Variation of the chemical composition of sediments under middle- and low-temperature hydrothermal conditions in the southern trough of Guaymas Basin,Gulf of California: Communication 1. results of the study of bulk sediment samples

The paper presents the results of the study of variations in the content of macro- and microelements (rare earth elements included) in the Upper Pleistocene sediments from DSDP Hole 477. The variations took place at the depth interval 110–191 m in the course of temperature drop to about 100°C in the upper part of the hydrothermal system. Variations in the content of most chemical elements in sediments from DSDP Hole 477 are manifested more weakly than in the underlying sediments of the interval 191–267 m of DSDP Hole 477A that were altered at a temperature of about 300°C. For many chemical elements, influence of the sedimentary cover on the compositional transformation of solutions during their interaction with sediments attenuates with the cooling of its upper part to the point of its complete termination.     

Hydrothermal alterations of the chemical composition in grain size fractions of sediments in the Guaymas Basin,Gulf of California

The paper presents data on the contents of macro- and microelements (rare earth elements included) determined in grain size fractions of the Upper Pleistocene hydrothermally altered and unaltered sediments from the Guaymas Basin (Gulf of California). Sediments subjected to high-temperature hydrothermal alteration were recovered by DSDP Hole 477A. In the finely dispersed fractions, which are mainly composed of clay minerals, alteration of the chemical composition was provoked by the hydrothermal transformation of terrigenous clay minerals. The concentration of microelements in these fractions takes place primarily at the cost of the hydrothermal finely dispersed ore minerals. Alteration of the chemical composition of the coarse-grained fractions is related to the replacement of clastogenic minerals by the secondary varieties and the formation of new minerals (including ore minerals and native metals) from the solutions. Hydrothermal alterations of the chemical composition of bulk samples depend on the degree of chemical element concentration in fractions and their content in samples.     

Clay minerals in sediments of the hydrothermally active southern trough in the Guaymas Basin (Gulf of California)

The results of the study of clay mineral alterations in Upper Pleistocene sediments of the southern trough in the Guaymas Basin (Gulf of California) due to the influence of hydrothermal solutions and heat produced by sill intrusions are discussed. Core samples from DSDP Holes 477 and 477A were taken for the analysis of clay minerals. Application of the method of modeling X-ray diffraction patterns of oriented specimens of the finely dispersed particles made it possible to establish the phase composition of clay minerals, determine their structural parameters, and obtain reliable quantitative estimates of their contents in natural mixtures. The modeling data allowed us to characterize reliably the transformation of clay minerals in sediments of the hydrothermally active southern trough in the Guaymas Basin. In Upper Pleistocene sandy–clayey sediments of the southern trough, changes in the composition of clay minerals occurred under the influence of a long-living hydrothermal system. Its lower part (interval 170.0–257.5 m) with maximum temperatures (~300°C) was marked by the formation of chlorite. Terrigenous clay minerals are not preserved here. Saponite appears at a depth of 248 m in the chlorite formation zone. Higher in the sedimentary section, the interval 146–170 m is also barren of terrigenous clay minerals. Sediments of this interval yielded two newly formed clay minerals (chlorite and illite), which were formed at lower temperatures (above 180°C and below 300°C, approximately up to ~250°C), while the relatively low-temperature upper part (110–146 m) of the hydrothermal system (from ~140°C to ~180°C) includes the mixture of terrigenous and newly formed clay minerals. Terrigenous illite is preserved here. Illitization of the mixed-layer illite–smectite was subjected to illitization. The terrigenous montmorillonite disappeared, and chlorite–smectite with 5–10% of smectite layers were formed. In the upper interval (down to approximately 110 mbsf), the composition of terrigenous clay minerals remains unchanged. They are composed of the predominant mixed-layer illite–smectite and montmorillonite, the subordinate illite, mixed-layer chlorite–smectite with 5% of smectite layers, mixed-layer kaolinite–smectite with 30% of smectite layers, and kaolinite. This composition of clay minerals changed under the influence of sill intrusions into the sedimentary cover at 58–105 m in the section of Hole 477. The most significant changes are noted in the 8-m-thick member above the sill at 50–58 m. The upper part of this interval is barren of the terrigenous mixed-layer illite–smectite, which is replaced by the newly formed trioctahedral smectite (saponite). At the same time, the terrigenous dioctahedral smectite (montmorillonite) is preserved. The composition of terrigenous clay minerals remains unchanged at the top of the unit underlying the sill base.     

Holocene laminated sediments from the southern Gulf of California: geochemical,mineral magnetic and microfossil study

Geochemical, magnetic mineral analyses and microfossils (radiolarians) are used to characterise a Holocene laminated sequence from the Alfonso Basin, northern Bay of La Paz, southern Gulf of California. In most cases, dark and light laminae show similar bulk chemical compositions and magnetic mineral properties. However, dark laminae contain relatively more terrigenous elements (Al, Si, Fe, K and Mg) supporting a pluvial origin related to the volcanic siliceous tuffs around the Bay of La Paz. In light laminae, calcium content is higher, representing biogenic input. The magnetic signal is dominated by low coercivity, fine‐grained low‐titanium titanomagnetites and magnetite. Hysteresis ratio parameters in domain state plots show that samples fall in the pseudo‐single domain field, indicating mixtures of single‐ and multi‐domain particles. Variations in hysteresis saturation magnetisation parameters for dark and light laminae reflect changes in relative mineral concentration. Results indicate a dominant volcanic source for magnetic minerals into the basin, associated with variable pluvial and/or aeolian transport. Low radiolarian abundance in dark laminae seems to be associated with larger penetration and longer residence time of oligotrophic subtropical waters into the bay that occurred during El Niño–Southern Oscillation (ENSO) events. Light laminae are the result of episodic pulses of high productivity. We suggest that dark/light laminae result from oceanographic and climatic cyclic processes, with main terrigenous input variation possibly associated with ENSO forcing of pluvial influx, and/or latitudinal migration of the Intertropical Convergence Zone. The laminated sequence of the Alfonso Basin formed a non‐annual depositional system, in contrast to the varved sediments characteristic of the central Gulf of California basins. Copyright © 2010 John Wiley & Sons, Ltd.     

Influence of a turbidite deposit on the extent of pyritization of iron,manganese and trace metals in sediments from the Guaymas Basin,Gulf of California (Mexico)

A core collected in the Guaymas Basin contained an organic-poor, Mn oxide-rich and (relatively) Fe oxide-rich turbidite layer that affected the distribution of Fe, Mn, C, S and trace metals. Results indicate that sediments not influenced by the turbidite layer achieved a 100% degree of pyritization and, by extension, that pyrite production is Fe-limited in these sediments. In contrast, the mud slide layer apparently supplied enough reactive Fe to transfer essentially 98% of the total S present at the base of the turbidite (17–19 cm) to the pyrite reservoir. C/S ratios showed rapid decreases with depth, from a high of 38 close to the sediment-water interface, to minimum values of 2.8 at the lower limit of the turbidite layer, a ratio equal to the average C/S value of normal marine modern sediments, where concentrations of organic C and pyrite supposedly have attained quasi-steady values. A significant part of the reactive Mn was associated with carbonates (41±12%) and, to a much lower degree, with pyrite (2.7±1.2%). The turbidite layer is currently showing a depletion of Mn relative to the host sediment. It is possible that Mn, a major metal constituent in these sediments, was initially present in high concentrations in the mud slide, but was eventually mobilized and transferred either to the water column or to the sediments immediately below the turbidite layer. Metals associated with this element probably followed the same path, affecting their incorporation into pyrite. The turbidite layer apparently affected the distribution of most of the trace metals associated with pyrite, except maybe Cd, Pb and, to a certain, extent Cr. However, Cu, Cr, Zn, Ni and Co were all found to be highly pyritized (>80%) in the sediments of the Guaymas Basin.     

Pleistocene sediments of the eastern Barents Sea (Central Deep and Murmansk Bank): Communication 2. Lithological composition and formation conditions

Llithology of massive diamictons was studied in two areas of the eastern Barents Sea using cores and geophysical data. These sediments dominate in the Pleistocene section as two seismostratigraphic complexes (SSC): Upper Weichselian (SSC III) and locally distributed Lower Weichselian (SSC V). Diamictons of these complexes represent tills produced by the geological activity of the Pleistocene Novaya Zemlya and Scandinavian ice sheets. The Upper Weichselian glacial sequence is laterally heterogeneous. It includes two seismic facies represented by ordinary (overconsolidated) tills (they also constitute SSC V) and a spacious moraine of the specific type with the normally consolidated sediments (they avoided compaction by the ice load) and certain lithological specifics. The last glacial sediments were formed in a specific subglacial setting similar to the sediments under fast ice streams of Antarctica. However, the specific features allow us to define these sediments as a new (Barents Sea) facies of tills related to zones of intense basal melting of glaciers.     

Mineralogy,chemistry, and grain size composition of recent sediments in the northern Tyrrhenian Sea: Contribution to the study of sediment transport and distribution

As a contribution to an environmental study on Tuscany's marine shelf, textural, mineralogical, and chemical characteristics of recent sediments in the northern Tyrrhenian Sea between Elba Island and Livorno have been analyzed. The data provide clear information on sediment sources and movement patterns. The main sediment source appears to be the Cecina River; very subordinate is the contribution of the Fine River. As to sediment movement patterns, the surveyed basin appears to be divided into two subbasins: (1) a greater, southern subbasin, bounded by Tuscany mainland, Elba Island and Elba Ridge, and Capraia Isle, and Vada Shoals; and (2) a smaller, northern subbasin, enclosed between Vada Shoals and Meloria Shoals (off Livorno port).In the former the coarse-grade Cecina River sediments are transported southward along most of the mainland coast by littoral drift and coastal current; a northward flowing countercurrent seems to be active only in the southernmost part. Silts and clays are distributed in concentric belts around basin's central part, being transported mainly by slow circular water movements. In the marginal western zone, very little terrigenous influx is coupled with a high biologic productivity, and biogenic debris sedimentation prevails there.In the northern subbasin the sediment contribution from Fine River is more appreciable. Here the environmental energies are very low and the coarse sediments are restricted to a few small pocket beaches where they are deposited by local creeks. Most of the subbasin area is occupied by sapropelitic muds, again distributed by slow small-scale gyres.     

Effects of grain size distribution on mineralogical and chemical compositions: a case study from size‐fractional sediments of the Huanghe (Yellow River) and Changjiang (Yangtze River)

The influence of hydrodynamics on the chemical composition of sediments is based on the uneven distribution of element abundances in different size fractions. In this study, 72 size‐fractional sediments from the Huanghe (Yellow River) and Changjiang (Yangtze River) riverbeds were measured with XRD, SEM, ICP‐AES and ICP‐MS. The analysis results show that the mineral and chemical characteristics change with grain size in the Huanghe and Changjiang sediments. According to the principal components analysis, three independent geochemical factors were found. The first factor elements, Zr, Hf, Th, U, Y, La and TiO₂ are influenced by the existence of heavy minerals. The second factor elements, Al₂O₃, alkalis, alkaline earth (excluding Ca and Sr) and most of the transitional metals are dominated by clay minerals. The third factor group includes Ca and Sr, which were controlled by calcium‐bearing mineral contents and chemical weathering intensities. The various grain size distributions greatly affect the mineralogical and chemical compositions of bulk sediments. Compared to other size fractions, the 5–6PHI size fractions of the Huanghe and Changjiang sediments have special mineralogical and chemical compositions, and intermediate volume percentages. Weight or volume percentage of each size fraction may be more suitable than mean grain‐size of the bulk sediment to elucidate the grain size effects. Chemical Index of Alteration (CIA) values increase steeply with decreasing grain size, while Weathering Index of Parker (WIP) values are relatively stable. Because of the big influence of the abundance of clay minerals on CIA values, it is questionable to use CIA as a proxy of weathering intensity. Considering the clay mineral effects, stability in values and heterogeneous material properties, WIP has the potential to indicate the chemical weathering intensity of sediments. Copyright © 2014 John Wiley & Sons, Ltd.