Scanning electron microscopy of quartz grains in supraglacial debris, Adishy Glacier, Caucasus Mountains, USSR

The surface microtopography of quartz grains in glacial depostis has often been attributed to mechanical release from source rocks during weathering and prior to entrainment by glaciers. Fractures on quartz particles, including subparallel and conchoidal features, often attributed to cryostatic pressure in ice and stick-slip processes at the base of glaciers, have been considered, in part, to result from mechanical weathering of source rocks. To test this hypothesis we studied 15 samples of supraglacial debris from the Adishy Glacier in the central Caucasus Mountains, USSR. Clasts in transport on the surface of the glacier originate primarily from the cirque headwall by weathering and mass wasting processes; a minor amount is presumed to have been derived from aeolian influx following reworking of older sediments down valley. The results show unequivocally that mechanical weathering is only likely to produce grains with pronounced fracture faces that lack subparallel and conchoidal fracture features. No fresh glacial-crushing type features were observed on these samples. Grains that had been glacially crushed, weathered and retransported, presumably by aeolian processes, were observed in four samples of the data set.     

A simple method to classify diamicts by scanning electron microscope from surface microtextures

Interpretation of quartz sand grain surface microtextures with scanning electron microscopy has been riddled with inconsistencies, invalid assumptions and much subjectivity. Therefore, a novel classification for analysing grain surface microtextures is presented based on the origin of complete grain surfaces. This novel method has solved most of the earlier problems of interpretation of surface microtextures, and it is easy to use and to quickly find evident genetic interpretations of diamicts. The data are plotted graphically in ‘2‐History Diagrams’ or ‘3‐History Diagrams’ for quick visual inspection and statistical evaluation. Source rocks and Quaternary glacial deposits from Scandinavia and Southern Ontario, representing different ice‐substrate dynamics, are analysed to define surface microtextures from typical glacigenic grains, bedrock and fluvially transported grains. Typical glacially crushed grains display large‐scale fractures and abrasion. Shield bedrock grains display large or small‐scale fractures and solution/precipitation microtextures. Fluvially transported grains exhibit abrasion and solution/precipitation microtextures.     

冰川沉积类型识别与ESR测年样品采样规范

电子自旋共振(ESR)技术是一种确定物质成分和结构的顺磁性质的分析方法,也能够用于沉积物定年。该方法的测量技术和测年的物理机制等还处于发展阶段。冰川作用过程十分复杂,形成各种类型的冰川沉积物,其顺磁信号的归零机制有显著差异,ESR测年的实验方案也有所差异。因此,识别冰碛物类型,采集合适的样品对于ESR测年的准确性十分重要。冰下融出碛和滞碛经过了冰下磨蚀过程,结构致密,细颗粒基质含量高,石英砂中的一些杂质芯的ESR信号能够衰退。许多冰上融出碛,结构疏松,但细颗粒基质含量高,不但经过了搬运过程中的冰下磨蚀过程使ESR信号衰退,又经历了沉积时的冰上阳光直射过程使信号衰退,一些样品的ESR信号能够完全晒退。冰水湖泊和冰水河流沉积的细砂和粉砂来源于冰下研磨的产物,信号会衰退;在搬运沉积过程中又可能被阳光直射,信号进一步衰退。其它类型的冰碛物的ESR信号衰退机制不明,或粒径不适合用ESR方法测年。采集冰碛物ESR年代样品时,最好同时采集信号衰退机制相同的现代冰碛物样品,以便对照,并用于扣除可能的残留信号。     

Temporal changes in subglacial meltwater activity: field evidence from the late Devensian in the north of Ireland

Temporal changes in meltwater abundance, distribution and characteristics (controlling subglacial processes and ice sheet dynamics) can be inferred from subglacial sediment successions. Field evidence for changes in subglacial meltwater characteristics over time is presented from two sites (Doonan, Drummee) near a former late Weichselian (Devensian) ice centre in the north of Ireland. On a macroscale, both sites investigated show subglacial diamicton overlying glacially planated bedrock platforms. In more detail, primary sedimentary structures and facies variability show a complex relationship between depositional processes and meltwater characteristics at the ice/bed interface (IBI). Sedimentary evidence suggests sediment transport and deposition took place by low-viscosity subglacial slurries (mobile sediment–meltwater admixtures), which are part of a continuum between the processes of subglacial sediment deformation and subglacial meltwater flooding. Subtle changes in meltwater abundance and distribution at the IBI controlled slurry rheology, mechanisms of particle support and detailed sediment depositional processes.     

Scanning electron microscopy of Pleistocene tills in Estonia

Tills from four Pleistocene glaciations were recovered from drill cores in Estonia and subjected to particle size and microtexture analyses by Scanning Electron Microscope (SEM). All tills were deposited by thick continental ice-sheets following the transport of, at most, several hundred kilometers during four Fennoscandian glaciations. The main problem is to determine if the type and range of microtextures present on the grain surfaces are diagnostic of transport in continental ice. The frequency of occurrence of microtextures including fractures, abrasion, and relief features are used to test the ability of continental ice to damage quartz particles emplaced as till. The range of quartz dissolution and presence of coatings on grains are also used to reconstruct the paleoenvironment that existed prior to transport as well as to estimate diagenetic effects that occurred following emplacement. The available data indicate a high degree of reworking of quartz grains from one glaciation to another. While the shapes and microtextures of grains from source rocks are not known, the great range of fracture and abrasion microfeatures, and high frequency of occurrence on grains in all tills, indicate that glaciers are effective crushing agents. An increase in the prevalence of chemically etched grains from older to younger tills suggests that some grains ( c . 50%) escape crushing, either because of preservation in the ice and lack of grain-to-grain contact, or as a result of massive reworking of weathered grains following interglaciations.     

Geochemical, mineralogical and sedimentological studies on the Taklimakan Desert sands

Major-element composition, mineral composition and grain-size distribution have been studied for Quaternary aeolian sediments from the Taklimakan Desert, north-western China, together with the variation of chemical and mineralogical compositions of different grain-size fractions. Aeolian sediments from the Taklimakan Desert have higher ratios of feldspar/quartz and calcite/quartz, finer grain size, poorer roundness of quartz and feldspar grains and lower abundances of frosted quartz, than found in aeolian sediments from other deserts such as the Saudi Arabian Desert. In spite of these immature mineralogical and sedimentological features, the aeolian sediments from the Taklimakan Desert show low regional variations in major-element and mineral compositions and are homogenized. These observations confirm that two processes, glacial activity within surrounding mountains and aeolian activity at the Tarim Basin, are important in the homogenization of the Taklimakan Desert sands. Taklimakan Desert sediments are constantly and effectively supplied from basement rocks in the surrounding mountains by glacial erosion. The supplied sediments are further homogenized by aeolian activity in the desert and are partly blown away, serving as the source of Chinese aeolian loess. Compositional differences are observed between loess (mainly 10–40 μm particles) and the <45 μm fraction of the Taklimakan Desert sediments, as well as between loess and whole rock of the Taklimakan Desert sediments. These observations provide constraints for precise modelling of loess formation, and for assessment of the chemical composition of the upper continental crust based on the chemical composition of aeolian loess.     

青藏高原北部可可西里库赛湖年纹层微区分析及形成机理

湖泊年纹层是进行高分辨率古气候环境研究的重要载体之一,其形成机理的研究能够为高分辨率古气候环境信息的提取提供重要的依据。本文以青藏高原北部可可西里库赛湖沉积的年纹层为研究对象,通过纹层薄片显微镜观察,以及纹层的扫描电镜、X衍射和同步辐射X射线荧光等微区分析,对库赛湖沉积年纹层的形态、沉积和成分特征进行了研究,以探讨库赛湖年纹层形成过程和机理。结果表明:年纹层层偶由深浅相间的微层组成,深色层主要由灰褐色—黑褐色的粗颗粒物质组成,磨圆中等、分选性差,矿物以石英、长石、白云母、黏土矿物等为主,其中石英含量占73%左右,且具有明显的风力搬运特征;浅色层呈灰白色,矿物颗粒较细,除石英、长石、白云母、黏土外,还有自生的文石,同时浅色层中含有大量的枝角类碎片和半月形介形类生物壳体。研究认为,库赛湖冬季温度低、风力强劲,风的机械搬运作用使大量的陆源物质在冰面堆积,等到春季湖泊开封,冰面上粗颗粒物质沉积到湖底形成库赛湖年纹层的深色层(粗颗粒层);夏季温度升高,冰雪融化,降水增加,河流搬运的陆源粗颗粒物质由于重力作用先在湖泊边缘沉积,而黏土矿物等细颗粒物质则在湖泊中心沉积,同时夏季湖水温度升高,蒸发作用加强,生物活动增强,湖泊自身的生物、化学作用加强,从而形成以细碎屑矿物、生物残体、自生碳酸盐沉积为主的浅色层(细颗粒层)。因此,库赛湖的年纹层层偶是由冬季冰面风成物质形成的粗颗粒深色层(冰融化后,风成物质沉降至湖底堆积)和夏季沉积的细颗粒浅色层两者交替而形成的。     

Quartz microtextures and microstructures owing to deformation of glaciolacustrine sediments in the northern Venezuelan Andes

Glaciolacustrine sediments, ranging in age from Early to Late Mérida (Wisconsinan) in sections in the northern Venezuelan Andes near Pedregal, were studied to assess the effect of small‐scale folding and faulting on the surface microtextures of individual grains. At site PED5, faulting of sediments beneath 35 m of Middle to Late Mérida glaciolacustrine, glaciofluvial and probable till deposits, has resulted in a maximum displacement of 1 m and many crushed sand grains are found along the shear zone. These dominantly quartz particles are typically smoothed and/or faceted with surface skins split from parent grains to produce adhering blade or wafer‐shaped coarse silts. Faulting with displacement of< 40 cm occurs in Late Mérida glaciolacustrine beds at sites PED13 and PED11, beneath ca. 1–5 m of sediment and is thought to result from the removal of lateral support during valley erosion and possibly seismic disturbance. Associated sediments exhibit a greater incidence of small‐scale fold structures and convoluted bedding but with similar numbers and types of crushed grains. All of the fault traces examined exhibit microstructural modifications, including microfaulting, folding and multiple domains associated with fluidisation and liquefaction. The microtextures described are distinct from those produced by glacial or glaciofluvial transport processes and potentially may be used to infer glaciotectonic or other post‐depositional disturbance of sediments. Rare euhedral quartz grains with distorted crystallographic axes may derive from the shear zone of the regional transform Boconó Fault, although many of these grains appear to be overprinted by glacial and/or recent deformation processes. Copyright © 2004 John Wiley & Sons, Ltd.     

Quartz and zircon decoupling in sandstone: Petrography and quartz cathodoluminescence of the Early Triassic continental Buntsandstein Group in Germany

This study illustrates how decoupling of quartz and zircon can be used advantageously in provenance research. Thirty‐eight fine‐grained to coarse‐grained arkose samples of the Early Triassic intracontinental Buntsandstein Group from the Central European Basin in Germany were analysed for their petrography and 1200 grains in 23 of these for their detrital quartz cathodoluminescence characteristics. The samples represent the Hessian and Thuringian sub‐basins and the Eichsfeld–Altmark Swell separating them. The Hessian Sub‐basin includes more metamorphic lithoclasts with a larger content of plutonic grains than are found further east in the Thuringian Sub‐basin. More than 90% of the detrital quartz from the eastern Thuringian Sub‐basin produce medium to bright blue cathodoluminescence colours and corresponding spectra that are typical for igneous or high‐temperature metamorphic origin. Differently, the quartz from the Hessian Sub‐basin mostly luminesces brown and dark to medium blue, typical for a low‐temperature metamorphic origin. Quartz from the Eichsfeld–Altmark Swell and the western Thuringian Sub‐basin is a mixture between these origins. The quartz indicates different catchments for the sub‐basins, possibly the Bohemian Massif and the Massif Central, with converging transport routes on and close to the eastern fringe of the swell. Taking published zircon data from the same samples into account, light mineral‐zircon grain‐size shifts are up to 2 Φ units. That can be explained by mineral decoupling due to different transport modes for quartz and zircon and different zircon‐size availability in the source areas, exaggerated by combined aqueous–aeolian transport, as well as sample preparation‐induced sorting. This study concludes that submerged highs significantly can influence continental sediment transport. Hence, vast, flat continental areas with submerged morphological highs and a seemingly straightforward transportation pattern may be more complex than expected. The results also illustrate that analysis of detritus that has been affected by different dominating transport modes, and further sorting during sampling and preparation can reveal additional source information.     

Glacially derived material in an Inner Mongolian desert lake during Marine Isotope Stage 2

Establishing the precise timing of continental glacial dynamics and abrupt high‐latitude climate events is crucial to understanding the causes of global climate change. Here we present multi‐proxy records in a lake sediment core from arid Inner Mongolia (Wuliangsuhai Lake) that show two distinct glacially derived sedimentation events at ～26.2–21.8 and ～17.3–11.5k cal a BP. Fine sediments from the Last Glacial Maximum separate these glacially derived coarse sediments. Within these intervals, the occurrence of granite clasts at ～24–23.5, 17.3–17 and 15.6–14.1k cal a BP implies either sediment discharge by meltwater as well as strong current flow in the Yellow River and/or sediment influx through hill‐slope mass wasting and landsliding from the nearby Yin Mountains. Surface microfeatures of quartz grains and spot elemental analysis of black specks in these intervals, however, indicate that physical weathering is dominant and that the provenance of the rocks is probably from a glacial source. To the best of our knowledge, this is the first time glacier‐derived materials have been detected in any desert lake in the Yellow River basin. The occurrence of granite clasts roughly correlates with Heinrich events in the North Atlantic, suggesting synchronous ice sheet dynamics in high‐ and mid‐latitude regions during the Last Glacial period. Although our data provide unprecedented evidence for the influence of glacier‐related processes in arid Inner Mongolia, further well‐dated records are clearly needed to re‐evaluate the correlative inference drawn between granite clast layers in Wuliangsuhai Lake and Heinrich events in the North Atlantic. Copyright © 2012 John Wiley & Sons, Ltd.     

Glacially-crushed quartz grains in late Quaternary deposits in the Virunga Mountains,Rwanda -indicators of wind transport from the north?

Quartz sand grains in late Quaternary deposits of the Virunga Mountains, northwestern Rwanda, were found to contain glacial-crushing microtextures. Glacially-crushed subangular grains generally lack sharp edges, and carry mainly low frequency, linear crushing features. Because there are no known tills in the Virunga Volcanoes (and because quartz is rare in volcanic terrain), it is likely the grains were delivered by aeolian transport from the Ruwenzori Massif, -150 km to the north. All the grains studied are consistent with crushing under low shear stress, and over short transport distances, in alpine glaciers. An increase in the percentage of glacially-crushed quartz from Holocene to Pleistocene beds likely reflects on the increased strength of the paleowind system (trade winds) during the last glacial maximum. Alternatively, it could reflect on the increased source area for glacially-crushed grains resulting from an increase in the extent of the Afroalpine belt during the last glaciation.     

Result from a comparison of UV and sunlight bleaching of feldspar and quartz

The influence of artificial UV light and sunlight on natural glow curves were compared for K-feldspar and quartz from a fluvial and an aeolian deposit. The results for feldspar grains show that the use of a UV lamp for bleaching instead of sunlight does not influence the accumulated dose plateau. Results on the quartz sample on the other hand show clear differences. This fact makes dating using quartz grains more complicated. The problem of finding the correct residual reached at sedimentation by using the regenaration technique starting from different artificial residuals is also discussed.     

Nature, origin and age of Holocene aeolian sand on Muckish Mountain, Co. Donegal, Ireland

Dissected sand sheets and flow-aligned sand shadows occur near the summit of Muckish Mountain, Co. Donegal. The sand is of medium to fine size and moderately sorted to moderately well sorted. Sand transport by northerly winds is indicated by the location and morphology of the deposits. The source of the sand is a series of friable quartzite beds immediately below the northern edge of the summit plateau. Minor additions of gravel and very coarse sand, derived from the disintegration of plateau clasts, were probably also incorporated within the deposits by aeolian action, although surface wash associated with heavy rain or snowmelt may have mobilized these particles. The absence of diagnostic aeolian transport textures on quartz grain surfaces reflects the short distance/duration of transport. ¹⁴C dates indicate two phases of sand sheet accumulation: one between c. 5,300 ande. 2,650 B.P. and again after c. 1,910–1,760B.P. The sand shadows have formed within the last hundred years in response to the construction of small cairns across the plateau. Sand sheet dissection suggests erosion is currently occurring, but this began prior to the late nineteenth century. Present-day sand accumulation is also apparent from the widespread scatter of grains trapped by surface Vegetation. The sand represents the first recognition of aeolian deposition in the uplands of Ireland.     

The relation between the crystallography of quartz, and upturned aeolian cleavage plates

The relation between the crystallography of artificially abraded quartz sand grains and aeolian surface textures has been studied using an X-ray precession camera and the scanning electron microscope (SEM). Crushed Brazilian quartz was sieved to between 250 and 350 μm, eroded in a paddle wheel device which simulated aeolian action at 8 m s^?1 for 3 h, and photographed with the SEM. A typical grain was selected and over 1100 photographs were combined to create a 3 × 3 m photomosaic; because of the large size, it was possible to observe and measure the angular and linear relations between the various features. After the c axis direction in the grain was determined by precession X-ray analysis, the most important aeolian features were related to the crystallography of quartz. The upturned plates or cleavage plates probably represent traces parallel to r(10ī1) and z(01ī1) cleavages in quartz. Blocky areas appear to be an expression of a cleavage parallel to m(10ī0). In addition, plate spacing on thirty-five experimental, modern, and ancient quartz sand grains is fairly constant. Assuming that abrasion in most sedimentary environments acts in the same manner with respect to quartz crystallography, much of the fine silt and clay in sediments and sedimentary rocks may be the result of cleavage following abrasion parallel to the r and z cleavage planes, while the less common blocky particles are probably the result of cleavage parallel to the m planes.     

Aeolian to marine transition in Cambro—Ordovician cratonic sheet sandstones of the northern Mississippi valley, U.S.A.

Cratonic quartz sandstones have presented several intractable problems. Besides their extreme textural and compositional maturity and paucity of shale, their sheet-like geometry is particularly notable. If the sandstones were entirely marine, as long supposed, such geometry is difficult to explain in terms of modern shelf sediments, which are generally held to be either relict or only slightly reworked by the Holocene transgression (palimpsest). Re-study of two quartz sandstones in the northern Mississippi Valley region reveals evidence for significant non-marine deposition followed by varying degrees of marine reworking during transgressions. Facies patterns are similar in the Cambrian Wonewoc and Ordovician St Peter sandstones, both of which overlie unconformities. In both, a large-scale cross-stratified facies believed to represent aeolian ergs passes laterally into a planar-and-channelled facies inferred to represent sand plains composed of braided fluvial and aeolian sand sheet deposits. Criteria of aeolian deposition in both facies include adhesion structures, large ripple index, fine climbing translatent lamination, grainfall and grainflow stratification. Criteria of braided fluvial deposition include shallow channels containing sequences of thinning-upward sets of trough cross-stratification, reactivation surfaces, low-index ripples, and polygonal cracks. Probable aeolian sand sheets contain flat bedding punctuated by small channels, adhesion structures, and coarse-sand ripples with large index. There is a conspicuous absence of trace and body fossils from these inferred non-marine deposits. In contrast is a burrowed and trough cross-stratified facies characterized by medium-scale cross-bedding alternating with bioturbated intervals and rare brachiopod or trilobite-mould coquinas, which is interpreted as shallow marine. In both formations, this last facies replaces laterally and overlaps the other two, reflecting transgression and variable reworking. The main areas of non-marine deposits in both formations are capped by a thin, burrowed subfacies that represents the culmination of each transgression; that is, a stillstand during which sediment influx ceased and both physical winnowing and bioturbation were intense. It is suggested that the sheet-like geometry of many cratonic quartz sandstones is due primarily to initial sand dispersal by aeolian and fluvial processes. That such processes must have been orders-of-magnitude more important on pre-Devonian, vegetation-free landscapes than they have been since, not only helps to explain the sheet-like character but also the exceptional maturity of the older cratonic sandstones.     

Testing the auto‐abrasion hypothesis for dust production using diatomite dune sediments from the Bodélé Depression in Chad

This study examines the role of quartz sand in the production of dust using mixtures of quartz sand from the Sahara and diatomite aggregates from the Bodélé Depression in Chad. An aeolian abrasion chamber is used to reproduce the physical processes of aeolian abrasion and test the hypothesis that the breakdown of saltating diatomite flakes as they collide in saltation, and with the surface, is the most prolific mechanism of dust production (auto‐abrasion). This hypothesis is tested against the competing hypothesis that a hard, higher‐density quartz sand impactor is required to abrade fine‐grained sediments to generate dust. The results show that dust can be produced by a mixture of saltating diatomite and quartz sand particles. However, quartz sand is not required for saltating aggregates to produce dust. Indeed, these results, which used a mixture of very coarse‐grained aggregate (1 to 2 mm diameter) with fine quartz sand, indicate that the addition of quartz sand can decrease dust production. For a very coarse aggregate (1 to 2 mm), a pure diatomite aggregate produced the most dust, although using a coarse‐grained aggregate (0·5 to 1·0 mm) with a mixture of 20% quartz and 80% aggregate was found to produce the most dust overall. The results of this study confirm the auto‐abrasion hypothesis for the breakdown of diatomite particles in the Bodélé Depression, which is the single biggest source of atmospheric mineral dust on Earth.     

川西高原甘孜黄土的成因

本文通过对甘孜满地黄土的粒度组分、石英砂的表面结构以及其它地质现象的综合研究,对甘孜黄土的成因进行了探讨。在黄土的概率累计曲线上,跃进组分和悬移组分反映明显,并以悬移组分为主。悬移组分粒径小于2φ~3φ,并以粉砂(4φ~8φ)为主,占悬移总体的94%~99%;对甘孜黄土进行扫描电镜观察表明,石英砂大部分为块状颗粒,少量(10%)呈纺锤形。采用矩阵法计算甘孜黄土的粒度参数:黄土的平均粒径(d₅₀)为5.057φ~5.883φ,明显大于古土壤(6.120φ~6.549φ).古土壤的标准偏差(σφ)为1.513~1.973,大于黄土(1.205~1.778);黄土和古土壤的偏度系数(SKφ)为-0.088~0.248,显示为正偏或近于对称。黄土和古土壤的尖度系数(Kφ)分别为0.123~1.702、0.023~0.059,前者峰形窄,后者峰形较宽。对甘孜黄土扫描电镜观察表明,石英砂大部分为方形或长方形颗粒,少量(10%)呈纺锤形。石英砂有密集的翻卷片、蛇曲脊、圆麻坑,这些结构反映了风成特征。另方面,少量石英砂显示冰川作用结构,例如大大小小的贝壳状断口、平行擦痕等。在甘孜西面、德格以南的金沙江东岸川藏公路980km路碑处,三阶地上部的黄土层中,发现3条冰楔。此外,甘孜黄土中孢粉稀少。根据上述特征推断,甘孜黄土应为冰缘风成黄土。      

Generation of hydrogen ions and hydrogen gas in quartz–water crushing experiments: an example of chemical processes in active faults

To understand the fundamental chemical processes of fluid–rock interaction during the pulverization of quartz grains in fault zones, quartz grains were crushed within pure water. The crushing experiments were performed batch style using a shaking apparatus. The crushing process induced a decrease in pH and an increase in hydrogen gas with increased shaking duration. The amount of hydrogen ions generated was five times larger than that of the hydrogen gas, which was consistent with the amount of Si radicals estimated from electron spin resonance measurements by Hochstrasser and Antonini (1972). This indicates that hydrogen gas was generated by consuming most of the Si radicals. The generation of hydrogen ions was most likely related to the presence of silanols on the newly formed mineral surface, implying a change of proton activities in the fluid after pulverization of quartz.     

Oxygen isotopes in single micrometer-sized quartz grains: tracing the source of Saharan dust over long-distance atmospheric transport

Oxygen isotope compositions were measured by ion microprobe in individual micrometer-sized quartz grains extracted from one aerosol sample collected on the Cape Verde Islands and from four surface samples (three soils and one sediment) representing potential source regions of aerosols in Western and Central Africa (Morocco, Algeria, Niger, and Chad). A large range of δ¹⁸O values, from +6.2‰ to +39.3‰ is present within the aerosol quartz grains. The different size fractions of the quartz grains from the surface samples overlap nearly entirely this range but show significant differences in their δ¹⁸O distributions for the different size fractions of the grains (i.e., different modes, different proportions of grains with low or high δ¹⁸O, ...). These differences in δ¹⁸O distributions can be related to different geological formations (i.e., mantle-derived magmatic rocks, crustal magmatic rocks, or sedimentary rocks) outcropping in each region, thus giving a fingerprint of the source region. Quartz grains with unusually high δ¹⁸O values between +30‰ and +40‰ were attributed to lacustrine cherts formed in evaporitic environments (Chad basin).The existence of distinct δ¹⁸O distributions for the surface samples, which reflect regional geology but indicate some transport of the grains, enables the characterization of mixing processes during dust emission in the atmosphere. Particles are mixed at a regional scale in the dust reservoir, but injection of fine particles into the high troposphere occurs as a discrete and localized event with no mixing during the subsequent long-range transport by the easterlies. The comparison of the δ¹⁸O distribution of the quartz from the aerosol sample with the equivalent size fractions in surface samples shows that the Niger area is the more probable source region for the aerosol although the Moroccan source cannot be excluded. This method gives a valuable tool to trace the source region of dust into the atmosphere or into sediment samples, allowing the reconstruction of air mass circulations.     

First known Cretaceous glaciation: Livingston Tillite Member of the Cadna‐owie Formation,South Australia

A 2 m‐thick diamictite occurs near the base of the Cretaceous Eromanga Basin succession at Trinity Well, at the northern extremity of the Flinders Ranges in South Australia. The diamictite consists of a matrix of silt‐ and clay‐size particles and a framework of sand and coarser materials up to small boulder size. Scanning electron microscope study reveals the presence of numerous quartz grains displaying extreme angularity and surface textures attributed to glacial crushing. Sandy sediments considered as fluvioglacial in origin and a locally developed facies displaying flow structures attributed to solifluction processes constitute the basal 3–5 m of the sequence. In places these directly underlie the diamictite and rest with angularity on Neoproterozoic Adelaidean strata. Conformably above the diamictite at the type locality ‘Recorder Hill’ is a sequence approximately 15 m thick of fine sand and silt units containing lonestones up to ～70 cm diameter and hummocky cross‐stratification. These sediments have been assigned to the Cadna‐owie Formation and are dated on palynology as Berriasian to Valanginian. The occurrence of diamictite containing glacially affected quartz grains contributes to our interpretation that the southern margin of the Eromanga Basin, and at least the adjacent part of the northern Flinders Ranges, were affected by glaciation in the Early Cretaceous. The associated dropstone and solifluction facies and nearby glendonite pseudomorphs after ikaite are further evidence of at least intermittent cold climates at this time.