Combining the standardized precipitation index and climatic water deficit in characterizing droughts: a case study in Romania

This paper characterizes droughts in Romania using the approach of both the standardized precipitation index (SPI) and climatic water deficit (WD). The values of the main climatic factors (rainfall, temperature, reference evapotranspiration, etc.) were obtained from 192 weather stations in various regions of Romania. Penman–Monteith reference evapotranspiration (ET_o-PM) was used to calculate WD as the difference between precipitation (P) and ET_o-PM. SPI was calculated from precipitation values. There is a clear difference between drought and aridity. Drought occurrence determines higher WD values for plains and plateaus and lower climatic excess water (EW) values for high mountains in Romania, depending on the aridity of the specific region considered and drought severity. WD calculated as mean values for both normal conditions and, for all locations studied, various types of drought was correlated with mean annual precipitation and temperature, respectively. The combined approach of WD and SPI was mainly carried out for periods of 1 year, but such studies could also be done for shorter periods like months, quarters, or growing season. The most arid regions did not necessarily coincide with areas of the most severe drought, as there were no correlations between WD and SPI and no altitude-based SPI zones around the Carpathian Mountains, as is the case for other climate characteristics, soils and vegetation. Water resource problems arise where both SPI values characterize extremely droughty periods and WD values are greatly below ?200 mm/year. This combined use of SPI and WD characterizes the dryness of a region better than one factor alone and should be used for better management of water in agriculture in Romania and also other countries with similar climate characteristics.     

Spatiotemporal distribution of aridity indices based on temperature and precipitation in the extra-Carpathian regions of Romania

In the last decades, droughts are a recurrent phenomena in many regions of the world, especially in the subtropics and mid-latitudes, affecting more and more the society. Aridity indices are often used to identify regions prone to that phenomenon. In this paper, we used data recorded in 30 locations in the extra-Carpathian areas of Romania over the period 1961–2007. The De Martonne aridity index (I _DM) and the Pinna combinative index (I _P) were employed in order to identify critical areas in the most important agricultural regions of the country. Monthly, seasonal, annual, and winter wheat and maize growing season datasets of I _DM and annual values of I _P were calculated. The trends were identified using the Mann–Kendall test and Sen’s slope, while ordinary Kriging technique was employed for interpolation. The main findings are that the most vulnerable to semi-aridity are the southeastern regions, especially during the warm period of the year, and that for Romania, the use of I _DM is more appropriate compared to I _P.     

Seasonal carbon dioxide balance and respiration of a high-arctic fen ecosystem in NE-Greenland

Summary  Turbulent fluxes of CO₂ were continuously measured by eddy correlation for three months in 1997 over a gramineous fen in a high-arctic environment at Zackenberg (74°28′12″N, 20°34′23″W) in NE-Greenland. The measurements started on 1 June, when there was still a 1–2 m cover of dry snow, and ended 26 August at a time that corresponds to late autumn at this high-arctic site. During the 20-day period with snow cover, fluxes of CO₂ to the atmosphere were small, typically 0.005 mg CO₂ m⁻² s⁻¹ (0.41 g CO₂ m⁻² d⁻¹), wheres during the thawed period, the fluxes displayed a clear diurnal variation. During the snow-free period, before the onset of vegetation growth, fluxes of CO₂ to the atmosphere were typically 0.1 mg CO₂ m⁻² s⁻¹ in the afternoon, and daily sums reached values up to almost 9 g CO₂ m⁻² d⁻¹. After 4 July, downward fluxes of CO₂ increased, and on sunny days in the middle of the growing season, the net ecosystem exchange rates attained typical values of about −0.23 mg m⁻² s⁻¹ at midday and max values of daily sums of −12 g CO₂ m⁻² d⁻¹. Throughout the measured period the fen ecosystem acted as a net-sink of 130 g CO₂ m⁻². Modelling the ecosystem respiration during the season corresponded well with eddy correlation and chamber measurements. On the basis of the eddy correlation data and the predicted respiration effluxes, an estimate of the annual CO₂ balance the calender year 1997 was calculated to be a net-sink of 20 g CO₂ m⁻² yr⁻¹. Received October 6, 1999 Revised May 2, 2000     

Net CO2 exchange of a subarctic mountain birch ecosystem

Summary  Net ecosystem CO₂ exchange was measured over a mountain birch forest in northern Finland throughout the growing season. The maximal net CO₂ uptake rate of about − 0.5 mg(CO₂) m⁻² s⁻¹ was observed at the end of July. The highest nocturnal respiration rates in early August were 0.2 mg(CO₂) m⁻² s⁻¹. The daily CO₂ balances during the time of maximal photosynthesis were about −15 g(CO₂) m⁻² d⁻¹. The mountain birch forest acted as a net sink of CO₂ from 30 June to 28 August. During that period the net CO₂ balance was −448 g(CO₂)m⁻². The interannual representativeness of the observed balances was studied using a simplified daily balance model, with daily mean global radiation and air temperature as the input parameters. The year-to-year variation in the phenological development was parameterised as a function of the cumulative effective temperature sum. The daily balance model was used for estimating the variability in the seasonal CO₂ balances due to the timing of spring and meteorological factors. The sink term of CO₂ in 1996 was lower than the 15-year mean, mainly due to the relatively late emergence of the leaves. Received October 11, 1999 Revised April 25, 2000     

Multivariate drought frequency estimation using copula method in Southwest China

This study reveals the impacts of climatic variable trends on drought severity in Xinjiang, China. Four drought indices, including the self-calibrating Palmer drought severity index (sc-PDSI), Erinç’s index (I _m), Sahin’s index (I _sh), and UNEP aridity index (AI), were used to compare drought severity. The ensemble empirical mode decomposition and the modified Mann-Kendall trend test were applied to analyze the nonlinear components and trends of the climatic variable and drought indices. Four and six climatic scenarios were generated in sc-PDSI, I _m, I _sh, and AI with different combinations of the observed and detrended climatic variables, respectively. In Xinjiang, generally increasing trends in minimal, average, and maximal air temperature (T _min, T _ave, T _max) and precipitation (P) were found, whereas a decreasing trend in wind speed at 2 m height (U ₂) was observed. There were significantly increasing trends in all of the four studied drought indices. Drought relief was more obvious in northern Xinjiang than in southern Xinjiang. The strong influences of increased P on drought relief and the weak influences of increased T _min, T _ave, and T _max on drought aggravation were shown by comparing four drought indices under different climate scenarios. Decreased U ₂ had a weak influence on drought, as shown by the AI in different climate scenarios. The weak influences of T and U ₂ were considered to be masked by the strong influences of P on droughts. Droughts were expected to be more severe if P did not increase, but were likely milder without an increase in air temperature and with a decrease in U ₂.     

The potential of vegetation feedback to alleviate climate aridity over the United States associated with a 2×CO2 climate condition

This study examines the potential impact of vegetation feedback on changes in summer climate aridity over the contiguous United States (US) due to the doubling of atmospheric CO₂ concentration using a set of 100-year-long climate simulations made by a global climate model interactively coupled with a dynamic vegetation model. The Thornthwaite moisture index (I _m ), which quantifies climate aridity on the basis of atmospheric water supply (i.e., precipitation) and atmospheric water demand (i.e., potential evapotranspiration, PET), is used to measure climate aridity. Warmer atmosphere and drier surface resulting from increased CO₂ concentration increase climate aridity over most of the contiguous US. This phenomenon is due to larger increments in PET than in precipitation, regardless of the presence or absence of vegetation feedback. Compared to simulations without active dynamic vegetation feedback, the presence of vegetation feedback significantly alleviates the increase in aridity. This vegetation-feedback effect is most noticeable in the subhumid regions such as southern, midwestern and northwestern US, primarily by the increasing vegetation greenness. In these regions, the greening in response to warmer temperatures enhances moisture transfer from soil to atmosphere by evapotranspiration (ET). The increased ET and subsequent moistening over land areas result in weaker surface warming (1–2?K) and PET (3–10?mm?month^?1), and greater precipitation (4–10?mm?month^?1). Collectively, they result in moderate increases in I _m . Our results suggest that moistening by enhanced vegetation feedback may prevent aridification under climatic warming especially in areas vulnerable to climate change, with consequent implications for mitigation strategies.     

Annual methane emission from Finnish mires estimated from eddy covariance campaign measurements

Summary  Measurements of landscape-scale methane emission were made over an aapa mire near Kaamanen in Finnish Lapland (69° 8′ N, 27° 16′ E, 155 m ASL). Emissions were measured during the spring thaw, in summer and in autumn. No effect of water table position on CH₄ emission was found as the water table remained at or above the surface of the peat. Methane emission fluxes increased with surface temperature from which an activation energy of −99 kJ mol⁻¹ was obtained. Annual emission from the site, modelled from temperature regression and short-term flux measurements made in three separate years, was calculated to be 5.5 ± 0.4 g CH₄ m⁻² y⁻¹ of which 0.6 ± 0.1 g CH₄ m⁻² y⁻¹ (11%) was released during the spring thaw which lasted 20 to 30 days. The effect of global warming on the CH₄ budget of the site was estimated using the central scenario of the SILMU (Finnish Research Programme on Climate Change) model which predicts annual mean temperature increases of 1.2, 2.4 and 4.4 °C in 2020, 2050 and 2100, respectively. Maximum enhancements in CH₄ emission due to warming were calculated to be 18, 40 and 84% for 2020, 2050 and 2100, respectively. Actual increases may be smaller because prediction of changes in water table are highly uncertain. Received September 17, 1999 Revised October 16, 2000     

Temperature and snow-melt controls on interannual variability in carbon exchange in the high Arctic

Summary Net Ecosystem CO₂ Exchange (NEE) was studied during the summer season (June–August) at a high Arctic heath ecosystem for 5 years in Zackenberg, NE Greenland. Integrated over the 80 day summer season, the heath is presently a sink ranging from −1.4 g C m⁻² in 1997 to −23.3 g C m⁻² in 2003. The results indicate that photosynthesis might be more variable than ecosystem respiration on the seasonal timescale. The years focused on in this paper differ climatically, which is reflected in the measured fluxes. The environmental conditions during the five years strongly indicated that time of snow-melt and air temperature during the growing season are closely related to the interannual variation in the measured fluxes of CO₂ at the heath. Our estimates suggest that net ecosystem CO₂ uptake is enhanced by 0.16 g C m⁻² per increase in growing degree-days during the period of growth. This study emphasises that increased summer time air temperatures are favourable for this particular ecosystem in terms of carbon accumulation.     

Rain-aerosol coupling in the tropical atmosphere of Southeast Asia: distribution and scavenging ratios of major ionic species

Both aerosol and rainwater samples were collected and analyzed for ionic species at a coastal site in Southeast Asia over a period of 9 months (January–September 2006) covering different monsoons. In general, the occurrence and distribution of ionic species showed a distinct seasonal variation in response to changes in air mass origins. Real-time physical characterization of aerosol particles during rain events showed changes in particle number distributions which were used to assess particle removal processes associated with precipitation, or scavenging. The mean scavenging coefficients for particles in the range 10–500 nm and 500–10 μm were 7.0 × 10⁻⁵ ± 2.8 × 10⁻⁵ s⁻¹ and 1.9 × 10⁻⁴ ± 1.6 × 10⁻⁵ s⁻¹, respectively. A critical analysis of the scavenging coefficients obtained from this study suggested that the wet removal of aerosol particles was greatly influenced by rain intensity, and was particle size-dependent as well. The scavenging ratios, another parameter used to characterize particle removal processes by precipitation, for NH₄ ⁺, Cl⁻, SO₄ ²⁻, and NO₃ ⁻ were found to be higher than those of Na⁺, K⁺, and Ca²⁺ of oceanic and crustal origins. This enrichment implied that gaseous species NH₃, HCl, and HNO₃ could also be washed out readily. These additional sources of ions in precipitation presumably counter-balanced the dilution effect caused by high total precipitation volume in the marine and tropical area.     

Atmospheric inorganic nitrogen in marine aerosol and precipitation and its deposition to the North and South Pacific Oceans

Aerosol and rain samples were collected between 48°N and 55°S during the KH-08-2 and MR08-06 cruises conducted over the North and South Pacific Ocean in 2008 and 2009, to estimate dry and wet deposition fluxes of atmospheric inorganic nitrogen (N). Inorganic N in aerosols was composed of ~68% NH₄⁺ and ~32% NO₃^– (median values for all data), with ~81% and ~45% of each species being present on fine mode aerosol, respectively. Concentrations of NH₄⁺ and NO₃⁻ in rainwater ranged from 1.7–55 μmol L⁻¹ and 0.16–18 μmol L⁻¹, respectively, accounting for ~87% by NH₄⁺ and ~13% by NO₃⁻ of total inorganic N (median values for all data). A significant correlation (r = 0.74, p < 0.05, n = 10) between NH₄⁺ and methanesulfonic acid (MSA) was found in rainwater samples collected over the South Pacific, whereas no significant correlations were found between NH₄⁺ and MSA in rainwater collected over the subarctic (r = 0.42, p > 0.1, n = 6) and subtropical (r = 0.33, p > 0.5, n = 6) western North Pacific, suggesting that emissions of ammonia (NH₃) by marine biological activity from the ocean could become a significant source of NH₄⁺ over the South Pacific. While NO₃⁻ was the dominant inorganic N species in dry deposition, inorganic N supplied to surface waters by wet deposition was predominantly by NH₄⁺ (42–99% of the wet deposition fluxes for total inorganic N). We estimated mean total (dry + wet) deposition fluxes of atmospheric total inorganic N in the Pacific Ocean to be 32–64 μmol m⁻² d⁻¹, with 66–99% of this by wet deposition, indicating that wet deposition plays a more important role in the supply of atmospheric inorganic N than dry deposition.     

Evaluation of Agricultural Climatic Resource Utilization During Spring Maize Cultivation in Northeast China Under Climate Change

Agricultural climatic resources （such as light,temperature,and water） are environmental factors that affect crop productivity.Predicting the effects of climate change on agricultural climatic resource utilization can provide a theoretical basis for adapting agricultural practices and distributions of agricultural production.This study investigates these effects under the IPCC （Intergovernmental Panel on Climate Change） scenario A1B using daily data from the high-resolution RegCM3 （0.25° ×0.25°） during 1951-2100.Model outputs are adjusted using corrections derived from daily observational data taken at 101 meteorological stations in Northeast China between 1971 and 2000.Agricultural climatic suitability theory is used to assess demand for agricultural climatic resources in Northeast China during the cultivation of spring maize.Three indices,i.e.,an average resource suitability index （Isr）,an average efficacy suitability index （Ise）,and an average resource utilization index （K）,are defined to quantitatively evaluate the effects of climate change on climatic resource utilization between 1951 and 2100.These indices change significantly in both temporal and spatial dimensions in Northeast China under global warming.All three indices are projected to decrease in Liaoning Province from 1951 to 2100,with particularly sharp declines in Isr,Ise,and K after 2030,2021,and 2011,respectively.In Jilin and Heilongjiang provinces,Isr is projected to increase slightly after 2011,while Ise increases slightly and K decreases slightly after 2030.The spatial maxima of all three indices are projected to shift northeastward.Overall,warming of the climate in Northeast China is expected to negatively impact spring maize production,especially in Liaoning Province.Spring maize cultivation will likely need to shift northward and expand eastward to make efficient use of future agricultural climatic resources.     

Atmospheric CO along the Trans-Siberian Railroad and River Ob: source identification using isotope analysis

The concentration, radiocarbon (¹⁴C) and stable isotope (¹³C and ¹⁸O) content of CO have been determined in air samples collected across Russia (about 8,500 km) and along the Ob river during the summer of 1999 to study the CO sources and sinks. An instrumented carriage on the Trans-Siberian railway and a boat on the river Ob were used as atmospheric measurement platforms. In general, CO mixing ratios, CO stable isotope ratios, as well as the abundances of ¹⁴CO over West Siberia were similar to those found at remote northern hemispheric baseline monitoring stations. Identified sources of CO along the Ob appear to be connected to methane oxidation based on an inferred δ¹³C_source = −36.8 ± 0.6‰, while the value for δ¹⁸O_source = 9.0 ± 1.6‰ identifies it as burning. Thus flaring in the oil and gas production can be supposed to be a source. The extreme ¹³C depletion and concomitant ¹⁸O enrichment for two of the boat samples unambiguously indicates contamination by CO from combustion of natural gas (inferred values δ¹³C_source = −40.3‰ and δ¹⁸O_source = 17.5‰). For these two samples, that have strongly elevated ¹⁴CO concentrations, the industrial area near Tomsk is identified as a source area using meteorological calculations. Along the Trans-Siberian Railroad background CO was to various degrees contaminated with CO from methane combustion (δ¹³C_source = −35.7 ± 6.2‰ and δ¹⁸O_source = 10.3 ± 1.8‰). The impact of industrial burning was discernable in the vicinity of Perm-Kungur.     

Laboratory measurements of the <Superscript>12</Superscript>C/<Superscript>13</Superscript>C kinetic isotope effects in the gas-phase reactions of unsaturated hydrocarbons with Cl atoms at 298 ± 3 K

The carbon kinetic isotope effects (KIEs) in the reactions of several unsaturated hydrocarbons with chlorine atoms were measured at room temperature and ambient pressure using gas chromatography combustion isotope ratio mass spectrometry (GCC-IRMS). All measured KIEs, defined as the ratio of the rate constants for the unlabeled and labeled hydrocarbon reaction k ₁₂/k ₁₃, are greater than unity or normal KIEs. The KIEs, reported in per mil according to ^Cl ɛ = (k ₁₂/k ₁₃−1) × 1000‰ with the number of experimental determinations in parenthesis, are as follows: ethene, 5.65 ± 0.34 (1); propene, 5.56 ± 0.18 (2); 1-butene, 5.93 ± 1.16 (1); 1-pentene, 4.86 ± 0.63 (1); cyclopentene, 3.75 ± 0.14 (1); toluene, 2.89 ± 0.31 (2); ethylbenzene, 2.17 ± 0.17 (2); o-xylene, 1.85 ± 0.54 (2). To our knowledge, these are the first reported KIE measurements for reactions of unsaturated NMHC with Cl atoms. Relative rate constants were determined concurrently to the KIE measurements. For the reactions of cyclopentene and ethylbenzene with Cl atoms, no rate constant has been reported in refereed literature. Our measured rate constants are: cyclopentene (7.32 ± 0.88) relative to propene (2.68 ± 0.32); ethylbenzene (1.15 ± 0.04) relative to o-xylene (1.35 ± 0.21), all × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹. The KIEs in reactions of aromatic hydrocarbons with Cl atoms are similar to previously reported KIEs in Cl-reactions of alkanes with the same numbers of carbon atoms. Unlike the KIEs for previously studied gas-phase hydrocarbon reactions, the KIEs for alkene–Cl reactions do not exhibit a simple inverse dependence on carbon number. This can be explained by competing contributions of normal and inverse isotope effects of individual steps in the reaction mechanism. Implications for the symmetries of the transition state structures in these reactions and the potential relevance of Cl-atom reactions on stable carbon isotope ratios of atmospheric NMHC are discussed.     

A study to discriminate local,urban and regional source contributions to the particulate matter concentrations in the city of Dresden,Germany

The fractions of local traffic (LT), urban background (UBG) and regional background (RBG) of the particle pollution at a traffic-influenced kerbside in Dresden, Germany, were determined by measurements of size-segregated mass concentration, chemical composition and particle size distributions in a network of five measurement stations partly existing and partly set up for this study. Besides the kerbside station, one urban background site and three rural sites were included in the study. Using data from these different sites, the LT, UBG, and RBG contributions were calculated, following the approach of Lenschow et al. (2001). At the kerbside site, 19% of the total number concentration (Dp_St = 10–600 nm) could be attributed to the RBG, 15% to the UBG, and 66% to the LT immediately nearby. Particle mass concentrations up to Dp_aer = 420 nm RBG amounts to 68%, UBG to 21%, and LT only to 11%. Highest mass concentrations were observed at all stations in autumn and winter during easterly inflow directions. The local traffic fraction of PM₁₀ mass at the kerbside station was found to be 30% for westerly inflow, but only 7% for southeasterly inflow due to the dominating transport fraction from up to 80% of the particle mass at this inflow direction. Size-resolved investigation showed the main fractions in both the particle size ranges of Dp_aer = 0.42 to 1.2 and 0.14 to 0.42 μm at all stations. The main components sulphate, ammonium and total carbon showed higher concentrations at south-eastern/eastern inflow in autumn at all stations, while nitrate at the kerbside and urban background site was higher during westerly inflow in winter. The chemical composition at the regional background site at westerly inflow (12% nitrate, 8% sulphate, 11% total carbon) was significantly different from that at easterly inflow (3% nitrate, 15% sulphate, 22% total carbon). The prevailing part of the ionic mass was always found in the fine particle range of Dp_aer = 0.14 to 1.2 μm at all stations. For all inflow directions highest total carbon concentrations were observed at the kerbside station, especially in the ultra-fine size range of Dp_aer = 0.05 to 0.14 μm with up to 30% of the whole carbon. PAH concentrations were always higher at south-eastern/eastern inflow especially during wintertime. Trace metal components and silicon were found mainly in the coarse mode fraction at the kerbside resulting from abrasion or resuspension.     

Water interaction with MgCl<Subscript>2</Subscript>×6H<Subscript>2</Subscript>O and NaCl surfaces: measurements of the uptake coefficient

The uptake of water vapor on MgCl₂×6H₂O and NaCl salt dry solid films was studied over the temperature range 240 to 340 K and at 1 Torr pressure of helium using a flow reactor coupled to a modulated molecular beam mass spectrometer. The H₂O to salt uptake data were obtained from the kinetics of H₂O loss on salt coated Pyrex rods. The following Arrhenius expression was obtained for the initial uptake coefficient of H₂O on MgCl₂×6H₂O films: γ ₀ (MgCl₂) = (6.5 ± 1.0) × 10⁻⁶ exp[(470 ± 40)/T] (calculated with specific BET surface area, quoted uncertainties are 1σ statistical). The rate of H₂O adsorption on NaCl was found to be much lower than on MgCl₂×6H₂O, and only an upper limit was determined for the corresponding uptake coefficient: γ (NaCl) ≤ 5.6 × 10⁻⁶ at T = 300 K. The results show that the rate of H₂O adsorption to salt surfaces is drastically dependent on the salt sample composition.     

Regional effects of large-scale extreme wind events over orographically structured terrain

Summary ?Above orographically structured terrain considerable differences of the regional wind field may be identified during large-scale extreme wind events. So far, these regional differences could not be resolved by climate models. To determine the relationships between large-scale atmospheric conditions, the influence of orography, and the regional wind field, data measured in the upper Rhine valley within the framework of the REKLIP Regional Climate Project were analyzed and calculations were made using the KAMM mesoscale model. In the area of the upper Rhine valley, ratios of the wind velocity in the Rhine valley at 10 m above ground level, ν_val, and the large-scale flow velocity, ν_lar, are between ν_val/ν_lar ≈ 0.1 and ν_val/ν_lar ≈ 1. The ν_val/ν_lar ratio exhibits a strong dependence on thermal stratification, δ, and decreases from ν_val/ν_lar ≈ 1 at δ = 0 K m⁻¹ to ν_val/ν_lar ≈ 0.2 at δ = 0.0075 K m⁻¹. In areas, where the lateral mountainous border of the Rhine valley is interrupted, the ν_val/ν_lar ratio increases again with increasing stability or decreasing Froude number. This is obviously due to flow around the Black Forest under stable stratification. It is demonstrated by model calculations that a complex wind field develops in the Rhine valley at small Froude numbers (Fr < 1) irrespective of the direction of large-scale flow. The ν_val/ν_lar ratio is characterized by small values in the direct lee side (ν_val/ν_lar ≈ 0.2) and high values on the windward side of the lateral mountainous border of the Rhine valley (ν_val/ν_lar ≈ 0.8). Received October 22, 2001; revised June 18, 2002; accepted June 23, 2002     

North Sea – Caspian Pattern (NCP) – an upper level atmospheric teleconnection affecting the eastern Mediterranean – implications on the regional climate

Summary ?A calendar of the negative and positive phases of the North Sea – Caspian Pattern (NCP) for the period 1958–1998 was used to analyse the implication of the NCP upper level teleconnections on the regional climate of the eastern Mediterranean basin. Series of monthly mean air temperature and monthly total rainfall from 33 stations across Greece, Turkey and Israel, for the same period, were used. For each month, from October to April, averages of the monthly mean temperatures and the monthly rainfall totals as well as the standardized values of both parameters were calculated separately for the negative (NCP (−)) and the positive (NCP (+)) phases of the NCP. At all stations and in all months, temperature values were significantly higher during the NCP (−) as compared with the NCP (+). Furthermore, apart from very few exceptions, the absolute monthly mean maximum and monthly mean minimum values were obtained during the NCP (−) and the NCP (+) phases, respectively. The maximum impact of the NCP on mean air temperature was detected in the continental Anatolian Plateau, where the mean seasonal differences are around 3.5 °C. This influence decreases westwards and southwards. The influence on the rainfall regime is more complex. Regions exposed to the southern maritime trajectories, in Greece and in Turkey, receive more rainfall during the NCP (−) phase, whereas in the regions exposed to the northern maritime trajectories, such as Crete in Greece, the Black Sea region in Turkey, and in all regions of Israel, there is more rainfall during the NCP (+) phase. The accumulated rainfall differences between the two phases are over 50% of the seasonal average for some stations. A comparison of the capabilities of the NCP, the North Atlantic Oscillation (NAO) and the Southern Oscillation (SO) indices to differentiate between below and above normal temperatures was made. The results have placed the NCP, as the best by far of all three teleconnections in its ability to differentiate between below or above normal temperatures and as the main teleconnection affecting the climate of the Balkans, the Anatolian Peninsula and the Middle East. These results may serve to downscale General Circulation Model (GCM) scenarios to a regional scale and provide forecasts regarding eventual temperature and/or precipitation changes. Received June 25, 2001; revised February 25, 2002; accepted March 3, 2002     

Impacts of Large-Scale Surface Modifications on Meteorological Conditions and Energy Use: A 10-Region Modeling Study

Summary  This paper summarizes results from a mesoscale modeling study to quantify the possible meteorological and energy-use impacts of large-scale increases in surface albedo and vegetative fraction. Ten regions in the U.S. were characterized and simulated in base- and modified-surface conditions. Time- and space-dependent meteorological variables were simulated for each region in four 3-day episodes to represent a range of seasonal variations. Using a simple interpolative procedure, a complete year of hourly weather data was created for each region (based on episodic meteorological simulation results) and input into energy-use models. The modified weather input was used to assess the effects of large-scale albedo and vegetative fraction changes on annual energy consumption in each of the ten areas targeted in this study. The simulations suggest annual electricity savings of between 1and 6.7 kWh m⁻² (of roof area) in residential neighborhoods and between 2 and 6.1 kWh m⁻² in office areas, depending on region. Annual gas penalties amount to up to 34.8 MJ m⁻² (of roof area) in residential neighborhoods and up to 21.1 MJ m⁻² in office areas. Received December 1, 1996 Revised May 11, 1998     

Spatial Heating Monthly Degree-Day Features and ClimatologicPatterns in Turkey

Summary  Degree-days as a measure of accumulated temperature deviations from a base temperature have many practical applications in various human related activities such as home cooling, heating, plant growth in agriculture and power generation in addition to energy requirement. Long temperature records are necessary for their reliable estimations at given stations. In this paper, degree-day measure has been applied to monthly temperature records for systematically changed base temperature values from − 25 °C to + 35 °C with 5 °C increments at 255 meteorology stations in Turkey. The results are represented in the form of spatial degree-day distribution maps, which are then related to various climatic, meteorological and topographic features of Turkey. For instance, free surface water bodies in forms of surrounding seas, lakes and rivers insert retardation in the expansion of heating degree-days over large regions. On the other hand, cold air penetration from polar regions in the northeastern Turkey originating from Siberia appears at moderate base temperature heating degree-days. Received August 20, 1998 Revised June 21, 1999     

Kinetics of the reactions of soot surface-bound polycyclic aromatic hydrocarbons with NO<Subscript>2</Subscript>

The kinetics of heterogeneous reactions of NO₂ with 17 polycyclic aromatic hydrocarbons (PAHs) adsorbed on laboratory generated kerosene soot surface was studied over the temperature range (255–330) K in a low pressure flow reactor combined with an electron-impact mass spectrometer. The kinetics of soot-bound PAH consumption due to their desorption and reaction with NO₂ were monitored using off-line HPLC measurements of their concentrations in soot samples as a function of reaction time, NO₂ concentrations in the gas phase being analyzed by mass spectrometer. No measurable decay of PAHs due to the reaction with NO₂ was observed under experimental conditions of the study (maximum NO₂ concentration of 5.5 × 10¹⁴ molecule cm⁻³ and reaction time of 45 min), which allowed to determine the upper limits of the first-order rate constants for the heterogeneous reactions of 17 soot-bound PAHs with NO₂: k < 5.0 × 10⁻⁵ s⁻¹ (for most PAHs studied). Comparison of these results to previous studies carried on different carbonaceous substrates, showed that heterogeneous reactivity of PAHs towards NO₂ is, probably, dependent on the substrate nature even for resembling, although different carbonaceous materials. Results show that particulate PAHs degradation by NO₂ alone is of minor importance in the atmosphere