Oxygen isotopes in single micrometer-sized quartz grains: tracing the source of Saharan dust over long-distance atmospheric transport

Oxygen isotope compositions were measured by ion microprobe in individual micrometer-sized quartz grains extracted from one aerosol sample collected on the Cape Verde Islands and from four surface samples (three soils and one sediment) representing potential source regions of aerosols in Western and Central Africa (Morocco, Algeria, Niger, and Chad). A large range of δ¹⁸O values, from +6.2‰ to +39.3‰ is present within the aerosol quartz grains. The different size fractions of the quartz grains from the surface samples overlap nearly entirely this range but show significant differences in their δ¹⁸O distributions for the different size fractions of the grains (i.e., different modes, different proportions of grains with low or high δ¹⁸O, ...). These differences in δ¹⁸O distributions can be related to different geological formations (i.e., mantle-derived magmatic rocks, crustal magmatic rocks, or sedimentary rocks) outcropping in each region, thus giving a fingerprint of the source region. Quartz grains with unusually high δ¹⁸O values between +30‰ and +40‰ were attributed to lacustrine cherts formed in evaporitic environments (Chad basin).The existence of distinct δ¹⁸O distributions for the surface samples, which reflect regional geology but indicate some transport of the grains, enables the characterization of mixing processes during dust emission in the atmosphere. Particles are mixed at a regional scale in the dust reservoir, but injection of fine particles into the high troposphere occurs as a discrete and localized event with no mixing during the subsequent long-range transport by the easterlies. The comparison of the δ¹⁸O distribution of the quartz from the aerosol sample with the equivalent size fractions in surface samples shows that the Niger area is the more probable source region for the aerosol although the Moroccan source cannot be excluded. This method gives a valuable tool to trace the source region of dust into the atmosphere or into sediment samples, allowing the reconstruction of air mass circulations.     

Morphoscopy and morphometry of quartz grains from loess and buried soil layers

A complex method is suggested for the study of surfaces of sand grains. With this method, middle- and late Pleistocene loess-palaeosol sequences of the Russian Plain, Dnieper Basin, were studied. Surface texture of grains pointed to a dry and cold climate for their formation. During deposition of loess layers predominantly aeolian and cryogenic processes formed the grain surfaces. During interglacial and interstadial periods chemical weathering dominated.     

ESR dating and trapped electrons lifetime of quartz grains in loess of China

This paper reports the preliminary application of ESR dating to loess strata. The samples were collected from the 7th palaeosol layer (S7) of the Luochuan section, Shaanxi province in China. The ESR age of S7 is 736 ka (total dose 2945 Gy, annual dose 4 mGy/year). This age represents the original eolian accumulation age. The result is consistent with the palaeomagnetic data (730 ka). We have also carried out thermal annealing experiments on quartz grains from the S7 sample. ESR intensities (g = 2.0005) increase from 25°C to 320°C. It may be that trapped electrons transfer into the E′ centre site. ESR intensities decrease from 340°C to 460°C due to thermal annealing. We obtained a mean-life of E′ centre electrons at 20°C of 6.66 × 10⁸ years. The activation energy is 1.35 eV and frequency factor is 3.7 × 10⁸ min⁻¹.     

Sand dunes as a major proximal dust source for late Pleistocene loess in the Negev Desert, Israel

Grain size analyses of three hilltop, primary eolian loess sequences in the Negev desert, southern Israel, show a bimodal grain-size distribution at 50-60 μm and 3-8 μm. Using analyses of mineralogy and OSL ages we demonstrate that the coarse mode is composed mostly of quartz grains and its relative magnitude increases regionally with time, suggesting an enhancement of a time-transgressive proximal dust source compared to a distal, Saharan fine-grain dust. The only proximal dust source for large amount of coarse silt quartz grains is the sands that advanced into Sinai and the Negev concurrently with the loess accretion during the late Pleistocene as a result of the exposure of the Mediterranean shelf. We therefore propose that the coarse silt quartz grains were formed through eolian abrasion within the margins of an advancing sand sea. This relationship between desert sand seas as a source for proximal coarse dust and desert margin loess deposits can be applicable to other worldwide deserts such as Northern Africa, China and Australia.     

Glacially-crushed quartz grains in late Quaternary deposits in the Virunga Mountains,Rwanda -indicators of wind transport from the north?

Quartz sand grains in late Quaternary deposits of the Virunga Mountains, northwestern Rwanda, were found to contain glacial-crushing microtextures. Glacially-crushed subangular grains generally lack sharp edges, and carry mainly low frequency, linear crushing features. Because there are no known tills in the Virunga Volcanoes (and because quartz is rare in volcanic terrain), it is likely the grains were delivered by aeolian transport from the Ruwenzori Massif, -150 km to the north. All the grains studied are consistent with crushing under low shear stress, and over short transport distances, in alpine glaciers. An increase in the percentage of glacially-crushed quartz from Holocene to Pleistocene beds likely reflects on the increased strength of the paleowind system (trade winds) during the last glacial maximum. Alternatively, it could reflect on the increased source area for glacially-crushed grains resulting from an increase in the extent of the Afroalpine belt during the last glaciation.     

The past in dust: current trends and future directions in Pleistocene geoarcheology of European loess

Loess is a main archive of Pleistocene landscapes and environments and therefore has an important connection to the preservation and interpretation of Paleolithic sites. In Europe, anthropogenic sites have been found in loess because of past local occupation. At one extreme, sites are well preserved with minimal disturbance often accompanied by embedded proxies to estimate ecological parameters. On the other hand, loess deposits have undergone post-depositional alterations such as weathering, pedogenesis or bioturbation due to changing environmental conditions or other disturbances that obscure anthropogenic sites. We outline the current state of research and connections between Paleolithic archeology and loess research while introducing a series of subsequent regional case studies as part of a special issue. We also make recommendations for future work to incorporate a wider variety of methods to create more robust inferences on hominin and environmental evolution and their connections.     

斜度驱动第四纪冰期-间冰期转换——来自中国黄土的证据

第四纪气候冰期-间冰期旋回与地球轨道周期性变化之间的关系是古气候研究的重点。文章利用中国黄土沉积的粒度和次生碳酸盐微量元素记录,在同一剖面中同时获得了冰量信息和地球轨道斜度信息。黄土的平均粒径反映了冬季风的强度从而指示了北半球高纬冰盖的变化,而次生碳酸盐（生物微钙体）的Sr/Ca比值记录了东亚夏季降水的变化,反映了斜度对东亚夏季风的控制作用。通过分析冰消期时粒度快速变化所处的夏季降水指示的斜度变化的相对位置,发现过去1.5 Ma以来的冰消期总在地球轨道处于较高斜度时发生,从而验证了斜度对第四纪冰期-间冰期旋回的驱动作用。

     

Surface microtextures of quartz grains from the central coast of Tamil Nadu

Quartz grain surface micro textures of 12 samples collected from the beach were examined under scanning electron microscopy to understand the role of coastal processes on their transportation and deposition. The study area has been divided into three sectors on the basis of drainage, geomorphology and nature of the beach and shelf topography. Surface textures of the northern sector display an array of mechanical features like conchoidal fracture, V marks and impact pits, indicating the dominance of mechanical processes. However, silica precipitation in the form of globules indicates an added influence of chemical processes in the Northern sector. The presence of chemical features in northern sector, where energy level is high, corroborates the addition of quartz grains from paleo-sediments, from the nearby Tertiary and Cretaceous formations. Central sector quartz grains display the signatures of chemical and mechanical processes. The presence of step like furrows in southern sector is an indicator of fluvial low energy conditions, and supplements the role of littoral currents in depositing the quartz grains along the coastal region.     

Radiolaria as paleoclimatic indicators: Pleistocene climatic fluctuations in the equatorial Pacific Ocean

Late Pleistocene radiolarian assemblages were examined in two cores (V24-58 and RC11-209) from the eastern equatorial Pacific Ocean, using Nigrini's 1970 method of recurrent group analysis. The radiolarian “climatic index” curves obtained by this analysis were in close agreement with fluctuations in carbonate levels established previously for the same cores. This correspondence suggests that equatorial radiolarian assemblages changed significantly in response to Pleistocene climatic oscillations. The radiolarian “climatic indices” of the two cores showed close agreement with each other. Our data indicate that equatorial radiolarian assemblages may prove useful for regional correlations between cores, and for paleoclimatic interpretations.     

Chronology of late Pleistocene Pampa loess from the Córdoba area in Argentina

In Argentina, loess/palaeosol sequences were studied from the two sections at Monte Ralo and Corralito, located near to the city of Córdoba in the east of the Pampean ranges. Infrared optically stimulated luminescence (IRSL) and thermoluminescence (TL) dating techniques were applied to set up a more reliable chronological framework for the Upper Pleistocene loess record. IRSL ages increase with depth and are stratigraphically consistent. The oldest loess exposed correlates at least to the penultimate glaciation. The luminescence dating study gives evidence for humid climate conditions with soil formation during the last interglacial period and the middle pleniglacial correlating to Marine Isotope Stage (MIS) 5 and 3, respectively. Three extended periods of soil formation are recorded in the loess/palaeosol sequences at the Corralito section. These buried soils most likely correlate with the last interglacial and early last glacial period. During the Middle Pleniglacial, two palaeosols are intercalated in the loess successions. In the Córdoba area, the periods of increased loess accumulation and deposition of loessic sediments correlate with more arid and glacial periods during the Early Pleniglacial, the Middle Pleniglacial and the Late Glacial. Copyright © 2009 John Wiley & Sons, Ltd.     

四川盆地白垩纪沙漠石英沙颗粒表面特征

石英具有较大的硬度和较高的化学稳定性，因而其颗粒表面特征能很好地反映沉积环境。而通过扫描电镜研究石英颗粒表面微细特征是分析沉积环境行之有效的方法。虽然多数人认为四川盆地白垩纪地层存在沙漠沉积(打儿凼组和夹关组)，但仍有人对沙漠沉积的存在持怀疑态度，并认为是河流成三角洲沉积。过去关于其沉积环境的判别主要是根据沉积结构和构造，并未对其石英沙颗粒表面特征进行过系统分析。笔者对采自四川盆地白垩系不同层位地层的样品进行了石英沙颗粒表面特征系统分析。结果表明，石英沙颗粒表面特征分析可以成功地将石英沙区分为风成和水成沉积。因此，本文从石英沙颗粒表面特征方面进一步肯定了四川盆地白垩纪古沙漠的存在。     

Thermoluminescence dating of coarse-grain quartz from the Malan loess at Zhaitang section, China

Thermoluminescence (TL) ages were obtained for five loess samples taken from the Zhaitang section near Beijing, China, using the coarse-grain quartz technique. The paleodose values have been determined by the method of total sample bleaching and regeneration of the TL growth curve. The method appears to be suitable for the age determination of loess samples up to about 150,000 yr where the annual dose-rate values are of the order 3–4 mGy/yr. This limit is a function of the total accumulated dose. The ages are in good agreement with those obtained by a fine-grain TL technique and are consistent with geological and geomagnetostratigraphic evidence.     

Aluminum and germanium paramagnetic centers in vein quartz and rock crystals from the Subpolar Urals

The major economic types of vein quartz and rock crystals from the Subpolar Urals were studied using electron paramagnetic resonance. Quartz is characterized by widely variable concentrations of aluminum and germanium paramagnetic centers. The average values and ranges of these concentrations increase from older to younger generations of quartz. The lowest content of aluminum and germanium paramagnetic centers is typical of granulated and primary fine-grained quartz; in coarse-grained quartz and rock crystals, the content is much higher. According to the data obtained, granulated and primary fine-grained quartz should be regarded as a potentially high-quality raw material for glass melting, because these quartz varieties are distinguished by the lowest contents of alien structural centers. Once mineral impurities eliminated, high-quality quartz concentrate can be produced from this quartz.     

Detrital carbonate grains as provenance indicators in the Upper Cretaceous Pietraforte Formation (northern Apennines)

The Upper Cretaceous Pietraforte Formation, an allochthonous unit of the Ligurian domain in the northern Apennines, provides a case study of the importance of detrital carbonate grains for provenance determination in sandstones. The Pietraforte Formation is composed of turbidite sandstones with subordinate conglomerate, deposited in an external sector of the Ligurian ocean, close to the Adriatic margin. The sandstones have a lithic composition, characterized by abundant sedimentary and metasedimentary rock fragments (35–56% of the terrigenous framework), little feldspar (<7%) that is almost exclusively plagioclase, and a high ratio of fine- to coarse-grained polycrystalline quartzose grains to total quartzose grains (average Q_p/Q_t=0.37). Carbonate rock fragments dominate the lithic association of both sandstones and conglomerates and provide the most detailed information for provenance determination. They are composed primarily of dolostones and a wide variety of limestones containing identifiable age-diagnostic microfossils. Fossils and rock textures of carbonate clasts document the erosion of Upper Triassic to Lower Cretaceous shelf and pelagic carbonate units which can be matched with Mesozoic rock types present in the Tuscan domain of the northern Apennines. Compositional results constrain the source of the Pietraforte Formation sandstones to the western margin of the Adriatic plate, from uplifted sedimentary and metasedimentary rocks of the Tuscan domain and its low-grade metamorphic basement. Coeval intrabasinal sources provided additional supplies to the depositional basin of the Pietraforte Formation; this intrabasinal supply consists of shelf carbonate allochems, planktonic foraminifera and argillaceous rip-up clasts. The presence of carbonate grains from shallow-water environments may indicate the existence during deposition of marginal shelf areas favourable for carbonate allochem production.     

不同气候带花岗岩母质发育的土壤中石英颗粒形态特征研究

石英颗粒形态特征已被广泛用于土壤风化和侵蚀与古气候重建的研究。我国花岗岩空间分布极为广泛,气候、植被与土地利用多种多样,其发育土壤中的石英颗粒形态必然也存在差异。本研究选取了我国5类气候带下的花岗岩母质发育的典型土壤的表层样品,利用扫描电镜分析石英颗粒形态特征,旨在进一步揭示气候对石英颗粒风化的影响。结果表明：1）石英颗粒形态特征具有明显的规律性,表现为随着纬度的降低,石英颗粒的圆化程度及溶蚀程度均有所增强,机械特征发育减弱。2）基于石英颗粒形态特征建立的半定量特征统计指标更好地表现出了显著的地带性差异,其与地理纬度之间具有显著的相关性,也进一步证明了气候因子对石英颗粒形态特征的影响。

     

Climatostratigraphy of Upper Pleistocene Vertebrates and the conditions of loess formation in Hungary

Having revised some reference vertebrate faunas from Hungary and from Central Europe their biostratigraphic positions could be determined more accurately. By extending the vole thermometer method to the continental parts of Central Europe fairly well identifiable average July temperature curves could be obtained for the Upper Pleistocene. The main events shown by the climatic curve for Hungary can be well correlated with the soil and loess complexes of the Paks loess profile, and also with the global climatostratigraphic scale.     

中国北方沙漠石英δ18O值的初步测定与分析

石英是岩石、沉积物中最常见的矿物之一,它的化学性质稳定,硬度大。在风化剥蚀、搬运、沉积和埋藏条件下,石英中氧同位素与外界环境氧同位素交换非常弱,即石英的δ¹⁸O值基本保持不变。因此,石英δ¹⁸O值被应用于气溶胶、黄土-古土壤堆积序列、日本和夏威夷土壤、深海沉积物的物源区的研究中。但是用石英δ¹⁸O值来探讨沙漠物源的报道尚不多,笔者在此选择位于内蒙古西部的巴丹吉林沙漠为重点研究区,对比分析浑善达克沙地、呼伦贝尔沙地、非洲南部的卡拉哈里沙漠沙丘沙石英δ¹⁸O值,试图探讨沙漠石英δ¹⁸O值与粒径、物源的关系。石英δ¹⁸O值分析测定的实验步骤如下^[1～3]:1)从每个     

Subglacial bed conditions during Late Pleistocene glaciations and their impact on ice dynamics in the southern North Sea

Passchier, S., Laban, C., Mesdag, C.S. & Rijsdijk, K.F. 2010: Subglacial bed conditions during Late Pleistocene glaciations and their impact on ice dynamics in the southern North Sea. Boreas, Vol. 39, pp. 633–647. 10.1111/j.1502‐3885.2009.00138.x. ISSN 0300‐9483. Changes in subglacial bed conditions through multiple glaciations and their effect on ice dynamics are addressed through an analysis of glacigenic sequences in the Upper Pleistocene stratigraphy of the southern North Sea basin. During Elsterian (MIS 12) ice growth, till deposition was subdued when ice became stagnant over a permeable substrate of fluvial sediments, and meltwater infiltrated into the bed. Headward erosion during glacial retreat produced a dense network of glacial valleys up to several hundreds of metres deep. A Saalian (MIS 6) glacial advance phase resulted in the deposition of a sheet of stiff sandy tills and terminal moraines. Meltwater was at least partially evacuated through the till layer, resulting in the development of a rigid bed. During the later part of the Saalian glaciation, ice‐stream inception can be related to the development of a glacial lake to the north and west of the study area. The presence of meltwater channels incised into the floors of glacial troughs is indicative of high subglacial water pressures, which may have played a role in the onset of ice streaming. We speculate that streaming ice flow in the later part of the Saalian glaciation caused the relatively early deglaciation, as recorded in the Amsterdam Terminal borehole. These results suggest that changing subglacial bed conditions through glacial cycles could have a strong impact on ice dynamics and require consideration in ice‐sheet reconstructions.     

Luminescence sensitivities of quartz grains from eolian deposits in northern China and their implications for provenance

The thermoluminescence (TL) and optically stimulated luminescence (OSL) sensitivities of quartz grains from deserts and loess–red clay sequences are used to trace eolian provenances in northern China. Our results indicate that the 110°C TL peak and OSL sensitivities of quartz grains show differences among Chinese deserts, which can be subdivided into four groups according to the spatial variations of luminescence sensitivities. Such differences are related mostly to the regional difference in rock types of mountains surrounding or adjacent to the deserts. We also examine the possible provenance changes between the Quaternary loess and the Tertiary eolian red clay, and the results indicate that the luminescence sensitivity of Tertiary red clay is higher than that of Quaternary loess (L1, L15, and L33), implying source materials of the eolian deposits changed relative to those of the Quaternary.