts of light soil and pebble-sized glass fragments. Fine-grained dark soil rich in vesicular glass is at the surface in both sections. The succession of similar soil types suggests that the trench correlates with 14220; but poor sample recovery makes thickness comparisons uncertain. Core 14230 appears to closely correlate with the middle of core 14220. The second layer from the top of 14220 and the top of 14230 are fine-grained with an unusually high percentage of light-matrix breccia, and the next stratum down in both cores is coarser and rich in light annealed-matrix breccia. The principal lithologic types that do not match, successionally, from core to core, are zones rich in vesicular glass and soil breccia. Such rock types are of regolith origin and probably represent patchy and discontinuous deposits.     

Shock metamorphic history of >4 Ga Apollo 14 and 15 zircons

During impact events, zircons develop a wide range of shock metamorphic features that depend on the pressure and temperature conditions experienced by the zircon. These conditions vary with original distance from impact center and whether the zircon grains are incorporated into ejecta or remain within the target crust. We have employed the range of shock metamorphic features preserved in >4 Ga lunar zircons separated from Apollo 14 and 15 breccias and soils in order to gain insights into the impact shock histories of these areas of the Moon. We report microstructural characteristics of 31 zircons analyzed using electron beam methods including electron backscatter pattern (EBSP) and diffraction (EBSD). The major results of this survey are as follows. (1) The abundance of curviplanar features hosting secondary impact melt inclusions suggests that most of the zircons have experienced shock pressures between 3 and 20 GPa; (2) the scarcity of recrystallization or decomposition textures and the absence of the high‐pressure polymorph, reidite, suggests that few grains have been shocked to over 40 GPa or heated above 1000 °C in ejecta settings; (3) one grain exhibits narrow, arc‐shaped bands of twinned zircon, which map out as spherical shells, and represent a novel shock microstructure. Overall, most of the Apollo 14 and 15 zircons exhibit shock features similar to those of terrestrial zircon grains originating from continental crust below large (~200 km) impact craters (e.g., Vredefort impact basin), suggesting derivation from central uplifts or uplifted rims of large basins or craters on the Moon and not high‐temperature and ‐pressure ejecta deposits.     

Earliest high-Ti volcanism on the Moon: 40Ar-39Ar,Sm-Nd,and Rb-Sr isotopic studies of Group D basalts from the Apollo 11 landing site

Abstract High-Ti basalts from the Apollo collections span a range in age from 3.87 Ga to 3.55 Ga. The oldest of these are the common Apollo 11 Group B2 basalts which yield evidence of some of the earliest melting of the lunar mantle beneath Mare Tranquillitatis. Rare Group D high-Ti basalts from Mare Tranquillitatis have been studied in an attempt to confirm a postulated link with Group B2 basalts (Jerde et al., 1994). The initial Sr isotopic ratio of a known Group D basalt (0.69916 ± 3 at 3.85 Ga) lies at the lower end of the tight range for Group B2 basalts (⁸⁷Sr/⁸⁶Sr = 0.69920 to 0.69921). One known Group D basalt and a second postulated Group D basalt yield indistinguishable initial ?_Nd (1.2 ± 0.6 and 1.2 ± 0.3) and again lie at the lower end of the range for the Group B2 basalts from Apollo 11 (+2.0 ± 0.4 to +3.9 ± 0.6, at 3.85 Ga). A third sample has isotopic (⁸⁷Sr/⁸⁶Sr = 0.69932 ± 2; ?_Nd = 2.5 ± 0.4; at 3.59 Ga; as per Snyder et al., 1994b) and elemental characteristics similar to the Group A high-Ti basalts returned from the Apollo 11 landing site. Ages of ⁴⁰Ar-³⁹Ar have been determined for one known Group D basalt and a second postulated Group D basalt using step-heating with a continuous-wave laser. Suspected Group D basalt, 10002, 1006, yielded disturbed age spectra on two separate runs, which was probably due to ³⁹Ar recoil effects. Using the “reduced plateau age” method of Turner et al. (1978), the ages derived from this sample were 3898 ± 19 and 3894 ± 19 Ma. Three separate runs of known Group D basalt 10002, 116 yielded ⁴⁰Ar/³⁹Ar plateau ages of 3798 ± 9 Ma, 3781 ± 8 Ma, and 3805 ± 7 Ma (all errors 2σ). Furthermore, this sample has apparently suffered significant ⁴⁰Ar loss either due to solar heating or due to meteorite impact. The loss of a significant proportion of ⁴⁰Ar at such a time means that the plateau ages underestimate the “true” crystallization age of the sample. Modelling of this Ar loss yields older, “true” ages of 3837 ± 18, 3826 ± 16, and 3836 ± 14 Ma. These ages overlap the ages of Group B2 high-Ti basalts (weighted average age = 3850 ± 20 Ma; range in ages = 3.80 to 3.90 Ga). The combined evidence indicates that the Group D and B2 high-Ti basalts could be coeval and may be genetically related, possibly through increasing degrees of melting of a similar source region in the upper mantle of the Moon that formed >4.2 Ga ago. The Group D basalts were melted from the source first and contained 3–5×more trapped KREEP-like liquid than the later (by possibly only a few million years) Group B2 basalts. Furthermore, the relatively LREE- and Rb-enriched nature of these early magmas may lend credence to the idea that the decay of heat-producing elements enriched in the KREEP-like trapped liquid of upper mantle cumulates, such as K, U, and Th, could have initiated widespread lunar volcanism.     

Petrography and geochemistry of five new Apollo 16 mare basalts and evidence for post‐basin deposition of basaltic material at the site

Abstract— We present the petrography and geochemistry of five 2–4 mm basalt fragments from the Apollo 16 regolith. These fragments are 1) a high‐Ti vitrophyric basalt compositionally similar to Apollo 17 high‐Ti mare basalts, 2) a very high‐Ti vitrophyric basalt compositionally similar to Apollos 12 and 14 red‐black pyroclastic glass, 3) a coarsely crystalline high‐Al basalt compositionally similar to group 5 Apollo 14 high‐Al mare basalts, 4) a very low‐Ti (VLT) crystalline basalt compositionally similar to Luna 24 VLT basalts, and 5) a VLT basaltic glass fragment compositionally similar to Apollo 17 VLT basalts. High‐Ti basalt has been reported previously at the Apollo 16 site; the other basalt types have not been reported previously. As there are no known cryptomaria or pyroclastic deposits in the highlands near the Apollo 16 site (ruling out a local origin), and scant evidence for basaltic material in the Apollo 16 ancient regolith breccias or Apollo 16 soils collected near North Ray Crater (ruling out a basin ejecta origin), we infer that the basaltic material in the Apollo 16 regolith originated in maria near the Apollo 16 site and was transported laterally to the site by small‐ to medium‐sized post‐basin impacts. On the basis of TiO₂ concentrations derived from the Clementine UVVIS data, Mare Tranquillitatis (?300 km north) is the most likely source for the high‐Ti basaltic material at the Apollo 16 site (craters Ross, Arago, Dionysius, Maskelyne, Moltke, Sosigenes, Schmidt), Mare Nectaris/Sinus Asperitatis (?220 km east) is the most likely source for the low‐Ti and VLT basaltic material (craters Theophilus, Madler, Torricelli), and a large regional pyroclastic deposit near Mare Vaporum (?600 km northwest) is the most likely source region for pyroclastic material (although no source craters are apparent in the region).     

Stratigraphy,evolution, and volume of basalts in Mare Serenitatis

Abstract– Fourteen major basaltic units in Mare Serenitatis have been identified and mapped from differences in TiO₂ wt%. The ages of these units have been inferred from their crater densities and reference to isotopically dated Apollo samples. It has been found that FeO and TiO₂ wt% of the units do not show any apparent trend with time. However, the oldest units have much greater variation in FeO and TiO₂ wt% than younger ones. No lateral trend in the age of the basaltic units is apparent within the basin. A vertical profile of Mare Serenitatis has been produced based on the depth of basalt within impact craters. The minimum depth of basalt has been estimated where craters have not exposed underlying highland material. The profile has been used to estimate the minimum volume of basalt within the basin to be ≈500,000 km³.     

Theoretical meteor radiants of Apollo,Amor, and Aten asteroids

A compilation of theoretical meteor radiants is presented for all numbered (through 2525) asteroids which approach the Earth's orbit to within 0.20 AU. On the basis of orbital similarity, asteroids associated with current meteor streams and Prairie Network fireballs are listed; plausible associations with medieval fireball radiants are also given. The best defunct comet candidates in terms of meteoric evidence appear to be 2101 Adonis and 2201 1947XC. Asteroids which may be either extinct comets or perturbed main belt asteroids accompanied by collisional debris (represented by fireballs) are 1917 Cuyo, 2202 Pele, 2061 Anza, and 2340 Hathor. 1566 Icarus and 1981 Midas are the only asteroids whose orbits approach to less than 0.07 AU of the Earth's orbit, have a northern radiant, and still show no certain meteoric activity. The majority of Atens, Apollos, and Amors do not pass sufficiently close (<0.07 AU) to the Earth's orbit for a reasonable expectation of meteoric activity, or have radiants south of ?20° declination, requiring southern hemisphere observations.     

Geochemical diversity of shergottite basalts: Mixing and fractionation,and their relation to Mars surface basalts

The chemical compositions of shergottite meteorites, basaltic rocks from Mars, provide a broad view of the origins and differentiation of these Martian magmas. The shergottite basalts are subdivided based on their Al contents: high‐Al basalts (Al > 5% wt) are distinct from low‐Al basalts and olivine‐phyric basalts (both with Al < 4.5% wt). Abundance ratios of highly incompatible elements (e.g., Th, La) are comparable in all the shergottites. Abundances of less incompatible elements (e.g., Ti, Lu, Hf) in olivine‐phyric and low‐Al basalts correlate well with each other, but the element abundance ratios are not constant; this suggests mixing between components, both depleted and enriched. High‐Al shergottites deviate from these trends consistent with silicate mineral fractionation. The “depleted” component is similar to the Yamato‐980459 magma; approximately, 67% crystal fractionation of this magma would yield a melt with trace element abundances like QUE 94201. The “enriched” component is like the parent magma for NWA 1068; approximately, 30% crystal fractionation from it would yield a melt with trace element abundances like the Los Angeles shergottite. This component mixing is consistent with radiogenic isotope and oxygen fugacity data. These mixing relations are consistent with the compositions of many of the Gusev crater basalts analyzed on Mars by the Spirit rover (although with only a few elements to compare). Other Mars basalts fall off the mixing relations (e.g., Wishstone at Gusev, Gale crater rocks). Their compositions imply that basalt source areas in Mars include significant complexities that are not present in the source areas for the shergottite basalts.     

The nature and origin of Boulder 1, Station 2, Apollo 17

The Boulder 1 breccias are similar in composition to other Taurus-Littrow massif samples and therefore probably derived from the same source, undoubtedly the Serenitatis basin. However, they are substantially different in texture from other Apollo 17 massif rocks, indeed are very nearly unique among the rocks returned by all Apollo missions. The boulder is set apart by its content of dark, rounded inclusions or bombs, up to several tens of centimeters in dimension, consisting largely of very fine, angular, mineral debris, welded together by a lesser amount of extremely fine-grained material that appears to be devitrified glass. To account for these uncommon structures, a phase of the basinforming impact event is sought that would produce relatively small amounts of debris and deposit them on or near the basin rim. It is suggested that the components of the boulder might represent very early, high angle ejecta from the Serenitatis event, and that the dark breccia inclusions are accretional structures formed from a cloud of hot mineral debris, melt droplets, and vapor that was ejected at high angles from the impact point soon after penetration of the Serenitatis meteoroid. This small amount of early high-angle ejecta would have remained in ballistic trajectories while the main phase of crater excavation deposited much larger amounts of deeper-derived debris and melt-rock on the rim of the basin, after which the early ejecta was deposited as a cooler (～450°C) stratum on top. The matrix of this breccia gained its modest degree of coherency by thermal sintering as the capping stratum cooled. The boulder is a fragment of this layer, broken out and rolled to the foot of the South Massif ? 55 m.y. ago.     

Boulder 1, Station 2, Apollo 17: Petrology and petrogenesis

Boulder 1, Station 2, Apollo 17 is a stratified boulder containing dark clasts and dark-rimmed light clasts set in a light-gray friable matrix. The gray to black clasts (GCBx and BCBx) are multigenerational, competent, high-grade metamorphic, and partially melted breccias. They contain a diverse suite of lithic clasts which are mainly ANT varieties, but include granites, basaltic-textured olivine basalts, troctolitic and spinel troctolitic basalts, and unusual lithologies such as KREEP norite, ilmenite (KREEP) microgabbro, and the Civet Cat norite, which is believed to be a plutonic differentiate. The GCBxs and BCBxs are variable in composition, averaging a moderately KREEPy olivine norite. The matrix consists of mineral fragments derived from the observed lithologies plus variable amounts of a component, unobserved as a clast-type, that approximates a KREEP basalt in composition, as well as mineral fragments of unknown derivation. The high-temperature GCBxs cooled substantially before their incorporation into the friable matrix of Boulder 1. The light friable matrix (LFBx) is texturally distinct from the competent breccia clasts and, apart from the abundant ANT clasts, contains clasts of a KREEPy basalt that is not observed in the competent breccias. The LFBx lacks such lithologies as the granites and the Civet Cat norite observed in the competent breccias and in detail is a distinct chemical as well as textural entity. We interpret the LFBx matrix as Serenitatis ejecta deposited in the South Massif, and the GCBx clasts as remnants of an ejecta blanket produced by an earlier impact. The source terrain for the Serenitatis impact consisted of the competent breccias, crustal ANT lithologies, and the KREEPy basalts, attesting to substantial lunar activity prior to the impact. The age of the older breccias suggests that the Serenitatis event is younger than 4.01±0.03 b.y.     

The albedo and diameter of 1862 Apollo

We report infrared thermal emission measurements of 1862 Apollo, which is the type example of an Earth-crossing asteroid. We derive a geometric albedo of 0.21 ± 0.02 which is within the albedo range of the S class of asteroids. The effective diameter was observed to vary with rotation from 1.2 ± 0.1 to 1.5 ± 0.1 km.     

Comparison of the analytical results from the surveyor,Apollo, and Luna missions

The principal chemical element composition and inferred mineralogy of the powdered lunar surface material at seven mare and one terra sites on the Moon are compared. The mare compositions are all similar to one another and comparable to those of terrestrial ocean ridge basalts except in having higher titanium and much lower sodium contents than the latter. These analyses suggest that most, if not all, lunar maria have this chemical composition and are derived from rocks with an average density of 3.19 g cm^–3. Mare Tranquillitatis differs from the other maria in having twice the titanium content of the others.The chemical composition of the single highland site studied (Surveyor 7) is distinctly different from that of any of the maria in having much lower amounts of titanium and iron and larger amounts of aluminium and calcium. Confirmation of these general characteristics of lunar highland material has come from recent observations by the Apollo 15 Orbiter. The inferred mineralogy is 45 mole percent high anorthite plagioclase and the parent rocks have an estimated density of 2.94 g cm^–3. The Surveyor 7 chemical composition is the principal contributor to present estimates of the overall chemical composition of the lunar surface.Presented at the NATO Advanced Study Institute on Lunar Studies, Patras, Greece, September 14–25, 1971. This paper is an expanded and updated version of a paper presented at the Apollo 12 Lunar Science Conference, Houston, Texas, January 11–14, 1971, and published in the Proceedings of this Conference (Turkevich, 1971).     

Annealing of radiation damage in zircons from Apollo 14 impact breccia 14311: Implications for the thermal history of the breccia

Impact breccia 14311, was collected from the Apollo 14 landing site as a potential sample of the underlying Fra Mauro Formation. Published zircon U‐Pb ages of >4000 Ma date the source material of the breccia and the apatite U‐Pb age of ~3940 Ma is interpreted as dating thermal resetting of the apatite U‐Pb systems. In this contribution we present new age information on the late stage thermal history of the breccia based on the annealing of radiation damage in the zircons. From Raman spectroscopic determination of the radiation damage within SIMS analytical spots on the zircons and the U and Th concentrations determined on these spots, we demonstrate that the radiation damage in the zircons has been annealed and we estimate the age of annealing at 3410 ± 80 Ma. This age is interpreted as a cooling age following heating of the breccia to above the annealing temperature of ~230 °C for stage 1 radiation damage in zircon, but below the temperature needed to reset the U‐Pb system of apatite (~500 °C). It is proposed that this thermal event was associated with the prolonged period of Mare volcanism, from 3150 to 3750 Ma, that generated massive basalt flows in the vicinity of the sample location.     

Geologic setting of Boulder 1, Station 2, Apollo 17 landing site

Boulder 1 at Station 2 is one of three boulders sampled by Apollo 17 at the base of the South Massif, which rises 2.3 km above the floor of a linear valley interpreted as a graben formed by deformation related to the southern Serenitatis impact. The boulders probably rolled from the upper part of the massif after emplacement of the light mantle. Orbital gravity data and photogeologic reinterpretation suggest that the Apollo 17 area is located approximately on the third ring of the southern Serenitatis basin, approximately 1.25 times larger than the analogous but fresher Orientale basin structure. The massif exposures are interpreted to represent the upper part of thick ejecta deposited by the southern Serenitatis impact near the rim of the transient cavity. Basin ring structure and the radial grabens that give the massifs definition were imposed on this ejecta at a slightly later stage in the basin-forming process. There is no clear-cut compositional, textural, or photogeologic evidence that Imbrium ejecta was collected at the Apollo 17 site.     

Valence state partitioning of V between pyroxene‐melt: Effects of pyroxene and melt composition,and direct determination of V valence states by XANES. Application to Martian basalt QUE 94201 composition

Abstract— Experiments on a Martian basalt composition show that D_v augite/melt is greater than D_v pigeonite/melt in samples equilibrated under the same fO₂ conditions. This increase is due to the increased availability of elements for coupled substitution with the V³⁺ or V⁴⁺ ions, namely A1 and Na. For this bulk composition, both A1 and Na are higher in concentration in augite compared with pigeonite; therefore more V can enter augite than pigeonite. Direct valence state determination by XANES shows that the V³⁺ and V⁴⁺ are the main V species in the melt at fO₂ conditions of IW‐1 to IW+3.5, whereas pyroxene grains at IW‐1, IW, and IW+1 contain mostly V³⁺. This confirms the idea that V³⁺ is more compatible in pyroxene than V⁴⁺. The XANES data also indicates that a small percentage of V²⁺ may exist in melt and pyroxene at IW‐1. The similar valence of V in glass and pyroxene at IW‐1 suggests that V²⁺ and V³⁺ may have similar compatibilities in pyroxene.     

Major and trace element chemistry of Boulder 1 at Station 2, Apollo 17

Twenty-seven samples of matrix and clast materials from Boulder 1 at Station 2, Apollo 17 have been analyzed for major and trace elements as part of the study of this boulder by Consortium Indomitabile. Both unusual and common types of material have been characterized. Gray and black competent breccia (GCBx and BCBx) and anorthositic breccia (AnBx) have compositions which are common at the Apollo 17 site and were common at the site of boulder formation. Light friable breccias (LFBx) have compositions which are not found at the Apollo 17 site other than in the boulder. Pigeonite basalt is a new type of lunar rock and has characteristics that would be expected of a highland volcanic rock. It is associated with LFBx material, and like LFBx material it is exotic to the Apollo 17 site. Coarse norite is an old primitive rock which is no longer (if ever) found as millimeter fragments at the Apollo 17 site. It was, however, present as millimeter fragments associated with GCBx and BCBx materials at the site and time of boulder formation. Therefore the boulder-forming process combined materials from at least two different localities or vertical strata; at least one of these (LFBx) has not been previously sampled and analyzed.