山东省黄河下游地区浅层地下水地球化学特征与环境质量评价

浅层地下水调查是山东省黄河下游流域生态地球化学调查项目中的一项工作内容。调查是按每16 km2采集1件浅层地下水样品的密度,分析测试As,Ba,Be,Ca,Cd,Co,Cu,Fe,Hg,Pb,Se,Zn,F-,Cl-,Cr6 ,NO2-,COD,pH等33项指标;通过对这些指标在浅层地下水中的背景变化规律研究认为:调查区内浅层地下水中各指标含量起伏变化大,局部富集程度高,特别是As,Fe,K,La,Sb,Sn,Zn,Cl-,NO2-等指标的变异系数均>3.0,说明这些指标在浅层地下水中分布极不均匀,虽然背景含量较低,但在局部地段会形成高含量区,影响浅层地下水质量。选择As,Ba,Be,Cd,Co,Cu,Fe,Hg,Mn,Mo,Ni,Pb,Se,Zn,F-,Cl-,Cr6 ,NO2-,COD,pH等20项指标,按《地下水环境质量标准》中的要求,对浅层地下水环境质量进行的单项组分和综合评价结果显示,达到较好级以上者不足9%,而较差和极差级者达90%以上,表明调查区内浅层地下水环境污染状况较为严重。     

山东省重要矿种成矿系列成矿谱系研究

以陈毓川院士"矿床成矿系列"理论为指导,以全省煤、油页岩、铁、铜、铅、锌、铝、金、银、钼、稀土、硫、萤石、重晶石、菱镁矿、钾、磷、金刚石、石膏、石墨、滑石、水泥用灰岩、膨润土等23个重要矿种为基础,辅以其他矿种,从山东省区域地质构造环境与区域成矿作用关系研究划分全省重要矿种成矿系列;按照鲁西陆块、胶北陆块和胶南-威海造山带构造单元建立全省区域成矿谱系,以揭示全省在不同地质历史时期、不同区域地质构造环境下成矿作用的时空演化关系。     

发射光谱法测定地质样品中8个微量元素

地质样品中Ag、Pb、Mo、Co、Sn、Mn、Ni、Cr 8个微量元素 ,有易、中、难挥发元素。本文采用饱和氯化钾溶液作载体 ,垂直电极发射光谱法 ,同时测定上述 8个元素 ,具方法简便、快速、灵敏、经济等优点。     

进口红土镍矿主要成分研究

红土镍矿进口量巨大、成分十分复杂且差异性大。为了比较全面了解进口红土镍矿的主要成分,以日照港为主,连云港、天津港为辅,从2013年1月至12月,按进港量多少,每月抽取11~25个样本,共228个。通过常量元素的全面分析,检出率大于35%的元素19个,分别是：镍、铁、氧、硅、镁、铝、铬、锰、钴、锌、钙、氯、钠、钾、钛、硫、钒、铜、磷等;其中,前10种全部检出;而含量全部大于1%的元素只有氧和铁。     

新疆东昆仑三岔顶地区水系沉积物地球化学特征及找矿方向研究

通过开展三岔顶一带1:5万水系沉积物测量,分析了研究Au,Ag,Cu,Pb,Zn,W,Sn,Mo,As,Bi,Sb,Cr,Ni,Co,Hg,Cd共16种元素地球化学参数特征及其相关性,认为该区元素的富集与地层、构造、岩浆岩明显相关;Hg,Cr,Ni,W,As,Au,Pb,Zn等元素变异系数较大,易于形成异常;Ag,As,Au,Co,Cr,Cu,Hg,Ni,Sb,Zn等10种元素不同程度富集,成矿可能性大。通过因子分析,提取了6种具有代表性的因子组合类型,讨论了各元素空间分布特征。全区共圈定31处地球化学综合异常,在综合异常查证的基础上,结合区域成矿地质条件、矿产地质特征,圈定出寒凝泉铬钴镍铜、黄沙河东铜银钼铅多金属、月牙湾铜银铅锌多金属3处找矿远景区,为该地区进一步开展找矿工作提供了基础地球化学依据。     

BIOCHEMICAL GENETIC STUDIES ON CUTYLEFISH SEPIELLA MAINDRONI （CEPHALOPODA： SEPIIDAE）——ACTIVE LOCI SCREENING OF ISOZYME

Screening of 46 putative enzyme-coding loci and 4 different kinds of tissues of Sepiella maindroni de Rochebrone, 1884 for enzymatic activities using starch gel electrophoretic technique proved that the 21 enzymes such as AAT, AK, ALP, AP, CK, DIA, ES, FBP, G3PDH, GPI, GRS,IDH, LDH, MDH, MEP, MPI, NP, PGDH, PGM, SOD and XO* , were active to Sepiella maindroni after being stained. The tissue exhibiting stable and clear bands was also determined. Among tissues tested, mantle muscle tissue was the best for electrophoretic survey of isozymes. Buccal bulb muscle, eye and liver were fairly good for some special enzymes, such as DIA, ES, MPI, NT, etc.     

Viral diseases of olive flounder in Korean hatcheries

In order to elucidate the state of diseases, especially viral diseases, and to prevent viral diseases from occurring in olive flounder hatcheries, a range of studies, including epidemiological study, were performed from 1997 to 2003. The location of the hatcheries investigated includes several representative sites in the east （Kangnung, Uljin, Pohang, Yangsan, Ulsan, Pusan）, south （Wando, Changheung, Goheung, Yeosu, Namhae, Tongyeong, Geoje, Jeju） and west （Seosan, Kunsan, Gochang, Yeongkwang, Mokpo, Chindo） costal areas of the Korea Peninsula. A total of 2000 cases have been examined in 7 years, in which mortality caused by viral agents accounts for 22%, or 446 cases. Mortalities associated with viral infection considerably increased from 14% in 1997 to 27% in 2003. A variety of viral diseases were observed, and the occurrences of viral epidermal hyperplasia, viral ascites and viral deformity, viral nervous necrosis, and hirame rhabdoviral disease are 14%, 51%, 25%, and 8% respectively. By investigating the viral infection of broodstock flounder, the infection rate of marine birnavirus （MABV） in hatcheries was identified to be approximately 30%, therefore, it is highly necessary to acquire and keep non-infected broodstock fishes.     

BIOCHEMICAL GENETIC STUDIES ON CUTTLEFISH SEPIELLA MAINDRONI (CEPHALOPODA: SEPIIDAE)──ACTIVE LOCI SCREENING OF ISOZYME

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山东省招莱金矿带金矿地球化学异常模式及地质效果

金矿带位于胶北隆起的西北部,栖霞复背斜北翼。矿床类型为蚀变岩型和石英脉型。金矿严格受NE、NNE向构造控制。金矿床最佳元素组合是:Au、Ag、Te、Bi;Au、Ag、Cu、As、Pb。找矿指示元素为:Au、Ag、Te、Cu、Pb、Zn、Sb、Mn、Ba等10种。Au与Ag、As、Te、Bi、Cu密切相关,Au与Ag、As、Te相关系数接近1。矿体异常按三级浓度带圈定,出现三个浓度带的元素有:Au、Te、Ag、Cu、还有Zn、Mo。外带与蚀变带空间展布基本一致,内带反映矿体空间位置。矿体元素轴向分带自上而下是:Sb、As、Ag、Pb、Bi、Cu、Se、Te、Au、Zn、Mn、Ba、Mo。矿体不同标高元素对比值(As×Ag)×100/Mn,矿体头部比值>2;矿体中部比值>0.5,<2;矿体尾部比值<0.5。矿体头尾晕判别函数分带指标,判别函数是:y=0.0685Ln(Ag×As)-0.0182Ln(Au×Te)-0.0203LnCu-0.1046LnMn。判别临界值Yc=-0.4960,当判别函数Yc大于或小于-0.4960时,分别为矿体头部和尾部指标。金矿床地球化学异常模式,异常元素在矿体空间有明显浓度分带和垂直分带。异常受构造控制,并与构造方向一致,且呈带状分布。矿体头部元素:Sb、As、Ag;近矿指示元素:Au、Te、Bi、Cu、Pb;矿体尾部指示元素:Mo、Ba、Mn、Zn。金矿原生晕可以有效地直接圈定破碎蚀变带及脉体含矿富集地段,以及寻找深部盲矿体和判断矿体剥蚀程度。     

卡帕藻的营养成分分析及综合比较

于1999年元月在海南陵水黎安港采集卡帕藻，应用HPLC、原子吸收等分析手段，系统测定其营养成分（主要包括蛋白质、氨基酸、脂肪、粗纤维、粗灰分、矿物质及微量元素等），并与其它几种大型藻类比较，综合评价卡帕藻的营养价值。结果表明卡帕藻蛋白质含量为6.20%，而粗脂肪和粗灰分较高，分别为2.88%和39.04%；卡帕藻中富含K、Na、Ca、Mg、P、Fe、Zn、Mn、Se等矿物元素，尤其是Se的含量远高于其它几种大型藻类。     

GEOCHEMICAL STUDY OF THE CORE S01 IN THE SOUTH CHINA SEA

Si, Ti, Al, Fe, Mn, Ca, Mg, K, Na, P and Sr, Ba, Rb, Ga, V, Zr, Cr, Ni, Co, Cu, Zn, Pb,Nb, Y, Th, La in the core S01 were analyzed and the pattems of their enrichment are discussed.Enrichment of Na, Fe, Mn, Ba, Cu elements in the core indicates volcanic material are an importantsoarce of the sediments in the area. The enrichment frequently varying with the deposition processshows bottom volcanism is frequent in the area and that the studied area is a margin basin with distinctoceanic characteristics. The abnormal enrichment of Mn at the layers(0-15 cm and 665-670 cm) of the core could beclosely related to and so, indicate, the wide deposition hiatus that have occurred in the West PacificOcean and adjacent margin seas since Late Pleistocene.     

舟山西蟹峙海洋倾倒区及邻近海域表层沉积物重金属污染及其生态风险评价

根据2011年7月浙江舟山西蟹峙海洋倾倒区及邻近海域表层沉积物重金属的监测结果,采用单因子指数法和Hakanson生态危害指数法分析表层沉积物重金属的污染特征,并评价其潜在生态风险。结果表明:沉积物重金属元素Cu、Zn、Pb、Cd、Cr、Hg、As含量均符合国家海洋沉积物质量一类标准;重金属元素污染程度由高到低依次为Zn、Cr、Pb、Cu、As、Cd、Hg,其中Cu、Pb、Cd、Hg和As 5种重金属元素为低污染水平,Zn和Cr 2种重金属元素为中等污染程度水平;7种重金属元素单个和综合潜在生态危害程度均为低风险水平,由高到低依次为Cd、Hg、As、Pb、Cu、Cr、Zn。     

MIGRATION CHARACTERISTICS OF MICROELEMENTS IN PROCESS OF LANDSCAPE GEOCHEMISTRY IN MT.NAMJAGBARWA AREA

To provide scientific basis for appraising natural resources in Mt. Namjagbarwa area, the migration characteristics of geochemical microelements, such as Zn, V, Ti, Pb, Ni, Cu, Cr, Co, Be and Ba, in the landscape zones of alpine scrub and meadow, the mountainous dark coniferous forest, the mountainous mixed broadleaf and coniferous forest, the mountainous quasi-subtropical semi-evergreen broadleaf forest, the mountainous subtropical evergreen broadleaf forest, and the valley quasi-tropical monsoon rainforest have been described in the paper.     

致密储层源储结构对储层含油性的控制作用——以鄂尔多斯盆地合水地区长6～长8段为例

鄂尔多斯盆地长6～长8段致密油是中国典型的致密油分布区。源储紧密接触是致密油的典型特征与成藏条件。致密油层非均质性强,石油运移多以垂向短距离为主。已有研究表明,储层非均质性是影响鄂尔多斯盆地合水地区剩余油分布的重要因素,但是目前对合水地区储层含油性影响因素的研究很少。通过分析合水地区长6～长8段源储结构及其与含油性的关系,研究其对储层含油性的控制作用。结果表明:合水地区长6～长8段源储结构复杂,长7段为源储一体型岩性组合,可细分为源夹储型、源储互层型与储夹源型3种类型,长6与长8段为研究区主要储层,与烃源岩形成邻源型岩性组合,细分为源储接触型、源储过渡型与源储间隔型3种类型;长7段源夹储型岩性组合的含油性最好,长6与长8段源储接触型岩性组合的含油性最好,最有利于致密油聚集;长6～长8段形成干酪根网络→孔隙+微裂缝型、干酪根网络+构造裂缝→孔隙+微裂缝型两种石油运移通道组合,为致密油充注提供有利的通道网络。     

化探样品中部分元素测定溶矿方法的改进

文章研究了用 1∶1王水分解化探样品中Cu、Pb、Zn、Co、Ni、Fe、Mn等元素新的样品溶解测定方法 ,即王水分解测定法 ,该法的检出限、准确度、精密度均达到 1∶5万化探样品分析要求。此法已用于化探及区域地质普查样品分析 ,并取得了较好效果     

潜流带生物地球化学特征研究进展

潜流带(即地表水-地下水交互作用带)是位于地表水和地下水之间发生物质和能量交换的,具有物理、化学、生物梯度的饱和含水带。潜流带内发生着强烈的生物地球化学过程,在改善水环境质量和维持水生态系统稳定中发挥着重要作用。潜流带生物地球化学特征主要受河床沉积物结构特征、水文特征、环境特征、生物群落格局、物质输入等因素的影响,潜流带内C、N、P元素以及有毒金属元素(Fe、Mn、As、Hg等)会发生氧化-还原、吸附与解吸、沉淀与溶解、生物催化等生物地球化学过程。原位监测、数值模拟、原位培养和地球物理探测等技术是潜流带中生物地球化学过程研究中常用的研究手段。未来针对潜流带的研究可以从监测和数值模拟技术、河床沉积物变化特征以及微生物生态系统的结构和功能等方面进一步开展。     

Geochemical analysis of marine sediments using fused glass disc by X-ray fluorescence spectrometry

A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard （for the trace elements）. The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% （n=12）.     

东天山图拉尔根镁铁—超镁铁质岩体辉石矿物学特征及其地质意义

东天山图拉尔根镁铁—超镁铁质岩体主要包含角闪橄榄岩相、辉石橄榄岩相和辉长岩相,辉石为各岩相主要造岩矿物之一。采用电子探针和LA-ICPMS技术对不同岩相中辉石的主量、微量元素进行测试分析,以探讨岩体的性质、来源和演化过程。东天山图拉尔根镁铁—超镁铁质岩体中斜方辉石属古铜辉石,而单斜辉石则为透辉石和顽透辉石。辉石温压计算表明其结晶温度为978℃~1059℃,结晶压力主要为0.71~4.80kbar。岩体母岩浆为亚碱性拉斑玄武质岩浆,是被俯冲板片交代过的亏损地幔发生13%~20%部分熔融的产物。岩体内不同岩相中辉石的化学成分变化较小,表明岩体的结晶分异程度较低,其中辉长岩相的结晶程度较角闪橄榄岩相和辉石橄榄岩相略高;岩浆上侵过程中,角闪橄榄岩相和辉石橄榄岩相受到富硅地壳物质的混染,而辉长岩相受到富铝围岩的混染。结晶分异作用和富硅地壳的混染是引起图拉尔根岩体硫饱和及硫化物熔离的重要因素。     

中华人民共和国人口电子地图集系统设计

“中华人民共和国人口电子地图集”是我国最新的第五次人口普查数据的集成,是以地图、文字、数字、图表等多种信息表达手段,全面反映了中国人口发展基本现状和趋势的科学参考图集。它可以实现对人口数据的输入/输出、分类、存储、查询、统计、制图、分析和管理,提供给决策者和研究者分析人口问题和制定人口政策的辅助工具。本文详细介绍了图集的系统总体设计、主要功能模块设计、内容组成等。在总体设计上,提出了以电子地图制作子系统、图集管理与集成子系统、图集浏览查询子系统和人口数据查询子系统为四大主要部分的系统结构,并进而对系统中的主要模块进行了介绍.如专题制图符号模型、数据库的目录树管理、电子地图集的管理与集成,通过这些模块,分析了系统的运行机制和流程;在图集内容上,在分析“五普”数据和我国人口实际国情的基础上,选取涉及十项主题(环境、人口分布、性别与年龄、人口变动、民族、家庭婚姻、生育、教育、就业、住房)近200幅地图组成图集的内容,反映我国人口的基本现状、动态变化、地域分布、结构构成等;最后,给出了使用不同制图符号建立的人口地图实例,可以直观地反映各项人口指标的区域差异和变化规律。     

Potential Effects of Episodic Deposition on Nutrients and Heavy Metals in Decomposing Litters of Suaeda glauca in Salt Marsh of the Yellow River Estuary,China

Episodic deposition has been recognized as a major factor affecting the decomposition rate of detrital material in salt marshes. In this paper, three one-off burial treatments, no burial treatment(0 cm, NBT), current burial treatment(10 cm, CBT) and strong burial treatment(20 cm, SBT), were designed in intertidal zone of the Yellow River Estuary to determine the potential influences of episodic deposition on nutrient(C, N) and heavy metal(Pb, Cr, Cu, Zn, Ni, Mn, Cd, V and Co) variations in decomposing litters of Suaeda glauca. Results showed that although various burial treatments showed no statistical difference in decomposition rate of S. glauca, the values generally followed the sequence of CBT(0.002 403/d) SBT(0.002 195/d) NBT(0.002 060/d). The nutrients and heavy metals in decomposing litters of the three burial treatments exhibited different variations except for N, Cu, Cr, Ni and Co. Except for Mn, no significant differences in C, N, Pb, Cr, Cu, Zn, Ni, V and Co concentrations occurred among the three treatments(P 0.05). With increasing burial depth, Cr and Cd levels generally increased while Cu, Ni and Mn concentrations decreased. Although episodic deposition was generally favorable for C and N release from S. glauca, its influence on release was insignificant. In the three burial treatments, Pb, Cr, Zn, Ni, Mn, V and Co stocks in S. glauca generally evidenced the export of metals from litter to environment, and, with increasing burial depth, the export amounts increased greatly. The S. glauca were particular efficient in binding Cd and releasing Pb, Cr, Zn, Ni, Mn, V and Co, and, with increasing burial depth, stocks of Cu in decomposing litters generally shifted from release to accumulation. The experiment indicated that the potential eco-toxic risk of Pb, Cr, Zn, Ni, Mn, V and Co exposure would be serious as the strong burial episodes occurred in S. glauca marsh.