Geochronology of Late Cenozoic volcanism in the area of Van Lake,Turkey: An example of development dynamics for magmatic processes

An isotope-geochronological study has been performed to examine the products of Late Cenozoic collision volcanism on the northern coast of Van Lake, Turkey. We obtained 45 new K-Ar dates, based on which the principal time characteristics of volcanic activity in the region have been determined. The total duration of magmatic activity in the area of the northern coast of Van Lake has lasted ∼15 myr; it has had an expressed discrete nature, when periods of intense volcanic activity alternated with lasting breaks in eruptions. Four stages of Neogene-Quaternary volcanism have been identified: Middle Miocene (15.0–13.5 myr), Late Miocene (10–9 myr), Pliocene (5.8–3.7 myr), and Quaternary (1.0–0.4 Ma). The average duration of the stages has been 1–2 myr; the stages were separated from each other with periods of inactivity of approximately equal lengths (∼3 myr). For each of the Pliocene and Quaternary stages, three additional phases of volcanism have been identified, which were separated from each other with short time intervals (a few hundred thousand years). The last burst of volcanic activity in the area in question took place ∼400 ka; similar to Quaternary volcanism in general, it was not characterized by a high intensity. An important result of the studies performed was to confirm the existence of a separate Middle Miocene stage of collision volcanism for the Caucasian-Anatolian Segment of the Alpine Fold Belt. The data generated allow concluding that Neogene-Quaternary volcanism in this portion of the belt started much earlier (∼15 Ma) than assumed by the majority of the previous researchers.     

Erratum: Geochronology of Late Cenozoic volcanism in the area of Lake Van,Turkey: An example of developmental dynamics for magmatic processes [Doklady earth sciences, 433(2), pp. 1031–1037]

An isotope-geochronological study has been performed to examine the products of Late Cenozoic collision volcanism on the northern coast of Lake Van, Turkey. We obtained 45 new K—Ar dates, based on which the principal time characteristics of volcanic activity in the region have been determined. Volcanic activity in the northern coast of Lake Van has lasted ∼15 myr; it has had an expressed discrete nature, when periods of intense volcanic activity alternated with long-lasting pose periods. Four stages of Neogene—Quaternary volcanism have been identified: Middle Miocene (15.0—13.5 Ma), Late Miocene (10—9 Ma), Pliocene (5.8—3.7 Ma), and Quaternary (1.0—0.4 Ma). The average duration of the stages was 1—2 myr; the stages were separated from each other with periods of inactivity of approximately equal lengths (∼3 myr). For each of the Pliocene and Quaternary stages, three additional phases of volcanism have been identified, which were separated from each other with short time intervals (a few hundred thousand years). The last burst of volcanic activity in the study area occurred ∼400 ka; similar to Quaternary volcanism in general, it was not characterized by a high intensity. An important result of the studies performed was to confirm the existence of a separate Middle Miocene stage of collision volcanism for the Caucasian—Anatolian Segment of the Alpine Fold Belt. New geochronological data generated presented in this paper indicate that Neogene—Quaternary volcanism in this portion of the belt started much earlier (∼15 Ma) than assumed by the majority of the previous researchers.     

Two stages of explosive volcanism of the Elbrus area: Geochronology,petrochemical and isotopic-geochemical characteristics of volcanic rocks,and their role in the neogene-quaternary evolution of the Greater Caucasus

The chronology of evolution of the young explosive volcanism in the Elbrus area of the Greater Caucasus is revealed. The isotopic-geochronological data indicate that ignimbrites and associated volcanic rocks were formed during the Middle Pliocene (3.0–2.75 Ma) and Early Pleistocene (0.84–0.70 Ma) stages of magmatic activity of the Greater Caucasus. The presence of two groups of pyroclastic rocks significantly different in age and analysis of their location indicate two spatially combined volcanic centers different in age in this part of the Elbrus volcanic area: Pliocene Tyrnyauz center localized in the eastern and southern parts and Quaternary Elbrus volcanic center which is the only newest center of volcanic activity both in the Elbrus and in the entire neovolcanic area. The analysis of chronology of magmatic events and compositional peculiarities of the young igneous rocks of the Elbrus area for the period from 3 Ma to the Holocene shows that the caldera stage of the evolution of the Elbrus Volcano has not come yet and future catastrophic magmatism is highly possible.     

Neogene–Quaternary Magmatism of the Çaldıran Plain and its Vicinity (Eastern Turkey): an Example of Post-Collisional Transition from Subduction to Intraplate Type

This paper is aimed at studying the chronological evolution of the Neogene–Quaternary volcanic activity within the Çald?ran plain and its mountainous framing (Eastern Turkey). It is shown that the last pulse of continental-margin magmatism related to the subduction and closure of Neotethys oceanic basin occurred in the Middle Miocene (13.5–12.5 Ma). The post-collision volcanism proceeding simultaneously with large-scale regional tectonic rearrangement and initiation of the long-term Çald?ran fault began in the Late Miocene (7–6 Ma), and reached maximum activity in the Middle Pliocene (4.7–3.6 Ma). The Quaternary period in the region evolution was marked by the abundant within-plate magmatic activity restricted to the regional SW–NE trending zone, and the formation of Eastern Turkey’s largest Tendürek shield volcano (Late Pleistocene–Holocene). Petrological-geochemical data indicate that magmas during the overall evolution of young volcanism of the Çald?ran plain was generated from a single mantle reservoir, whose composition gently one-way evolved with time. Calculations show that melting occurred in the upper part of the asthenosphere (immediately near the boundary with thinned lithospheric mantle), which was metasomatized by pre-existing long-continued subduction. The chemical variations of mantle source with time (from the Middle Miocene to Quaternary) were mainly determined by a decrease of subduction component and the presence of aqueous phases, with a general trend from E-MORB to OIB-type for generated magmas. The composition of Late Quaternary basic lavas of Tendürek Volcano in terms of most petrological-geochemical characteristics corresponds to within-plate alkaline basalts. The main trend of geochemical evolution of mantle source is correlated with a systematic change of the predominant serial affinity of igneous rocks from calcalkaline through moderately alkaline to Na-alkaline varieties. Discrete character of young magmatism within the Çald?ran plain, and its subsequent evolution (sulrasubduction → post-collision → within-plate) were mainly determined by periodical large-scale changes in geotectonic setting within the Eurasian–Arabian collision zone: (1) cessation of subduction, (2) break-up and deepening of oceanic slab with its subsequent break off, (3) inferred emergence of incipient rift setting under conditions of intense submeridional compression.     

Manifestations of miocene acid intrusive magmatism on the southern slope of the Greater Caucasus: First evidence from isotope geochronology

New isotope-geochronological data (K-Ar, Rb-Sr) provide tight geochronological constraints on the history of Late Cenozoic magmatism on the southern slope of the Greater Caucasus. Several previously unknown, rhyodacite intrusive bodies with an emplacement age of 6.9 ± 0.3 Ma (Late Miocene) are reported from the Kakheti-Lechkhumi regional fault zone in the Kvemo Svaneti-Racha area. Therefore, a pulse of acid intrusive magmatism took place in a period previously considered amagmatic in the Greater Caucasus. The petrological, geochemical, and isotopic data suggest that these rhyodacites are produced by crystallization differentiation of mantle-derived magmas, which are similar in composition to Miocene mafic lavas that erupted a few hundred thousand years later in the adjacent Central Georgian neovolcanic area. The presented results allow the conclusion that the volcanic activity within the Central Georgian neovolcanic area occurred at 7.2–6.0 Ma in two discrete pulses: (1) the emplacement of acid intrusions and (2) the eruption of trachybasaltic lavas. The emplacement of rhyodacite intrusions in the Kvemo Svaneti-Racha area marked the first pulse of young magmatism on the southern slope of the Main Caucasus range and simultaneously represented the second magmatic pulse (after granitoid magmatism of the Caucasian Mineral Waters region) within the entire Greater Caucasus.     

Early Pleistocene magmatism in the central part of the Greater Caucasus

An isotope-geochronological study of young magmatism in the central part of the Greater Caucasus (Kazbek neovolcanic area) on the territory of Russia and Georgia has been carried out. It was proved for the first time that, in the Early Pleistocene, there was a separate impulse of magmatic activity in this area. The area of endogenic activity for the period identified was contoured on the basis of the integrated isotope-geochronological, petrological-geochemical, and geological data. It has been shown that the Early Pleistocene volcanism inherits the area of Neogene volcanism in the Kazbek region and, therefore, presents the final impulse of the second (Pliocene) stage of the Late Cenozoic magmatism. Thus, Early Pleistocene volcanism was not a precursor of Late Quaternary magmatism as the latter has other spatial patterns of the location of volcanic centers.     

Mantle sources of the Cenozoic volcanic rocks of the Lake Kizi region in the eastern Sikhote Alin

The Middle Cenozoic lava sequence of the Lake Kizi region was studied. It characterizes the activity of sources in the Northern zone of the eastern Sikhote Alin: a Middle Eocene pulse of slab-related magmatism and prolonged injection of magmas from the sublithospheric convecting mantle in the Late Oligocene. Low contents of high field strength elements (Nb and Ta) with low Nb/Ta, Ce/Pb, and Nb/La and high K/Nb ratios and a low (⁸⁷Sr/⁸⁶Sr)₀ of 0.703399 were determined in a Middle Eocene dacite with an age of ∼43.5 Ma. Three phases of Late Oligocene volcanic eruptions were distinguished: (1) basaltic andesites (29–27 Ma), (2) basaltic trachyandesites and trachyandesites (27–24 Ma), and (3) andesites (∼23 Ma). The lavas of the first and third phases showed low Ce/Pb, Nb/La, and Ba/La and high K/Nb ratios, which are also characteristic of supraslab processes. The lavas of the second phase are shifted with respect to these ratios toward ocean island basalt compositions. The entire Late Oligocene volcanic sequence falls within a narrow range of the initial strontium isotope ratios, (⁸⁷Sr/⁸⁶Sr)₀, from 0.703661 to 0.703853. Such ratios are characteristic of volcanic and subvolcanic rocks with ages of ∼37, 31–23, and ∼16 Ma over the whole region of the Tatar Strait coast.     

The Ethiopian subcontinental mantle domains: geochemical evidence from Cenozoic mafic lavas

Summary Since the Cenozoic, Ethiopia was affected by a widespread volcanic activity related to the geodynamic evolution of the Afar triple junction. The plateau building phase was followed by the formation of the Main Ethiopian Rift (MER) accompanied by a bimodal volcanic activity in both the inner parts of the rift and its shoulders. Outside the rift, a concurrent volcanic activity occurred mainly along transversal tectonic lineaments, the most important of which is the Yerer-Tullu Wellel Volcano-Tectonic Lineament (YTVL) developing for ∼500 km westward of Addis Abeba. Scattered Pliocene – Quaternary volcanoes are reported also inside the plateau such as those out cropping nearby Lake Tana. Here we present the result of a study on carefully screened mafic lavas outcropping in two sectors located off-axis the MER, namely, the YTVL and the southern part of Lake Tana; and in one sector located in the southern tip of the MER close to Megado, in the Sidamo region. The screened samples are petrographically fresh and have SiO₂<52 wt.% and MgO>4 wt.%, to minimise crystal fractionation effects. Most of the samples belong to the Late Miocene – Quaternary volcanic activity of the East African Rift System (EARS), although a number of samples along the YTVL are representative of the Late Eocene – Early Miocene Ethiopian Volcanic Plateau flood basalts. The selected mafic lavas offer the opportunity to assess the geochemical diversity, if any, of the subcontinental mantle domains along the MER (Megado and the easternmost part of the YTVL) and in sectors far away from the MER (YTVL and Lake Tana). The samples have a wide compositional range: from basanite to alkali basalt, hy-normative basalt, qz-normative basalt, basaltic andesite, hawaiite, trachybasalt, and trachyandesite. The major and trace element characteristics of the mafic lavas demonstrate an origin from a relatively fertile and trace element enriched lithospheric mantle at pressure variable from ∼2.0 to 3.5 GPa. Moreover, systematic variations in K/Nb, Ba/Nb, and Ba/Rb demand for the contribution of trace amounts of phlogopite to melt production. The geochemical signature coupled with the geographical distribution of the Late Miocene – Quaternary samples along the YTVL (∼500 km) and the Lake Tana and Megado sectors set constraints on a relatively homogenous lateral continuity of the deeper lithospheric mantle domains (∼2–3.5 GPa). On the other hand, the trace element characteristics of the Ethiopian Volcanic Plateau samples along the YTVL, demand for a chromatographic process en route to the surface and indicate a shallower lithospheric mantle domain (<2 GPa) with a different geochemical signature. Overall, the selected mafic lavas provide evidence for vertically zoned lithospheric mantle domains: the shallower domain (<2 GPa) consists of an enriched mantle component with a geochemical signature similar to continental crust material (EM II), whilst the deeper domain (∼2–3.5 GPa) consists of an enriched component similar to the average composition of the subcontinental lithospheric mantle (SCLM). Supplementary material to this paper is available in electronic form at Appendix available as electronic supplementary material     

Neotectonics of East Anatolian Plateau (Turkey) and Lesser Caucasus: implication for transition from thrusting to strike-slip faulting

The east Anatolian plateau and the Lesser Caucasus are characterised and shaped by three major structures: (1) NW- and NE-trending dextral to sinistral active strike-slip faults, (2) N-S to NNW-trending fissures and /or Plio-Quaternary volcanoes, and (3) a 5-km thick, undeformed Plio-Quaternary continental volcano-sedimentary sequence accumulated in various strike-slip basins. In contrast to the situation in the east Anatolian plateau and the Lesser Caucasus, the Transcaucasus and the Great Caucasus are characterised by WNW-trending active thrust to reverse faults, folds, and 6-km thick, undeformed (except for the fault-bounded basin margins) continuous Oligocene-Quaternary molassic sequence accumulated in actively developing ramp basins. Hence, the neotectonic regime in the Great Caucasus and the Transcaucasus is compressional–contractional, and Oligocene-Quaternary in age; whereas it is compressional–extensional, and Plio-Quaternary in age in the east Anatolian plateau and the Lesser Caucasus.Middle and Upper Miocene volcano-sedimentary sequences are folded and thrust-to-reverse-faulted as a result of compressional–contractional tectonic regime accompanied by mostly calc-alkaline volcanic activity, whereas Middle Pliocene-Quaternary sequences, which rest with angular unconformity on the pre-Middle Pliocene rocks, are nearly flat-lying and dominated by strike-slip faulting accompanied by mostly alkali volcanic activity implying an inversion in tectonic regime. The strike-slip faults cut and displace dykes, reverse to thrust faults and fold axes of Late Miocene age up to maximum 7 km: hence these faults are younger than Late Miocene, i.e., these formed after Late Miocene. Therefore, the time period between late Serravalian (∼ 12 Ma) continent–continent collision of Arabian and Eurasian plates and the late Early Pliocene inversion in both the tectonic regime, basin type and deformation pattern (from folding and thrusting to strike-slip faulting) is here termed as the Transitional period.Orientation patterns of various neotectonic structures and focal mechanism solutions of recent earthquakes that occurred in the east Anatolian plateau and the Caucasus fit well with the N–S directed intracontinental convergence between the Arabian plate in the south and the Eurasian plate in the north lasting since Late Miocene or Early Pliocene in places.     

Geochronology of Pliocene volcanism in the Dzhavakheti Highland (the Lesser Caucasus). Part 2: Eastern part of the Dzhavakheti Highland. Regional geological correlation

The results of isotopic-geochronological study of the Pliocene volcanic rocks in reference sections and volcanic edifices of eastern part of the Dzhavakheti Highland (the northwestern Lesser Caucasus) are considered. The isotopic-geochronological data obtained here are correlated with data on western part of the Dzhavakheti Highland, which have been considered in previous part of this work. Based on correlation, time spans of principal volcanic events of the Pliocene in the study region as a whole are determined, and general trends of the young magmatism evolution within the region are established. In sum, the isotopic-geochronological dates evidence that the Pliocene magmatism of the Dzhavakheti Highland developed practically without essential breaks during the period of about 2 Ma long, from 3.75 to 1.75–1.55 Ma ago. The areal basic volcanism that was most widespread at that time is divisible into five discrete phases according to the isotopic dates obtained. Comparatively short pauses, which separated these phases of magmatic activity, were a few hundreds thousand years long, not more. Chemical composition of moderately acidic to silicic volcanics, which are of a limited distribution in the Dzhavakheti Highland, and their age relations with basic lavas of the region suggest that they are most likely the differentiation products of parental basic mantle-derived magmas. The analyzed distribution of volcanic centers, which erupted basic lavas of the Dzhavakheti Highland, evidence that first two phases of basic magmatism were connected here with volcanic activity in southwestern part of the region (northern termination of the Egnakhag Ridge), whereas activity of volcanoes situated on the east, predominantly in water-shed part and on slopes of the submeridional Dzhavakheti Ridge, controlled development of the third and fourth phases. Consequently, magmatic activity of the Pliocene stage in history of the Neogene-Quaternary magmatism of the Dzhavakheti Highland laterally migrated from the west to the east, being controlled by development of regional submeridional extension zones. Volcanic ridges marking the latter are formed by volcanic edifices, which are amalgamated at their bases and have erupted lavas of close age and composition. The migration of volcanic activity can be described in terms of the “domino effect,” when cessation of volcanism in one zone led to formation of the other submeridional zone of extension and magmatic activity displaced from the west eastward in sublatitudinal direction. In general, evolution of the Pliocene magmatism of the Dzhavakheti Highland, was similar, despite the essential regional peculiarities, to the generalized trend of magmatism evolution in the continental rifts and intraplate zones of the “hot-spot” type.     

Geochronology of eruptions and parental magma sources of Elbrus volcano,the Greater Caucasus: K-Ar and Sr-Nd-Pb isotope data

Complex geochronological and isotope-geochemical studies showed that the Late Quaternary Elbrus volcano (Greater Caucasus) experienced long (approximately 200 ka) discrete evolution, with protracted periods of igneous quiescence (approximately 50 ka) between large-scale eruptions. The volcanic activity of Elbrus is subdivided into three phases: MiddleNeopleistocene (225–170 ka), Late Neopleistocene (110–70 ka), and Late Neopleistocene-Holocene (less than 35 ka). Petrogeochemical and isotope (Sr-Nd-Pb) signatures of Elbrus lavas point to their mantle-crustal origin. It was shown that hybrid parental magmas of the volcano were formed due to mixing and/or contamination of deep-seated mantle melts by Paleozoic upper crustal material of the Greater Caucasus. Mantle reservoir that participated in the genesis of Elbrus lavas as well as most other Neogene-Quaternary magmatic rocks of Caucasus was represented by the lower mantle “Caucasus” source. Primary melts generated by this source in composition corresponded to K-Na subalkali basalts with the following isotopic characteristics: ⁸⁷Sr/⁸⁶Sr = 0.7041 ± 0.0001, ƒ_Nd = +4.1 ± 0.2, ¹⁴⁷Sm/¹⁴⁴Nd = 0.105–0.114, ²⁰⁶Pb/²⁰⁴Pb = 18.72, ²⁰⁷Pb/²⁰⁴Pb = 15.62, and ²⁰⁸Pb/²⁰⁴Pb = 38.78. The temporal evolution of isotope characteristics for lavas of Elbrus volcano is well described by a Sr-Nd mixing hyperbole between “Caucasus” source and estimated average composition of the Paleozoic upper crust of the Greater Caucasus. It was shown that, with time, the proportions of mantle material in the parental magmas of Elbrus gently increased: from ∼60% at the Middle-Neopleistocene phase of activity to ∼80% at the Late Neopleistocene-Holocene phase, which indicates an increase of the activity of deep-seated source at decreasing input of crustal melts or contamination with time. Unraveled evolution of the volcano with discrete eruption events, lacking signs of cessation of the Late Neopleistocene-Holocene phase, increasing contribution of deep-seated mantle source in the genesis of Elbrus lavas with time as deduced from isotope-geochemical data, as well as numerous geophysical and geological evidence indicate that Elbrus is a potentially active volcano and its eruptions may be resumed. Possible scenarios were proposed for evolution of the volcano, if its eruptive activity were to continue.     

Geochemistry and geochronology of the mafic lavas from the southeastern Ethiopian rift (the East African Rift System): assessment of models on magma sources,plume–lithosphere interaction and plume evolution

Major and trace element and isotopic ratios (Sr, Nd and Pb) are presented for mafic lavas (MgO > 4 wt%) from the southwestern Yabello region (southern Ethiopia) in the vicinity of the East African Rift System (EARS). New K/Ar dating results confirm three magmatic periods of activity in the region: (1) Miocene (12.3–10.5 Ma) alkali basalts and hawaiites, (2) Pliocene (4.7–3.6 Ma) tholeiitic basalts, and (3) Recent (1.9–0.3 Ma) basanite-dominant alkaline lavas. Trace element and isotopic characteristics of the Miocene and Quaternary lavas bear a close similarity to ocean island basalts that derived from HIMU-type sublithospheric source. The Pliocene basalts have higher Ba/Nb, La/Nb, Zr/Nb and ⁸⁷Sr/⁸⁶Sr (0.70395–0.70417) and less radiogenic Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 18.12–18.27) relative to the Miocene and Quaternary lavas, indicative of significant contribution from enriched subcontinental lithospheric mantle in their sources. Intermittent upwelling of hot mantle plume in at least two cycles can explain the magmatic evolution in the southern Ethiopian region. Although plumes have been originated from a common and deeper superplume extending from the core–mantle boundary, the diversity of plume components during the Miocene and Quaternary reflects heterogeneity of secondary plumes at shallower levels connected to the African superplume, which have evolved to more homogeneous source.     

Formation of the Late Cenozoic volcanic complexes of the Lesser Caucasus

The paper considers the role of the lithospheric mantle and asthenosphere during the Late Cenozoic collision volcanism of the Lesser Caucasus. The results of petrogeochemical studies show that the products of volcanism of the West Volcanic Zone of Armenia and the calc-alkaline andesite–dacite–rhyodacite complex of the Neogene Kelbadzhar and Karabakh plateaus were formed from an enriched source in a suprasubduction setting. Late Pliocene–Quaternary moderately alkaline and alkaline volcanic rocks of the Lesser Caucasus differ in petrogeochemistry from suprasubduction volcanic rocks. In trace element contents and patterns, they are similar to rocks formed from an enriched mantle source. Comparative analysis of the geological and geophysical data suggests the model of lithospheric slab break-off of the thickened lithosphere as the triggering mechanism for Late Cenozoic magmatism of the Lesser Caucasus.     

The structure of the Monte Amiata volcano-geothermal area (Northern Apennines, Italy): Neogene-Quaternary compression versus extension

The tectonic evolution of the Mt Amiata volcano-geothermal area is under discussion. Some authors state that this region, as well as the hinterland of the Northern Apennines, were affected by compression from the Cretaceous to the Quaternary. In contrast, most authors believe that extension drove the tectonic evolution of the Northern Apennines from the Early Miocene to the Quaternary. Field data, seismic analyses and borehole logs have been integrated in order to better define the structural features of the continental crust in the Mt Amiata geothermal area. In this paper I propose the hypothesis that the structure of the crust in the Mt Amiata volcano-geothermal area derives from two main geological processes: (1) contractional tectonics related to the stacking of the Northern Apennines (Cretaceous–Early Miocene), (2) subsequent extensional collapse of the hinterland of the mountain chain, and related opening of the Northern Tyrrhenian Sea (Early Miocene–Quaternary). Compressional and extensional structures characterise the Mt Amiata region, although extensional structures dominate its geological framework. In particular the extension produced: (a) Middle-Late Miocene boudinage of the previously stacked tectonic units; (b) Pliocene–Quaternary normal faulting which favoured the emplacement of a magmatic body in the middle-upper crust; and (c) the eruption of the Mt Amiata volcano, which gave rise to an acid and intermediate volcanic complex (0.3–0.19 Ma). The extension produced the space necessary to accommodate the Middle-Late Miocene marine and continental sediments. Pliocene and Quaternary normal and transtensional faults dissected the previous structures and influenced the Early Middle Pliocene marine sedimentation within the structural depressions neighbouring the Mt Amiata volcano. The magmatic body was emplaced at depth (about 6–7 km) during the Pliocene extension, and produced the eruption of the Mt Amiata volcano during the Late Pleistocene. This gave rise to local uplift, presently reaching about 3,000 m, as well as a negative Bouguer anomaly (−16 mgal), both centred on the Mt Amiata area. The crustal dome shows a good correspondence with the convex shape of the regional seismic marker known as the K-horizon, which corresponds to the 450°C isotherm, and the areas with greatest heat flow. This is probably a consequence of the above-cited magmatic body presently in the process of solidification. A Late Pleistocene eruption occurred along a crustal fissure striking N50° (Mt Amiata Fault), which crosscuts the crustal dome. Hydrothermal circulation, proven by the occurrence of thermal springs and gas vents (mainly CO₂ and H₂S), mainly occurs along the Mt Amiata Fault both in the northeastern ans southwestern sides of the volcano.     

K-Ar dating of quaternary volcanics: Methodology and interpretation of results

The K-Ar method and its modifications play a unique role in the geochronology of young volcanic rocks, which has important fundamental and economic aspects. This method provides an opportunity for dating Quaternary rocks, from the oldest (1–2 Ma) to the most recent ones (<30 ka). This paper discusses physical and geochemical prerequisites for the use of the K-Ar method in the solution of this problem. The key factor providing favorable proportions of radiogenic and nonradiogenic ⁴⁰Ar for the K-Ar system in volcanic rocks is the low solubility of argon (0.n–0.0n ppb) in silicate melts and crystallizing rocks and minerals. The sources and controlling factors of errors in the K-Ar dating of young rocks were evaluated in detail. The main analytical problem in the K-Ar dating of young rocks is concerned with the conditions and methods of measurements of very low (0.0n–0.00n ppb) contents of radiogenic ⁴⁰Ar accompanied by much higher (by a factor of 3–10 or even more) contents of nonradiogenic ⁴⁰Ar. The main stages in the development of the K-Ar method in Russia and other countries that provided a solution to this problem are described. We describe the analytical mass spectrometer system and method designed in the Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, which allowed us to carry out for the first time in Russia systematic studies on the geochronology of Quaternary volcanics up to late Pleistocene-Holocene age. The main characteristics of the method are the absolute sensitivity of measurements (5 × 10^?3 A/Torr) and background signal levels for argon isotopes (3 × 10^?3 ng ⁴⁰Ar and 1 × 10^?5 ng ³⁶Ar). The problems of excess radiogenic argon and variations in the initial ⁴⁰Ar/³⁶Ar ratio in young volcanics are discussed. The results of an investigation of the distribution of K-Ar isotopes among various constituents of young volcanics and the corresponding approach to the choice of material (geochronometer) for analysis are presented. This approach is illustrated by the example of geochronological results for three volcanic centers of the Caucasus differing in the time of occurrence and duration of the active phase: Elbrus, Samsari, and Aragats. A tentative regional time scale was proposed for Neogene-Quaternary magmatic events. This scale generalized the available data for the Greater and Lesser Caucasus and embraces the period from the late Miocene (8.5 Ma) to the late Neopleistocene-Holocene (<35 ka). An interesting feature of the young magmatism of the Caucasus is the synchronous occurrence of distinctive types of volcanic activity in particular volcanic areas. An important prognostic aspect related to the proposed time scale of the young magmatism of the Caucasus is the evidence that the most recent stage of volcanic activity, the youngest occurrences of which were dated at a few thousands to tens of thousands of years, is not yet finished.     

Neotectonics of East Anatolian Plateau (Turkey) and Lesser Caucasus: implication for transition from thrusting to strike-slip faulting

Abstract

The east Anatolian plateau and the Lesser Caucasus are characterised and shaped by three major structures: (1) NW- and NE-trending dextral to sinistral active strike-slip faults, (2) N-S to NNW-trending fissures and /or Plio-Quatemary volcanoes, and (3) a 5-km thick, undeformed Plio-Quatemary continental volcanosedimentary sequence accumulated in various strike-slip basins. In contrast to the situation in the east Anatolian plateau and the Lesser Caucasus, the Transcaucasus and the Great Caucasus are characterised by WNW-trending active thrust to reverse faults, folds, and 6-km thick, undeformed (except for the fault-bounded basin margins) continuous Oligocene-Quaternary molassic sequence accumulated in actively developing ramp basins. Hence, the neotectonic regime in the Great Caucasus and the Transcaucasus is compressional-contractional, and Oligocene-Quaternary in age; whereas it is compressional-extensional, and Plio-Quatemary in age in the east Anatolian plateau and the Lesser Caucasus.

Middle and Upper Miocene volcano-sedimentary sequences are folded and thrust-to-reverse-faulted as a result of compressional- contractional tectonic regime accompanied by mostly calc-alkaline volcanic activity, whereas Middle Pliocene-Quaternary sequences, which rest with angular unconformity on the pre-Middle Pliocene rocks, are nearly flat-lying and dominated by strike-slip faulting accompanied by mostly alkali volcanic activity implying an inversion in tectonic regime. The strike-slip faults cut and displace dykes, reverse to thrust faults and fold axes of Late Miocene age up to maximum 7 km: hence these faults are younger than Late Miocene, i.e., these formed after Late Miocene. Therefore, the time period between late Serravalian (~ 12 Ma) continent-continent collision of Arabian and Eurasian plates and the late Early Pliocene inversion in both the tectonic regime, basin type and deformation pattern (from folding and thrusting to strike-slip faulting) is here termed as the Transitional period.

Orientation patterns of various neotectonic structures and focal mechanism solutions of recent earthquakes that occurred in the east Anatolian plateau and the Caucasus fit well with the N-S directed intracontinental convergence between the Arabian plate in the south and the Eurasian plate in the north lasting since Late Miocene or Early Pliocene in places. © 2001 Éditions scientifiques et médicales Elsevier SAS     

Relationships between Volcanism, Hydrothermal Alteration and Epithermal Gold-Silver Mineralization in the Muka Mine Area in the Kitami Metallogenic Province, Hokkaido, Japan

Abstract: Neogene magmatism in the Muka mine area in the Kitami metallogenic province was characterized on the basis of K-Ar age data by felsic–to–mafic terrestrial extrusive and intrusive volcanism from Late Miocene to Early Pliocene. The geology of the Muka mine area comprises the Upper Cretaceous-Paleocene Yubetsu Group, consisting primarily of sandstone and shale; Upper Miocene Ikutahara Formation, consisting of clastic and felsic volcaniclastic rocks and Kane-hana Lava (rhyolite) of 7. 5 Ma; Upper Miocene Yahagi Formation, consisting of clastics, felsic volcaniclastics and rhyolite lavas; Late Miocene andesite and rhyolite dikes (Chidanosawa Rhyolite of 7. 2 Ma and Hon-Mukagawa Andesite of 6. 6 Ma); Lower Pliocene Hakugindai Lava (basalt: 4. 0 Ma); and Quaternary System. The volcanism consists of earlier Late Miocene felsic extrusive activity during the sedimentation of the Ikutahara Formation, later Late Miocene felsic extrusive and intrusive activities during the sedimentation of the Yahagi Formation and intermediate intrusive activity after the sedimentation of the Yahagi Formation and Early Pliocene mafic extrusive activity. The Muka gold-silver ore deposit occurs primarily in the felsic volcaniclastic rocks and Kanehana Lava of the Ikutahara Formation and in Hon-Mukagawa Andesite. These wall–rocks, the clastic rocks of the Ikutahara Formation and the clastic and felsic volcaniclastic rocks of the Yahagi Formation were affected to various extents by hydrothermal alteration. The hydrother-mal alteration can be divided into two stages (early and late) based on the modes of occurrence and mineral assemblages. Early hydrothermal alteration is characterized by regional and vein-related alterations associated with epithermal gold-silver mineralization in a near-neutral hydrothermal system. Regional alteration can be subdivided into a zeolite zone (mordenite+adularia±heulandite–clinoptilolite series mineral±smectite±quartz°Cristobalite±opal–CT) and a smectite zone (smec–tite±quartz±opal–CT). Vein-related alteration can be subdivided into a K-feldspar zone (quartz+adularia±illite±interstratified illite/smectite±pyrite), an illite zone (quartz+illite°Chlorite±interstratified illite/smectite±smectite±pyrite) and an interstratified illite/smectite zone (quartz+interstratified illite/smectite±smectite±pyrite). The adularization age of 6. 8 Ma in the K-feldspar zone that developed in Kanehana Lava hosting ore veins coincides well with the epithermal gold-silver mineralization age of 6. 6 Ma. Late hydrothermal alteration is characterized by a kaolinite zone (kaolinite±dickite±alunite±quartz°Cristobalite± tridymite±pyrite) in an acid hydrothermal system, and cuts early alteration zones such as the K-feldspar zone. Other modes of occurrence of acid alteration are a 7Å halloysite-kaolinite vein in the hydrothermal explosion breccia dike and smectite–kaoli–nite veins along joint planes of Kanehana Lava. The style of the gold-silver deposit associated with early near-neutral hydrothermal alteration is a low-sulfidation epithermal type. The low-sulfidation epithermal gold-silver mineralization of 6. 6 Ma in the vicinity of the Muka ore deposit was essentially accompanied by felsic volcanic activity during the sedimentation of the Yahagi Formation, and was closely related both temporally and spatially to the felsic intrusive activity of Chidanosawa Rhyolite of 7. 2 Ma. The related hydrother-mal activity of the gold-silver mineralization took place at intervals of approximately 0. 4–0. 6 Ma after the volcanic activity related to the mineralization.     

Geological structure of the Kashevarov Trough (central Sea of Okhotsk)

This paper reports the composition and age of rocks dredged from the Kashevarov Trough (central Sea of Okhotsk) during cruise 41 of the R/V Akademik M.A. Lavrentyev in 2006. It was found that the Late Cretaceous and Eocene volcanics from the Kashevarov Trough and Okhotsk-Chukotka volcanic belt, structures of which are traceable in the Sea of Okhotsk, have similar petrographic and geochemical features. The Cenozoic sedimentary cover consists of three different-age complexes: (1) the late Oligocene (∼28.2–24.0 Ma); (2) the terminal late Oligocene-early Miocene (24.0–20.3 Ma); (3) the terminal late Pliocene-early Pleistocene (2.0–1.0 Ma). The upper Oligocene-lower Miocene sediments were deposited in relatively shallow-water settings, whereas the late Pliocene-early Pleistocene complex was formed in deeper environments, which was probably determined by tectonic processes. The geological data indicate that the Kashevarov Trough and the surrounding underwater rises represented in the Oligocene-early Miocene a single shelf zone of the Sea of Okhotsk, which is underlain by a structurally integral Mesozoic basement and is now subsided to depths of 800–1000 m.     

Post-Collisional Transition from Subduction- to Intraplate-type Magmatism in the Westernmost Mediterranean: Evidence for Continental-Edge Delamination of Subcontinental Lithosphere

Post-collisional magmatism in the southern Iberian and northwesternAfrican continental margins contains important clues for theunderstanding of a possible causal connection between movementsin the Earth's upper mantle, the uplift of continental lithosphereand the origin of circum-Mediterranean igneous activity. Systematicgeochemical and geochronological studies (major and trace element,Sr–Nd–Pb-isotope analysis and laser ⁴⁰Ar/³⁹Ar-agedating) on igneous rocks provide constraints for understandingthe post-collisional history of the southern Iberian and northwesternAfrican continental margins. Two groups of magmatic rocks canbe distinguished: (1) an Upper Miocene to Lower Pliocene (8·2–4·8Ma), Si–K-rich group including high-K (calc-alkaline)and shoshonitic series rocks; (2) an Upper Miocene to Pleistocene(6·3–0·65 Ma), Si-poor, Na-rich group includingbasanites and alkali basalts to hawaiites and tephrites. Maficsamples from the Si–K-rich group generally show geochemicalaffinities with volcanic rocks from active subduction zones(e.g. Izu–Bonin and Aeolian island arcs), whereas maficsamples from the Si-poor, Na-rich group are geochemically similarto lavas found in intraplate volcanic settings derived fromsub-lithospheric mantle sources (e.g. Canary Islands). The transitionfrom Si-rich (subduction-related) to Si-poor (intraplate-type)magmatism between 6·3 Ma (first alkali basalt) and 4·8Ma (latest shoshonite) can be observed both on a regional scaleand in individual volcanic systems. Si–K-rich and Si-poorigneous rocks from the continental margins of southern Iberiaand northwestern Africa are, respectively, proposed to havebeen derived from metasomatized subcontinental lithosphere andsub-lithospheric mantle that was contaminated with plume material.A three-dimensional geodynamic model for the westernmost Mediterraneanis presented in which subduction of oceanic lithosphere is inferredto have caused continental-edge delamination of subcontinentallithosphere associated with upwelling of plume-contaminatedsub-lithospheric mantle and lithospheric uplift. This processmay operate worldwide in areas where subduction-related andintraplate-type magmatism are spatially and temporally associated. KEY WORDS: post-collisional magmatism; Mediterranean-style back-arc basins; subduction; delamination; uplift of marine gateways