The geologic history of the Nicoya Ophiolite Complex, Costa Rica, and its geotectonic significance

Costa Rica forms part of an intra-oceanic arc between the Pacific and Caribbean oceans; the Nicoya Ophiolite Complex is located along its Pacific border. In this study, evidence is given that the Nicoya Complex is composed of ridge-formed oceanic crust that suffered a strong compressional stress during Late Santonian times. As a result of this, isoclinal folding and large-scale nappe emplacement occurred at a shallow crustal depth. The principal component of this compressional stress was E-W-directed. It is also demonstrated that, from this time, the complex was situated between a subducting plate and a volcanic arc. From that Campanian until the Middle Eocene the zone was undulated, and generally at a great depth below sea level. During the Eocene—Oligocene epoch a new tectonic stress affected the area. It produced open folding with upthrusting in the ophiolite complex and overthrust folding of the overlying rock series. As a result of crustal thickening during this tectonic phase, the area was uplifted. From Miocene times, the zone was shaped into a dome and a synform. These undulations are attributed to compression of the subducting Coco Plate, west of the area.The Upper Santonian tectonic phase demonstrates how compressional stress produced the break-up of the Caribo-Pacific plate west of the study area, as a result of which, a Caribbean plate without an associated oceanic ridge and a Pacific plate originated. The compressional stress in question was presumably generated by the opposed spreading directions of the new Mid-Atlantic Ridge and an older ridge to the west of the study area.Furthermore, it is argued that the Cretaceous obduction of the ophiolite belt along the Pacific coast of the American continents, was produced by the directional change of these continents during the birth of the Mid-Atlantic Ridge. This created intra-plate compressional stress and converted originally passive continental margins into active zones, where thrusting of oceanic crust on to a continental margin (obduction) could occur. When the Mid-Atlantic Ridge started spreading, the obduction phase ended due to subduction of the oceanic plate below the leading edge of the continent.     

Composition of organic matter in subducted and unsubducted sediments off the Nicoya peninsula, Costa Rica (ODP Leg 170, Sites 1039 and 1040)

Investigation of sediment samples from Sites 1039 and 1040 (ODP Leg 170) drilled off the Nicoya peninsula (Costa Rica) by organic geochemical and organic petrological methods has revealed that subduction has only little influence on the composition of the sedimentary organic matter. Organic carbon contents reached 1.5% in the Pleistocene samples but Miocene and Pliocene sediments had an average organic carbon content of less than 0.5%. Organic carbon/sulfur ratios are generally below 2.8, reflecting an intense sulfate reduction in the uppermost sediments which was enhanced by sulfate supply both from sea water and deeper strata. Microscopical examinations indicate that the organic matter is mainly derived from marine sources. A small amount of terrigenous organic matter is, however, present as well according to n-alkane and fatty acid distributions. The alkenone unsaturation index U₃₇^k′ shows only a slight decrease during the Miocene and Pliocene, and stronger variations in the Pleistocene, probably indicating more stable sea surface temperatures during the Miocene and Pliocene. Variations in the Pleistocene can possibly be related to glacial/interglacial changes.     

Modeling a tsunami from the Nicoya,Costa Rica,seismic gap and its potential impact in Puntarenas

Although subduction zones around the world are known to be the source of earthquakes and/or tsunamis, not all segments of these plate boundaries generate destructive earthquakes and catastrophic tsunamis. Costa Rica, in Central America, has subduction zones on both the Pacific and the Caribbean coasts and, even though large earthquakes (Mw = 7.4–7.8) occur in these convergent margins, they do not produce destructive tsunamis. The reason for this is that the seismogenic zones of the segments of the subduction zones that produce large earthquakes in Costa Rica are located beneath land (Nicoya peninsula, Osa peninsula and south of Limón) and not off shore as in most subduction zones around the world. To illustrate this particularity of Costa Rican subduction zones, we show in this work the case for the largest rupture area in Costa Rica (under the Nicoya peninsula), capable of producing Mw ～ 7.8 earthquakes, but the tsunamis it triggers are small and present little potential for damage even to the largest port city in Costa Rica.The Nicoya seismic gap, in NW Costa Rica, has passed its ～50-year interseismic period and therefore a large earthquake will have to occur there in the near future. The last large earthquake, in 1950 generated a tsunami which slightly affected the southwest coast of the Nicoya Peninsula. We present here a simulation to study the possible consequences that a tsunami generated by the next Nicoya earthquake could have for the city of Puntarenas. Puntarenas has a population of approximately eleven thousand people and is located on a 7.5 km long sand bar with a maximum height of 2 m above the mean sea level. This condition makes Puntarenas vulnerable to tsunamis.     

Two Types of Plagiogranite from Mesozoic Ashin Ophiolite (Central Iran): a Mark of Tectonic Setting Change from Jurassic to Cretaceous

Geotectonics - The Ashin ophiolite is situated in the western part of Central Iran and presents two stages of Jurassic and Cretaceous spreading. The Ashin ophiolite represents fragments of the...     

Composition of manganese nodules and manganese carbonates from Loch Fyne,Scotland

Manganese nodules and manganese carbonate concretions occur in the upper 10–15 cm of the Recent sediments of Loch Fyne, Argyllshire in water depths of 180–200 m. The nodules are spherical, a few mm to 3 cm in diameter, and consist of a black, Mn-rich core and a thin, red, Fe-rich rim. The carbonate occurs as irregular concretions, 0.5–8 cm in size, and as a cement in irregular nodule and shell fragment aggregates. It partially replaces some nodule material and clastic silicate inclusions, but does not affect aragonitic and calcitic shell fragments.The nodules are approximately 75% pure oxides and contain 30% Mn and 4% Fe. In the cores, the principal mineral phase is todorokite, with a Mn/Fe ratio of 17. The rim consists of X-ray amorphous Fe and Mn oxides with a Mn/Fe ratio of 0.66. The cores are enriched, relative to Al, in K, Ba, Co, Mo, Ni and Sr while the rims contain more P, Ti, As, Pb, Y and Zn.The manganese carbonate has the composition (Mn_47.7 Ca_45.1 Mg_7.2) CO₃. Apart from Cu, all minor elements are excluded from significant substitution in the carbonate lattice.Manganese nodules and carbonates form diagenetically within the Recent sediments of Loch Fyne. This accounts for the high Mn/Fe ratios in the oxide phases and the abundance of manganese carbonate concretions. Mn concentrations in the interstitial waters of sediment cores are high (ca. 10 ppm) as also, by inference, are the dissolved carbonate concentrations.     

Near-regional CMT and multiple-point source solution of the September 5, 2012, Nicoya,Costa Rica Mw 7.6 (GCMT) earthquake

We use acceleration data from the Observatorio Vulcanologico y Sismologico, Universidad Nacional de Costa Rica (OVSICORI-UNA) and Laboratorio de Ingenieria Sismica, Universidad de Costa Rica (LIS-UCR) seismic network for the relocation and moment-tensor solution of the September 5, 2012, 14:42:03.35 UTC, Nicoya, Costa Rica earthquake (Mw 7.6 GCMT). Using different relocation methods we found a stable earthquake hypocenter, near the original OVSICORI-UNA location in the Nicoya Peninsula, NW Costa Rica at Lat 9.6943°N, Lon 85.5689°W, depth 15.3 km, associated with the subduction of the Cocos plate under Caribbean plate. Acceleration records at OVSICORI-UNA and LIS-UCR stations (94–171 km), at 0.03 < f < 0.06 Hz were used in the waveform inversion for a single-point centroid moment tensor (CMT). Using spatial grid search the centroid position was found at the depth of 30 km, situated at Lat 10.0559°N, Lon 85.4778°W, i.e. of about 41 km NNE from the epicenter. The centroid time is 14:42:18.89 UTC, i.e. 15.54 s later relative to the location-based origin time. The nodal plane (strike 318°, dip 27° and rake 115°) is the fault plane that agrees with the geometry of the subducted slab at Nicoya, NNW Costa Rica. Increasing the maximum studied frequency from 0.06 to 0.15 Hz, the multiple point source inversion model leads to two subevents. The first one was located near the centroid and the second subevent was situated 20 km along strike and 10 km down dip from the first subevent and 6 s later. The uncertainty of the source model was carefully examined using complementary inversion methods, viz the iterative deconvolution and non-negative least squares.     

From Jurassic rifting to Cretaceous subduction in NW Iranian Azerbaijan: geochronological and geochemical signals from granitoids

Previous interpretations of a Jurassic subduction in Iran were based on trace element classification diagrams for granitoids, but their reliability is questionable, underscored by modern examples of continental break-up zones such as the Baja California. We present new field observations, bulk rock geochemistry, Sr and Nd isotope analyses and U–Pb zircon geochronology to assess the age and tectonic setting of previously undated intermediate to felsic magmatic rocks cropping out in the Precambrian basement of NW Iranian Azerbaijan. The geochronology revealed an uneven distribution in space and time: Late Jurassic (159–154 Ma) intrusions and dikes are alkaline to calc-alkaline. Their melt source is mantle dominated with a distinct continental contribution disclosed by radiogenic isotopes and abundant inherited zircon cores. Mid-Cretaceous (112–96 Ma) plutonic bodies and associated volcanic rocks occur only to the east of the major Siah Cheshmeh–Khoy Fault. They have geochemical signatures typical of a metasomatized mantle. In consistence with the sedimentation history of the area, our new interpretation attributes the Late Jurassic magmatism to thinning of a continental lithosphere in a rift-related setting. Mid-Cretaceous magmatism was produced by oceanic subduction beneath the Central Iran continent. We interpret the 40-Ma age gap between the two magmatic episodes as the time of opening of the oceanic basin witnessed by the Khoy ophiolite in the study area.     

Middle Jurassic age of basalts and the post-obduction sedimentary sequence in the Guevgueli Ophiolite Complex (Republic of Macedonia)

The Guevgueli Ophiolite Complex near Demir Kapija (Eastern Vardar Ophiolitic Unit) was studied for the age and facies of the overlying sediments. Cherts in direct contact with basalts are dated to late Bathonian–early Callovian with radiolarians. The post-obduction sequence, here informally named the Demir Kapija group, is composed of polymictic conglomerate, probably Kimmeridgian in age, and a more than 350-m thick carbonate succession. The carbonate succession consists of hemipelagic, slope and platform margin facies and contains algae and benthic foraminifers indicative of the Tithonian age. These new data support the previously proposed palaeogeographical connection between the Guevgueli and South Apuseni ophiolite complexes.     

Platinum-Group Mineral Characterization in Concentrates from High-Grade PGE Al-rich Chromitites of Korydallos Area in the Pindos Ophiolite Complex (NW Greece)

The Pindos ophiolite complex, located in the north-western part of continental Greece, hosts various podiform chromite deposits generally characterized by low platinum-group element (PGE) grades. However, a few locally enriched in PPGE + Au (up to 29.3 ppm) chromitites of refractory type are also present, mainly in the area of Korydallos (south-eastern Pindos). The present data reveal that this enrichment is strongly dependant on chromian spinel chemistry and base metal sulfide and/or base metal alloy (BMS and BMA, respectively) content in chromitites. Consequently, we used super-panning to recover PGM from the Al-rich chromitites of the Korydallos area. The concentrate of the composite chromitite sample contained 159 PGM grains, including, in decreasing order of abundance, the following major PGM phases: Pd-Cu alloys (commonly non-stoichiometric, although a few Pd-Cu alloys respond to the chemical formula PdCu₄), Pd-bearing tetra-auricupride [(Au,Pd)Cu], nielsenite (PdCu₃), sperrylite (PtAs₂), skaergaardite (PdCu), Pd-bearing auricupride [(Au,Pd)Cu₃], Pt and Pd oxides, Pt-Fe-Ni alloys, hollingworthite (RhAsS) and Pt-Cu alloys. Isomertieite (Pd₁₁Sb₂As₂), zvyagintsevite (Pd₃Pb), native Au, keithconnite (Pd₂₀Te₇), naldrettite (Pd₂Sb) and Rh-bearing bismuthotelluride (RhBiTe, probably the Rh analogue of michenerite) constitute minor phases. The bulk of PGE-mineralization is dominated by PGM grains that range in size from 5 to 10 µm. The vast majority of the recovered PPGM are associated with secondary BMS and BMA, thus confirming that a sulphur-bearing melt played a very important role in scavenging the PGE + Au content of the silicate magma from which chromian spinel had already started to crystallize. The implemented technique has led to the recovery of more, as well as noble, PGM grains than the in situ mineralogical examination of single chromitite samples. Although, the majority of the PGM occur as free particles and in situ textural information is lost, single grain textural evidence is observed. In summary, this research provides information on the particles, grain size and associations of PGM, which are critical with respect to the petrogenesis and mineral processing.     

Magmatism and crustal evolution in Costa Rica (Central America)

New major element and trace element data of Lower Tertiary volcanics and of rocks of the Aguacate volcanic series permit a better understanding of the petrochemical evolution in the Costa Rica area. This evolution of the magmatic and tectonic processes shows clearly the transformation of oceanic crust with basic magmatism into a continental crust with intermediate to acidic magmatic activity. The main trend since the upper Cretaceous is characterized by a continual increase of the silica level of the magmatic products which build up the present tectonitic crust of Costa Rica.Only the Aguacate volcanic series is contrasting from all other magmatic series by predominance of alkaline rocks which are petrochemically quite similar to the volcanics of the East-Pacific Islands. It is considered, therefore, that the Aguacate volcanics represent remnants of Upper Tertiary island volcanoes.

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Zusammenfassung Neue chemische Gesteinsanalysen und Spurenelement-Daten von tertiären Vulkaniten Costa Ricas erlauben eine bessere Interpretation der petrochemischen Entwicklung im südlichen Mittelamerika. Sie ist gekennzeichnet durch einen kontinuierlichen Anstieg des SiO₂-Gehaltes der magmatischen Förderprodukte von der Oberkreide bis zur Gegenwart. Hierin kommt die Umwandlung ozeanischer in kontinentale (tectonitic) Kruste zum Ausdruck.Abweichend von allen anderen magmatischen Serien Costa Ricas weist die Aguacate-Serie eine Vorherrschaft von alkalinen Gesteinen auf, die petrochemisch denen der ost-pazifischen Inselvulkane ähnlich sind. Es wird daher die Möglichkeit erörtert, da\ die Aguacate-Serie stark abgetragene Reste tertiärer Inselvulkane darstellt.

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Resumen Nuevos análisis químicos y datos de elementos trazas en los volcanitos terciarios de Costa Rica permiten una mejor interpretación de la evolución quimica del magmatismo en la zona de América Central. Dicha evolución está caracterizada por un continuo aumento en el contenido de SiO₂ de las rocas volcánicas desde el Cretácico superior hasta el Reciente. El aumento de silice manifesta la transformación de la corteza oceánica en una corteza continental (tectonítica).La Serie Aguacate se diferencia de todas las otras series magmáticas de Costa Rica, mostrando una predominación de las rocas alcalinas, que químicamente se parecen a las de las islas volcánicas en el Pacífico oriental. Por esta razón se discute la posibilidad de que la Serie Aguacate representa los restos fuertemente erosionados de islas volcánicas terciarias.

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Paleomagnetic study of Jurassic and Cretaceous rocks from the Mixteca terrane (Mexico)

Three sites from Cretaceous limestone and Jurassic sandstone in northern Oaxaca, Mexico, were studied paleomagnetically. Thermal demagnetization isolated site-mean remanence directions which differ significantly from the recent geomagnetic field. The paleopole for the Albian–Cenomanian Morelos formation is indistinguishable from the corresponding reference pole for stable North America, indicating tectonic stability of the Mixteca terrane since the Cretaceous. Rock magnetic properties and a positive reversal test for the Bajocian Tecomazuchil sandstone suggest that the remanence could be of primary origin, although no fold test could be applied. The Tecomazuchil paleopole is rotated 10°±5° clockwise and displaced 24°±5° towards the study area, with respect to the reference pole for stable North America. Similar values were found for the Toarcien–Aalenian Rosario Formation, with 35°±6° clockwise rotation and 33°±6° latitudinal translation. These data support a post-Bajocian southward translation of the Mixteca terrane by around 25°, which was completed in mid-Cretaceous time.     

New cirripedes (Crustacea,Thoracica) from the Jurassic and Cretaceous of the United Kingdom

Extensive new material of scalpelliform cirripedes, including articulated individuals, from the Late Jurassic (Tithonian) Kimmeridge Clay of Dorset, southern England, is described and used as a basis for taxonomic revision of the family Zeugmatolepadidae. Two subfamilies, the Zeugmatolepadinae and Martillepadinae nov., are established and two new genera (Martillepas, Concinnalepas) in the latter subfamily are described from the Upper Jurassic and one (Icenilepas) from the Upper Cretaceous Chalk. Material from the Kimmeridge Clay of Dorset also includes the oldest fossil representative of the family Pollicipedidae for which a new genus and species, Etcheslepas durotrigensis, are erected, and the oldest calanticid, Cretiscalpellum sp. nov. Jurassic taxa established by T.H. Withers in 1928, on the basis of sparse material, are redescribed, and referred to the new genera as Martillepas ovalis, M. costata, M. hollisi, Concinnalepas concinna and Etcheslepas fragilis.     

Aalenian to Cenomanian Radiolaria of the Bermeja Complex (Puerto Rico) and Pacific origin of radiolarites on the Caribbean Plate

The study of the radiolarian ribbon chert is a key in determining the origins of associated Mesozoic oceanic terranes and may help to achieve a general agreement regarding the basic principles on the evolution of the Caribbean Plate. The Bermeja Complex of Puerto Rico, which contains serpentinized peridotite, altered basalt, amphibolite, and chert (Mariquita Chert Formation), is one of these crucial oceanic terranes. The radiolarian biochronology presented in this work is mainly based by correlation on the biozonations of Baumgartner et al. (1995) and O??Dogherty (1994) and indicates an early Middle Jurassic to early Late Cretaceous (late Bajocian?Cearly Callovian to late early Albian?Cearly middle Cenomanian) age. The illustrated assemblages contain about 120 species, of which one is new (Pantanellium karinae), and belonging to about 50 genera. A review of the previous radiolarian published works on the Mariquita Chert Formation and the results of this study suggest that this formation ranges in age from Middle Jurassic to early Late Cretaceous (late Aalenian to early?Cmiddle Cenomanian) and also reveal a possible feature of the Bermeja Complex, which is the younging of radiolarian cherts from north to south, evoking a polarity of accretion. On the basis of a currently exhaustive inventory of the radiolarite facies s.s. on the Caribbean Plate, a re-examination of the regional distribution of Middle Jurassic sediments associated with oceanic crust, and a paleoceanographic argumentation on the water currents, we come to the conclusion that the radiolarite and associated Mesozoic oceanic terranes of the Caribbean Plate are of Pacific origin. Eventually, a discussion on the origin of the cherts of the Mariquita Formation illustrated by Middle Jurassic to middle Cretaceous geodynamic models of the Pacific and Caribbean realms bring up the possibility that the rocks of the Bermeja Complex are remnants of two different oceans.     

The geologic history of the Caribbean-Cocos plate boundary with special reference to the Nicoya ophiolite complex (Costa Rica) and D.S.D.P. results (Legs 67 and 84 off Guatemala): A synthesis

The Pre-Upper Senonian basement of Costa Rica crops out in the Santa Elena and Nicoya peninsulas. From south to north and from base to top the basement includes: the Esperanza, Matapalo and Santa Elena units. The Esperanza unit is Albian-Santonian in age and consists mainly of pillow basalt and massive basalt flows. The Matapalo unit includes Callovian to Cenomanian radiolarite and includes massive basalt flows, basalt, and dolerite basement. The Santa Elena unit contains ultramafic and mafic rocks in which harzburgite is the major component. The most important tectonic features of the Nicoya Complex are the large Santa Elena and Matapalo nappes. Nappe emplacement was from north to south during upper Santonian time. The sedimentary cover of the Nicoya Complex comprises:

1. (1) the Campanian El Viejo Formation that consists of shallow-water sediments in the north (Santa Elena Peninsula) and the Campanian-Maastrichtian Sabana Grande Formation of deep-water origin in the South (Nicoya Peninsula);

2. (2) Paleocene strata indicating deposition in a deep-water environment comprises the Rivas, Las Palmas and Samara Formations;

3. (3) a post-upper Eocene (?) sequence that consists of the shallow-water Barra Honda and Montezuma Formations.

Two unconformities are significant geological features of the upper-Senonian to Tertiary history of Costa Rica. The lower one is at the base of the Sabana Grande Formation and marks a major change in the geologic conditions (basalt is scarce in the Campanian-Tertiary series); the upper unconformity at the base of the Barra Honda and Montezuma Formations is not as major as the lower one. During post-Campanian time, normal faulting occurred in two stages separated by a strong erosional phase.The geology of the landward slope of the adjacent Middle America Trench is outlined by interpreting multifold seismic reflection records off the west coast of Costa Rica and the DSDP Legs 67 and 84 transects off Guatemala. The western Caribbean plate boundary may have been under extensional stress for the last 75 m.y. The strong landward-dipping reflectors of the Middle America Trench landward slope off Guatemala could be equivalent to the on-land pre-Campanian overthrusts of Costa Rica. The available data are consistent with the Convergent Extensional margin concept.     

First fossil insect from Lower Cretaceous Lebanese amber in Syria (Diptera: Ceratopogonidae)

Lebanoculicoides bloudani a new species of Ceratopogonidae from the Lower Cretaceous ambers of Syria and Lebanon is studied. The new species is characterized, described, illustrated, and compared with the other fossil taxa of the same extinct genus. A key to the species of the genus Lebanoculioides is proposed.     

High fidelity preservation of fossil insects from the Crato Formation (Lower Cretaceous) of Brazil

Fossil insects from the Lower Cretaceous (Aptian) Crato Formation of north-east Brazil are preserved as goethite replacements in laminated limestones of lacustro-lagoonal origin. They display remarkable degrees of morphological detail down to the macromolecular level in some examples. We document the fidelity of preservation and reveal an astonishing variety of morphological detail comparable in some instances with that found in amber inclusions.     

The Middle Jurassic radiolarites and pelagic limestones of the Nieves unit (Rondaide Complex, Betic Cordillera): basin starvation in a rifted marginal slope of the western Tethys

Middle Jurassic radiolarites and associated pelagic limestones occur in the Rondaide Nieves unit of the Betic Cordillera, southern Spain. The Rondaide Mesozoic includes: (a) a thick succession of Triassic platform carbonates, comparable to the Alpine Hauptdolomit and Kössen facies; (b) Lower Jurassic pelagic limestones comparable to the Alpine Hierlatz and Adnet facies; (c) the Middle Jurassic Parauta Radiolarite Formation, described herein; and (d) a thin Upper Jurassic-Cretaceous condensed limestone succession. The Parauta Radiolarite Formation and associated limestones were studied with respect to stratigraphy, petrography, micropalaeontology (radiolarians, calcareous nanno- and microfossils) and facies. Radiolarite sedimentation occurred in the Middle Bathonian in a restricted and dysoxic deep Nieves basin, perched in the distal zone of a continental margin fringing the Tethyan ocean. This margin was adjacent to a young narrow oceanic basin between the South-Iberian margin and a continental block called Mesomediterranean Terrane. The Nieves basin was part of a marine corridor between the Proto-Atlantic and Piedmont-Ligurian basins of the Alpine Tethys. The regional tectonic position, the stratigraphical evolution since the Triassic, the age and the nature of the Mesozoic facies and the palaeogeographic relations to adjacent domains show striking analogies between the Betic Rondaide margin and coeval units of the Alps.     

The Aguacaliente Fault,source of the Cartago 1910 destructive earthquake (Costa Rica)

On 4 May 1910, the most destructive earthquake in the history of Costa Rica (Ms 6.4) destroyed the city of Cartago, a major city located in the Valle Central of Costa Rica. Using both palaeo‐seismological and morphotectonic analyses, we have found evidence that points to the Aguacaliente Fault (AF) as the source of this earthquake. This structure is a N100° E trending, strike‐slip fault situated to the south of Cartago and within a wide band of deformation. We excavated two trenches near Bermejo, south of Cartago. We found evidence of three surface ruptures within the last 1000 years on this fault. The age of the most recent rupture is consistent with the Cartago 1910 earthquake. The AF is a seismogenic source capable of producing large earthquakes (Mw 6.5–6.9) with an estimated recurrence interval of about 500 years.