Daily availability of nutrients and metals in a eutrophic meso-tidal coastal lagoon (Óbidos lagoon, Portugal)

This baseline reports daily variations of physico-chemical parameters, nutrients and metals in water of two sites [eutrophic conditions (BB) versus reference (LL)] in Óbidos coastal lagoon (Portugal). Dissolved oxygen in BB varied between 40% saturation levels (night) and 190% (daylight). , and ratios to Al of Mn, Fe and Pb in suspended particulate matter increased during the period of lower oxygenation, indicating exportation of nutrients and metals from the sediment to water at night. At LL, O₂ values oscillated always around 100%. and Mn/Al ratio at LL were always lower than at BB and no increases were found during the night. The input of and Mn provided from the sediment at BB during the night could surpass the contribution of freshwater discharges. PCA confirmed the separation of most samples from BB and LL. These results pointed to the importance of assessing chemical conditions over day-night cycles.     

Grain-growth kinetics in wadsleyite: Effects of chemical environment

Grain-growth kinetics in wadsleyite was investigated using a multianvil high-pressure apparatus. Fine-grained wadsleyite aggregates were synthesized by isostatic hot-pressing and were subsequently annealed under high pressure and temperature in a controlled chemical environment. Wadsleyite samples show normal grain-growth characterized by a log-normal grain-size distribution following the relation, where n is a constant, L the grain-size at time t, L₀ the grain-size at time t = 0 and k is a rate constant that depends on temperature T and chemical environments (fO₂: oxygen fugacity in Pa, C_OH: water content in H/10⁶Si) as:

     

Source parameters and scaling relationships in the Friuli-Venezia Giulia (Northeastern Italy) region

We estimated the source parameters of 53 local earthquakes (2.0<M_L<5.7) of the Friuli-Venezia Giulia (Northeastern Italy) area, recorded by the short-period local seismic network of the Istituto Nazionale di Oceanografia e Geofisica Sperimentale (OGS), in the period 1995-2003. Data were selected on the basis of high quality locations and focal mechanisms. Standard H/V spectral ratios (HVRS) of the three-component stations of the network were performed in order to assess local amplifications, and only stations showing HVRS not exceeding two were considered for the source parameters estimation. Both velocity and acceleration data were used to compute the SH-wave spectra. Observed spectra were corrected for attenuation effects using an independent regional estimate of the quality factor Q and a station dependent estimate of the spectral decay parameter k. Only earthquakes with M_L>3.0 recorded with a sampling rate of 125 cps were used to compute k, thus allowing to visualize a linear trend of the high frequency acceleration spectrum up to 40-50 Hz. SH-wave spectra, corrected for attenuation, showed an ω⁻² shape allowing a good fit with the Brune model. Seismic moments and Brune radii ranged between 1.5×10¹² and 1.1×10¹⁷  N m and between 0.1 and 2.7 km respectively. We obtained M_o=1.1×10¹⁷  N m for the seismic moment of the Kobarid (SLO) main shock, in good agreement with the Harvard CMT solution (M_o=3.5×10¹⁷  N m). Brune stress drops were confined to the range from 0.07 to 5.31 MPa, with an average value of 0.73 MPa and seem to be approximately constant over five orders of magnitude of seismic moment. Radiated seismic energy computed from two nearby stations scales with seismic moment according to , and apparent stress values are between 0.02 and 4.26 MPa. The observed scatter of Brune stress drop data allowed to hypothesize a scaling relation between seismic moment and corner frequency in order to accommodate both Brune stress drop and apparent stress scalings. No systematic differences are evidenced between stress parameters of earthquakes with different focal mechanisms. As a consequence, a relation of the seismic stress release with the strength of rocks can be hypothesized. A high correlation (r>0.9) of Brune stress drop is found with both apparent stress and RMS stress drop, according to and respectively.     

Comparison of Galerkin-type discretization techniques for two-phase flow in heterogeneous porous media

A comparison of Standard Galerkin, Petrov-Galerkin, and Fully-Upwind Galerkin methods for the simulation of two-phase flow in heterogeneous porous media is presented. On the basis of the coupled pressure-saturation equations, a generalized formulation for all three finite element methods is derived and analysed. For flow in homogeneous media, the Petrov-Galerkin method gives excellent results. But this method fails miserably for problems with heterogeneous media. This is because it is not able to capture correctly processes that take place at interfaces when, for instance, the capillary pressure-saturation relationship after Brooks and Corey is assumed. The Fully-Upwind Galerkin method is superior to the Petrov-Galerkin approach because it is able to give correct results for flow in homogeneous and heterogeneous media for the two models of van Genuchten and Brooks-Corey. The widely used formulation which is correct for the homogeneous case cannot be used for heterogeneous media. Instead the straightforward approach of gradp_c in combination with a chord-slope technique must be utilized.