The July 2007 rock and ice avalanches at Mount Steele, St. Elias Mountains, Yukon, Canada

A large rock and ice avalanche occurred on the north face of Mount Steele, southwest Yukon Territory, Canada, on July 24, 2007. In the days and weeks preceding the landslide, several smaller avalanches initiated from the same slope. The ice and rock debris traveled a maximum horizontal distance 5.76 km with a maximum vertical descent of 2,160 m, leaving a deposit 3.66 km² in area on Steele Glacier. The seismic magnitude estimated from long-period surface waves (M _s) is 5.2. Modeling of the waveforms suggests an estimated duration of approximately 100 s and an average velocity of between 35 and 65 m/s. This landslide is one of 18 large rock avalanches known to have occurred since 1899 on slopes adjacent to glaciers in western Canada. We describe the setting, reconstruct the event chronology and present a preliminary characterization of the Mount Steele ice and rock avalanches based on field reconnaissance, analysis of seismic records and an airborne LiDAR survey. We also present the results of a successful dynamic simulation for the July 24 event.     

Mid-Holocene lateral collapse of Antuco volcano (Chile): debris avalanche deposit features,emplacement dynamics,and impacts

Antuco (37.4°S, 71.4°W; Chile) is a dominantly basaltic stratovolcano whose original?~?3300 m altitude main cone experienced a catastrophic sector collapse at?~?7.1 cal ka BP, producing a volcanic debris avalanche deposit (VDAD) with hummocky surface and?~?6.4 km³ of volume. We carried out geological studies of its debris avalanche deposit, which was distributed to the W and displays a longitudinal facies transformation from edifice’s megablocks and block to mixed facies in distal areas (up to 25 km from the scar). Our observations support the behavior of the avalanche beginning as a translational slide, and then as plug flow when confined within the Laja River valley. Clay abundance and high content of hydrothermally altered material may suggest active participation of water; flow velocities are estimated to?~100 m s^?1. We primarily identify the steep-sided flanks of the cone, and hydrothermal alteration promoted the edifice instability, while basement seismogenic structures may have ultimately triggered the landslide. Subsequent landslide-led events include the transformation of the volcanic activity with explosive eruptions producing a sequence of dilute pyroclastic density currents (PDCs) ending?~3.4 ky BP, and extensive lava effusion rapidly reconstructing the collapsed edifice. Moreover, the Antuco VDAD also blocked the natural output of the Laja Lake, increasing its level by?~200 m and then triggering cataclysmic outburst floods by dam rupture, preserved as high-energy alluvial beds with ages between 2.8 and 1.7 ky BP. The Antuco constitutes an excellent example of a critical chain of events initiated by a stratovolcano lateral collapse and warns for detailed hazard investigations to better comprehend its related impacts.

     

A giant avalanche on K2 mount,Karakorum

On September 16th, 1986, an ice avalanche from a hanging glacier near the K2 peak at 7800 m asl, Karakorum, triggered a massive avalanche of ice and snow. Ice and snow, impacting on the path, formed a dust cloud at the advancing tip. Grounding on the firn basin surface, ice and snow broke into fine powder and covered the whole basin. Fine powder of the dust cloud rose up to 500–600 m and drifted 4–5 km away. On the basis of field observations and measurements, topography and weather, conditions of the avalanche formation are analyzed. Judging by the data obtained, the avalanche was extremely large, its vertical descend being 2500 m, the maximum motion speed 124 m/s, volume of the avalanche mass 2 × 10⁵ m³ to 10⁷ m³, and impact pressure, as the avalanche grounded, 2.3 × 10⁶ Pa. It could have been one of the largest avalanches ever recorded, causing danger for mountaineering and expedition activities in this area.     

The AD 1717 rock avalanche deposits in the upper Ferret Valley (Italy): a dating approach with cosmogenic 10Be

On 12 September AD 1717, a rock volume larger than 10 million m³ collapsed onto the Triolet Glacier, mobilized a mass composed of ice and sediment and travelled more than 7 km downvalley in the upper Ferret Valley, Mont Blanc Massif (Italy). This rock avalanche destroyed two small settlements, causing seven casualties and loss of livestock. No detailed maps were made at the time. Later investigators attributed accumulations of granitic boulders and irregular ridges on the upper valley floor to either glacial deposition, or the AD 1717 rock avalanche, or a complex mixture of glacial deposition, earlier rock avalanche and AD 1717 rock avalanche origin. In this study, we present cosmogenic ¹⁰Be exposure ages from nine boulders in the extensive chaotic boulder deposit with irregular ridges, two from Holocene glacier‐free areas, and one from a Little Ice Age moraine. Exposure ages between 330 ± 23 and 483 ± 123 a from eight of nine boulders from the chaotic deposit indicate that at least seven were deposited by the AD 1717 rock avalanche. The other three boulders yielded ¹⁰Be exposure ages of 10 900 ± 400, 9700 ± 400 and 244 ± 97 a, respectively. Our results are in good agreement with the existing chronology from dendrochronology and lichenometry, and radiocarbon analysis of wood samples, but not with older ¹⁴C ages from a peat bog in the upper part of the valley. Based on the new age control, the rock avalanche deposits cover the whole bottom of the upper Ferret valley. Copyright © 2012 John Wiley & Sons, Ltd.     

Glacial runoff characteristics of the Koxkar Glacier,Tuomuer-Khan Tengri Mountain Ranges,China

This paper presents the glacial runoff characteristics of the Koxkar Glacier, China using flow records collected near the snout of the glacier in four consecutive years (2005–2008). The mean annual discharge of the Koxkar Glacier is 102.86 × 10⁶ m³, in which 93.6% occurs in ablation season (May–October). August brings about maximum discharge of about 29.6% to the total streamflow followed by July of some 26.0%. During the study years, total discharge varies little from year to year, whereas the inter-annual variability in monthly discharge is prominent, particularly in the beginning and in the end of the melt season. Seasonal runoff variability shows great monthly variations in discharge with mean coefficient of variation ranging from 0.02 in January to 0.77 in April. The mean diurnal amplitudes are found to be 0.90, 1.86, 4.71, 4.92, 1.17 and 0.43 m³ s⁻¹ for May, June, July, August, September and October, respectively. In the melt season, the maximum runoff is observed during 1800–0200 hours and the minimum occurs during 0700–1000 hours. Delaying effects are prominent in discharge over the ablation period. The time-lag between meltwater generation and its appearance in the streamflow near the snout of the glacier varies between 4.00 and 10.00 h, and time to peak varies between 10.00 and 17.00 h over the entire melt season. The relationship between discharge and temperature on monthly scale (R ² = 0.77) is better than that on daily scale (R ² = 0.55).     

Grain growth kinetics of dolomite,magnesite and calcite: a comparative study

The rates of grain growth of stoichiometric dolomite [CaMg(CO₃)₂] and magnesite (MgCO₃) have been measured at temperatures T of 700–800°C at a confining pressure P _c of 300 MPa, and compared with growth rates of calcite (CaCO₃). Dry, fine-grained aggregates of the three carbonates were synthesized from high purity powders by hot isostatic pressing (HIP); initial mean grain sizes of HIP-synthesized carbonates were 1.4, 1.1, and 17 μm, respectively, for CaMg(CO₃)₂, MgCO₃, and CaCO₃, with porosities of 2, 28, and 0.04% by volume. Grain sizes of all carbonates coarsened during subsequent isostatic annealing, with mean values reaching 3.9, 5.1, and 27 μm for CaMg(CO₃)₂, MgCO₃, and CaCO₃, respectively, in 1 week. Grain growth of dolomite is much slower than the growth rates of magnesite or calcite; assuming normal grain growth and n = 3 for all three carbonates, the rate constant K for dolomite (≃5 × 10⁻⁵ μm³/s) at T = 800°C is less than that for magnesite by a factor of ~30 and less than that for calcite by three orders of magnitude. Variations in carbonate grain growth may be affected by differences in cation composition and densities of pores at grain boundaries that decrease grain boundary mobility. However, rates of coarsening correlate best with the extent of solid solution; K is the largest for calcite with extensive Mg substitution for Ca, while K is the smallest for dolomite with negligible solid solution. Secondary phases may nucleate at advancing dolomite grain boundaries, with implications for deformation processes, rheology, and reaction kinetics of carbonates.     

Formation mechanism and evolution process of the Chada rock avalanche in Southeast Tibet,China

The Chada rock avalanche is a prehistoric high-elevation giant rock landslide located in the Boshula Mountains, Lhorong County, Southeast Tibet. It is composed of conglomerates with a volume of 6.62?×?10⁶ m³ and has a height difference of 1450 m and a transport distance of 3155 m. The accumulational landform shows characteristics indicating rock avalanches. With a unique red conglomerate as the marker of landslide movement, we combined the results of geological surveys, aerial surveys, and engineering geological drilling to determine the entrainment and geomorphic features of the rock avalanche. The rock avalanche was divided into the main scarp, entrainment zone (residual deposit, mixed deposit, and impact fragmentation areas), transport zone (compressed, local landslide, and longitudinal ridge areas), and deposit zone. The sequence of deposits in the valley indicates that the rock avalanche formed before the first-stage terrace and after the second-stage terrace. Combined with 3D numerical simulation, four movement stages were obtained: (1) the rock mass was broken and disintegrated due to progressive failure, initiating high-speed sliding; (2) the sliding mass scraped the thick previous slope material and formed oblique ridges by forward extrusion and lateral friction; (3) the 4.95?×?10⁶ m³ sliding mass was compressed and decelerated to form bending ridges, and the 1.67?×?10⁶ m³ sliding mass continued to move through the channel; and (4) the sliding mass extended to form longitudinal ridges in the channel and hummocks in the valley. The rock avalanche accelerated three times and decelerated three times during its motion.

     

Statistical evaluation of PM<Subscript>10</Subscript> and distribution of PM<Subscript>1</Subscript>, PM<Subscript>2.5</Subscript>, and PM<Subscript>10</Subscript> in ambient air due to extreme fireworks episodes (Deepawali festivals) in megacity Delhi

Temporal variation of PM₁₀ using 2-year data (January, 2007–December, 2008) of Delhi is presented. PM₁₀ varied from 42 to 200 μg m⁻³ over January to December, with an average 114.1 ± 81.1 μg m⁻³. They are comparable with the data collected by Central Pollution Control Board (National Agency which monitors data over the entire country in India) and are lower than National Ambient Air Quality (NAAQ) standard during monsoon, close to NAAQ during summer but higher in winter. Among CO, NO₂, SO₂, rainfall, temperature, and wind speed, PM₁₀ shows good correlation with CO. Also, PM₁₀, PM_2.5, and PM₁ levels on Deepawali days when fireworks were displayed are presented. In these festive days, PM₁₀, PM_2.5, and PM₁ levels were 723, 588, and 536 μg m⁻³ in 2007 and 501, 389, and 346 μg m⁻³ in 2008. PM₁₀, PM_2.5, and PM₁ levels in 2008 were 1.5 times lower than those in 2007 probably due to higher mixing height (446 m), temperature (23.8°C), and winds (0.36 ms⁻¹).     

Movement of seasonal eddies and its relation with cyclonic heat potential and cyclogenesis points in the Bay of Bengal

Movement of seasonal eddies in the Bay of Bengal (BOB) and its relation with cyclonic heat potential (CHP) and cyclogenesis points have been investigated in this study using 6 years (2002–2007) of global ocean monthly analysis datasets based on the Simple Ocean Data Assimilation (SODA) package (SODA v2.0.4) of Carton et al. (2005) and Indian Meteorological Department cyclogenesis points. The region dominated by anticyclonic eddies with CHP greater than 70 × 10⁷ J/m² as well as good correlations (>0.9) with sea surface height (SSH) and 26°C isothermal depth (D ₂₆) can be a potential region of cyclogenesis. The region dominated by cyclonic eddies with CHP greater than 50 × 10⁷ J/m² and good correlation (>0.9) with both SSH and D ₂₆ can serve as a potential region of high-level depression. Potential cyclogenesis regions are the southern BOB (5°N–12°N) for the post-monsoon season and the head of BOB (north of 15°N) during southwest monsoon. Seven potential regions are identified for the eddy formation for different seasons, which are consistent with the cyclogenesis points. The CHP distributions alone are able to explain the cyclone tracks for the pre-monsoon and post-monsoon seasons but not for the monsoon season.     

The Todagin Creek landslide of October 3, 2006, Northwest British Columbia, Canada

The Todagin Creek landslide is located at 57.61° N 129.98° W in Northwest British Columbia. A seismic station 90 km north of the landslide recorded the event at 1643 hours coordinated universal time (UTC; 0943 hours Pacific daylight time (PDT)) on October 3, 2006. The signal verifies the discovery and relative time bounds provided by a hunting party in the valley. The landslide initiated as a translational rock slide on sedimentary rock dipping down slope at 34° and striking parallel to the valley. The landslide transformed into a debris avalanche and had a total volume estimated at 4 Mm³. An elevation drop of 771 m along a planar length of 1,885 m resulted in a travel angle (fahrb?schung) of 21.3°. The narrowest part of the landslide through the transport zone is 345 m. The widest part of the divergent toe of the landslide reaches a width of 1,010 m. Landslide debris impounded a lake of approximately 32 ha and destroyed an additional 67 ha of forest. The impoundment took 7 to 10 days to fill, with muddied waters observed downstream on October 13. No clear linkage exists with precipitation and temperature records preceding the landslide, but strong diurnal temperature cycles occurred in the days prior to the event. The Todagin Creek area appears to have an affinity for large landslides with the deposits of three other landslides >5 Mm³ observed in the valley.     

Decoding the complex internal chemical structure of garnet porphyroblasts from the Zermatt area,Western Alps

Garnet is a prototypical mineral in metamorphic rocks because it commonly preserves chemical and textural features that can be used for untangling its metamorphic development. Large garnet porphyroblasts may show extremely complex internal structures as a result of a polycyclic growth history, deformation, and modification of growth structures by intra‐ and intercrystalline diffusion. The complex internal structure of garnet porphyroblasts from garnet–phengite schists (GPS) of the Zermatt area (Western Alps) has been successfully decoded. The centimetre‐sized garnet porphyroblasts are composed of granulite facies garnet fragments overgrown by a younger generation of grossular‐rich eclogite facies garnet. The early granulite facies garnet (G‐Grt) formed from low‐P, high‐T metamorphism during a pre‐Alpine orogenic event. The late garnet (E‐Grt) is typical of high‐pressure, low‐temperature (HPLT) metamorphism and can be related to Alpine subduction of the schists. Thus, the garnet of the GPS are polycyclic (polymetamorphic). G‐Grt formation occurred at ~670 MPa and 780°C, E‐Grt formed at ~1.7 GPa and 530°C. The G‐Grt is relatively rich in Prp and poor in Grs, while E‐Grt is rich in Grs and poor in Prp. The Alm content (mol.%) of G‐Grt is 68 of E‐Grt 55. After formation of E‐Grt between and around fragmented G‐Grt at 530°C, the GPS have been further subducted and reached a maximum temperature of 580°C before exhumation started. Garnet composition profiles indicate that the initially very sharp contacts between the granulite facies fragments of G‐Grt and fracture seals of HPLT garnet (E‐Grt) have been modified by cation diffusion. The profiles suggest that Ca did not exchange at the scale of 1 µm, whereas Fe and Mg did efficiently diffuse at the derived maximum temperature of 580°C for the GPS at the scale of 7–8 µm. The Grt–Grt diffusion profiles resulted from spending c. 10 Ma at 530–580°C along the P–T–t path. The measured Grt composition profiles are consistent with diffusivities of log D_MgFe = ?25.8 m²/s from modelled diffusion profiles. Mg loss by diffusion from G‐Grt is compensated by Fe gain by diffusion from E‐Grt to maintain charge balance. This leads to a distinctive Fe concentration profile typical of uphill diffusion.     

The prehistoric Mt Wilberg rock avalanche, Westland, New Zealand

The Mt Wilberg rock avalanche in Westland, New Zealand occurred before 1300 AD and may have occurred as a consequence of an Alpine fault earthquake in ca. 1220 AD or earlier. Its ∼40 × 10⁶ m³ deposit may have briefly obstructed the Wanganui River, but only about 25% of its surface morphology still survives, on terraces isolated from river erosion. The landslide appears to have moved initially as a block, in a direction controlled by a strong rock mass at the base of the source area, before disintegrating and spreading across terraces, fans, and floodplains. Rock avalanche deposits in Westland have relatively short expected lifetimes in the rugged terrain and high rainfall of the area; hence, the hazard from such events is under-represented by their current remnants.     

Macrofaunal Spatial Patterns in Relationship to Environmental Variables in the Richibucto Estuary,New Brunswick,Canada

Estuarine macrobenthos respond to a variety of environmental gradients such as sediment type and salinity, and organic enrichment. A relatively new influence, organic loading from suspended bivalve culture, has the potential to alter this response. A study on soft-bottom macrobenthic communities was carried out in the Richibucto estuary (46°40′N, 64°50′W), New Brunswick, Canada, with samples collected from 18 stations in late September and early October 2006. The site consisted of a large tidal channel originating upstream in a small river. The channel was punctuated by bag culture of oysters along its length. A total of 88 species were recorded. The mean values of abundance, species richness, and diversity (H′) of macrofauna were 11,199 ind. m⁻² (ranged from 4,371 to 19,930 ind. m⁻²), 23.4 species grab⁻¹ and 3.29 grab⁻¹, respectively. In general species richness and H′ increased from the upper estuary to the estuarine mouth. Multivariate analyses clearly exhibited the spatial distribution in community structure, which coincided with the locations along the estuary (the upper, the lower and the mouth), as well as inside and outside the channel. Species richness and diversity H′ showed strong positive correlations with salinity (21.2–25.2 ppt), and abundance was positively correlated with water depth (1.0–4.5 m). Abundance and species richness were negatively correlated with both of silt–clay fraction (3.3–24.8%) and sorting (σ_I). Species richness was also negatively correlated with organic content (1.9–12.7%). The BIO-ENV analyses identified silt–clay fraction, σ_I and salinity as the major environmental variable combination influencing the macrofaunal patterns, and silt–clay fraction as the single best-correlated variable.     

Magnesium self-diffusion in orthoenstatite

Magnesium self-diffusion coefficients were determined experimentally for diffusion parallel to each of the three crystallographic directions in natural orthoenstatite (En₈₈Fs₁₂). Experiments were conducted at 1 atm in CO-CO₂ gas mixing furnaces, which provided oxygen fugacities equivalent to the iron-wüstite buffer. Diffusion of ²⁵Mg was induced in polished samples of oriented orthoenstatite using a film of isotopically enriched ²⁵MgO as the source material. Very short (<0.15 μm) diffusional penetration profiles were measured by ion microprobe depth profiling. The diffusion coefficients determined for four temperatures (900, 850, 800, 750 °C) provide the activation energies, E _a , and frequency factors, D _o, where D = D _o exp (−E _a /RT) for Mg self-diffusion parallel to each crystallographic direction: a-axis, E _a  = 360 ± 52 kJ/mole and D _o = 1.10 × 10⁻⁴ m²/s; b-axis, E _a  = 339 ± 77 kJ/mole and D _o = 6.93 × 10⁻⁶ m²/s and c-axis, E _a  = 265 ± 66 kJ/mole and D _o = 4.34 × 10⁻⁹ m²/s. In this temperature range, any possible anisotropy of cation diffusion is very small, however the activation energy for diffusion parallel to the c-axis (001) is the lowest and the activation energies for diffusion parallel to the a-axis (100) and b-axis (010) are higher. Application of these diffusion results to the silicate phases of the Lowicz mesosiderite meteorite provides cooling rates for the silicate portion of the meteorite (4–11 °C/100 years) that are similar, although slower, to previous estimates. These silicate cooling rates are still several orders of magnitude faster than the cooling rates (0.1 °C/10⁶ years) for the metal portions. Received: 22 January 1997 / Accepted: 2 October 1997     

Paragenesis of unusual Fe-cordierite (sekaninaite)-bearing paralava and clinker from the Kuznetsk coal basin,Siberia, Russia

Sekaninaite (X_Fe > 0.5)-bearing paralava and clinker are the products of ancient combustion metamorphism in the western part of the Kuznetsk coal basin, Siberia. The combustion metamorphic rocks typically occur as clinker beds and breccias consisting of vitrified sandstone–siltstone clinker fragments cemented by paralava, resulting from hanging-wall collapse above burning coal seams and quenching. Sekaninaite–Fe-cordierite (X_Fe = 95–45) is associated with tridymite, fayalite, magnetite, ± clinoferrosilite and ±mullite in paralava and with tridymite and mullite in clinker. Unmelted grains of detrital quartz occur in both rocks (<3 vol% in paralavas and up to 30 vol% in some clinkers). Compositionally variable siliceous, K-rich peraluminous glass is <30% in paralavas and up to 85% in clinkers. The paralavas resulted from extensive fusion of sandstone–siltstone (clinker), and sideritic/Fe-hydroxide material contained within them, with the proportion of clastic sediments ≫ ferruginous component. Calculated dry liquidus temperatures of the paralavas are 1,120–1,050°C and 920–1,050°C for clinkers, with calculated viscosities at liquidus temperatures of 10^1.6–7.0 and 10^7.0–9.8 Pa s, respectively. Dry liquidus temperatures of glass compositions range between 920 and 1,120°C (paralava) and 920–960°C (clinker), and viscosities at these temperatures are 10^9.7–5.5 and 10^8.8–9.7 Pa s, respectively. Compared with worldwide occurrences of cordierite–sekaninaite in pyrometamorphic rocks, sekaninaite occurs in rocks with X_Fe (mol% FeO/(FeO + MgO)) > 0.8; sekaninaite and Fe-cordierite occur in rocks with X_Fe 0.6–0.8, and cordierite (X_Fe < 0.5) is restricted to rocks with X_Fe < 0.6. The crystal-chemical formula of an anhydrous sekaninaite based on the refined structure is | \textK_0.02 |(\textFe_1.54^{2 +} \textMg_0.40 \textMn_0.06 )_{\Upsigma 2.00}^M [(\textAl_1.98 \textFe_0.02^{2 +} \textSi_1.00 )_{\Upsigma 3.00}^T1 (\textSi_3.94 \textAl_2.04 \textFe_0.02^{2 +} )_{\Upsigma 6.00}^T2 \textO₁₈ ]. \left| {{\text{K}}_{0.02} } \right|({\text{Fe}}_{1.54}^{2 + } {\text{Mg}}_{0.40} {\text{Mn}}_{0.06} )_{\Upsigma 2.00}^{M} [({\text{Al}}_{1.98} {\text{Fe}}_{0.02}^{2 + } {\text{Si}}_{1.00} )_{\Upsigma 3.00}^{T1} ({\text{Si}}_{3.94} {\text{Al}}_{2.04} {\text{Fe}}_{0.02}^{2 + } )_{\Upsigma 6.00}^{T2} {\text{O}}_{18} ].     

The characteristics and failure mechanism of the largest landslide triggered by the Wenchuan earthquake, May 12, 2008, China

Strong earthquakes are among the prime triggering factors of landslides. The 2008 Wenchuan earthquake (M _w = 7.9) triggered tens of thousands of landslides. Among them, the Daguangbao landslide is the largest one, which covered an area of 7.8 km² with a maximum width of 2.2 km and an estimated volume of 7.5 × 10⁸ m³. The landslide is located on the hanging wall of the seismogenic fault, the Yingxiu–Beichuan fault in Anxian town, Sichuan Province. The sliding mass travelled about 4.5 km and blocked the Huangdongzi valley, forming a landslide dam nearly 600 m high. Compared to other coseismic landslides in the study area, the Daguangbao landslide attained phenomenal kinetic energy, intense cracking, and deformation, exposing a 1-km long head scarp in the rear of the landslide. Based on the field investigation, we conclude that the occurrence of the landslide is controlled mainly by the seismic, terrain, and geological factors. The special location of the landslide and the possible topographic amplification of ground motions due to the terrain features governed the landslide failure. The effects of earthquakes on the stability of slopes were considered in two aspects: First, the ground shaking may reduce the frictional strength of the substrate by shattering of rock mass. Second, the seismic acceleration may result in short-lived and episodic changes of the normal (tensile) and shear stresses in the hillshopes during earthquakes. According to the failure mechanism, the dynamic process of the landslide might contain four stages: (a) the cracking of rock mass in the rear of the slope mainly due to the tensile stress generated by the ground shaking; (b) the shattering of the substrate due to the ground shaking, which reduced the frictional strength of the substrate; (c) the shearing failure of the toe of the landslide due to the large shear stress caused by the landslide gravity; and (d) the deposition stage.     

Bubble nucleation in rhyolite and dacite melts: temperature dependence of surface tension

Surface tension (σ) profoundly influences the ability of gas bubbles to nucleate in silicate melts. To determine how temperature impacts σ, experiments were carried out in which high-silica rhyolite melts with 5 wt% dissolved water were decompressed at temperatures that ranged from 775 to 1,085°C. Decompressions were also carried out using dacite melts with 4.3 wt% dissolved water at 1,150°C. Water bubbles nucleated in rhyolite only when decompressions exceeded 95 MPa at all temperatures. Bubbles nucleated in number densities that increased as decompression increased and at hotter temperatures at a given amount of decompression. After correcting decompression amounts for temperature differences, values for σ were estimated from nucleation rates and found to vary between 0.081 and 0.093 N m⁻¹. Surface tension decreases as temperature increases from 775 to 875°C, but then increases as temperature increases to 1,085°C. Those values overlap previous results, but only when melt viscosity is less than 10⁴ Pa s. For low-viscosity rhyolite, there is a strong correlation of σ with temperature, in which σ increases by 6.9 × 10⁻⁵ N m⁻¹ C⁻¹. That variation is robust for 5–9 wt% dissolved water, as long as melt viscosity is ≤10⁴ Pa s. More viscous rhyolite deviates from that correlation probably because nucleation is retarded in stiffer melts. Bubbles nucleated in dacite when decompressions exceeded 87 MPa, and occured in one or more events as decompression increased. Surface tension is estimated to be 0.083 (±0.001) N m⁻¹ and when adjusted for temperature agrees well with previous results for colder and wetter dacite melts. At a given water content, dacite melts have lower surface tensions than rhyolite melts, when corrected to a fixed temperature.     

Tectonics and thermal structure of western Satpura,India

Increased seismicity and occurrences of hot springs having surface temperature of 36–58 °C are observed in the central part of India (74–81° E, 20–25° N), where the NE trending Middle Proterozoic Aravalli Mobile Belt meets the ENE trending Satpura Mobile Belt. Earlier Deep Seismic Sounding (DSS) studies along Thuadara-Sendhwa-Sindad profile in the area has showed Mesozoic Sediments up to around 4 km depth covered by Deccan Trap and the Moho depth with a boundary velocity (P_n) of 8.2 km/s. In the present study, surface heat flow of 48 ± 4 mW m^?2 has been estimated based on P_n velocity, which agrees with the value of heat flow of 52 ± 4 mW m^?2 based on Curie point isotherms estimates. The calculated temperature-depth profile shows temperature of 80–120 °C at the basement, which is equivalent to oil window temperature in Mesozoic sediments and around 570–635 °C at Moho depth of 38–43 km and the thermal lithosphere is about 110 km thick, which is comparatively higher than those of adjoining regions. The present study reveals the brittle–ductile transition zone at 14–41 km depth (temperature around 250–600 °C) where earthquake nucleation takes place.     

Sea level and paleotemperature records from a mid-Holocene reef on the North coast of Java, Indonesia

Mid-Holocene age fossil-fringing reefs occur along the tectonically stable north coast of Java, Indonesia, presenting an opportunity for sea level and paleoclimate reconstruction. The fossil reef at Point Teluk Awur, near Jepara, Central Java, contains two directly superposed horizons of Porites lobata microatolls. Corals in the lower horizon, 80 cm above modern sea level, yielded Uranium series dates of 7090 ± 90 year BP, while corals in the upper horizon at 1.5 m grew at 6960 ± 60 year BP. These dates match the transgressive phase of regional sea-level curves, but suggest a mid-Holocene highstand somewhat older than that recorded on mid-Pacific islands. Paleotemperature was calibrated using Sr/Ca and δ¹⁸O values of a modern P. lobata coral and the locally measured sea surface temperature (SST), yielding SST–Sr/Ca and SST–δ¹⁸O calibration equations [T _Sr/Ca = 91.03–7.35(Sr/Ca) and T_{d¹⁸ \textO} T_{{\delta^{18} {\text{O}}}}  = −3.77 to −5.52(δ¹⁸O)]. The application of the local equations to Sr/Ca and δ¹⁸O measurements on these corals yielded a range of temperatures of 28.8 ± 1.7°C, comparable to that of the modern Java Sea (28.4 ± 0.7°C). A paleo-salinometer [Δδ¹⁸O = ∂δ¹⁸O/∂T ( T_{d¹⁸ \textO} T_{{\delta^{18} {\text{O}}}}  − T _Sr/Ca)], re-calculated using the local parameters, also suggests Java Sea mid-Holocene paleosalinity similar to modern values.     

Proton migration in portlandite inferred from activation energy of self-diffusion and potential energy curve of OH bond

A fundamental mechanism on the atomic level for self-diffusion in the proton layer of portlandite, Ca(OH)₂, was investigated by conducting hydrogen–deuterium (H–D) exchange diffusion experiments and by deriving potential energy curves of OH vibrations from optical absorption measurements. Synthetic single crystals of portlandite were used in H–D experiments between 250 and 450°C at 150 MPa. Arrhenius parameters for proton diffusion perpendicular to the c-axis gave a frequency factor of 1.0 × 10⁻¹⁰ m²/s and activation energy of 0.61 eV (58.5 kJ/mol). The activation energy corresponds to the height of the potential barrier between two oxygen atoms across an interlayer. The potential barrier height was also theoretically estimated using the OH potential energy curve (OH-PEC) determined by optical absorption measurements. Experimental and theoretical results suggest that the potential barrier height cannot be simply determined by overlapping two OH-PECs. The potential barrier derived theoretically was 3.11 eV. This is too high for the activation energy of the proton diffusion. It implies that the interaction between a diffusing proton and the vacancy of a proton site, and the shortening of interlayer oxygen distance by thermal vibration reduce the potential barrier.